Mula Education Society’s

Arts, Commerce & Science College, Sonai.

Department of Chemistry (P.G.)

ACA – R -17 Academic Year: 2019-20

Rev : 00 Midterm Examination
Semester: III
Date:
2727/10/2017
Class: M.Sc.-I
(Semester – III) CREDIT SYSTEM (2019 Pattern)
Subject: CCTP-3, CHO - 150: Organic Chemistry
Date: 17/09/2019] [Time: 1 Hours] [Max. Marks: 20]
Instructions to the candidates:
1) All questions are compulsory.
2) Figures to the right indicate full marks.
3) Answers to the two sections should be written in separate answer books.

Section-I
Q1. Write the reactions with mechanism (any 2) (4)
a. Knorr pyrrol synthesis b. Paal knor Pyrrole synthesis c. Hantzsch pyrrole synthesis
Q2. Write reactions of pyrrole (3)
Q3. Write product with mechanism (3)
H
N

a. SO2Cl2

CHCl3
b. NaOH
N
H

HNO3
c.
H2SO4
N
H

Section-II
Q.4) Attempt the Following 03 Marks
1. Phenyl thioethyl chloride react 600time faster than 1-chloropropan.

2. Define the carbocation, with suitable example.

3. Define the Favorskii rearrangement, with suitable example
Q.5) Write the short note on. (Any 2) 04 Marks
1. Short Note on Non- Classical carbocation?
2. Explain the Benzil-Benzilic acid rearrangement with example and mechanism.
3. Define the Fries Rearrangement with example and mechanism.

4. Explain the Hoffmann rearrangement with example and mechanism.

Q6.) Suggest the mechanism (Any 1) 03 marks
Ph Ph O H
H
a. Ph C C H Ph C C H
-H2O

OH OH Ph
O OH
O

Cl

b. NaOH