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OPERATORS
(1) |x0 i = δ (x − x0 )
1
(2) |p0 i = √ eip0 x/h̄
2π h̄
The normalizations of both the position and momentum eigenfunctions
give us more delta functions:
ˆ
(3) hx1 |x0 i = δ (x − x1 ) δ (x − x0 ) dx
(4) = δ (x1 − x0 )
ˆ
1
(5) hp1 |p0 i = ei(p0 −p1 )x/h̄ dx
2π h̄
(6) = δ (p0 − p1 )
1
EIGENFUNCTIONS OF POSITION AND MOMENTUM; UNIT OPERATORS 2
(7) P̂ ≡ |αihα|
Note that this is a completely general expression; we can choose any ba-
sis states |αi (they could be the eigenstates of position or momentum, or
the discrete set of states for some system such as the states of the infinite
square well or harmonic oscillator) and the projection operator gives the
component of |ψi ’along’ that basis vector. In practice, to do calculations
we usually express |ψi in position or momentum space (or in matrix form
if it’s a spin state) but in this formula, |ψi is just an abstract symbol repre-
senting some arbitrary state.
For a complete set of discrete basis states we can define the unit operator
This works because it’s just like expressing a 3-d vector as a sum of its
components in some basis, such as rectangular coordinates
(11) v = vx x̂ + vy ŷ + vz ẑ
Since the basis consisting of the states |αi is complete, we can write any
other state in terms of that basis set. We’re using the projection operator for
each basis state to project out the new state onto each of the basis states in
turn, then adding up the result:
or
EIGENFUNCTIONS OF POSITION AND MOMENTUM; UNIT OPERATORS 3
ˆ
(13) |ψi = dα |αi hα |ψ i
Example 1. Armed with these results, it’s worth looking at Example 3.6 in
Lancaster & Blundell in a bit more detail. In that example, they extend the
creation-annihilation operator representation to cases where the momentum
(and hence the energy) states merge into a continuum. In that case, the
commutation relation for the operators becomes
h i
(14) ap , aq = δ (3) (p − q)
†
L&B are dealing with a 3-d particle in a box with periodic boundary
conditions (rather than requiring the wave function to be zero outside the
box), so the momentum eigenstate |pi is just a plane wave so that its position
space representation is
1
(15) hx |p i = √ eip·x
V
0 D E
(16) p p = â†p 0 â†p0 0
D E
†
(17) = 0 âp âp0 0
0 D E
(3) 0
(19) p p
= 0 δ p−p 0
= δ (3) p − p0
(20)
Now we want to get the position space version of the state |pi. From 1
(generalized to 3-d) we see that
EIGENFUNCTIONS OF POSITION AND MOMENTUM; UNIT OPERATORS 4
(21) φp (x) ≡ hx |p i
ˆ
d 3 x0 x x0 x0 |p
(22) =
ˆ
d 3 x0 δ (3) x − x0 x0 |p
(23) =
ˆ
(24) |xi = d 3 q |qi hq |xi
ˆ
(25) = d 3 q |qi hx |qi∗
ˆ
(26) = d 3 qφq∗ (x) |qi
Therefore
ˆ
(27) hx| = d 3 qφq (x) hq|
ˆ
(28) hx |pi = d 3 qφq (x) hq |p i
ˆ
(29) = d 3 qφq (x) δ (3) (q − p)
(30) = φp (x)
0 0 D E
(31) p q |pq = 0 âp0 âq0 â†q â†p 0
âp0 âq0 â†q â†p = âp0 δ (3) q − q0 + â†q âq0 â†p
(32)
= δ (3) q − q0 δ (3) p − p0 + â†p âp0 + âp0 â†q âq0 â†p
(33)
= δ (3) q − q0 δ (3) p − p0 + â†p âp0 +
(34)
δ (3) q − p0 + â†q âp0 δ (3) p − q0 + â†p âq0
(35)
0 0
p q |pq = δ (3) q − q0 δ (3) p − p0 + δ (3) q − p0 δ (3) p − q0
(36)
0 0 0 0
(37) p q = p q
ˆ ˆ
(39) hrs |pq i = d 3 yφr∗ (x) φs∗ (y) ψp (x) ψq (y)
3
d x
ˆ ˆ
(40) = d xφr (x) ψp (x) d 3 yφs∗ (y) ψq (y)
3 ∗
(41) = hr |p i hs |q i
ˆ ˆ
1 3 0
d 3 q0 p0 q0 q0 |y p0 |x
(42) |xyi = √ d p
2! ˆ ˆ
1 3 0
d 3 q0 φp∗0 (x) φq∗0 (y) p0 q0
(43) = √ d p
2! ˆ ˆ
1 3 0
d 3 q0 φp0 (x) φq0 (y) p0 q0
(44) hxy| = √ d p
2! ˆ ˆ
1 3 0
d 3 q0 φp0 (x) φq0 (y) p0 q0
(45) = √ d p
2!
The √12! is there because the double integral extends over all values of
both p0 and q0 so it counts the state |p0 i |q0 i twice, once as |p0 i |q0 i and
once as |q0 i |p0 i. It’s a square root because we’re dealing with a raw wave
function and it’s the square modulus of this that must be normalized.
With this, we get, using 36
ˆ ˆ
1
d p d 3 q0 φp0 (x) φq0 (y) p0 q0 |pq
3 0
(46) hxy |pqi = √
2!
1
(47) = √ [φp (x) φq (y) + φq (x) φp (y)]
2
This is the symmetrized wave function for two identical bosons. Follow-
ing through the same argument using anticommutators for fermions gives
the fermion result
1
(48) hxy |pq i f ermion = √ [φp (x) φq (y) − φq (x) φp (y)]
2