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Chemistry (BII) T10 MDCAT Entry Test (2019)

(Series 2)
Carboxylic acids and Halogens
Q.1 Aqueous solution of which amino acids turns blue Litmus red?
A) His C) Gla
B) Lys D) Pro

Q.2 Which is neutral amino acid

A) Histidine C) Aspartic acid
B) Valine D) Lysine

Q.3 A dipeptide contains _____________ amino acid

A) Three C) Five
B) Four D) Two

Q.4 The given compound is present in red–algae in ocean bed. NH2 – CH2 – CH2 – CH2 COOH in what way this differs from
the amino acids obtained by the hydrolysis of protein.
A) It does not form zwitterions C) It is –amino acid
B) It is insoluble in water D) It forms polyamide

Q.5 Which is not an amino acid

A) Alanine C) Aniline
B) Glycine D) Lysine

Q.6 Identify the phenyl Alanine out of followings

A) HO – CH2 (CH) (NH2) – COOH C) C6H5 – CH2 – CH (NH2) COOH
B) HS – CH2 (CH) (NH2) – COOH D) CH3–CH(OH)CH(NH2)COOH

Q.7 The Number of peptide bonds in tripeptide are

A) One C) Four
B) Two D) Three

Q.8 The amino acid found in cheese is

A) Glycine C) Aspartic acid
B) Tyrosine D) Alanine

Q.9 –Amino succinic acid is another name for also called

A) Lysine C) Alanine
B) Aspartic acid D) Glutamic acid

Q.10 When one molecule of aspartic acid and one molecule of glutamic acid are allowed to react to form amide linkage the
maximum number of probable product will be
A) Two C) Four
B) Three D) One

Q.11 The nature of Alanine is

A) acid C) neutral
B) basic D) weakly acidic

Q.12 What is formula of glutamic acid?

A) NH2CH2COOH C) HOOC(CH2)2CH(NH2)COOH
B) CH3CH2 CH2 COOH D) Cl3CCOOH

Q.13 The dipolar structure of Zwitterions is also called

A) double salt C) internal salt
B) health salt D) external salt

Q.14 Which of the following pairs has same type of linkage between their structural unit
A) PVC and bakelite C) Proteins and nylon
B) Nylon and polyethylene D) Proteins and PVC

Q.15 What is the name of amino acid, NH2–CH(R)–COOH where ‘R’ is CH3 group?
A) Glycine C) Lysine

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 B)
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Alanine
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D) Guanine

Q.16 –amino acids are compounds having carboxylic acid as well as amino functional groups attached to:
A) Same carbon atom C) Neighbouring carbon atoms
B) Alternate carbon atoms D) Adjacent carbon atoms

Q.17 Identify the ‘zwitterion’ from followings

+ +
- -
N H 2 - CH - CO 2 N H 3 - CH - CO 2
A) | C) |
R R
+ +
- -
N H 4 - CH - CO 2 N H 2 - CH - CO
B) | D) |
R R

Q.18 Two or more amino acids condensed to form protein by a peptide linkage which is present between two atoms:
A) C and C C) C and N
B) O and C D) C and H

Q.19 The amino acids which largely exist in dipolar ionic form are:
A) –amino acids C) –amino acids
B) –amino acids D) –amino acids

Q.20 Organic compound containing both amino and carboxylic group is known as:
A) Amid acid C) Saccharide
B) Fatty acid D) Amino acids

Q.21 Which of the following structures is not an α-amino acid?

H 2 N - CH - COOH
A) | C) H 2 N - CH 2 - CH 2 - CH 2 - CH 2 - COOH
CH 2OH
H 2 N - CH - COOH H 2 N - CH - COOH
B) | D) |
CH 3 CH 3- Ph

Q.22 In basic conditions, amino acid exists in which of the following forms:
A) H3N+ CH2 COOH C) H3N+ CH2 COO–
B) H2N CH2 COOH D) H2N CH2 COO–

Q.23 At Low pH or in acidic condition amino acid acts as:

A) H3N+ CH2 COOH C) H3N+ CH2 COO–
B) H2N CH2 COOH D) H2N CH2 COO–

Q.24 The amino acids which are prepared in human body are called:
A) Essential amino acids C) –amino acids
B) Non-essential amino acids D) –amino acids

Q.25 Which one is a basic amino acid

A) Arginine C) Aspartic acid
B) Alanine D) Glycine

Q.26 Which of the following reagent is used for identification of amino acids?
A) Fehling’s solution C) Ninhydrin
B) Benedicts solution D) Copper sulphate

Q.27 The structure shown below represents:

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O

OH
N
NH CH3
A) Proline C) Glycine
B) Histidine D) Lysine

Q.28 Indicate the cyclic amino acid from the following:

A) Valine C) Glutamic acid
B) Alanine D) Proline

Q.29 Identify the structure………..

NH
H2N OH

O CH3
A) Basic Amino acids C) –amino acids
B) Dipeptide D) –amino acids

Q.30 The skeletal formula of dipeptide formed between aspartic acid and phenylalanine is given below:

O NH2
NH
HO

O
O O
H3C
How many functional groups are present in its formula?
A) 1 C) 4
B) 2 D) 3
Q.31 Which of the following pairs is wrong?
A) Benzyl acetate & Jasmine C) Iso – butyl formate & Raspberry
B) Amyl butyrate & Apricot D) Ethylbutyrate & Orange(octyl acetate)
Q.32 Which of the following reaction conditions lead to partial reduction of carboxylic acids to alcohols?
A) LiAlH4 C) P2O5
B) HI in presence of P D) H2SO4
Q.33 Acetic Acid is commercially prepared…
A) By oxidation of ethyl alcohol C) From acetylene
B) By hydrolysis of methyl nitrile D) From all of the above quoted methods
Q.34 Boiling points of Carboxylic acids are relatively higher due to…
A) Hydrogen bonding among its molecules C) Solubility of these in water
B) Higher molecular masses of these D) All of the above
Q.35 Formic acid was isolated first time from…
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A) Stings of ants
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C) Beetles
B) Distillation of red ants D) Cockroaches
Q.36 The reverse process of Esterification is called as
A) Neutralization C) Reduction
B) Substitution reaction D) Hydrolysis
Q.37 The IUPAC name of Glycine is:
A) 2-amino acetic acid C) 2-amino butanoic acid
B) 2-amino propanoic acid D) 1-amino acetic acid
Q.38 The Ninhydrin reaction is also widely used to “visualize” amino acids separated by
A) Column chromatography C) Paper chromatography
B) Thin Layer chromatography D) Solvent Extraction
Q.39 The complete reduction of Carboxylic acid is done by using
A) H2\Ni C) NaBH4
B) LiAlH4 D) HI and Red Phosphorus
Q.40 Which of the following metal cannot evolve hydrogen from Acetic Acid?
A) Sodium C) Magnesium
B) Potassium D) Zinc
Q.41 Which of the following is fatty acid?
A) Oxalic acid C) Ethanoic acid
B) Phthalic acid D) Succinic acid
Q.42 RMgBr on reacting with CO2 followed by acid hydrolysis produces Lactic acid. What is R in this case?
A) Ehtyl C) Propyl
B) Methyl D) None of these
Q.43 The sting of Bee has the pH
A) Less then 7 C) Equal to 7
B) Greater then 7 D) Equal pH of Water
Q.44 Salts of the carboxylic acid can be converted into respective carboxylic acid by treating with
A) Water C) Mineral Acid
B) Base D) Alcohol
Q.45 Which of the following react with NaOH to produce an acid and an alcohol?
A) CH3COOH C) HCHO
B) C6H5COOH D) CH 3CH2COOH
Q.46 Carboxylic acid undergoes ionization due to
A) Hydrogen bonding C) High reactivity of α-hydrogen
B) Absence of α-hydrogen D) Resonance stabilization of carboxylate ions
Q.47 A fruity smell is produced by the reaction of C2H5OH with
A) PCl5 C) CH3COCH3
B) CH3COOH D) None of these
Q.48 Which compound gives CO2 with NaHCO3?
A) Hexanol C) N-butanol
B) Phenol + acetic acid D) Acetic acid
Q.49 On strong heating, ammonium acetate gives
A) Urea C) Acetamide
B) Formamide D) Methyl cyanide
Q.50 Which one of the following orders of acid strength is correct?
A) RCOOH > HC ≡ CH > HOH > ROH C) RCOOH > HOH > ROH > HC ≡ CH
B) RCOOH > ROH > HOH > HC ≡ CH D) RCOOH > HOH > HC ≡ CH > ROH

Q.51 Cl2O7 is an anhydride of

(a) HClO (b) HClO2 (c) HClO3 (d) HClO4

Q.52 Chlorine reacts with NaOH in cold state to form

(a) Perchlorate (b) Chlorate (c) Chlorite (d) Hypo chlorite

Q.53 The strongest reducing agent amongst the following hydrogen halides
(a) HF (b) HCl (c) HBr (d) HI

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Q.54
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When bleaching powder is treated with ammonia, the products are
(a) CaO and N2 (b) CaO and Cl2 (c) Ca (OH)2 and N2 (d) CaCl2 and N2

Q.55 Amongst the following halogens, the highest bond energy is present in
(a) F2 (b) Cl2 (c) Br2 (d) I2

Q.56 Reaction of chlorine with cold & hot NaOH is an example of

(a) Oxidation reaction (b) Reduction reaction (c) Disproportionation reaction (d) Neutralization reaction

Q.57 Astatine (At) is in Group VII of the Periodic Table. Which of the following is a property of astatine?
A) It forms a basic oxide. C) It is displaced by chlorine from aqueous potassium
astatide.
B) It is a good conductor of electricity. D) It displaces iodine from aqueous potassium iodide.

Q.58 Elements X and Y are in Group VII of the Periodic Table. X is a liquid at room temperature. Y is a solid at
room temperature.

1. Atoms of Y have more protons than atoms of X.

2. Molecules of Y have more atoms than molecules of X.

3. Y displaces X from aqueous solutions of X ions.

A) 1 only C) 3 only
B) 2 only D) 1,2 and 3

Q.59 Which statement about the elements chlorine, bromine and iodine is correct?
A) They are all gases at room temperature and pressure. C) They become darker in colour from chlorine to bromine to iodine.
B) They are in the same period of the Periodic Table. D) They possess one electron in the outermost shell.

Q.60 Which substance in the table is the element iodine?

State at room temperature Electrical conductivity when molten
A) Liquid Good
B) Liquid None
C) Solid Good
D) Solid None

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