CHEMISTRY

1. Reaction of NaBH4 with BF3. (c) Easy removal of the (a) 4 , 4 (b) 4 , 6
O(C 2H 5) 2 in diglyme at room accumulated aluminium on the
temperature produces mainly cell floor in the molten (c) 6 , 4 (d) 6 , 6
(a) H2 condition 13. Which one of the following is a
(b) B2H6 (d) Increase of the specific gravity correct representation of
(c) B2H3F3 of the electrolyte tetraammine copper(II)
(d) (CH3 OCH2CH2)2O 8. During the extraction of iron from hexacyanoferrate (III)?
(a) [Cu (NH 3 )4 ] [Fe(CN )6 ]
hematite, limestone is added to the
2. P4O10 on reacting with water does blast furnance to
not form (a) remove silica as slag (b) [Cu (NH ) ] [Fe(CN ) ]
3 4 3 6

(a) Tetra metaphosphoric acid (b) remove silica as gangue

(c) reduce hematite (c) [Cu (NH ) ] [Fe(CN ) ]
3 4 6 2
(b) Phosphorus acid
(c) Orthophosphoric acid (d) oxidize coke to carbon monoxide (d) [Cu (NH ) ] [Fe(CN ) ]
3 4 3 6 2
9. Match the List-I (Metal) with List- 14. The complex compound used in
(d) Pyrophosphoric acid
II (Process of Extraction) and select the chemotherapy of cancer is
3. The pair of compounds
the correct answer using the codes
given below the lsits: [ ]
(a) cis – Pt IV (NH 3 )4 Cl 2 Cl 2
cis – [Pt (NH ) Cl ]
containing peroxy (-O-O-) group is List-I List-II IV
(a) H2SO5 and PbO2 (b) 3 2 4
(Metal) (Process of
(b) HClO4 and H2S2O8 Extraction) (c) cis – [Pt (NH ) Cl ]
II
3 2 2
(c) P2O5 and MnO2
trans - [Pt (NH ) Cl ]
A. Aluminium 1. Blast furnance II
(d) H2SO5 and H2S2O8 B. Iron 2. Mond process (d) 3 2 2
C. Nickel 3. Bayer process 15. An example of a hexadentate ligand is
4. Which of the following is para D. Copper 4. Cyanide (a) 2, 2'-bipyridyl
magnetic? process (b) ethylene diaminetetraacetate ion
(a) Cr(CO)6 5. Froth (c) dimethyl glyoxime
(b) Fe(CO)5 floatation (d) iminodiacetate ion
(c) Ni(CO)4 Codes: 16. Haemoglobin, a complex
(d) V(CO)6 (a) A B C D containing iron is a constitutent of
2 5 4 1
(b) A B C D blood. The oxidation state of iron
5. A mixture of NaCl, NaBr and 3 1 2 5 in the complex is
K2Cr2O7 on heating with conc. (c) A B C D (a) Zero (b) +1
H2SO 4 produces redish brown 2 1 4 5 (c) +2 (d) +3
vapours consisting of (d) A B C D 17. The compound with zero dipole
3 5 2 1
(a) CrO 2 Cl 2 + Br2 10. Which one of the following high- moment is
spin complexes has the largest (a) cis–2 butene
(b) CrO 2 Cl 2 + CrO 2 Br2
CFSE (Crystal field stabilization (b) trans-2 butene
(c) CrO 3 + CrO 2 Br2 (c) but-1-ene
energy)?
(d) 2-methyl-1-propene
(a) [Mn (H 2 O )6 ]
(d) Br2 + Cl 2 O 2+
18. Consider the following statements
6. Among the following complex (b) [Cr (H O ) ]
2 6
2+ about intermolecular and
intramolecular hydrogen bonds:
ions, the species containing Fe3+
in strongest ligand field is
(c) [Mn(H O ) ] 2 6
3+
1. Both types of H-bonds are
(a) [Fe(CN )6 ]3− (d) [Cr (H O ) ]
2 6
3+ temperature-dependent
2. Intramolecular H-bond
11. Target nucleus A is converted to
(b) [Fe(H O ) ]
2 6
3+
product nucleus B by (p, n)
disappears on increasing the
concentration
(c) [Fe(F)6 ]3− reaction: A(p, n) B. 3. Intramolecular H-bond
In this case
(d) [Fe(NH3 )6 ]3+ (a) A and B are isotopes
disappears on decreasing the
concentration
(b) A and B are isobars 4. The boiling points of
7. In the electrolytic purification of (c) A and B are isotones
crude aluminium, the addition of compound having
(d) A has higher atomic number intramolecular H-bond are
fused cryolite and fluorspar to than that of B
Al2O3 causes lower than that of those
12. How many − particles and compounds which have
(a) Easy reduction of alumina to
the metal − particles are emitted in passing intermolecular H-bond
(b) Lowering of the fusion Which of the statements given
from Th 232 to Pb 208 ?
temperature of Al2O3 90 82
 above are correct? reactions does not involve
(a) 1, 2 and 4 (b) 3 and 4 carbocation intermediacy? (a)
(c) 1, 3 and 4 (d) 1 and 2
19. The bond dissociation energies (∆H )
(a) (CH 3 )3 C Br + OH →
of three alkyl halides are as follows: (CH 3 )3 C − OH
(b)
CH3Cl : 84 kcal/mol
CH2=CHCl : 207 kcal/mol (b) (CH 3 )3 C OH 20%H SO
2 4
→
85− 90º C (c)
C6H5 - CH2Cl : 166 kcal/mol (CH 3 )2 C = CH 2 (d)
The cleavage of the C-Cl bond in
the halide with least ∆H produces (c) (CH 3 )3 C CH 2 Br EtOH → 29. The quantum number which is not
derived from the solution of
(a) Two free radicals (CH 3 )2 C = CH CH 3 Schrodinger wave equation for
(b) Two cations
−
(c) Two anions (d) 2CH3 CHO OH → hydrogen atom is
(d) One cation and one anion CH3CH(OH) – CH2 - CHO (a) Azimuthal quantum number
20. The electrophilic centre(s) in the 24. The boiling points of three (b) Principal quantum number
molecule (c) Spin quantum number
isomeric pentanes-1, 2, and 3 are:
1 2 3 4 1. 9.5ºC 2. 28ºC (d) Magnetic quantum number
CH 2 = CH − CO − CH 3 is /are
3. 36ºC
(a) C3 only (b) C1 and C3
1, 2 and 3 are respectively
(c) C1 and C2 (d) C2 and C4
21. Consider the basicity of the (a) n-pentane, isopentane, neopentane +
following aromatic amines: (b) isopentane, neopentane, n-
pentane 30. +
(c) n-pentane, neopentane, isopentane
(d) neopentane, isopentane, n-
1. 2. pentane The shape of which one of the
25. Addition of Br2 to cis-2-butane orbitals corresponds to the angular
yields wave function shown in the figure
(a) meso-2, 3-Dibromobutane given above?
(b) (± ) 2, 3-Dibromobutane (a) d x 2 − y 2 (b) dxy
3. 4. (c) (+) 2, 3- Dibromobutane (d) Py (d) Px
(d) (-) 2, 3-Dibromobutane 31. The 'd' orbital which has the
OCH3 CH3
Which one of the following 26. Anti-Markownikoff's addition of maximum electronic probability
HBr is not observed in density lying along two axes is
represents the correct increasing
(a) Propene (b) 1-Butene known as
order of the basicity of the above (c) 2-Butene (d) 2-Pentene
amines? 27. Polymerization using Ziegler-Natta (a) d x 2 − y 2 (d) d 2 z
(a) 2 < 1 < 4 < 3 (b) 1 < 2 < 3 < 4 catalysts is advantageous over (d) dxy (d) d xz
(c) 4 < 3 < 1 < 2 (d) 2 < 3 < 4 < 1 free radical polymerization because 32. Which one of the following pairs
22. Match List-I (Compound) with (a) it can lead to living polymers of species (atoms/ions) will have
List-II (C-C Bond Length in Å) and via anionic polymerization identical ground state electronic
select the correct answer using the (b) it permits step-reaction configuration?
codes given below the lists: polymerization resulting in a (a) Li + and He– (b) Cl– and Ar
List-I List-II highly cross-linked polymer (c) Na and K (d) F+ and Ne
(Compound) (C-C Bond (c) it gives highly branched 33. Match the List-I (Atomic Number
polymer with a high degree of of Element) with List-II (Block to
Length in Å)
crystallinity Which of the Element Belongs)
A. Ethane 1. 1.20 (d) it gives linear polymer and select the correct answer using
B. Ethylene 2. 1.40 molecules permitting the cosdes given below the lists:
C. Acetylene 3. 1.54 stereochemical control List-I List-II
D. Benzene 4. 1.33 28. In the reaction (Atomic Number (Block to
Codes: 1. CH3I excess of Element) Which the
(a) A B C D 2. Ag2O Element
2 1 4 3 X
(b) A B C D N CH 3
3. Heat Belongs)
3 4 1 2 H
A. 24 1. p
(c) A B C D the final product X is B. 38 2. f
2 4 1 3 C. 49 3. s
(d) A B C D D. 59 4. d
3 1 4 2 Codes:
23. Which one of the following (a) A B C D
 2 1 3 4 38. Among the following species, the mole of MnO −4 to one mole of
(b) A B C D one having the highest bond
4 3 1 2 strength is Mn 2+ ion is
(c) A B C D (a) 4 (b) 5
2 3 1 4 (a) O2 (b) O +2
(c) 6 (d) 7
(d) A B C D (c) O −2 (d) O 22 − 44. HCN behaves as a very weak acid
4 1 3 2 39. Match List-I (Molecule or Ion) with in acqueous medium whereas it
34. The number of and bonds List-II (Hybridisation of the Central acts as a strong acid in liquid
between two carbon atoms in CaC2 ammonia because
Atom in the Molecule) and select
is (a) Electro negativity of oxygen
(a) Three bonds and no the correct answer using the codes is greater than that of nitrogen
bonds given below the lists: (b) Ionization energy of oxygen is
(b) Two bonds and one List-I List-II less than that of nitrogen
bond (Molecule (Hybridisation of (c) Proton affinity of water is less
(c) Two bonds and one or Ion) the Central Atom than that of ammonia
bond in the Molecules) (d) Dipole moment of water is
(d) One bond and one bond A. XeF4 1. dsp 2 greater than that of ammonia
35. The ionic radii of K+, Ca2+, Cl– and B. H2O 2. sp 3 45. The ratio ortho hydrogen: para
S2– ions decrease in the order C. PCl5 3. sp 3d 2 hydrogen
D. [Pt (NH 3 )4 ] 4. sp 3d
2+
(a) Cl - > S2− > K + > Ca 2+ (a) decreases with the increase of
Codes: temperature
(b) K + > Ca 2+ > Cl − > S2−
(a) A B C D (b) increases with the increase of
(c) S2− > Cl − > K + > Ca 2+ 3 2 4 1 temperature
(d) Ca 2+ > K + > Cl − > S2− (b) A B C D (c) is independent of temperature
1 4 2 3
36. The bonds found in the structural (c) A B C D (d) is highest at 100ºC and then
formula of carbon dioxide are 3 4 2 1 decreases
(d) A B C D 46. Which one among the following
(a) O C O 1 2 4 3 has the highest catenation power?
40. Which one of the following is the (a) O (b) S
(b) O C O redox reaction? (c) Se (d) Te
(a) Pb(CH3COO)2+Na2CrO4 → 47. K, KO2, Ca, CaH2, Na, Na2O2, Li and
(c) O C O
PbCrO4 ↓ +2CH3COONa Li2O react with water.
Which of the following substances
(d) O C O (b) Fe + 2HCl → FeCl2+H2 ↑
yield the same gaseous product?
37. Match List-I (Name of the (c) BaCl2 + H2SO4 → BaSO4 ↓ (a) K and KO2
Compound) with List-II (Structure/ +2HCl (b) Ca and CaH2
Geometry of the Molecule) and (d) Ca(OH)2+2HCl → CaCl2+ (c) Na and Na2O2
select the correct answer using the 2H2O (d) Li and Li2 and Li2O
codes given below the lists: 41. In the reaction: 48. Consider the following
List-I List-II HNO3+I2 → HIO3+NO2+H2O compounds:
(Name of the (Structure /Geometry Stoichiometric number of moles of 1. K2CO3 2. MgCO3
Compounds of the Molecule HNO 3 and I 2 reacting will 3. CaCO3 4. BeCO3
A. Chlorine 1. Triangular respectively, be Which one of the following
trifluoride planar (a) 10 and 1 (b) 10 and 2 arrangements in the increasing
B. Boron 2. Triangular (c) 1 and 1 (d) 1 and 2 order of their thermal stabilities is
trifluoride pyramidal 42. Chlorine gas reacts with aqueous correct?
C. Nitrogen 3. T-shaped KOH solution as per chemical (a) 1 < 2 < 3 < 4 (b) 2 < 4 < 3 < 1
Trifluoride equation: (c) 3 < 2 < 1 < 4 (d) 4 < 2 < 3 < 1
D. Sulphur 4. Regular
3Cl 2 + 6KOH → 5KCl + KClO3 + 3H 2 O 49. A solution of sodium in liquid
hexafluoride octahedral ammonia is blue due to the
Codes: The reaction is an example of presence of
(a) A B C D (a) Neutralization reaction (a) Sodium amide
2 1 3 4 (b) Substitution reaction (b) Solvated sodium atoms
(b) A B C D (c) Double decomposition
3 4 2 1 (c) Solvated sodium ions
reaction (d) Solvated electrons
(c) A B C D
2 4 3 1 (d) Disproportionation reaction 50. The enthalpy of formation of CO2
(d) A B C D 43. The number of faradays (F) of
and H2O are –395 kJ and –285 kJ
3 1 2 4 electricity required to convert one
 respectively and the enthalpy of (b) –67 kcal mol–1 the Arrhenius equation is direct
combustion of acetic acid is -869 (c) –688 kcal mol–1 related to
kJ. The enthalpy of formation of (d) It can not be calculated, we (a) The entropy change in the
acetic acid is reaction
G fº for O 2 (g )
must have
(a) 235 kJ (b) 340 kJ (b) The free energy change in the
(c) 420 kJ (d) 491 kJ 55. For which of the following reaction
51. In the case of neutralisation of reactions, the entropy change (c) The energy of activation in the
weak acid with weak base in ( S) is negative? reaction
aqueous medium, the enthalpy of (d) Change in entropy and free
neutralization is low, because 1. C(s ) + H 2 O(g ) 
→ CO(g ) + H 2 (g ) energy in the reaction
(a) the reaction is slow 2. N 2 (g ) + 2O2 (g ) 
→ 2NO2 (g ) 60. The half life for a given reaction
(b) the electrolytes are partially was halved as the initial
ionized 3. N 2 (g,10atm)  → N 2 (g,1atm ) concentration was doubled. What
(c) a part of the energy evolved is the order of the reaction?
4. O 2 (g,1atm)  → O 2 (g,10 atm)
is utilized in the dissociation (a) Zero order (b) First order
of the electrolytes Select the correct answer using the (c) Second order
(d) the ions are solvated and codes given below: (d) Fractional order
hence more energy is required (a) 1, 2 and 3 (b) 1 and 4 61. Consider the following statements:
for effective collision (c) 2 and 4 (d) 2 and 3 An increase in the rate of a reaction
52. When hydrogen gas is subjected 56. If the entropy of vaporization of a for a rise in temperature is due to
to Joule-Thomson effect at room liquid is 110 JK–1 mol–1, and its 1. the increase in the number of
enthalpy of vaporization is 50,000 collisions
temperature, it gets heated up 2. the shortening of the mean
instead of being cooled, because J mol–1, the boiling point of the
free path
(a) hydrogen is the lightest gas liquid is
3. the increase in the number of
and hence can not be cooled (a) 354.5 K (b) 454.5 K activated molecules
(b) in hydrogen, the van der (c) 554.5 K (d) 394.5 K 4. the increase in pressure of the
Waals' force of attraction is 57. What is the free energy change system.
small G when 1.0 mol of water Which of the statements given
(c) it is a real gas and hence converted at 100ºC and 1 above are correct?
atmospheric pressure is converted (a) 1 and 2 (b) 2 and 3
behaves abnormally (c) 1 and 3 (d) 1, 3 and 4
(d) its Joule-Thomson coefficient to steam at 100ºC and 1 62. A 5.0×10 –3 molar solution of
is less than zero at room atmospheric pressure in a potassium permanganate has
temperature reversible manner? optical density of 1.5 at 680
53. The Joule-Thomson experiment is (a) –970 cal (b) –26 cal m using a 10 mm cell. Its
an example of which of the (c) zero (d) 970 cal extinction coefficient is
following proceses? 58. Match List-I with List-II and select (a) 0.75 lit mol–1 cm–1
1. Isothermal process the correct answer using the codes (b) 300.00 lit mol–1 cm–1
2. Isenthalpic process given below the lists: (c) 7.50 lit mol–1 cm–1
3. Adiabatic process List-I List-II (d) 30.00 lit mol–1 cm–1
63. High quantum yields of
4. Isochoric process 1 photochemical reactions are due to
Select the correct answer using the A. Ionic strength 1. Ci Zi2
2 (a) Lowering of activation energy
codes given below: B. Chemcial 2. (∂G/∂ni )T,P,nj (b) high frequency of collision
(a) 1 and 2 (b) 2 and 3 potential (c) Accompanying side reactions
(c) 1 and 4 (d) 2 and 4 C. Entropy of 3. nRT x i In xi (d) Formation of free radicals
54. The following equation represents Mixing 64. Consider the following statements:
the oxidation of glucose: The role of the catalyst is to
D. Frre energy 4. -nR n i In xi 1. reduce the activation energy
C6 H12O6 (s ) + 6O2 (g ) 
→ 6CO2 (g ) of mixing 2. increase the activation energy
+ 6H2O (l) Codes: 3. increase the rate of attainment
Following data is given : (a) A B C D
3 2 4 1 of equilibrium
Substance G fº (kcal mol–1) (b) A B C D 4. decrease the rate of attainment
of equilibrium
C6 H12 O 6 (s ) –218 1 4 2 3
Which of the statements given
(c) A B C D
CO2(g) –94 3 4 2 1 above are correct?
H2O(l) –57 (d) A B C D (a) 2 and 4 (b) 1 and 4
What is the standard free energy 1 2 4 3 (c) 1 and 3 (d) 2 and 3
of the reaction, ∆ Gº ? 59. During the course of chemical 65. The combination of SO2 and O2 to
(a) 67 kcal mol–1 reaction, the frequency factor A in give SO3 is catalyzed by NO. This
 catalyst is adversely affected by below: is almost twice that of H2O.
the presence of a trace amount of Codes: 76. Assertion (A) : When iodine is
As. Therefore, As acts as (a) Both A and R are individually heated under atmospheric pressure
(a) Auto catalyst true and R is the correct condition, it transforms to vapour
(b) Negative catalyst explanation of A without passing through the liquid
(c) Promoter state.
(b) Both A and R are individually
(d) Catalytic poison Reason (R) : If the triple point
66. Match List-I with List-II and select true but R is not the correct pressure of a system is high and
the correct answer using the codes explanation of A unless external pressure is applied
given below the lists: (c) A is true but R is false to exceed the triple-point pressure,
List-I List-II (d) A is false but R is true sublimation will take place.
A. Stability of 1. Protective 69. Assertion (A) : KMnO 4 and 77. Assertion (A) : The vapour
colliod efficiency K2Cr2O7 are intensely coloured pressure of 0.45 molar urea
B. Purification 2. Peptization compounds. solution is more than that of 0.45
of colloid molar solution of sugar.
Reason (R) : Transition metal
C. Gold number 3. Flocculation Reason (R) : Lowering of vapour
D. Formation of 4. Tyndall compounds having electrons in d-
pressure is directly proportional to
a sol effect orbitals are coloured due to d-d the number of species present in
5. Dialysis transition. the solution.
Codes: 70. Assertion (A) : Sodium metal can 78. Assertion (A) : For a weak
(a) A B C D not be obtained by the electrolysis electrolyte, the plot of molar
3 5 1 2 of its salt in aqueous solution.
(b) A B C D Reason (R) : Sodium is above conductivity (Am) against c (c
1 2 4 5 hydrogen in electro-chemical is concentration in mol lit–-1) is
(c) A B C D series and it reacts with water to nearly linear.
3 2 1 5 produce sodium hydroxide and Reason (R) : The molar
(d) A B C D hydrogen. conductivity at infinite dilution
1 5 4 2 71. Assertion (A) : The ligand field (Aºm) for an electrolyte can be
67. A silver iodide sol has been theory for complexes is also called considered equal to the sum of the
prepared by adding slight excess adjusted crystal field theory. limiting molar conductivities of the
of KI solution to AgNO3 solution Reason (A) : The results of ligand individual ions.
having the same concentration as field theory and adjusted crystal 79. Consider the following statements
that of KI solution. The silver iodide field theory are same after about base catalyzed dehydroha-
sol particles are adjusting some of the parameters logenation reactions of alkyl
(a) Positively charged in crystal field theory. halides:
(b) Negatively charged 72. Assertion (A) : The carbon- 1. They are -elimination
(c) Neutral halogen bond in an aryl halide is reactions
(d) Partially positively charged shorter than the carbon-halogen 2. They follow biomolecular
and partially negatively bond in an alkyl halide elimination mechanism
charged Reason (R) : A bond formed of an 3. They involve formation of an
68. In coagulating a negatively sp3 orbital should be shorter than intermediate carbocation
charged lypohobic colloid, very the corresponding bond involving 4. The eliminating groups or
little amount of AICI3 is required in an sp2 orbital. atoms must have trans-
comparison to amount of NaCl 73. Assertion (A) : In the addition of periplanar geometry
required, because Grignard reagent to carbonyl Which of the statements given
(a) The molecular mass of AICl3 compound, the R group of RMgX
above are correct?
is more than that of NaCl attacks carbonyl carbon
(a) 1, 3 and 4 (b) 2, 3 and 4
(b) The ionic charge of Al3+ is Reason (R) : The carbon-
(c) 2 and 3 (d) 2 and 4
three times that of Na+ magnesium bond of the Grignard
80. Match List-I (Reaction) with List-
(c) Al3+ ion is slightly smaller than reagent is highly polar, carbon
being negative relative to II (Reagent) and select the correct
Na+ in size answer using the codes given
electropositive magnesium.
(d) The charge density of Al3+ ion below the lists:
74. Assertion (A) : Cycloheptatrienyl
is more than that of Na+ List-I List-II
cation shows unusual stability.
Reason (R) : All unsaturated (Reaction) (Reagent)
Directions :– compounds having (4n + 2) A. Oppenauer 1. Peracides
The following 10 (Ten) items electrons show unusual stability. oxidation
consist of two statements: one 75. Assertion (A) : Considering van B. Baeyer-Villiger 2. CrO2Cl2
labelled as the 'Assertion (A)' and der Waal's equation of state for a oxidation
the other as 'Reason (R)'. You are real gas (P+n2a/V2) (V-nb)= nRT; C. Etard reaction 3. Red P+Br2
to examine these two statements the constant 'a' for O2 is much less D. Hell-Volhardt- 4. Zn/Hg, HCl
carefully and select the answers to than that for H2O(g). Zelinsky reaction
these items using the codes given Reason (R) : The molar mass of O2 5. Acetone/
Al-isopropoxide
 Codes: above are correct?
(a) A B C D (a) 1, 2 and 3 (b) 1, 2 and 4 4.
5 1 2 3 (c) 1, 3 and 4 (d) 2 and 4
(b) A B C D 84. Consider the following molecules: (a) 1 and 2 (b) 1 and 3
2 3 4 1 (c) 1 and 4 (d) 2 and 4
(c) A B C D 87. cis- trans isomerism is shown by
5 3 2 1 (a) CH3 CH = CHCH3
(d) A B C D
2 1 4 3 I. (b)
81. Match List-I (Reaction ) with List-
II (Reagent) and select the correct (c) CH3 CH2 CH = CH2
answer using the codes given (d) (CH3)2 C = C (CH3)2
below the lists: 88. Consider the following sequence
List-I List-II II. of reactions:
(Reaction) (Reagent) +
A. Wolff-Kishner 1. NaCN Which one of the following RMgX CH CHO
3→ A H 3O
→ B
reduction represents their correct The compound B is a
B. Wittig 2. Ph3P=CH2 configurational notation in terms (a) Carboxylic acid
reaction (b) Primary alcohol
of the Cahn-Prelog-Ingold system?
C. Benzoin 3. Conc. NaOH (c) Secondary alcohol
I II
condensation (a) R S (d) Tertiary alcohol
D. Cannizzaro 4. N2H4/KOH (b) S E 89. The organolithium reagent
reaction 5. NaOBr (c) R Z required for preparing nonan-5-ol
Codes: (d) S Z from ethyl formate in two steps is
(a) A B C D 85. (a) C9H19 Li (b) C8H17Li
4 3 1 2 (c) C4H9Li (d) C2H5Li
(b) A B C D
1 2 5 3 90. From which one of the following
(c) A B C D halides, a Grignard reagent can not
4 2 1 3 A. be prepared?
(d) A B C D
1 3 5 2 C6H5
82. Consider the following statements (a)
about chirality: Cl
H (b) CH2 = CH – Cl
1. Molecules which are not C6H5
B. Cl H CH 2 − C ≡ CH
superimposable on their mirror
images are achiral C6H5 (c) |
Br
2. A chiral molecule can have Which one of the following
simple axis of symmetry CH 2 − C ≡ C - CH 3
3. a carbon atom of which four statements regarding the (d) |
projections shown above (A and Cl
different groups are attached 91. Consider the following statements
is a chiral centre B) is correct?
4. a compound whose molecules (a) Both the projections represent about − diketones:
are achiral exhibits optical the same configuration 1. They show keto-enol
activity (b) Both A and B are optically tautomerism
Which of the statements given active 2. The enol form is capable of
above are correct?
(a) 1, 2 and 4 (b) 2, 3 and 4 (c) Only A is optically active forming an intramolecular
(c) 2 and 3 (d) 1 and 4 (d) Only B is optically active hydrogen bond
83. Consider the following statements 86. Which of the following 3. The methylene group flanked
about dimethylcyclohexanes: compounds can be represented as by two carbonyl groups can
1. trans-1, 2-dimethylcyclohe- threo and erythro isomers? be easily alkylated
xane is more stable than the Which of the statements given
corresponding cis-isomer
above are correct?
2. cis-1, 3-dimethylcyclohexane 1.
is an optically inactive meso (a) 1 and 2 (b) 1 and 3
form (c) 2 and 3 (d) 1, 2 and 3
3. trans-1, 3-dimethylcyclohe- 92. Consider the following statements
xane is more stable than the 2. about aromatic compounds:
corresponding cis-isomer 1. They are planar compounds
4. cis-1, 2-dimethylcyclohexane 2. They are annulenes having
is an unresolvable racemic 3. 4n-electrons
mixture
Which of the statements given 3. They sustain a ring current
4. They contain a delocalized
 electron cloud having (2n +4)
electrons
Which of the statements given
above are correct?
(a) 2 and 3 (b) 1 and 3
(c) 1, 2 and 4 (d) 2, 3 and 4
93. Benzene reacts with methyl
chloride in presence of anhydrous
AlCl3 to give toluene. The reaction
is called
(a) Alkylation of benzene
(b) Friedal-Craft's reaction
(c) Methylation
(d) All of the above
94. The number of electrons in
anthracene according to Huckel
rule is
(a) 12 (b) 14
(c) 10 (d) 20
95. Which one of the following
descriptions correctly defines a fat?
(a) Fats are a mixture of sodium
salts of long chain fatty acids
(b) Fats are carboxylic esters
derived from glycerol
(c) Fats are carboyxlic esters
derived from a mixture of
simple alcohols
(d) Fats are sodium salts of
alkylbenzene sulfonic acids
96. Consider the following statements
about sucrose:
1. Hydrolysis of sucrose with
dilute acid yields an equimolar
mixture of D-glucose and D-
fructose
2. Acid hydrolysis of sucrose is
accompanied by a change in
optical rotation
3. In sucrose, the glycosidic
linkage is between C 1 of
glucose and C2 of fructose
4. Aqueous solutions of sucrose
exhibit mutarotation
Which of the statements given
above are correct?
(a) 1, 2 and 3 (b) 1 and 4
(c) 2, 3 and 4 (d) 2 and 4
97. The configurational description of
the C2 epimer of D-glucose is
(a) 2R, 3S, 4R, 5R
(b) 2S, 3S, 4R, 5R
(c) 2S, 3R, 4S, 5R
(d) 2R, 3S, 4R, 5S
98. In peptide chemistry phenyl
isothiocyanate is used
(a) for identifying the C-terminal
residue of a peptide chain (c) I < III < II (d) III < II < I
(b) for identifying the N-terminal 102. The number of signals that appear
residue of a peptide chain in the 1 H − NMR spectrum of
(c) for protection of the amino
group in peptide synthesis
(d) as a reagent for bringing about
coupling between the
carboxyl and amino groups in is
peptide synthesis (a) Five (b) Two
99. Kiliani-Fischer synthesis converts (c) Three (d) Eight
an aldopentose to a 103. Consider the proton NMR
(a) mixture of aldohexose and
spectrum of the following
ketohexose compound:
(b) mixture of aldohexoses
ClC H 2 − CHCl 2
differing in configuration at C6
(c) mixture of aldohexoses
(I ) (II)
differing in configuration at C2 Which one of the following
(d) single aldohexose correctly represent the
100. Match List-I with List-II and select multiplicities of the signals due to
the correct answer using the codes the protons marked I and II
given below the lists: respectively?
List-I List-II (a) Doublet, Singlet
(b) Singlet, Doublet
A. n → * 1. Bathochromic
(c) Doublet, Triplet
transition shift (d) Triplet, Doublet
B. → * 2. Forbidden 104. the compressibility factor for
transition transition hydrogen at room temperature and
C. → * 3. Occurs in the at any range of pressure is
transition vacuum UV (a) less than 1 (b) equal to 1
region (c) greater than I (d) zero
D. Extended 4. Strong 105. A gas can be liquefied at a
conjugation absorption temperature T K and pressure P
with high provided that
value (a) T = Tc and P < Pc
Codes: (b) T < Tc and P > Pc
(a) A B C D
4 1 2 3 (c) T > Tc and P > Pc
(b) A B C D (d) T < Tc and P < Pc
2 3 4 1 106. If the average speed of N 2
(c) A B C D molecules at 300 K is 515 m/s, the
4 3 2 1 average speed of CO at 600 K
(d) A B C D
2 1 4 3 would be approximately,
101. Consider the carbonyl stretching (a) 515 m/s (b) 1030 m/s
frequency in the infrared spectra (c) 258 m/s (d) 725 m/s
of the following compounds: 107. The mean free path ( ) of a gas is
CH 3 − CO − NH − CH 3 given by the expression
I 1
=
C6 H 5 − CO − NH − CH 3 2 n 2
II where n is the number of molecules
CH 3 − CO − NH − C6 H 5 per unit volume of the gas and
is the collision diameter. The mean
III free path is
Which one of the following is the
(a) independent of temperature
correct increasing order of the
but dependent on pressure
carbonyl stretching frequency?
(b) independent of pressure but
(a) I < II < III (b) II < I < III
dependent on temperature
 (c) independent of concentration assumed? (a) 1 and 2 (b) 2 and 3
(d) dependent on both pressure 1. The solution is dilute (ideal) (c) 3 and 4 (d) 1 and 3
and temperature 116. Consider the following statements:
2. The H f (latent heat of
108. An equilibrium mixture for the The ionic conductivity of Na+ ions
reaction fusion of pure solvent) is
independent of temperature is greater than that of the Li+ ions
2 A 2B g 2A 2 g + B2 g in aqueous medium, because
between the actual and normal
had 0.5, 0.1 and 0.4 moles of A2B, freezing point 1. the ionic radius of Na+ ion is
A2 and B2 in a two litre vessel 3. The solid-phase consists of greater than that of Li+ ion.
respectively. The equilibrium pure solvent 2. the velocity of Na + ion is
constant (K) is
Select the correct answer using the greater than that of Li+ ion.
(a) 0.004 mol lit–1
(b) 0.008 mol lit–1 codes given below: 3. the Li+ ion is more solvated
(c) 0.016 mol lit–1 (a) 1 and 2 (b) 2 and 3 than Na+ ion in water
(d) 0.032 mol lit–1 (c) 1 and 3 (d) 1, 2 and 3 4. Li + ion and Na + ion have
109. When a liquid is in equilibrium with 113. If the molar solubility of La(OH)3 different electron densities.
its vapour, the thermodynamic at 298 K is x, the solubility product Which of the statements given
criterion for equilbrium is Ksp is
(a) Entropy of the liquid phase is above are correct?
(a) 3x3 (b) 9x2
greater than entropy in the (a) 1 and 3 (b) 2 and 3
(c) 27x 3
(d) 27x4
vapour phase (c) 1 and 4 (d) 2 and 4
(b) Enthalpy of the liquid phase 114. Match List-I (Term) with List-II
117. The limiting molar conductivities
(Unit) and select the correct answer
is less than enthalpy in the
vapour phase using the codes given below the ( )
at infinite dilution A ºm at 298 K
(c) Chemical potential in the liquid lists: for KOH, KNO3 and NH4NO3 are
phase is equal to the chemical List-I List-II 239, 125 and 128 S cm 2 mol –1
potential in the vapour phase (Term) (Unit) respectively. If a 0.1 M solution of
(d) Gibbs free energy of the two A. Dissociation 1. mol lit–1 NH4OH has a molar conductivity
phases is different constant of of 24 S cm2 mol–1, the degree of
110. Consider the following: acetic acid dissociation is
1. Sodium chloride B. Ionic product 2. mol2 lit–2 (a) 0.024 (b) 0.24
2. Sodium nitrate of water (c) 0.10 (d) 0.05
3. Sodium bromide C. Extinction 3. lit mol–1cm–1 118. The standard electrode potentials
Which is the correct increasing coeffcieint of Ni2+ | Ni and Co2+ | Co are –0.25
order of the solubility of silver D. Gas constant 4. lit mol–1 atm and –0.28 volts respectively. The
chloride in 0.1 M solution of the deg–1 voltage of the cell Co | Co2+ (a = 1)
above compounds? Codes: || Ni2+ (a =1) | Ni is
(a) 1 < 2 < 3 (b) 2 < 3 < 1 (a) A B C D (a) +0.03 V (b) –0.03 V
(c) 3 < 1 < 2 (d) 1 < 3 < 2 1 2 3 4 (c) +0.53 V (d) –0.53 V
111. Solution A is prepared by (b) A B C D 119. The chemical reaction
3 2 1 4
dissolving 1.80 gm of glucose in Zn(S) + 2HCl(1 M ) = ZnCl 2 (1 M ) + H 2
100 ml of water and solution B is (c) A B C D
1 4 3 2 (1 atm)
prepared by dissolving 1.2 gm of
acetic acid in 200 ml of water. (d) A B C D Hº = −153kJ mol−1
Which one of the following is 3 4 1 2
Sº = –17.3 JK–1 mol–1
correct? 115. Which of the following will act as
can be carried out reversibly in a
(a) The osmotic pressure of A buffer solution?
voltaic cell.
1. 100 ml of 0.1 M NaOH + 100ml
( A ) > osmotic pressure of B ( B ) If the standard enthalpy and
of 0.1 M acetic acid entropy changes for the reaction
(b) A = B 2. 100 ml of 0.1 M NaOH + 200ml at 298 K are those given above, the
(c) < of 0.1 M acetic acid maximum electric work available
A B
3. 200 ml of 0.1 M NH3+100 ml of from the reaction at this temperature
(d) A = 2 B per mol of H 2 produced is
0.1 M HCl
112. Freezing point lowering expression 4. 100 ml of 0.1 M HCl +100 ml of approximately equal to
is Tf = K f m 0.1 M Sodium acetate (a) 5 kJ (b) 148 kJ
Select the correct answer using the (c) 153 kJ (d) 158 kJ
where K f = R Tf2 /1000 Hf 120. Match List-I (Scientist) with List-
codes given below:
which of the following are II (Contribution) and select the
 correct answer using the codes 55. d 56. * 57. b 92. (b) Aromatic compounds are
given below the lists: 58. d 59. c 60. b charac
List-I List-II 61. c 62. * 63. d terized by planarity, extra stability
(Scientist) (Contribution) and (4n +2) number of delocalized elec-
4. c 65. d 66. a trons
A. Michaelis 1. Effect of
Menton temperature on the 67. a 68. b 69. a where n is a whole number.
reaction rate 70. a 71. a 72. c
B. Arrhenius 2. Enzyme catalysis 73. a 74. a 75. b
C. Eyring 3. Photochemical 76. a 77. c 78. d
reaction 94. (b)
79. a
D. Einstein 4. Transition state
theory 80. c (Jerry March)
Anthracene
5. Collision theory 81. c 82. c number of electrons = 14
Codes: 83. a (Jerry March) 99. (c) The pair of aldores obtained
(a) A B C D 84. b 85. c 86. * from the kiliani -F ischer synthesis
2 4 5 3 differ only in configuration about
87. a 88. c 89. b
(b) A B C D C-2 and hence are epimers.
3 1 4 2 90. c 91. a 92. b
116. (a) Because of very small
(c) A B C D 93. c (Soloman) size of Li+ ion.
2 1 4 3 94. b (Jerry & March) uuu
(d) A B C D 95. b 96. a
3 4 5 2 97. c
Author: Professor Anand
98. c (Jerry & March)
Answers Shekhar
99. c 100. c 101. c
Available online at
102. b 103. c 104. a
1. b (Cotton & Wilkin Page 234) www.kadiravan.com.
2. b (Cotton & Wilkin) 105. b
3. d (Cotton & Wilkin) 106. b (Atkins)
4. b (J. D. Lee) 107. c 108. c 109. d
5. a (Cotton & Wilkin) 110. d (Atkins)
6. a (J. D. Lee) 111. b 112. d 113. d
7. b (J. D. Lee) 114. a
8. d (J. D. Lee) 115. b (Atkins)
9. b 10. b 11. b 116. a 117. a 118. d
12. c 13. c 14. c 119. c 120. c
15. b 16. c 17. b
18. d 19. a 20. a EXPLANATION:
21. a 22. b 23. d
24. d 25. a 26. c 2. (b) P4 O10 does not give phospho-
27. d 28. a 29. c rus
acid on reacting with H2O
30. b 31. b 32. b
O
33. c 34. b 35. c |
20. (a)
36. b 37. d 38. d CH 2 = CH − C + — CH 3
39. d 40. b 41. d 23. (d) Aldol condensation does not
42. c 43. b 44. c involve carbocation intermediacy
45. b 46. b 47. a 30. (b) dxy point in between the axis
48. a (Cotton & Wilkinson) [ ]
Gº = Gfº Products [ ]
− Gfº Reactants
54. (c)
49. d 50. d 51. c = [(6 × −94) + (6 × −57)] − [1× −218]
52. b (Puri & Sharma) = –564 – 342 + 218
53. b = – 906 + 218
54. c (Puri & Sharma) = – 688K Cal mol–1