HIGHER SECONDARY IST YEAR

CHEMISTRY
TIME:2 ½ Hrs MARKS:70
PART-I
I. Answer all the questions.
Choose the most appropriate answer 15x1=15
1.The oxidation number of oxygen in OF2 is
a) +1 b) +2 c) -1 d) -2
2.Galena is the ore of
a) Zinc b) copper c) Lead d) silver
3.which of the following set of quantum numbers is incorrect
a) n=3; l = 3; m= -1; s = +1/2 b) n=2; l = 0; m= 0; s = -1/2
c) n=3; l = 1; m= 1; s = -1/2 d) n=1; l = 0; m= 0; s = +1/2
4. Which of the following forms stable gaseous negative ion.
a) F b) Cl c) Br d) I
5. Which of the following statement(s) given above is/are not correct.
1.P4O10 and SO3 are acidic oxides
2. N2O and CO are compound oxides
3. Na2O2, BaO2 are basic oxides
4.ZnO is an amphoteric oxide.
a) 1 and 4 b)only 2 c)2 and 3 d)only 4
6. The Weiss indices of a plane are 1/2, 1/2, 1/2. Its miller indices willbe
a) (011) b) (010) c) (222) d) ( ½ ½ ½)
7. The molecules of a gas A travel four times faster than the molecules of gas B at the same temperature. The
ratio of molecular weight (MA/MB) will be
a) 1/16 b) ¼ c) 4 d) 16
8.The correct order of polarisation of anions is
a) I- > Br- > Cl- > F- b) Br- > Cl- > I- > F-
c) F-> Cl-> Br-> I- d) Cl- > F- > Br- > I-
9 .Which of the following is not a state functions?
a) q b) q + w c) U d) V +PV.
10.Which of the following is a heterogeneous equilibrium?
a) N2(g) + 3H2(g) 2NH3(g). b) CaCO3(s) CaO(s) + CO2(g)
c) 2 NO2(g) N2 O4(g) d) 2SO2(g) + O2(g) 2SO3(g)
11.The correct order of stability of carbocation is
a) 10> 20 > 30 b) 20 > 30 > 10 c) 30> 20> 10 d) 10 > 30 > 20
12. If an organic compound contains nitrogen along with sulphur, a blood red colour will be obtained due to
a) Fe (CNS)3 b) Na4[Fe(CN)5 NOS]
c) Fe4[Fe(CN)6] d) Na(CNS)
 13. Statement I : The melting point of n-pentane is less than neopentane
Statement II : n-pentane will be better packed in the crystal lattice than neo pentane.

a. Both the statements are true but statements II is not the correct explanation of statement I.
b. Both the statements are true and statement II is the correct explanation of statement I.
c. Statement I is true but statement II is false.
d. Statement I is false, but statement II is true.

14.The electrophile involved in the sulphonation of benzene is

a) SO2+ b) NO2- c) SO3H+ d) SO3
15. 15.The SN1 reaction of alkyl halides is not affected by the nature of the
a). alkyl group b). halogen c). medium d). nucleophile

PART II
II.II.ANSWER ANY 6.QN.NO.21 IS COMPULSORY 6X 2 =12

116.Calculate the mass of NaOH present in 1 litre of a decinormal solution.

17. What is shape of the orbital with (i) n = 2 and l = 0 ; (ii) n = 2 and l = 1?
18.Draw the resonance structures of ozone.
19. Write the units of Vanderwaal’s constants a and b?
20.What are isotonic solutions?

21.Find the product

Zn/Hg
i)C6H5COCH3
HCl

NaOH
ii) CH3 -CHO + CH3-CHO
22.Write Lassaigne’s test to detect an organic compound containing sulphur.

23.Write about Huckel’s rule of aromaticity.

24.Predict the shapes of BF3 and CH4 using VSEPR theory.

PART-III
III. Answer Any Six Questions in which Question No.30 is compulsory 6x3=18

25. Mention three important uses of H2O2.

26.Why Beryllium and Magnesium do not give colour in flame test?
27.Why electron affinity of fluorine is less than chlorine?
28.What are miller indices?

29. At 25°C, Kc for the reaction 3C2H2(g) C6H6(g) is 4.0. If the equilibrium concentration of C2H2
is 0.5 mol. lit-1. What is the concentration of C6H6?
30. In I order reaction the initial concentration of the reactant as 0.05mole/litre and the rate constant
1.5x10-3 min-1. What is the initial rate of the reaction?
31.Write Friedal craft’s alkylation reaction.

32.Direct fluorination of alkanes is not possible.Why?

33.Write any three differences between electrophiles and neucleophiles.

PART-IV
IV. Answer All the Questions 5x5=25
34. i) A compound on analysis gave the following percentage composition: C - 54.54%, H = 9.09%,
0 = 36.36%.calculate its empirical formula (3)
ii) State volumetric law.(2)

(or)

i) Explain the principle involved in froth flotation process.(3)

ii)What is calcination?Give example.(2)

35. i) What is the total number of orbitals associated with the principal quantum number n=3 ? (2)
ii) State Aufbau principle.and explain (n+l) rule.(3)
(or)

i) Define Joule-Thomson effect.(2)

ii) Describe Linde's process of liquefaction of gases with neat diagram.(3)

36.What are the properties of electrovalent compounds(5)

(or)

Differentiate rate and rate constant(5)

37.i)State first law of thermodynamics.(2)

ii)Enthalpy of neutralisation of a weak acid or base will be lower than the neutralisation of strong acid
and strong base.Why?(3)
(or)

i)Explain the purification of compounds by using thin layer chromatography.(3)

ii)What is Rf value.?(2)

38.Give the IUPAC names for:

i) Diethyl ether

ii) Oxalic acid

iii) Acetone

iv) Ethyl methyl amine

v) Acetaldehyde

(or)

An organic compound (A) of Molecular formula C6H6 on treatment with Br2 in the presence of FeBr3 to
give compound (B). Compound (B) react with sodium in ether solution to give compound (C) of
molecular formula C12H10. Identify (A), (B), (C). Explain the reactions.