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Limbah Nuklir
Limbah Nuklir
(C) All Rights Reserved. The following article is copyrighted by the author
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of the author.
General Considerations
Alternatives for the disposal of nuclear fuel waste have been assessed by
Atomic Energy of Canada Limited (AECL). For Canada, disposal in space
and the conventional "transmutation" methods are "expensive". The
geological disposal concept has three variants: a) ice sheet disposal; b)
seabed disposal; and, c) land-based geological disposal. The ice sheet
disposal is not available in Canada while the sea-bed disposal system
presents considerable risks.
Cost Recovery ?
Only pages 77, 231 and 265 contain some paragraphs concerning this
important subject. And then, only in one of them, page 265, is it mentioned
that the utilities with nuclear generating will have enough to compensate
for the economic cost of the nuclear fuel disposal -- from $ 20 to 40 billion
1991 dollars. It is stated:
... the utilities with nuclear generating stations are including the cost of
managing used fuel in the rates currently being charged to electricity
consumers.
One is led to belive that the cost of disposal is included in the rates being
charged by Ontario Hydro, Hydro-Quebec and New Brunswick Power for
electricity. The amount charged is estimated to be sufficient to fund
implementation of the proposed disposal concept, with operation of a
disposal facility beginning in 2025. (See details in Appendix I) Yet a recent,
pre-election examination by the Government of Ontario revealed a
negligible portion of such reserve as being designated for this purpose.
The cost of the project will be approximately $75.00 to $ 150.00 per family
per year in extra electrical cost, considering the population of all Canada
and assuming that ultimately all Canadians would pitch in.
But for Ontario, New Brunswick and Quebec alone, (the provinces with
nuclear power plants) without federal assistance, new charges of
approximately $ 200.00 to $ 400.00/ year per family, or between $50.00 and $
100.00 per invoice would have to be levied. To add the costs of other
nuclear wastes would indeed tip the heavy burden to intolerable levels.
We also believe that the true cost of the proposed disposal facility is too
elevated for the Canadian consumer to accept, and too high for the federal
and provincial budgets to absorb.
The second phase involves "fuel fabrication", in which the waste actinides
are incorporated in reactor fuel elements. This could be done either
homogeneously, with the waste actinides uniformly dispersed throughout
the normal fuel, or heterogeneously with the waste actinides concentrated
in special fuel elements, sometimes referred to as "target" fuel elements;
there also exist intermediate versions.
The third step is "reactor irradiation", in which the waste actinides are
partially burnt up -- or transmuted. The scale of operation required is such
that the power reactor would have to be used to provide sufficient capacity.
These would be of any of the familiar types, especially LWRs (Light Water
Reactors) or FBRs (Fast Breeder Reactor)
The HWR (Heavy Water Reactor) CANDU is not included in this category.
The reprocessing of the fuel to recover U and Pu (and the Th fuel cycle) is
required. Recycling of the waste actinides may take many cycles since it is
not feasible to obtain adequate destruction during a single phase.
It differs from that of the normal fuel cycle in the inclusion of the
partitioning step and the
recycling of the waste actinides, which are shown dashed; in the normal
cycle the fission products (FPs) plus waste actinides go directly to
conditioning interim storage, and disposal.
It might appear from the above Figure that actinide partitioning and
transmutation would have only a small impact on the fuel cycle; but this is
not so: Recycling of the waste actinides affects all parts of the cycle.
The properties of some of the waste actinide nuclides make them difficult
to handle.
Several kilowatts of head may have to be dissipated and substantial
neutron shielding will be required necessitating remote operation. The
problems are less in homogeneous that in heterogeneous recycling, but
the decay heat is still significant in the former case, and neutron shielding
is still needed. the neutron shielding will, incidentally, also serve as
gamma-ray shielding, while remote operation serves to control alpha
hazards.
Particularly severe problem areas in the handling of the waste actinides
can be identified to be:
1) The HLW (high level waste) partitioning plant, which does not exist in the
normal cycle.
2) The fuel fabrication plant, which requires more remote operation and
maintenance, compared with remote operation and "hands-on"
maintenance in the normal cycle.
3) Fuel transport, since (a) neutron shielding and heat dissipation in the
"actinide partitioning and transmutation" case will reduce the capacity of
the transport flasks, and (b) fresh fuel must be transported in the same
flasks as spent fuel.
Estimates have been documented from two sources. The Ispra Laboratory
values for the "actinide partitioning and transmutation" cycle are $ 360/kg
HM (heavy metal) higher than those for the normal cycle, this being the
estimated cost of the partitioning step itself. The difference in the ORNL
(Oak Ridge National Laboratory) case is made up of $ 195/kg HM for
reprocessing waste treatment plus $240/kg HM for fuel fabrication waste
treatment. Agreement between the Ispra and ORNL figure is reasonable,
but it should be noted that different ground rules have been applied.
The reduction in the potential long-term hazard of the HLW and other
wastes is, of course, the incentive for actinide partitioning and
transmutation. The reduction is, however, less than might have been hoped
because the overall decontamination factors obtainable under realistic
conditions be only in the range 50-100, while the hazard reductions are
smaller again.
Since the long-term hazards are already considered to be low, there is little
incentive to reduce them further by actinide partitioning and transmutation.
Indeed, the incremental cost of introducing actinide partitioning and
transmutation appears to be unduly high in relation to the prospective
benefits.
We note again that Canada dose not have a reprocessing facility required
for actinide partitioning and transmutation. We also note that the waste
actinides from partitioning and the fuel actinides go to fuel fabrication, and
after that would be used mainly in fast reactors, which Canada does not,
nor intends to have. Effectively, this conventional transmutation procedure
would force Canada to export nuclear materials.
Because of the present low prices for uranium -- this is one of the reasons
why Canada is not interested in using recycling nuclear fuel from actinide
partitioning and transmutation process -- there are no incentives to recycle
plutonium in LWRs (light water reactor).
Therefore several states (USA, Spain, Sweden, and others) have opted for
direct disposal of the spent fuel, whereas some states still hang on with the
reprocessing of spent fuels in order to recover plutonium (France, U.K.,
Commonwealth of Independent States and Japan). Other states consider
both options e.g. Federal Republic of Germany. Initially, the recovered
plutonium was foreseen to fuel fast reactors, but because of the same
reason (low uranium price the deployment of this reactor type will be
delayed for at least another 20 to 40 years.
a) by photons
b) by neutrons
c) by charged particles
It may be appropriate to note that the current U.S. National Energy Strategy
includes four key goals for nuclear policy: a) maintain safety and design
standards; b) reduce economic risk;
c) reduce regulatory risk; and, d) establish an effective high-level nuclear
waste program.
By way of review, for the Bohr-Rutherford model of the atom, the nucleus is
composed of the heavy particles or hadron or the proton and the neutron
and surrounded by a cloud of electrons (or light particles or leptons) the
number of which depends on the atomic number (for neutral atoms) and
also the valence state (for ionized atoms). Alpha particles are Helium
nuclei, 4He.2 consisting of two protons and 2 neutrons and beta particles
are electrons (negative charge) and positrons (positive charge) and gamma
rays, the short wave length of the electromagnetic radiation band and the
proton is a hadron. Alpha particles and protons are strongly interacting
particles as are all hadrons.
The alteration of decay rates by extra nuclear processes may not be truly
random and requires a new theoretical model. As these effects occur, the
term nuclear may need to be expanded to reactions and processes
involving the entire atom and even multi-atom crystal matrix forms rather
than just mass-energy changes in only the nucleus.
Not too well known is a quite prodigious body of work on the persistent
effects of chemical states and physical environment on the deviation in the
lifetimes of nuclear decay rates from the accepted decay law. Theoretical
as well as experimental research has been conducted. In 1947, R. Daudel
and E. Segré predicted that under certain conditions a dependence of the
decay constant on the chemical and physical environment of the nucleus
should be observable and subsequent to these predictions such a
dependence was experimentally observed (with R. F. Leinzinger and C.
Wiegand) in the K capture decay of 7Be and the internal conversion decay
of the 99m isomeric state of Technetium.
n ® p + e- + n (1)
p + n « p + n' (2)
At this time, Brown's Gas generators are mass produced in the Bautou, a
major research city in the People's Republic of China by the huge
NORINCO factory which also manufacturers locomotives and ordnances --
and services the nation's nuclear industry complex. Most of these
generators (producing up to 4,000 litres/hour/2.4 water at 0.45 MPa with
power requirements ranging from 0.66 kW up to 13.2 kW) are marketed for
their superior welding and brazing qualities, costing between $ 2,000 and $
17,000. Some units have been used for the decontamination of radioactive
materials since 1991. In general, Brown's Gas generators produce between
300 and 340 litres of Brown's Gas per 1 kW energy DC current
approximately and one litre of water produces 1.866.6 approximately litres
of gas. A generator which produces 10,000 litres per hour has been built
specifically for the reduction of nuclear waste.
On August 24, 1991, Baotou's Nuclear Institute # 202 released a report, The
results of experiments to dispose of radiation materials by Brown's Gas
which establishes that experimentation on Cobalt 60 radiation source
decreased radiation by about 50% or half-life of radiation -- but sometimes
more radiation is decreased which needs investigation of possibilities for
decreasing more of the radiation in single treatments of exposure to
Brown's Gas flame, lasting only a few minutes, in the samples as described
in the table below.
The Brown's Gas generating units that produced such effects are not
expensive -- a far cry from the multi-million processes tabled by AECL.
They are powered by low energy requirements and require only small
volumes of water, at most a few liters per hour as fuel. Furthermore, the
training required for operation is minimal.
The Hon. Bedell has reported, "it has been my good pleasure to witness
experiments done by Prof. Yull Brown in which it appeared to me that he
significantly reduced the radioactivity in several nuclear materials. Under
the circumstances, I believe it is very important for our federal government
to completely investigate Dr. Yull Brown's accomplishments in this area."
On August 6, 1992, almost a year after the Chinese nuclear report, Prof. Yull
Brown made a special demonstration to a team of 5 San Francisco field
office observers from the United States Department of Energy, at the
request of the Hon. Berkeley Bedell. Cobalt 60 was treated and resulted in
a drop of Geiger readings from 1,000 counts to 40 -- resulting in radioactive
waste residue of about 0.04 of the original level. Apprehensive that
somehow the radioactivity might have been dispersed into the ambient
environment, the official requested the California Department of Health
Services to inspect the premises. The health services crew found no
radioactivity in the air resulting from this demonstration nor from another
repeat demonstration held for their benefit.
This sequence of experiments was monitored by the Hon. Daniel Haley, the
legislator who established the forerunner New York State Energy Research
and Development Agency.
Prof. Brown, during his 27 years of studying water and its atomic structure,
experimenting with disassociation of water into its constituent parts of
hydrogen and oxygen has noted that there are many variations of the
atomic structures of the various waters dependent on the mixing of the
three hydrogen isotopes (1H - protium, 1H2 - deuterium, 1H3 - tritium)
which combine into six combinations of hydrogen and the six oxygen
isotopes (8O14, 8O15, 8O16, 8O17, 8O18, and 8O19 ) -- or practically, 36
types of water -- 18 are stable and 18 have short life.
Now, because we have all of these types of water, we could have 36 types
of Brown's Gas, and much more with special modifications of the gas; at
the moment only a few are under investigation. His studies have led to the
observation that the anomalous behaviour of water depends on the ability
of water to modify energetics and physicochemical properties of the
various permutations of the hydrogen/oxygen isotopes. As is known the
lifetime, modes of decay and thermal neutron capture cross-sections vary
significantly between these isotopes; likewise, Brown has seen the various
stages of his gas offer very different effects. He has found that he can
modulate a number of suitable mixes for his technology, thus providing an
engineering tool in decontamination of nuclear wastes.
This type of experiment, which may have been highly dependent on the a
mix of waveform signaling, involving superimposition of square waves
containing specific repetition rates developed by Dynamic Engineering of
Sacramento, California, indicates that research and development can
determine the fine-tuning of special non-Hertzian procedures for the
transmutation of specific isotopes.
Cost: less than $ 1,000 for a coil. Duration: about 24 hours. Result: up to 97
% reduction of radioactivity.
APPENDIX I
Economic Considerations
The combined declared cost for the disposal concept can range from $
18.85 to $ 19.91 billion (1991 dollars)+ financing, tax and non-routine
factors that could double the cost up to $ 40 billion.
APPENDIX II
The Buffer
The container would be separated from the rock by a dense buffer material,
such as compacted mixture of sand and bentonite. (Page 118)
There are advantages and disadvantages for both methods. If the buffer
were compacted in place, the sequence of emplacement activities would be
to place and compact all or most of the buffer material, drill holes in the
buffer large enough to accept the disposal containers, place the containers
in these holes, and close the holes by compacting more buffer material
above the container. The potential for worker exposure to radiation would
be lower than if the buffer were placed and compacted around a preplaced
container. Also, the potential for damaging a container during the
compaction process would be reduced. The general procedure would be
suitable for both the in-bore hole and in-room emplacement options. A
detailed procedure would include provisions for quality control.
Bibliography
General Considerations
and
Appendix I, II
Conventional Transmutation
OECD Nuclear Energy Agency. Actinide and fission product separation and
transmutation. Proceedings of the Information Exchange Meeting, Mito
City, November 6-8, 1990. OECD # 37290. 1991.
Advanced Transmutation
Brown, Yull. Welding. U.S. Patent 4,014,777. March 29, 1977. ["The invention
also relates to atomic welding to which the mixture {of hydrogen and
oxygen generated ion substantially stoichiometric proportions} is passed
through an arc causing disassociation of both the hydrogen and oxygen
into atomic hydrogen and oxygen which on recombination generate an
extremely hot flame."]
Puharich, Andrija [Henry K.]. Method and apparatus for splitting water
molecules. U.S. Patent 4,394,230. July 18, 1983.
Smith, Wilbert B.. The new science. Ottawa. The Keith Press. 1964. 72 p.
Yull Brown's Gas. Planetary Association for Clean Energy Newsletter. Vol. 6
(4), July, 1993. p. 10 - 11.
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Last updated: 01-11-2006 /// 04-17-2007