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 sa lai. sala
i .
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sa salai
.
sal
ada ada ada a d a a da
w w.P w w.P w w.P w w.P w w.P
w w w w w
rg ✁✂✂✁✄ ☎✆✝✞ ✟✠✆✡✝✟
rg ✠☛✆✂☞✄✆✌☞✁✄ rg ✍✎✏✑✒ SHANMUGAM
rg S
STD - XIIlai.O i . O
CHEMISTRY ANSWER i
KEY. O i . O
a s a a s ala a s ala St.JOHN’S MHSS
as ala CHENNAI -116 asal
PORUR
d d PARTP-aI d d d
w .Pa w .Pa w . w .Pa w .Pa
ww I. Choose the w
w
best answer ww ww 10x1=10 w
w
1. b) Al2O
i rg 2O ( correct answer is.OAlr2gO3.nH2O )
.O3.2H i i.O rg i.O rg
2.d sala
a c) non-metals d asala d a sala d a sala d asa
l
a a a a a
w.P w.P w.P w.P w.P
ww 3. d) ability to form ww p-p -bonds with itselfww ww ww
d) I 127Org
4.
l a i . la i .Org l a i .Org l a i .Org
5.adas
a
d) 52.67 d a sa d a sa d a sa d a sal
a a a a
w w.P6. d) Gementricalwisomerism w.P w w.P w w.P w w.P
w w w w w
7. b) London
i . O rgforces i .Org i .Org i .Org
8. as l a
c)aAssertion is true reason l a
sisafalse sa l a sa l a sal
a d d a d a d a d a
w.P9. a) 1- (iii) , 2-(iv)w,w3-(i).Pa, 4-(ii) w.P
a
w.P
a
w.P
a
w w w w w w w w w
10. d) nitro cellulose
g .Org .Org .Org
l a i.Or sulphoxide l a i l a i l a i
11. b)aDimethyl
d a s d a sa d a sa da sa d a sal
a a isabook answer is but-3-ene-1-oic
a a
w w.P12. a) but-3-enoic w w.(Pis correct ) but optionw(d)
acid w.P w w.P acid
w w.P
w 13. c) Schiff base
w w w w
g g g g
14. i.Ordigestive systems donot icontain
a) Human .Or the necessary enzymei.O r cellulase to hydrolysei.cellulose
called Or
sala sala sala sala sal

Padasalai
ada b) Chloroxylenol and -Terpineol
ada da da da
.Pa .Pa .Pa
15.
w.P w.P wPART - II w w
ww ww ww ww ww
.Org .Org .Org .Org
II. Answer any 6 questions( Question no.24 is compulsory 6 x 2 =12
l a i l a i l a i l a i
16.das a
Sodium a
ethyl xanthate which
d saacts as a collector isdalso
a saadded d a sa d a sal
a a .Pa carbonate etc w.Pa a
w w .P Depressing agents w w.Psuch as sodium cyanide, w wsodium w w w.P
w w w w w
17. Uses of Borax:
g .Orgof coloured metal ions .Org .Org
l a i.Oris used for the identification
l a i l a i l a i
d a s 1.aBorax
d a sa d a sa d a sa d a sal
a 2. In the manufacture .Paoptical and borosilicate Pa enamels and glazes
.glass, .Pfora pottery .Pa
w w .P w w w w w w w w
w w as a flux in metallurgy w
3. It is also used w
and also acts as a preservative w
18. Inter ihalogen
l a .Org compounds: lai.Org la i .Org l a i .Org
d a a halogen combines awith
sEach d sa other halogens to form d aasaseries of compounds dcalled
a sa inter halogen d a sal
a a a a a
w w.P compounds. w w.P - ClF, BrF3 , IF5 ww.P
example w w.P w w.P
w w w w w
19. k = AeO rg
-Ea/RT
k = rg
rateOconstant Org factor
A = pre-exponential
i.O rg
s a lai. sala
i.
sala
i.
sala sal
ada Ea
.Pa
da= a same units as RxT)
activation energy (indthe
.Pa .Pa
da ada
w.P w ww ww w . P
ww ww R = universal w
gas constant T= absolute w
temperature (in Kelvin). ww

l a i . Org l a i . Org l a i . Org a i .Org

20. s
a a is a solution whichaconsists
Buffer sa sa acid and its conjugate
of a mixture of a weak
a a
l
a (or) a weak base asal
sbase
d d d d d
w .Pa and its conjugatewacid. .PaThis buffer solution resists
w .Pa drastic changes in itsw.pHPaupon addition of a small w .Pa
ww quantities of w w (or) bases, and this ability
acids ww is called buffer actionww ww
Basic buffer rg solution : a solution rcontaining
g a weak base and rg its salt.
l a i . O l a i . O l ai . O la i .Org
d a a
sExample d a sa NH4OH and NHd4 aClsa
: Solution containing
d a sa da sal
a a a  a a
w w.P21. Faraday’s Laws w wof.Pelectrolysis : First w w.P
Law
w w.P ww.P
w w w w w
SHANMUGAM S St.JOHN’S MHSS PORUR CHENNAI -116 Mob:9841945665
rg .Org .Org .Org
alai.O a l ai la i l a i
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Send Your Questions
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sa salai
.
sal
ada ada ada a d a a d a
w w.P w w.P w w.P w w.P w w.P
w w w w w
✓✓✔ Alcoholysis rg : In presence of a ilittle acid, methyl acetate is cleaved
rg rg by ethyl alcohol toi.Oform
rg ethyl
i . O . O i . O
sala sala sala sala
acetate
d a da d a d a d a sal
a a a a a
w w.P w w.P w w.P w w.P w w.P
w This is calledw‘ trans esterification’. w w w
g rg rg rg
23. i.Or
V itamin: i.O i.O i.O
da 1. V sala sala
da in plants and takenPby
itamins are synthesized a
danimals sala
chiefly through a da
diet. sala das
al
w .Pa P a
w. coenzymes or a constituents . a . P . P a
ww 2. Mostly theseware
w w ww of coenzymes. www w ww
Hormone:
1. Hormones
l a i . Org are secreted mostly
l a i . Obyrgendrocrine glands and
l a i . rg by neurosecretory icells
some
O l a . Orgof animals.
d a s2.aMostly these are excitatory,
d a sa sometimes inhibitory d a sanever act as coenzyme.“
but
da sa d a sal
a a a a a
w w.P24. Aniline w w.P w w.P w w.P w w.P
w It does not underw go F riedel -Crafts reaction w (alkylation and acetylation) w we know aniline is basic w in
.Org substitution reaction.
it donates its lone pair torg
.Org .O g
nature and the lewis acid AlCl3 to form an adduct which inhibits rfurther the
l a i l a i .O l a i l a i
sa
electrophilic
da sa sa sa sal
a ada a da ad a a da
w.P w . P w.P w.P w.P
ww ww w
w - III
PART ww ww
g g no.33 is compulsory)g .O=r18g
i.Or any 6 questions( Question
III. Answer i.Or i.Or 6 xi3
a sala das
ala asa
la
asa
la
as al
w . Pad w .Pa w. Pad w. Pad w. Pad
ww 25. ww ww ww ww
i.O rg i.O rg i.O rg i.Or
g
sala sala sala l a sal

Padasalai
s a
da da da da da
w .Pa w .Pa w.Pa w.Pa w.Pa
ww ww ww ww ww
i.O rg i.O rg i .Org i.O rg
a sala a sala a sa l a
a sala as al
w . Pad w. Pad w. Pad w. Pad w. Pad
ww ww ww ww ww
i.O rg i.O rg i .Org i .Or g
s a la s a l a sa la sa l a s al
a ada ada a ada
w. Pad w.P w .P w. Pad w .P
ww ww ww ww ww

l a i .Org la i .Org l a i .Org l a i .Org

26.dasW ahen dissolved in water, d a a mono (H SO .H O)
itsforms d a a dihydrates (H SO .2H
sand d a s2aO) and the d a sal
a reaction is exothermic. a 2 4 a 2 2 a4 a
w w.P w w.P w w.P w w.P w w.P
w w w w w
C6H12O6 + H2SO4. 12C + H2SO4.11H2O
i . O rg i . O rg i . O rg i . O rg
l a
i)ahybridiz sp3ads2al
a l a l a l
27. as
a d ation :
a d a d asa a d asa a d asa
w.P w.P w.P w.P w.P
ww ww : Oxalato is a negative
ii) N ature of ligand
ww weak field ligand (oxalate ww anion is a bidentate ligand)
ww
iii)Geometry : octahedral
i . O rg i . Org i . Org i .Org
28. s a l a
Examples for a z ero order l a
sareaction: sa l a sa l a sal
d a
a 1. P hotochemical reaction d a
a between H and I .Pa d a a d a a d a
w w.P w w.P 2
w w2 w w.P w w.P
w w w w w
2.Decomposition of N 2O on hot platinum surface

l a i .Org of acetone in acidlamedium

i .Org is zero order withlarespect
i .Org to iodine la i .Org
sal
3.Iodination
d a sa d a sa da sa d a sa d a
a a a a a
w w.P w w.P
SHANMUGAM S w w.PPORUR CHENNAI -116wMob:9841945665
w.P ww.P
w w St.JOHN’S wMHSS w w

l a i .Org l a i .Org la i .Org l a i .Org

a Send Your Questions a sa id - padasalai.net@gmail.coma al
das das & Answer Keys to our daemail das das
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i
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. i.
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sa salai
.
sal
ada ada ada .Pa
d a
.Pa
d a
w w.P✕✖✗ Characteristics w w .P
w w.P
ww w w
w w of Chemical adsorption w w w
.Org .Org .Org .Org
1. It is very slow
la i l a i l a i l a i
d a a
s2.Monolayer d a sa is formed
of the adsorbate
d a sa d asa d a sal
a Pa a a a
w w.P 3.It is very specific
w w.depends on nature of w w.P and adsorbate. ww.P
adsorbent ww.P
w w w w w
30.
i . O rg i . O rg i . O rg i . O rg
l a l a l a l a l
a d asa a d asa a d asa a d asa a d asa
w.P w.P w.P w.P w.P
ww ww ww ww ww
i.O rg .Org i.O rg rg
sala sa la i
sala s alai.O al
a da a a as
w. Pad w .Pa w.Pad w. Pad w. Pad
ww ww ww ww ww
i.Org i.Org i.O rg i .Org
s a l a s a l a s a l a sa l a al
a a a ada as
w. Pad w.Pad w. Pad w .P w.Pad
ww ww ww ww ww
i.O rg rg .Or g .Org
sala a lai.O l ai l a i
sal
a d a a da s d asa
a chloroform and alcoholic a d a sa
a d a
w w.P31. i) Aliphatic (or) w w.P primary amines react
aromatic
w w.Pwith
w w.P KOH to give isocyanidesw w.P
w (carbylamines), w which has an unpleasant w smell. This reaction is known
w as carbylamines test.wThis test
used to identify the primary amines.
i . O rg i .O rg i . O rg i . O rg
la a
sal acid to give ethylddiazonium
sal a sal a sal

Padasalai
ii)aEthylamine reacts with nitrous chloride, which is unstable and it is
a d asconverted a d a a a a da a d a
w.P w.P w.P w.P w.P
to ethanol by liberating N 2 .
ww 32. ww ww ww
The monomer is tetrafluroethylene. W hen the monomer is heated with oxygen (or) ammonium ww
rg under high pressure, Teflon
persulphate
i.O rg is obtained.
i.O rg i.O rg i.O
ala ala ala sala al
das das das da
Pad
as
w .Pa w .Pa w .Pa w. Pa w.
ww ww ww ww ww
It is used for coating articles and preparing non-stick utensils.
la i. Org l a i . Org la i .Org l ai .Org
33.
a sAa 2- propanol , B sa1- propanol sa sa sal
Pad ada a d a a d a a d a
w w. w w.P - IV.P
PART w
w w w.P w w.P
w w w w w
IV . Answer all the questions 5 x 5 = 25

l a i .Org alum la i .Org la i .Org l a i .Org

sal
34. a) i) Potash 3M
a s a a s a a s a a s a a
a d ad a d a d a d
w w.P w w.P w w.P w w.P w w.P
w w w w w
i . O rg i . O rg i . O rg i . O rg
l a l a a
sal - Crystalline formdasal a l
a d asaii) a)- sulphur - aCrystalline
d asa form b) d
a -asulphur
a 2M dasa
a
w.P .P .P
ww - Amorphous formwwwd) colloidal sulphurw- w w.P w.P
ww c) - w
sulphur Amorphous form ww
.Org .Org .Org .Org
(OR)
l a i l a i l a i l a i l
d a sb)ai) any five differencesda sa lanthanoids anddactinoids
between a sa d a sa ✘✙ dasa
a a a a .Pa
w w.P35. a) LimitationswofwV .P BT i ) 1. It does w
not w.P the colour of the complex
explain w w.P w w
3M
w w w w w
2. It considers only the spin only magnetic moments and does
i . O rg i. O rg i . O rg i .Org
sa l a sa l a
not consider the other l a
components
sa of magnetic la
moments.
sa sal
a d a a d a a da a d a da
w.P w.P series.
ii) spectrochemcial w.P w.P w2M.Pa
w w w w w w w w w w
SHANMUGAM S St.JOHN’S MHSS PORUR CHENNAI -116 Mob:9841945665
l a i .Org l ai .Org la i .Org l a i .Org
a Send Your Questionsa sa id - padasalai.net@gmail.com
a al
das das & Answer Keys to our
daemail das das
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i
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. i.
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sa salai
.
sal
ada ada ada a d a a da
w w.P w w.P w w.P w w.P w w.P
w w w w w
(OR)
la i .Org la i .Org l a i .Org l a i .Org
d a sa da sa d a sa d asa d a sal
a b) i) Number of atoms a a a a
w w.P w w.P in a fcc unitcell ww.P w w.P w.P
2M
w
w w w w w
ii)la i .Org between pH andlapOH i .Org a i . O rg
a i . O rg
a s a Relation
a s a a s al a s al 3M
asa
l
a d a d a d a d a d
w.P w.P w.P w.P w.P
ww ww ww ww ww
i.O rg .Org i.O rg rg
sala sa la i
sala s alai.O al
a da a a as
w. Pad w .Pa w.Pad w. Pad w. Pad
ww ww ww ww ww
i.Org i.Org i.Org i .Org
s a l a s a l a s a l a sa l a al
a a a ada as
w. Pad w.Pad w. Pad w .P w. Pad
ww ww ww ww ww
i.O rg rg .Or g .Org
sala a lai.O l ai l a i al
a da s asa a sa as
w . Pad w .Pa w. Pad w. Pad w. Pad
ww ww ww ww ww
i.O rg i.O rg i.O rg i.Or
g
sala sala sala l a sal

Padasalai
s a
da da da da da
w .Pa w .Pa w .Pa
w w .Pa .Pa
ww 36. ww product of a compound
a) i)The solubility ww is defined as the product
wwof the molar concentration
ww 2M
rg
of the constituent rgto the power of its stoichiometric
ions, each raised rg rg
co – efficient in a balanced
s a lai.O s a lai.O s a lai.O sala
i.O al
da
equilibrium equation.
ada a a as
w .Pa ii) ECu2+ /Cu= 0.34Vw.Pand Fe2+ /Fe = -0.44 . w.
Pad . Pa d
3M. Pad
ww ww
E
ww w ww w ww
N o we can’ t store copper sulphate in an iron vessel. Iron is more reactive than copper and it will
g
.Orcopper rg
.Osolution. rg solution in an ironi.O
.OCuSO rg
la i
displace from its sulphate
l a i la i
N o,we can’ t store
l a vessel.Because
d a sa d asa d a sa 4
d a sa d a sal
a iron is more reactive a copper.
than a a a
w w .P w w.P w w.P w w.P w w.P
w w w (OR) w w
i.Org affecting electrolytic
b) i) Factors Orgconductance
i . i .Org i .Org 3M

d a sala a
1) Solvent of higher dielectric
d
la
sa constant show highdconductance
a sa la
in solution dasa
l a
d a sal
a a .PaV iscosity of the medium. a a
w w.P 2) Conductance w wis.Pinversely proportionalwtowthe w w.Pi.e., conductivity ww.P
w w w w w
increases with the decrease in viscosity.
i . O rg i . O rg i . O rg i . O rg
l a l a l a l a l
a d asa3 )If the temperatureaofdathe saelectrolytic
a d asa conductance also
solution increases,
a d asa
increases.
a d asa
w.P ii) Peptisation: w.P w.P w.P w2M.P
ww ww ww ww ww
By addition of suitable electrolytes, precipitated particles can be brought into colloidal state.
rg
i.O is termed as peptisation rg rg rg
The
alaprocess lai.O and the electrolytelaadded
i.O is called peptising or .O
laidispersing agent.
al
as asa das
a as a as
w. 37.Pad w . P a d
w .Pa .Pad .Pad
ww ww colloids or sols definite
a) i) In lyophillic ww between dispersionwww
wwattractive force or affinitywexists 2M
medium
g and dispersed phase. Examples:
g sols of protein g
and starch.
i.O r i.O r i .Or i.O rg
s a l a s a l a sa l a sal s a la
P ada SHANMUGAMa d a S St.JOHN’S MHSS a da a d a a da
w.P w.P w.P w.P
PORUR CHENNAI -116 Mob:9841945665
w .
ww w w w w w w w w

l a i .Org l ai .Org la i .Org l a i .Org

a Send Your Questions a sa id - padasalai.net@gmail.com
a al
das das & Answer Keys to our daemail das das
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. i.
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sa salai
.
sal
ada ada ada .Pa
d a
.Pa
d a
w w.P w w .P
w w .P
w w w w
w w reaction
ii) K noev enagal w w w 3M

la .Org
Benzaldehyde
i la i .Org acid in presencelaof
condenses with malonic
i rg
.Opyridine l ai .Org
forming cinnamic acid,

d a saP yridine act as the basic

da a
scatalyst. d a sa d asa d a sal
a a a a a
w w.P w
Rosenmund reductionw.P w w.P w w.P ww.P
w w w w w
Aldehydes can be prepared by the hydrogenation of acid chloride, in the presence of palladium
rg g rg reduction.
i.Orreaction is called Rosenmund rg
sal ai.O by barium sulphate.aThis
supported
sal ai.O sal ai.O sal sal
da da da da da
w .Pa w .Pa (OR)
w .Pa w .Pa w .Pa
ww b) i) Test to w w
differentiate alcohol and w w
phenols ww ww3 M
1) P henol
l a i . Orgreact with benzeneldiazonium
a i. Org chloride to formlaai.red
Orgorange dye, but ethanol
l a i . rg
Ohas
a sano reaction with it. a sa a sa a sa a sal
w. Pad a d
w.P colouration with neutral
2) P henol gives purple
a d
w.Pferric chloride solution,
d
.Pa do not
walcohols w.P
a d
w w w w w w w w w w
give such coloration with F eCl3 .
g g rg .OrN gaOH.
i.Or reacts with N aOHatolagive
3)aP lahenol i.Orsodium phenoxide.aEthyl
l a i.Oalcohol l a i
d a s d a s d a s does not react
d a sa with
d a sal
a ii) Phthalein reaction: a a a a
w w.P w w.P w w.P w w.P w w.P
w w w w w
On heating phenol with phthalic anhydride in presence of con.H2SO4, phenolphthalein is obtained

i.O rg rg .Or g .Org

sala a lai.O l ai l a i al
a da s asa a sa as
w .Pad w .Pa w. Pad w. Pad w. Pad
ww ww ww ww ww
i.O rg i.O rg i.O rg i.Or
g
sala sala sala l a sal

Padasalai
s a
da da da da da
w .Pa .Pa .Pa .Pa .Pa
ww 38. ww states that during thewoxidation
a) i)Popoff ’s rule.It
w
w ww ketone, a (C– CO) bond
of an unsymmetrical
w w wwis w
cleaved in such a way that the keto group stays with the smaller alkyl group.
i.O rg i.O rg i .Org i.O rg
a sala a sala a sa l a
a sala as al
w . Pad w. Pad w. Pad w. Pad w. Pad
ww ww ww ww ww

la i.Org l a i.O rg
la i .Org l ai .Or g
a sii)a retains diaz o group as a sa sa s al
Pad .Pa
d P ada Pad
a
P ada
w. w w . w. w .
ww w w ww ww ww
i.O rg rg rg .Org
sala s a lai.O sala
i.O
sa l a i al
a ada a a as
w . Pad w.P w. Pad w. Pad w. Pad
ww w w ww
(OR) ww ww
b) i) rg rg rg rg
s a lai.O sala
i.O
sala
i.O
sala
i.O
sal
ada .Pa
da
.Pa
da
.Pa
da ada
w.P w w w w . P
ww ww ww ww ww
i.O rg i.O rg i.O rg i.O rg
a sala a sala da sala a sala as al
w. Pad . Pad .Pa . Pad . Pad
ww w ww w ww w ww w ww
ii) Antihistamines : Examples -Cetirizine,levocetirizine, desloratadine, brompheniramine

l a .Org
Terfenadine
i l a i.Org l ai .Org la i .Org
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