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Simulation Notes
Simulation Notes
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Simulations are also performed to detect
abnormal conditions like
• Formation of hydrates due to fall in Pressure & Temperature.
• Fall in temperature below Hydrocarbon or Water- Dew Point.
• Flashing of liquids across Control Valves or Drain Valves, etc.
• Condensation Of Vapors due to cooling.
• Latent heat data required at relieving conditions (Temperature And
Pressure) for Safety Valve Sizing calculations.
• Time behavior of inventory streams during Depressurization.
• Minimum temperatures during Venting from High Pressure To
Atmosphere, which may affect material selection upstream or
downstream of vent valve (inclusive).
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DYNAMIC SIMULATION
• It is an extension of steady-state process simulation
whereby time dependence is built into the model.
• It requires increased calculation time and is
mathematically more complex than a steady state
simulation.
• For process design, it is used for operator training and
optimum process control.
• It is used to study the response of the process to
sudden changes in operating conditions.
• In dynamic process design simulators, the key
operating conditions are maintained using simple PID
(Proportional, Integral and Derivative) controllers.
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Major Steps Involved In Development
Of Steady State Process Simulation
Use of this simulation software for chemical
processing involves the following steps:
• Selection of components
• Selection of a thermodynamic properties package
• Construction of a flow sheet
• Specification of known stream and unit
compositions and conditions
• Running the simulation program
• Interpretation of the results
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In many cases, simulation results DO NOT
reflect what is really happening in a plant
Why
• Improperly selected thermodynamic models
• Inadequate model parameters
• Incorrect hypothetical components generation
• Problems with plant data consistency
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Recommended Property Methods
Type Of System Aspen Recommended Property Method
TEG Dehydration PR
Sour Water PR, Sour PR
Cryogenic Gas Processing PR, PRSV
Air Separation PR, PRSV
Atm Crude Tower PR, PR Options, GS
Vacuum Tower PR, PR Options, GS (<10 mm Hg), Braun K10, Esso K
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Some Commonly Used Property
Methods
• Peng-Robinson (PR) model is ideal for VLE calculations
as well as calculating liquid densities for hydrocarbon
systems.
• PR property package rigorously solves any single-, two-,
or three-phase system with a high degree of efficiency
and reliability and is applicable over a wide range of
conditions:
Temperature Range > -271°C or -456°F
Pressure Range < 100,000 kPa or 15,000 psia
For Oil, Gas, or Petrochemical applications, the PR EOS is
the generally recommended property package.
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Some Commonly Used Property
Methods
• SRK (Soave-Redlich-Kwong ) model provides
comparable results to PR, but its range of
application is significantly more limited:
Temperature Range > -143°C or -225°F
Pressure Range < 5,000 psia or 35,000 kPa
• SRK EOS should not be used for non-ideal
chemicals such as alcohols, acids or other
components. These chemicals are more
accurately handled by the Activity Models (highly
non-ideal) or the PRSV EOS (moderately non-
ideal)
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Some Commonly Used Property
Methods
• Chao Seader method is useful for heavy
hydrocarbons, where the pressure is less than
10342 kPa (1500 psia), and temperatures
range between -17.78 and 260°C (0-500°F).
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Some Commonly Used Property
Methods
• Glycol Property Package applicable over the
range of temperatures, pressures, and
component concentration encountered in a
typical TEG-water dehydration system:
between 15°C to 50°C and between 10 atm to
100 atm for the gas dehydrator, and between
202°C to 206°C and 1.2 atmospheres for the
glycol regenerator.
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