Adv FT1 Paper1 Sol PDF

1
AITS-FT-I-(Paper-1)-PCM (Sol.)-JEE(Advanced)/18
FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS

FULL TEST – I
PAPER-1
Q. Q. Q.
ALL INDIA TEST SERIES
PHYSICS CHEMISTRY MATHEMATICS

No. No. No.
1. A 24. C 47. B
2. D 25. D 48. C
3. B 26. C 49. A
4. B 27. B 50. A
5. D 28. A 51. B
6. A 29. D 52. A
7. A 30. A 53. C
8. C 31. A 54. C
9. ABC 32. AB 55. AC
10. AD 33. ABC 56. AD
11. BCD 34. BD 57. AC

12. BC 35. BC 58. ABD
13. D 36. A 59. B
14. C 37. B 60. D
15. C 38. C 61. C

16. A 39. A 62. A
17. A 40. A 63. B
18. C 41. D 64. D
19. 4 42. 4 65. 0

20. 2 43. 5 66. 2
21. 6 44. 5 67. 8

22. 8 45. 6 68. 1
23. 3 46. 4 69. 7
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2
Physics PART – I
SECTION – A
    
1. 
aB  a A    rB,A  2 rB,A 
 5j  4i  3j  12i  16j 
aB along y  axis should be zero.
 11  3  0
4
    rad / s 2
3
80
aB   4  12  i   i m / s2
3

2. y tan 
2
 y
dy  sec 2 d 
2 R Q

4   B 
8  Bdy cos  
0
 B
a b  c  d
.d  0I0 x
 
2  
4
8 I 2  I0
0 4 0x0 . . sec 2  cos    B.d  0I0
2 2 a b c  d
x2 
4 S P
2 
0I0   B.d  0I0
3 a b c  d
  2 I
 B.d  0I0  0I0  0 0
a b  c  d 3 3
3. Let R  2  R1
t R  4
3CE   
qt   1  e 2R1C 
2   q

t q1
dq 3E 
2R1C
I  e 2  64  q1   q  q1 
dt 4R1
+ +
2
Heat loss in R1   I R1dt
8v
C - -C
 576 J
2
so, heat lossin R  4 is  576   384 J
3
4. Maximum power transfer will takes place when v P is maximum.
5. aC  R  for no slipping 
3
VC  R  VC is the speed of cylinder w.r.t plank 
)
nk
la
aC  3aP  0
tp
.r.
F
(w
VC  3VP  0 V
P
C
a
P
a
S C  3SP  0

f
f
6. Let T1 and T2 be the initial and final temperature, then
P0 V  nRT1 ...... i 
 W
 P0  A   V  Ah   nRT2 ....  ii
 
Where h is the displacement of piston.
Also, work done on gas  U
3
Wh  nCV T  nR  T2  T1  ........  iii
2
From euqation  i  ,  ii  and  iii 
2 WV
Wh   Wh  P0 Ab
3 A
WV
or, Ah 
5
P0 A  W
3
 
 W  Wv 
T2   P0   V  
 A  5
 P0 A  W 
 3 
5 5
T2  T1   300  5  75K.
4 4
v v
7. f 
2    2  0.6r  2    1.2r 
f v     1.2r 
  
f v    1.2r 
v
Here 0
v
f
 100  
   1.2r   100
f    1.2r 
 0.16
Gm 2
8. P 
8 R 4
4
P
B
V / V
3dR Gm2
B. 
R 8R 4
Gm 2
dR 
24BR3
20
9. I1  2
z1
2 100 100
I1
 A at 450 leading
5 2
20 2
I2   A at 450 lagging I2 XL  50
z2 5 50
1
I1R.M.S  A
5 40 V
2
I2R.M.S  A
5
10. For central height fringe

dsin   2mm
4mm sin   2mm
  300 S1 y
y 
tan300 
2
1
y m.
3 S2
For bright fringe  dsin   2   n
where n is 0,1,2,3.........
11. N12  N22  N2

 1
N2  mg
2
m   sin   f 
f  m 2  2
N1  m2 1 2
x
f
N1 N2
m2 x
5
 1  dx  1  O
12. dE  2    
 40  x  2 
 dx
dE  x
4 0 x D C
7
E In 2
440
A B
  dx
13. & 14.

Writing energy equation
dv d 2
mgv  mv I i R .....  i  
dt dt
C1 C2
v  a
dv d
a
dt dt B
i
Ba2 Bva
i  .....  ii
2R 2R R
From equation  i  and  ii 
g
3m dv B 2a 2
 mg  v v
2 dt 6mR
 B2 a2 
  t 
4mgR  6mR 
v  2 2 1 e   
Ba  
 
B 2a 2
dv 2g  6mR t
 e
dt 3
15. & 16.

Vemit  Vcollector
V  iR I
hc  2A e
Vstop    2v
e e
i  2V
i
I  2  iR
i 1  R   2
2V V V I R
2
i
1 R
4R
P  i2R  2
1  R 
dP
0
dR
2
4 1  R   4R  2 1  R   0
4  4R  8R
R  1
6
17. & 18.

V  2gh  1 m / s 1 m/s
8 3 1
  t   10Xt 2 370
100 5 2
1
t  sec
5
4 1
 x    100  16 cm
5 5
horizontal range from point B  16  6  10cm
Force required to keep the vessel in equlibrium  AV 2 cos 370
 0.12 N
SECTION – C
0 q2R2
19. FR    mR2 
4
  q2 
F  R m  0 
 4 
F F
 R 
2m  q2
m 0
4
m  4
q  5  10 4
0
20. After refraction through the quarter cylinder the emergent ray falls on the parabolic reflector
parallel to x – axis.
1
tan         y1 (x1, y1)
dy
A
dx  x1 ,y1 

2 tan  y1
tan2  2
 
1  tan  x 2  x1
2 
1
 x 2  m  50 cm. C
2
(x2, 0)
Ac is a normal at A
2
1 m 2 1  3F  3F 3F
21. . v0  K    .
2 2 2 K  2 K
4  9F2
v 20 
Km
v0  6 m / s
7
22. In the frame of the heavy cylinder the particle comes in with speed V and then bounces off.


2 v
f  2mv cos2   Rd cos   vn 

 
2
v
f 8 
 mv 2nR.
 3
z2 z2
23. f  f0  2 ......  i
n3 n3
z2 z2
E  E0 2  2  4 ii 
n n
Solving (i) and (ii) n = 2 z = 4
nh
L  mvr 
2
h
L  t  n
2
n h
 .
t 2
  1027  15
8
Chemistry PART – II
SECTION – A
24. (C)
Fact based
25. (D)
Zone refining is based on difference in solubility of impurity in its molten as well as solid state.
26. (C)
1.435 gm
No. of moles of AgCl =  0.01 moles
M AgCl
No. of moles of CoCl3.4NH3 = 0.01 moles
1 ionizable Cl per mole of CoCl3.4NH3
27. (B)


AgI  s  
 Ag  aq   I  aq
 
K sp   Ag  aq  I  aq  




Ag  aq  2CN  aq 
  Ag  CN2   aq

 Ag  CN 2 
Kf   
 Ag  CN 
Now, let a moles of AgI dissolved in CN- solution



AgI  s   2CNaq 
  Ag CN 2   Iaq
 aq
1 mole 0 0
12 x  mole x mole xmole
As CN   M.V  1 1  1 mole

x.x
 Kc  2
1  2x 
also K c  K f .K sp
x2
 2
 1.19  10 17 M2  7.11 1019 M2
1  2x 
 x  0.5
28. (A)
O
CHO COOH COOH CHO
H OH H OH HO H HO H O Na - Hg HO H
-H2O
HO H Br2 Pyridine pH 3 - 5 HO H
HO H HO H HO H
H OH H2O H OH H H OH
H OH
H OH H OH H OH H OH H OH
OH OH OH OH OH
D - mannose
9
29. (D)
OH
HBr Me3CO- CH2I2/Zn(Cu)

Br
Me3COH Et2O
30. (A)
d  A
  k . A  ; for first order reaction
dt
 A   A0  kt; for zero order reaction
1 1
  kt for sec ond order reaction
 At  A0
31. (A)
2KMnO4  KBr  H2 O  KBrO3  2KOH  2MnO2
32. (A, B)
O O
OH O
O
-H2O
H
(A)
OH (C)
+
(B) H
OH
O O O O
NH3 -H2O
H
(E) NH2 (D) OH
N
H
33. (A, B, C)
U  nCV T  T  0; U  0 
H  nCP T  T  0; H  0 
1st law U  q  w  0
10
 q  w
V2
w    Pext dv
V1
Pext  P2 ; w  P2 V2  V1 

 RT RT 
w  P2   
 P2 P1 
 P 
 RT 1  2 
 P1 
 P 
 q  RT 1  2 
 P1 
34. (B, D)
1 a
PC 
27 b 2
VC  3Vb
8 a
TC 
27 Rb
35. (B, C)
Kw
As for salt of strong acid and weak base degree of hydrolysis, h 
Kb .C
36. (A)
D
+ +
O O D
D-O-D
H3C C CH3 H3C C CH3 + D2O
O D O D
H3C C CH H3C CH CH2
+
H D+ H
return to keto form
+
O D O O
-D+ repeat
H3C C CH2 D H3C C CH2 D D 3C C CD3
37. (B)
As deprotonation step in case of iodination is rate determining.
11
38. (C)
o RT
Ecell  Ecell  lnQ
nF
RT  C2 
Ecell 0 ln  
nF  C1 
 1 
RT  50 
 ln  
nF  2 
 100 
 0V
39. (A)
oxidation half  cell reaction
Ag  s   Ag  aq   e 
Re duction half  cell reaction
AgCl  s   e   Ag  s   Cl  aq 
Net cell Reaction : 
AgCl  s  
 Ag  aq  Cl  aq
At equilibrium : 
RT
0
Ecell  0  E cell  n K sp
nF
and E0cell  E0Cl / AgCl/ Ag  E0 Ag / Ag
 0.57V
K sp  1010  10
 3.16  10 10
40. (A) O
O Base
PPh3 +
Ph3P
Br OEt
OEt
-
O O
CH3CHO +
Ph3P
Me OEt OEt
12
41. (D) H
OH O O
O
- - +
O O + H-B
O H H OH
B Me
C O
H
H
O O
- +
O O + H-B
-
Me O
H
O O H
+ O O
- H-B
O O
O OH
Me OH
Me OH
-H2O
-CO2
COOH
Me
SECTION – C
42. 4
d 68  32
Enantiomeric excess =  100   100  36%
d 68  32
 Optical rotation of this mixture = 36%   11.10  = 4
43. 5
Aldol condensation
44. 5
I3 , XeF4 , H2 O, NH2 , H2 S
45. 6
H O O H
B O O B
-
O B O
B O O B
O H
H O
46. 4
 1340
n  4
2r1 2  3.14  53
13
Mathematics PART – III
SECTION – A
x 6 12 5 5 x 3 4 4 x 3
47. f ' x   x  x   2x 2  99
6 15 20 3
f "  x   x5  4 x 4  3x 3  4x 2  4x

x x 4  4 x 3  3x 2  4x  4 
2
x  x  1 x  2   x  1
Pt of inflexion at X = -1, 0 &1
So -1+0+1 = 0
 4 17  A
48. Equation of BC is x + y = 7 so B =  , 
3 3  y = 2x + 3
Let slope of AB is m so,
m2 2 1

1  2m 1 2
1 C ( 3, 4 )
m B
7 y=x+1
So equation of AB is 3x + 21y – 123 = 0
 17 21   67 131 
So A ≡  ,  mid-point of AB =  , 
 4 4   24 24 
Equation of medium through C is 7x + y = 25
49.    
 xy 2 dx  y 2 dx  2 xydy   x 2 ydx  2 xydx  x 2dy  0
 
e xy dx  e  y dx  xd  y    e x ydx  e  2 xydx  x dy   0
x 2 x 2 2 x 2 x 2
d  e xy   d  e x y   0
x 2 x 2
e x xy 2  e x x 2 y  C
Passing through (1, 1) so C = 2e so, curve is xy  x  y   2e1 x xy ( x  y )  2e1 x
50.
10 B
10 W
1 1
2 2
15 B 10 B
10 W 15 W
10 15
15
25 10 25
25
25
11 B 15 B 6 B 10 B
10 W 6 W 15 W 11 W
Required probability,
14
1 15 10 1 10 15
    
2 25 21 2 25 21
1 15 10 1 10 6 1 10 15 1 15 11
          
2 25 21 2 25 21 2 25 21 2 25 21
2 20 4
  
2 11 11  20  4 7
1  1
5 10
3 y=x
51. Required area is times the area of loop y
2
1
y = f(x) y  f 1  x
3
2

 2  x  x 2  x  dx 
0
o 1 3 2 x
2
4
52. Let I   g  x  dx
2
Using by parts
4 4
I  x.f 1  x     f 1  x  dx
2 2
4
→ 1
1 1 1
I  4f  4   2f  2    f  x  dx
2
Now,
f 1  f  x    x
f 1  f  0    0  f 1  2   0
alsof 1  f 1   1  f 1  4   1
b f b
1
 f  x  dx     f  x  dx  bf  b   af (a)
a f a
1 4
 f  x  dx   f 1  x  dx  1.f 1  0.f 0 
0 2
1 4
 x 
3
 x  sin x  2 dx   f 1  x  dx  4
0 2
1
1
4  x 4 x 2 cos x 
also 2 f  x  dx  4      2x 
 4 2  0
53. Let x = cos

1 
x ,  
2 4

 2
cos 1 cos 2 2
As lim  lim
 1  1
4 cos   4 cos  
 
2 2
2
lim 2 2
  sin 

4
n
Coeff. X3r in 1  x  x 2  . 1  x  
n
54.
 
15

 coeff .of x 3 r in  a0  a1x  .....a2 x 2 n n
c0 
 nc 1  ..... 

n
 Cr
55.  Tangents are  r . so, they intersect on A(1,1)

directrix.
Point of intersection = (2,0) mid-point of (1,1) & (2,0)
5 3  5 3
(4,2) is  ,   , 
 2 2
 2 2
3 S
0
Slope of axis = 2 3 B
(4,2)
5
2
2
1
Equation of directrix, y    x  2 
3
x  3y  2
AB is focal chord,
462 8
BS = ( r distance from B on directrix) = 
10 10
1 3  2 2
AS = ( r distance from A on directrix) = 
10 10
8 6
So, focus divides AB in 1: 4 ratios. So S =  , 
5 5
56. By Rotation theory P (z3)

z2
 cos e i  Q (z2)
z1 
O  R (z1)
z3 cos 2 i 
 .e
z2 cos 
z2 2 cos2  3
so  
z3 z1 cos 2 2


6
57. AXE  CYE A

so, ar  AXE   ar  CYE   1 Y
E
ar  BYC   ar  BEC   1
41  ar  BEC   1
X
ar  BEC   31  ar  ABE   ar  AXB   ar  AXE  C
 so, ar  AXB   21 B
ar  ABC   2ar  BEC   61

A B C
58. , , HP
a b c
16
2b a c
  
B A C
 2bB  aC  cA
 aB  cB  aC  cA
 a B  C   c  A  B 
c
so, r 
a
A B C2
2 2
c
, , areinHP  r 2 
a b c a
59 – 60. A  (3, 2, 1), B  (4, 1, 2) point of intersection  (0, 0, 0)

1 19
Area of triangle = (3iˆ  2 jˆ  kˆ )  (4iˆ  jˆ  2kˆ ) 
2 2
 14 7 7 
Also image of (0, 0, 0) w.r.t plane  is  , , 
 3 3 3 
 14 16 2 
Image of (0, 0, 0) w.r.t AB is  , , 
 3 3 3
3 x  14 3 y  7 3z  7
Equation of line joining these two points =  
0 3 3
n 1
61 – 62. x
i 1
i  2i xi  i 2  0 
n 1 2

i 1
xi  i 2   2i x i  i 2  i 2  0
n 1 2

i 1
xi  i 2  i  0
so, xi  2i 2
Now, x12 +……+ xn2 = 280
2 12  22  ........n 2   280
n7
y1  y 2  y 3  7
y 11  y 21  y 31  4
4  3 1
C3  6C3  20
15  14  13 15
Total triangles formed = C3 
6
N of isosceles triangles formed = 15 × 7
15  7
probalality = 6
15  14  13
3
13
63 – 64. p (n) = p(n - 1) + p(n - 2)
17
SECTION – C
65. Consider y = ax 2  bx  c
Slope of BA. Slope of BC = -1
D D
4a . 4a  1
b b
x1  x  C
2a 2 2a A
D2 b2 b (x 10) (x 20)
 2
 2   x1  x2   x1x2  0 B
16a 4a 2a 
 b D 
, 
 2a 4a 
D2 b2 b b  c
 2
 2    0
16a 4a a  2a  a
 D  0or 4

sin x
66. I  dx
 1  tan2 x

2
sin x
I 2 dx
 1  cot 2 x

2

2
 4 cos x sin xdx
0
8

3
I   2
67. PA = PR = 8 – a A
So PQ = 8 – a + b 8-a
Also QD = QR = 8 – b P
So QP = 8 – b + a
aB
8–a+b=8–b+a Sa
ab
PQ  8
C bR
b Q 8-b D
68.  
det A 1  A  5I   det(A 1 ).de  A  51
 4
69. Tangent at  5,  is 5 x  3 y  9 x=1 is directrix of Hyperbola.
 3
 9 5
So, A =  1,  & B = (0, 3)
 3 

18
Area of figure OGAB is

B
9 5  1  9 5 
1     1  3   C A  
 3  2  3   5, 3 
    
9 5 5
 
3 6
H O G (3, 0 )
18  5

6
Area of required figure is
18  5  36  2 5 D F x=1
4  E
 6  3
Integral part of area is 7.

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1

ANSWERS, HINTS & SOLUTIONS

PHYSICS CHEMISTRY MATHEMATICS

10. AD 33. ABC 56. AD

11. BCD 34. BD 57. AC

15. C 38. C 61. C

18. C 41. D 64. D

19. 4 42. 4 65. 0

21. 6 44. 5 67. 8

23. 3 46. 4 69. 7

4. Maximum power transfer will takes place when v P is maximum.

VC  R  VC is the speed of cylinder w.r.t plank 

10. For central height fringe

11. N12  N22  N2

13. & 14.

15. & 16.

17. & 18.

K sp   Ag  aq  I  aq  

As CN   M.V  1 1  1 mole

HBr Me3CO- CH2I2/Zn(Cu)

(E) NH2 (D) OH

Pext  P2 ; w  P2 V2  V1 

return to keto form

Mathematics PART – III

55.  Tangents are  r . so, they intersect on A(1,1)

56. By Rotation theory P (z3)

57. AXE  CYE A

ar  ABC   2ar  BEC   61

59 – 60. A  (3, 2, 1), B  (4, 1, 2) point of intersection  (0, 0, 0)

63 – 64. p (n) = p(n - 1) + p(n - 2)

Area of figure OGAB is

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