KISHORE VAIGYANIK PROTSAHAN YOJANA - 2014

Date : 02-11-2014 Duration : 3 Hours Max. Marks : 160

STREAM - SB/SX
GENERAL INSTRUCTIONS
• The Test Booklet consists of 120 questions.

• There are Two parts in the question paper. The distribution of marks subjectwise in each
part is as under for each correct response.

MARKING SCHEME :
PART-I :
MATHEMATICS
Question No. 1 to 20 consist of ONE (1) mark for each correct response.

PHYSICS
Question No. 21 to 40 consist of ONE (1) mark for each correct response.

CHEMISTRY
Question No. 41 to 60 consist of ONE (1) mark for each correct response.

BIOLOGY
Question No. 61 to 80 consist of ONE (1) mark for each correct response.

PART-II :
MATHEMATICS
Question No. 81 to 90 consist of TWO (2) marks for each correct response.

PHYSICS
Question No. 91 to 100 consist of TWO (2) marks for each correct response.

CHEMISTRY
Question No. 101 to 110 consist of TWO (2) marks for each correct response.

BIOLOGY
Question No. 111 to 120 consist of TWO (2) marks for each correct response.
 KVPY-2014 QUESTION PAPER - STREAM (SB/SX)

PART-I
One Mark Questions

MATHEMATICS
1. Sol- Let a,a1,a2 _ _ _ _ _ _ _ be the length of siden of square inscribed in circle c0,c1,c2 _ _ _ _ _
and r1, r2, r3, _ _ _ _ _ be radius of circle c1, c2, _ _ _ _ _
then, a 20  2   r12

2
r1 

8 4 2
2a12  a12   r22 r2 
  


 Area  Ci  .i

i0

4 8  2
 2   
 2 2 2
1


Ans. (D)

2. Sol.(A) [ x  y ]  [ x ]  [ y ]

3 5
for x  ,y 
2 3

3 5  3  5 
2  3  2  3
     
 9  10 
  6   1 1
 
 3  2 false
(B) [ xy ]  [ x ][ y ]
3 5
for x  ,y 
2 3

15 
 6   1 1
 
 2  1 false
(C) [2 x ]  2[7 / 2]
for x = 7/2
[27 / 2 ]  2[7 / 2]
1/2
 128    23
 
 11  8 false
 x  [x]
 (D)  y   [ y ] true  x  R
 
Ans. (A)

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3. An = (nCr) max
case- n = 2k (even)  An = 2kCk
 n – 1 = 2k – 1 (odd)  An–1 = 2k–1Ck–1 or 2k–1Ck
An
 1.9  A 2
n –1

2k
Ck
 1.9  2k – 1 2
C k –1
 1.9  2  2 which is true for
every n = even
n = 2, 4, 6,.......... 20  10 numbers
case- n = (2k – 1) (odd)
An = 2k–1Ck or 2k–1Ck–1
 An–1 = 2k–2Ck–1
An
 1.9  A 2
n –1

2k –1
Ck
1.9  2k – 2  2.0
C k –1

2k – 1
1.9  2
k
1.9 k  2k – 1  2k
10  k
 n  19
 n = 19 only
total = 11
Ans-(C)

4. Ans-(B)

(0,1)

1 1
,
2 2

( 1 + 2,0 )

5. Sol-

Ans - (B)

6. Sol-

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AS’ = SS’ = SB
 e = 1/3
a=3
Ans - (D)

7. Sol- AB=BC

2  1
Cos  and Sin 
3 2 6
 1
2     cos   sin 
2 6
y 1
cos   
2a 6

a 3

y 2
Ans- (C)
1 1
8. cos 4 x  2
 sin 4 x 
cos x sin2 x
1 1
 cos 4 x  sin4 x  
sin x cos2 x
2

cos2 x  sin2 x
 (cos2 x  sin2 x )  1 
sin2 x  cos2 x

 1 
 cos 2 x 1  2 2 0
 sin x  cos x 
 cos2x  0
2x = t, t  [0,4 ]
sin2 x  cos2 x  1
sin2 x (1  sin2 x )  1
 t (1  t )  1
 t  t2  1
 t2  t 1 0
D<0

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x  5
 , x2
9. Sol. f ( x )   x  2
 1 , x  2

f(x) is discontinuous at x = 2
f(x) = 2
x 5
 2
x 2
 x  5  2x  4
x9.
Ans(B)

10. Sol- f(x)  [x]sin x

Ans - (D)

11. Sol. sinx = tan2x

sin2x = sinx(1 – sin2x)
sin x (sin2x + sin – 1) = 0
5 1
sin x  0 sin x 
2

5 1 5 1
x  0,  sin1 ,   sin1
2 2

Ans(B)

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1
2
12. Sol- I   f(x )dx
0

Let x2=t
1
dx  dt
2 t
1
dt
I  1 f(t)
0 2 t

1 1
 
2 2 t
1 1
dt dt
 f(t) 2   f(t) 2
0 0 t 5I

Ans-(D)

13. Sol.f'(x) = 1 +f(x) f(0) = 0

f (x)
1
1 f (x)
ln (1 + f(x)) = x
then f(x + y) = f(x) + f(y) f(x) f(y)
Ans(C)

n
14. Sol.  cos(2 [ x]{xy })
0

1 1
n  cos(2 [ x ]1dx )  n  | dx  n
0 0

Ans(C)

5 1 1 5 6
15. Sol- P(B) = 1.  1. . .  .......... 
6 6 6 6 7
Ans -(B)

16. =
x i
n 3
n
2
2
x i

–
 xi 

= n  n 
 

y 1  y 2  y 3  ......  y n
̂ =
n
x1  x 2 x1  x 2
  x 3  x 4  .........  x n
= 2 2
n
x 1  x 2  ........  x n
= = .......(1)
n
2 2
 x1  x 2   x1  x 2 
     x 32  ......  x n2  2

̂ =
 2   2  –
y 1


n 
 n 


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1
(2x 12  2x 22  4 x 1x 2 )  x 32  ........  x n2  2

=
4 –
y 1


n 
 n 


1 2
( x 1  x 22 )  x 1x 2  x 32  ......  x n2  x  2
=
2 
–
i 

n  n 
 

2
x 12  x 22  .......  x 22  x i 

 –
n  n 
 
̂  .........(2)
by (1) and (2) (B) is correct

17. Sol- Let side length = 2a

3
 GA=GB=a
2
1
 cos   
3

3
a 2a
2
3
G a
2

D B

Ans -(C)

18. Ans -(A)

19. Ans- (D)

5 5 3 5 4 2 4  5 2 5 2
20. Sol. C2 2  C3  C4    
1  1 3 1 2 1 4 2 3
20 + 10×6 + 5[8 + 6] + 10 + 20 = 180

Ans - (C)

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PHYSICS

2L, m
21.

M(2L)2
J = mv J.L = 
12
V
 J/M
Cm

ML2
J.L= 
3
3J
=
ML
J2 3J2
ke=  = 2J2/m
2m 2m
Ans. (C)

22.

1 1
mgh = mv2+ I  2
2 2
1 1 MR 2 2
mgh = mv2 + .
2 2 2
1 1 3
gh = mv2 + mv2 = v2
2 4 4
4gh 4gh
V2 = V=
3 3
V= 2gh

Vp 4
  2/3
VR 32
Ans. (C)

23. V (r) = kr
k
U (r) = mkr 2 =
r
du k
F=-  mk  =
dr r
2 r
T=
k
Ans. (A)

24. Ans. (D)

25. A1V1 = A2V2

1 2
P+ dv = Const.
2
d = density
P1V1 = P2V2
Ans. (B)

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 KVPY-2014 QUESTION PAPER - STREAM (SB/SX)

26. Ans. (B)

27. Ans. (D)

28. PV2 = C
PV.V = K
nRT.V = K
VT = K
V1T1 = V2T2
V2>V1 T2<T1
P1V12 = P2V22
V2 2 P1

V12 P2
K2
P. C
T2
P
k
T2
P1 T2
2
 12
T1 T2
P1 T12

P2 T2 2
Ans. (B)

29.

 v o 
n’ = n  v  v 
 s 

 v 
n” = n  v  v 
 s 

n' v  v s

n" v  v s
n' v  v s 330  30 360
    1.2
n" v  v s 330  30 300
Ans. (C)

30. (A)

30 cm
31.

1 1 1
 
v u f
1 1 2
 
f fm fl
1 1 2 1
  
f  10 5
f = -5

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1 1 1
 
v 30 5
1 1 1
 
v 5 30
 6  1 5
 
30 30
v = -6cm

Ans. (B)

32.
Ans. (D)

Vx
33.

vy = ay.t
eE l
vy = .
m u
vx = u
eEl
tan  =
mu2
tan 1
4
tan 2
tan 1
tan 2 =  0.1
4
Ans. (A)

+q

+q -q
34.
-a/2 a/2

 KQ 
W1 = q  
 R 
 KQ kq 
W2 =    ( q)
 R a 
kq2
W=
a
Ans. (C)

C
35. Q= E
2
C.KC C2K CK
Ceq =  
C  KC C(1  k) 1  K
CK
Q= E
1 k
 CK C 
 Q =  1 k  2 E
 

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 CK C 
 Q =  1 k  2 E
 
2ck  c(k  1)
=
2(1  k)
2ck  ck  c ck  c
= 
2(1  k) 2(1  k)
Ans. (B)

36. V = ed
100
E=
20um
100
V1 = 1  5v
20
Ans. (A)

dN
37.  n
dt
dN
 dt
dt
6.93
 10 4
6.9
= 10-4
Ans. (D)

N 160  6200  1010

38. N=
4R 2 6.62  1034  3  108
5  1019  10 16  62  10 7
= =
4  3.14  3.24 20  10 34  108
5  1019  10 496
= =  1019
4  3.14  3.24 10
= 1.25 ×1019
Ans. (C)

1 1 1 1
 2 
1 2 2
3  4 9  125
39. 2 = 1 1 1 1 64
2
 2 
3 5 9 25
125
2  1
64
Ans. (B)

40. 10×8 = 80
11×7.5 = 82.5
Energy required = 82.5-80
= 2.5
Ans. (A)

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CHEMISTRY
41. KSP AgBr = (Ag+) (Br-) = (5×10-10) (10-3) = 5×10-13
Ksp AgBr
Concentration of Br- in 10-2M aq AgNO3 =
[ Ag  ]
5  10 13
=  5  10 11 m
(10 2 )
Ans. (D)

42. Over bromination take place in activated Aniline

Ans. (A)

43. +6 is maximum oxidation state of Cr

Ans. (D)

44. Ans. (C)

45. Al2O3 is amphoteric oxide

Ans. (C)
Ea 1
46. ln k = ln A – 
R T
Ans. (A)

47. Ni(CO)4 is tetrahedral with d10 configuration

Ans. (C)

48. Ozonolysis and intramolecular aldol

Ans. (A)

49. Ans. (B)

50.
Ans. (A)

51. When QC > KC

Reaction move in backward direction
Ans. (A)

52. SN-1 Reaction, more stable carbocation is formed

Ans. (C)

53.
Ans. (D)

54. Wolf kishner Reduction

Ans. (B)

55. Compound is AsCl3

Ans. (C)

56. Valency factor of KMnO4 = 5

5e- + MnO4- + 8H+  Mn+2 + 4H2O
Ans. (D)

57. Ans. (C)

H 6000 J
58.  S = T  213k  22J/K.mol
Ans. (A)

59. Ullmann reaction

Ans. (A)

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60. Ans. (C)
Energy of t2g orbitals < eg orbitals in octahedral complexes

BIOLOGY
61. (C) 62. (A) 63. (B) 64. (D) 65. (C) 66. (B) 67. (D)
68. (B) 69. (A) 70. (D) 71. (C) 72. (A) 73. (D) 74. (C)
75. (D) 76 (A) 77. (A) 78. (B) 79. (A) 80. (B)

PART-II
Two Mark Questions

MATHEMATICS
81. Ans-(A)
n
n
  k wk n
1 w 
2
w 
n

82. eR0  e  e

 when n is multiplying of 3, then

S=e, 1/e
when n is not multiple of three,then
s= e1/ 2 e1/ 2
Ans- (C)

83. Sol- y = ax2 + bx + c

a > 0, b < 0, c < 0
Also y(1) = a + b + c < 0

Ans-(B)

84.

1 r1 r
Sol- Sin    2
3 AP1 AP2
AP2  AP1  r1  r2
r2 3  r1 3  r1  r2
r2 ( 3  1)  r1  3 1 
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r2
 2 3
r1
Ans- (D)

85.

Sol- Let f(x) = 3x3 - 25x

f’(x) = 9x2 - 25
5
f’(x) = 0  
3
f(-5/3) = 250/9  27.7
f(5/3) = -250/9  -27.7
 n can take 55 values

Ans-(C)

86. Ans-( )
 /2
87. Sol- In   xn cos xdx
0

n

 In +n(n-1)In-2 =   .......(1)
2
  n
   ( 2)
 In   I  n  2 !I 

In  2  n   n 2  2 
Also   n!  n  2 !  =    =    = e  1 2
n2     n 2  n!  n  2  n! 
Ans- (A)

n n
88. Sol-  [x][ x ]dx   2dx  ............
1 1

= 50 for n = 8
66 for n = 9
Ans - (B)

89. Ans- (B), Check for n = 1, 2 , 3,......

90. Sol- No correct Option

(1,17), (2,17),(3,17),(4,17),(4,17),(6,17),(7,17)_ _ _ _ _ _ _ (16,17),(18,17) = 17 points
Also (17,1), (17,2), _ _ _ _ _ _ _ _ _ _ _ _ _ (17,16), (17,18) = 17 points

So there are more then 34 points.

Ans-()

PHYSICS
Initial Final
w
V=W'R
91.
A
From cons. of anguler momentum about A

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2Rw
 v=
7
2w
 W’ =
7
Ans. (C)

92. Ans. (A)

Tmin

mv 2 Tmax
93. Tmax - mg = ....(i)
R
mg cos
V mg mg
from energy cons.
ki + ui = kf + uf
1
O + mg (R-R cos  ) = mv2+0
2
V2 = 2gR (1-cos  )
Put in eq. (i)
Tmax = 3mg - 2mg cos 
Tmax
Tmin =4
 =60°
Ans. (B)

R
94. Heat cap. is define as C = Cv +
1 
3 R
C= R R
2 1 3
Ans. (D)

95. Ans. (A)

96. Ans. (C)

97. At steady state capacitor will belave as open circuit

1 2

2V 4V

6V
So charge store in 1  F = 1×4 = 4  C
in 2  F = 2 × 4 = 8  C
Ans. B

2P
98. F=
C
2  1.5  103
mg =
3  108
m = 10-6kg
Ans. (D)

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99. E =  + eV
E =  + e (.9)
1.1E =  + e(.9)
.1E = .3e
E = 3eV put
 2.4eV
Ans. (B)

100. (MLoT-2  -4) = (ML2T-1)  (ML2T-2  -1)  (LT

T-1) 
Solving we get
Ans. (C)

CHEMISTRY
101. Ans. (A)

PM dRT
102. d= M=
RT P
M = 123
 acetic acid exist as dimer
Ans. (B)

103.  E =  H -  (PV) =  H -  ngRT

Ans. (D)

104. Ans. (C)

105. N2 (g) + 2H2(g)  N2H4(g)

 =  (BDE) Reacant   (BDE)Pr oducts
Ans. (B)

106. Vk+ + VCl- = 133 + 181

KCl form FCC Lattice
 2(VK+ + VCl-) = a = edge length of unit cell
V = a3
Ans. (C)

107. K2Cr2O7+6FeSO4+ 7H2SO4  Cr2(SO4)3 + 3Fe2 (SO4)3+ K2SO4 + 7H2O

Ans. (B)

108. EoCell = SRP cathode - SRP anode

= -0.44 - (-0.74) = 0.3V
o -
 G = - nF E Cell (n = 6 ele )
Ans. (C)

109. Ans. (A)

110. XeF6 + 3H2O  XeO3 + 6HF

XeO3 is SP3 hybrid and pyramidal
Ans. (C)

BIOLOGY

111. (B) 112. (D) 113. (D) 114. (A) 115 (C) 116. (D) 117. (C)
118. (B) 119. (A) 120. (A)

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