Aits 1718 Open Test Jeea Paper 2 Sol

1 AITS-OT-(Paper-2)-PCM (Sol)-JEE(Advanced)/18
FIITJEE JEE(Advanced)-2018
ANSWERS, HINTS & SOLUTIONS
OPEN TEST
PAPER-2
Q. Q. Q.
PHYSICS CHEMISTRY MATHEMATICS
No. No. No.
1. B 24. C 47. C
ALL INDIA TEST SERIES
2. B 25. D 48. A
3. B 26. B 49. D
4. A, C 27. A, C, D 50. A, B, C
5. A, B, C, D 28. A, D 51. A, B, C, D
6. B, C 29. A, B, C 52. A, B
7. B, C, D 30. A, B, D 53. A, B, C
8. A, B, C 31. A, B, D 54. A, C
9. D 32. C 55. B
10. C 33. D 56. A
11. 8 34. 4 57. 3
12. 6 35. 4 58. 1

13. 9 36. 2 59. 4
14. 6 37. 9 60. 1
15. 3 38. 7 61. 6
16. 3 39. 3 62. 7
17. 4 40. 1 63. 1
18. 2 41. 8 64. 1
19. 5 42. 4 65. 1
20. 4 43. 2 66. 8
21. 02200.00 44. 00252.65 67. 00000.25
22. 00004.37 45. 01299.00 68. 00000.20
23. 00009.37 46. 00123.00 69. 00003.50
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AITS-OT-(Paper-2)-PCM (Sol)-JEE(Advanced)/18 2
Physics PART – I
SECTION – A
1 1 1 1 1 1
1.       v  40mm
v u f v 20 40
v  40 
m     2
u  20 
 separation between the two images formed = (20)2  (1)2  20.025 mm
2. Path difference at angular position  is d sin .
V
3. Let  m
2 I1
 3R   3R 
mR    2m  R  
8 8  7R
rCM      I2
3m 8
Moment of Inertia of sphere about a horizontal are passing
through the hinge.
2 2
  3R     3R  
I  I1  m  R  
 2I  2m R  
  8    
 8  
2 2 2 2
2  3R   11R    2  3R   5R   69mR2
I   mR2  m    m  8      2m  R 2
 2m  8   2m  8   
 5  8      5      20
7R 27
  6mgR  3mg   mgR
8 8
d2  27
I 2  mgR  0
dt 8
46R
 T  2
45g
 1  
 1  50 cos 2 
2R
/2
4. f   f0   ,  = t B
 1  1 cos  
 100 2  R
R 1
k  
A
v 100 O
   
1  2k cos  2  
t  
  
 1  k cos  2  
 
             k   
1  k cos  2    k sin  2    1  2k cos  2    2 sin  2  
dt            
 2
d    
1  k cos  2  
  
k  
 sin    0   0,     0, 2
2 2 2
98
fmin  f0 at   0
99
102
fmax  f0 at   2
101
5. Basic knowledge to write angular momentum and kinetic energy of the system.
y mgx mgy
6. x , and F  y   
2  2
 
mg mg F(y)
Work done by F  y    F  y  dy 
 ydy 
0
2  0
4 F(y)
Second method: Using WET, we can write
K f  K i  WF  Wmg  0
x
      mg
 WF   Wmg    mg     
  2 4  4 y
Concept: Work energy power
xmg

7. For resonance I10 V10 V20

I20  I10 sin 
L R
V0 V0 XL
  I20
Xc XL2  R 2 XL2  R2
C
 XL2  R 2  X C XL
L ~
 L2 2  R2 
C V = V0 sin t
2
1 R 
2 I20
    
LC  L 
2
1 R 90°
  
LC  L 
v10
v0
I10
v20
8. By energy conservation
1 Mm 2 1 2
v  kx
2 mM 2
m 1 5
 xJ 5  m
M(M  m)K 236 6
GM
9. v2  (R2  x 2 )
R3
10. The waves emitted from the source cease to reach the recorder after the source’s speed exceeds
that of sound:
v 0  R sin t;
g
Where  
R
v 02
The corresponding x = R cos t = R 1
2
SECTION – C
11. Assume that on circular face of cylinder, a charge q of P

surface charge density (in magnitude) appears. So,        O X
 ˆ    M
Q = s, EP  j , EM(Q )  EM(q)  EM(Q  )  0 …(1)
0
 q Y
EP(q)  (  ˆj)
40a2 ++++++
+
    ˆ
EP(Q )  EP(q)  EP(Q  )  j …(2)
0
From equation (1) and (2)
 ˆ
EP(q)  j
0
q qS
  2
 Q
4 a 4a2
 qQ  1 1  qQ
Fcylinder   2   (a   )2  a2 
2 2 2  
40  a (a   )  40a (a   )
qQ(2  2a) 2qQa
= 2 2

40 a (a  ) 40 a4
q qS q2
  V 
20 a3 4a2 82 0 a5
Second Method:
Due to induction, Q  s and + Q = + s will appear at upper 
0
surface and lower surface of conductor. These two charged 
Q
system will act like a capacitor for region inside the conductor, so
due these charges, net electrostatic field at inside the conductor

has magnitude
0 E
      +Q
Since net field due to all charges inside the conductor is zero.
 q 
E  2

0 4 0 a 0
q
 
4 a2
12. F1 = 3F and F0 = 2F1 = 6F = 60 N FB

F1
x0 2x0 R/3
A C
B C O
R
F0 F1 F
y
1 gsin  2
13. h   tan  
2 v 20 cos2  v0
gsin 2 g sin 

v0  2 h=1m
2cos ( tan   h) 
x
4  = 8m
10   8  8
= 5  9 m/s
4 4 3 
2    8   1
5 5 4 
1 
  8R  3R  R 3
qin  2   12R
14.   5R
0 0 0
3R
8R
9 3 a a
15.  
15 5 g 15 
5
12 3
3 53 37
a g
5 9 2 4
I
16. T  2
mgd
1 mgd
f
2 I
1 (2m)(g)(3 / 4) 1 18g
f0  
2  m 2  2 13
  m 2 
 3 
When disc is removed
1 1 6g
f 
mg( / 2) 2 
2
m 2 / 12
f 6g 13 13
 
f0  18g 3
1
17. K mv 2
2
dK 1 2 dm 1 dv
 v  m  2v
dt 2 dt 2 dt
1 1
= 9t 2  18   54  2  3t  3
2 2
dK
 9  2  18  54  18
dt t  2
= 1296 J/s
18. for block B N

m2g  T = m2a2 …(i) T
(A)
T + N = m1a2 …(ii) v1 m1
by circular motion dynamics N
m1g
m v2 a0
m1g  m1a0  N  1 rel (from
R R T
hemisphere )
on solving these equation and (B)
putting of all variable we get aA = m2
2 17 m/s2
and aB = 8 m/s2
dm
19. F= u and P = Fv
dt
0 aV
20. i (k  1)A sin t
d
q   | i | dt
SECTION – D
21. T = T Extension …(i)

mg F 
 Y e
S S 
mg
  e   compression …(ii)
SY
If there is no change in length, it means extension due to temperature raise must be equal to the
elastic compression due to weight. So
mg
T 
SY
SYT 1.1 10 5  10  10 4  10  2.0  1011
 m   2.2  103 kg
g 10
2usin 
22. T 4s
g
First collision occur after 5/20 sec
5
So, t = 4   3.75 s
20
S1 = 3.75  10 = 37.5 m
When ball collide with wall B, then total time elapse
t = 0.25 + 1.5 = 1.75 s
t = 4  1.75 = 2.25 s
S = 2.25  2.5 = 5.625 m
23. Initially V800 = V1000

 V = 0.8 V (V is volume inside water)
 H = 0.8 H = 0.8  50 cm = 40 cm
If we displace the block by dy inside water then
 a
dy  dx 1  
 A
Where dx is the new dipped part of block on displacing the block by dy
0.5
 dW =   x(0.5)2 1000g  (0.5)3 800g dx 3  W = 9.375 J
  4
0.4
Second Method:
a  Area of cube A  Base area of container.
h
H x
AH  ah  A  H  y   a h  x  y 
a A
 y x  xy x
A a Aa
Fex  FB  mg  ga h  x  y   a3B g
 A 
 a  x  y   g  a   x g
A a
x0
aA g x20 0.2 a  A  a 
W   Fex dx   Here x 0 
0  A  a  2 A
1 3 1
aA g a2 0.04  a  A  a 
2
0.04a 2  A  a  0.04     1000  10
W     g  4 4 4
 A  a 2 A2 2A 2 1
300 75
   9.375 Joule
32 8
Third Method: a    
h0
y 2 2 y
h
H 1 x
x
  3
h0  , x  y  , x  3y  x 
5 5 20
3a 3V
m0  mass of liquid displace = ax  
20 20
x  y 4  9
Vertical displacement of liquid = h    
2 5 10 10
g 3V 9
WFB  work done by force of buoyancy to raise the liquid  m0 g    g 
10 20 10
3 1 9 1
   1000  10    84.375 J
20 8 10 2
Wmg  Work done by weight to displace the body downward by distance x
120 3 1
 mgx   800  10    75 J
8 20 2
According work energy theorem
WFex  WFB  Wmg  0
 WFex   WFB  Wmg  84.375  75  9.375 Joule
Chemistry PART – II
SECTION – A
24. B  Tl  Ga  Al  In
kJ / mole : 800 589 579 577 558
The last element (Tl) has exceptionally high first ionisation energy due to poor screening caused
by f-electrons.
The second element (Al) has exceptionally low first ionisation energy due to good screening
caused by s & p electrons.


HCOOH  HCOOH  
 HCOOH2  HCOO

25. 25M 25M 0 0

3 3 3
25  10 10 10
3
10
%  100  0.004%
25
26. H F Cl
o o o
125.8 C O 108 C O 111.3 C O
H F Cl
Higher the electronegativity of bonded atom, lesser is the bond angle between the bonds.
27. 14 17
7p 0p
Cl m O m
O 117o O Cl 111o Cl
Cl2 O  H2O  2HOCl
28. H2C Cl H2C Cl
H2C CH2
S
Mustard gas structure
O H H
29.
O Cl O
HO OH
Cl CH
O Cl O
O (Driving force is relief in angle
H H strain on hydration)
30. The formula of complex is:

[CrCl2(en)4]2 [PdCl4]
Hence, i = 3.
31. Here carbon is sp3 hybridised Here carbon is sp2 hybridised

(A) which is more electronegative.
CH3 CH2 Cl H2C CHCl
Hence bond will be shorter
(B) CH2 CH2 CH2 CH Cl

1.34 Å 1.38 Å
No resonance In vinylchloride C=C bond length
is longer due to lone pair and
double bond resonance
(C) C–C bond length are different in all

three cases
(D) CH3–CH2–Cl CH2 = CHCl

2.05 D 1.44 D
In CH2 = CH – Cl charge separation is less.

32. E.W
N2 = 42
H3PO2 = 33
HN3 = 43
P4O6 = 27.5
33. 12N2  4H3PO2  8HN3  P4 O6  2H2 O 

P4 O6  6H2O  4H3PO3
6 moles H2O reacts with 1 mole P4O6
1 2 1
2 moles H2O reacts with  mole P4O6
6 3
2
 fraction of P4O6 left unreacted =
3
SECTION – C
34. pH range of indicator = 3.4 – 4.6

 pOH range of indicator = 9.4 – 10.6
9.4  10.6
 pKb of indicator   10
2

InOH   
 In  OH

In 
pOH  pK b  log
InOH
For solution to appear in the colour of In+, pOH  10.6
In  In 
In limiting case; 10.6  10  log    4
InOH InOH
35. HO
X OH
HO
HO
36.
Cl
O O
HO CHO , C C C
H , H
Cl
Do not contain any -hydrogen but still fails to undergo Cannizaro reaction. In case of
HO CHO
,
the corresponding hydroxide is strongly stabilised by –R effect of –CHO. Consequently, the
-
electrophilicity of the carbonyl carbon is reduced and the OH does not attack the carbonyl group.
Cl
O
In case of C , C CHO
H
Cl
The intermediate formed due to attack of OH- cleaves to give a stable anion.
Cl Cl Cl Cl
O O
  HCOOH
C OH
  C OH   

H H
Cl Cl Cl Cl
37. O
CH3 COOH
 i Alk. KMnO i  NaOH/NaClO


4
N H  
ii  NH3 aq ,   ii H
CH3 NH2
P  Q R 
O
i  NaNO2  HCl 0o C
ii OH
COO


N2
 CO2
+
N2
T  S
2 

T  U 
O
C OH
CH3  Cl
Also, 
anhyd. AlCl3
 No reaction
NH2
38. Me
Et Et Me Me
C C C C
H H Me Me Me Me
Me
Et H
C C
H Et
39. C3H8O3  nCH3MgI 

 nCH4
mass 0.092g
0.92 67
moles mole mole
92 22400
 1 m mole  3 m mole
So, on comparing each molecule of C3H8O3 must give 3 molecule of CH4
40. Rate  k C3H6*  (i)
C3H6  C3H6*  C3H6* 

Kc  for step1  
C3H6 C3H6  C3H6 
 C3H6*   K c  C3H6 
 
Substituting in equation (i)
R = k. Kc[C3H6]
R = k [C3H6]
v
41. 
2r
Z
v
n
n2
r
Z
Z2
 3
n
He 4 1 32 25
   
H 27 8 27 33
x=5
y=3
x+y=8
42. b, c, d, f
43. One mole of the above compound (X) on hydrolysis followed by heating produces 4 moles of
CO2.
Hence, 0.5 M of X produce 2 moles of CO2.
SECTION – D
44. Ca3  PO4 2  8Mg  Ca3P2  8MgO

A B 
Ca3P2  6H2O  3Ca  OH 2  2PH3

A  C
2PH3  3CuSO 4  Cu3P2  3H2 SO4
 X,Black 
 2Ke2  Z
46. v     , so, atomic no. (Z)  slope of the graph.
 h  n
So, statement (1) is True.
h 1
  , slope of the graph 
2qVm m
So, statement (2) is True.
From, PV = nRT
 nR  1
V   T , so, slope of graph 
 P  P
So, statement (3) is also correct.
1
 P   nRT  , so, slope  T
V
So, statement (4) is incorrect.
Mathematics PART – III
SECTION – A
1 d x3 3 1 d y3
47.
3 dx
e y 1  
3 dx
e 0   
48. Each prime can go in one of the five slots – x1, x2, x3, x4 and none of these.
 sin12 B  sin12 C  4  4
49. 44   = where ,  are distinct positive real number whose
  sin2A  sin 2B  sin 2C  4
     
4
 
 
 2 
AM is a and two GM’s are b, c
50. Any combination of 4 points gives 3 new intersection points
51. f(1  x)  f(1  x)

 f(1 + x) = –f(1 – x)
 /2  /2
cos  1
52. I  d   cos d  1
0
10  6 cos  4 0
cos  cos     
 
 for   0,   I > 0
10  6 cos  10  6cos       2

53. For area of parallelogram PQRS to be least line L makes angle with L1 and L2
4
54. Centre of the circle is at (a, a)

a2 + (a – 2)2 = (a – 4)2 + (a – 3)2
21
a=
10
55. D5
56. 5
C1  4
C1  D4  4 C1   3
C1  D3  3 C1  2C1 
SECTION – C
3
57. C1  D3  3C1  D2  2C1
58. Let x = r cos ; y = r sin 

sin 2
 r2 
cos   sin4 
4
59. Exactly four girls are together – Exactly four girls are together and B1 B2 are together
5! 8! 58
p=
13!
3 5 34
60. tan  = , tan  = 
5 4cos  4
 1 2
61. 9 1    9   6
 3 3
2 2 2   2
2
62.  = 2  2 2 2 =  3  3   3  3 
2 2   2 2
63. Denominator = nC0 n+k–1Cn–1 + nC1 n+k–2Cn–1 + nC2 n+k–3Cn–1 + … nCk–1 nCn–1 + nCk n–1Cn–1
= coefficient of x n–1 in
n
C0 (1 + x)n+k–1 + nC1 (1 + x)n+k–2 + nC2 (1 + x)n+k–3 + … nCk–1 (1 + x)n + nCk (1 + x)n–1
= coefficient of x n–1 in
n
C0 (1 + x)n+k–1 + nC1 (1 + x)n+k–2 + nC2 (1 + x)n+k–3 + … nCk–1 (1 + x)n + nCk (1 + x)n–1
n n–2 n n–3 n k–1
+ Ck+1 (1 + x) + Ck+2 (1 + x) + … Cn (1 + x)
n–1
= coefficient of x
n+k–1 –1 n k–1 n
(1 + x) (1 + (1 + x) ) = (1 + x) (x + 2)
n–1
= coefficient of x in
n n
n
 Cr 2r xn r (1  x )k 1 = 2 r n
Cr k r
C r 1 .
r 1 r 1
64. Let r1, r2 and r are in-radius of ABD, ADC and ABC respectively
c b
r1   r ; r2   r and EF  2 r12  r22  2 r  AI
a a
 
m
 m  1 r  1 mr 1 m  mr  m  r  1  mr 1 
65. r 1 r m Cr
=  

r 1  r m Cr



m  mr mr 1 m  r  1 r !  m  r  ! 
=  m

r 1  Cr

r . m!



r 1
m 
mr m  m  r  1 ! r  1 !  m  mr mr 1  m
=  m

r 1  Cr

m!
 =
   m
r 1  C
m
C
  m  1 .
 r r 1 
66. Let the variable chord be x cos + y sin = p. Let this chord intersect the hyperbola in A and B
2
x2 y2  x cos   y sin  
The joint equation of OA and OB is  
4 8  p 

 1 cos2   2  1 sin2   2 2 sin  cos 
    x    y  xy  0
4 p2  8 p2  p2
1 cos2  1 sin2 
  2
  2
 0  p2  8 .
4 p 8 p
The variable line touches the fixed circle, thus perpendicular distance of (0, 0) = Radius
 Equation of the circle is x2 + y2 = 8
SECTION – D
5 4
C1 2  1 
67. p 7
  
C3 3  2 
68. L = circumference of unit circle = 2

69. From the figure it is clear that for arg z 
circle should
2
either lie in second quadrant or touch the positive (f(), 1)
imaginary axis.
 f(  )  1
 2  7  13  1
 2  7  12  0
34

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1 AITS-OT-(Paper-2)-PCM (Sol)-JEE(Advanced)/18

12. 6 35. 4 58. 1

2. Path difference at angular position  is d sin .

7. For resonance I10 V10 V20

11. Assume that on circular face of cylinder, a charge q of P

12. F1 = 3F and F0 = 2F1 = 6F = 60 N FB

gsin 2 g sin 

18. for block B N

21. T = T Extension …(i)

23. Initially V800 = V1000

25. 25M 25M 0 0

Cl2 O  H2O  2HOCl

28. H2C Cl H2C Cl

30. The formula of complex is:

31. Here carbon is sp3 hybridised Here carbon is sp2 hybridised

(B) CH2 CH2 CH2 CH Cl

(C) C–C bond length are different in all

(D) CH3–CH2–Cl CH2 = CHCl

In CH2 = CH – Cl charge separation is less.

33. 12N2  4H3PO2  8HN3  P4 O6  2H2 O 

34. pH range of indicator = 3.4 – 4.6

39. C3H8O3  nCH3MgI 

40. Rate  k C3H6*  (i)

C3H6  C3H6*  C3H6* 

44. Ca3  PO4 2  8Mg  Ca3P2  8MgO

Ca3P2  6H2O  3Ca  OH 2  2PH3

Mathematics PART – III

50. Any combination of 4 points gives 3 new intersection points

51. f(1  x)  f(1  x)

54. Centre of the circle is at (a, a)

58. Let x = r cos ; y = r sin 

68. L = circumference of unit circle = 2

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