MSDS Praepagen HY

SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
PRAEPAGEN HY Page 1(92)

Substance key: SXR004885 Revision Date: 22.09.2016
Version : 8 - 1 / EU Date of printing : 17.09.2018
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier

Trade name
PRAEPAGEN HY
Material number: 107829
Chemical nature: Quaternary ammonium compounds, C12-14-(even
numbered)alkyl(hydroxyethyl)dimethyl, chlorides - EC no. 931-
275-3 (former CAS 85736-63-6)as aqueous solution (approx.
40%)
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector : Industrial & Institutional Cleaning
Type of use : Raw material for detergents
Exposure scenarios: see annex
1.3. Details of the supplier of the safety data sheet

Identification of the company
Clariant Produkte (Deutschland) GmbH
65926 Frankfurt am Main
Telephone no. : +49 69 305 18000
Information about the substance/mixture
BU Industrial & Consumer Specialties
Product Stewardship
e-mail: SDS.Europe@clariant.com
1.4. Emergency telephone number

00800-5121 5121 (24 h)
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture

Classification (REGULATION (EC) No 1272/2008)
Acute toxicity, Category 4 H302: Harmful if swallowed.
Skin corrosion, Category 1C H314: Causes severe skin burns and eye damage.
Serious eye damage, Category 1 H318: Causes serious eye damage.
Specific target organ toxicity - repeated H373: May cause damage to organs through
exposure, Category 2 prolonged or repeated exposure.
Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life.
Chronic aquatic toxicity, Category 2 H411: Toxic to aquatic life with long lasting effects.
SAFETY DATA SHEET

2.2 Label elements

Labelling (REGULATION (EC) No 1272/2008)
Hazard pictograms :
Signal word : Danger
Hazard statements : H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.
H373 May cause damage to organs through prolonged or
repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements :
Prevention:
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray.
P264 Wash skin thoroughly after handling.
P273 Avoid release to the environment.
Response:
P314 Get medical advice/ attention if you feel unwell.
P391 Collect spillage.
Disposal:
P501 Dispose of contents/ container to an approved waste
disposal plant.
Hazardous components which must be listed on the label:

N-(2-hydroxyethyl)-N,N-dimethyl alkyl-C12-14-(even numbered)-1-aminium chloride
2.3 Other hazards

Taking into account all available toxicty and ecotoxicity data, it can be concluded that the
ingredients of the mixture described here do not fulfil the criteria to be classified as either PBT or
vPvB.
This substance/mixture contains no components considered to be either persistent,
bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher.
No additional hazards are known except those derived from the labelling.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Hazardous components
Chemical name CAS-No. Classification Concentration
EC-No. (% w/w)
Registration number
N-(2-hydroxyethyl)-N,N-dimethyl Not Assigned Acute Tox. 4; H302 >= 30 - < 50
alkyl-C12-14-(even numbered)-1- Skin Corr. 1C; H314
SAFETY DATA SHEET

aminium chloride 01-2119484688-17- STOT RE 2; H373

0000 Aquatic Acute 1;
01-2119484688-17- H400
0001 Aquatic Chronic 2;
H411
For explanation of abbreviations see section 16.
SECTION 4: First aid measures
4.1 Description of first aid measures

General advice : Remove/Take off immediately all contaminated clothing.
Show this safety data sheet to the doctor in attendance.
In case of skin contact : In case of contact, immediately flush skin with soap and plenty
of water.
In case of eye contact : In the case of contact with eyes, rinse immediately with plenty
of water and seek medical advice.
If swallowed : If swallowed, seek medical advice immediately and show this

container or label.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms : No symptoms known currently.
Risks : No hazards known at this time.
4.3 Indication of any immediate medical attention and special treatment needed
Treatment : Treat symptomatically.
SECTION 5: Firefighting measures
5.1 Extinguishing media

Suitable extinguishing media : Water spray jet
Foam
Carbon dioxide (CO2)
Dry powder
5.2 Special hazards arising from the substance or mixture

Specific hazards during : In case of fires, hazardous combustion gases are formed:
firefighting Carbon monoxide (CO)
Nitrogen oxides (NOx)
Hydrogen chloride
Combustion gases of organic materials must in principle be
graded as inhalation poisons.
SAFETY DATA SHEET

5.3 Advice for firefighters

Special protective equipment : Self-contained breathing apparatus
for firefighters
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures

Personal precautions : Wear suitable protective clothing.
6.2 Environmental precautions

Environmental precautions : Do not empty into drains.
6.3 Methods and material for containment and cleaning up

Methods for cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Can be landfilled or incinerated, when in compliance with local
regulations.
6.4 Reference to other sections

Information regarding Safe handling, see chapter 7., For personal protection see section 8., For
disposal considerations see section 13.
SECTION 7: Handling and storage
7.1 Precautions for safe handling

Advice on safe handling : Handle and open container with care.
Advice on protection against : Observe the general rules of industrial fire protection
fire and explosion
Hygiene measures : Keep away from food and drink. Clean skin thoroughly after
work; apply skin cream.
7.2 Conditions for safe storage, including any incompatibilities

Further information on : - sensitive to frost - In case of the product becoming opaque,
storage conditions thickening or being frozen due to the effects of cold, allow to
thaw slowly at room temperature. Stir briefly before use.
7.3 Specific end use(s)

Specific use(s) : No further recommendations.
SAFETY DATA SHEET

SECTION 8: Exposure controls/personal protection
8.1 Control parameters

Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:
Substance name End Use Exposure routes Potential health Value
effects
N-(2-hydroxyethyl)- Workers Dermal Long-term systemic 1,25 mg/kg
N,N-dimethyl alkyl- effects bw/day
C12-14-(even
numbered)-1-aminium
chloride
Remarks: DNEL
Workers Inhalation Long-term systemic 2,2 mg/m3
effects
Remarks: DNEL
General Dermal Long-term systemic 0,9 mg/kg
population effects bw/day
Remarks: DNEL
General Inhalation Long-term systemic 3,1 mg/m3
population effects
Remarks: DNEL
General Oral Long-term systemic 0,9 mg/kg
population effects
Remarks: DNEL
General Dermal Long-term local 0,02 % in
population effects mixture (by
weight)
Remarks: DNEL
Workers Dermal Long-term systemic 1,25 mg/kg
effects bw/day
Remarks: DNEL
Workers Inhalation Long-term systemic 2,2 mg/m3
effects
Remarks: DNEL
General Dermal Long-term systemic 0,9 mg/kg
population effects bw/day
Remarks: DNEL
General Inhalation Long-term systemic 3,1 mg/m3
population effects
Remarks: DNEL
General Oral Long-term systemic 0,9 mg/kg
population effects
Remarks: DNEL
General Dermal Long-term local 0,02 % in
population effects mixture (by
weight)
Remarks: DNEL
Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:
Substance name Environmental Compartment Value
N-(2-hydroxyethyl)-N,N-dimethyl Soil 0,61 mg/kg dry
SAFETY DATA SHEET

alkyl-C12-14-(even numbered)-1- weight (d.w.)

aminium chloride
Sewage treatment plant 190 µg/l
Oral 16,7 mg/kg food
Fresh water 4 µg/l
salt water 0,4 µg/l
Water (intermittent release) 1,4 µg/l
Fresh water sediment 4,8 mg/kg dry
weight (d.w.)
Marine sediment 0,48 mg/kg dry
weight (d.w.)
Soil 0,61 mg/kg dry
weight (d.w.)
Sewage treatment plant 190 µg/l
Oral 16,7 mg/kg food
Fresh water 4 µg/l
salt water 0,4 µg/l
Water (intermittent release) 1,4 µg/l
Fresh water sediment 4,8 mg/kg dry
weight (d.w.)
Marine sediment 0,48 mg/kg dry
weight (d.w.)
8.2 Exposure controls
Personal protective equipment
Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary, face
shield.)
Hand protection
Remarks : These types of protective gloves are offered by various
manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
Break through time : 30 min

Glove thickness : 0,4 mm
Remarks : For short-term exposure (splash protection): Nitrile rubber
gloves.
Break through time : 480 min

Glove thickness : 0,7 mm
Remarks : Long-term exposure Impervious butyl rubber gloves
Skin and body protection : Depending on the degree of hazard, when handling corrosive
substances, aprons, boots or full protective clothing made of
suitable materials (e.g. rubberized or PVC-coated) must also
be worn.
For details, see the BG-Information number 595.
Protective measures : Avoid contact with skin and eyes.

SAFETY DATA SHEET

SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties

Appearance : Liquid
Colour : light yellow
Odour : characteristic
Odour Threshold : not tested.
pH : 5,5 - 8,5 (20 °C)

Concentration: 10 g/l
pour point : 0 °C
Method: ISO 3016
Boiling point : not determined
Flash point : > 100 °C

Method: DIN/ISO 2592 (open cup)
Evaporation rate : not tested.
Upper explosion limit : Not applicable
Lower explosion limit : Not applicable
Combustion number : Not applicable
Vapour pressure : approx. 23 hPa (20 °C)

Corresp. to vapour pressure of water
Relative vapour density : not tested.
Density : 0,9837 g/cm3 (20 °C)

Method: DIN EN ISO 12185
0,9740 g/cm3 (40 °C)

0,9626 g/cm3 (60 °C)

Bulk density : Not applicable
Solubility(ies)
Water solubility : soluble, Data corresponds to that of the active component
Solubility in other solvents : not tested.

Solvent: fat
SAFETY DATA SHEET

Partition coefficient: n- : log Pow: 2,3

octanol/water Information refers to the main component.
Auto-ignition temperature : Not applicable
Decomposition temperature : approx. 247 °C

Method: Thermogravimetry
The substance or mixture is not classified self-reactive.
Viscosity
Viscosity, dynamic : approx. 100 mPa.s (20 °C)
Viscosity, kinematic : not tested.
Explosive properties : Information refers to the main component.

There are no chemical groups associated with explosive
properties present in the molecule.
Oxidizing properties : Information refers to the main component.

There are no chemical groups associated with oxidising
properties present in the molecule.
9.2 Other information

Surface tension : 24,9 mN/m
Metal corrosion rate : The product shows corrosion properties to metals (Steel or
Aluminium), but not sufficient to classify it as corrosive. The
corrosion rate is < 6,25 mm/y at 55 ºC.
Minimum ignition energy : not tested.
Particle size : Not applicable
Self-ignition : Not applicable
SECTION 10: Stability and reactivity
10.1 Reactivity
See section 10.3. "Possibility of hazardous reactions"
10.2 Chemical stability
Stable
10.3 Possibility of hazardous reactions
Hazardous reactions : No dangerous reaction known under conditions of normal use.
Stable
10.4 Conditions to avoid

Conditions to avoid : Keep away from strong acids.
SAFETY DATA SHEET

10.5 Incompatible materials

Materials to avoid : not known
10.6 Hazardous decomposition products

Amine compounds
SECTION 11: Toxicological information
11.1 Information on toxicological effects

Acute toxicity
Product:
Acute oral toxicity : Acute toxicity estimate: 1.250 mg/kg
Method: Calculation method
Acute inhalation toxicity : Remarks: Study not performed as the substance is corrosive.
Acute dermal toxicity : Remarks: Study not performed as the substance is corrosive.
Components:
N-(2-hydroxyethyl)-N,N-dimethyl alkyl-C12-14-(even numbered)-1-aminium chloride:
Acute oral toxicity : LD50 (Rat, male and female): > 300 - 2.000 mg/kg , >200 <
2000 mg/kg
Method: OECD Test Guideline 401
GLP: yes
Acute inhalation toxicity : Remarks: Study not performed as the substance is corrosive.
Acute dermal toxicity : Remarks: Study not performed as the substance is corrosive.
Skin corrosion/irritation
Components:
Species: Rabbit
Exposure time: 4 h
Result: Corrosive
GLP: yes
Serious eye damage/eye irritation

Product:
Remarks: Study not performed as the substance is corrosive.
Components:
SAFETY DATA SHEET

Respiratory or skin sensitisation

Product:
Components:
No sensitisation effects are known
Germ cell mutagenicity

Product:
Genotoxicity in vitro : Test Type: Ames test
Species: Salmonella typhimurium
Metabolic activation: with and without
Result: Negative with and without metabolic activation
GLP: yes
Remarks: Test result obtained from the mixture.
: Test Type: Chromosome Aberration Test

Species: V79 cells (embryonic lung fibroblasts) of the Chinese
hamster
Result: Negative with and without metabolic activation
GLP: yes
Remarks: Test result obtained from the mixture.
Germ cell mutagenicity- : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.
Information refers to the main component.
Components:
Genotoxicity in vitro : Test Type: Ames test
Species: Salmonella typhimurium
Concentration: 0,0016 - 1,6 µg/plate
Result: negative
GLP: yes
: Test Type: Chromosome aberration test in vitro

SAFETY DATA SHEET

hamster
Concentration: 5 - 200 µg/ml
Result: negative
GLP: yes
: Test Type: HGPRT assay

hamster
Concentration: 2,5 - 230 µM
Result: negative
GLP: yes
Germ cell mutagenicity- : It is concluded that the product is not mutagenic based on
Assessment evaluation of several mutagenicity tests.
Carcinogenicity
Product:
Carcinogenicity - : Contains no ingredient listed as a carcinogen
Assessment
Components:
Remarks: From scientific point of view the study is not necessary.
Carcinogenicity - : Not applicable

Assessment
Reproductive toxicity
Product:
Reproductive toxicity - : No indications of toxic effects were observed in reproduction
Assessment studies in animals.
No reproductive toxicity to be expected.
Information refers to the main component.
Components:
Effects on fertility : Test Type: Fertility
Remarks: The study is not necessary from a scientific

perspective.
Effects on foetal : Species: Rat, female

development Application Route: Oral
SAFETY DATA SHEET

Exposure time: Gestation days 6-19

Dose: 25 - 50 - 100 mg/kg
Group: yes
50 mg/kg
50 mg/kg
Number of exposures: Once daily
GLP: yes
Reproductive toxicity - : No reproductive toxicity to be expected.

Assessment No teratogenic effects to be expected.
STOT - single exposure

Product:
Remarks: Based on available data, the classification criteria are not met.
Components:
Remarks: Based on available data, the classification criteria are not met.
STOT - repeated exposure

Product:
Exposure routes: Oral
Target Organs: Gastrointestinal tract
Components:
Assessment: May cause damage to organs through prolonged or repeated exposure.
Repeated dose toxicity

Components:
Species: Rat, male and female
NOAEL: 75 mg/kg
Application Route: oral (feed)
Exposure time: 90 d
Number of exposures: continuously
Dose: 15 - 50 - 75 mg/kg
Group: yes
Method: OPPTS 870.3100
GLP: yes
Aspiration toxicity
Product:
no data available
SAFETY DATA SHEET

Components:
No aspiration toxicity classification
SECTION 12: Ecological information
12.1 Toxicity
Product:
Plant toxicity : NOEC: 12,3 mg/kg
End point: Growth
Test period: 21 d
Species: Avena sativa (oats)
Method: OECD Guide-line 208
GLP: yes
NOEC: 4,12 mg/kg

End point: Growth
Test period: 21 d
Species: Lactuca sativa (lettuce)
GLP: yes
NOEC: 111 mg/kg

End point: Growth
Test period: 21 d
Species: Dicotyledonae: Glycine max (soybean)
GLP: yes
Components:
Toxicity to fish : LC50 (Danio rerio (zebra fish)): 4,2 mg/l
Exposure time: 96 h
Test Type: semi-static test
Analytical monitoring: yes
GLP: yes
Remarks: The details of the toxic effect relate to the nominal
concentration.
Toxicity to daphnia and other : EC50 (Daphnia magna (Water flea)): 0,19 mg/l
aquatic invertebrates Exposure time: 48 h
GLP: yes
concentration.
SAFETY DATA SHEET

Toxicity to algae : NOEC (other algae): 0,02 mg/l

22 - 212 µg/l
Exposure time: 28 d
Test Type: flow through
GLP: no
EC50 (Desmodesmus subspicatus (Scenedesmus

subspicatus)): 0,14 mg/l
End point: Growth rate
Exposure time: 72 h
Test Type: static test
GLP: yes
concentration.
Toxicity to microorganisms : EC50 (activated sludge, domestic): 19 mg/l

End point: Bacteria toxicity (respiration inhibition)
Exposure time: 3 h
Test Type: aquatic
Analytical monitoring: no
GLP: yes
concentration.
NOEC (Natural microorganism): 1.000 mg/l

End point: Nitrate formation rate
Exposure time: 28 d
Test Type: Soil
Analytical monitoring: no
Method: OECD 216
GLP: yes
concentration.
Toxicity to fish (Chronic : NOEC: 0,16 mg/l

toxicity) Exposure time: 28 d
Species: Danio rerio (zebra fish)
Test Type: flow through
GLP: yes
Toxicity to daphnia and other : NOEC: 0,1 mg/l

aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) End point: Reproduction rate
Species: Daphnia magna (Water flea)
SAFETY DATA SHEET

GLP: yes
concentration.
Toxicity to soil dwelling : Test Type: artificial soil

organisms NOEC: 125 mg/kg
Exposure time: 56 d
End point: mortality
Species: Eisenia fetida (earthworms)
GLP:yes
concentration.
Species: other soil dwelling arthropod

Remarks: The study is not necessary from a scientific
perspective.
Plant toxicity : NOEC: 3,2 mg/kg

Exposure time: 14 d
End point: Growth
Species: Lactuca sativa (lettuce)
GLP:yes
concentration.
NOEC: 3,2 mg/kg

Exposure time: 14 d
End point: Growth
Species: Avena sativa (oats)
GLP:yes
concentration.
Sediment toxicity : Remarks: The study is not necessary from a scientific

perspective.
Toxicity to terrestrial : Species: other avian

organisms Remarks: Not applicable
12.2 Persistence and degradability

Product:
Chemical Oxygen Demand : 767 mg/g
(COD) Method: DIN 38409-H-41
Dissolved organic carbon : 252 mg/g

(DOC) Method: DIN 38409 T. 3
SAFETY DATA SHEET

Components:
Biodegradability : Test Type: aerobic
Inoculum: activated sludge, non-adapted
Concentration: 50 mg/l
Result: Readily biodegradable.
Biodegradation: 87 %
Related to: CO2 formation in % of theoretical value
Exposure time: 28 d
Method: OECD Test Guideline 301B
GLP: yes
Test Type: aerobic

Inoculum: activated sludge, non-adapted
Concentration: 0,2 mg/l
Result: Readily biodegradable.
Biodegradation: approx. 100 %
Related to: DOC decrease
Exposure time: 26 d
Method: OECD Test Guideline 303A
GLP: yes
Physico-chemical : Remarks: Readily biodegradable, according to appropriate

removability OECD test.
Stability in water : Remarks: Not applicable
Photodegradation : Test Type: air

Remarks: Not applicable
Test Type: water

Test Type: Soil

12.3 Bioaccumulative potential

Product:
Bioaccumulation : Species: Fish
Bioconcentration factor (BCF): 18
Remarks: No bioaccumulation is to be expected (log Pow <=
4).
Components:
Bioaccumulation : Remarks: Due to the low logPow bioaccumulation is not
expected
SAFETY DATA SHEET

12.4 Mobility in soil

Product:
Distribution among : Remarks: The substance does not evaporate into the
environmental compartments atmosphere from the surface of water.
Components:
Distribution among : adsorption
environmental compartments Medium: water - soil
Koc: log Koc: <= 5
Remarks: Not expected to adsorb on soil.
12.5 Results of PBT and vPvB assessment

Product:
Assessment : Taking into account all available toxicty and ecotoxicity data, it
can be concluded that the ingredients of the mixture
described here do not fulfil the criteria to be classified as
either PBT or vPvB..
: This substance/mixture contains no components considered

to be either persistent, bioaccumulative and toxic (PBT), or
very persistent and very bioaccumulative (vPvB) at levels of
0.1% or higher..
Components:
Assessment : Remarks: The substance does not meet the criteria for PBT or
vPvB substance.
12.6 Other adverse effects

Product:
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
Components:
Environmental fate and : not available
pathways
Additional ecological : The product should not be allowed to enter drains, water
information courses or the soil.
SAFETY DATA SHEET

SECTION 13: Disposal considerations
13.1 Waste treatment methods

Product : In accordance with local authority regulations, take to special
waste incineration plant or underground disposal site
Contaminated packaging : Regulations concerning reuse or disposal of used packaging

materials must be observed.
SECTION 14: Transport information
Section 14.1. to 14.5.
ADR
UN no. UN 3265
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Hazard inducer(s): Fattyalkyl dimethylhydroxyethylammonium chloride
Class: 8
Primary risk: 8
Packing group: III
Hazard no. : 80
Environmental hazards: Special marking provision: environmentally hazardous
Remarks Shipment permitted
ADN
UN no. UN 3265
Class: 8
Primary risk: 8
Packing group: III
RID
UN no. UN 3265
Class: 8
Primary risk: 8
Packing group: III
Hazard no. : 80
SAFETY DATA SHEET

IATA
UN no. UN 3265
Class: 8
Primary risk: 8
Packing group: III
IMDG
UN no. UN 3265
Class: 8
Primary risk: 8
Packing group: III
Marine pollutant: Marine Pollutant
EmS : F-A S-B
14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International
Bulk Chemicals Code)
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
Other regulations : The surfactant(s) contained in this mixture complies(comply)
with the biodegradability criteria as laid down in Regulation
(EC) No.648/2004 on detergents. Data to support this
assertion are held at the disposal of the competent authorities
of the Member States and will be made available to them, at
their direct request or at the request of a detergent
manufacturer.
15.2 Chemical safety assessment

Chemical Safety Assessments (CSAs) are available for the component substances contained in this
product.
SECTION 16: Other information
Full text of H-Statements

H302 : Harmful if swallowed.
H314 : Causes severe skin burns and eye damage.
H373 : May cause damage to organs through prolonged or repeated
SAFETY DATA SHEET

exposure if swallowed.
H400 : Very toxic to aquatic life.
H411 : Toxic to aquatic life with long lasting effects.
Full text of other abbreviations
Acute Tox. : Acute toxicity
Aquatic Acute : Acute aquatic toxicity
Aquatic Chronic : Chronic aquatic toxicity
Skin Corr. : Skin corrosion
STOT RE : Specific target organ toxicity - repeated exposure
ADN - European Agreement concerning the International Carriage of Dangerous Goods by Inland
Waterways; ADR - European Agreement concerning the International Carriage of Dangerous
Goods by Road; AICS - Australian Inventory of Chemical Substances; ASTM - American Society
for the Testing of Materials; bw - Body weight; CLP - Classification Labelling Packaging
Regulation; Regulation (EC) No 1272/2008; CMR - Carcinogen, Mutagen or Reproductive
Toxicant; DIN - Standard of the German Institute for Standardisation; DSL - Domestic Substances
List (Canada); ECHA - European Chemicals Agency; EC-Number - European Community
number; ECx - Concentration associated with x% response; ELx - Loading rate associated with
x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances
(Japan); ErCx - Concentration associated with x% growth rate response; GHS - Globally
Harmonized System; GLP - Good Laboratory Practice; IARC - International Agency for Research
on Cancer; IATA - International Air Transport Association; IBC - International Code for the
Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk; IC50 - Half maximal
inhibitory concentration; ICAO - International Civil Aviation Organization; IECSC - Inventory of
Existing Chemical Substances in China; IMDG - International Maritime Dangerous Goods; IMO -
International Maritime Organization; ISHL - Industrial Safety and Health Law (Japan); ISO -
International Organisation for Standardization; KECI - Korea Existing Chemicals Inventory; LC50
- Lethal Concentration to 50 % of a test population; LD50 - Lethal Dose to 50% of a test
population (Median Lethal Dose); MARPOL - International Convention for the Prevention of
Pollution from Ships; n.o.s. - Not Otherwise Specified; NO(A)EC - No Observed (Adverse) Effect
Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect
Loading Rate; NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic
Co-operation and Development; OPPTS - Office of Chemical Safety and Pollution Prevention;
PBT - Persistent, Bioaccumulative and Toxic substance; PICCS - Philippines Inventory of
Chemicals and Chemical Substances; (Q)SAR - (Quantitative) Structure Activity Relationship;
REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the Council
concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RID -
Regulations concerning the International Carriage of Dangerous Goods by Rail; SADT - Self-
Accelerating Decomposition Temperature; SDS - Safety Data Sheet; TCSI - Taiwan Chemical
Substance Inventory; TRGS - Technical Rule for Hazardous Substances; TSCA - Toxic
Substances Control Act (United States); UN - United Nations; vPvB - Very Persistent and Very
Bioaccumulative
Further information
Other information : Observe national and local legal requirements
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Clariant makes no warranties, express
or implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and
assumes no liability in connection with any use of this information. Any user of this product is
responsible for determining the suitability of Clariant's products for its particular application.
Nothing included in this information waives any of Clariant's General Terms and Conditions of
SAFETY DATA SHEET

Sale, which control unless it agrees otherwise in writing. Any existing intellectual/industrial
property rights must be observed. Due to possible changes in our products and applicable
national and international regulations and laws, the status of our products could change. Material
Safety Data Sheets providing safety precautions, that should be observed when handling or
storing Clariant products, are available upon request and are provided in compliance with
applicable law. You should obtain and review the applicable Material Safety Data Sheet
information before handling any of these products. For additional information, please contact
Clariant.
REG_EU / EN
SAFETY DATA SHEET

Exposure scenario
Number Title
ES 1 Formulation or re-packing; Washing and cleaning products, Solid
PROC3, PROC5, PROC8b, PROC9, PROC15 - ERC2
Quaternary ammonium compounds, C12-14, even numbered, alkyl(hydroxyethyl)
dimethyl, chlorides
ES 2 Formulation or re-packing; Washing and cleaning products, Liquid
dimethyl, chlorides
ES 3 Industrial use; Washing and cleaning products, Solid
dimethyl, chlorides
ES 4 Industrial use; Washing and cleaning products, Liquid
PROC1, PROC3, PROC5, PROC8b, PROC10, PROC13 - ERC4
dimethyl, chlorides
ES 5 Professional use; Washing and cleaning products, Solid
PROC3, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC13 - ERC8a
dimethyl, chlorides
ES 6 Professional use; Washing and cleaning products, Liquid
PROC1, PROC3, PROC5, PROC8a, PROC8b, PROC9, PROC10, PROC13 - ERC8a
dimethyl, chlorides
ES 7 Consumer use; Washing and cleaning products, Liquid
PC35 - ERC8a
dimethyl, chlorides
ES 8 Consumer use; Washing and cleaning products, Solid
PC35 - ERC8a
dimethyl, chlorides
1. ES 1: Formulation or re-packing; Washing and cleaning

products, Solid
1.1. Titles of Contributing scenarios (CS)
SAFETY DATA SHEET

Environment
CS1: Formulation or re-packing (Formulation into mixture) ERC2
Workers
CS2: Formulation or re-packing (Manufacture or formulation in the chemical PROC3
industry in closed batch processes with occasional controlled exposure
or processes with equivalent containment condition)
CS3: Formulation or re-packing (Mixing or blending in batch processes) PROC5
CS4: Formulation or re-packing (Transfer of substance or mixture PROC8b
(charging/discharging) at dedicated facilities)
CS6: Formulation or re-packing (Transfer of substance or mixture into small PROC9
containers (dedicated filling line, including weighing))
CS8: Formulation or re-packing (Use as laboratory reagent) PROC15
1.2. ES 1 Conditions of use affecting exposure

1.2.1 ES 1 - CS 1: Control of environmental exposure: Formulation or re-packing
(Formulation into mixture) (ERC2)
Amount used
Annual amount per site : <= 3200 tonnes/year
Daily amount per site : <= 10670 kg/day
Frequency and duration of use

Continuous exposure : 300 days per year
Environment factors not influenced by risk management

Flow rate of receiving surface : 18.000 m3/d
water
Conditions and measures related to sewage treatment plant

Type of Sewage Treatment Plant : Municipal Sewage Treatment Plant
Flow rate of sewage treatment : 2.000 m3/d
plant effluent
Effectiveness (of a measure) : 99 %
Waste management measures

Disposal methods : Dispose of waste product or used containers according to
local regulations.
1.2.2 ES 1 - CS 2: Control of worker exposure: Formulation or re-packing

(Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition)
(PROC3)
SAFETY DATA SHEET

Remarks : Sampling
Product characteristics
Concentration of the Substance in : > 25 %
Mixture/Article
Physical Form (at time of use) : Solid, low dustiness

Remarks : Covers use at ambient temperatures., Covers solid products
only.

Exposure duration : <8h
Human factors not influenced by risk management

Dermal exposure : Palm of one hand
Covers skin contact area up to : 240 cm²
Other operational conditions affecting workers exposure

Outdoor / Indoor : Indoor use
Risk Management Measures

Organisational measures to : Advanced (industrial) exposure controls assumed.
prevent /limit releases, dispersion Assumes a good basic standard of occupational hygiene is
and exposure implemented
Technical conditions and : Advanced (industrial) exposure controls assumed.
measures Manufacture or formulation in the chemical industry in closed
batch processes with occasional controlled exposure or
processes with equivalent containment condition
Provide a basic standard of general ventilation (1 to 3 air
changes per hour).
Exposure routes : inhalative

Technical conditions and : Local exhaust ventilation
measures
Effectiveness (of a measure) : >= 90 %
Exposure routes : Dermal

Personal protective measures : Wear suitable gloves tested to EN374.
Use suitable eye protection.
Note : Moderate hazard

Risk management measures are based on qualitative risk
characterisation.
1.2.3 ES 1 - CS 3: Control of worker exposure: Formulation or re-packing (Mixing or

blending in batch processes) (PROC5)
Mixture/Article
SAFETY DATA SHEET


only.


Dermal exposure : Assumes that potential dermal contact is limited to inside
hands / one hand / palm of hands.


measures Provide a basic standard of general ventilation (1 to 3 air
changes per hour).

measures

Personal protective measures : Wear chemically resistant gloves (tested to EN374) in
combination with specific activity training.

characterisation.
1.2.4 ES 1 - CS 4: Control of worker exposure: Formulation or re-packing (Transfer of

substance or mixture (charging/discharging) at dedicated facilities) (PROC8b)
Remarks : Product delivery
Mixture/Article ECETOC TRA worker V3
Concentration of the Substance in : <= 40 %

Mixture/Article ART
Physical Form (at time of use) : Liquid, Low viscosity

Remarks : Substances in preparations / mixtures
Physical Form (at time of use) : Solid, Powder products
SAFETY DATA SHEET

Remarks : Covers solid products only.

Exposure duration : 4h

Dermal exposure : Assumes that potential dermal contact is limited to hands.

Room size : 300 m3
Ventilation rate per hour : 1
Transfer of liquid products - falling : > 1000 L/min, ART

liquids

Type of Application (Use) : Splash loading
Ensure that the distance from worker to task is greater than 1
m.
Handling that reduces contact between product and adjacent
air.
measures Use in semi-closed process with opportunity for exposure

measures


characterisation.

Remarks : Material transfers
Concentration of the Substance in : >= 5 - <= 25 %
Mixture/Article
SAFETY DATA SHEET


Remarks : Covers solid products only., Covers use at ambient
temperatures.




changes per hour).

measures


characterisation.

substance or mixture into small containers (dedicated filling line, including weighing))
(PROC9)

Mixture/Article ART

SAFETY DATA SHEET





Room size : 300 m3
Transfer of liquid products - falling : 100 - 1000 L/min, ART

liquids

m.
air.

measures

combination with ‘basic’ employee training.

characterisation.

(PROC9)
SAFETY DATA SHEET


Mixture/Article

temperatures.




changes per hour).

measures


characterisation.
1.2.8 ES 1 - CS 8: Control of worker exposure: Formulation or re-packing (Use as

laboratory reagent) (PROC15)
Mixture/Article

temperatures.
SAFETY DATA SHEET





changes per hour).

measures


characterisation.
1.3. ES 1 Exposure estimation and reference to its source

1.3.1 ES 1 - CS 1: Environmental release and exposure: Formulation or re-packing
Release route Release rate Release estimation method

Water 0,6 kg/day EUSES v2.1
Air 0 kg/day EUSES v2.1
Soil 0 kg/day EUSES v2.1
Protection target Exposure estimation and reference to its source RCR

(based on EUSES v2.1)
SAFETY DATA SHEET

Freshwater 0,000709 mg/L 0,177

Freshwater sediment 0,857 mg/kg dry weight 0,177
Marine water 0,0000691 mg/L 0,173
Marine sediment 0,0853 mg/kg dry weight 0,173
Sewage treatment plant. 0,0030 mg/L 0,0158
Indirect exposure to humans 0,0000383 mg/kg bw/day < 0,01
via the environment
Soil 0,0000081 mg/kg dry weight < 0,01
1.3.2 ES 1 - CS 2: Worker exposure: Formulation or re-packing (Manufacture or

formulation in the chemical industry in closed batch processes with occasional
controlled exposure or processes with equivalent containment condition) (PROC3)
Route of exposure and type Exposure estimate RCR

of effects
Worker - inhalative, long-term 0,01 mg/m³ (ECETOC TRA worker V3, Tier 1) < 0,01
- systemic
Worker - inhalative, long-term 0,01 mg/m³ (ECETOC TRA worker V3, Tier 1) 0,01
- local
Worker - inhalative, short-term 0,04 mg/m³ (ECETOC TRA worker V3, Tier 1) 0,04
- local
Worker - dermal, long-term - 0,138 mg/kg bw/day (ECETOC TRA worker V3, Tier 1) 0,11
systemic
Worker - combined, long-term 0,115
- systemic
1.3.3 ES 1 - CS 3: Worker exposure: Formulation or re-packing (Mixing or blending in

batch processes) (PROC5)

of effects
- systemic
- local
- local
systemic
- systemic
1.3.4 ES 1 - CS 4: Worker exposure: Formulation or re-packing (Transfer of


of effects
SAFETY DATA SHEET

Worker - inhalative, long-term 0,15 mg/m³ (ART, Tier 2, Raw material delivery) 0,068
- systemic
- local
Worker - inhalative, short-term 0,3 mg/m³ (ART, Tier 2, Raw material delivery) 0,3
- local
Worker - dermal, long-term - 0,411 mg/kg bw/day (ECETOC TRA worker V3, Tier 1, 0,329
systemic Raw material delivery)
- systemic


of effects
Worker - inhalative, long-term 0,002 mg/m³ (ECETOC TRA worker V3, Material < 0,01
- systemic transfers)
- local transfers)
Worker - inhalative, short-term 0,012 mg/m³ (ECETOC TRA worker V3, Material 0,012
- local transfers)
Worker - dermal, long-term - 0,247 mg/kg bw/day (ECETOC TRA worker V3, Material 0,197
systemic transfers)
- systemic

(PROC9)

of effects
- systemic
- local
- local
- systemic

(PROC9)
SAFETY DATA SHEET


of effects
- systemic transfers)
- local transfers)
Worker - inhalative, short-term 0,024 mg/m³ (ECETOC TRA worker V3, Material 0,024
- local transfers)
systemic transfers)
- systemic
1.3.8 ES 1 - CS 8: Worker exposure: Formulation or re-packing (Use as laboratory

reagent) (PROC15)

of effects
- systemic
- local
- local
systemic
- systemic
1.4. ES 1 Guidance to Downstream User to evaluate whether he

works inside the boundaries set by the Exposure Scenario
ECHA guidance for downstream users
Section 2
2. ES 2: Formulation or re-packing; Washing and cleaning

products, Liquid
Environment
CS1: Formulation or re-packing (Formulation into mixture) ERC2
Workers
CS2: Formulation or re-packing (Manufacture or formulation in the chemical PROC3
SAFETY DATA SHEET

industry in closed batch processes with occasional controlled exposure

or processes with equivalent containment condition)
CS3: Formulation or re-packing (Mixing or blending in batch processes) PROC5
CS8: Formulation or re-packing (Use as laboratory reagent) PROC15

2.2.1 ES 2 - CS 1: Control of environmental exposure: Formulation or re-packing
Amount used
Annual amount per site : <= 3200 tonnes/year
Daily amount per site : <= 10670 kg/day


water

plant effluent

local regulations.
2.2.2 ES 2 - CS 2: Control of worker exposure: Formulation or re-packing

(Manufacture or formulation in the chemical industry in closed batch processes with
occasional controlled exposure or processes with equivalent containment condition)
(PROC3)
Remarks : Sampling
SAFETY DATA SHEET


Mixture/Article ART




Room size : 300 m3

liquids

Open systems


characterisation.
2.2.3 ES 2 - CS 3: Control of worker exposure: Formulation or re-packing (Mixing or

blending in batch processes) (PROC5)

Mixture/Article ART
SAFETY DATA SHEET





Room size : 300 m3
Handling of contaminated objects : 1 - 3 m2, Activities with open liquid surfaces or open
reservoirs - activity with agitated surfaces, ART

Open systems
m.
measures

measures


characterisation.

SAFETY DATA SHEET


Mixture/Article ART




Room size : 300 m3

liquids

m.
air.

measures


characterisation.

SAFETY DATA SHEET


Mixture/Article ART




Room size : 300 m3

liquids

m.
air.

measures

SAFETY DATA SHEET


characterisation.

(PROC9)

Mixture/Article ART




Room size : 300 m3

liquids

m.
air.

SAFETY DATA SHEET

measures


characterisation.

(PROC9)

Mixture/Article ART




Room size : 300 m3

liquids

SAFETY DATA SHEET

m.
air.

measures

characterisation.

2.2.8 ES 2 - CS 8: Control of worker exposure: Formulation or re-packing (Use as

laboratory reagent) (PROC15)

Mixture/Article ART



Remarks : Activities with open liquid surfaces or open reservoirs - activity
with undisturbed surfaces (no aerosol formation)

Handling of contaminated objects : 0,1 - 0,3 m2, Activities with open liquid surfaces or open
reservoirs - activity with undisturbed surfaces (no aerosol
formation), ART

SAFETY DATA SHEET


measures

Technical conditions and : Handle in a fume cupboard or under extract ventilation.
measures

characterisation.


2.3.1 ES 2 - CS 1: Environmental release and exposure: Formulation or re-packing


via the environment
Soil 0,0000081 mg/kg dry weight < 0,01
2.3.2 ES 2 - CS 2: Worker exposure: Formulation or re-packing (Manufacture or


of effects
Worker - inhalative, long-term 0,021 mg/m³ (ART, Tier 2) < 0,01
SAFETY DATA SHEET

- systemic
Worker - inhalative, long-term 0,021 mg/m³ (ART, Tier 2) 0,021
- local
Worker - inhalative, short-term 0,17 mg/m³ (ART, Tier 2) 0,17
- local
systemic
- systemic
2.3.3 ES 2 - CS 3: Worker exposure: Formulation or re-packing (Mixing or blending in


of effects
- systemic
- local
- local
systemic
- systemic


of effects
- systemic
- local
- local
- systemic


of effects
Worker - inhalative, long-term 0,038 mg/m³ (ART, Material transfers) 0,017
SAFETY DATA SHEET

- systemic
- local
Worker - inhalative, short-term 0,076 mg/m³ (ART, Material transfers) 0,076
- local
systemic transfers)
- systemic

(PROC9)

of effects
- systemic
- local
- local
- systemic

(PROC9)

of effects
Worker - inhalative, long-term 0,022 mg/m³ (ART, Material transfers) < 0,01
- systemic
- local
Worker - inhalative, short-term 0,044 mg/m³ (ART, Material transfers) 0,044
- local
systemic transfers)
- systemic
2.3.8 ES 2 - CS 8: Worker exposure: Formulation or re-packing (Use as laboratory

reagent) (PROC15)
SAFETY DATA SHEET


of effects
- systemic
- local
Worker - inhalative, short-term 0,00028 mg/m³ (ART, Tier 2) < 0,01
- local
systemic
- systemic

Section 2
3. ES 3: Industrial use; Washing and cleaning products,

Solid
Environment
CS1: Industrial use (Use of non-reactive processing aid at industrial site (no ERC4
inclusion into or onto article))
Workers
CS2: Industrial use (Manufacture or formulation in the chemical industry in PROC3
closed batch processes with occasional controlled exposure or
processes with equivalent containment condition)
CS3: Industrial use (Mixing or blending in batch processes) PROC5
CS4: Industrial use (Transfer of substance or mixture (charging/discharging) PROC8b
at dedicated facilities)
CS5: Industrial use (Roller application or brushing) PROC10
CS6: Industrial use (Treatment of articles by dipping and pouring) PROC13

3.2.1 ES 3 - CS 1: Control of environmental exposure: Industrial use (Use of non-
reactive processing aid at industrial site (no inclusion into or onto article)) (ERC4)
SAFETY DATA SHEET

Amount used
Annual amount per site : <= 0,09 tonnes/year
Daily amount per site : <= 0,41 kg/day


water

plant effluent

local regulations.
3.2.2 ES 3 - CS 2: Control of worker exposure: Industrial use (Manufacture or

Mixture/Article

only.




SAFETY DATA SHEET

changes per hour).


characterisation.
3.2.3 ES 3 - CS 3: Control of worker exposure: Industrial use (Mixing or blending in

Mixture/Article

only.




measures Provide a good standard of general ventilation (not less than 3
to 5 air changes per hour).


characterisation.
3.2.4 ES 3 - CS 4: Control of worker exposure: Industrial use (Transfer of substance

or mixture (charging/discharging) at dedicated facilities) (PROC8b)
SAFETY DATA SHEET

Mixture/Article

only.




changes per hour).
Use in semi-closed process with opportunity for exposure


characterisation.
3.2.5 ES 3 - CS 5: Control of worker exposure: Industrial use (Roller application or

brushing) (PROC10)

Mixture/Article ART

SAFETY DATA SHEET




Room size : 300 m3
Roller, spreader, flow application : > 3 m²/h

measures


characterisation.
3.2.6 ES 3 - CS 6: Control of worker exposure: Industrial use (Treatment of articles

by dipping and pouring) (PROC13)

Mixture/Article ART



SAFETY DATA SHEET


Room size : 300 m3
Handling of contaminated objects : > 3 m2, Activities with open liquid surfaces or open reservoirs
- activity with agitated surfaces, ART

measures

measures


characterisation.

3.3.1 ES 3 - CS 1: Environmental release and exposure: Industrial use (Use of non-


SAFETY DATA SHEET


via the environment
Soil 0,0991 mg/kg dry weight 0,163
3.3.2 ES 3 - CS 2: Worker exposure: Industrial use (Manufacture or formulation in the

chemical industry in closed batch processes with occasional controlled exposure or
processes with equivalent containment condition) (PROC3)

of effects
- systemic
- local
- local
systemic
- systemic
3.3.3 ES 3 - CS 3: Worker exposure: Industrial use (Mixing or blending in batch

processes) (PROC5)

of effects
- systemic
- local
- local
systemic
- systemic
3.3.4 ES 3 - CS 4: Worker exposure: Industrial use (Transfer of substance or mixture

(charging/discharging) at dedicated facilities) (PROC8b)

of effects
SAFETY DATA SHEET

- systemic
- local
- local
systemic
- systemic
3.3.5 ES 3 - CS 5: Worker exposure: Industrial use (Roller application or brushing)

(PROC10)

of effects
- systemic
- local
- local
systemic
- systemic
3.3.6 ES 3 - CS 6: Worker exposure: Industrial use (Treatment of articles by dipping

and pouring) (PROC13)

of effects
- systemic
- local
- local
systemic
- systemic

SAFETY DATA SHEET

Section 2
4. ES 4: Industrial use; Washing and cleaning products,

Liquid
Environment
CS1: Industrial use (Use of non-reactive processing aid at industrial site (no ERC4
inclusion into or onto article))
Workers
CS2: Industrial use (Chemical production or refinery in closed process without PROC1
likelihood of exposure or processes with equivalent containment
conditions)
CS3: Industrial use (Manufacture or formulation in the chemical industry in PROC3
CS4: Industrial use (Mixing or blending in batch processes) PROC5
CS5: Industrial use (Transfer of substance or mixture (charging/discharging) PROC8b
at dedicated facilities)
CS6: Industrial use (Roller application or brushing) PROC10
CS7: Industrial use (Treatment of articles by dipping and pouring) PROC13

4.2.1 ES 4 - CS 1: Control of environmental exposure: Industrial use (Use of non-
Amount used
Annual amount per site : <= 0,09 tonnes/year
Daily amount per site : <= 0,41 kg/day


water

plant effluent
SAFETY DATA SHEET


local regulations.
4.2.2 ES 4 - CS 2: Control of worker exposure: Industrial use (Chemical production or

refinery in closed process without likelihood of exposure or processes with equivalent
containment conditions) (PROC1)
Remarks : Spraying
Closed systems

Mixture/Article ART




Room size : 300 m3
Handling of contaminated objects : > 3 m2
Contamination : > 90 %, ART

measures Chemical production or refinery in closed process without
likelihood of exposure or processes with equivalent
containment conditions

SAFETY DATA SHEET


characterisation.
4.2.3 ES 4 - CS 3: Control of worker exposure: Industrial use (Manufacture or

Remarks : Sampling

Mixture/Article ART




Room size : 300 m3

liquids

Open systems

SAFETY DATA SHEET


characterisation.
4.2.4 ES 4 - CS 4: Control of worker exposure: Industrial use (Mixing or blending in


Mixture/Article ART




Room size : 300 m3

m.
measures


SAFETY DATA SHEET

characterisation.
4.2.5 ES 4 - CS 5: Control of worker exposure: Industrial use (Transfer of substance

or mixture (charging/discharging) at dedicated facilities) (PROC8b)

Mixture/Article ART




Room size : 300 m3

liquids

m.
air.


characterisation.
SAFETY DATA SHEET

4.2.6 ES 4 - CS 6: Control of worker exposure: Industrial use (Roller application or

brushing) (PROC10)

Mixture/Article ART




Room size : 300 m3

measures


characterisation.
4.2.7 ES 4 - CS 7: Control of worker exposure: Industrial use (Treatment of articles

by dipping and pouring) (PROC13)
SAFETY DATA SHEET


Mixture/Article ART




Room size : 300 m3

measures

measures


characterisation.

4.3.1 ES 4 - CS 1: Environmental release and exposure: Industrial use (Use of non-
SAFETY DATA SHEET



via the environment
4.3.2 ES 4 - CS 2: Worker exposure: Industrial use (Chemical production or refinery

in closed process without likelihood of exposure or processes with equivalent
containment conditions) (PROC1)

of effects
- systemic
- local
- local
Worker - dermal, long-term - 0,001 mg/kg bw/day (ECETOC TRA worker V3, Tier 1) < 0,01
systemic
Worker - combined, long-term < 0,01
- systemic
4.3.3 ES 4 - CS 3: Worker exposure: Industrial use (Manufacture or formulation in the

chemical industry in closed batch processes with occasional controlled exposure or
processes with equivalent containment condition) (PROC3)

of effects
- systemic
- local
- local
systemic
SAFETY DATA SHEET


- systemic
4.3.4 ES 4 - CS 4: Worker exposure: Industrial use (Mixing or blending in batch

processes) (PROC5)

of effects
- systemic
- local
- local
systemic
- systemic
4.3.5 ES 4 - CS 5: Worker exposure: Industrial use (Transfer of substance or mixture

(charging/discharging) at dedicated facilities) (PROC8b)

of effects
- systemic
- local
- local
systemic
- systemic
4.3.6 ES 4 - CS 6: Worker exposure: Industrial use (Roller application or brushing)

(PROC10)

of effects
- systemic
- local
- local
systemic
SAFETY DATA SHEET


- systemic
4.3.7 ES 4 - CS 7: Worker exposure: Industrial use (Treatment of articles by dipping

and pouring) (PROC13)

of effects
- systemic
- local
- local
systemic
- systemic

Section 2
5. ES 5: Professional use; Washing and cleaning products,

Solid
Environment
CS1: Professional use (Widespread use of non-reactive processing aid (no ERC8a
inclusion into or onto article, indoor))
Workers
CS2: Professional use (Manufacture or formulation in the chemical industry in PROC3
CS3: Professional use (Mixing or blending in batch processes) PROC5
CS4: Professional use (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
CS5: Professional use (Transfer of substance or mixture PROC8b
CS6: Professional use (Transfer of substance or mixture into small containers PROC9
(dedicated filling line, including weighing))
CS7: Professional use (Roller application or brushing) PROC10
SAFETY DATA SHEET

CS8: Professional use (Treatment of articles by dipping and pouring) PROC13

5.2.1 ES 5 - CS 1: Control of environmental exposure: Professional use (Widespread
use of non-reactive processing aid (no inclusion into or onto article, indoor)) (ERC8a)
Amount used
Amounts used : 2700 tonnes/year
Remarks : Professional use, Consumer use
Remarks : Professional use


water

plant effluent

local regulations.
5.2.2 ES 5 - CS 2: Control of worker exposure: Professional use (Manufacture or

Remarks : Sampling
Mixture/Article

only.


SAFETY DATA SHEET



Organisational measures to : Basic (professional) exposure controls assumed.
Technical conditions and : Basic (professional) exposure controls assumed.
changes per hour).
Note : Low hazard
characterisation.
5.2.3 ES 5 - CS 3: Control of worker exposure: Professional use (Mixing or blending

in batch processes) (PROC5)
Mixture/Article

only.




changes per hour).

SAFETY DATA SHEET

Note : Low hazard

characterisation.
5.2.4 ES 5 - CS 4: Control of worker exposure: Professional use (Transfer of

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)
Mixture/Article

only.




changes per hour).

Note : Low hazard

characterisation.

Mixture/Article

only.
SAFETY DATA SHEET





changes per hour).

Note : Low hazard

characterisation.

(PROC9)
Mixture/Article

only.




SAFETY DATA SHEET


changes per hour).

Note : Low hazard

characterisation.
5.2.7 ES 5 - CS 7: Control of worker exposure: Professional use (Roller application or

brushing) (PROC10)

Mixture/Article ART




Room size : 300 m3

measures

SAFETY DATA SHEET


Note : Low hazard

characterisation.
5.2.8 ES 5 - CS 8: Control of worker exposure: Professional use (Treatment of

articles by dipping and pouring) (PROC13)

Mixture/Article ART




Room size : 300 m3

measures

Note : Low hazard

characterisation.
SAFETY DATA SHEET


5.3.1 ES 5 - CS 1: Environmental release and exposure: Professional use
(Widespread use of non-reactive processing aid (no inclusion into or onto article,
indoor)) (ERC8a)


Sewage treatment plant. 0,00185 mg/L < 0,01
via the environment
5.3.2 ES 5 - CS 2: Worker exposure: Professional use (Manufacture or formulation in

the chemical industry in closed batch processes with occasional controlled exposure
or processes with equivalent containment condition) (PROC3)

of effects
- systemic
- local
- local
systemic
- systemic
5.3.3 ES 5 - CS 3: Worker exposure: Professional use (Mixing or blending in batch

processes) (PROC5)

of effects
SAFETY DATA SHEET

- systemic
- local
- local
systemic
- systemic
5.3.4 ES 5 - CS 4: Worker exposure: Professional use (Transfer of substance or

mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

of effects
- systemic
- local
- local
systemic
- systemic

mixture (charging/discharging) at dedicated facilities) (PROC8b)

of effects
- systemic
- local
- local
systemic
- systemic

mixture into small containers (dedicated filling line, including weighing)) (PROC9)

of effects
SAFETY DATA SHEET

- systemic
- local
- local
systemic
- systemic
5.3.7 ES 5 - CS 7: Worker exposure: Professional use (Roller application or brushing)

(PROC10)

of effects
- systemic
- local
- local
systemic
- systemic
5.3.8 ES 5 - CS 8: Worker exposure: Professional use (Treatment of articles by

dipping and pouring) (PROC13)

of effects
- systemic
- local
- local
systemic
- systemic

Section 2
SAFETY DATA SHEET

6. ES 6: Professional use; Washing and cleaning products,

Liquid
Environment
CS1: Professional use (Widespread use of non-reactive processing aid (no ERC8a
Workers
CS2: Professional use (Chemical production or refinery in closed process PROC1
without likelihood of exposure or processes with equivalent containment
conditions)
CS3: Professional use (Manufacture or formulation in the chemical industry in PROC3
CS4: Professional use (Mixing or blending in batch processes) PROC5
CS5: Professional use (Transfer of substance or mixture PROC8a
(charging/discharging) at non dedicated-facilities)
CS6: Professional use (Transfer of substance or mixture PROC8b
CS7: Professional use (Transfer of substance or mixture into small containers PROC9
(dedicated filling line, including weighing))
CS8: Professional use (Roller application or brushing) PROC10
CS9: Professional use (Treatment of articles by dipping and pouring) PROC13

6.2.1 ES 6 - CS 1: Control of environmental exposure: Professional use (Widespread
Amount used
Remarks : Professional use


water

SAFETY DATA SHEET


plant effluent

local regulations.
6.2.2 ES 6 - CS 2: Control of worker exposure: Professional use (Chemical

production or refinery in closed process without likelihood of exposure or processes
with equivalent containment conditions) (PROC1)
Remarks : Spraying
Closed systems

Mixture/Article ART




Room size : 300 m3
Handling of contaminated objects : > 3 m2
Contamination : > 90 %, ART

measures Chemical production or refinery in closed process without
likelihood of exposure or processes with equivalent
containment conditions
SAFETY DATA SHEET


Note : Low hazard

characterisation.
6.2.3 ES 6 - CS 3: Control of worker exposure: Professional use (Manufacture or

Remarks : Sampling

Mixture/Article ART




Room size : 300 m3

liquids

Open systems
Note : Low hazard
SAFETY DATA SHEET


characterisation.
6.2.4 ES 6 - CS 4: Control of worker exposure: Professional use (Mixing or blending

in batch processes) (PROC5)

Mixture/Article ART




Room size : 300 m3

m.
measures

Note : Low hazard

characterisation.

SAFETY DATA SHEET

substance or mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

Mixture/Article ART




Room size : 300 m3

liquids

Open systems
measures

Note : Low hazard

characterisation.

SAFETY DATA SHEET


Mixture/Article ART




Room size : 300 m3

liquids

air.

Note : Low hazard

characterisation.

(PROC9)

Mixture/Article ART

SAFETY DATA SHEET





Room size : 300 m3

liquids

air.

Note : Low hazard

characterisation.
6.2.8 ES 6 - CS 8: Control of worker exposure: Professional use (Roller application or

brushing) (PROC10)

Mixture/Article ART

SAFETY DATA SHEET




Room size : 300 m3

measures

Note : Low hazard

characterisation.
6.2.9 ES 6 - CS 9: Control of worker exposure: Professional use (Treatment of

articles by dipping and pouring) (PROC13)

Mixture/Article ART



SAFETY DATA SHEET


Room size : 300 m3

measures

Note : Low hazard

characterisation.

6.3.1 ES 6 - CS 1: Environmental release and exposure: Professional use
(Widespread use of non-reactive processing aid (no inclusion into or onto article,
indoor)) (ERC8a)


via the environment
6.3.2 ES 6 - CS 2: Worker exposure: Professional use (Chemical production or

refinery in closed process without likelihood of exposure or processes with
equivalent containment conditions) (PROC1)
SAFETY DATA SHEET


of effects
- systemic
- local
- local
Worker - dermal, long-term - 0,000136 mg/kg bw/day (ECETOC TRA worker V3, Tier < 0,01
systemic 1)
Worker - combined, long-term < 0,01
- systemic
6.3.3 ES 6 - CS 3: Worker exposure: Professional use (Manufacture or formulation in

the chemical industry in closed batch processes with occasional controlled exposure
or processes with equivalent containment condition) (PROC3)

of effects
- systemic
- local
- local
systemic
- systemic
6.3.4 ES 6 - CS 4: Worker exposure: Professional use (Mixing or blending in batch

processes) (PROC5)

of effects
- systemic
- local
- local
systemic
- systemic

SAFETY DATA SHEET

mixture (charging/discharging) at non dedicated-facilities) (PROC8a)

of effects
- systemic
- local
- local
systemic
- systemic

mixture (charging/discharging) at dedicated facilities) (PROC8b)

of effects
- systemic
- local
- local
systemic
- systemic

mixture into small containers (dedicated filling line, including weighing)) (PROC9)

of effects
- systemic
- local
- local
systemic
- systemic
6.3.8 ES 6 - CS 8: Worker exposure: Professional use (Roller application or brushing)

SAFETY DATA SHEET

(PROC10)

of effects
- systemic
- local
- local
systemic
- systemic
6.3.9 ES 6 - CS 9: Worker exposure: Professional use (Treatment of articles by

dipping and pouring) (PROC13)

of effects
- systemic
- local
- local
systemic
- systemic

Section 2
7. ES 7: Consumer use; Washing and cleaning products,

Liquid
Washing and cleaning products (PC35)

Environment
SAFETY DATA SHEET

CS1: Consumer use (Widespread use of non-reactive processing aid (no ERC8a
Consumer
CS2: Consumer use (Washing and cleaning products) PC35
7.2.1 ES 7 - CS 1: Control of environmental exposure: Consumer use (Widespread

Amount used
Remarks : Consumer use


water

plant effluent

local regulations.
7.2.2 ES 7 - CS 2: Control of consumer exposure: Consumer use (Washing and

cleaning products) (PC35)
Remarks : Laundry and dish washing products

Manual
Mixture/Article Concentration of substance in product
Concentration of the Substance in : <= 0,02 %

SAFETY DATA SHEET

Mixture/Article Concentration after dilution for use maximum, AISE REACT
Physical Form (at time of use) : Liquid

Frequency of use : 1,4 uses per day
Remarks : AISE REACT

Conditions and measures related to protection of consumer (e.g. behavioural advice,

personal protection and hygiene)
Consumer Measures : Ensure that splashes and spills are avoided by product
design.
Consumer Measures : Ensure that direct skin contact is avoided.


Textile pretreatment
Mixture/Article


Covers skin contact area up to : 857,5 cm²

design.


Clothing (all kind of materials), towel
Mixture/Article
SAFETY DATA SHEET

Amount used
Amounts used : 230 grams


design.

Remarks : Hand dishwasing (liquid regular, liquid concentrate) for

consumer use
Mixture/Article

design.

Remarks : Machine dishwashing (powder, liquid, tablet) for consumer

use
Mixture/Article

design.
SAFETY DATA SHEET


7.3.1 ES 7 - CS 1: Environmental release and exposure: Consumer use (Widespread


via the environment
7.3.2 ES 7 - CS 2: Consumer exposure: Consumer use (Washing and cleaning

products) (PC35)

of effects
Consumer - dermal, long-term 0,004 mg/kg bw/day (AISE REACT) < 0,01
- systemic
Consumer - combined, long- < 0,01
term - systemic

products) (PC35)

of effects
Consumer - dermal, long-term 0,057 mg/kg bw/day (AISE REACT) 0,064
- systemic
Consumer - combined, long- 0,064
term - systemic

products) (PC35)
SAFETY DATA SHEET


of effects
- systemic
term - systemic

products) (PC35)

of effects
- systemic
Consumer - oral, long-term - 0,000495 mg/kg bw/day (AISE REACT) < 0,01
systemic
term - systemic

products) (PC35)

of effects
Consumer - oral, long-term - 0,000495 mg/kg bw/day (AISE REACT) < 0,01
systemic
term - systemic

Section 2
8. ES 8: Consumer use; Washing and cleaning products,

Solid
Washing and cleaning products (PC35)

Environment
SAFETY DATA SHEET

CS1: Consumer use (Widespread use of non-reactive processing aid (no ERC8a
Consumer
8.2.1 ES 8 - CS 1: Control of environmental exposure: Consumer use (Widespread

Amount used
Remarks : Consumer use


water

plant effluent

local regulations.


Manual

SAFETY DATA SHEET

Physical Form (at time of use) : Powder products



design.


Textile pretreatment



Covers skin contact area up to : 857,5 cm²

design.


Clothing (all kind of materials), towel
SAFETY DATA SHEET

Mixture/Article
Amount used
Amounts used : 290 grams


design.

8.3.1 ES 8 - CS 1: Environmental release and exposure: Consumer use (Widespread


via the environment

products) (PC35)

of effects
- systemic
term - systemic
SAFETY DATA SHEET


products) (PC35)

of effects
Consumer - dermal, long-term 0,034 mg/kg bw/day (AISE REACT) 0,038
- systemic
Consumer - combined, long- 0,038
term - systemic

products) (PC35)

of effects
- systemic
term - systemic

Section 2

MSDS Praepagen HY

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SAFETY DATA SHEET

according to Regulation (EC) No. 1907/2006

PRAEPAGEN HY Page 1(92)

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

1.3. Details of the supplier of the safety data sheet

1.4. Emergency telephone number

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Serious eye damage, Category 1 H318: Causes serious eye damage.

Acute aquatic toxicity, Category 1 H400: Very toxic to aquatic life.

PRAEPAGEN HY Page 2(92)

2.2 Label elements

Signal word : Danger

Hazard statements : H302 Harmful if swallowed.

Hazardous components which must be listed on the label:

2.3 Other hazards

SECTION 3: Composition/information on ingredients

PRAEPAGEN HY Page 3(92)

aminium chloride 01-2119484688-17- STOT RE 2; H373

SECTION 4: First aid measures

4.1 Description of first aid measures

If swallowed : If swallowed, seek medical advice immediately and show this

Risks : No hazards known at this time.

SECTION 5: Firefighting measures

5.1 Extinguishing media

5.2 Special hazards arising from the substance or mixture

PRAEPAGEN HY Page 4(92)

5.3 Advice for firefighters

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and material for containment and cleaning up

6.4 Reference to other sections

SECTION 7: Handling and storage

7.1 Precautions for safe handling

7.2 Conditions for safe storage, including any incompatibilities

7.3 Specific end use(s)

PRAEPAGEN HY Page 5(92)

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

PRAEPAGEN HY Page 6(92)

alkyl-C12-14-(even numbered)-1- weight (d.w.)

Break through time : 30 min

Break through time : 480 min

Protective measures : Avoid contact with skin and eyes.

PRAEPAGEN HY Page 7(92)

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Colour : light yellow

Odour Threshold : not tested.

pH : 5,5 - 8,5 (20 °C)

Boiling point : not determined

Flash point : > 100 °C

Evaporation rate : not tested.

Upper explosion limit : Not applicable

Lower explosion limit : Not applicable

Combustion number : Not applicable

Vapour pressure : approx. 23 hPa (20 °C)

Relative vapour density : not tested.

Density : 0,9837 g/cm3 (20 °C)

0,9740 g/cm3 (40 °C)

0,9626 g/cm3 (60 °C)

Bulk density : Not applicable