Nama : Alma Tyara Simbara

NIM : 1705233

Kelas : Kimia C 2017

TUGAS 2

KIMIA KOORDINASI

2.33 The nitride ion,N3-, can be a monodentate or a bridging ligand. Name the following
compound :

Jawab : ammonium tetrabromo-tantalum (IV)-µ-nitrogentetrabromo-tantalum(IV)

2.34 Write formulas for the following compound :

a. Pentaammine(dinitrogen)ruthenium(II) chloride

b. Aquabis(ethylenediamine)thiocyanatocobalt(III) nitrate

c. Sodium hexsaisocyanochromate(III)

Jawab :

a. [Ru(NH3)5(N2)2]Cl2
b. [Co(H2O)(en)2(SCN)](NO3)2
c. Na4[Cr(CN)6]

2.35 Write formulas for the following compound :

a. Bis(methylamine)silver(I) acetate

b. Barium dibromodioxalatocobaltate(III)

c. Carbonytris(triphenylphosphine)nickel(0)

Jawab :

a. [Ag(NH2CH3)2]CH3COO
b. Ba3[CoBr2(C2O4)2]2
 c. [Pd(NH3)2(Pph3)2[Au(C2O4)2]2

2.36 Write formulas for the following compound :

a. Tetrakis(pyridine)bis(triphenylarsine)cobalt(III) chloride

b. Ammonium dicarbonylnitrosylcobaltate(-1)

c. potassium octacyanomolybdenate(V)

d. diammienedichloroplatinum(II) (Peyrone’s salt)

Jawab :

a. [Co(py)4(C18H15As)2]Cl3

b. NH4[Co(CO)2NO]

c. K4[Mo(CN)8]

d. [Pt(NH3)2Cl2]

2.37 Write formulas for the following compound :

a. Hexaamminecobalt(III) pentachlorocuprate(II)

b. Tetrakis(pyridine)platinum(II) tetrachloroplatinate(II)

c. diamminebis(triphenylphosphine)palladium(II) bis(oxalato)aurate(III)

Jawab :

a. [Co(NH3)6][CuCl5]
b. [Pt(C5H5N)4][PtCl4)]
c. [Pd(NH3)2(Pph3)2] [Au(C2O4)2]2

2.38 Write formulas for the following compound :

a.(Ethylenediamine)iodonitritochromium(III)-µ-dihydroxotriamminechloro-
cobalt(III) sulfate

b.Bis(ethylenediamine)cobalt(III)-µ-isocyano-µ
thiocyanatobis(acetylacetonato)chromium(III) nitrate

Jawab :
 a.

b.

2.39 Write formulas for the following compound :

a. pentaamminechromium(III)-µ-hydroxopentaamminechromium(III) chloride

b. diammine(ethylenediamine)chromium(III)-µ-bis(dioxygen)tetraamminecobalt(III)

bromide

jawab :

a.

b.

H
O

[(NH3)5Cr Cr(NH3)5]Cl5

2.40 Write formulas for the following compound :

a. dichlorobis(pyridine)tungsten(III)-µ-dichlorodichlorobis(pyridine)tungsten(III)

b.ammoniumdichloroiodotungsten(III)-µ-bromo-µ-chloro-µ
iododichloroiodotungstate(III)

Jawab:

a.

Cl
[Cl2(py)2W W(py)2Cl2]
Cl
 b.

Br
NH4[Cl2(I)W Cl W(I)Cl2]
I

3.1 Two compounds have the formula C2H6O. One, known as common grain alcohol or
ethanol, is composed of the ethyl (C2H5-) radical bound to the hydroxyl (-OH) group,
whereas the second, dimethyl ether, an extremely volatile organic solvent not suitable for
human ingestion, has two methyl (CH3-) groups bound to a central oxygen atom. Classify
these compounds: Are they (a) isomers, (b) structural isomers, and/or (c) stereoisomers?
More than one of these terms may apply.

Jawab :

Etanol dimetil eter

Etanol dan dimetileter merupakan suatu isomer karena mempunyai jumlah dan jenis atom
yang sama namun sifatnya berbeda. Etanol dan dimetil ini merupakan suatu isomer
struktur karena mempunyai nomor dan jenis ikatan kimia yang berbeda(jenis dan jumlah
atom sama namun strukturnya berbeda)

3.15 Draw structural formulas for the following compounds:

a. Cis-carbonylchlorobis(triphenylphosphine)iridium(I)
b. Trans-choloronitrotetraamminechromium(III) nitrate
c. Trans-diammine-trans-dinitrobis(pyridine)cobalt(III) nitrate

3.16 How many additional internal mirror planes are there in the first four parts of Figure 3.7?
Draw diagrams that illustrate these additional planes.

3.17 Draw structural formulas for the following compounds:

a. Potassium trans-dichlorobis(oxalato)cobaltate(III)
b. (Acetylacetonato)-cis-dicholoro-trans-bis(triphenylarsine)rhenium(III)