Professional Documents
Culture Documents
Management
alappat@iitd.ac.in
Different kind of solid waste ?
• Biomedical waste (BMW)
• E-waste
• fly ash from thermal power plants
• C&D (construction and demolition) waste
• Industrial hazardous waste
• Plastic waste
• Municipal Solid Waste (MSW)
New solid waste streams
• Agro-wastes
• Scrap automobiles
• Institutional hazardous wastes
• Sludge from ETPs (Effluent treatment
plants) and STPs (Sewage treatment plants)
• Waste solar panels
What is MSW ?
• Waste collected by the Municipality
• Waste from houses, markets, parks,
institutions, offices, gardens, street
sweeping, etc etc
• Waste that contains: paper, plastics, glass,
leather, rubber, metals, stale food, leaves,
stones, debris, etc
• Waste other than: BMW, fly ash, haz waste,
radioactive waste, etc
Issues with MSW
• Huge volume / quantity
• Possibility of decay
• Bad odour
• Pollution of air / soil / water
• Infectious diseases
• Bird / dog / rodent menace
• Poor aesthetics
How to manage MSW ??
• Storage at source of generation
• Primary collection
• Municipal storage
• Transportation to processing stations
• Waste processing / treatment
• Final disposal
Hierarchy of waste management
plan
• Reduction at the source – reuse
• Recovery and recycling
• Waste processing (with some recovery)
• Waste transformation (without recovery)
• Final disposal
History of MSW Management in
India
MSW Disposal – early model
City Boundary
Land-dump
After 1980s-1990s
MSW
(raw mixed)
MSW
(raw mixed) 1980s onwards
Windrow
Composting
Separation Rejects
Techniques
Green
Compost
Maturation
MSW
(raw mixed)
Storage Pit
MSW
1990s at Deonar, Bombay
(raw mixed)
Drying
Pelletization
Refuse Land-dumps
Derived Fuel
2010 onwards
MSW
(raw mixed)
Manual Rejects
Moisture and Pre-sorting
Gaseous loss
Storage Pit
(5 day storage)
0-100 mm
< 80 mm
RDF (10-100 mm) Ballistic Separator Rejects (10-100 mm)
10 mm sieve
0-10 mm
3%
12% Paper and Paperboard
Glass
Metals
37%
11% Plastics
Rubber and Leather
Textiles
5% Wood
Food
4%
Yard Trash
3% 6% Other
8%
11%
Udaipur
Food Waste
Paper waste
Plastic
Glass
Fine earth and ash
Textile
Rubber/Leather
Metals
Kanpur
Percentage(%)
Food
Paper and Cardboard
Plastics
Textile
Wood
Glass
Metals
coal ash
leather
Ultimate and Proximate Analysis
Moisture
Non-combustibles
Inerts
As
S discarded
or
N
Dry as
H Volatile Weight received
O Matter
Ultimate Proximate
Characterization of Waste
• Laboratory analysis
• Theoretical estimation
Calculation of Heat Content,
Moisture Content, Ash Content
Material Moist. Heat Content*
Paper 4-10 % 5000-8000 BTU/lb
Plastics 1-4 12000-16000
Textiles 6-15 6500-8000
Rubber 1-4 9000-12000
Leather 8-12 6500-8500
Food 50-80 1500-3000
Wood 15-40 1000-8000 Btu/lb
Glass 1-4 50-100
Tins 2-4 100-500
Metals 2-6 100-500
Non-ferrous 2-4 100-500
Dirts /ash 6-12 1000-5000
Autogenous
Incineration
Incineration possible
With auxiliary Fuel
Incineration
Is not 1500 kacl/kg 2400 kcal/kg
advisable
Suitability for Incineration: Fuel
Triangle (Tanner Diagram)
Perform ultimate and proximate analysis on the waste sample
given below.
Componen %C %H %O %N %S % Inerts
ts
Paper 43.5 6 44 0.3 0.2 6
ULTIMATE ANALYSIS
Higher heat content as received = 540330 / 103 = 5246 kJ/kg of raw MSW
Thump rule :
This shows that the given raw MSW is not incinerable as such.
After drying, heat content = 540330 / 78.16 = 6913 kJ/kg of dry MSW
This shows that DRYING makes the given MSW incinerable with auxilliary fuel.
However, for proper incineration, it is better to have a higher heat content.
Hence improve the heat content further by removing ferrous metals (possible
by using a magnetic separator) from the dry MSW.
Now, heat content after removing moisture and all inert materials
This is very good for incineration. You can burn this MSW without any
auxulliary fuel recovering heat for power generation. But remember, it is
costly as all inert materials are to be removed after drying the MSW.
TREATMENT
TECHNIQUES FOR MSW
• Biological route: for biodegradable portion,
the most acceptable option
• Composting
• Biomethanation
• Chemical Route: not popular for MSW
• Physico-chemical Route: not popular for MSW
• Thermal Route: for combustable portion,
Costliest; but rapid
• Incineration
• Gasification Pyrolysis
Composting of MSW
• Composting: organized method of
producing compost by adopting and
accelerating the natural decomposition
phenomenon
• Compost : an organic manure containing
N,P,K and other micro-nutrients
• Compost should be used with other
chemical fertilizers for optimum results
Composting Techniques
• Anaerobic Composting
• Aerobic Composting
– Conventional windrow Composting
– Rapid Composting
• Vermi-composting
• Mechanical Composting
• Composting: aerobic or anaerobic
• Aerobic composting:
using aerobic microorganisms,
end products are CO2, NH3, nitrates, etc
Carbon is the source of energy
exothermic reaction and temp. rises
all pathogens are killed
overall, it takes 2-3 months
no foul smell
• Anaerobic composting:
using anaerobic microorganisms
reduction reaction
end products are CH4, CO2, H2S, etc
temperature does not increases
pathogens are not killed
it takes 4 to 6 months
odour problem
large space requirements
For MSW, on municipal scale,
Aerobic Composting is preferred
Factors affecting Aerobic
Composting
• Microorganisms
• Shredding of refuse
• C/N ratio
• Temperature
• Moisture content
• Windrow details
• Aeration/turning
Micro-organisms
• In the aerobic systems, there are many
organisms actively participating !
bacteria, actnomycetes, fungi, others
• In the initial stages: mostly mesophilic form
(temp 30 to 40 oC)
• then: mostly thermophilic bacteria and fungi
(60 to 70 oC)
• In final stage: mesophilic bacteria and fungi
• Bacteria: breaks down mostly protein and
other organic matter
• Fungi and Actinomycetes decomposes
lignin and cellulose
• Most of the organisms for composting are
readily available in the MSW itself.
• But there are inoculums and enzymes
claiming to hasten composting. This is
required for sure for agricultural and
industrial wastes
Shredding of the MSW
• For better bacterial invasion
• Shredding destroy the natural resistance of the
vegetation to microbial invasion
• Provides larger surface area
• Better availability of oxygen
• Uniform and rapid decomposition
• Materials become more homogeneous
• Better fly control/moisture control
• Desirable size for composting: less than 2
inch
• Material size governs (to certain extent) the
size of the finished product
• Compost for flower gardens/lawn: < 1 cm
C/N ratio
• C/N ratio available is important as all C present
may not be available for degradation
• For rapid composting, initial C/N ratio of the
waste = 30 is ideal. (range 26 to 32)
• If C/N ratio is >>30, add N sources like blood,
sewage sludge, slaughter house wastes, etc.
• If C/N ratio is <<30, add C sources like straw, saw
dust, paper, etc.
• For the finished compost product: C/N ratio = 16-
20 is the best
• If C/N ratio is >>20, robbing of nitrogen
takes place. There shall be a delay for the
availability of N to the plants. This is
because the excess C tend to use N in the
soil to build cell protoplasm.
• If C/N ratio is <<20, that compost cannot
improve the soil structure considerably.
Temperature
• MSW has good insulation properties; so the
temperature shoots up in aerobic composting.
• It may increase to 65 to 70 oC. But optimum temp
is 50 to 60 oC
• If temp is > 70 oC, it may inactivate the
enzymes/organisms
• All pathogens shall be killed if 50 to 60 oC is
maintained for 5-7 days
• No temp. rise in anaerobic composting
Moisture Content
• Optimum : 45 to 55 % by weight
• If moisture is considerably less than the optimum,
the physiological needs of the organisms are not
met.
• If moisture is considerably greater than the
optimum, pores may be blocked affecting the
oxygen supply. System may turn anaerobic
• If moisture is < 40%, just add water
• No composting if moisture is < 12 %
Windrow Dimensions
• For aerobic composting, materials should be
loosely packed.
• If windrow height is too much, self weight causes
some compression and the pore space reduces
• If windrow height is too low, heat loss will be
high and temperature goes below optimum
• Height can be more in cold season/countries
• For MSW, for simple windrow, height shall not
be more than 1.5 to 1.8 m and not less than 1 to
1.2 m , width: 2.4 m to 3.6 m
• Height is in between 1.8 to 2.7 m for the
windrows with air circulation arrangement
at the center. In this case, width is 3.6 m to
6.1 m
• Turning / mixing equipment also decides
the height of the windrows
Finished Product – Ripe Compost
B e s i d e s , Ve r m i - c o m p o s t c o n t a i n s b e n e f i c i a l
Microorganisms, Actinomycetes, Micro-nutrients
Enzymes and Hormones in available form
Rotary Drum Composting
• To decrease the composting time to about 7-
10 days to get green compost
• Another 10 to 15 days maturation to get ripe
compost
• To get very high quality compost (all N, P.
K about 3%)
• Rotary drum composting is a sort of High
rate Composting !
Air required for aerobic composting
Ca Hb Oc Nd + [(4a+b-2c-3d)/4] O2 aCO2
+ [(b-3d)/2] H2O + dNH3
Oxidation of NH3:
NH3 + 2O2 H2O + HNO3