KHANDELWAL COLLEGE OF MANAGEMENT SCIENCE & TECHNOLOGY,

BAREILLY

B.Sc Ist Year Inorganic Chemistry

Assignment – 1st

(i) Explain Heisenberg’s uncertainty principle. (MJPRU 2018)

(ii) Write a short note on Afbau’s principle. (2018)
(iii) Derive the Schrodinger wave equation.
(iv) Significance of Ψ And Ψ 2
(v) Difference between orbit and orbital.
(vi) Describe the dual nature of electrons. Explain De-Broglie’s equation.
(vii) Describe Quantum Numbers.
(viii) Describe Hund’s rule and Pauli’s Exclusion principle.

Assignment – 2st

1. What is VSEPR theory? How is it useful in explaining the geometry of

the molecules? With the help at this theory, explain the geometry of NH3
and H2O molecules. (2018)
2. Describe atomic and ionic radii.
3. Discuss electronegativity.
4. Explain electro affinity. Why electron affinity of F is less than that of Cl?
5. Describe hybridization and types of hybridization.
6. Discuss M.O.T write the structure of O2--,O2---,O2+ and the order of
stability.
7. Draw M.O. diagram of any one hetronuclear diatomic molecule.(HF)
(2018)

Assignment – 3st

1. Define lattice energy. Explain how it is determined with the help of

Born-Haber cycle. (2018)
2. Define Fazan rule with suitable example. (2018)
3. Explain the diagonal relationship between Li and Mg.
4. Write S.N.-
(i) Polarization
(ii) Radius ratio rule
(iii) Co-ordination no.
(iv) Ionic structure of NaCl
(v) Hydrogen Bonding
(vi) Frenkel’s defect
 Assignment – 4st

1. Discuss preparation and chemical properties of diborane. Describe its

structure and give additional factures which support the bridge structure.
(2018)
2. What are carbides? Disuses the methods of preparation of ionic and
covalent carbides and properties.
3. What is silicates? Draw the structure of different type of silicates?
4. Write S.N. on hydrides.
5. Justify the position of s-block elements in the periodic table. Discuss their
general, physical and chemical properties? (2018)

Assignment – 5st

1. Write S.N. On
(i) Anomalous behavior of fluorine.
(ii) Anomalous behavior of Born. (2018)
(iii) Basic nature of Iodine.
(iv) Applications of noble gases. (2018)
(v) Interhalogen compounds.
(vi) Geomety of XeO4. (2018)
2. Write dawn the electronic configuration of noble gases discuss their
position in periodic table.
3. How the inert gases are extracted from air. How they are separated. Write
the preparation properties and sttucture different xenon fluoride, xenon
oxides and xenon oxy fluoride.

Assignment – (second paper)

ASSIGNMENT 1

STRUCTURE AND BONDING & MECHANISM OF ORGANIC REACTIONS

Q.1 Write short note on the following-
(a) Resonance
(b) Hyperconjugation (MJPRU-2018)
(c) Aromaticity
(d) Hydrogen bonding (MJPRU-2018)
(e) Inductive effect
(f) Mesomeric effect
Q.2 What is Hybridisation? Explain SP, SP2 and SP3 hybridisation with
example.
Q.3 What are carbocations? Explain their types and stability./ Write a
short note on carbocation with example. (MJPRU-2018)
Q.4 Write short note on the following:
(a) Carbon free radical
(b) Carbene
(c) Homolytic and Hetrolytic bond fission (MJPRU-2018)

ASSIGNMENT 2: ALKANES AND CYCLOALKANES

Q.1 Explain the following reactions of alkane formation
 Wurtz reaction,
 Kolbe reaction (MJPRU-2018)
 Corey-House reaction
Q.2 Explain the mechanism of Halogenation of alkanes?
Q.3 Write prepration and uses of chloroform. (MJPRU-2018)
Q.4 Explain Baeyer Strain theory of stability of cycloalkanes? (MJPRU-
2018)
Q.5 Write a short note on Banana bond. (MJPRU-2018)
Q.6 Explain why chair conformation of cyclohexane is more stable than
boat form? (MJPRU-2018)
Q.7 Explain the methods of formation, conformation and chemical
reactions of cycloalkanes. (MJPRU-2018)
ASSIGNMENT 3: ALKENES, DIENES AND ALKYNES
Q.1 Write short note on the following-
 Saytzeff rule
 Hofmann elimination
 Markovnikov's rule
Q.2 Give the following reactions-
 Hydroboration-oxidation
 Oxymercuration-reduction
 Epoxidation
 Ozonolysis of alkenes and alkynes
 Polymerisation reaction of alkenes and alkynes
Q.3 Explain the following: (MJPRU-2018)
(i) 2-butene is more stable than 1-butene.
(ii) Alkene is more reactive than alkyne for electrophilic addition
reactions.
Q.4 What are dienes? Explain the structure and stability of 1,3 butadiene.
(MJPRU-2018)
Q.5 Write the reactions for the following: (MJPRU-2018)
1. Acetylene from etane
 2. 1,3 butadiene from 1-butene
3. Diels-Alder reaction.
ASSIGNMENT 4: STEREOCHEMISTRY OF ORGANIC
COMPOUNDS
Q.1 What are conformations? Discuss the conformations of n-butane
Q.2 Write a short note on Walden inversion.
Q.3 What is geometrical isomerism?
Q.4 Define different types of elements of symmetry giving suitable
example.
Q.5 What is optical isomerism? Discuss the optical isomerism of lactic
acid.
ASSIGNMENT 5: ARENES, AROMATICITY, ALKYL AND ARYL
HALIDES
Q.1 What are electrophilic substitution reactions? Explain the mechanism
of nitration and Fridal Craft’s reaction in benzene./ Write a note on
Friedel-Craft’s alkylation. (MJPRU-2018)
Q.2 Discuss the mechanism of halogenation and mercuration of benzene.
(MJPRU-2018)
Q.2 Write short note on the following-
 Huckel’s rule of aromaticity (MJPRU-2018)
 Molecular orbital model of benzene/discuss the structure and
stability of benzene. (MJPRU-2018)
 Ozonolysis in benzene
 DDT and BHC. (MJPRU-2018)
 Polyhelogen compound (MJPRU-2018)
Q.4 How will you prepare the following from Benzene-
 Acetophenone
 Toluene
 Chlorobenzene
Q.5 Write the reactions for the following: (MJPRU-2018)
1. Phenol from nitrobenzene
2. Benzene from propene
3. Benzoic acid from aniline
 Bsc First Year Paper-III
ASSIGNMENT - 01

Q.1) Write the Vander Waal’s equation for ‘n’ mols of gas (MJPRU 2012,13,14,15,16)

a)What lead vander waal’s to modify ideal gas equation? (2011,14)

b)Describe the relation between critical constant and vander waal constant. (2011)

Q.2) Give maxwell’s law of distribution of molecular velocity. (MJPRU 2016)

Q.3) What are the postulates of the kinetic theory of gases? Also derive the kinetic gas
equation- PV=1/3mNC2 (MJPRU 2013,18)

Q.4) Explain “law of Corresponding States.” (MJPRU 2014,18)

Q5) Explain following with proper equation, graph in two pages----

a) Critical Temprature. What is It’s importance? (2016)

b) Collision frequency and Collision Diameter. (2013,14,15)
c) Mean Free Path. (2015)
d) Melting , Boiling point And Sublimation. (2014,15)
e) Boyle’s Temprature. (2012)
f) Calculate root mean square velocity of CO2 molecule at 1000°C and O2 at 27°C
g) Liquefaction of gases. (2016)

ASSIGNMENT-02
Q.1) What are liquid crystals? How are they classified? Discuss the applications of liquid
crystals. (MJPRU 2011,14,15)

Q.2) Differentiate clearly in between smetic liquid crystals and nematic liquid crystals. What
are cholestric liquid crystals? (MJPRU 2014)

Q.3) Discuss the structure of liquids in brief. How Parachar helpful in the elucidation of
molecular structure. (MJPRU 2018)
 ASSIGNMENT – 03
Q.1) What is a crystal? Differentiate between crystalline and amorphous solids.
(MJPRU 2015,16)
Q.2) Describe any method of determining the crystal structure. (MJPRU
2015,16,18)
Q.3) Define space lattice (2011,12,16) and unit cell.Draw the crystal structure of NaCl.
(2016,18)
Q.4) Describe the structural difference between solid, liquid and gas. (MJPRU
2011,14,18)
Q.5) Explain following―
a) Type of unit cell. (2012)
b) Miller Indices. (2012,13)
c) Laws of crystallography. (2015,16)
d) Bragg’s Equation. (2012,14,15,16)
e) Calculate the miller indices of the crystal planes for which the intercepts along the
axes are-
i) (a,b,c) ii) (a/2,2b/3,∞c) (2016)

ASSIGNMENT – 04
Q.1) What do you understand by order of reaction. Deduce an expression for the rate
constant of a second order reaction. What are the main characteristics of a second order
reaction.
(MJPRU 2013,16)
Q.2) Deduce an expression for the rate constant of a first order reaction. What are the main
character of first order reaction . (MJPRU 2015)
AND
Prove that for a first order reaction the half life period of reaction is independent of
initial concentration of the reactant. (MJPRU 2016)
Q.3) Write Arhenius equation for reaction. (MJPRU 2014,16,18)
Q.4) Energy of Activation. (MJPRU 2013,14,15,18)
Q.5) Discuss the Transition state Theory of reaction rates. Compare it with the collision
theory.
(MJPRU 2012,14)
Q.6) Factor affecting the rate of reaction. (MJPRU 2018)
Q.7) Numerical ―
a) If a first order reaction is 20% completed in 1200 sec. Calculate the time for 80%
completion of reaction. (MJPRU 2016)
b) The rate constant of a reaction at 27⁰C and 37⁰C are 1.5×10-3 sec-1 and 3.6×10-3 sec-1
respectively .Calculate the energy of activation and frequency factor (A) of the reaction.
(R= 8.32 J/K-mol) (MJPRU 2016)
 ASSIGNMENT – 05

Q.1) Discuss Hardy-Schulze rule giving example. (MJPRU 2014,13,14,18)

Q.2) What are colloids? Discuss different types of colloidal system with examples. Also write
one method for prepration of colloidal solution. (MJPRU 2015,18)
Q.3) What are lyophilic and lyophobic sols? (MJPRU 2015,16)
Q.4) Explain catalyst poisons and catalysis promoters. (MJPRU 2013,14)
Q.5) Write a short note on micelle and critical micelle concentration. (MJPRU 2014)
Q.6) Define ― (Atleast in one page)
a) Gold number. (MJPRU 2013,16)
b) Enzyme catalyst. (MJPRU 2015,18)
c) Browniun Movement. (MJPRU 2015)
d) Tyndall Effect. (MJPRU 2013,14)
e) Emulsifiers. (MJPRU 2011)