mlffc nAx cuAu nn0N rr6.

L uoc
Cffu 1. (tF ai6m)
1. (0,75 di6m) Cho BaO vio dung dich HzSO+ thu dugc kCt tta A, dung dch B. ThOm mQt luqng du b6.t

nh6m vao dung dich B thu dugc dung dich C vi khi H2 bay 16n. ThCm dune dich-K2CO3 vao dung dich C

tt 6y tinhrutiSt tua D. X6c dinh thenh ph&r cua A, B, C, D vi vii5t PTHH cria c6c phan ung xiy ra
NQi dung Di6m
Cho BaO vao dung dich HzSO+ 02s
BaO+HzSO++BaSO+J+H2O
BaO + H2O + Ba(OH)z (n6u c6)
f6t tua A li BaSOa, drurg dlch B c6 th6 h HzSO+ du hoqc Ba(OH)2
* THI: Dung li
dch B dung dich H2SOa du 02s
2N +3HzSOa
- Alz(SO+) 3 + 3H2
Dung dich C ldAldSO4)3
Alz(SOa)r + 3NazCO: + 3HzO + 2AI(OH[ + 3CO2 + 3NazSOe
f6ttuaDhAl(OfD3
* Tl12: Diing dich B ld Ba(Og2 0125

Ba(OH)2 + 2IlzO + 2N-' Ba(AlOz)2+ 3tfz

Dung dich C li dung dich Ba(AlO)2

Ba(AlOz)z + Na2CO3 + BaCOs + 2NaAlOz

fiSt tua D ld BaCO3

2. (0,75 chi dung th6m dturg dich NaOH vd dugc ph6p dun n6ng,
rc.7s ili6m) Chi hiy trinh biy phuong ph6p h6a
hqc de ph6n biQt c6c dung dich ri6ng biQt NaCl, Ba(HCO:)2, FeClz, MgCl2, NI{4C1, BaClz.

NQi dung Di5m

- Dun n6ng ntrg c6c dung dich m6u thri: 0,15
+ Dung dlch ndo c6 sui bqt khf vd c6 ktit tua r6ng xu6t hign li Ba(HCO3)2
Ba(HCq)2 + COzT + HzO
-)BaCOrJ
+ Circ dung dich cdn l+i k*r6ng c6 hi-Gntuqng gi
- Cho dung 0,15
dch NaOH vdo c6c miu thri cdn lpi:
+ Dung dich FeClz xu6t trign t6t tua ting xanlr, h6a ndu ngoai ktdng khf

FeClz + 2NaOH -- Fe(OtDzl + 2NaCl

. 4Fe(OfD, +Oz+2HzO -+4Fe(OH)3[

+ Dung dichNHnCl c6 ktrf mui khai bay ra: 0,15

NH4CI + NaOH NaCl + NHrt + HzO

-
+ Dung dich MgClz c6 k6t tuatreng xu6t hign: 0,15

MgCl2 + 2NaOH Mg(OH)2 + 2NaCl

-
+ Dung dich nao kh6ng c6 hi€n tuqng gi ld BaCl2 vi NaCl.
- Cho dung dlchNaOH du vao dung dlch Ba(HCO3)2: 0,15

2NaOH + Ba(HCOr)2 + BaCO3I +Na2CO3 + 2H2O

Lgc bo t<i5t Ura BaCOs, thu 6y dung dch nu6c 19c chua NazCO:, NaOH du, ctro dung
dich ndy tac dgng voi 2 dung dich BaClz, NaCl.
+ Dung dich BaClz c6 k6t tua t6ng xu6t nien:

BaClz +NaaCO3 -+ BaCOr J + 2NaCl

+ Dung dchkhdng co hi€ntuqng liNaCl.

Ciu2. (1,5 tli6m)

1. (0,75 tti6m) C6 cdc dung dich vi cMt l6ng dpg trong cdc lq ri6ng biQt h6 tinh bQt, axit a:retic, nrgu
etylic, ch6t bdo, glucozcr duo. c diinh s6 ngdu nhi€n (l), (2), (3), (4), (5). Bi& (l) tham gia phAn rmg tdng
bac (phan tmg trlng guong); (z)tac(rng duo. c voi dung dich NaFICOT; tir (3) bang hai phan fmg h6a hgc
teo ra (a) vd tu (4) b6ng mQt phan ung h6a hgc tqo ra (2); (5) k{ri tac dgng voi dung dich NaOH tao ra hai

san phdm htiu ccr. Xric dinh c6c chitrmg voi cdc s6 ttru t.u (l), Q), (3), (4), (5) vd viiSt ptl*t ctia c6c
phan tmg x6y ra
NQi dung Di6m
(1) li glucozn; (2) li arit axetic; (3) H tinh b$t; (a) h rugu etylic; (5) h ch6t b6o. 02s
PTFIH: CoFIrzOo + Ag2OCoFIrzOz + 2Agl 0'5
CH3COOH +NaFICOT CHTCOONa+ HzO + COz
(CoFIroOs)n * nH2O--+ nC6H12O6
-
enzim
C#IrzOo >2CzHsOH+2COz
CzHsOH + 02 4''^
>CHgCOOH + HzO
+
RqOO)sC:Hs 3NaOH --+ 3RCOONa + C:Hs(Ott)r
(0; di6m) Cho c6c
2. rc.75 Cfu,CzIh,Czfu,CzHa, C2H5CI, C6H6 (benzen), C6H5CI (clobenzen). HEy
viiSt so d6 chuy6n h6a bi6u di6n mdi li6n hQ gita cric ch6t tr€n. ViiSt PTfil{ ctra c6c phan rmg xiy ra theo

so d6 chuyen h6a d6.

NQi dung Ei6m

')
cH, trr ,
c#, -l3bcrn, dP crnu
(s)
c2H5cl
02s
(6)l

+
C6H6
-gCoFIsCl
PTHH: 05
0) 2crl4 ##i",,h+ c2a2+3H2
A) CzHu+*%cztu
(3) CzHa+Hz ACzFk
(4) ACzH++Hz
crrL
(5) CzHe +Cb -- CzHsCI +HCl
 6000c
3CzHz --il Cogo
.Fe-

Ciu 3. (1,5 ili6m)

1. (0,5 tli6m) BIng phuong ptuip h6a hqc h6y tlch ri6ng COzralJr6i h6n hqe khf gdm: SO2, SO3, 02,

COz. Vitit PTHH cua cric phan rmg xiy ra.

NQi dung Di6m

- D6n h6n hgrp k*ri qua dung dich BaClz du thi SOr bi h6p tftr h6t, thu 16y h6n hW khf 0r25

bay ru:

SO3 + BaClz+ H2O + BaSO+ +2HCl

- Dan hdn hgp khf cdn lar qua dung dich Brz du, SO2 bi Mp thu hiit, ttru 6y h6n hqp khi

bay ra:

SO2 + Br2+2ll2O -+ 2HBr + HzSO+

- DAn h6n hqp 2 lrtrf con ler qua dung dch NaOH du thi COz bi Mp thp hi5t: 02s
CO2+2NaOH --+ NazCOr + H2O
Cho dung dich tao thenh tdc dUng voi dung dich HzSO+ lo6ng, du, thu 6y lJri CO2bay ra
NazCOl + HzSO+ * NazSOa + H2O + COz

2. (1,0 ili0m) DC hda tan hoan toan 15,84 gam h5n hqp Q g6m FezO:, CuO, Fe3Oa cAn dung h0t 540 ml

dung dich axit HCI I M. MAt khac, n6u l6,y 0,275 mol h5n hqp Q d5t n6ng trong ting st (kh6ng c6 khdng
khi), r6i thdi mQt lu6ng khi Hz du di qu4 sau khi phan rmg xhy rahoan toan thu dugc m gam ch6t rin vn

12,15 gamH2o. Tinh m vi thanh phan phan ffim kh6i lugng cia cdc ch6t c6 trong h6n hqp Q ban dAu.
NQi dung Di6m
Ggi s6 mol Fe2O3, Fe3Oa, CuO c6 tong 15,84 gam h6n hqp Q l6n luqt ldx, y, z.Tac6: 02s
l60x+ 232y + 802:15,84 (1)
rIHCI= 0,54.1:0,54 mol
* 15,84 gam Q + HCI: 02s
FezOr + 6HCl 2FeCls + 3HzO
-
x6x
FerOn + 8HCl -+ 2FeClr + FeClz + 4IlzO
y8y
CuO+2HCl-CuClz+HzO
z2z
+ nHct= 6x + 8y t 2z:0,54 A)
* 0,275 mol 02s
Q + H2:
FezOr + 3Hz +2Fe+ 3HzO
 lo< 2lo(. 3kx
FetO+ + 4Hz+ 3Fe + 4H2O

ky 3ky 4ky
CuO+H:+ Cu +HzO
la, kz kz

- 56 mol H2O = 3k + 4W + le,: 0,675 (3)

Mat kh6c: to( + ky *ka= 0,275 (4)

Tt(3)vd(4):6x+l7y-16z=0 (5)
Giai hQ 0), (2),(5), ta du-o. c: 02s
x=0,05; y:0,02;z:0,04
: 2,5,
Thay x, y, z vito (3) ta duo. c k

Vfly nr. : 2.5.0,025 + 3.5.0,01 : 0,4 mol; ncu : 5.0,02 : 0,1 mol
-+ m: 56.0,4 + &.0,1= 28,8 gam
% lrh}i ltqmg FezOr = 50,5o/o; o/oF etO+ : 29,29Yo; %CuO = 20,2 lo/o

CAu 4. (1p5 tli6m) Cho m gam h6n hqrp Na2CO3, KzCO: vin 221,76 gam nudc dugc22l,76 ml dung

dich A c6 D : 1,0822 gan/ml. Cho tu tu dung dich HCI O,zMvdo dung dich A vd ludn klruAy ddu ttr6y

thodt ra 4,4 gam khi COz vi cdn l4i dung dich B. Cho dung dch B t6c dpng voi dung dich Ca(Ott)2 du
thuduo.c 6 gamk6ttua.

1. Tinhm.
2.Tirh*r6 Uctr dung dlch HCI 0,2 M iH dung.
3. Tinh n6ng itQ phan mm cdc chhtrong drxrg dich A.
NQi dung Di6m
1. Thay NazCOt vd KzCOr blng mQt chit tucrng duong h M2CO3 02s
Khi nh6 tu tir dung dich HCI vao dung dch A thi phan ung xiy ra theo thrl t.u:

MzCOs+HCl+MHCOT+MCl
xxx
MHCO3 + HCI -+ MCI + HzO+ COz
0,1 0,1 0,1

MHCO3 + Ca(OH)z du * CaCOr + MOH + HzO i

0,06 0,06
+x:0,1 +0106:0,16mol
M[t l,ih6c: khOi luqrrg MzCQ + t<trOi lugng HzO : klr5i tuqng dd A 02s
.-- kh6i lugng lvl2cq : kh6i lugng dd A - l,rtrOi luqng HzO = 221,76.1,0822 -221,76 =
18,228672 gam.
a

-) m: 18,228672 gam.

2. SO mol HCl: x * 0,1 : 0,16 * 0,1 : 0,26 mol 02s

- Vdd HCI = Ai,26/0,2: 1,3 lit
'. ,
3. Gqi a, b hn luqt li s6 mol cta NazCOr vi KzCOg c6 tong m gam h5n hgrp,'ta c6 hQ 02s
PT:

a+b=0;16 (t)
l06a+ 138b: 18,228672 Q)
Giei h$ (1), (2) tac6: a:0,120354;b:0,039646
C% NazCO3 tong A : ( I 06.0,1203 5 4.100W Q21,7 6.1,0822) : 5,3 I 6Yo 02s
C% K2CCa trong A = ( I 3 8. 0, 03 9 & 6.1 00%y Q21,7 6.1,0822) : 2,28o/o

Cf,u 5. (1,5 ili6m) Cho m gam h5n hqp A g6m Fe ve Mg tac aung
"
lft Hz (dktc). MAt khac, n6u cho m gam h5n hq'p A vdo 400 ml dwrg dich chria AgNO: 1,5 M vi
Cu0'{Os)z 1 M, phan img xong, lgc bo ph&r ch.it ran tnu dugc dung dich B chira ba mu6i. Th6m dung
dich NaOH du vdo dung dich B, lgc l6y kCttua ttem nung ngoai kh6ng khf dtin ktrOi tuqng kh6ng AOi tnu

dugc 48 gam ch6t r'in. finn giltacta m vd tinh khOi luqng mdi muiSi trong dung dich B.
{. NQi dung Di6m
*A+HCldu: 025
Mg+2HCl-MgClz+Hz

Fe + 2HCl ---+ FeClz + Hz

-s6molHz:x+y=0,5 (l)
* A + 400 ml dung dlch chfa AgNO3 M vd Cu(NO3)z I 14, thu dugc dung
1,5 dch B 0'5
chua ba mu6i n6n Mg, Fe, AgNO3 <t0u hi5t, Cu(NO)2 cdn ho{c chua phan img.

56 mol Mg(NOr)z: s5 mol Mg: x mol; 56 mol Fe(NOl)z : s6 mol Fe : y mol

Ggi z li s6 mol Cu(NO:)z du ( 0 < z <0,4)-- 56 mol Cu(NO:)z p.u : (0,4 -z)
Theo DLBT g6c nitrat:

Si5 mol AgNO3 + 2.sti mol Cu(NO zh:2.s6 mol Fe(NO311+ Z.s6 mol Mg(NO3)2 + 2.s6
mol Cu(NO3)2 du t

-r 0,6 +2.0,4:2x*2y +22+ x * y * z:0,7 Q)

*DDB+ddNaOHdu: t
05
Cu(NO:)z + 2NaOH Cu(OH)z + 2NalrtrOi
-

MeNO3)z + 2NaOH * Mg(OH)2 + 2NalIO3

Fe(NO:)z + 2NaOH + Fe(OH)z + 2NaNO:

Nung ktittuangoii kh6ng khi it6nkhOi luqng kh6ng tt6i:

Cu(OH)2-CuO+HzO
zz
Mg(OH)2 -- MgO + HzO
xx
4Fe(OH)z * 02 "'+ ZFezOt+ 4HzO
y 0,5y

- tch6i luqng chdt rin : 40x + 80y + 802 = 48 + x+ 2y * 2z= 1,2 (3)
Giaihe (1), (2),(3)tac6: x =0,2;y=0,31 z:0,2 -+m:24.0,2 + 56.0,3 :2l,6gam 0rs
tchiii luqng m6i mu5i tong B ld:
fhOi luq,ng Mg(NO:)z : 148.0,2=29,6 gam; Kh5i lugng Fe(NO:)z: 180.0,3 :54 gatrr;
fhOi luqng Cu(NOl)z: 188.0,2 :37,6 garr.
Ciu 6. (1,25 ili6m) Hda tan hoan todn a gam h6n hqp A g6m Na vd mQt kim lo4i R h6a tri II Rh
kim loAi c6 hidroxit ludng tinh) vio nudc, sau phan ung thu dugc dung dich B vi V lit khf Hz.NiSu cho

dung dich B tric dUng vira thi voi 300 ml dung dich HCI 0,25 M tao thantr mQt dung dich chi chta hai
ch6t tan. M{t kh6c, khi h6p thg vira h6t 1,008 lit khi COz vdo dung dch B, thu dugc 1,485 gam mQt ch6t
t6t tua vi dung dich nudc 19c chi chta ch6t tan NalICOt. Bitit c6c phan (mg xiy ra hod.ur toan vi c,ic th6

tich ktri do d tlktc. X6c ttinh t6n kim loai R.

NQi dung Di6m

nH61 = 0,3.0,25 = 0,075 mol; s6 mol COz = 1,008122,4 = 0,045 mol 0'5
Ggi x, y Hn luqt li s0 mol ctaNa vi R trong a gam hdn hgp A.
2Na + 2HzO+ 2NaOH + H2 (l)
x x 0,5x
R+2NaOH+NazROz+Hz A)
v2vvv
Dung dich B thu dugc g6m: Na2ROz vd c6 thti co NaOH du t

Cho B t6c dung vsi dd HCI wa dti thu dugc dd c62 chiittan. 0,25
" NaOH + HCI + NaCl + H2O (3)
(x-2y) (x-2y)
NazROz + 4HCl
- RClz + 2NaCl + zIhO (4)

v4vv
 + nHCt: x+2y = 0,075 (*)
Cho B trlc dgng vdi COz: 02s
NaaROz + 2COz+ 2llzo R(OH)z + 2NaHCOg (s)
-
2y
NaOH + COz+NaHCOg (6)
(x-2y) (x-2y)
Si5 mot COz= x-Zy * 2y :0,045 -"+ x : 0,045 02s
Thay x veo (*) --' y: 0,015 * S5 mol R(OH)2:0,015 mol

-+ R * 34: 1,48510,015 -+ R : 65 (Zn)

Vay R ldZn.
Ciu 7. (1,5 ili6m) H6n hqrp X g6m 2 este c6 ti lQ s6 mol trong h6n hgp ld 1 : 3. Cho a gam h6n hgrp X
vio drurg dich NaOH du, sau phan rmg thu dugc 9,84 gammutSi cria mQt axit htu co don chfc vd6,36
gam h5n hqp 2 rugu no, don chtc, m4ch tt 6rrg (c6 sri nguy6n tfi C < 5). Niiu ttiit ch6y het 6,36 gam h6n
hW2rugu thu dugc 6,72lit COz (ttktc). Bii5t cric phan rmg xAy ra hoan toan.

1. X6c dlnh cdng thfc c6u t4o 2 este, viiit pfruf ctra ciic phan tmg xiy ra.

t
2.Tinha.
NQi dung Ei6m
1. D?t c6ng thric ctra2 este ld, RCOOC-H2n*l 02s
RCOOC,H 2;a s NaOU + RCOONa + CrH rr*rOH

CnH zn*toH ** o, J+ rco, + (i + l) H 20

6?6
ffro, =0r3 = nnr-oz;*roH ) 0r3 = n.ffi+ n =2r5

Rugu c6 sO nguy6n ttl C nh6 hcrn c6 th6 H CHTOH ho{c CzHsOH; rugu c6 s6 C
02s
lcm hcrn d?t h CnHzn+rOH
Ilruqu = IlRcooNa = oesre = 0r3 : 2r5 :0112 mol
) M*coo*u: 9,84 : 0,12 82 : +
Mn: 15 +COng thftc R ld CH:-
* Trudme hop 1:
2 este li: CHICOOCH3 (X1) vn CH:COOCnHzn*r (Xz)
Do ti lQ mol2 este ld I : 3
02s
-Ni5u: [*,u *rlxz-3a-> 4a=0,12-+a= 0,03
rnruqu = 32.0,03+ 0,09.(14n+18)= $,lS)1:3
+Rugu cdn l4i c6 c6ng thfc CIHzOH
"Do2 ruqu m4ch thA"g rAn2 este li: .
CH3COOCHT vd CH3COOCHzCHzCHT
Ho{c CHTCOOCH: vd CHgCOOCH(CH3> 0,25

- Ni5u: [*, 3a =0109;[*, = a = 0,03

rrrusu: 32.0,09 + 0,03.(14n+18) = S,16+ rt=7 > 5 +(Logi)
* Tnrdqre hqm 2:
 2 este li: CH:COOCzHs (Xr) vd CHTCOOCnHzn*r (Xz) | O,fZS
- Ntiu: [*, a = 0,03;n x, =3a= 0,09
n1uqu = 46.0,03+ 0,09.(l4n+18) : f,lS+ n:2,67 +(Loei)
- Ni5u: o*, 3a = 0,09;[*, a = 0,03
rnruqu: 46.0,09+ 0,03.(l4n+18) = 6,36* n:4
+Rugu cdn l4i c6 cdng thtc C+H9OH

Do 2 rugu m4ch th[rrg n€n2 este c6 c6ng thfc c6u tpo ld:
CH3COOCHzCHT vd CH3COOCHzCHzCHzCHT
Ho[c CH3COOCH2CH3 vi CH3COOCH(CH3)CHzCHIr\vrrl/irvrrzvrrl
| 0rl25
2. Ap dung finh lu$t bno toan kh6i lugng ta c6: I

meste+ IrINaoH : Illmu6i * fllrugu

a+ 0,12.40:9,84 + 6,36
a = 1114 gam