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22179-Article Text-79512-1-10-20150212 PDF
22179-Article Text-79512-1-10-20150212 PDF
Key Words: Dry season, Jamuna River, Physiochemical variables, Wet season
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J. Environ. Sci. & Natural Resources, 7(1): 249 – 256, 2014 ISSN 1999-7361
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J. Environ. Sci. & Natural Resources, 7(1): 249 – 256, 2014 ISSN 1999-7361
matter. Usually, the time is taken as 5 days and the yellow color at 420nm. When the sample is
temperature 20°C as per the global standard. The colored, distil a 500mL sample with dil. NaOH and
BOD test is among the most important method in collected the distillate in an Erlenmeyer flask
sanitary analysis to determine the polluting power, containing 200 ml of 0.1 N H2SO4.. Make up the
or strength polluted water. It serves as a measure of volume of distillate to 250ml in a volumetric flask.
the amount of clean diluting water required for the Take 5-10 ml aliquot, neutralize with 0.1N NaOH
successful disposal of sewage by dilution. The test to pH 4-5, and add 2 ml nessler’s reagent .Proceed
has its widest application in measuring waste as above for measurement. Distil as above and
loading to treatment plants and in evaluating the collect only 100 ml of the distillate in an
efficiency of such treatment systems. The test Erlenmeyer flask. Titrate with 0.02 N H2SO4, using
consists in taking the given sample in suitable a mixed indicator (200 mg methyl red in 100 ml
concentrations in dilute water in BOD bottles. Two 95% ethyl or isopropyl alcohol + 100 ml methylene
bottles are taken for each concentration and three blue in 50 ml 95% ethyl alcohol), until the
concentrations are used for each sample. One set of indicator turns a pale lavender. Carry a blank
bottles is incubated in a BOD incubator for 5 days through all the steps.
at 20°C; the dissolved oxygen (initial) content (D1)
in the other set of bottles will be determined Sulphates
immediately. At the end of 5 days, the dissolved Gravimetric Method with Ignition of Residue
oxygen content (D2) in the incubated set of bottles Sulphate is precipitated in hydrochloric acid
is determined. medium as barium sulphates by the addition of
barium chloride. The precipitation is carried out
COD (Chemical Oxygen Demand) near the boiling temperature and after a period of
Procedure digestion the precipitate is filtered; washed with
COD results are reported in terms of mg of oxygen. water until free of chlorides, ignited and weighed
N/8 or 0.125 N solution of oxidizing agent is used as barium sulphates.
in the determination. Normality double the strength Chlorides
is used. This allows the use of larger samples. Procedure
Thus, each ml of 0.25 N solution dichromate is If water containing chlorides is titrated with silver
equivalent to 2 mg of oxygen. An excess of nitrate solution, chlorides are precipitated as white
oxidizing agent is added, the excess is determined silver chloride.
by another reducing agent such as ferrous Potassium chromate is used as indicator, which
ammonium sulphate. An indicator ferroin is used in supplies chromate ions. As the concentration of
titrating the excess dichromate against ferrous chloride ions Approaches extinction, silver ion
ammonium sulphate. Blanks are used also treated concentration increases to a level at which reddish
and titrated to get the correct value of COD. brown precipitate of silver chromate is formed
Nitrate (NO2- and NO3-) indicating the end point.
Procedure Calcium
The reaction with the nitrate and brucine produces Procedure
yellow color that can be used for the colorimetric To a 100 ml sample add sufficient KOH (20%)
estimation of nitrate. The intensity of color is solution to bring the pH to about 12 and precipitate
measured at 410 nm. The method is recommended Mg2+ as Mg(OH)2.Add 5-10 drops of
only for concentration of 0.1– 2.0 mg/l. All strong calconcarboxylic acid indicator (0.4% in methanol)
oxidizing and reducing agent interfere. Sodium and titrate underMagnetic stirring with 0.05M
arsenide is used to eliminate interference by EDTA solution till the color changes from wine-red
residual chlorine; sulphanilic acid eliminates the to paleblue. Alternatively, add 5 drops of murexide
interferences and chloride interference is masked indicator (0.1g stirred with 2.5 ml Deionised water
by addition of excess NaCl. High concentration of and filtered) and titrate with 0.05M EDTA solution
organic matter also may interfere in the till the color changesfrom orange to violet.
determination.
Data Processing and Analysis
Ammonia . The relevant data were processed and analyzed
Procedure through manually and for computer based analysis
To a 100mL sample, add a little NAOH to MS Excel of Office 2007 version was used.
neutralize the acid used for storage and then add 1
ml 10% ZnSO4. 7H2O followed by 1 ml 10%
NAOH. Stir and filter. (Ca, Fe, Mg, S2- are
Precipitated). Collect the colorless middle fraction,
and 1 drop of 50% EDTA mix well and 2 ml of
Nessler’s reagent (70gKI+160HgI2+160gNaOH
diluted to I liter). Shake well. Measure the resulting
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J. Environ. Sci. & Natural Resources, 7(1): 249 – 256, 2014 ISSN 1999-7361
Results and Discussions 8.4 to9.3 (in wet season). In pH average value of
samples were found 8.63 and 8.9 where the
Physical Parameters standard value 7.25 and the standard deviation is
pH 0.98 in dry season and 1.17 in wet season (Table
The higher values of pH represent that there is high 01).the permissible limit of pH for irrigation: 6.0
chloride, bicarbonate, carbonate etc. that means the −8.4 (Ayers and Westcot, 1985), 6.5 −8.5 (FAO,
water is alkaline. In Jamuna river water there is a 1992), 6.0–8.5 (ADB, 1994) or 6.0 – 9.0 (GOB,
significant variation of pH in various sampling 1997).
station in both seasons (Table 01).pH of the water
samples ranged from 8.0 to 9.1 (in dry season) and
Table 1. Comparison the physical parameters of Jamuna River water during dry and wet season
32.5 35.9
32.59±
(ºC)
129.6 109.8
130.04 109.48±39.
130.6 109.6 165 500 500 1000 < 450
±24.72 26
130.4 110
129.3 109
0.96 0.3
DO (ppm)
1.06 0.6
1.01±3. 4.0-6.0
1.1 0.3 0.45±4.28 6.5 4.0-6.0 NA NA
88 (mg/I)
0.8 0.4
1.1 0.8
33 52.6
BOD (ppm)
33.8 49
34.26± 59.04±38.2 (-) or below
32.4 50.8 5.0 NA NA NA
20.69 1 2 (mg/I)
34.4 54.4
40 56
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J. Environ. Sci. & Natural Resources, 7(1): 249 – 256, 2014 ISSN 1999-7361
2 11 2.7
(ppm)
2 831.6 731.6
(ppm)
2 969.4 873.4
(ppm)
2 251.8 284.8
(ppm)
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J. Environ. Sci. & Natural Resources, 7(1): 249 – 256, 2014 ISSN 1999-7361
the BOD, the more rapidly oxygen is depleted in water i.e. the higher amount of organic compounds
the stream. This means less oxygen is available to in water which demands higher COD and as a
higher forms of aquatic life. The consequences of result the lower quality of water for fish and other
high BOD are the same as those for low dissolved aquatic life. Where as in wet season it shows
oxygen: aquatic organisms become stressed, moderate values it refers moderate quality of water
suffocate, and die. Sources of BOD include leaves (Table 2).
and woody debris; dead plants and animals; animal
manure; effluents from pulp and paper mills, Nitrate (NO2- and NO3-)
wastewater treatment plants, feedlots, and food- Nitrate concentration is low in fresh domestic
processing plants; failing septic systems; and urban wastewater but in the effluent of nitrifying
storm water runoff. biological treatment plants nitrate may be found in
concentrations of up to 30 mg. In present study
In present study BOD values varied between 20 to Nitrate (NO2- and NO3-) concentration of sample
43 ppm in dry season and 40 to 64 ppm in wet water ranges from 78 to 98 ppm in dry season and
season (Table 01).In Comparison between average 77 to 99 ppm in wet season, this is very high in
value and standard value of BOD is showed higher respect to standard value (Table 02). Comparison
deviation (Table 01) it refers to the lower quality of between the average value and standard value of
the river water i.e. the higher rate of pollution of Nitrate (NO2- and NO3-) is shown higher deviation
water, it refers that the higher the deviation the (Table 02) refers to the lower quality of the river
lower the quality of water for fish and other aquatic water i.e. the higher amount contamination from
life. ADB (1994) and GOB (1997) proposed BOD fertilizers, municipal wastewaters, feedlots, septic
of 10 mg l−1 in irrigation water quality standards systems in water which causes higher concentration
for Bangladesh. of Nitrate (NO2- and NO3-), it refers that the higher
Chemical parameters the deviation the lower the quality of water for fish
and other aquatic life and for common uses. FAO
COD (1992) recommended threshold value (30 mg l −1).
The measure of COD determines the quantities of
organic matter found in water. This makes COD Ammonia
useful as an indicator of organic pollution in It represents the presence of fecal matter from
surface water (King et al., 2003 and Faith, 2006). latrine. In present study Ammonia concentration of
In the conjunction with the BOD test, the COD test sample water ranges from 8 to 13 ppm in dry
is helpful in indicating toxic conditions and the season and 2.1 to 3.3 ppm in wet season, this is
presence of biologically resistant organic very high in respect to standard value (Table
substances (Sawyer et al., 2003). In present study 02).Comparison between average value and
COD values varied between 86 to 112 ppm in dry standard value of Ammonia is shows higher
season and 8 to 10 ppm in wet season (Table deviation (Table 02) that refers to the lower quality
02).Comparison between average value and of the river water i.e. the higher amount organic
standard value of COD in dry season shows higher matter content.
deviation refers to the lower quality of the river
Table 3. Comparison the average value of Nitrate and Ammonia with their standard value
Parameter Average Value Standard (DoE, 2001)
Dry Wet
Nitrate (ppm) 88.04 84.83 0.1
Ammonia (ppm) 11.22 2.7 0.05
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J. Environ. Sci. & Natural Resources, 7(1): 249 – 256, 2014 ISSN 1999-7361
concentrations in the study area of both seasons are kinds of present salt as well as the soil texture and
presented. Chloride content of samples ranged the salt tolerance of crop. The suitability of surface
between 950 to 976 ppm in dry season and 850 to water for irrigation is restrictive on the effects of
891 ppm in wet season (Table 2).Comparison mineral constitutes of water on both the plant and
between average value and standard value of soil. Excessive amount of dissolved ions in
Chloride is shown the higher deviation (Table 2) irrigation water affects plants and agricultural soil
refers to the higher impurity of the river water physically and chemically, thus reducing the
which is unsuitable for common uses and aquatic productivity. The physical effects of these ions are
life. to lower the osmotic pressure in the plant structural
. cells, thus preventing water from reaching the
Calcium branches and leaves. The chemical effects disrupt
The calcium concentrations in study area ranged plant metabolism. The comparison of the river
between 243 to256 ppm in dry season and 243 to water quality in the study area with the National
255 ppm in wet season (Table 2).Comparison and International recommended guidelines for
between average value and standard value of irrigation water quality represent in Table 1.
Calcium is shown the higher deviation (Table 2)
refers to the higher impurity of the river water Conclusion
which is unsuitable for common uses and aquatic
life. Almost all the samples in the study area Among the all tested physical parameters; pH,
showed high concentration of calcium that means temperature and BOD exceeds standard level. On
those concentration falls out of range of natural the other hand, in chemical analysis it is found that
freshwater. This high concentration may be due to COD, Nitrate, Amonia, Sulphate, Cloride and
primarily domestic discharges into theriver, and the Calcium level are much higher that permissible
presence of CO2 which cause CaCO3 to dissolve. amount. The overall test results reveal that the
water of Jamuna River is suitable for irrigation.
Evaluation of surface water for irrigation Government need to take proper steps to control
purposes the effluent discharge to the river. Jamuna is a big
Irrigation water criteria depend on both the river and many cities are situated on the bank of
chemical composition and the nature of plants to be Jamuna. In this industrial era in Bangladesh, the
irrigated, soil type, climate, amount and method of government should take strict measureto maintain
irrigation and drainage. The suitability of water for of suitability of water in jamuna river for surface
irrigation can be determined by the amount and irrigation.
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