CHLAA This Booklet contains 24 pages. Wu Test Booklet Code Do not open this Test Booklet until you are asked to do so. Read carefully the Instructions on the Back Cover of this Test Booklet. [Important Instructions : 1. The Answer Sheet is inside this Test Booklet. When you are directed to open the Test Booklet, take out the Answer Sheet and fill in the particulars on Side-1 and Side-2 carefully with blue/black ball point pen only. 2. The test is of 3 hours duration and this Test Booklet contains 180 questions. Each question carries 4 marks. For each correct response, the candidate will get 4 marks. For each incorrect response, one mark will be deducted from the total scores. The maximum marks are 720. Use Blue/Black Ball Point Pen only for writing particulars on this page/marking responses. Rough work is to be done on the space provided for this purpose in the Test Booklet only. 5. On completion of the test, the candidate must hand over the Answer Sheet to the Invigilator before leaving the Room/Hall. The candidates are allowed to take away this Test Booklet with them. 6. The CODE for this Booklet is GG. Make sure that the CODE printed on Side-2 of the Answer Sheet is the same as that on this Test Booklet. In case of discrepancy, the candidate should immediately report the matter to the Invigilator for replacement of both the Test Booklet and, the Answer Sheet. 7. The candidates should ensure that the Answer Sheet is not folded. Do not make any stray’ marks on the Answer Sheet, Do not write your Roll No. anywhere else except in the specified space in the Test Booklet/Answer Sheet. 8. Use of white fluid for correction is not permissible on the Answer Sheet.1. Offtets are produced by 8. ‘The correct order of steps in Polymerase Chain (1) Parthenocarpy Reaction (PCR) is (2) Parthenogenesis @). Denaturation, Extension, Annealing (3) Mitote divisions (2) Denaturation, Annoaling, Extension oe (@) Annealing, Extension, Denaturation 2, "The experimental proof for semiconservative|” (4) Extension, Denaturation, Annealing replication of DNA was first shown in a @) Plant 9. In India, the organisation responsible for @ Vins assessing the safety of introducing genetically 1, Basins modified organisms for public use is @) Fungus (2) Research Committee on __Genetie Naren: gh Sauaee Manipulation REG) oye ease Me lion 0° Piatt Saloni (2) Genetic Engineering Appraisal Committee and F. Stahl OBA et : (2) Francois Jacob and = Lac operon (3) Council for Scientific - and Industrial cenaueane Research (CSIR) poe soe ae (4) Indian Couneil of Medical Research (ICMR) Martha Chase 10. Which of the following is commonly used as a (A) Alec Jeffreys ~ Streptococcus vector for introducing a DNA fragment in human pneumoniae lymphocytes ? 4. Which of the following pairs is wrongly} (1) phage matched ? (2) pBRs22 (2) XO type sex Grasshopper : Determination ADTs 2) TH. Morgan Linkage a oe tol aaa oe ance {11+ Use of bioresources by multinational companies eee ee and organisations without authorisation from the Starch eyntheeis in pea : Multiple alleles | concerted country and ita people ksgalied 5. Solect the correct statement : (1) Biodegradation (Q) - Spliceosomes take part in translation. 2) Bivexploitation (2) Transduction was discovered by S. Altman. (3) Biopiracy (2) Punnett square was developed by a British] (4) _Bio-infringement scientist in Stahl coined the term “linkage”, [22+ A ‘new’ variety of rice was patented by a foreigr Ko Migcraeies paseo company, though such varieties have beer 6. Which of the following has proved helpful in] present in India for along time. ‘Ths is related to preserving pollen as fossils ? bee (1) Oitcontent o noe oo cata tstas (3) Sharbati Sonora (4). Pollenkitt. <"' . SARGE See Which of the following flowers only once in its|18. Select the correct match Hbeseied, (Q) TH, Morgan — Transduction ee @) G.Mendel = Transformatior (2) Papaya 0) enters an electric field E =-Ep! p= constant > 0) at t= 0. If pis its de-Broglie wavelength initially, then its de-Broglie wavelength at time tis @) dot @ dy de ( + @) St) mVy @ 7 ei; 14 Fe) ( TVG For a radioactive material, half-life 10 minutes. If initially there are 600 number of| nuclei, the time taken (in minutes) for the 107. In the circuit shown in the figure, the voltage V; is 20 V, Vg = 0 and Vop = values of Ip, Ic and P are given by 20V @) Tp=20nA, Ty=40nA, Ty =25 uA, Ty=40qA, Io=5mA, @ To=5mA, @) Ig=5mA, B=200 @) Ic=10 mA, B= 250 108. In a p-n junction diode, change in tempe due to heating (2) does not affect resistance of p-n juneti (2) affects the overall V — I characteris pn junction (3) affects only forward resistance disintegration of 450 nuclei is (4) affects only reverse resistance kth 109, Inthe combination. of the following gal @ 16 output ¥ can be written in terms of inputs 3) 10 Bas ), 20 2 = 106. When the light of frequency 2ip (where vp is| Be threshold frequency), is incident on a metal a plate, the maximum velocity of electrons emitted [> is vy. When the frequency of the incident radiation is increased to 5yo, the maximum velocity of electrons emitted from the same plate] (1) AvB +A.B is vp. The ratio of v to vp is @ 4: AB @) 2:1 (@) A.B+A.B @) 1:4 ne @) 1:2 eee CHLAAIGG/Page 12 ‘SPACE FOR ROUGH WORK110. A carbon resistor of (47 + 4-7) kO is to be marked |113. ‘The efficiency of an ideal heat engine working ith Laing bed aURiRe SNe ibe ite between the freezing point and boiling point of identification. The colour code sequence will be ae ei () Yellow ~ Green ~ Violet ~ Gold ais nae (2) Green ~ Orange ~ Violet ~ Gold (3). 20% (8) Yellow ~ Violet - Orange ~ Silver (4) 268% (4) Violet Yellow - Orange ~ Silver 114. The volume (V) of a monatomic gas varies with < di its temperature (1), as shown in the graph. The 111. A set of ‘n’ equal resistors, of value ‘R’ each, are ratio of work done by the gas, to the heat connected in series to a battery of emf ‘E’ and absorbed by it, when it undergoes a change from internal resistance ‘R’. The current drawn is I. state A to state B, is Now, the ‘n’ resistors are connected in parallel to y the same battery. Then the current drawn from t \o" battery becomes 10 I. The value of ‘nis i AC @ 2 i @ 9 é @ u : oe Dag (@) 10 leg 112. A battery consists of a variable number ‘n’ of| (2) 2 ‘identical cells having internal resistance ‘r i each) which are connected in series. ‘The @ 2 terminals of the battery are short-circuited and 2 the current I is measured. Which of the graphs w 2 shows the correct relationship between I and n? : I 115. The fundamental frequency in an open organ ' pipe is equal to the third harmonic of a closed a organ pipe. If the length of the closed organ pipe Oss is 20 em, the length of the open organ pipe is, (1) 125¢em @) 16cm i @) bm ® (4) 1320m Oo =n 116. At what temperature will the rms speed of oxygen molecules become just sufficient for : escaping from the Earth's atmosphere ? 4 (Given : @) ‘Mass of oxygen molecule (m) = 2-76 x 107° kg Oo +H Boltzmann's constant kp = 1:38 x 109 J K™) i a) 5016 «10K ea @) 1254x108K wt t c eee (3) 8:360x 104K oon 2508 x 10°K CHLANIGG/Page 13 ‘SPACE FOR ROUGH WORK Englishuz. 118. 119. 120. ‘CHLAAIGGIPage 14 ‘The power radiated by a black body is P and it radiates maximum energy at wavelength, Mo. If the temperature of the black body is now changed so that it radiates maximum energy at wavelength Pho the power radiated by it becomes nP. The value of nis 256 1» 288 o ® al 2) 356 @ 4 3 3 w 3 ‘Two wires are made of the same material and have the same volume. The first wire has cross-sectional area A and the second wire has cross-sectional area 3A. If the length of the first wire is increased by Al on applying a force F, how much force is needed to stretch the second wire by the same amount ? a) 4F @ F @) 6F () 9F ‘A small sphere of radius ‘r falls from rest in a ‘viscous liquid. As a result, heat is produced due to viscous force. The rate of production of heat when the sphere attains its terminal velocity, is proportional to @ # @ © @ 2 @) ¢ A sample of 0-1 g of water at 100°C and normal pressure (1-013 x 10° Nm™) requires 54 cal of| heat energy to convert to steam at 100°C. If the! volume of the steam produced is 167-1 ec, the change in internal energy of the sample, is (MD 422d (2) 845d (3) 20875 (4) 10433 121, ‘The kinetic energies of a planet in an elliptics orbit about the Sun, at positions A, B and C an Ky, Kp and Ko, respectively. AC is the majo axis and SB is perpendicular to AC at th position of the Sun S as shown in the figurt ‘Then B Al ie Q) KgKy>Ke (3) Ky>Kg>Ke () KyW,> Wo figure. The wedge is given an acceleration ‘a’ towards the right. The relation between a and @ Ow S Woe Wa for the block to remain stationary on the wedge (3) Wa>Wp>We is " () We>Wa>Wa 127. A moving block having mass m, collides with another stationary block having mass 4m. The lighter block comes to rest after collision. When the initial velocity of the lighter block is v, then ib acneea the value of coefficient of restitution () will be Ghssease a) 08 7 @) 04 @ a= 8 (3) 025 4) 05 @ a-—8— 128, Which one of the following statements is/132, A student measured the diameter of a small steel! incorrect ? ball using serew gauge of least count (1) Frictional force opposes the relative motion. oe Mt cn aie ae each (2) Coefficient of sliding friction has 26 divisions above the reference level. If screw dimensions of length gauge has a zero error of ~ 0-004 cm, the correct (3) Limiting value of static friction is directly fn eee proportional to normal reaction. a oes (4) Rolling friction is smaller than sliding] (3) 0525 em friction. (4) 0521 em CHLAAIGGIPage 16 ‘SPACE FOR ROUGH WORK English183. Unpolarised light is incident from air on a plane |186. In which case is the number of molecules of water ‘maximum ? i seesiuice tt) AA surface of a material of refractive index ‘y’. At a cy Ones eee vite particular angle of incidence , it is found that Pea the reflected and refracted rays are| (19°? mol of water perpendicular to each other. Which of the| (3) 1g g of water following options is correct for this situation ? isa @ 2) 197. Consider ‘the change in oxidation state of Mi Bromine corresponding to different emf values & 4(4) shown in the diagram below : a) — 182V, 2 15Y, BrO; ———> BrO; ——> HBrO (8) Reflected light is polarised with its electric vector perpendicular to the plane of Br say Be GEEy oom ‘Then the species undergoing disproportionation (4) Reflected light is polarised with its electric] is vector parallel to the plane of incidence @ Br (@) HBO 134. In Young's double slit experiment the separation a s' “7 pa (3) BrOy 4 between the slits is 2 mm, the wavelength 2 of| the light used is 5896 A and distance D between the screen and slits is 100 em. It is found that the|198. Among CaH, BeH, BaH, the order of ionie (4) Bros angular width of the fringes is 0-20°. To increase character is the fringe angular width to 0-21° (with same () Bel, cor the electrophile involved is 2 (1) dichloromethyl anion (CHCI,) (2) dichlorocarbene (:CCly) e (3) formyl cation (CHO ) @ (4) dichloromethyl cation (CHC12) Carboxylic acids have higher boiling points than aldehydes, ketones and even alcohols of| comparable molecular mass. It is due to their (1) more extensive association of carboxylic! acid via van der Waals force of attraction (2) formation of intermolecular H-bonding (3) formation of carboxylate ion (4) formation of intramolecular H-bonding Compound A, OgHy 0, is found to react with NaOI (produced by reacting Y with NaOH) and. yields a yellow precipitate with characteristic smell. A and Y are respectively Qe on-ery ana OH CHy 2) CHy 4S OH andy @ ()- cH, - cH, - 0H and 1, Ho -€_)~ cH, - Of and, 154, 155. 156. Which of the following molecules represents the order of hybridisation sp®, sp”, sp, sp from left to right atoms ? () CH, = CH-CH = CH, (2) CH,-CH=CH- CH, (3) CH,=CH-C=CH (4) HC=C-C=cH Which of the following carbocations is expected to be most stable? NO, Ns NO. NO, i o yd H @ Pa NO, @ le See Which of the following is correct with respect to = effect of the substituents ? (R = alkyl) () -NH,>-OR>-F (2) -NR,>-OR>-F (3) -NR,<-OR<-F (@) -NH,<-OR<-F CHLANGGIPage 18 ‘SPACE FOR ROUGH WORK English157. 158. 159. 160. 161. Regarding cross-linked or network polymers, which of the following statements is incorrect ? (2) Examples are bakelite and melamine. (2) They contain strong covalent bonds in their polymer chains. ‘They are formed from bi- and tri-functional ‘monomers. They contain covalent bonds between various linear polymer chains. ‘Nitration of aniline in strong acidic medium also gives m-nitroaniline because (2) Im absence of substituents nitro group always goes to m-position, In acidic (strong) medium aniline is present as anilinium ion. In electrophilic substitution amino group is meta directive. In spite of substituents nitro group always g0es to only m-position. @) « @) 3) reactions w ‘The difference between amylose and amylopectin () Amylopectin have 1 > 4 a-linkage and 1 6 frlinkage Amylose is made up of glucose and galactose Amylose have 146 Blinkage Amylopectin have 14 o-linkage and 16 celinkage A mixture of 2:3 g formic acid and 4°5 g oxalic acid is treated with conc. HySO,. The evolved gaseous mixture is passed through KOH pellets. Weight (in g) of the remaining product at STP will be @ 28 @) 44 @) 30 (@) 14 Which of the following oxides is most acidic in nature ? @ @ 14 linkage and @ 162. 163. 164. 165. 166. For the redox reaction MnO; +C02- + H*'—+ Mn”* + CO, + H,0 the correct coefficients of the reactants for the balanced equation are MnO; C,0;- H’ @ 2 1a @ 5 ies @ 2 5.16 @ 1 5 8 Which one of the following conditions will favour maximum formation of the product in the reaction, Ag(g) + By (g) = Xp(g) AH =-XI? High temperature and high pressure High temperature and low pressure Low temperature and low pressure Low temperature and high pressure @ @) @ @) When initial concentration of the reactant is doubled, the half-life period of a zero order reaction @) istripled (2) remains unchanged (8) is doubled (4) ishalved ‘The bond dissociation energies of Xj, Yy and XY are in the ratio of 1: 0'5 : 1. AH for the formation of XY is —200 kJ mol”, The bond dissociation energy of X, will be (2) 800k mot (2) 400 kJ mol (3) 100kJ mol* (4) 200k mor ‘The correction factor ‘a’ to the ideal gas equation corresponds to (2) electric field present between the gas molecules @ Bao (2) forces of attraction between the gas (2) Cao molecules (3) Beo (3) volume of the gas molecules (4) _Mgo (4) density of the gas molecules CHLAAIGG/Page 19 ‘SPACE FOR ROUGH WORK EnglishA 167. 168. 169. 170. Following solutions were prepared by mixing different volumes of NaOH and HCI of different concentrations : M M a 60mt Mc + 40mL Neon M M b.s5mt, MHL ¢ 45 mL, FF NaOH cmt M HCL 25 mL NaoH 4 100mt ™ ycr+100 mL M Nao 10 10 pH of which one of them will be equal to 1? @ a @ ec @) a @ b ‘On which of the following properties does the coagulating power of an ion depend ? (1) Both magnitude and sign of the charge on the ion (2) The sign of charge on the ion alone (8) Size of the ion alone (4) ‘The magnitude of the charge on the ion alone Given van der Waals constant for NHs, Hz, Op and CO, are respectively 4-17, 0-244, 1:96 and 3:59, which one of the following gases is most, ‘easily liquefied ? 0, 2) Cg @) Hy (4) NH ‘The solubility of BaSO, in water is 2-42x10 gL at 298K. The value of its solubility product (K,,) will be (Given molar mass of BaSO, = 233 g mol) (2) 1-08 107% mol” L* (2) 10810" mol? L: (3) 1.08 107? mol? LE? (4) 08x 107? mol” L 171. Identify the major products P, Q and R in the following sequence of reactions : Miydecas AlCly a + CH,CH,CH,CI () 02 GH,O7A Q+R P Q R CH(CH3) @ oe CHyCH(ORDCH, OH CH(CH,) @ oO = , CH - CO -CHy CH,CH,CH,; CHO eee CH,CH,CH, CHO fe , CHsCH, - OH 172. Which of the following compounds can form a awitterion ? (1) Benzoie acid (2) Glycine (3) Acetanilide (4) Aniline CHLAA/GG/Page 20 SPACE FOR ROUGH WORK English173. 174. 175. 176. The compound C;Hg undergoes the following reactions 3OR/A , Bro/Fe | Zn/ HCl OH eee ee ee HO ‘The product ‘Cis (1) B-bromo-2,4,6-trichlorotoluene (2) p-bromotoluene (3) o-bromotoluene (4) m-bromotoluene Which oxide of nitrogen is not a common pollutant introduced into the atmosphere both due to natural and human activity ? @ No (2) NO (3) NO, (4) NyO5 The compound A on treatment with Na gives B, and with PCls gives C. B and C react together to give diethyl ether. A, Band C are in the order (1) CgH,Cl, CH, CHjOH (C3HsOH, C3H,ONa, CoH,Cl CyH,OH, CyH,Cl, CpH,0Na CyHOH, CpHg, CHCl @) @) @) Hydrocarbon (A) reacts with bromine by substitution to form an alkyl bromide which by Wartz converted to gaseous hydrocarbon containing less than four carbon ‘atoms. (A) is reaction is (1) CH3-CHy (2) CH, (3) CH, =CH, (4) CH=CH 177. 178. 179. Consider the following species : CN’, CN”, NO and CN Which one of these will have the highest bond order? (CNT @ oN (@) CNT () NO ‘Magnesium reacts with an element (X) to form an ionic compound. If the ground state electronic configuration of (X) is 1s” 2s” 2p, the simplest formula for this compound is @) Mgx (2) MgsX, (3) MgX, (4) MaxX, Tron exhibits bee structure at room temperature. Above 900°C, it transforms to fec structure. The ratio of density of iron at room temperature to that at 900°C (assuming molar mass and atomic radii of iron remains constant with temperature) is v3 » i Set aa @ (3) “ lin g/ I Which one is a wrong statement ? (1) The electronic configuration of N atom is 1 agt 292 2p 2p tH ty Ltithy ‘The value of m for d,2 is zero. ® (3) An orbital is designated by three quantum numbers while an electron in an atom is designated by four quantum numbers. ‘Total orbital angular momentum of electron in‘s orbital is equal to zero. “ CHLAAIGG/Page 21 ‘SPACE FOR ROUGH WORK EnglishRead carefully the following instructions : 1. Each candidate must show on demand his/her Admit Card to the Invigilator. 2. No candidate, without special permission of the Superintendent or Invigilator, would leave his/her seat. 3. The candidates should not leave the Examination Hall without handing over their Answer Sheet to the Invigilator on duty and sign the Attendance Sheet twice. Cases where a candidate has not signed the Attendance Sheet second time will be deemed not to have handed over the Answer Sheet and dealt with as an unfair means case. 4. Use of Electronic/Manual Caleulator is prohibited. 5. The candidates are governed by all Rules and Regulations of the examination with regard to their conduct in the Examination Hall. All cases of unfair means will be dealt with as per Rules and Regulations of this examination. 6. No part of the Test Booklet and Answer Sheet shall be detached under any cireumstances, 7. The candidates will write the Correct Test Booklet Code as given in the Test Booklet/Answer Sheet in the Attendance Sheet. CHLAA/GG/Page 24 English