Professional Documents
Culture Documents
50–59
Tran Thi Thanh Thuy∗ 1 , Doni Prakasa Eka Putra1 , Wawan Budianta1 , and Hemanta
Hazarika2
1 Geological Engineering Department, Faculty of Engineering, Gadjah Mada University, Yogyakarta, Indonesia
2 Geotechnical Engineering Group, Department of Civil and Structural Engineering, Faculty of Engineering, Kyushu
University
50
IMPROVEMENT OF EXPANSIVE SOIL BY ELECTRO-KINETIC METHOD
cations will move from the anode toward is precipitation or mineralization, that provides
the cathode by both electro-osmosis and the greatest contribution to increase in strength.
electro-migration. On the other hand, electro- The reaction usually occurs when pH values of
migration phenomena cause anions transport the soil solution are greater than seven. There-
in the revese direction of cations transport, i.e., fore, the pH values of the soil solution need to
from the cathode to the anode. be maintained above seven during treatment in
With an application of DC current, the oxida- order to maximize its efficiency by appropriate
tion and the reduction will occur in turn at the injection of chemical ions at both electrodes
anode and the cathode (Ahmad et.al. 2006). (Jajudin, 2012).
Anode: Monovalent cations, such as sodium and
potassium, are commonly found in expansive
clay soil and these cations can be exchanged
2H2 O − 4e− → O2 ↑ +4H+ Eo = +1.229 (1) with cations of higher valences, such as cal-
cium. This ion exchange process takes place
Cathode: quite rapidly, often within a few hours. The
calcium cations replace the sodium cations
around the clay particles, decreasing the size
2H2 O + 2e− → H2 ↑ +2OH− Eo = −0.828
of the bound water layer and enabling the
(2)
clay particle to flocculate. The flocculation
where Eo is a standard reduction electro-
causes a reduction in plasticity, an increase
chemical potential. At the anode, the oxidation
in shear strength of the clay soil, and an im-
process generate an acid front, while at the cath-
provement in texture from a cohesive mate-
ode, alkaline will be produced by the reduc-
rial to a more granular, sand-like soil. The
tion process. pH value is different at the elec-
change in the structure causes a decrease in the
trodes, low pH at the anode, and high pH at the
moisture sensitivity and increases the work-
cathode. Therefore, the dissolution of ions will
ability and constructability of the soil. The
occur near the anode and precipitation occurs
magnitude of soil stabilization is usually mea-
near the cathode.
sured by the increase in strength as determined
Electro-kinetic treatment induces several
from undrained shear strength test (Justin and
changes in the pore fluid chemistry, soil fabric,
Robert, 2004).
and hydraulic conductivity. The electro-kinetic
process can be enhanced by the use of some
non-toxic enhancement solutions (stabilization 2 Materials and methods
agents), such as lime or calcium chloride solu-
tions. These chemical solutions can be fed at One natural soil at a site in Karangjati, Ngawi
either anode or cathode depending on the ions Regency, East Java, Indonesia was taken as soil
to be transferred into the soil. By the addition of sample. For electro-kinetic treatment, the sam-
an appropriate enhancement agent, some prop- ples were prepared near liquid limit condition.
erties of the soil such as texture, plasticity, com- The electrolyte solution, which was chosen for
pressibility and permeability will be altered; treatment, was pure water and calcium chloride
therefore they can be very effective in improv- with 1 mol/l concentration.
ing soil characteristics by reducing the amount The schematic diagram of test equipment is
of clay size particles and increasing the shear shown in Figure 1. The soil sample was stored
strength (Nasim, et al., 2012). When cations are on the central compartment of the container.
used as stabilizing agents, ions migrate into Anolyte and catholyte were installed on the
soils through processes of electro-migration electrode compartments, which filled with the
and electro-osmosis. These ions improve soil electrolyte solutions. The compartment A and
strength by three mechanisms, namely cation B were filled with pure water to simulate the
exchange, mineralization, and precipitation of ground water in the field. A cotton filter sep-
species in the pore fluid (Thakur et al., 2011). It arates the soil sample from four sides of com-
partment to prevent the soil particles to move The electrodes were connected to a constant
from one side to the other sides while it allows electric current DC power supply with output
the movement of water and chemical species. of 10A at 13V. The weight of aluminum elec-
The electrode compartments were filled with trodes was measured before and after electro-
(a) pure water and (b) chemical solution that kinetic treatment by an electronic balance to de-
is a 1 mol/l solution of calcium chloride con- termine the corrosion effect.
stituted at anolyte and pure water at catholyte. Outline of four electro-kinetic experiments
The selection of the chemical substance and its conducted in this research is showed on Table
concentration was chosen based upon the types 1. For each test, an approximately 2 kg of nat-
that have been utilized successfully on a re- ural soil was used. The soil specimen was ap-
search of Ahmad et al. (2011) and Moayedi et proximately 5 cm thick. In order to achieve near
al. (2012). The electrolyte solutions need to be liquid limit condition, the soil specimen was
observed and maintained (a) no-flow and (b) at mixed with pure water and covered by a plastic
flow condition. No-flow condition was created wrap. During the treatment, the pH values of
by filling compartment A and B by pure water anolye and catholye were measured at the fol-
with 50 mm height. Water was pumped from lowing periods:
the compartment A and supply to the com-
partment B to create the flow condition. The • First 12 hours: every 1 hour.
water-level at the compartment A was 50 mm • After 12 hours to 3 days: every 3 hours
height and the water lever at compartment B • After 3 days: every 6 hours
was maintained a 3 mm higher than that at the
compartment A causing a small flow of water Each electro-kinetic experiment took approxi-
with hydraulic gradient of 0.005. mately 6 days, based on studies conducted by
Two 1 mm-thick of aluminum plates were Rustamaji (2007). After the treatment, mois-
used as the cathode and the anode. The se- ture content test, Atterberg limits test, one di-
lection of aluminum electrodes was based on mension consolidation test, un-drained shear
a suggestion of Grey and Schlocker (1969) on strength test, and X-ray diffraction analysis
their research about electrochemical alteration were conducted.
of clay soils. They noticed two main reasons
for choosing Aluminum as electrodes: (1) Alu- 3 Results and discussion
minum anodes are often used in engineering
practice for electro-osmotic dewatering; (2) pH value of anolyte and catholyte
Aluminum can be combined with hydroxide Due to electrolysis reactions (i.e., oxidation
ions to form various hydroxyls–aluminum at the anode and reduction at the cathode),
compounds in soil. These compounds have in general, pH value in the anolyte compart-
interesting properties: they can interlayer with ment tends to decrease while pH value in the
certain clay minerals or precipitate externally catholyte compartment tends to increase. How-
in the pore space as amorphous or crystalline ever, the pH value is also affected by water from
hydroxides and thus modify the mineralogy two-flanked compartment A and B causing the
composition, and presumably the physical decrease or increase of pH value in the anolyte
properties of soil. Szynkarczuk (1994) also and catholye compartment is interrupted.
mentioned that Aluminum is the preferred ma- Figure 2 shows the pH values of anolyte and
terial since it does not color the supernatant. catholyte of four soil samples after treatment.
Tajudin (2012) confirmed the stabilization ef- In general, the disparity of pH value between
fects due to strengthening by electro-kinetic anolyte and catholyte of Ca-PW-CL and Ca-
can be enhanced by appropriate choice of the PW-WF is greater than of PW-PW-CL and PW-
electrode material (aluminum instead of steel) PW-WF systems. It confirms that electro-kinetic
or by the addition of sodium silicate or calcium method is more effectively when using calcium
chloride at the anode chloride instead of pure water as anolyte. pH
Anode corrosion
Aluminum electrodes used in electro-kinetic
treatment became a chemically active material.
Under apply a DC power, the cation moves to
the anode while the anion moves to the cath-
ode. At the anode, the dissolution of aluminum
atoms occurs, causing anode to lose its atomic
weight. The aluminum ion Al3+ moves from Figure 3: Distribution corrosion effect at the
the anode torward the cathode, causing the electrodes after electro-kinetic treatment.
atomic weight of cathode increasing.
The relationship between corrosion at anode havior of soil specimen. The highest liquid
and weight increasing at cathode is showed in limit and plasticity index (i.e., 86.14 and 60.92,
Figure 3. In all samples, the increase in the respectively), were shown by Ca-PW-CL sys-
weight of the cathode is greater than the lost tem, which was treated in no flow condition
of weight of the anode (approximately 2 times). with calcium chloride at the anolyte. Liquid
This, confirms that the cathode attracts not only limit and plasticity index of Ca-PW-WF system.
the aluminum anions dissolved from the anode which was treated in flow condition with cal-
but also calcium ions and the anions exist on cium chloride at the anolyte, were lowest (i.e.,
soil specimen. Degree of anode corrosion of 79.2 and 53.28, respectively).
the Ca-PW-CL system and Ca-PW-WF system
is higher than the others indicating that anode
Compressibility of treated soil
corrosion by calcium chloride will be higher
than by pure water. On the other hand, de- Terzhagi and Peck (1967) after Abbasi (2012) es-
gree of anode corrosion of Ca-PW-CL system is tablished a linear correlation between primary
higher than Ca-PW-WF system and degree of compression index Cc and liquid limit LL for re-
anode corrosion of PW-PW-CL system higher molded soil follows:
than PW-PW-WF system. This indicates that
degree of anode corrosion decreases with flow Cc = 0.009( LL − 10) (3)
condition. The high pH value at the catholyte
Based on Equation (3), the compression index
promotes precipitation of calcium and other
of untreated soil is estimated to be about 0.753.
metals in the cathode. Therefore, the weight
As the result in Table 4 shows that compression
of cathode of Ca-PW-CL system increased very
indices, Cc of the treated soils were lower than
high due to its high alkaline environment.
those of the untreated soils. It is known that the
lower the Cc is, the stiffer the soil specimen will
Atterberg limits of treated soil be. Thus, treated soil samples were stiffer than
Table 2 shows the Atterberg limits of the soil the untreated soil samples.
before and after electro-kinetic treatments. In After the electro-kinetic treatment, Ca-PW-
general, the liquid limit (wL) and plasticity in- CL system had the lowest Cc (i.e., 0.52), while
dex (IP) of treated soils became lower than PW-PW-CL system had the highest Cc (i.e.,
the untreated soil. The decrease in the liquid 0.742). Ca-PW-CL and Ca-PW-WF systems (i.e.,
limit is an indication of the strengthening be- Cc equal 0.52 and 0.50, respectively), which
Po
System Cc (kg/cm2 ) eo
PW-PW-CL 0.742 0.031 1.787
Ca-PW-CL 0.52 0.03 2.181
PW-PW-WF 0.55 0.03 2.101
Ca-PW-WF 0.50 0.30 2.107
References
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diction of compression behavior of normally con-
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Ahmad, K. B., Kassim, K. A., Taha, M. R. (2006)
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soil. Malaysian Journal of Civil Engineering 18(2),
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