Page 1/7

Safety data sheet

According to Regulation (EC) No. 1907/2006
Article 31
Printing date 12.09.2012 Version number 1 Revision: 12.09.2012

* 1 Identification of the substance/mixture and of the company/undertaking

· 1.1 Product identifier
· Trade name: NAFTOSAFE KD 25
· CAS Number:
69-72-7
· EC number:
200-712-3
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the preparation leadfree stabilizer composition for PVC processing
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
CHEMSON POLYMER-ADDITIVE AG
Industriestraße 19 FAX 0043 4255 2435 7
A-9601 ARNOLDSTEIN TEL 0043 4255 2226 0
· Further information obtainable from:
During the working time (07 am to 05 pm)
product safety department
Mr. Gerd Pack
Tel.: +43 42552226 252
Fax: +43 4255 24 35 7
Mobilphone.: +43 664 81 96 97 0
Email: gerd.pack@chemson.com
· 1.4 Emergency telephone number:
Riyadh
Drug and Poisons Information Centre
Pharmacy Department
College of Medicine
King Khalid University Hospital
P.O. Box 7805
Riyadh 11472
Director: Dr Saddique
E-mail: zsaddiqu@ksu.edu.sa

2 Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008

GHS05

Eye Dam. 1 H318 Causes serious eye damage.

GHS07

Acute Tox. 4 H302 Harmful if swallowed.

(Contd. on page 2)
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 Page 2/7
Safety data sheet
According to Regulation (EC) No. 1907/2006
Article 31
Printing date 12.09.2012 Version number 1 Revision: 12.09.2012

Trade name: NAFTOSAFE KD 25

(Contd. of page 1)

· Classification according to Directive 67/548/EEC or Directive 1999/45/EC

Xn; Harmful
R22: Harmful if swallowed.

Xi; Irritant
R41: Risk of serious damage to eyes.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms

GHS05 GHS07

· Signal word Danger

· Hazard statements
H302 Harmful if swallowed.
H318 Causes serious eye damage.
· Precautionary statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264 Wash thoroughly after handling.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor/physician.
P301+P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.

3 Composition/information on ingredients
· 3.1 Substances
· CAS No.:
69-72-7 salicylic acid
· EC number: 200-712-3
GB
(Contd. on page 3)

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Safety data sheet
According to Regulation (EC) No. 1907/2006
Article 31
Printing date 12.09.2012 Version number 1 Revision: 12.09.2012

Trade name: NAFTOSAFE KD 25

(Contd. of page 2)

4 First aid measures

· 4.1 Description of first aid measures
· General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
· After inhalation Remove to fresh air; consult doctor if symptoms persist.
· After skin contact
remove any contaminated clothing.
Wash affected area with water and soap immediately and rinse thoroughly.
· After eye contact Rinse opened eye for several minutes under running water.
· After swallowing Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

5 Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents Water with full jet.
· 5.2 Special hazards arising from the substance or mixture
Carbon monoxide (CO)
Formation of irritant gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained respiratory protective device.

6 Accidental release measures

· 6.1 Personal precautions, protective equipment and emergency procedures
Avoid formation of dust.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to item 13.
· 6.4 Reference to other sections
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

7 Handling and storage

· 7.1 Precautions for safe handling Ensure good ventilation/extraction at the workplace.
(Contd. on page 4)
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Safety data sheet
According to Regulation (EC) No. 1907/2006
Article 31
Printing date 12.09.2012 Version number 1 Revision: 12.09.2012

Trade name: NAFTOSAFE KD 25

(Contd. of page 3)
· Information about fire - and explosion protection:

Keep ignition sources away - Do not smoke.

· 7.2 Conditions for safe storage, including any incompatibilities

· Storage
· Conditions to be met by storerooms and receptacles: Keep container closed
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Store in dry condition
· Storage class VCI: LGK11
· Klassifizierung nach Betriebssicherheitsverordnung (BetrSichV): -
· 7.3 Specific end use(s) No further relevant information available.

* 8 Exposure controls/personal protection

· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
· Additional information: The lists valid during the making were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
· Respiratory protection: Filter P1.
· Protection of hands:

Protective gloves.

· Material of gloves Rubber gloves

· Eye protection: Safety glasses
· Body protection: Protective work clothing.

9 Physical and chemical properties

· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
Form: Powder
Colour: white
· Odour: odourless
(Contd. on page 5)
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Safety data sheet
According to Regulation (EC) No. 1907/2006
Article 31
Printing date 12.09.2012 Version number 1 Revision: 12.09.2012

Trade name: NAFTOSAFE KD 25

(Contd. of page 4)

· pH-value (1.8 g/l) at 20°C: 3.6

· Change in condition
Melting point/Melting range approx: 158-160°C
Boiling point/Boiling range: 211-240°C
· Flash point: 157°C
· Ignition temperature: 535°C
· Danger of explosion: Not determined
· Explosion limits: Not determined
· Lower: Not determined
· Upper: Not determined
· Vapour pressure at 30°C: >0.0001 hPa
· Density at 20°C: 1.44 g/cm³
· Bulk density at 20°C: 300-500 kg/m³
· Solubility in / Miscibility with
Water at 20°C: 1.8 g/l
· 9.2 Other information No further relevant information available.

10 Stability and reactivity

· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
No decomposition if used in accordance with recommendations.
· 10.3 Possibility of hazardous reactions No dangerous reactions known
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products: No dangerous decomposition products known

11 Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values relevant for classification:
Oral LD50 891 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rat)
· Primary irritant effect:
· on the skin: local irritation possible
· on the eye: Strong irritant with the danger of severe eye injury.
· Sensitization: No sensitizing effects known.
(Contd. on page 6)
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Safety data sheet
According to Regulation (EC) No. 1907/2006
Article 31
Printing date 12.09.2012 Version number 1 Revision: 12.09.2012

Trade name: NAFTOSAFE KD 25

(Contd. of page 5)
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version.
Irritant
Harmful

12 Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
EC50 180 mg/l (Daphnia magna, 24 Stunden)
LC50 90 mg/l (12)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water hazard class 1 (self-assesment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.

13 Disposal considerations
· 13.1 Waste treatment methods
· Recommendation

Must not be disposed together with household garbage. Do not allow product to reach sewage
system.

· European waste catalogue

06 00 00 WASTES FROM INORGANIC CHEMICAL PROCESSES
06 03 00 wastes from the MFSU of salts and their solutions and metallic oxides
06 03 14 solid salts and solutions other than those mentioned in 06 03 11 and 06 03 13
· Contaminated packaging:
· Recommendation: Disposal must be made according to official regulations.
GB
(Contd. on page 7)

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Safety data sheet
According to Regulation (EC) No. 1907/2006
Article 31
Printing date 12.09.2012 Version number 1 Revision: 12.09.2012

Trade name: NAFTOSAFE KD 25

(Contd. of page 6)

* 14 Transport information
· 14.1 UN
· ADR, ADN, IMDG, IATA Void
· 14.2 UN proper shipping name
· ADR, ADN, IMDG, IATA Void
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class Void
· 14.4 Packing group
· ADR, IMDG, IATA Void
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex
II of MARPOL73/78 and the IBC Code Not applicable.
· Transport/Additional information: Not dangerous according to the above specifications.
· UN "Model Regulation": -

15 Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the
substance or mixture
· Waterhazard class: Water hazard class 1 (Assessment by list): slightly hazardous for water.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
· Department issuing MSDS: Product safety department: Mr. Klaus Dolleschal
· Abbreviations and acronyms:
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
· * Data compared to the previous version altered.
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