FIITJEE

MOCK TEST
for Class XIIth

Set – II

CHEMISTRY (CBSE)
Time: 3 hrs. Maximum Marks: 70

General Instructions:

(a) All Questions are compulsory

(b) Section – A: Q.No. 1 to 20 are very short answer questions(objective type) and carry
1 mark each.
(c) Section – B: Q.No. 21 to 27 are short answer type questions and carry 2 marks each.
(d) Section – C: Q.No. 28 to 34 are long answer type questions and carry 3 marks each.
(e) Section – D: Q.No. 35 to 37 are also long answer type questions and carry 5 marks
each.
(f) There is no overall choice. However an internal choice has been provided in two
questions of two marks, two questions of three marks and all the three questions of
five marks weightage. You have to attempt only one of the choices in such questions.
(g) Use log tables if necessary, use of calculators is not allowed.

Name of the Candidate : .........................................................................................................

Enroll Number : .........................................................................................................

Date of Examination : .........................................................................................................

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Mock Test Paper-CBSE-1920-C-XII (Set-2)-Chemistry-2

SECTION  A
Read the given passage and answer the Q.1 - 5 that follows:
The vapour pressures of two liquids A and B are respectively 400 mm and 600 mm of Hg at a
certain temperature. Mixing of the two liquids forms an ideal solution which obeys Raoults’s law
at all concentrations. In order to prepare a dilute solution, 16 moles of liquids A and is mixed
with 4 moles of liquid B. The variation of vapour pressure over the ideal solution with mole
fraction of the liquids is given below.
600

400
V.P
(in mm of Hg)

XA = 1 Mole fraction XB = 1

1. What is the mole fraction of A in the solution?

2. What is the partial pressure of B over the solution?

3. What is the total vapour pressure over the solution due to A and B?

4. 600

400
V.P
(in mm)

XA = 1 0.5 XB = 1
Mole fraction

What is the vapour pressure of the solution at point ‘P’?

5. What is the mole fraction of vapours of liquid A over the solution?

Questions 6 to 10 are one word answers:

6. The process by which ores containing oxygen and other non-metals, are heated in
absence of oxygen to expel volatile impurities is called

7. The dipolar ion which is formed when an alpha amino acid is dissolved in water is called

8. What is the colloid called if both the dispersed phase and dispersion medium are
liquids?

9. What is the chemical name of the simplest aromatic ketone that gives iodoform
reaction?

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 Mock Test Paper-CBSE-1920-C-XII (Set-2)-Chemistry-3

10. Name the 3d-transition period element which di-positive ion contains five unpaired
electrons in ground state?

Questions 11 to 15 are multiple choice questions:

11. The IUPAC name of the compound shown below is

NO 2

NO 2
(A) m-nitronitrobenzene (B) 1, 3-dinitrobenzene
(C) 1, 3-dinitrophenyl (D) 3-nitro-1-nitrobenzene

12. Which of the following is a colourless complex?

(A) [Fe(CN)6]4– (B) [FeF6]3-
2+
(C) [Fe(H2O)6] (D) [Fe(CN)6]3–

13. In Reimer Tiemann reaction, phenol reacts with

(A) Br2/H2O (B) CHCl3/KOH
(C) FeCl3 (D) Conc. HNO3/Conc.H2SO4

14. The reaction shows below is an elementary reaction

2X  g   Y  g 
 X2 Y  g
How many times will the rate of above reaction increase if the concentrations of both X
and Y are doubled?
(A) 4 times (B) 6 times
(C) 8 times (D) 12 times

15. During adsorption of a gas on a solid, the entropy of the process

(A) increases (B) decreases
(C) remains constant (D) depends on the nature of gas

Questions 16 to 20:
(A) Both assertion and reason are correct statements, and reason is the correct explanation of
the assertion.
(B) Both assertion and reason are correct statements, but reason is not the correct explanation
of the assertion.
(C) Assertion is correct, but reason is wrong statement.
(D) Assertion is wrong, but reason is correct statement.

16. Assertion: Reaction of CH3Br with KCN forms major and minor products.
Reason: Nucleophile CN– contains two different donor atoms.
 
17. Assertion: The activation energy of the reaction H  g Cl  g 
 H  Cl  g is zero.
Reason: The reaction takes place in gaseous state.

18. Assertion: PVC(polyvinyl chloride) is an addition polymer.

Reason: Water molecules are lost when its monomers are combined to form the
polymer

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Mock Test Paper-CBSE-1920-C-XII (Set-2)-Chemistry-4

19. Assertion: Both glucose and fructose can form osazone, when treated with
phenylhydrazine.
Reason: Both contains aldehyde groups in addition to other functional groups.

20. Assertion: The largest interhalogen compound formed between iodine and fluorine is
IF8.
Reason: Iodine contains seven electrons in the outermost orbit.

SECTION  B

21. Can Nickel spoon be used to stir AgNO3 solution? Give reason.
o
(EoAg+/Ag=0.80V, ENi2
/Ni
= -0.25V)

22. Which of the following two compounds would react faster by SN2 pathway:
1-bromobutane or 2-bromobutane. Explain why?
OR
Allyl chloride is more reactive than n-propyl chloride towards nucleophilic substitution
reaction through SN1 path. Explain why?

23. What products are expected when the following are hydrolysed ?
(i) Lactose (ii) Sucrose

24. Write the structure of major product(s) in the following:

1. NH2NH2 Conc.NaOH
(i) CH3CH2CHO 
2. KOH, glycol/heat
 (ii)  CH3 3 CCHO  

25. What type of synthetic detergents are biodegradable and why?

26. Define
(i) ideal solution (ii) isotonic solution

OR

State the factors that affect the solubility of gas in liquid

27. (i) Which noble gas is used in filling balloons for meterological observations?
(ii) Complete the equation
XeF2  PF5  

SECTION  C

28. 19.5 g of CH2FCOOH is dissolved in 500g of water. The depression in the freezing point
of water observed is 1.0 oC. Calculate van’t Hoff factor of CH2FCOOH. (Kf for water is
1.86 K Kg mol-1)
OR
18 g of glucose (Molar mass = 180 g/mol) is dissolved in 1kg of water. At what
temperature will this solution boil? ( Kb of water = 0.52 K kg/mol , Boiling point of pure
water = 373.15 K)

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 Mock Test Paper-CBSE-1920-C-XII (Set-2)-Chemistry-5

29. The rate constant of a reaction is 1.5  107 s-1 at 500C and 4.5  107 s-1 at 100oC.
Evaluate activation energy Ea (in KJ mol-1). Given log 3 = 0.48

30. Write the monomers and give one use each of the following polymers:
i. Nylon-6
ii. Buna-N
iii. PVC

31. Explain the role of

i. Cryolite in the electrolytic reduction of Alumina
ii. Carbon monoxide in purification of Nickel
iii. Calcium carbonate in smelting of Haematite.

32. (i) Give the electronic configuration of d-orbital of Ti in [Ti(H2O)6]3+ion in octahedral

crystal field.
(ii) Why is this complex colored?
(iii) What is the colour of NiCl2(aq) solution?

33. Give chemical test for distinction between following pair of organic compounds:
(i) Phenol and cyclohexanol
(ii) Ethanal and Propanal
(iii) Benzyl amine and benzamide

34. Give chemical reactions for the following:

(i) Anisole reacts with acetyl chloride in presence of anhydrous AlCl3
(ii) Phenol reacts with bromine in presence of CS2
(iii) t-butyl methyl ether reacts with HI.
OR
a) Explain why
i) amides are weaker bases than amines?
ii) There are two –NH2 groups in semicarbazide , however only one such group is
involved in the formation of semicarbazide.
b) Convert Aniline to p-nitroaniline.

SECTION  D

35. An aromatic compound ‘A’ (Molecular formula C8H8O) gives positive 2,4-DNP test. It
gives a yellow precipitate of compound ‘B’ on treatment with iodine and sodium
hydroxide solution. Compound ‘A’ does not give Tollen’s or Fehling’s test. On drastic
oxidation with potassium permanganate it forms a carboxylic acid ‘C’ (Molecular formula
C7H6O2), which is also formed along with the yellow compound in the above reaction.
Identify A, B and C and write all the reactions involved.
OR
A colourless substance ‘A’ (C6H7N) is sparingly soluble in water and gives a water
soluble compound ‘B’ on treating with mineral acid. On reacting with CHCl3 and
alcoholic potash ‘A’ produces an obnoxious smell due to the formation of compound ‘C’.
Reaction of ‘A’ with benzenesulphonyl chloride gives compound ‘D’ which is soluble in
alkali. With NaNO2 and HCl, ‘A’ forms compound ‘E’ which reacts with phenol in weakly
alkaline medium to give an orange dye ‘F’. Identify compounds ‘A’ to ‘F’.

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Mock Test Paper-CBSE-1920-C-XII (Set-2)-Chemistry-6

36. a) Explain why on addition of 1 mol of NaCl to 1 litre of water, the boiling point of water
increases, while addition of 1 mol of methyl alcohol to one litre of water decreases its
boiling point.
(b) For a reaction A + B  Products, the rate law is; Rate = k [A][B]3/2
Can the reaction be an elementary reaction? Explain
(c) Consider a cell given below
Cl– (aq) | Cl2(g) || Cu2+ (aq) | Cu(s)
Write the reactions that occur at anode and cathode

OR
(a) How does sprinkling of salt help in clearing the snow covered roads in hilly areas?
(b) Oxygen is available in plenty in air yet fuels do not burn by themselves at room
temperature. Explain.
(c) Write the Nernst equation for the cell reaction in the Daniel cell. How will the ECell be
affected when concentration of Zn2+ ions is increased?
(d) What advantage do the fuel cells have over primary and secondary batteries?

37. When a chromite ore (A) is fused with sodium carbonate in free excess of air and the
product is dissolved in water, a yellow solution of compound (B) is obtained. After
treatment of this yellow solution with sulphuric acid, compound (C) can be crystallised
from the solution. When compound (C) is treated with KCl, orange crystals of compound
(D) crystallise out. Identify A to D and also explain the reactions.
OR
When an oxide of manganese (A) is fused with KOH in the presence of an oxidising
agent and dissolved in water, it gives a dark green solution of compound (B). Compound
(B) disproportionates in neutral or acidic solution to give purple compound (C). An
alkaline solution of compound (C) oxidizes potassium iodide solution to a compound (D)
and compound (A) is also formed. Identify compounds A to D and also explain the
reactions involved.



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