Sec: SUPER CHAINA WAT-36 Date: 11-01-20

Time:3hrs 2012_P1 Max.Marks:210

KEY SHEET

PHYSICS
1 D 2 C 3 B 4 C 5 B

6 C 7 A 8 C 9 D 10 D

11 D 12 AB 13 D 14 A 15 BC

16 2 17 3 18 2 19 4 20 2

CHEMISTRY
21 D 22 B 23 C 24 B 25 C

26 C 27 A 28 C 29 B 30 D

31 AB 32 AC 33 ABD 34 ABCD 35 CD

36 0 37 4 38 5 39 0 40 6

MATHS
41 B 42 A 43 B 44 D 45 C

46 A 47 D 48 D 49 C 50 C

51 AB 52 ACD 53 ABCD 54 AB 55 BC

56 5 57 8 58 2 59 8 60 2
Narayana IIT Academy 11-01-20_SUPER CHAINA_JEE-ADV_2012-P1_WTA-36_Key&Sol’s
SOLUTIONS
PHYSICS
11. Conceptual
12. Conceptual

13.
Ep  0

 Q  q  q  q Q  q (Q  q )  Q  q  
k        0
 2 0 2 0 2 0 2 0 2 0  2 0  

14. Conceptual
15. Conceptual
19.   2 1  cos  

 b 
 2 1  
 R b 
2 2

Q 
 
4 0

20.    E. ds

CHEMISTRY
OH Cl I
SOCl2 NaI Alc KOH
pyridine Acetone 
21.
22.

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Narayana IIT Academy 11-01-20_SUPER CHAINA_JEE-ADV_2012-P1_WTA-36_Key&Sol’s

23. Given reaction follows SN1 mechanism, carbocation stability increases the rate of
reaction
24. Alcohols are having hogher boiling point than ethers
Br
OH
O OH
Na
H Br
Dry Ether

CH 2Br CH 2Br
25.
26. Conceptual
27. PCC is the best for converting alcohol to corresponding carbonyl compound
O O O
Br Br

28. H-

29. H 2O will open the cyclobromonium ion where partial carbo cation is more stable
30. it is an an Electrophilic substitution reaction
-NHCOCH3 is stronger activating group than –CH3
31.

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Narayana IIT Academy 11-01-20_SUPER CHAINA_JEE-ADV_2012-P1_WTA-36_Key&Sol’s
32.

33. In Williamson ether synthesis

34.

35. LiA1H 4 can reduce the ester, acid chloride and aldehyde in to alcohol

BH3 can also reduce the carboxylic acid in to alcohol

NaBH 4 can reduce the alddehyde in to alcohol

Raney Ni can also reduce the aldehyde in to alcohol

36. DU of the given molecular formula is 0 so we can’t construct the cyclic ethers
37.

38.
MgBr
H3C + HCHO H3C OH
OH

H3C MgBr CH3CHO CH3

+ H3C
OH

H3C MgBr CH3CH2CHO CH3

H3C

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Narayana IIT Academy 11-01-20_SUPER CHAINA_JEE-ADV_2012-P1_WTA-36_Key&Sol’s
H3C CH3

MgBr + HCHO OH
H3C
H3C O CH3
H3C MgBr + H3C OH
H3C CH3
CH3
39. Acid catalised hydration leads to rearrangement & X is 30 alcohol
HBO gives anti markonikov’s product & Y is 10 alcohol
OMDM gives markonikov’s product & Z is 20alcohol
Cl Cl
Cl
Cl
R+S
40. R+S

MATHS
41. (B)
x y 1
Equation of any circle through (0, 0) and (1, 0) ( x  0)( x  1)  ( y  0)( y  0)   0 0 1  0
1 0 1
 x2  y 2  x   y  0
If it represents C3 , its radius =1
 1  (1 / 4)  ( 2 / 4)     3

As the centreof C3 , lies above the x-axis, we take    3 and thus an equation of C3
is x 2  y 2  x  3 y  0 Since C1 and C2 interest and are of unit radius, their common
tangents are parallel to the joining their centres (0, 0) and (1/ 2, 3 / 2) .
So, let the equation of a common tangents be 3 x  y  2  0
k
It will touch C1 , if | | 1  k  2
3 1
From the figure, we observe that the required tangent makes positive intercept on the
y-axis and negative on the x-axis and hence its equation to 3 x  y  2  0
42. (A)
T  S1
i.e., xx1  yy1  ( y  y1 )  x12  y12  2 y1

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Narayana IIT Academy 11-01-20_SUPER CHAINA_JEE-ADV_2012-P1_WTA-36_Key&Sol’s
Passes through (0, 0)
 x2  y 2  y  0
43. (B)
a2
m  A(a, o)on (1) 
a 2  b2
b2
n  (o, b) on (1) 
a 2  b2
d  a 2  b2  m  n
44. (D)
1
The normal at P (at12 , 2at1 ) is y  xt1  2at1  at13 with slope say tan   t1  . If it meets
3
7 2
. Then angle  between parabola (tangent at
curve at Q (at2 2 , 2at2 ) then t2  t1  
3 t1
1
t1 
t2 1
Q) and normal at P is given by tan   
t 2 3
1 1
t2
 1 
   tan 1  
2 3
45. (C)
Equation of a tangent to the parabola y 2  4 x is y  mx  1 / m. it will touch the circle
0  m(3)  (1 / m)
( x  3)  y 2  9 whose centre is (3, 0) and radius is 3 if 3
1  m2
Or if (3m  1/ m)2  9(1  m2 )
Or if 9m 2  6  1 / m 2  9  9m 2
Or if m 2  1 / 3, i e. m
.   1/ 3
As the tangent is above the x-axis, we take m  1/ 3 and thus the required equation is
3 y  x  3.
46. (A)
Let P ( at12 , 2at1 ); Q ( at22 , 2at2 )
Normals at P & Q on the parabola intersect on the parabola  t1t2  2
at12  at22  a 2 (t1t2 ) 2  a 2 (2) 2  4a 2
47. (D)
Equation of normal at p  3cos ,2sin  is 3x sec   2 y cos e c   5
5
 3
9sec2   4cosec2
But Min. of 9 sec 2   4 cos ec 2   25
1
 no such  exists.
48. (D)

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Narayana IIT Academy 11-01-20_SUPER CHAINA_JEE-ADV_2012-P1_WTA-36_Key&Sol’s
     
         
x 2  y sin 2
cos    
a  2  b  2 
   
  
    2 
 cos    1eq
 2 
 
x cos   y sin   P  2eq = (2)
49. (C)
a
Slope of the line is equal to slope of the normal to the curve.
b
either a > 0 & b < 0 (or) a < 0 & b > 0.
50. (C)
S, T =  2  r cos ,0  r sin 
r 2 cos  sin   2sin   4  0
4 8
RS.RT =  8
sin  cos  sin 2
51. (A,B)
Conceptual
52. (A,C,D)
Common chord is the diameter of the circles cut by x2  y 2  2 gx  2 fy  c  0
53. (A,B,C,D)
2t  0 2
Slope of PV = 
t2  0 t
t
Equation of QV is y   ( x)
2
16 8 
On solving with y 2  4 x , Q   , 
t t 
2

1
Area of PVQ is .PV .VQ = 20
2
 PV .VQ = 40
By solving above equation t  4,  1

54. (A,B)
 b2  a 2 x b2 y
L  ae  normal is  2  a 2e2 passes through (0,-b)
 a  ae b a

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Narayana IIT Academy 11-01-20_SUPER CHAINA_JEE-ADV_2012-P1_WTA-36_Key&Sol’s

5 1
e4  e2  1 solving e 
2
55. (B,C)
y  mx  m 2  3
m2
y  2x  1
56. (5)

x
Equation of line joining origin and centre of circle C 2  (2,1) is, y 
2
 x  2y  0
Let equation of common tangent is x – 2y + c = 0…………..(1)
 perpendicular distance from (0, 0) on this line
= perpendicular distance from (1, 1)
c c 1
| || |
5 5
1
 c  1 c  c 
2
Equation of common tangent is
1
x  2y   0 or 2 x  4 y  1  0 ………..(2)
2
Perpendicular from (2, 1) on the line (2)
4  4 1 1 5
r | | 
20 2 5 10
57. (8)
at12 at22 at32
1
58. ar ABC  2at1 2at2 2at3  a 2  t2  t1  t3  t2  t1  t3 
2
1 1 1
at1t2 at2t3 at3t1
1 a2
Also PQR  a  t1  t2  a  t2  t3  a  t3  t1    t3  t1  t1  t2  t2  t3 
2 2
1 1 1
ar ABC
 2
ar PQR
59. (8)
Locus of intersection of normal at Pi and Qi is n 2  y 2   4  3 n2 + y2 = (4 + 3)2
2

CKi = 7
n
  7 175  7n = 56 n = 8
i 1

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