Professional Documents
Culture Documents
ADRIAN BEJAN
I. Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
A. Second-Law Analysis in Engineering . . . . . . . . . . . . . . . . . . . . 2
B. Second-Law Analysis in Heat Transfer . . . . . . . . . . . . . . . . . . . 3
11. Irreversibility, Entropy Generation, and Lost Available Work
(Lost Exergy). . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
A. Opensystems . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
B. The Absolute Temperature Factor To . . . . . . . . . . . . . . . . . . . . 8
111. Local Entropy Generation in Convective Heat Transfer . . . . . . . . . . . . I1
A. Conductive versus Viscous Effects . . . . . . . . . . . . . . . . . . . . . 12
B. Entropy Generation Profiles and Maps . . . . . . . . . . . . . . . . . . . 13
C. The Entropy Generation Number Ns . . . . . . . . . . . . . . . . . . . . 16
D. The Impact of Heat Transfer Augmentation on Entropy Generation . . . 21
IV. Entropy Generation Minimization in Heat Exchanger Design . . . . . . . . . 25
A. Heat Exchangers with Zero Pressure Drop . . . . . . . . . . . . . . . . . 27
B. Heat Exchanger Geometry for Minimum Irreversibility . . . . . . . . . . 29
C. Sensible Heat Units for Energy Storage . . . . . . . . . . . . . . . . . . 34
V. Thermal Insulation Systems . . . . . . . . . . . . . . . . . . . . . . . . . . . 38
A. Minimization of Entropy Generation in an Insulation System
of Fixed Identity . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
B. Engineering Applications . . . . . . . . . . . . . . . . . . . . . . . . . . 43
VI. Concluding Remarks . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
Nomenclature . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
References.. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 54
Note Added in Proof . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
I. Introduction
A. SECOND-LAW
ANAL YSlS I N ENGINEERING
At the root of the growing interest in the thermodynamic irreversibility
of heat transfer lies the emphasis placed today on energy conservation
and the efficient use of energy. In any power plant, for example, the ther-
modynamic nonideality (irreversibility) of any of its engineering compo-
nents causes a decrease in the net power output of the cycle. Likewise, in
a refrigeration plant the irreversibility accumulated over various compo-
nents leads to an increase in the mechanical power input required by the
refrigeration cycle. Either way, the thermodynamic irreversibility of com-
ponents such as heat exchangers, mixers, turbines, and compressors
amounts to a penalty in otherwise available work or, on a unit time basis,
available mechanical power. From an engineering standpoint, it makes
good sense to first identify the irreversibility associated with various com-
ponents and, second, to design for less irreversibility in order to avoid the
imminent loss of available mechanical power.
The above conclusion follows directly from the sirrzultaneous consider-
ation of the first and second laws of thermodynamics,* as we demonstriate
in greater detail in the next section. This is certainly not a new conclusion,
its first statement and engineering use dating back to the work of Gouy [I]
and Stodola [2]. Since then, the same principle was restated by others,
who in the process clarified its implications and made it more accessible
to engineering practice [3-61.
Today, there is a growing consensus that irreversibility analysis is a
powerful approach, in fact, the only one, to deciding which installation or
process is efficient or inefficient [7, 81. In addition, through irreversibility
minimization the engineer can make specific design decisions aimed at
conserving available work. Citing only a few examples, this approach and
its relation to cost minimization was exploited by Tribus and Evans [9] in
a cornerstone study of the thermoeconomics of seawater desalination.
More recently Kestin c’t ( I / . [ 10, 113 established the thermodynamic faun-
dations for evaluating the available work potential of geothermal installa-
tions. Gaggioli, Wepfer, and Elkouh [ 121 relied on second-law concepts to
show the great margin for improvement present in the contemporary de-
* In the thermal engineering literature, this procedure is recognized simply as “second-
law analysis.”
St-cO N I ) - L A W
ANALYSIS 3
I N HF.AI TRANSFER
B. SEWND-LAWAN.AL~YSIS
The place occupied by heat transfer and thermal design in the greater
picture described so far is central. Engineering components and devices
for heat transfer are inherently irreversible. For example. a two-fluid
counterflow heat exchanger draws its irreversibility from two distinct
mechanisms, namely. heat transfer across the stream-to-stream tempera-
ture difference and fluid friction (pressure drop) in the two flow passages.
We shall consider this example in detail in Section I l l . For now, it is nec-
essary to keep in mind how common and indispensable heat exchangers
are in power systems and in many other applications. This underlines the
important connection which muht be made between heat transfer and fluid
mechanics, on the one hand, and thermodynamic irreversibility. on the
other.
The ultimate motive behind the infusion of entropy generation analysis
in heat transfer and thermal design is economic. Consider for a moment
the many factors which affect the decision of whether one thermal system
design is better than another [ 191. A number of these factors are political
in nature, but, to a large extent, the decision is the result of a cost-benefit
analysis, which takes into account the expense associated with manufac-
turing the device (capital cost) and the expense associated with running
the device (operating cost). The combination of design parameters which
yields the minimum cost subject to various constraints represents the eco-
nomic optimum design. An important component in the cost analysis is
the degree of thermodynamic ineffectiveness exhibited by the device.
This component is the cost of electrical power required by the device
when it functions in t h e sense o f a wor-k-absorbing thermal system. or the
revenue derived from the sale of electrical power when the device func-
tions in the work-producing mode. I t is clear that minimizing irrevers-
ibility in the thermal system yields a decrease in the operating cost. This
effect is usually accompanied by a parallel increase in the capital cost,
which demonstrates that the least irreversible design is not necessarily the
economic optimum. However. in order to make a sound economic deci-
4 ADRIANBEJAN
sion, the thermal designer must understand the true thermodynamic per-
formance of the heat transfer device; in other words, the designer must
know the irre versibiliry picture .
The work which lies ahead of heat transfer engineers, researchers, and
educators is to finally make the connection, to fill the gap, between the
traditional practice of heat transfer and the contemporary implications of
the second law. This is an activity which must be pursued in engineering
schools as well as in industrial circles, at the fundamental and applied
level as well. In order to be able to minimize the thermodynamic irrevers-
ibility of heat transfer equipment, engineers must first understand the fun-
damentals of the entropy generation mechanism. Also, they must under-
stand precisely "where" in the heat transfer device irreversibility is being
produced, and "how much" is being produced locally. This requirement
is very similar to the relevance of "local" Nusselt number and skin fric-
tion information to the conceptual design of efficient and compact heat ex-
changers.
In this contribution the reader is exposed to a summary of first steps in
the direction of second-law analysis in basic heat transfer and thermal tie-
sign. The presentation is intended to introduce the inexperienced reader
to the new methodology of irreversibility analysis and irreversibility mini-
mization in heat transfer. At the same time, the article is intended to show
the experienced heat transfer researcher the wealth of research opportu-
nity which exists in this growing sector of heat transfer. The monograph
stops short of investigating the relationship between irreversibility mini-
mization in thermal design and economic optimization of heat transfer
equipment. However, a number of thoughts in this direction are offered in
Section VI.
In writing the article. this author made a special effort to bring together
as much of the existing heat transfer irreversibility work as possible.
Despite the relative absence of publications on this subject, it is possible
that many workers in heat transfer have entertained second-law ideas
over the recent past. If so, it is hoped that through this article a more ef-
fective dialogue is initiated.
It has been pointed out already that the concept of thermodynamic irre-
versibility and its relation to the one-way destruction of available work
are not new. Brief expositions of this subject are found in some of the
SEC O N I I - L A W ANALYSIS 5
A. O P E NSYSTEMS
Consider the open thermodynamic system shown schematically in Fig.
1, which is the most general model of a heat transfer device such as a heat
exchanger. The system is said to operate in steady state and steady flow.
This means that the thermodynamic state of matter surrounded by the
control surface does not vary with time, although it can vary from one
point t o another inside the control surface. In addition, the mass streams
piercing the control surface. mi and m k , are constant in time. The thermo-
dynamic state at each of the inlet or outlet ports is represented by proper-
ties averaged over the port cross section; in other words, the bulk flow
model applies. The energy transfer interactions exhibited by the system
are shaft (shear) work transfer at a rate W , and heat transfer at a rate Qo.
The positive sense of these interactions is assumed as shown in Fig. I .
The system is in thermal communication with the environment, which is
modeled as a heat reservoir o f temperature T o . Most importantly, how-
ever, the control surface is drawn to include the actual heat transfer de-
vice p/rr.s those immediately adjacent parts of the environment affected by
the functioning of the device. This choice makes the heat transfer interac-
tion Qo reversible. as it takes place across an infinitely small temperature
difference. As will soon become apparent, this choice is motivated by the
cw SYSTEM
-- I
-- '1
inlet
m, -
' HEAT , outlet
(I) rnz - TRANSFER (k)
DEVICE 1
To .~
>
~i~L Qo
In writing the first law we assumed that the changes in kinetic energy and
gravitational potential energy experienced by streams mi and mk are neg-
ligible compared with the enthalpy changes retained in Eq. (2.1). The neg-
ative of the right-hand 4ide of Eq. (2.2) is the net rate of entropy genera-
tion in the system, S,,,, , a quantity which is always positive and in fhe
reversible limit equal to zero:
S,en = C
k
(ms)k - C (ms)i - Qo/To
1
(2.3)
(2.4)
I=I k=1
describing an upper bound for the work transfer* of which the system of
Fig. 1 is capable. As indicated in Eq. (2.4), the algebraically maximum
work W,,, is achieved through reversible operation, i.e.,
w,, = 9 mi(h
!=I
- T,S)i -
k=l
mk(h - ToS)k (2..5)
* In what follows we use the terms"work transfer" and "heat transfer" for W and Q o ,
respectively, instead of the unit time terminology of "mechanical power transfer" and "heat
transfer rate."
SECONI)-LAWANALYSIS 7
ACTUAL
WORK
YAXIYUY
AVAILABLE
WORK
'LOST
AVAILABLE
AVAILABILITY
WORK
OUT
FIG.2. Schematic representation of availability analysis of a thermodynamic system.
8 ADRIANBEJAN
B. THE ABSOLUTE
TEMPERATURE
FACTORTo
Instead of Fig. 1, let u s focus on a system in communication with more
than one heat reservoir. The new system is shown in Fig. 3, where it is as-
sumed that the system executes an integral number of cycles experiencing
the net energy interactions Qi (i = 0, 1, ..., n ) and W . For simplicity, we
consider a closed system. Again, the system boundary is chosen such that
all irreversibilities, if present, are located inside the system.
The analysis presented below is based on a communication by Jackson
[29]. In a manner identical to the preceding analysis, we apply the first and
second laws of thermodynamics to obtain
W = i Q i
i=l
(2.9)
i=O
S t c or. 1)- L. 4 w ANALYSIS
Fit,. 3 . Closed system operating 111 c y c l e 5 while in thermal communication wilh n heat
reservoir\.
and
(2.12)
(3.2)
In Eq. ( 3 . 2 ) .us, r u , and I > , are the local velocity components in the Carte-
sian system.
From examining Eqs. ( 3 . I ) and (3.2) it is evident that high temperature
and velocity gradients are the features responsible for entropy generation
in the convective heat transfer situation considered here. Another impor-
tant effect likely to influence S"' .. is the variation in absolute temperature
through the continuum. For the same temperature and velocity gradients,
S"' increases as the temperature of the medium decreases. This effect is
exploited in Section V . in the minimization of entropy generation in
systems exposed to large variations in absolute temperature. In most heat
transfer applications. however. it is safe to replace T appearing as denom-
* Note that for the remainder of the al-trcle we are dropping the subscrrpt "gen" in the
symbol for entropy generation rate. The prrnles indicate the local character of S. 1.e.. per
unit volume S " ' (W/m.'). per unit area .Y'" (Wlm'). or per unit length S ' t W / m ) .
12 ADRIANBEJAN
A. CONDUCTIVE
VERSUS VISCOUSEFFECTS
This is particularly true in the case of subsonic gas flow. It is easy to show
that the order of magnitude of p@ relative to the conduction part in Eq.
(3.8) is dictated by the dimensionless group EcPr [36]. In other words, in
convective heat transfer problems in which the energy conservation state-
ment may be considered without the viscous dissipation term, the group
EcPr is much smaller than unity.
St-cON [>-LAWA Y A L Y S I S 13
Comparing this conclusion with Eq. (3.4) we see that the energy argu-
ment by which Eq. ( 3 . 8 ) is regularly simplified has absolutely no bearing
on the question on whether or not the viscous dissipation effect is neg-
ligible in the makeup of entropy generation. It is quite possible to have a
heat transfer problem where, although the energy equation can be simpli-
fied according to EcPr e I , the entropy generation figure is in fact domi-
nated by viscous effects. This is the case in which T is so small that the ag-
gregate group EcPr/T is actually of order one. This observation is moti-
vated by the fact that sometimes, perhaps suggested by first-law rules of
thumb and the desire to simplify the analysis, the viscous effect is
neglected ( I priori in the second-law treatment of convective heat transfer
processes.
0 0.5 1
R
FIG.4. Entropy generation profiles for heat transfer to laminar pipe flow [34].
depends on the radial position R, on the Peclet number Pe, and on the
group EcPr/7, which determines the relative importance of viscous ef-
fects. The Peclet number governs the relative importance of irreversibility
due to conduction in the longitudinal direction. We see that when Pe < 4,
the axial conduction contribution dominates the radial conduction effect.
Figure 4 displays a family of entropy generation profiles in the cross
section, for cases in which the axial conduction effect is negligible, Pe 4
4.The value of ECPr/T increases gradually to the point where viscous ef-
fects take over. In all cases, the pipe wall region acts as a strong source of
irreversibility. When E3cPr/T = 0, the maximum S”’ occurs inside the
fluid, at R = <+, the same place where due to the wall curvature effect
the maximum temperature gradient is located. As viscous effects take
over, the point of highest irreversibility migrates toward the wall and, for
EcPr/.r > f , it coincides with the wall.
As a second example, consider the development of laminar momentiim
and thermal boundary layers along a flat plate. The situation is shown
schematically in the horizontal plane of the isometric drawing of Fig. 5 . At
a sufficiently large distance away from the solid wall the velocity and tem-
perature are uniform, vX,= and T , . The wall temperature is constant, I”*.
The entropy generation surface presented in Fig. 5 is based on the c1,as-
sical Blasius-Pohlhausen solution [38] which, for the special case Pr = 1,
StC'ONl)-l,,4W ANALYSIS
FIG. 5 . Entropy generation \urface foi- laminar boundary flow and heat transfer over a
flat plate [34].
reduces to
HIH, = Ltfldr) (3.14)
V J 1 J . X = (ltldr) (3.15)
The similarity variable r) is equal to v ~ c ~ , ~ / ( u x while
) ] ~ ~ *f (, q ) I \ the func-
tion tabulated by Howarth [39] Combining solutions (3.14) and (3.15)
16 ADRIANBEJAN
with the S"' formula (3.11, and neglecting the terms associated with gra-
dients in the longitudinal direction x, yields
( S " ' / k )(vT*/f3muz,,)2 = (1 + Ec/7)fl12/Rez (3.16)
Here, Re, is the Reynolds number u,,,x/v. The three-dimensional display
of Fig. 5 was constructed using (xz),,,/v) and ( y u , , , / v ) in the horizontal
plane andfl12/Re, in the vertical direction. It is evident that the entropy
generation is limited to the boundary layer. In the y direction, S""is
highest, reaching a maximum at the solid wall. The longitudinal variation
of S"' is as l / x , indicating that like all gradients in the boundary layer so-
lution S"' blows up at the origin.
Entropy generation profiles of the type presented in Figs. 4 and 5 may
be constructed for other basic laminar flow solutions. More examples of
such plots may be found in Bejan [34]. However instructive, this visuali-
zation technique is limited to laminar solutions for which analytical ex-
pressions (exact or approximate) for velocity and temperature may be
available. In turbulent flow one has to rely on average (integral) heat
transfer and friction results, condensed in experimental correlations. 'The
method by which the experimental heat transfer and fluid friction informa-
tion is combined to reveal the irreversibility picture is presented in the
next paragraph.
c. THE ENTROPYGtVtRATlON N U M B E RN s
,,-qr
Consider a duct of arbitrary cross section, shown schematically as a
round tube in Fig. 6. The sketch represents an infinitesimally short pas-
sage in a heat exchanger, for example. The heat flux per unit length q ' , the
mass flow rate m ,the wetted perimeter p , and the cross-sectional area A
are specified. In steady state a finite temperature difference AT exists
between the wall and the bulk temperature of the fluid. The schematic
Fig. 6 also applies to ducts with the cross section varying periodically in
- 1
m,P,T ''
-m,P-dP,T+ dT
',
\ j j
P
1-dx-I
FIG. 6. Infiiiitesimally short duct in a heat transfer device.
St C O N 0-1 A W A N A L Y S I S 17
the flow direction. I n such ciiseh, q ' represents the heat flux averaged
over a length L containing an integral number of periods, whereas A be-
comes the minimum flow area.
It can be shown that for ( i t / \ ' prrrc' . s r r h s r m n c . c ~ flowing through the
system, the rate of entropy generation per unit length is [40]
(3.17)
We recognize here the contribution due to fluid friction in the duct. the
first term in Eq. (3.17), and the irreversibility due to heat transfer across a
nonzero temperature difference. I n many cases the temperature dif-
ference number 7 = 1777' is much smaller than unity; hence. one can
write ap prox imatel y
(3.18)
i
-2 ~
-4
FIG. 8. The entropy generation number as a function of A and the ratio of heat transfer
coefficient to fluid pumping power R , Eq. (3.31) [40].
imum: for sufficiently small value\ of A . the optimum ratio i \
R,,p, 3IA (3.34)
Based o n Fig. 8 and Eq. (3.33). we conclude that increasing the ratio of
heat transfer coefficient to pumping power ( R )is not ,sii,jfic.ic,iir to ensure
improved thermodynamic performance, Since N s , depends o n more than
just R . the true effect of a proposed design change can only be evaluated
by estimating the changes induced in R and A , and eventually in N S , .
- xi - i-X , i
(0) lb)
FIG. 9. Heat transfer augmentation by finning a bank of tubes in cross flow: (a) smooth
tubes; (b) finned tubes.
o,l , , 1 , l L l L ~ IU ~ i - I1
L:
2 10 100
Re, x I 0-3
F I G . 10. Entropy generation number due to heat transfer augmentation, N,,,, versus ref-
erence surface parameters Re, and 4, .
mately the same array geometry, an inconsistency which does not affect
the main conclusions of this example.
The results of evaluating the available work conservation potential of
finning are summarized in Figs. 10 and 11. The entropy generation
number, Eq. (3.36), was plotted in Fig. 10 based on friction factor and
Stanton number data compiled by Kays and London [48]. It is evident
that, depending on the value of & , the augmentation techniques under
study can either decrease or increase the rate of available work destruc-
tion in the heat transfer device. There exists a special class of reference
<I
-’
a1
’ a2
2 10 100
Re, x I O - ~
FIG. 11. The function &,,(Ke,) for Ns.a= I . corresponding to three different finning
techniques.
SI-CONI)-LAW ANALYSIS 25
HEATER EXPANDER
p2
I
REGENERATIVE
I
HEAT EXCHANGER
COMPRESSOR COOLER
ENTROPY
FIG.12. Countertlow heat exchanger for a Brayton cycle heat engine [42].
pressure drop in the regenerative heat exchanger; (2) the inlet to the
heater is already as hot as possible, i.e., as hot as the expander outlet; and
(3) the inlet to the cooler is as cold as the compressor outlet. This limiting
case corresponds to a completely reversible regenerator (AT = 0, A P =
0). From this example it is apparent that the effective stream-to-stream
heat exchange in the regenerator is only one of the by-products of its true
function, that of allowing the hot and cold ends of the power cycle to corn-
municate (trade fluid) in the least irreversible manner. As discussed in
Section V,B,3, the function of the regenerative heat exchanger is to
practically insulate the hot end of the cycle from the cold end.”
McClintock [51] appears to have been the first to recognize that the
concept of irreversibility minimization has a definite place in heat ex-
changer design. In a generally unnoticed conference article, McClintock
establishes the connection between Keenan’s “irreversibility” quantity
as a means of measuring thermodynamic nonideality [24] and the engi-
neering task of designing efficient heat exchangers. He discusses the irre-
(4.1)
where T I , Tz are the inlet absolute temperatures of the two streams and
N,, is the number of heat transfer units UAlmc,. This result is shown
plotted in Fig. 13 as Sarn/tnc.,,versus the heat exchanger effectiveness E,
which in the example shown here is given by
€ = Nt,/( 1 + N,,) (4.2)
28 ADRIANBEJAN
Nt.
0 0.2 0.5 I 2 4 10 a
FIG. 13. Entropy generation rate in a balanced counterflow heat exchanger with zero
pressure drop. (After Tribus [54].)
The symmetry of Eq. (4.1) is reflected graphically in Fig. 13. The en-
tropy generation rate is invariant to the transformation T 1 / T z+ T z / T , ,
meaning that in Fig. 14 the absolute temperature may be measured in
either direction on the abscissa. In other words, Tl may be assigned to
either the warm inlet or the cold inlet without changing the appearance of
result (4.1).
The entropy generation rate reaches a clear maximum when N,, = 1,
maximum given by
Sec"/ln('P = In[* + i(Tl/TZ + Tz/T,)I (4.3)
This feature is not intuitively obvious since we would expect the heat
ii
STREAM 2
CONTROL
VOLUME
/ TI T*
TE M P E R ATUR E
STREAM 1
FIG. 14. Schematic of counterflow heat exchanger with imbalanced capacity rates [42].
Sc( Y N I)- 1,A w A NA L Y s I s 29
where subscripts C. H. out, and in refer to the cold stream, hot stream.
outlet, and inlet, respectively. The "+" sign applies to counteiflow and
the sign to parallel flow. l h i s expression holds for ideal gases and
L b _ ' '
B. H t . 4 1 E X C H A N ( ; t R GF.OMI I K Y F-OK M I N I M U M I R R E V t R S I R I I . I I Y
2 have been associated with the minimum and maximum capacity rates
(rnc,) in counterflow. Defining the entropy generation number N, in the
manner indicated in Eq. (3.24),
Here, R is the ideal gas constant, the rest of the symbols having been de-
fined in Fig. 14 and in the Nomenclature.
Equation (4.7) is based on the assumption that the heat exchanger is
“nearly ideal,” in other words, (AP/P)l,ze 1 and 1 - E 6 1, where E is
the effectiveness (Tl,out- T1)/(Tz - T I ) .This assumption makes visible in
Eq. (4.7) the two mechanisms responsible for entropy generation. The
first two terms account for irreversibility due to heat transfer betwee:n
streams, across a nonzero temperature difference. The last two terms,
individually, represent the fluid friction effect in each of the two ducts of
the heat exchanger. It is easy to see that in the Ntu + limit the second
term vanishes, and the AT irreversibility is due solely to flow imbalance
(Cmax> Cmin).Figure 15 shows how the imbalance contribution to N F ,
the first term in Eq. (4.71, varies with the capacity ratio and the absolute
temperature ratio. From a practical fiesign viewpoint, it is important 1.0
know the magnitude of the imbalance contribution when one seeks to
minimize N, by increasing the N,, and by decreasing the friction AP’s: the
imbalance component tells the designer when he or she has reached the
point of diminishing returns in the minimization of overall Ns, since in the
limit N,, -+ 00, APl,z-+ 0. the imbalance term is the sole survivor in
Eq. (4.7).
A further simplification of the Ns Eq. (4.7) is achieved when one con-
siders the case of nearly balanced capacity rates, Cmin= CmaX . Applying
the calculus limits as C,,in C,,,, the number of entropy generation
-+
units becomes
St,c ONIFLAWANALYSIS 31
10 ’
10’ 1 1 ,
05 1 2
1, 1,
F I G . IS. The entropy generation due l o capacity rate imbalance in a counterflow heat ex-
changer [4?].
where
NS.irnhalancv = [(~nla,/(’,nln) - I I [(];/TI) - I - In 72/71] (4.9)
N,y, = [ ( T 2 / T 1 ) 1 2- (7‘,/7;)1’’]2 N,’,
+ (c’min/crnax)
(Klc,,,),( A P / P ) , (4.10)
N,?, = (C’,,,,,,/C,,,,,,)
[(72/7’1)1’2 - (T1/T2)”*12N& + ( R / ( . , ) , ( A P / P ) ,
(4.11)
In this limit Nshas separate terms describing the rate of entropy genera-
tion o n each of the two sides of the heat exchanger. Moreover, the irre-
versibility of each side N s , , , appears a s the sum of one contribution due to
heat exchanger A T and one contribution due to frictional AP losses:
N.5, 2 =: +
Ns.A~r,:? NS,AP,.P (4.12)
This form is similar to the f o r m of N,, for an elementary heat exchanger
passage. Eq. (4. I). Equation ( 4 . 8 ) is pivotal in the design process, as it
permits the minimization of N , , for each side of the heat exchanger. sepa-
rately. Furthermore. the analytical form of N,, and N,, is similar (iden-
tical in the balanced flow case). s o that the design procedure for each side
is the same.
Equation (4.15) contains the usual heat exchanger notation, where, in ad-
dition, we defined
a, = 1, a2 = Cmin/Crnax (4.16)
b1 = Crnin/ Cm ax b, = 1 (4.17)
70 = [ ( T , / T , Y - (Tl/T2)”’]2, g = G/(2pP)”’ (4.18)
Thus, g plays the role of dimensionless mass velocity, while T~ has the
same significance as the temperature difference number ( 7 ) relative to the
difference between inlet temperatures, TI and T,.
The dependence of N s , , , on design parameters such as Re, 4L/D, andl g
is shown qualitatively on the three-dimensional logarithmic plot of Fig.
16. The graphic construction of Fig. 16 is actually based on empirical data
on turbulent flow inside smooth tubes, where both St and f a r e propor-
tional to Rep0.,; one can construct qualitatively similar three-dimensional
plots for other heat exchanger surfaces.
(4.19)
and
= 2g[abr0 (R/c,) (jC/St)]1/2 (4.20)
For common heat exchanger surfaces the group (f/St)1/2is only a weak
function of the Reynolds number [42]. Therefore, Eq. (4.20) establishes a
SECONI)-LAW
ANALYSIS 33
FIG. Ih. Number of entropy generation units for one side of the heat exchanger, as a
function of L / r , , . g. and hRt.
(hence r , , = 11/41 [4!].
C . SENSIBLE
H E A I U U I T SFOR ENERGYSTORAGE
As a second example consider the minimization of irreversibility i.n a
sensible heat unit for energy storage. Traditionally, the thermal design
and optimization of a sensible heat storage unit relies on the view that the
system thermal Performance can be assessed based on how much thermal
energy the unit can store. In short, a unit is considered more efficient than
another if-for the same heat input and the same amount of storage
material-it is capable of storing more thermal energy. This point of view
is generally accepted and serves as basis for testing and evaluating the
thermal performance of sensible heat (fluid and solid) storage units [57].
Bejan [S8] analyzed t h e performance of such units by treating them as
systems intended to store available work, the function they perform in
most power applications.
Consider, for example, the system shown schematically in Fig. 17. It
consists of a large liquid bath of mass M and specific heat C placed in an
insulated vessel. Hot gas enters the system through one port, is cooled by
flowing through a gas-liquid heat exchanger immersed in the bath, and is
eventually discharged into the atmosphere. Gradually, the bath tempera-
ture T as well as the gas outlet temperature To,, rise, approaching the hot
gas inlet temperature 7', . It is assumed initially that the bath temperature
equals the environment temperature T o . The bath is filled with an incom-
pressible liquid such as water or oil. The stream m carries an ideal gas, for
example, high-temperat ure steam or air. The stream of hot gas is supplied
continuously at T , and P o ; before entering the unit, the stream is com-
pressed to Po + AP in order to overcome the pressure drop caused by
friction in the heat exchanger.
The time dependence of the bath temperature and the gas outlet tem-
perature can be derived analytically and the result is available in the engi-
neering literature [S9]. Of interest here is the total amount of entropy gen-
erated from the beginning of the charging process until an arbitrary time r
(S/mc,t) = (R/c,,) In(l + AP/Po)+ T - (1 + T)
+ 0-'{ln[l + ~ ( -1 c ~ " ) ] - ~ ( -
1 e-"")} (4.21)
In Eq. (4.21),T is the dimensionless temperature difference ( T , - T o ) / T o ,
while 8 is a number proportional to the elapsed time, i.e., the total quan-
tity of hot gas used over a given time period t :
0 = mc,t/MC (4.22)
.1 1 q u ~ dh s a l exchanger
Fic, 17 Schematic 01 wnwhle hedt (trill l o i energy storage from d 5tre.inl ot hlgh temper-
ature g ~ [ \i x ]
where A is the total heat transfer area on the gas side, U is the overall heat
transfer coefficient based on A . and UA/(rwc,) is the heat exchanger
number of transfer u n i t \ N,, .
According to the Gouy-Stodola theorem (2.7), T,S given by Eq. (4.71)
equals the available work destroyed due to process irreversibility. We can
compare the lost portion of the ;ivailable work with the maximum avail-
able work associated with the same amount of hot gas, m(',,/.
ct',,,,, = IW,J I,, [T - In(l + TI] (4.24)
Equation (4.24)is based o n calculating the drop if gas availability from the
.
inlet condition T , P,, , before compression to Po + A P . to the "dead"
state T o , P o . Dividing Eqs. (4.7I ) and (4.74)side by side, one arrives at the
number of entropy generation units for the 0 -+ (3 heating (charging)
From Eqs. (4.21)and (4.24). i t is easy to see that .'V, will again
have two parts, one describing irreversibility caused by friction. the other
irreversibility due to heat transfer across the nonideal heat exchanger
surface:
%AT
0 5
0 5
8-
FIG. 18. Entropy generation caused by heat transfer across a finite temperature dif-
ference, as a function of heat exchanger N , , , temperature difference T, and charging time 8:
(a) T = 0 ; ( b ) T = I : (c) T = 2 [5X].
S t u )hi I )- LAw A NA L Y S Is 37
!
0 1 2 3
T, - T<,
-
To
Fit, I9 Optimum \tornge ternperdure l o r niinirnurn destruction of avdilnble uork during
the chdrging process 1581
initially at 7 0 . In the c) + x limit, the gas stream exits the heat ex-
changer as hot as it enters: its available work content is again dissipated
entirely by direct heat transfer to atmospheric temperature.
The optimum time t),,,, and the corresponding Ny,yT can be determined
as functions of N,,, and T. An interesting result associated with this op-
timum situation is the optimum temperature of the sensible heat u n i t , re-
produced here in Fig. 19. We see that when the storage unit operates at
the optimum, the total amount of thermal energy stored as sensible heat at
the end of the charging proce\s. hlC( - To),is far from the maximum
TL T, Q, I
J
''
/'"
20. The first conclusion is that thermal insulation systems. as a class. are
varied, numerous. and complex. There is considerably more to this class
than the textbook-style example shown in Fig. 20a. The second conclu-
sion which must be stressed in this article is that the heat transfer from 7-k,
to 7; is ~ r o lticc~es.wr-ilyc . o r i . s f t i r r / across the insulation. In a heat engine.
for example, the heat transfer decreases in magnitude, a decrease which
accounts for the net work output of the engine. Therefore. applying again
the Gouy-Stodola theorem ( 2 . 7 ) . i t makes perfect sense to inquire into
the possibility of reducing the irreversibility of an insulation system. par-
ticularly in large-scale power- refrigeration applications. The objective of
this design procedure is to squecre the most available work out of a given
insulation system, in the manner illustrated in Fig. 20b.
A. M I N I M I L A T I O N
OF ENTROPk G t N F R A T l O N IN A N
1 N S l I L A l I O N S l S I t - M Of- FIX1 1) I1)F:NTITY
(5.3)
I
.'I2
y,,,,,(T)= 7 A 1 ' ( A / / ) tlT
(klP2IT) (5.4)
1 'I1
(j
.I2
sign. there exists an infinity ofde\igns in which q ( T ) may or may not come
close to q,,,,,(T).The ability of achieving a heat transfer distribution y ( T )
which closely resembles 4(,,,41’)depends on the amount and distribution of
lateral heat transfer effect.
We learn by examining Fig. 2 2 that insulation systems exposed to large
absolute temperature ratios p,.\tand to benefit most from a de\ign where
the heat leak function is controlled externally via principle ( 5 . 4 ) . Cryo-
genic insulations are examples of such systems. Below. we review a
number of applications in which low-temperature systems are thermody-
namically optimized from the viewpoint of irreversibility minimiz a t ion ’
discussed in this monograph.
B. E N G I N E [ - R I APPI
N G I( AIIOV\
1. M l J c . / l l r l l i c ~ t rSlr/’po’t
l 5
COOLANT m,cp
8L - 8”
’ t t t t t t
4, -t - 4 I\ I- 4”
A , k(T)
HEAT CURRENT
0 x L
FIG. 23. Intermediate cooling effect provided by a stream of cold helium gas in counter-
flow with the conduction heat flow through a structural support [69].
capacity rate of this stream is mc,, then the support heat leak varies ac-
cording to dq/dT = rnc,, . If the support conductivity is temperature inde-
pendent and if the stream flow rate is selected such that m c , =
( A k l / r )In(T,/T,), then, from Table 11, the lateral cooling provided by ithe
cold stream is the optimum required for the job. In reality, the conduc-
tivity of most structural materials varies strongly with the temperature,
particularly at low temperatures. Consequently, the one-stream interme-
diate cooling technique, which has been popular for some time starting
with the work of Scott [68], can only approximately approach the irre-
versibility minimum ( 5 . 5 ) . In such cases, one still faces the design ques-
tion of using the best capacity rate mc,, which will differ from
( A K l / t ) In(T,/T,) listed in Table I1 for “ k = constant” materials. The op-
timum capacity rate mc,, for actual structural supports is reported in Bejan
and Smith [69].
Another important aspect of the optimum design of cryogenic supports
is the design and fabrication of the stream-to-conducting solid heat ex-
changer which houses the intermediate cooling effect dictated by 1he
variational principle. This is a difficult task when we think that bringing a
gaseous stream in good thermal contact with a conduction heat current in
a solid piece implies machining holes and channels in the solid, thereby
weakening the structural member. The entropy generation minimization
in this class of heat exchangers is discussed in Bejan and Smith [69]. The
heat exchanger fabrication is less difficult and more economic if, instead
of building a continuous heat exchanger from T1 to T, between gas stream
and mechanical support. one builds a succession of discrete heat ex-
changers (cooling stations). The optimum heat leak function required by
Eq. (5.4) is therefore approximated by a stepwise-varying function.
Hilal and Boom [70] addressed the question of optimum cooling and
spatial positioning of di.vcrete heat exchangers on conducting mechanical
supports. Their work was motivated by the need to design least-
irreversible support structure\ for ;I stadium-size superconducting energy
storage system [MI. A s shown i n Fig. 24. Hilal and Boom considered a
support stretching from 7 , = 1.8 K (magnet temperature) to I , , , =
300 K (room temperature), the support being cooled at ( N t I ) discrete
points (nodes. cooling stations) hy contact with a refrigeration plant. Con-
sequently. the conduction heat flow along the support has a stepwise vari-
ation in temperature. The refrigerator power input associated with cooling
each point along the support i4
Wi = A ~ i [ ( l l / A . r l -
) ll-,/A.rl-l] for i = 2 . .... !Y + I (5.7)
and
W , = Aylll/A.r for i = 1 (5.8)
where
(5.10)
and Axi is the support length between the ith and (i + I ) t h cooling stations
(Fig. 24). A s in Fig. 23. A is the support cross-sectional area. €actor Ci ap-
pearing in Eq. (5.9) is the "Carnot efficiency" of the refrigerator cooling
node i; note that C', = 1 if the refrigerator is reversible. and I ' , '
, 1 if the
refrigerator is irreversible [7 I ] . '
W/A = (5.11)
1-1 i=l
with
I)! = (YI ~ Yl+l)l,, YN+2 = 0 (5.12)
Equation (5.11) muht be minimized subject to the constraint of fixed sup-
port length,
\! I
I. = AXi (5.13)
I=I
* The "Carnot efliclency . of il refrigerator i \ defined a s the ratio of the actual refrigerator
power requirement divided by the Carnot (minimum) power requirement
46 ADRIANBEJAN
ROCK 300K
t
TN+, T H
xi-l
SUPPORT
Ti = T c
\ \ \
FIG.24. Schematic of striictural support cooled at a number of discrete points. (After
Hilal and Boom [70].)
Hilal and Boom [70]. ’The optimum node temperatures T 2 , ..., TNfl are
given by the solution to the following set of equations:
a&, aD.
( 1 / D f F l ) a 7 ; + ( l / D : ” )-jf = 0 , i = 2 ,..., N + 1 (5.14)
i IZ
.V+l
winL/A = Df‘2 (5.16)
i=l
Hilal and Boom [70] applied this optimization procedure to various de-
signs of superconducting systems. For example, for a 10,000 MW hr en-
ergy storage solenoid supported by a Narmco epoxy -fiberglass structure
with two intermediate heat exchangers (nodes) the optimum node temper-
atures are T2 = 1I . I K , T3 = 70.3 K, while the optimum spacing between
cooling stations is AxJL = 0.305, Ax2/L = 0.325, Ax.JL = 0.370.
For the minimum refrigerator power requirement the authors found
WinLIA = 94.5 Wlcm, a value used later in the cost analysis of the pro-
posed system.
It is worth pointing out that the choice of calculating and minimizing the
total refrigerator power. as d o n e in Eq. (5.1 I ) , is analogous t o minimizing
the total entropy generated i n t he space residing below room temperature.
As in the derivation which led to the statement of the ~ ; ~ i / ~ \ ~ - . S ~ ~ i ( l o l ( i
t i i ~ ~ o r o t t(i3 . 7 ) , it is n o t difficult to prove that thr r q f k i , y c t ~ i / ( i ipoit'"r -
tic~rtlrclt o tiiuintciiii ( i c ~ t i l t l, \ p i ( (' i ~ o l d(heloir* e n \ ~ i r t i t i t ? i v t ~t ct~ t i i p o r t r t i r r )r
ryirci1.v t l i c (.old . s p t i c - c cirtrop\' g(,tii,rotioii rate times ~tiot i t ~ . c o l r i t ct c~r i i p r r -
otidrc' 1 ) t t / i c t ~ i i \ - i r o t i t ? i o iI iO~ i ~ . l i r cI1 l h t , rc;fiig[>rotorriyjects i i v t i t . T h e cold
space entropy generation rate must include the entropy generation asso-
ciated with the leakage of heat from environment into the cold space.
Before leaving the subject ot' mechanical supports for low -temperature
systems. it should be recognized that due to manufacturing constraints
the single-stream continuous cooling method of Fig. 23 can be imple-
mented less expensively in a rn;inner similar t o the method described by
Hilal and Boom (Fig. 24). Specitically. the cold stream t i i ( ' , , i \ forced to
make thermal contact with the conducting support discretely. :it a number
of points (cooling stations). T h e optimum spacing of cooling stations is
found based o n an optimization procedure involving the use of 1,agrange
multipliers (721. At present. the design and construction of mechanical
support\ for rotating superconducting windings are based o n the discon-
tinuous version of the method of b$g. 23. T h e most recent support system
of this hind was designed, constructed. and tested by Tepper t r l . 1731.
where
2 vAF
Y
S= [pip - pi-lp] [(l/T(i-l)) - ~ / p ] (5.18)
i= 1
3. Counterflow H E U Exchangers
~ Fucing a Lurgr End-to-End
Temprrat ure RNt io
We return now to the subject of regenerative counterflow heat ex-
changers considered in detail in Section IV. This time we base the discus-
sion on the balanced-flow heat exchanger schematic of Fig. 25. A straight-
forward entropy generation calculation in the dashed element may be
SECON [)-LAW ANALYSIS 49
L --
FIG 2 5 Counterflou heat exchangci ‘i\ thcrm‘tl insulation system in the urmiend-cold
end direction [h2]
--
refrigerator
300 K I +
expansion
engines
min
heat
exchqer
FIG. 26. Intermediate cooling of the main counterflow heat exchanger of a helium refrig-
erator.
ANALYSIS
Srt ONI)-I,AW 51
where C,,,is the current cost of electric power and the product T,S Ah rep-
resents the available power lost due to fluid friction. Conceptually,
Fadden's proposal is an extreme case of the more general cost formula vi-
sualized by McClintock. the extreme case where the cost of heat transfer
irreversibility is negligible compared with the cost of fluid friction irre-
versibility.
The above schemes for irreversibility cost calculation and minimization
stress one major difference between entropy generation analysis and cost
analysis. As pointed out by Urdaneta and Schmidt [86], the entropy gen-
eration analysis is irz\wriuJrt with time and place for a given process. The
invariant, fundamental character of second-law analysis stresses t h e im-
portance of the material assembled in the present monograph. This mate-
rial serves as starting point for thermal design engineers engaged not only
in irreversibility minimization. but also in cost minimization. The real
need for a reference work on the emerging subject of second-law analysis
in heat transfer was the motivation behind the writing of thi\ review.
NOhll N( I A I URE
ACKNOWLEDGMENT
This article is partially based on research supported by Contract No. N00014-79-C-0006
from the Office of Naval Rewarch, the Power Program.
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58 ADRIANBEJAN
The author would like to use this opportunity to bring to the reader's attention a number of
developments which have taken place since the completion of this article.
In the area ofsolar r n c ~ rciiKineering.
,~~ attention is drawn to a study of the second-law as-
pects of solar collector operation [91]. In this study, solar collectors are for the first time ana-
lyzed as installations for the efficient harvesting and delivery of exergy (not energy). It is
shown that the fraction of exrrgy delivered by solar collector systems is adversely affected
by heat transfer irreversibilities occurring between the sun and the collector, between the
collector and the ambient air. and inside the collector. The study uses as working examples
an isothermal collector. a stream-cooled (nonisothermal) collector, and the design of the
collector-user heat exchanger. to show how solar collector systems can be designed for
maximum exergy delivery.
In the area of rurbuleiic~crc.sc,crrch, attention is drawn to the discovery of the buckling
property of inviscid fluid fibers of finite thickness (jets, wakes, shear layers) which serves
as origin for the turbulent motion of fluids [92]. This property follows from the fact that
inviscid fluid layers cannot generate entropy [Eq. (3. I)], hence, they possess electric proper-
ties analogous to those of slender beams in longitudinal compression [93]. It has been shown
that the natural behavior of any inviscid fiber is to buckle and to execute a "meandering"
motion in which the wavelength is a precise multiple of the fiber thickness. The buckling
property accounts for observed features of turbulent flow and, most important, it proviides
for the first time a theoretical explanation for the transition from laminar to turbulent flow.