FT 00.

raw
PDF 01-089-2803 Co O Cobalt Oxide
8000 PDF 01-074-1657 Co3 O4 tricobalt tetraoxide | Cobalt Oxide
PDF 01-077-2176 K2 O potassium dioxide | Potassium Oxide
PDF 00-013-0373 Al2 O3 χ-Al2 O3 | Aluminum Oxide

7000

6000

5000
Counts

4000

3000

2000

1000

0
10 20 30 40 50 60 70 80 90

2Theta (Coupled TwoTheta/Theta) WL=1.54060

Yes 0 PDF 01-089-2803 Pattern List #3 FT 00.raw #1 PDF 01-089-2803 Cobalt Oxide Co O Indexed 16.5281 %
Yes 1 PDF 01-074-1657 Pattern List #3 FT 00.raw #1 PDF 01-074-1657 tricobalt tetraoxide | Cobalt Oxide Co3 O4 Indexed 72.7076 %
potassium dioxide | Potassium
Yes 2 PDF 01-077-2176 Pattern List #3 FT 00.raw #1 PDF 01-077-2176 K2 O Indexed 9.5412 %
Oxide
Yes 3 PDF 00-013-0373 Pattern List #3 FT 00.raw #1 PDF 00-013-0373 χ-Al2 O3 | Aluminum Oxide Al2 O3 Blank 42.0031 %

3.820 6.73 % 1.0000 Yes 1.54060 Hexagonal P63mc (186) 3.21000 5.24000 2
4.680 24.16 % 1.0000 Yes 1.54060 Cubic Fd-3m (227) 8.06500 8
3.910 3.79 % 1.0000 Yes 1.54060 Cubic Fm-3m (225) 6.09000 2
(1) 65.32 % 1.0000 Yes 1.54060 Hexagonal P (0) 5.57000 8.64000 5

46.76 5.322 No F26= 318.4(0.0028, 29)

524.58 6.098 No F30= 999.9(0.0002, 30)
225.87 1.385 No F20= 999.9(0.0002, 20)
232.14 3.647 No F6= 1.3(0.1330, 34)
 Co O
Cobalt Oxide 2.77994 32.173 615 1 0 0
2.62000 34.196 438 0 0 2
2.45575 36.561 999 1 0 1
1.90666 47.658 213 1 0 2
1.60500 57.363 306 1 1 0
1.47897 62.777 284 1 0 3
1.38997 67.309 39 2 0 0
1.36861 68.504 196 1 1 2
Hexagonal 74.93 1.34351 69.968 92 2 0 1
P63mc (186) 46.76 1.31000 72.033 15 0 0 4
5.32 1.22787 77.709 29 2 0 2
1.18502 81.088 14 1 0 4
3.820
1.08762 90.184 62 2 0 3
3.21000 1.05072 94.297 19 2 1 0
1.03021 96.785 52 2 1 1
5.24000
1.01487 98.755 27 1 1 4
1.00000 2
0.98063 103.537 39 1 0 5
1.63240
0.97522 104.347 20 2 1 2
0.95333 107.804 5 2 0 4
0.92665 112.460 24 3 0 0
0.90036 117.639 59 2 1 3
0.87362 123.705 31 0 0 6
0.87362 123.705 31 3 0 2
ANX: AX
Analysis: Co1 O1 0.83680 134.007 24 2 0 5
Formula from original source: Co O 0.83319 135.193 6 1 0 6
ICSD Collection Code: 43458
0.81964 140.036 7 2 1 4
Calculated Pattern Original Remarks: Wurtzite type
Minor Warning: No e.s.d reported/abstracted on the cell dimension. No R 0.80250 147.429 17 2 2 0
factors reported/abstracted
Wyckoff Sequence: b2(P63MC)
Unit Cell Data Source: Powder Diffraction

Structure
Publication: Nature (London)
Detail: volume 193, page 867 (1962)
Authors: Redman, M.J., Steward, E.G.
Primary Reference
Publication: Calculated from ICSD using POWD-12++

CuKα1 Not specified

1.54060
318.4 (0.0028,29)
 Co3 O4
Cobalt Oxide 4.65633 19.045 150 1 1 1
2.85141 31.346 316 2 2 0

tricobalt tetraoxide 2.43169 36.936 999 3 1 1

2.32816 38.642 90 2 2 2
2.01625 44.921 204 4 0 0
1.85024 49.205 1 3 3 1
1.64626 55.797 84 4 2 2
1.55211 59.510 316 5 1 1
Cubic 240.8 1.42570 65.408 358 4 4 0
Fd-3m (227) 524.58 1.36323 68.812 13 5 3 1
6.1 1.34417 69.929 1 4 4 2
1.27519 74.323 25 6 2 0
4.680
1.22990 77.557 70 5 3 3
8.06500 1.21584 78.626 35 6 2 2
1.16408 82.863 20 4 4 4
1.12933 86.014 8 5 5 1
1.00000 8
1.07773 91.244 31 6 4 2
1.00000
1.04997 94.385 94 7 3 1
1.00812 99.653 36 8 0 0
0.98530 102.850 1 7 3 3
0.97803 103.925 1 6 4 4
0.95047 108.278 15 8 2 2
0.93127 111.615 58 7 5 1
ANX: AB2X4
Analysis: Co3 O4 0.92512 112.744 15 6 6 2
Formula from original source: Co3 O4 0.90169 117.361 21 8 4 0
Delete duplicate: Delete: See PDF 01-074-1656; WFM 12/04
0.88525 120.952 4 9 1 1
ICSD Collection Code: 27498
Minor Warning: No e.s.d reported/abstracted on the cell dimension. No R 0.87996 122.179 1 8 4 2
factors reported/abstracted 0.85973 127.268 5 6 6 4
Wyckoff Sequence: e d a(FD3-MS)
Unit Cell Data Source: Single Crystal 0.84544 131.321 51 9 3 1
0.82313 138.721 86 8 4 4
0.81056 143.730 2 9 3 3

Structure
Publication: J. Phys. Chem. Solids
Detail: volume 25, page 1 (1964)
Authors: Roth, W.L.
Primary Reference
Publication: Calculated from ICSD using POWD-12++

CuKα1 Not specified

1.54060
999.9 (0.0002,30)
 K2 O
Potassium Oxide 3.51606 25.310 883 1 1 1
3.04500 29.307 999 2 0 0

potassium dioxide 2.15314 41.925 607 2 2 0

1.83620 49.607 303 3 1 1
1.75803 51.973 179 2 2 2
1.52250 60.788 71 4 0 0
1.39714 66.918 95 3 3 1
1.36177 68.896 166 4 2 0
Cubic 94.2 1.24312 76.581 110 4 2 2
Fm-3m (225) 225.87 1.17202 82.180 60 5 1 1
1.38 1.07657 91.371 29 4 4 0
1.02940 96.887 55 5 3 1
3.910
1.01500 98.737 59 6 0 0
6.09000 0.96291 106.254 39 6 2 0
0.92872 112.079 21 5 3 3
0.91810 114.072 35 6 2 2
1.00000 2
0.87902 122.403 11 4 4 4
1.00000
0.85277 129.188 36 7 1 1
0.84453 131.595 30 6 4 0
0.81381 142.360 59 6 4 2

ANX: A2X
Analysis: K2 O1
Formula from original source: K2 O
ICSD Collection Code: 60489
Calculated Pattern Original Remarks: DIS O2( with disorderly orientation
in halide position. Stable from 590 to 645K, m.p
919 K, 645-719 K: trigonal (2nd ref., Tomaszewski)
Minor Warning: No R factors reported/abstracted. Magnitude of e.s.d. on
cell dimension is >1000 ppm
Wyckoff Sequence: b a(FM3-M)
Unit Cell Data Source: Single Crystal

Structure
Publication: Acta Crystallogr.
Detail: volume 5, page 851 (1952)
Authors: Carter, G.F., Margrave, J.L., Templeton, D.H.
Primary Reference
Publication: Golden Book of Phase Transitions, Wroclaw
Detail: volume 1, page 1 (2002)
Authors: Carter, G.F., Margrave, J.L., Templeton, D.H.
Publication: Calculated from ICSD using POWD-12++

CuKα1 Not specified

1.54060
999.9 (0.0002,20)
 Al2 O3
Aluminum Oxide 4.80000 18.469 15 1 0 0
2.88000 31.027 25 0 0 3

χ-Al2 O3 2.41000 37.281 50 2 0 0

2.12000 42.612 50 2 0 2
1.96000 46.284 35 1 0 4
1.39500 67.034 100 2 1 4

Hexagonal 101.96
P (0) 232.14

-1.000
5.57000

8.64000
1.00000 5
1.55117

Sample Preparation: Sample obtained by heating gibbsite to 470 C

Unit Cell Data Source: Powder Diffraction

Primary Reference
Publication: Am. Mineral.
Detail: volume 46, page 771 (1961)
Authors: Brindley, Choe.

Not specified
1.54060
1.3 (0.133,34)