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Solder Analysis STRENGTH Rep 20nov2006
Solder Analysis STRENGTH Rep 20nov2006
626
2. FE-MODELING OF THE MINIMELF Figure 2 schematically defines the geometry of axial and
STRUCTURE sideward displacement between the MiniMelf and the
2.1 Discretization of the Structure and its copper pad as used by Siemens and for the FE-
Components calculations.
The finite element model of the MiniMelf consists of the
following structural components (see Figure 3): an elec- surface covering
tric resistor made of an Alumina ceramic, two caps made
of SnPb-Ni plated iron, two solder joints, two copper 100% 50%
pads, and an FR-4 laminate. The solder material can no displacement axial (x-) displ. sideward (y-) displ.
deform elastic-plastically and is also susceptible to creep.
Linear-elastic stress-strain relations are assumed for all y y y
other materials.
cap
In order to study the influence of different processing
technologies on reliability and lifetime the solder joints
are modeled from real micrographs. Figure 1 provides pad x x x
some information regarding the test method (Mil-Std-883,
method 1011, condition B) which was used for acceler- resistor
ated aging of the actual structure as well as for loading
input during the FE-calculations.
Fig. 2: Definition of Axial and Sideward Displacement
T(°C)
In Figure 4 real micrographs together with the FE-meshes
180
of reflow- as well as wave-soldered joints of a MiniMelf
125 structure are presented, before and after several thousand
thermal cycles, with and without axial and sideward dis-
placement. Note that due to symmetry only a quarter or
16
half of the structure needs to be analyzed. Table 1 pro-
time t vides information regarding the degrees of freedom
-55
(DOF) of the various FE-meshes and the type of elements
used for discretization.
30min 10sec
Fig. 1: Loading History According to Mil-Std-883,
Method 1011, Condition B
right solder
joint
copper pad
627
reflow, no displacement:
reflow, x-displacement:
reflow, y-displacement:
wave, no displacement:
wave, x-displacement:
wave, y-displacement:
Fig. 4: MiniMelf Structure, Solder Joints Before and After Thermal Cycling, and FE-Mesh
628
Table 1: Finite Element Mesh Data 1
Sij = σ ij + pδ ij , p = − σ ii , (2.3)
3
processing configuration element types DOF
reflow no C3D20R 9189 ε epl is the current equivalent plastic strain:
soldered displacement C3D15
x-displ., 50% 27852
2 pl pl
y-displ., 50% 18525 ε epl = ∫ 3
d ε ij d ε ij , (2.4)
wave no C3D20R 12927
soldered displacement C3D15 and σ Y denotes the current yield stress which is deter-
C3D10
mined as a function of equivalent plastic strain from uni-
x-displ., 50% C3D10 14451
axial loading experiments. In what follows the von Mises
y-displ., 50 % C3D20R 17481
yield criterion will be used together with an elastic-linear
C3D15
isotropic strain hardening law (for material data see Ta-
C3D10
bles 2-4).
Note that with the exception of the wave soldered Mini- In order to mathematically describe the change in strain
Melf with axial displacement all FE-models were built by due to thermal loading isotropic material behavior is as-
using quadratic brick elements with reduced integration. sumed:
Tetrahedra and triangular prisms were used for improved
shaping as well as for filling. Due to time-constraints the dε ijth = αdT δ ij . (2.5)
mesh of the wave-soldered configuration with axial dis-
placement was created automatically by means of the In this equation α represents the coefficient of linear
appropriate routines provided by the CAE software thermal expansion, dT is the change in temperature, and
IDEAS. It is based on quadratic tetrahedra with ten δ ij denotes the Kronecker tensor.
nodes.
For isotropic materials the creep strain rate is described by
2.2 Theoretical Background and Material Parameters a hyperbolic flow rule which was used before in the litera-
In this paper the accumulation of irreversible strains and ture (see Darveaux et al. [7], Pan [12] and Osmat [13]):
energies during thermal cycling of the MiniMelf structure
is used as a measure of the development of damage in the ⎛ ∆H ⎞
[ ]
ε& ecr = A sinh( Bσ e ) exp ⎜ −
n
solder material. These strains may result from plastic ⎟ (2.6)
⎝ Rθ ⎠
deformation as well as from creep. In order to describe
the material behavior of the solder 62Sn36Pb2Ag it is where A, B, n are material constants, ∆H is the activation
assumed that the increment of the total strain, dε ij , can enthalpy, R is the gas constant, and θ denotes the abso-
additively be decomposed into four parts: elastic, dε ijel , lute temperature. Moreover, the equivalent stress, σ e , is
(reversible), plastic, dε ijpl , (irreversible but independent of defined as follows:
the loading rate), creep, dε ijcr , (irreversible and dependent 3
σe = Sij Sij . (2.7)
on the loading rate), and thermal, dε ijth , as follows: 2
dε ij = dε ijel + dε ijpl + dε ijcr + dε ijth . (2.1) Once the stresses and irreversible strain rates are known
they can be used to obtain the corresponding dissipated
In order to compute the contribution of irreversible plastic energy densities:
deformation to the strain the Prandtl-Reuss equations of
time-independent J 2 -plasticity are solved: ∫ ∫
W pl = σ ij d ε ijpl , W cr = σ ij d ε ijcr . (2.8)
629
Table 2: Material Data for Hyperbolic Creep Law creased. Note that the locations of maximum strain do not
always correspond to the location of experimentally ob-
∆H [J mol ]
-1 -1 -1
A [sec ] B [Pa ] n
served first failure. This may be attributed to local imper-
Darveaux et 9.62*104 8.7022*10-8 3.3 67426
al. [7]
fections in the real situations as well as to insufficiently
Osmat [13] 1.17*1025 5.8015*10-11 5 84200 detailed FE modeling (in particular intermetallic layers at
Pan [10,12] 1.746*10 6
1.2594*10-7 1.88882 61417
the interface between the solder joint and adjacent com-
ponents were not implemented). Figure 5 displays the
maximum of the equivalent plastic and of the equivalent
As it was mentioned before all components of the Mini- creep strain as a function of time.
Melf with the exception of the solder were treated as 0.012
t [sec]
0.70
shear G xz = G zy = 3.0, N/A N/A N/A
moduli reflow, no displ.
G xy = 8.4 0.60
(GPa) reflow, y- displ.
wave, no displ.
CTE α x = α y = 15.9 , 16.6 12.0 5.4 0.50 wave, y- displ.
(10-6·1/K) wave, x- displ.
equivalent creep strain
α z = 80.0
0.40
630
plastic strain distribution creep strain distribution
∫ ∫
2 pl pl 2 cr cr
ε epl = dε ij dε ij ε cr
e = dε ij dε ij
3 3
reflow,
no displacement
reflow,
y-displacement
wave,
no displacement
wave,
x-displacement
wave,
y-displacement
Fig. 6: Plastic vs. Creep Deformation in Solder Joints of a MiniMelf Structure after Several Cycles (Arrows
Point to the Location of Maximum Deformation)
3.2 On the Importance of the Creep Parameters plastic as well as creep strain is independent of the choice
In order to quantitatively assess the influence of the dif- of constants. However, the absolute value of the resulting
ferent sets of creep constants (Darveaux et al. [7], Ozmat strain varies considerably (cf., Figure 7): If the creep
[13], and Pan [10,12], see Table 2) on the development of parameters of Pan [10,12] are used, 11.3% of equivalent
irreversible strains various FE-runs were performed. It creep strain results after one cycle, whereas the data by
turns out that the location of the maximum of equivalent
631
Darveaux et al. [7] and Ozmat [13] lead to 8.2% and 5.8% −γ
⎛ ∆ε cr ⎞
of maximum strain, respectively. Nf = ⎜ e ⎟ (4.1)
⎝ C ⎠
0,009
the increment of creep strain per cycle, ∆ε cre , can be used,
0,008
in combination with two material parameters, C = 0.497
0,007 and γ = 2.457, to predict the number of thermal cycles,
equivalent plastic strain
t [sec]
Fig. 7: Maximum of Equivalent Plastic and Creep
Strain as a Function of Time for Different
Creep Constants
632
( )
−0.626
N 0 = 13579
. ⋅ 105 ∆W cr . (4.3)
( )
−0.469
N 0 = 5.68 ∆ε cr
e , (4.2)
†
An assumption that seems justified in view of Figure 5.
633
Table 8: Cycles to Failure Predicted with the Energy and strains at thermo-mechanically loaded interfaces
Partitioning Approach. become infinitely large. Consequently, the FE-results
which were obtained depend upon the mesh size and the
reflow, no displ. wave, no displ. principle use of such quantities as strain and energy densi-
Nf ≈17 ≈28 ties for damage law evaluation becomes quite problem-
atic.
4.4 Oxidation Damage Law
In fact this issue was addressed before in the paper by
According to Huang et al. [9] the number of cycles to
Paydar et al. [17] who showed that for the test conditions
failure in solder subjected to atmospheric oxidization can
considered there exists a strong dependence of the com-
be computed from:
puted irreversible strains from the size of the used mesh.
1
Nf = (4.7) For the solution of this problem Paydar et al. [17,18]
⎛ Qa ⎞
KW ∆W cr + K0 exp⎜ − ⎟ tD suggest to study the variables of interest at a certain radial
⎝ 2 RTmax ⎠ distance, R, from the singular interface. This radius is
chosen such that it leads into regions of the solder remote
where various parameters have been used (see [9]): Tmax from the singularity but characteristic for the actually
= 398 K (maximum temperature), t D = 1800 sec (hold observed critical strains. The procedure is illustrated in
Figure 10. However, it should be noted that, in general,
time), Qa = 26300 J mol (activation energy for atmos-
this approach does not allow to easily switch from one
pheric oxidation), KW = 6.2 ⋅ 10 −2 mm3 J , and K0 = geometry to another and that the proper radial distance
12.2 ⋅ 10 sec . The resulting critical number of cycles
−3 -0.5 can reliably only be identified in combination with metal-
are summarized in Table 9. Note that the second expo- lograhic observations. Therefore this method will not be
nential factor in the denominator of Eqn. (4.7) is domi- considered further in this paper.
nant and, therefore, no difference between the critical
loading cycles can be observed in Table 9. This is consis-
tent with the results presented by Huang et al. [9]. In
comparison with the experimentally obtained lifetimes
shown in Table 6 it must be concluded that Eqn. (4.7) in
combination with the materials parameters used overesti-
mates the influence of atmospheric oxidation, at least for
the testing procedure used in the case of the MiniMelf
(Mil-Std-883, method 1011, condition B with an upper
hold temperature of 125 °C). Fig. 10: Dimensions and Characteristic Radius for a
Solder Joint According to Paydar et al. [18]
Table 9: Cycles to Failure Predicted with an
4.6 Case-Criterion
Oxidation Damage Law
A more feasible method in order to arrive at a lifetime
reflow, no displ. wave, no displ. prediction that avoids the singularity problem is to suita-
Nf 104 104 bly average the parameters of interest with respect to the
total volume of the solder joint. For example: Compute
the total energy dissipated in the solder joint (which is
4.5 Preliminary Summary of Results and Discussion non-singular) and divide by the total volume of the solder
By comparison of the numerically obtained lifetimes to obtain an expression for the current dissipated energy
shown in Tables 5, 7-9 with the experimental results of density. This value can now suitably be compared with
Table 6 it must be concluded that none of the damage the critical energy density, Wf , which, according to Pan
laws presented so far leads to a realistic description unless
the material parameters in these laws are “adjusted.” Note [10], is a material constant: Wf = 4.55 ⋅ 10 8 J m 3 .
that in all relationships either the maximum of dissipated
A detailed FE-analysis of a reflow soldered MiniMelf
strain or dissipated strain energy density was used to
without displacement shows (cp., Figure 11) that the in-
predict the critical number of cycles. For all the variants
crease of energy per cycle due to creep is a constant and
of the MiniMelf structure that were studied these maxi-
equal to ∆W = 2.84 ⋅ 10 5 J ( m 3 cycle ) if divided by the
cr
mum values occurred at the interface between the solder
joint and the metal cap or the copper pad, respectively. volume of the solder. In contrast to that the averaged
energy dissipated due to time-independent plasticity,
It is well known that within the framework of the continu- pl
um mechanics theory presented in Subsection 2.2 stresses ∆W , decreases with increasing number of cycles.
634
Moreover, it is by an order of magnitude smaller than Wf
cr Nf = . (4.9)
∆W . ∆W + ∆W cr
pl
1,2E-05
show that in order to arrive at a lifetime prediction which
1,0E-05 is not too conservative the irreversibly dissipated energy
averaged with respect to the total solder volume can sim-
8,0E-06
ply be used without additional parameters.
6,0E-06
Table 11: Cycles to Failure Predicted with Damage
4,0E-06 time-independent plasticity Law According to Vaynman and McKeown
time-dependent plasticity
2,0E-06
reflow, no displ. wave, no displ.
0,0E+00 Nf 1600 3140
1 1,5 2 2,5 3 3,5 4
635
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