CHEMISTRY-XII Chapter 9

CARBAN COMPOUNDS WITH OXYGEN CONTAINING FUNCTIONAL GROUPS

01. The compountds in which C-atom of the benzene ring is directly attached with OH-group, are called 1
_________.
a) Phenols b) Halides
c) Alcohols d) None of these A
03. When the C-atom of open chain is directly bonded with OH-group then the compound formed are 2
called ___________
a) Halides b) Alcohols
c) Benzene d) None of these B
04. The formula for propyl alcohol is _____________ 3
a) CH3OH b) C2H5OH
c) CH3-CH2-OH d) CH3-CH2-CH2-OH D
05. The general formula for primary alcohol is ___________ 4
a) R – OH b) R – Cl
c) R – NH3 d) None of these A
06. The general formula for secondary alcohol is ___________ 5
a) R – OH b) R – Cl

Cl
H
| |
R− C−OH R−OH −R
| | C
c) R d) NH 3
07. The general formula for tertiary alcohol is ___________ 6
a) R – OH b) R – Cl

R CI
| |
R− C−OH R−C−Cl
| | C
c) R d) NH 3
08. The alcohols which contain only one OH—group, are called ___________ alcohols. 7
a) Monohydric b) Dihydric
c) Complex d) Simple A
09. We can represent n-propyl alcohol as _________ 8
a) CH3 - OH – CH3 b) CH3 – CH2 – CH2 – OH
c) CH3 – CH2 – OH d) None of these B
10. The alcohols containing two OH – groups are called __________ alcohols. 9
a) Formic b) Benzonic
c) Dihydric d) Trihydric C
11. The formula for glycol is __________ 10
a) CH3OH b) CH3R

CH 2 − CH 2
| |
C
c) OH OH d) CH3 – CH2 – OH
12. The alcohols containing three OH – groups are called __________ alcohols. 11
a) Trihydric b) Dihydric
c) Simple d) Monohydric A
14. The alcohols which have more than one OH – groups are called ________ alcohols 12
a) Polyhydric b) Monohydric
c) Simple d) Dihydric A

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 CHEMISTRY-XII Chapter 9
CARBAN COMPOUNDS WITH OXYGEN CONTAINING FUNCTIONAL GROUPS
15. The compounds in which C – atoms of carbonyl group is directly bonded with at least one H – atom, 13
are called __________
a) Aldehydes b) Dihydric
c) Monydric d) Polyhydric A
O 14

||
16. H−C−H is the formula for __________
a) Benzophenone b) Cyclohexanone C
c) formaldehyde d) None of these
17. The compounds which are formed by the displacement of OH – group of carboxylic group by any 15
halogen atom, are called ___________
a) Acid halides b) Benzamide
c) Formamide d) None of these A
18. The compounds which are formed by the displacement of OH – group of carboxylic group by an 16
amino group, are called ___________
a) Acid halides b) Acid amides
c) Esters d) Methanol B
19. The formula for ethyl benzoate is _________ 17
O O
|| ||
a)
CH 3 −C −NH 2 b)
H−C −NH 2
O
||
c)
C6 H 5−C −OC 2 H 5 d) CH3 – CH2 – OH
C
20. The formula for methanol is ____________ 18
a) C2H5OH b) CH3OH
c) CH3CI d) None of these B
ZnO /atm 200
19
⃗
21. CO + 2H2 400−450 0 C _____________
a) CH3OH b) C2H5OH
A
c) CO2 + H2 d) C12H22O11
22. CH3 – OH + SOCl2  ____________ 20
a) 2C2H5OH b) CH3OH + H2O
c) CH3Cl + SO2 + HCl d) None of these C
23. Methanol is used to prepare ___________ 21
a) Formaldehyde b) Oxygen
c) Hydrogen d) Alcohol A
24. Methanol is used to prepare in paints and _________ 22
a) Acids b) Base
c) Varnish d) None of these C
25. Ethyl alcohol is prepared by the fermentation of _______ 23
a) Starch b) Water
c) Soil d) Fire A
26. When primary alcohols react with acidified “K2Cr2O7”, then _________ are formed 24
a) Methyl alcohol b) Aldehydes
c) Oxygen d) Hydrogen B
ZnCl 2
25
⃗
27. C2H5OH + HCl ΔH _____________
a) C2H5(OH)2 + Cl2 b) C2H5Cl + H2O
B
c) C2H5 + HCl d) None of these

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 CHEMISTRY-XII Chapter 9
CARBAN COMPOUNDS WITH OXYGEN CONTAINING FUNCTIONAL GROUPS
28. The process to prepare esters, is called ___________ 26
a) Esterification b) Ethers
c) Alkyl halides d) Halogens A
29. Ethyl alcohol is used to purify ____________ 27
a) NaCl b) Na2CO3
c) NaOH d) None of these C
31. Formaldehyde is also called __________ 28
a) Methanal b) Alcohol
c) Acetone d) Bakelite A
32. The formula for acetaldehyde is ___________ 29
a) Methanol b) CH3CHO
c) C2H5OH d) CH3OH B
35. The formula for acetic acid is __________ 30
a) CH3COOH b) C2H5OOH
c) CH3OH d) C2H5OH A
37. The formula for phenol is ___________ 31
a) C6H5 – OH b) CH3 – OH
c) C2H5 – OH d) CH3 – Cl A
39. The phenol is a ____________ antiseptic 32
a) Low b) Great
c) Powerful d) Hydroxide C
40. The formula for ethyl bisulphate is __________ 33
a) C2H5HSO4 b) C2H5OH
c) CH3OH d) CH3Cl A
1219. When phenol is reduced in the presence of Zn dust, we get 34
a) Cyclohexene b) Cycolhexane
c) Benzene d) Benzyne C
1220. Alcohol reacts with halogen acid to produce 35
a) Alkyl halides b) Aldelydes
c) Ketones d) Alkanes A
1221. Acetone may be converted to iodoform by heating with 36
a) Br2 b) I2
c) F2 d) CI2 B
1222. Nitration of phenol gives 37
a) O-nitrophenol b) p-nitrophenol
c) m-nitrophenol d) Both O and p-nitrophenol D
1223. The functional group aldehyde is 38
a) R – X b)  COX
c)  CHO d) COOR C
1224. Which of a following is used as anesthetics? 39
a) Alcohol b) Ether
c) Aldehyde d) Acid B
1225. Treatment of a secondary alcohol with a suitable oxidizing agent (K2Cr2O2) results in the formation 40
of
a) Ketone b) Aldehyde
c) Ether d) Alkyl halide A
1226. Which of the following is a chief constituent of vinegar? 41
a) Alcohol b) Glucose
c) Sucrose d) Acetic acid D
1229. The formaldehyde in the presence of K2Cr2O7 and H2SO4 gives 42
a) Ethanol b) Acetic acid
c) Formic acid d) None of these C
1230. The formula of glycine is 43
a) Cl CH2  COOH b) NH2  CH2  COOH
c) NO2 CH2 COOH d) None of these B
1233. Which of the following is known as wood spirit? 44
a) ethyl alcohol b) propyl alcohol
c) methyl alcohol d) butyl alcohol C

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 CHEMISTRY-XII Chapter 9
CARBAN COMPOUNDS WITH OXYGEN CONTAINING FUNCTIONAL GROUPS
1234. Methyl alcohol possesses 45
a) burning taste b) poisonous
c) causing madness d) all these D
1235. Oxidation of methyl alcohol gives 46
a) formaldehyde b) acetone
c) ester d) acid A
1237. The malt-sugar in the presence of yeast or invertase gives 47
a) fructose b) glucose
c) lignin d) alcohol B
1238. Glucose in the presence of zymase is converted into 48
a) alcohol b) acid
c) ethyl alcohol d) ketone C
1239. Alcohols react with carboxylic acids, acid halides, acid anhydrides to produce the class of 49
compounds known as
a) Grignard’s reagent b) esters
c) amides d) none of these B
1240. Dehydration of ethyl alcohol yields 50
a) aldehyde b) ketone
c) acid d) alkene D
1241. Ethyl alcohol may be identified by 51
a) ring test b) iodoform test
c) tollen’s test d) Baeyer’s test B
1242. Oxidation of formaldehyde yields 52
a) acetic acid b) formic acid
c) sulphuric acid d) lactic acid B
1243. Formaldehyde on reduction gives 53
a) methyl alcohol b) ethyl alcohol
c) formic acid d) acetic acid A
1244. Which of the following gives Fehling’s solution test positive? 54
a) aldehyde b) ketone
c) acid d) ester A
1247. The oxidation of acetaldehyde gives 55
a) propanol b) acetone
c) formic acid d) acetic acid D
1249. Acetic acid reacts with thionyl chloride to give 56
a) acetic anhydride b) acetyl chloride
c) ethyl acetate d) none of these B
1250. Oxidation of 2-propanol gives 57
a) propanone b) butanone
c) pentanone d) none of these A
1251. The hydroxyl derivatives of aromatic hydrocarbons which have the  OH group directly bonded to 58
the ring C-atom are called
a) alcohols b) ketones
c) esters d) phenols D
1252. Dow’s process is used for the preparation of 59
a) esters b) ethers
c) alcohols d) phenols D
1253. Which of the following is weakly acidic in nature? 60
a) alcohol b) phenol
c) aldehyde d) amide B
1254. Phenol is used in the preparation of 61
a) aspirin b) phenacetin
c) salol d) all of these D
1262. Which of the following is produced when an aqueous solution of butan-2-ol is refluxed with dil 62
acidified KMnO4?
a) Butanol b) Butanoic acid
c) Butanone d) Butene C
1272. Which one of the following compounds gives an immediate precipitate with aqueous silver nitrate? 63
a) CH3CH2CH2Cl b) CH3CCl3
c) CH3COCl d) C6H5Cl C

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 CHEMISTRY-XII Chapter 9
CARBAN COMPOUNDS WITH OXYGEN CONTAINING FUNCTIONAL GROUPS
1275. Which class of compounds is commonly used for the artificial flavouring in jams? 64
a) Aldehydes b) Ketones
c) Carboxylic acids d) Esters D
938. Rectified spirit contains 65
a) 95.6 % alcohol b) 75.0 % alcohol
c) 100.0 % alcohol d) 85.4 % alcohol A
939. Alcoholic fermentation is brought out by the action of 66
a) Yeast b) CO2
c) O2 d) CO A
940. What is the end product in the process of fermentation 67
a) Methyl alcohol b) Ethanol
c) CH3CHO d) Ethylene B
941. Which is an isomer of ethanol 68
a) CH3OH b) CH3OCH3
c) C2H3OC2H5 d) C6H5OH B
942. Glycerine is a 69
a) secondary alcohol b) tertiary alcohol
c) trihydric alcohol d) ester C
945. A product formed by the reaction of sodium with ethanol is 70
a) H2O b) NaOH
c) NaH d) H2 D
946. Which of the following alcohols is least soluble in water 71
a) CH3OH b) C2H7OH
c) C6H13OH d) C10H21OH D
955. Aldehydes may be distinguished from ketones by the use of 72
a) conc H2SO4 b) Grignard’s reagent
c) Pyrogllol d) Fehlings solution D
956. A an aldehyde on oxidation gives 73
a) an alcohol b) a ketone
c) an acid d) an amine C
961. Which compound undergoes iodoform reaction 74
a) HCHO b) (CH3)2CO
c) CH3OH d) CH2ClCOOH B
969. The reagent that reacts easily with both acetaldehyde and acetone is 75
a) Fehlings solution b) Grignard’s reagent
c) Schiff’s reagent d) Tollen’s reagent B
974. Williamson’s synthesis is used to prepare 76
a) acetone b) P.V.C
c) bakelite d) diethylether D
977. The reaction, in which an alkyl halide reacts with sodium alkoxide to produce ether, is known as 77
a) hydrolysis b) kolbe’ reaction
c) Williamson’s synthesis d) Wurtz rection C
978. According to lewis concept, ethers behave as 78
a) acid b) base
c) neutral d) none of the above B
981. on heating ethyl ether to 400oC in the presence of Al2O3 we get 79
a) acetylene b) ethylene
c) ethane d) ethyl alcohol B
983. The reaction of formic acid with concentrated H2SO4 gives 80
a) CH3COOH b) HCNO
c) CO2 d) CO D
984. The acid present in vinegar is 81
a) CH3COOH b) HCl
c) H2SO4 d) HNO3 A

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