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Maxwell's Equation For Nanotechnology PDF
Maxwell's Equation For Nanotechnology PDF
Milan Perkovac
I. Technical School TESLA, Klaiceva 7, Zagreb
milan@drives.hr
Abstract - Classical physics, which includes Maxwell's Despite the uncertain physical meaning of
equations, a hundred years ago couldn’t explain the the wave function ψ at the famous Schrödinger's
stability of atoms, the periodic table of elements, the
chemical bond, the discrete excitation energies of equation, “2ψ+8π2m(E-U)ψ/h2=0, the equation has
atoms and their energetic state, the ionization of played an important role in the development of
atoms, the spectra, including its fine structure and quantum physics. The wave function ψ(x,y,z)=ψ(r)
transition rules, experimental evidence about x-ray is the solution of the Schrödinger equation, i.e. it is
spectra and the behavior of atoms in electric and a mathematical expression involving the
magnetic fields, the properties of the matter in solid coordinates (x, y, z) of a particle in space
( r = xˆi + yˆj + zkˆ , where î , ˆj and k̂ are unit
state. That was the reason why classical physics fails
when applied to the atomic area, i.e. to the area of
nanometers or below. Now the situation has changed. vectors; all vectors below are bold letters). If we
It's because within the framework of classical physics, solved the Schrödinger equation for a particle in a
with the help of Maxwell's equations, we can derive given system then, depending on the boundary
Schrödinger's equation, which is the foundation of condition, the solution is a set of allowed wave
quantum physics. With this new knowledge all of the functions of the particle, each corresponding to an
above can now be explained within the framework of
allowed energy level. The physical meaning of the
classical physics. This article describes the procedure
for obtaining the equation, which replaces the
wave function ψ is that the square of its absolute
Schrödinger's equation using classical physics. value, |ψ|2, at a given point is proportional to the
probability of finding the particle in a small element
of volume, dxdydz, at that point. For an electron in
I. INTRODUCTION an atom, this gives the idea of atomic and molecular
orbital. All of this was obtained without the use of
Maxwell's equations. After the explanation of
The whole twentieth century in physics is
radiation [1, 2], Maxwell's equations can give a lot
mostly passed in the search for answers to
more contributions to quantum physics, than has
fundamental questions of matter, primarily on the
been the case so far. It's because from Maxwell's
relationship between waves and particles.
equations we can derive Schrödinger's equation,
Discussions about this are still going on. All the
which is the foundation of quantum physics.
studies are based on unique natural laws that apply
The meaning of physical quantities in
universally in the universe and the atom. But this
Maxwell's equations is completely clear. Therefore,
general approach to the macroscopic and
the meanings of the wave functions of these
microscopic scale seemed questionable in the case
equations, which are derived from Maxwell's
of Maxwell's equations. In fact, Maxwell's
equations, are completely clear.
equations have reached excellent results in the
This article describes how Schrödinger's
macroscopic scale. Their application in the
equation is obtained using classical physics, with
microscopic scale at first glance seemed
special emphasis on Maxwell's equations. With this
disappointed. Namely, Maxwell's equations
equation all the previous disadvantages of
previously couldn’t explain the stability of atoms,
Maxwell's equations can now be explained in the
the periodic table of elements, the chemical bond,
framework of classical physics.
the discrete excitation energies of atoms and their
energetic state, the ionization of atoms, the spectra,
including its fine structure and transition rules,
experimental evidence about x-ray spectra and the II. DERIVATION OF WAVE EQUATION
behavior of atoms in electric and magnetic fields,
the properties of the matter in solid state. That was Maxwell’s equations are the four differential
the reason why classical physics fails when applied equations describing the space and time, i.e. (r, t),
to the atomic area, i.e. to the area of nanometers or dependence of the electromagnetic field [3, 4, 5, 6]:
below. This is why the entire physics divided into
♦ Gauss’s law for electric flux (electric flux begins
two branches: (traditional) classical and (new)
and ends on charge or at infinity);
quantum physics.
∇ ⋅ D (r , t ) = ρ (r, t ) , (1a)
a) Let’s take curl of Faraday’s law, i.e. of (2c):
♦ Gauss’s law for magnetism (magnetic field lines
don’t begin or end); ∂ (∇ × B )
∇ × (∇ × E ) = − . (3)
∂t
∇ ⋅ B (r, t ) = 0 , (1b)
On the other hand, for each vector E is true:
♦Faraday’s law of electromagnetic induction; a
changing B produce E; ∇ × (∇ × E ) = ∇(∇ ⋅ E ) − ∇ 2E , (4)
ρ ∂H ∂2H
♦ Gauss’s law for electric flux; ∇ ⋅ E = , (2a) ∇2 H − μ g − με =0. (11)
ε ∂t ∂t 2
♦ Gauss’s law for magnetism; ∇ ⋅ B = 0 , (2b) Equations (6) and (11) are required wave equations.
These two vector equations constitute six
∂B component equations with seven unknowns (Ex, Ey,
♦ Faraday’s law; ∇×E = − , (2c)
∂t
Ez, Hx, Hy, Hz, ρ). The system becomes determined
∂E if viewed without charge, i.e. ρ = 0 . So we get:
♦ Ampère’s law; ∇ × B = μJ + με . (2d)
∂t
L'dx / 2
C'dx
δ
Fig. 2a L'dx / 2
2ρ 2ρ
C L
Fig. 2b
Figure 1. Lecher line (section); twin-lead transmission line Figure 2. Lecher line is presented with an infinitely small
consisting of pair of wires of diameter 2ρ, separated by δ. capacitors C ' dx and inductors L ' dx (Fig. 2a), which are
concentrated at its end; C at the open end of the line, and L on its
short-circuited end (Fig. 2b).
0 Uuo 2.398 δ ρ = ep /Z 0
where ρ is the radius of each conductor and δ is the
distance between the conductors. 1 2 3 4 5 6 δ/ρ
Transmission line can be a model for the Figure 3. Phase velocity of electromagnetic wave on Lecher’s
observation of electromagnetic waves, given that line as a function of ratio δ/ρ. Areas of stability of atoms is
they have the same differential equation. It takes determined in accordance with [12] (Z=82, lead, δ/ρ=2.398).
σ(δ/ρ) 1
H
70
82 × σ(2.398) =
× σ(2.398) = 82
82 ×
× 0.835
0.836 6
9~~ 68.518
1 σ 0 10
4
82 n λ0 Ξ
60
A0=(μ0/ε0)1/2e2Z σ(δ/ρ)
σ Z e
Decay modes: p+e- +ν
103
50
A0=377×2.56×10-38×82×σ(2.4) Atomic number
40
1
H Elementary particles 10 2
=6.62×10-34 J˙s 2He 2
He
2 3
Li
30 δ
3 All elements of 101
Li
4 3 the periodic table
20 Be 2ρ 2ρ
4 82
Pb 10 0
10 65 LECHER LINE
_δ
118
Uuo
15 Z = 82 σ(2.397 973)=0.835 585 5.044×10^29 ρ δ/ρ 10
-1
0
2.4 10^6 10^12 10^18 10^24 10^30 10 0 101000 10 2000 103000 104000 10 5000 10 6000
Figure 4. Structural coefficient of twin-lead transmission line, Figure 5. Structural coefficient of twin-lead transmission line,
2 2
σ (δ / ρ ) = [ ln(δ / ρ ) + 1 / 4] ln[(δ / ρ ) / 2 + (δ / ρ ) / 4 − 1 ] σ (δ / ρ ) = [ ln(δ / ρ ) + 1 / 4] ln[(δ / ρ ) / 2 + (δ / ρ ) / 4 − 1 ]
(Lecher line) in function of δ/ρ (log-lin scale), Ref. 12. (Lecher line) in function of δ/ρ (log-log scale), Ref. 12,
(Elements and Particles).
From the physical point of view σ is a coefficient All above is generally true at the macroscopic and
of the structure of transmission lines, so we will call the microscopic level.
it structural coefficient dependent on the parameters
δ and ρ , more specifically on δ / ρ , (see Fig. 4
and Fig. 5).
Natural frequency of electromagnetic LC IV. THEORY ON MICROSCOPIC SCALE
oscillator is determined by (20), i.e.,
Now we will adjust the previous equations
for the microscopic scale. From Newton’s second
ν = 1 / 2π LC . (26)
law, F = ma , we substitute a = v 2 / ra and
This means that the oscillatory period of a LC Coulomb’s law for F, and also from relativistic
oscillator is equal to mass we obtain:
2 When the electromagnetic wave leaves the atom it
____
1-β
2 K
ra/(0.1R0)
K ra.=.R0 2 carries out the energy Eem , and vice versa, when it
E
U }
11 Eem /(mc2)
β
Eem
v_..
β.=.c
enters the atom, it brings in the same energy. This
means that due to the reduction of energy Eem , the
0
.
atom should be compensated with equally large
E energy eV :
-1
R0=|q.Q|/(4πε0mc2) Eem = − E = eV . (36)
E.=.K+U.=.-Eem U
-2
0.2 0.4 0.6 0.8 1 From the expressions (35) and (36) we obtain
| qQ | 1 − eV / mc 2
or ra = , (40)
2
8πε eV 1 − eV / 2mc 2
| qQ | 1− β
ra = 2
, (32)
4πε mc β2 while from (40) we obtain eV using (28) and (36):
qQ mc 2 | qQ | 1 − eV / mc
2
| qQ | 1 − eV / mc
2
U= =− β2 . (34) eV = =
4πε ra 1− β 2 2 2
8πε ra 1 − eV / 2 mc 2C 1 − eV / 2 mc
(44)
2
1 − eV / mc
Thus, the electromagnetic energy, Eem , (see Fig. 6) = π Z LC | qQ | ν = Aν .
2
is equal to the total mechanical energy E with 1 − eV / 2 mc
negative sign,
From (29) and (43) follows
Eem = − E = − ( K + U ) = mc 2 1 − 1 − β 2 . ( ) (35)
A = π Z LC | qQ |
1 − eV / mc
2
. (45)
2
1 − eV / 2 mc
70
H1+ ; A0 Eem | ν → 0 = A0ν . (51)
σ σ = p 2 /Z =68.518 σ=
60
0 μ0 /ε0 e2Z
Zσ = p02
50 This, in the case of A0 = h , proves the validity of
A
p0 = 1 0 =8.277 56
40
e μ0c empirically derived Planck-Einstein's relation
He2+ ;σ = p02 /2 = 34.259 Eem = hν , but also shows that Planck-Einstein's
30 α -1 = 2p02 = d02 =(11.706 237)2 = 137.036 relation is limited only to relatively low frequencies
Li3+;22.839 ν . If this frequency is high, then
20
Be4+;17.129 Nd60+; Hg80+; Es99+
10
Ca20+; Zr40+; 1.142 0.856 0.692
2
p0
d0 10
3.426
1.713 Atomic number Z Eem | ν → ∞ = mc . (52)
00 p0 20 30 40 50 60 70 80 90 99
E0 ⎛ 2π ⎞
λ | eV / m c 2 → 1 → 0 m . (59) H y ( z,t ) = − cos ⎜ z ⎟ sin (ωt ) , (69)
μ /ε ⎝ λ ⎠
Phase velocity, according to (49), (54) and (57), where E 0 is the maximum value, i.e., the amplitude
(see Fig. 8) is
of electric field strength, E x ( z,t ) , the x-component
2 of the electric field dependent on the z-axis of the
eV 1 − eV / mc
uem = λν = . (60) rectangular coordinate system and the time t, and
2m 2
1 − eV / 2 mc H y ( z,t ) is the y-component of the magnetic field
If the voltage is low, then dependent on the z-axis of the rectangular
coordinate system and the time t. If we use the
second derivation of the equations (68) and (69)
uem | eV / m c 2 → 0 = eV / 2 m with respect to z, we get equations:
(61)
2
= ½ m v / (2 m) = v / 2 . 2 2
∂ E x ( z,t ) ⎛ 2π ⎞
2
+⎜ ⎟ E x ( z,t ) = 0 , (70)
On the other hand, Maxwell's equations also require ∂z ⎝ λ ⎠
that the following relationship be satisfied for the
phase velocity: 2 2
∂ H y ( z,t ) ⎛ 2π ⎞
2
+⎜ ⎟ H y ( z,t ) = 0 . (71)
uem = 1 / με , (62)
∂z ⎝ λ ⎠
(72)
From (60) and (62) we get
2 2 2 3
∂ H y ( z ,t ) 8π meV (1 − eV / 2 mc )
2 H y ( z ,t ) = 0.
eV 1 − eV / mc 2
+
2 2 4
1/ με = . (64) ∂z A0 (1 − eV / mc )
2m 2
1 − eV / 2 mc (73)
System of equations (63) and (64) have solutions Since eV = − E , we can write,
μ and ε as follows:
2 2 2 3 the y-component of the magnetic field dependent on
∂ E x ( z ,t ) 8π mE (1 + E / 2 mc )
− E x ( z ,t ) = 0, the z-axis of the rectangular coordinate system and
2 2 2 4
∂z A0 (1 + E / mc ) the time t. Meaning of all the other physical
(74) quantities in this article is also completely clear.
The solutions of differential equations (76)
2 2 2 3 and (77) are the same as the known solutions of the
∂ H y ( z ,t ) 8π mE (1 + E / 2 mc ) Schrödinger’s equation only the meaning of the
− H y ( z ,t ) ) = 0,
∂z
2
A0
2
(1 + E / mc
2 4
) wave function is different.
(75)