Sol Aits Jeea FT Iv Paper 2 PDF

1 AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
From Long Term Classroom Programs and Medium / Short Classroom Program 4 in Top 10, 10 in Top 20, 43 in Top
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FULL TEST –IV

(Paper-2)
Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. C C A
ALL INDIA TEST SERIES
2. A B C
3. D B A
4. B C C
5. A D C
6. C C B
7. A A B
8. A C D
9. D C C
10. C A B
11. A C B
12. C B B
13. A B D
14. B D B
15. A, B, C A,C A, B
16. A, B, C A,C A, B, C, D
17. A, D B,D A, B, C
18. A, B, D B,D C, D
19. A, C, D A, B, D A, C
20. C, D B, C, D A, C
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AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13
2
Physics PART – I
SECTION – A
1. A is at rest instantaneously (for no slipping at A)

1 V 
V B – V A = B  0  (2R) 2
2 R 
1 V 
VC – VA = B  0( 3 R) 2
2 R 
1 V  2 BV0R
⇒ VB – VC = B  0  [R ] =
2 R  2
2. force = (P – P0) A = Ma
by P1V1 = P2V2
P0hA = P(h – x) A
P0h
⇒P=
h–x
 Ph  A
So force =  0 – P0  =a
 h – x  M
P0 Ax P Ax
a= ⇒ 0 ; (for small x)
M(h – x) Mh
Mh
T = 2π
P0 A
L
3. τrestoring = (mg sinθ L + (mg sin θ
2
 L  L  KL L
+  K sin θ  +  sin θ 
 4 4  2 2
 3mg 5KL  2
restoring =  2 + 16  θ (θ : small)
 
3mg 5kL2
+
1 2 16
frequency of oscillation) =
2π Ι
mL2 4mL2
where Ι = mL2 + =
3 3
4. From law of radioactive decay.

Activity µ Number of nuclear of that nucleus present in the sample.
Activity does not depend upon the rate of the formation of nucleus.
In given reaction B decays into E and C.
Total activity of B = rate of decay of B into E + rate of decay of B into C = l5N2 + l3N2
5. The EMF will be induced in the loop, only when there is a change in the flux through the loop.
When the loop was completely inside the field region, for some time (say t1) there is no change in
the flux, hence that time would not be included in the calculation.
b b 2b
The time for which EMF was induced = + =
v v v
6. That wire will break first whose stress reaches the breaking stress (for that
material) first.
F F
Stress = = where F is the tension in the wire. F is same in both the wires.
A πr 2
1
Thus stress ∝ 2 for the wire of smaller radius, the stress is more.
r
Thus the wire with smaller radius will break first.
If rA < rB, then wire A will break first.
If rA > rB, then wire B will break first.
If rA = rB, either of them could break.
8. As the magnetic field is uniform and the particle is projected in a direction perpendicular to the
field, it will describe a circular path. The particle will not hit the yz-plane if the radius of the circle is
mv
smaller than d. For the maximum value of v, the radius is just equal to d. Thus = d.
Bq
Bqd
∴ v=
m
u − u0
9. F = ηA
y
F
⇒ u = y + u0
ηA
1
⇒ u = −2 y + 1 = 100 y + 1
10 × 1
10. The velocity of upper plate is same as that of the layer in contact with the plate i.e. layer at y = 2
cm.
u = 100 (0.02) + 1 = 3 m/s
11. T2 ∝ r3 (Kepler's law)
4
TA2 rA3 r3 1 T 1
= = 3
= Get A =
TB2 rB3 (4r) 64 TB 8
12. For geostationary satellite, time period = 1 planet day (by def.)
Let T = 1 planet day
T0 = 1 planet year
4 π2 3 4 π2 3  m 
Now T2 = rG = r
Gm Gm  M 
4 π2 3
= r = T03 or T = T0
GM
k k 2500
13-14. ω = , ω′ = = = 10 rad/sec
M M+m 25
M
ω′ = ω
M+m
x1 = A sin φ1
1 2 1
Potential energy stored in the spring at (t = t1) = kx1 = Mω2 sin2 φ1
2 2
Let v and v′ be the velocity of system just before collision and just after collision, so using COLM
Mv MAω cos θ
v′ = =
(M + m ) (M + m )
1 2 1(
kx1 + M + m ) v ′2
Total energy after collision = PE + KE =
2 2
1  M + msin θ 
2
1 2  M + m sin θ 
2
= MA 2 ω2   = kA   =8J
2  M+m  2  M+m 
1( 1  M + m sin2 θ 
M + m ) A ′2 ω′2 = MA 2 ω2  
2 2  M+m 
Imax (a1 + a2 )2
15. =
Imin (a1 − a2 )2
a1 I 4 2
= 1 = =
a2 I2 9 3
Imax
∴ = 25
Imin
If an identical paper is pasted across second slit shifted C.B.F. will back in central point.
tD
shift = ( µ − 1)
d
nλ D
fringe width =
d
shift (µ − 1)t
∴ n= = = 15 .
fringe width λ
16. The change in magnetic flux is zero, hence the current in the ring will be zero.
17. Both (A) and (D) depend on g.
n(n − 1) n=4
18. =6 ⇒ n=4
2 3
If the initial state were n = 3, in the emission spectrum, no wavelengths 2
shorter than λ0 would have occurred. This is possible if initial state were n = 2
∴ (A), (B) and (D)
1
19. From COE (A) is correct.

The force outside the earth varies as inverse square of the distance.
∴ motion is not simple harmonic. However, from symmetry of motion, the motion will be
periodic.
∴ (C) is correct.
From COE
1 GMm  3GMm 
mv 2 = − − −
2 2R  2R 
2GM
⇒ v=
R
∴ (A), (C) and (D) are correct.
20. The current through R1 is constant.
6
Chemistry PART – II
SECTION – A
pKa1 + pKa2 4 + 9
1. pH at isoelectric point = = = 6.5
2 2
2. Net reaction does not involve any aqueous species.
2+
5. Cr ( SCN)2 (NH3 )4  , shows geometrical (or cis-trans) and linkage isomerism.
6. O O O O
(i) EtO−
H3C C CH2 C O CH2 CH3 
O→ H3C C CH C O CH2 CH3
(ii) H C H
CH2 OH
O O CH3
∆, −OH2
O O H3C C CH C O CH 2
H3C C CH C O CH2 CH3

O O
O CH2 O
←
(Michael)
 H3C C C C O CH2 CH3
H3C C CH C O CH2 CH3
CH2
EtO−
O O
OH CH3
C O CH2 CH3 C O Et
+
Li / ∆
 →
O + H2O + CO2 + Et − OH
O
C O CH2 CH3
O
∆
7. FeSO4  → Fe2O3 + SO3 + SO2
8. Energy of e− in H-atom = - E
Energy of e− in Li+2 = - 9E
1
Energy supplied by photon = IE + mv 2
2
IE = E
1
∴ Ep = 9E + mv 2
2
2 (Ep − 9E )
v=
m
9. In reverse osmosis water moves from more concentrated to less concentrated solution
10. π = iCRT, (i=2)
11. Let conc. of both reactants at equilibrium is x M

2
PbEDTA 2 −  H+ 
Keq =  2
  
x
x = 10−3
12. Chelation increases stability of complexes
14. OH
+
aq.K 2 CO3
P + Q  → R 
HCN
→ S 
H /H2 O
heat
→
O
O
OH
OH OH
← 
+
−H2 O ←
H /H2 O

O heat
CN
O OH
O OH HO
(S)
HCN
O
O
O
+ aq. K 2 CO3
→ H
H H H OH
(P ) (Q) (R )
15.
Cl
→ Cl → Cl
KCN H Pt
 
2
Cl CN NH2
CF CO H HIO4 H O+
16. Trans-2-butene 
3 3
→ epoxide →
3
diol  → 2CH3CHO
17. He and H2 are not hydrogen like particles
18. Radius of cation is smaller than parent atom and that of anion is more than parent atom
19. (A) O
O
C
H 2C O
CH O →
I
CH2 I
I2 will attack the double bond to form a cyclic halonium ion. It then undergoes on intramolecular
reaction. Formation of five membered ring is favoured because (i) attack by a nucleophile on a
halonium ion normally takes place at the more substituted site.
(ii) Formation of five membered ring is more probable.
8
(B) O
O
+ C
Br O
O 
→
H3C
Br CH2
O
(C)
C
O
Option(C)gives
C
O
(D)
Option(D)gives C O
1, 4 and 1,5-dicarboxylic acids give anhydrides whereas 1,6 and 1, 7-diacids give ketones when
heated with P2O5.
Mathematics PART – III

SECTION – A
1. Normal to y2 = 4ax with slope m is

y = mx – 2am − am3 ..... (1)
(1) touches x2 − y2 = a2 if
(−2am − am3)2 = a2 (m2 − 1)
i. e. if m6 + 4m4 + 3m2 + 1 = 0 ..... (2)
(2) is a sixth degree equation in m with no odd power terms and whose coefficients are all
positive.
⇒ (2) has no real root
∴ |S| = 0
2. Given x + y + z = 5 → (1)
and x2 + y2 + z2 = 9 → (2)
1
(
We have yz = ( y + z ) − y 2 + z2 
2
2
 )
1
( )
= ( 5 − x ) − 9 − x 2  (using) (1) & (2))
2
2

= x2 − 5x + 8
⇒ y, z must be the roots of the equation
( )
u2 − ( 5 − x ) u + x 2 − 5x + 8 = 0 → ( 3 )
As y, z are real, we must have discriminant of (3) ≥ 0
⇒ (5 − x)2 – 4 (x2 – 5x + 8) ≥ 0
⇒ 3x2 – 10x + 7 ≤ 0
⇒ (3x – 7) (x – 1) ≤ 0
 7
⇒ x ∈ 1, 
 3
⇒ Number of integer values that x can take is 2
3. 2 sin2x + sin2 2x = 2
⇒ −2(1 − sin2 x) + 4 sin2 x cos2 x = 0
⇒ cos2 x.cos 2x = 0 → (1)
sin 2x + cos 2x = tan x
⇒ 2 sin x cos2 x + cos 2x cos x = sin x
⇒ sin x cos 2x + cos 2x cos x = 0
⇒ cos 2x (sin x + cos x) = 0 → (2)
Common roots of (1) and (2) are given by cos 2x = 0
( 2n − 1) π
⇒ x= ,n ∈ N
4
nπ
In [0, 4π] we have x = , where n = 1, 3, 5,……,15 → (3)
4
Now, − 2 sin2 x + sin x ≤ 0
⇒ 2 sin2 x − sin x ≥ 0
⇒ (sin x) (2 sin x − 1) ≥ 0
1
⇒ sin x ∈[−1, 0] or ≤ sin x ≤ 1 → (4)
2
5π 7π 13π 15π
Among the 8 values given by (3), only 4 values, i.e., x = , , , satisfy (4)
4 4 4 4
10
1
4. We have w = z +
z
Take z = eiθ (∵ |z| = 1).
We have w = eiθ + e−iθ = 2cos θ
We know that w is real and | w | ≤ 2
x2 − 1 (
2 x2 − 1 ) (
−3 x 2 − 1 )
2 2 2
5. The scalar triple product of the three given vectors is 2x − 1 2x + 1 x
3x 2 + 2 x2 + 4 x2 + 1
1 2 −3 1 2 0
( 2
)
= x − 1 2x − 1 2x + 1 2 2
x 2
( 2
= x − 1 2x − 1 2x + 1 ) 2 2
5x 2 (using C3 → C3 + C2 + C1)
2 2 2 2 2 2
3x + 2 x +4 x +1 3x + 2 x +4 5x + 7
1 0 0
( )
= x 2 − 1 2x 2 − 1 −2x 2 + 3 5x 2 (using C2 → C2 − 2C1)
2 2 2
3x + 2 −5x 5x + 7
( )(
= x 2 − 1 15x 4 + x 2 + 21 )
Vector are non–coplanar ⇒ Scalar triple product ≠ 0 ⇒ x2 – 1 ≠ 0 (∵ 15x4 + x2 + 21 ≠ 0) ⇒x ≠ ± 1
( )
1/ n
6. We have f ( x ) = a − xn so that
1/ n
 n 
( ) ( ) ( ( ))
1/ n
  
1/ n 1/ n 
f° f ( x ) = f  a − xn  =  a −  a − x
n
  = a − a − xn
    
 
⇒ g ( x ) = f° f° .....f ( x ) = x
2m times
dx dx dx dt
∴ ∫ = ∫x = ∫x =− ∫ nt (using t = 1 + x−n)
(1+ (g ( x )) ) (1 + x ) (1 + x )
1/ n 1/ n
n 1/ n 1/ n
(g ( x ))
n n n n +1 −n
 
1
1  t −1/ n+1  1
( )
1−
=−  +c = 1 + x −n n +c
n 1 1− n
 − + 1 
 n 
7. Given y = f ( x ) ,z = g ( x ) we have
dy dy / dx f ′ ( x ) d2 y d  f ′  dx g′f ′′ − f ′g′′ 1
= = and =  ′ = .
dz dz / dx g′ ( x ) dz 2 dx g
  dz ( g′)2 g′
8. f ( x ) is continuous at x = 3
( )
⇒ f 3− = f ( 3 ) = f 3+ ( )
a | x2 − x − 6 | (
−a x 2 − x − 6 )=a
Now f 3 ( )=
−
lim−
x →3 6+x−x 2
= lim−
x →3 6+x−x 2
x − [x] x−3
( )
f 3 + = lim+
x →3 x−3
= lim+
x →3 x − 3
=1
 x 
 x 
∫
 x tdt   0 
 x 2 + tdt 
  ∫
f ( 3 ) = b lim  3   form  = b lim 
3
 = 9b
x →3
 x − 3   0  x →3  1 
   
 
 
1
⇒ a = 9b = 1 ⇒ b = and a = 1
9
n n
9. Vn = ∑r =1
Sr = 2 ∑ r = n (n + 1)
r =1
Vn n +1
∴ lim 2
= lim =1
n→∞ n n→∞ n
10. (i) Vn = n (n + 1) ⇒ V1 < V2 < V3 < .....

⇒ Statement − 2 is true
n n n
∑  r − r + 1 = 4 1 − n + 1

1 1 1 1 1 1 1 1
(ii) Qn = ∑ S S
r =1 r r +1
=
4 ∑
r =1 (
r r + 1)
=
4 r =1
⇒ Q1 < Q2 < Q3 < ……….
⇒ Statement −1 is false
11. We have
 2a− x , x<0
f (x) = 
−x x
a + a , x ≥ 0
Clearly, f(x) is continuous in R.
 a2x − 1 
For x > 0, f ′ ( x ) = −a− x loge a + a x loge a = ( a x – a −x) loge a =  log a
 a x  e > 0 for x > 0
 
⇒ f ( x ) is monotonic increasing for x > 0
For x < 0, f ( x ) = 2a− x ⇒ f ′ ( x ) = −2a− x loge a < 0
⇒ f ( x ) is monotonic decreasing for x < 0
0 1 0 1
 −2a   −a + a 
−x −x x
∫ 2a ∫ (a )
−x −x x
12. Required area = dx + +a dx =   + 
−1 0  loge a  −1  loge a 0
2
1 1   −1   3a − 2a − 1
=  −2 − ( −2a )  + + a  − 0 =
loge a  loge a  a   aloge a
1 1 2 2
15. The equation of the line is b 3 y + a 3 x + a 3 b 3 = 0
1 1
2 1 2 1
a3 −a 3
This can be written as y = − 1
x − a3 b3 ⇒ m= 1
, c = −a 3 b 3
b3 b3
Consider the parabola y2 = 4ax
12
1
3 2 1
a a ab
= 1
=− 1
= −a 3 b 3 = c
m
−a 3 a3
1
b3
∴ Condition for tangency for the parabola y2 = 4ax is satisfied
∴ The given line touches y2 = 4ax
Similarly the line touches x2 = 4by
1
16. ( x + iy ) 5 = a + ib
∴ x + iy = ( a + ib)5 = a5 + 5a4 (ib) + 10a3 (− b2) + 10a2 (−ib3) + 5ab4 + ib5
Equating the real and imaginary parts x = a5 – 10a3b2 + 5ab4 ⇒ y = 5a4b – 10a2b3 + b5
x y 4 2 2 4 4 2 2 4 4 4 4 4
p = − = (a − 10a b + 5b ) − (5a – 10a b + b ) = −4a + 4b = −4 (a − b )
a b
= −4(a2 – b2) (a2 + b2) = −4(a + b)( a − b) ( a +ib) (a −ib)
∴ a − b, a + b, a + ib and a – ib are all factors of p.
π
17. Since 0 < θ < ,0 < sin2 θ, cos2 θ, tan2 θ < 1
4
∞
1
( A ) ∑ sin2k θ = = s ec 2 θ
k =0 1 − sin2 θ
∞
1
(B) ∑ cos
k =0
2k
θ=
1 − cos θ 2
= cosec 2 θ
∞
1 cos2 θ cos2 θ
(C) ∑
k =0
tan2k θ =
1 − tan2 θ
=
cos2 θ − sin2 θ
=
cos 2θ
∞
π
(D) cot θ > 1 in 0 < θ <
4
. Hence, ∑ cot
k =0
2k
θ does not exist.
19. 3y = 9 − 3x ⇒ 9 − 3x > 0 ⇒ x < 2

Similarly, y < 2
c.c 2 c 3
20. Area ( T ) = =
2 2
c
c3
Area (R ) =
2
− x 2 dx ∫
0
3 3 3
c c c
= − =
2 3 6
Area ( T ) c3 6
lim+ = lim+ . 3 = 3
c →0 Area (R ) R →0 2 c

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1 AITS-FT-IV-(Paper-2)-PCM(S)-JEE(Advanced)/13

FULL TEST –IV

Q. No. PHYSICS CHEMISTRY MATHEMATICS

1. A is at rest instantaneously (for no slipping at A)

4. From law of radioactive decay.

11. T2 ∝ r3 (Kepler's law)

17. Both (A) and (D) depend on g.

19. From COE (A) is correct.

20. The current through R1 is constant.

H3C C CH C O CH2 CH3

10. π = iCRT, (i=2)

11. Let conc. of both reactants at equilibrium is x M

12. Chelation increases stability of complexes

17. He and H2 are not hydrogen like particles

Mathematics PART – III

1. Normal to y2 = 4ax with slope m is

10. (i) Vn = n (n + 1) ⇒ V1 < V2 < V3 < .....

∑  r − r + 1 = 4 1 − n + 1

19. 3y = 9 − 3x ⇒ 9 − 3x > 0 ⇒ x < 2

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