HINTS & SOLUTIONS

Hints: (CHEMISTRY)

1. A
Given total mass of carbon = 1.2 × 10-9
9
1.2 10
No. of moles of carbon atom =
12
Total number of C-atoms = 1 × 10-10 × 6 × 1023
= 6 × 1013

2. A
3RT
Vrms =
M
Given that MA = 2MB
Vrms ( A)
and =2
Vrms (B)
2
TA Vrms (A)  MA
= 2
TB Vrms (B)  MB
TA
= 42 = 8
TB
PA TA P 8
= = 8 Hence A =
PB TB PB 1
PA : PB = 8 : 1

3. A
nRT 2  0.0821  100
V=  = 66litre (aprox)
P 0.25

4. D
Radial node will occur where (r) = 0
For (r) = 0 either 2 − 8 + 12 = 0 or ( − 1) = 0
if 2 − 8 + 12 = 0
 2 − 6 − 2 + 12 = 0
 ( − 6) − 2( − 6) = 0
 ( − 2)( − 6) = 0
  = 2,  = 6
When  = 2
2r
= 2  r = a0
a0
When  = 6
2r
= 6  r = 3a0
a0
Now when ( − 1) = 0   = 1
2r a0
=1 r=
a0 2
a0
Radial nodes are present at r = , a0 and 3a0
2

5. B
Since IE3 >> IE2, hence there must be 2 electrons in the outermost shell of the atom.

6. A
Geometry of XeO2F4 is octahedral. In octahedral geometry all the positions are identical.
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7.
H H
C C C
H H
Allene is non-polar and non-planar molecule. Therefore both the assertion and reason are the
correct statements, but reason is not correct explanation for the assertion.

h
8. =
2m q V
On making potential difference (V) four time de-Broglie wavelength will become half so assertion is
correct.
Kinetic energy of charged particle initially at rest, when accelerated through a potential difference V
volt is
q × V. So reason is correct.
Both assertion and reason are correct and reason is correct explanation

9. Both the assertion and reason are correct and reason is correct explanation of assertion.

10. B

CaCO3 ⎯⎯ → CaO + CO2

11. A
CaO + H2O ⎯⎯
→ Ca(OH)2

12. B
Ca(OH)2 + NH4Cl ⎯⎯
→ CaCl2 + NH3 (g) + H2O
NH3 + H2O + CO2 ⎯⎯
→NH4HCO3 NH4HCO3 + NaCl ⎯⎯
→NH4Cl + NaHCO3

2NaHCO3 ⎯⎯→Na2CO3 + CO2 + H2O

13. B
O3 2H 2e H2O O2
H2O2 O2 2H 2e

14. B
MnO4 8H 5e Mn2 4H2O

15. B
Na2O2 H2SO4 Na2SO4 H2O2

Matrix Match Type :

1. A-S, B-R, C-P, D-Q
2p2y
C2 : 1s2 , * 1s2 , 2s2 , * 2s2 ,
2p2z

2 * 2 2 * 2
2p2y 2
*
2p2y
NO : 1s , 1s , 2s , 2s , , 2p , x
2p2z *
2p2z
2p2y
N2 : 1s2 , * 1s2 , 2s2 , * 2s2 , , 2p2x ,
2p2z
2p2y
CN : 1s2 , * 1s2 , 2s2 , * 2s2 , , 2p2x
2p2z

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2p2y *
2p1y
O2 : 1s2 , * 1s2 , 2s2 , * 2s2 , 2p2x , ,
2p2z *
2p1z
2p1y
B2 : 1s2 , * 1s2 , 2s2 , * 2s2 ,
2p1z

2. A-QS, B-PRT, C-QRT, D-QS

HITS & SOLUTIONS (MATHS) :

1. (D)
The radical centre of the circles drawn on the sides of a triangle as diameters coincides with the ortho centre
of the triangle.

2. (A)

3. (D)
Equation of the normal to the parabola y2 = 4x is
y = -tx + 2t + t3
Therefore, condition for current lines will be
p 1 2p + p3
q 1 2q + q3 = 0
r 1 2r + r 3
 p+q+r=0 ( p  q  r)
 Common root between the given quadratic equation is 1

4. (C)

If Image of point A (2, 3) in the above variable line is B (h, k), then
AP = BP
 (h − 1)2 + (k − 2)2 = (2 − 1)2 + (3 − 2)2
 x2 + y2 − 2x − 4y + 3 = 0

5. (B)
The incentre of the triangle ABC is at O.
The image of A with respect to y = x, say A1 is (2, 1)
 −11 2 
The image of A with respect to y = -2x, say A2 is 
 5 5 
, .

A1 and A2 lie on BC, Hence the equation of BC is x – 7y + 5 = 0

5 1
Now the in-radius = length of perpendicular from O upon BC = =
50 2
6. (A)

7. (A)
2 2
t 2 = − t1 − and t 4 = − t 3 −
t1 t3
2 2
Adding, we get t 2 + t 4 = − t1 − t 3 − −
t1 t 3

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2 2
 t1 + t 2 + t 3 + t 4 = − −
t1 t 3
1 1
 + = 0  t1 + t 3 = 0
t1 t 3
Now, point of intersection of tangents at A and C will be (at1t3, 4(t1 + t3)). Since t1 + t3= 0, This point will lie on
X-axis, which is axis of parabola.
8. (A)

9. (D)

10. (D)
11. (A)
12. (D)
The equations of the bisectors are givne by x.y = 0 and x + y + 2 = 0
There bisectors intersect at the point P(-1, -1).
Focus S, is the foot of parallel from P to MN, where [M(1, 1), N(0, -2)]
i.e. point of intersection of lines, MN (3x – y – 2 = 0) and PS (x + 3y + 4 = 0)
 1 −7  2 2
 Focus is  ,  MS = , NS = 4
5 5  5 5
,
  2  2 
2   4.  
  5  5 
Length of latus rectum = 2 
 2 2 
+4
 5 5 

16 2
=
53 / 2
Circle passing through PMN is
(x − 0).(x − 1) + (y − 1)(y + 2) = 0  x2 + y2 − x + y − 2 = 0
 Equation of tangent at (-1, -1), which is also the equation of directrix, is 3x + y + 4 = 0

13. (D)
14. (A)
15. (B)

 ' s OAP and QTP are similar

AP OA OP
 = =
PT QT PQ
x + 1 h OP
 = = ...(1)
PT 1 x
Perimeter of  OAP = 8  OA + AP + OP = 8
 (h + 1).(x + 1) = 8 ...(2)

Now OP = hx  OT + PT = hx  PT = hx − h
Thus h (x − 1) = x + 1 ...(3)
2

From equ. (2) and (3)

 8  8
h2  − 2 = h=2
 h + 1  h +1

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5 5
From the equ. (2) we have (h + 1).(x + 1) = 8  x =  PQ =
3 3
Coordinates of the centre Q are (h, 1) or (2, 1)
 The equation of the circle is
(x − 2)2 + (y − 1)2 = 1

5 8 4x
AP = 1 + x = 1 + =  Equation of the line OT is y=
3 3 3
4x 3 
Solving with y = , we get the coordinates of R  ,2
3 2 
Equation of the circle passing through O and R is
 3
(x − 0)  x −  + (y − 0)(y − 2) + (4x − 3y) = 0
 2
If Passes through Q(2, 1), so we get  = 0

1. A- R, B- Q, C- PS, D- ST
(a) K = mh − m2  m2 − hm + K = 0
 m1 + m2 = h and m1m2 = k
If tangents intersect axes at concyclic points, then
m1m2 = 1  K = 1  Locus of P is y = 1
(b) y2 − 4y − 2x = 0  (y − 2)2 = 2(x + 2)
2
It’s directrix is x + 2 = −  2x + 5 = 0
4
(c) Any point on the parabola is P(t2, 2t). The circumcentre Q(h, k) of PAB is mid-point of P(t2, 2t) and the
centre C(-3, 2) of the circle. Hence,
t2 − 3
h= , and k = t + 1
2
Elimination t, we get (k - 1)2 = 2h + 3
 3
 Locus of P(h, k) is - (y − 1)2 = 2x + 3 = 2  x + 
 2
3
Which is a parabola, whose tangent at the vertex is x + =0
2
Also, a tangent to parabola with slope 1 is
 3 1
y − 1 = 1 x +  +  y − 1 = x + 2  y = x + 3
 2 2
1
 3 2
A tangent to parabola with slope – 1 is y − 1 = −1 x +  +
 2  −1
 y − 1 = −x − 2  y = −x − 1
2
(d) A tangent to parabola y2 = 12x is y = mx + , which is tangent to circle
m
9
2(x 2 + y 2 ) = 9  x 2 + y 2 = if
2
2
 3 9
   = (1 + m2 )  m4 + m2 − 2 = 0  m  1
 m 2
 The equation of two common tangents are y = x + 3or y = −x − 3
2. A-R, B-PQRS, C-Q, D-PQR
(c) Any point on the circle can be written as
(x,y)  (−7 + 8cos , −8 + 3sin )

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Thus, 3x + 4y = −33 + 8(3cos  + 4sin )

 −73  3x + 4y  7
(d) Let the equation of the circle be x2 + y2 = 1. If vertices of the triangle are (csoi ,sin i ); i = 1,2,3 , then the
orthocentre is
((cos 1 + cos 2 + cos 3 ),sin 1 + sin 2 + sin 3 ) and the circumcentre is the origin.
 Distance between the circumcentre and the orthocentre
= ( cos 1 )2 + ( sin 1 )2

= 3 + 2(cos(1 − 2 ) + cos(2 − 3 ) + cos(3 − 1 ))  3

HINTS & SOLUTIONS (PHYSICS) :

SOLUTIONS :

1. A
Initially, the ball will move in negative y-axis direction with increasing speed. Subsequently, its
velocity will change direction, but since the collision is not perfectly elastic, therefore, the speed will
be less than that before collision

2. B
−dl 0 T
= v − ucos    −d =  (V − ucos ) dt ...(1)
dt 0

T
UT =  v cos  dt ...(2)
0

v
Solving above 2 equations, T =
v 2 − u2

3. am = −a'm
Mg
2T = Mg  T =
2
Mg
Mg − = mam
2
Mg
− m'g = m'am
2
Mm' g
mm' g − = mm'am
2
Mmg
− − m'mg = mm'am
2
Mg 4 1 1
2mm'g = [m + m']  = +
2 M m m'

4.

Nsin30 = mg
2Mv 2
Ncos30 =
3r
1 3rg
= 2
3 2v
3rg
v2 =
2

5. − T dt = m(v − 2g(2 ))

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 T dt = 2mv

 3mv = m  2 g
2
v= g
3

6. T = Mg
Tcos  = mg
mv 2
Tsin  =  sin 
( sin )2

2r
t=
v
v 2
= = 2f
r t

T = m(2f)2
Mg = m(4f 2 )
Mg 1 Mg
f2 = f =
4m 2 m

8. a1 = gsin  + gcos 
a2 = gsin− gcos 

10, 11.

v0 v
m = 3mv  v = 0
2 6
v0 3 3v 0
m = 2mv '  v ' =
2 4

v0 v 
12. m = m  0  + 2mv ''
2  4
v0
v '' =
8
 v  mv 0
IA = m  0  =
 8 8

13, 14,15

m
u = mv cos30 + mv cos30
2
u 4
=v 3v= ...(1)
2 2 3
u2
v 2 3 1
e= = =
ucos30 4  3 3
mu2 mu2 mu2
− 2 =
4 1 6

Matrix Match :

1. WD (By all focus) = KE

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2. Fmin (for all 3 at rest) = 10 N

Fmin (for slipping between B and C) = 20 N
Fmin (for slipping between A and B) = 35 N

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