Professional Documents
Culture Documents
GRADE 11
1
DISCOVERY OF AN ELECTRON
An electron was discovered by cathode ray discharge tubes experiment.
A cathode ray tube is made of glass containing two thin pieces of metal
called electrodes, sealed in it. The electrical discharge through the gases
could be observed only at very low pressures and at very high voltages .
The pressure of different gases could be adjusted by evacuation. When
sufficiently high voltage is applied across the electrodes , the current
starts to flow through a stream of particles moving in the tube from the
negative electrode to the positive one . These rays were called the
cathode rays or cathode ray particles.
The flow of current from cathode to anode was further checked by
making a hole in the anode and coasting the tube behind anode with
phosphorescent material called zinc sulphide coating , a bright spot on
the coating is developed .
2
Results of the experiment
The cathode rays start from cathode and move towards the
anode.
These rays were not visible but their behaviour could be
observed with a certain kind of material called FLOUROSCENT
OR PHOSPHORESCENT MATERIALS.
In the absence of electrical or magnetic field these rays travel in
straight lines.
In the presence of electrical or magnetic field , the behaviour of
cathode rays are similar to that expected from negatively
charged particles suggesting that the cathode rays consist of
negatively charged particles called electrons.
The characteristics of cathode rays do not depend upon the
material of electrodes nature of the gas present in the tube .
3
CHARGE TO MASS RATIO OF
ELECTRON
The measure of mass ratio of an electrical charge (e) to the mass
of an electron (me) by using the cathode rays discharge tube and
applying electrical and magnetic field perpendicular to each
other as well as to the path of electrons .
The amount of deviation of the particles from their path in the
presence of electrical and magnetic field depend upon:
1) The magnitude of the negative charge on the particle, greater
the magnitude of the charge on the particle , greater is the
interaction with the electric and magnetic field and thus
greater is the deflection.
2) The mass of the particle: lighter the particle , greater the
deflection and vice versa.
3) The strength of the electrical and magnetic field-the deflection
of electrons from its original path increases with the increase
in the voltage across the path electrodes or the strength of the
magnetic field.
4
When only electric field is applied, the
electrons deviate from their path and hit the
cathode ray tube at point A.
When only magnetic field is applied electron
strikes the cathode ray tube at point C.
When electrons deviate from their path,
then both electrical and magnetic field is
applied , it is possible to bring them back
and electrons go and hit the screen at point
B.
= 1.758820 x 1011 C kg-1
5
Discovery of protons and neutrons
Electrical discharge carried out in the modified cathode rays
tube led to the discovery of particles carrying positive charge
also known as canal rays.
The characteristics of these rays are:
7
Thomsons model of an atom
According to Thomson, atom was in a
spherical in shape which had positive
charged particle sand negative charged
particles equally distribution and hence it
was electrically neutral.
Its observation could be called as a plum
pudding model or a watermelon.
8
Rutherford’s model of atom
Famous experiment of Rutherford was the α-
particle scattering experiment.
A stream of high energy α particles from a
radioactive source was directed at a thin foil of a
gold metal. The thin foil had a circular fluorescent
zinc sulphide screen around it .Whenever α-
particles struck the screen, a tiny flash of light
was produced at the point.
9
The results of this experiment were unexpected.
(1) most of the α-particles passed through the gold
foil undeflected.
(2)a small fraction of α-particles was deflected by
small angles
(3) a very few α-particles (-1 in 20,000) bounced
back , that is were deflected by nearly 180 degree.
Observations:
Most of the space in the atom is empty as most of the
α-particles passed through the foil undeflected.
A few +vely charged α-particles were deflected.
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Atomic number and mass number
Atomic number(Z)=number of protons
present in the nucleus = number of
electrons in the neutral atom.
Electrons and protons together ina nucleus
are / were called nucleons.
Mass number (A)= number of protons
(z)=number of neutrons(n)
12
Isobars and isotopes
Isobars are elements having the same mass
number but different atomic number.
Whereas isotopes are elements having same
atomic number but a different mass number.
Hydrogen has 3 isotopes:
13
Draw backs of Rutherford’s model
of atom.
It could not explain the gravitational force in
nature.
It could not explain planetary motion under the
influence of gravity.
It could not explain Maxwell's electromagnetic
radiation property.
It could not explain quantum mechanics as a
whole.
14
The Electromagnetic Spectrum
Visible light is a small portion of
the electromagnetic radiation
spectrum detected by our eyes.
Electromagnetic radiation
includes radio waves,
microwaves and X-rays.
Described as a wave traveling
through space.
There are two components to
electromagnetic radiation, an
electric field and magnetic field.
15
The Wave Nature of Light
Wavelength, , is the
distance between two
corresponding points
on a wave.
Amplitude is the size or
“height” of a wave.
Frequency, , is the
number of cycles of the
wave passing a given
point per second,
usually expressed in Hz.
Planck’s Quantum Theory
Higher T = shorter λ (higher E) maximum.
Couldn’t explain with classical physics
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Electromagnetic Radiation
In 1900 Max Planck studied black body
radiation and realized that to explain the
energy spectrum he had to assume that:
1. energy is quantized
2. light has particle character
Planck’s equation is
hc
E h or E
h Planck’s constant 6.626 x 10 -34
J s 18
The Wave Nature of Light
The fourth variable of light is velocity.
c
Frequency is inversely proportional to wavelength.
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The Wave Nature of Light
Electromagnetic radiation can be categorized in terms of
wavelength or frequency.
20
The Particulate Nature of Light
Photoelectric effect: light striking a metal
surface generates photoelectrons.
21
The Particulate Nature of Light
Photoelectric effect is
used in photocathodes.
23
The Particulate Nature of Light
The photoelectric effect is not explained using a wave
description but is explained by modeling light as a particle.
24
Photoelectric Experiments
a) For > 0, the number of electrons
emitted is independent of frequency.
Value of 0 depends on metal used.
hc
E h
26
The Particulate Nature of Light
Binding Energy - energy holding an electron to a
metal.
27
Example Problem 6.2
The laser in a standard laser printer emits
light with a wavelength of 780.0 nm. What is
the energy of a photon of this light?
28
The Wave Nature of Light
Refraction is the bending of light when it passes
from one medium to another of different density.
Speed of light changes.
Light bends at an angle depending on its wavelength.
Light separates into its component colors.
29
Example Problem 6.3
In a photoelectric experiment, ultraviolet
light with a wavelength of 337 nm was
directed at the surface of a piece of
potassium metal. The kinetic energy of the
ejected electrons was measured as 2.30 x
10-19 J. What is the electron binding energy
for potassium?
30
Atomic Spectra
Atomic Spectra: the particular pattern of
wavelengths absorbed and emitted by an element.
31
Atomic Spectra
33
Example Problem 6.4
When a hydrogen atom undergoes a transition from E3 to
E1, it emits a photon with = 102.6 nm. Similarly, if the
atom undergoes a transition from E3 to E2, it emits a
photon with = 656.3 nm. Find the wavelength of light
emitted by an atom making a transition from E2 to E1.
34
The Bohr Atom
Bohr model - electrons orbit the
nucleus in stable orbits.
Although not a completely
accurate model, it can be used to
explain absorption and emission.
Electrons move from low
35
The Bohr Atom
Ground state: the lowest state
(orbital)where the electrons are initially
present is called the ground state.
Excited state: the state where the electrons
on gaining energy I subjected to go to a
higher energy level is called the excited
state.
Atoms return to the ground state by emitting
energy as light.
36
Atomic Spectra and the Bohr Atom
The Rydberg 1 1 1
equation is an R 2 2
empirical equation n1 n 2
that relates the R is the Rydberg constant
wavelengths of the R 1.097 107 m -1
lines in the
hydrogen n1 n 2
spectrum. n’ s refer to the numbers
of the energy levels in the
emission spectrumof hydrogen
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Atomic Spectra and the Bohr Atom
Example 4-8. What is the n 2 4 and n1 2
wavelength of light 1 1 1
R 2 2
emitted when the n1 n 2
hydrogen atom’s energy 1 1 1
1.097 107 m -1 2 2
changes from n = 4 to n = 2 4
2? 1
1.097 10 m 7 -1 1
1
4 16
1
1.097 107 m -1 0.250 0.0625
1
1.097 107 m -1 0.1875
1
2.057 106 m -1
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Atomic Spectra and the Bohr Atom
In 1913 Neils Bohr incorporated Planck’s
quantum theory into the hydrogen
spectrum explanation.
Here are the postulates of Bohr’s theory.
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Atomic Spectra and the Bohr Atom
Light of a characteristic wavelength (and
frequency) is emitted when electrons move from
higher E (orbit, n = 4) to lower E (orbit, n = 1).
This is the origin of emission spectra.
Light of a characteristic wavelength (and
frequency) is absorbed when electrons jump from
lower E (orbit, n = 2) to higher E (orbit, n= 4)
This is the origin of absorption spectra.
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42
Atomic Spectra and the Bohr Atom
Bohr’s theory correctly explains the H
emission spectrum.
The theory fails for all other elements
because it is not an adequate theory.
43
The Wave Nature of the Electron
In 1925 Louis de Broglie published his Ph.D.
dissertation.
A crucial element of his dissertation is that electrons
have wave-like properties.
The electron wavelengths are described by the de
Broglie relationship.
h
mv
h Planck’s constant
m mass of particle
v velocity of particle 44
The Wave Nature of the Electron
Example 4.9. Determine the wavelength, in m, of an electron,
with mass 9.11 x 10-31 kg, having a velocity of 5.65 x 107 m/s.
Remember Planck’s constant is 6.626 x 10-34 Js which is also equal to
6.626 x 10-34 kg m2/s.
h
mv
6.626 10 kg m / s s
34 2 2
9.1110 kg5.65 10 m/s
-31 7
1.29 1011 m 45
The Quantum Mechanical
Picture of the Atom
Werner Heisenberg in 1927 developed the
concept of the Uncertainty Principle.
It is impossible to determine simultaneously
both the position and momentum of an
electron (or any other small particle).
Detecting an electron requires the use of
electromagnetic radiation which displaces the
electron!
Electron microscopes use this phenomenon
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The Quantum Mechanical Model of the Atom
47
The Quantum Mechanical Model of the Atom
49
On solving the Schrödinger equation we get
three set of number which are called the
quantum numbers which give us the location
space and the 3-D spatial orientation of the
orbital.
The probability density gives us the
probability of an electron in the region that is
where the electrons in most probable to be.
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Potential Energy and Orbitals
n can be written in terms of two
components.
53
Quantum Numbers
When solving the Schrödinger equation,
three quantum numbers are used.
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Quantum Numbers
The principal quantum number, n, defines the
shell in which a particular orbital is found.
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Quantum Numbers
The secondary quantum number, l, indexes energy
differences between orbitals in the same shell in an atom.
l has integral values from 0 to n-1.
l specifies subshell
Each shell contains as many l values as its value of n.
56
Quantum Numbers
The energies of orbitals are specified
completely using only the n and l quantum
numbers.
57
Quantum Numbers
The third quantum number is the magnetic
quantum number, ml.
For l = 1, ml = -1, 0, +1
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Quantum Numbers
60
Summing up
n defines the shell ,determines the size of the orbital and also to a large extent
the energy of the orbital.
There are n subshells in the nth shell. l identifies the sub shell and determines
the shape of the orbital there are (2l+1)orbitals of each type in a subshells
that is one s orbital (l=0) three p orbitals(l=1) and 5 d orbitals(l= 2) per
subshells. To some extent l also determines the energy of the orbital in a multi
electron atom.
designates the orientation of the electron of the orbital . For a given value of l
or has (2l+1) values , the same as the number of orbitals per subshells. it
means that the number of orbitals is equal to the number of ways in which they
are oriented
refers to orientation of the spin of the electron 61
Shapes of atomic orbitals
According to max born the square of the wave
function at a point gives the probability density
of the electron at that point.
For 1s orbital the probability density is maximum
at the nucleus and its decreases sharply as we
move away from it
For a 2s orbital the probability density first
decreases sharply to zero and then again starts
increases.
After reaching a small maxima it decreases again
and approaches zero as the value of r increases
further. 62
The region where this probability of finding an
electron reduces to zero is called nodal
surfaces or simply nodes.
In general, for an ns orbital , an ns orbital has
(n-1)nodes, that is number of nodes increases
with the increase of quantum number
n.therefore for 2s it will be 1 and for 3s it will
be 2.
Boundary surface diagrams of constant
probability density for different orbitals give a
fairly good representation of the shapes of the
orbitals . In this representation, a boundary
surface or a contour surface is drawn in space
for an orbital on which the value of probability
density is constant.
63
In the boundary surface diagrams the nucleus is
taken to be at the origin or rather it is . Here, ,
diagrams are not spherical like the s-orbital. Here
the p-orbital consists of two section s called
lobes. That are on either sides of the plane where
the two lobes touch each other. The size, shape
and energy of the three orbitals are identical .
Since the lobes are considered along the x, y and
the z axis they are designated as the above:-
65
d- orbitals
The 5 d-orbitals are designated as:-
71
Pauli exclusion principle
According to this principle :- no two electrons
in this atom have the same set of four
quantum numbers.
Or
It can also be stated otherwise as only two
electrons may exist in the same orbital and
these orbital must have opposite spins
The maximum number of electrons which can be
accommodated in the shell with the quantum
number n is according to the 2n2 rule. 72
Hund’s rule of maximum multiplicity
This rule deals filling of electrons in the orbitals
belonging to the same subshells of equal energy
called degenerate orbitals.
It states that pairing of electrons in the
orbitals belonging to the same sub shell (p,d,
or f) does not take place until each orbital of
that sub shell gets one electron that is singly
occupied.
Some of the orbitals acquire extra stability due to
their symmetry. 73
Electronic configuration
The distribution of electrons into orbitals of an
atom is called its electronic configuration.
Electronic configuration can be represented in
two ways:-
(a)Normal notation and
(b) orbital diagram
As given in the textbook.
The electron in the completely filled electronic shell
with the highest principal quantum number are
called valence electrons.
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