Chemistry Book Back PDF

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HIGHER SECONDARY - SECOND YEAR
CHEMISTRY
ONE MARK
QUESTION & ANSWER
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Compiled by:
I ai .
ol
Mr.R.ANNAMALAI
is LA
al v A
M.Sc(Chem).,M.Sc (Psy).,M.Phil.,B.Ed., B.Music.,
w. kP.G. TEACHER IN CHEMISTRY
M
GOVT. GIRLS HR.SEC.SCHOOL,
ww
N A
GINGEE. VILLUPURAM DIST.
email:ssssmalai@gmail.com
.A N
R
Design:
Raasi Computers 199, Balaji Complex, Gandhi Bazaar, Gingee - 604 202.
Mobile No.94442 82044
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Higher Secondary - Second Year

BLUE PRINT - CHEMISTRY
Time : 180 Mins. Maximum Marks : 150
OBJECTIVES KNOWLEDGE UNDERSTANDING APPLICATION SKILL TOTAL
S.No
E/LA SA VSA O E/LA SA VSA O E/LA SA VSA O E/LA SA VSA O
1 Atomic Structure - - - 1(1) - - 1(3) - - - - 1(1) - 1(5) - - 10
2 Periodic Classification 1(5) - - - - - - 1(1) - - 1(3) - - - - - 09
3 p-Block elements - - 1(3) - - - 1(3) - 1(5) - - - - - - 1(1) 12
4 d-Block elements - 1(5) 1(3) - - - 1(3) 1(1) - - - 1(1) 1(5) - - - 18
5 f-Block elements - - - - - 1(5) - 1(1) - - - 1(1) - - - - 07
6 Co-ordination & Bio-coordination

1(5) - - - - - - 1(1) - 1(5) - - - - - - 11
Compounds
7 Nuclear Chemistry - - - - 1(5) - - - - - - 1(1) - - 1(3) - 09
8 Solid state - - - - -
o m
- 1(3) - 1(5) -
c
- - - - - 1(1) 09
9 Thermodynamics-II -
I - - 1(1) -
ai
-
. - 1(1) - 1(5) - - - - 1(3) - 10
10 Chemical equilibrium-II
is
-
LA - 1(3) -
ol
- 1(5) - - - - - 1(1) - - - 1(1) 10
11 Chemical Kintics-II
al v A- - 1(3) - - - - 1(1) - - 1(3) - - 1(5) - - 12
12 Surface Chemistry
w. k M1(5) - - 1(1) - - 1(3) 1(1) - - - 1(1) - - - - 11
13 Electrochemistry - I
14 Electrochemistry-II
ww
N A -
-
-
-
- 1(1) 1(5) - 1(3) -
- - 1(5) - - -
- -
- 1(5) -
- - 1(5) -
- - -
-
-
-
-
14
10
16 Hydroxy Derivatives .A N
15 Isomerism in Organic Chemistry -
-
- 1(3) - 1(5) - - - - - - - - - - - 08
17 Ethers
18 Carbonyl Compounds
R -
-
- 1(3) -
- 1(3) -
- - 1(3) -
- 1(1) - 1(5) -
- 1(5) -
-
-
-
-
-
-
- 1(1) 1(5) -
- - -
- 1(1) 1(5) -
-
- -
- 1(1) 07
- -
12
14
19 Carboxylic Acids - - 1(3) - 1(5) - - - - 1(5) - 1(1) - - - - 14
20 Organic Nitrogen Compounds 1(5) - - - - - - 2(1) - - - 1(1) - - 1(3) - 11
21 Bio molecules - - - 1(1) - - - 1(1) 1(5) - - - - - - - 07
22 Chemistry in Action - - - - - - 1(3) - - 1(5) - - - - - - 08
23 Problem in Chemistry
TOTAL 20 5 24 6 25 20 24 10 15 25 6 10 20 10 9 4 233
No. of Questions Marks
Summary / E / LA 8 80 Part-I MCQ - 30 / 30
Short Answer (SA) No. 12 60 Scheme of options Part-II VSA - 15 / 21
Very Short Answer (VSA) No.21 63 Scheme of Sections Part-III SA - 7 / 12
Objective(O) 30 30 Part-IV E / LA - 3 / 6 & 1 Compulsory (Either or Type)
233
Knowledge : 24% Application : 24%
Understanding : 34% Skill : 18%
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INDEX
S.No. LESSON Page No
1 ATOMIC STRUCTURE - II 1
2 PERIODIC CLASSIFICATION - II 2
3 p - BLOCK ELEMENTS 3
4 d - BLOCK ELEMENTS 4
5 f - BLOCK ELEMENTS 6
6 COORDINATION COMPOUNDS AND
BIO-COORDINATION COMPOUNDS 7
7 NUCLEAR CHEMISTRY 8
8 SOLID STATE - II 9
9 THERMONYNAMICS - II 10
10 CHEMICAL EQUILIBRIUM - II 10
11 CHEMICAL KINETICS - II 11
12 SURFACE CHEMISTRY 12
13 ELECTRO CHEMISTRY - I 13
14 HYDROXY DERIVATIVES 15
15
16
ETHERS
CORBONYL COMPOUNDS
co m 17
18
17 CARBOXYLIC ACIDS
I ai . 20
18
o l
ORGANIC NITROGEN COMPOUNDS
s A 22
i L
19 BIOMOLECULES 24
20
l v
GOVERNMENT EXAMINATION MARCH - 2006
a A 26
k
21 GOVERNMENT EXAMINATION JUNE - 2006 28
22
. M
GOVERNMENT EXAMINATION OCTOBER - 2006
w
30
23
24
25
w A
w
GOVERNMENT EXAMINATION JUNE - 2007
N
32
34
36
26
27
28
N
.A
38
40
42
29
30
31
R
44
46
48
32 GOVERNMENT EXAMINATION MARCH - 2010 50
34 GOVERNMENT EXAMINATION OCTOBER - 2010 54
44 GOVERNMENT P.T.A MODEL QUESTION PAPER I - V 74
R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, vii

DISTRICT SECRETARY, TNHSPGTA, VILLUPURAM DT
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HIGHER SECONDARY - SECOND YEAR
CHEMISTRY
INORGANIC CHEMISTRY
1. ATOMIC STRUCTURE - II 2 x 1= 2
Choose the correct answer
1. En= - 313.6 , If the value of Ei = -34.84 to which value ‘n’ corresponds

n2
a) 4 b) 3 c) 2 d) 1
2. Dual character of an electron was explained by

a) Bohr b) Heisenberg c) de-Broglie d) Pauli
3. de-Broglie equation is
co m
mv
a) λ= h b) λ=hmv c)
I hv
λ= m d)
h
λ= mv
ai .
s o l A
i
4. The value of Bohr radius for hydrogen atom is
l v L
a) 0.529 x 10-8cm
. k a
M A
b)0.529 x 10-10cm c)�0.529 x 10-6cm d)�0.529 x 10-12cm
w
5. Which of the following particle having same kinetic energy, would have the maximum de-Broglie wave
length
a) α - particle
ww
N
b) proton A c) β - particle d) neutron
.A N
6. If the energy of an electron in the second Bohr orbit of H-atom is - E, what is the energy of the electron
in the Bohr’s first orbit?
a) 2E b) -4E
R c)
7. The energy of electron in an atom is given by En=

-2E d) 4E
4π2me4 2π2me2 2π2me4 2πme4

a) - b) - c) - d) -
n2h2 n2h2 n2h2 n2h2
8. The bond order of Oxygen molecule is

a) 2.5 b) 1 c) 3 d) 2
9. The hybridisation in SF6 molecule is

a) sp3 b)�sp3d2 c) sp3d d) sp3d3
10. The intramolecular hydrogen bonding is present in

a) o-nitrophenol b) m-nitro phenol c) p-nitrophenol d) None
R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 1

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2. PERIODIC CLASSIFICATION - II 1 x 1= 1
Choose the correct answer:-
1. The value of C-C distance found experimentally in a saturated hydrocarbon is
a) 1.34Å b) 1.36Å c) 1.54Å d) 1.56Å
2. On moving down the group, the radius of an ion
a) Decreases b) Increases c) No change d) None of these
3. Effective nuclear charge (Z*) can be calculated by using the formula
a) Z* = Z - S b) Z* = Z + S c)� Z* = S - Z d)�Z = Z* - S
4. Pick the correct statement
a) Carbon having more nuclear charge than boron
b) The size of carbon atoms is larger than boron
c) Carbon forms electron deficient compounds
d) Carbon forms ionic compounds
5. Comparing the ionisation energy of fluorine with carbon, fluorine has
a) higher ionisation energy b) lower ionisation energy
c) same ionisation energy d) none of these
co m
I
6. Among the following which has the maximum ionisation energy
ai .
a) Alkali elements
o l A
b) Alkaline elements
s
c) Halogens d) Noble gases
7. The electron affinity of an atom
l v i L
.
c) is independent of its sizek a
a) directly proportinal to its size
M A b) inversely proportional to its size

d) none of these
ww A
8. Among the following which has higher electron affinity value
a) Fluorine
w
b) Chlorine
N c) Bromine d) Iodine
of bonded atoms is
.A N
9. The scale which is based on an empirical relation between the energy of a bond and the electrongativities
a) Pauling scale
c) Sanderson’s scale R b) Mulliken’s scale
d) Alfred and Rochow’s scale
10. Electron affinity is expressed in
a) KJ b) J c) KJ mol d) KJ mol-1
11. The bond length of Cl2 molecule is
a) 0.74 b) 1.44 c) 1.98 d) 2.28
12. The order of ionization energy
a)s<p<d<f b) s>p>d>f c) s>d>p>f d) s<d<p<f
13. Across the period, electron affinity
a) decreases b) increases c) decrease and the increases d) increase and then decreases
14. Noble gases have .................. electron affinity
a) High b) Low c) Zero d) Very low
15. When XA>> XB, A - B bond is
a) polar covalent b) non-polar covalent c) Ionic d) metallic
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3. p - BLOCK ELEMENTS 1 x 1= 1
Choose the correct answer:
1. Which of the following does not belong to group 13?
a) B b) Al c) Ge d) In
2. Which of the following is most abundant in earth’s crust?
a) C b) Si c) Ge d) Sn
3.An element which was burnt in limited supply of air to give oxide A which on treatment with water gives
an acid. B Acid B on heating gives acid C which gives yellow precipilate with AgNO3 solution A is
a) SO 2 b) NO 2 c) P2O3 d) SO3
4. The compound with garlic odour is
a)P2 O 3 b)P2 O 5 c) H3PO3 d) H3PO4
5. The shape of PCl5 is
a) pyramidal b) trigonal bipyramidal c) linear d) tetrahedral
6. The compound used as smoke screen
m
a) PCl3 b) PCl5 c) PH3 d) H3PO3
7. Which shows only - 1 oxidation state?
i . co
a) F b) Br
o l
c) Cl
AI d) I
a
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8. One can draw the map of building on a glass plate by
v L
a) HI b) HF
k al c) HBr
A d) HCl
.
9. Among the halogen acid, the weakest acid is
a) HF b) HCl
ww c) HBr
A M d) HI
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10. Halogens belong to the group number
N
a) 14 b) 15
.A N
c) 17
11. The noble gases are unreactive because they
a) have same number of electrons
d) 18
R
b) have an atomicity of one
c) are gases with low densities
d) have stable electronic configuration
12. The shape of XeF4 is
a) tetrahedral b) octahedral c) square planar d) pyramidal
13. Which is not known?
a) XeF6 b) XeF4 c) XeO3 d) ArF6
14.The lightest gas which is non-inflammable is
a) He b) H2 c) N2 d) Ar
15. Which of the following has highest first ionisation energy?
a) He b) Ne c) Ar d) Kr

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4. d - BLOCK ELEMENTS 2 x 1= 2
1. The general electronic configuration of d-block element is
a) (n-1)d1-10 ns0-2 b) (n-1) d1-5 ns2 c) (n-1)d0 ns1 d) None of these
2. Formation of coloured ions is possible when compounds contains
a) paired electrons b) unpaired electrons c) lone pairs of electrons d) none the above
3. Paramagnetism is common in
a) p-block elements b) d-block elements c) s-block elements d) f-block elements
4. The colour of Ti(H2O) ion is due
6
3+
a) d-d transistion b) Presence of water molecules

c) Inter atomic transfer of electrons d) none the above
5. The electronic configuration of chromium is
a) 3d6 4s0 b) 3d5 4s1 c) 3d4 4s2 d) 3d3 4s2 4p1
6. Paramagnetism is the property of
a) paired electrons b) completely filled electronic subshells
c) unpaired electrons
o m
d) completely vacant electronic subshells
c
7. d-block elements form coloured ions because
I ai .
o l
a) They absorb some energy for d-s transition
s A
v i
b) They absorb some energy for p-d transition
l L
k a
c) They absorb some energy for d-d transition
. M A
ww
d) They do not absorb any energy
A
8. The correct electronic configuration of copper atom is
a) 3d10 4s1 w
b) 3d10 4s2
N c) 3d9 4s2 d) 3d5 4s2 4p4
9. Copper is extracted from
a) cuprite
.A
b) copper glance
N c) malachite d) copper pyrites
R
10. Silver salt used in photography is
a) AgCl b) AgNO3 c) AgF d) AgBr
11. Sodiumthiosulphate is used in photography because of its
a) Oxidizing behaviour b) Reducing behaviour
c) Complexing behaviour d) Photochemical behaviour
12. Excess of sodium hydroxide reacts with zinc to form
a) ZnH2 b) Na2 ZnO2 c) ZnO d) Zn(OH)2
13. Which of the following compounds will not give positive chromyl chloride test?
a) CuCl2 b) HgCl2 c) ZnCl2 d) C6H5Cl
14. Which of the ions will give colourless aqueous solution?
a) Ni2+ b) Fe2+ c) Cu2+ d) Cu+
15. Which of the following compounds is not coloured?
a) Na2CuCl4 b) Na2CdI4 c) K4 [Fe(CN)6 ] d) K3[Fe(CN)6]
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16. In the extraction of Cu, the reaction which does not take place in the Bessemer converter is
a) 2CuFeS2 + O2 Cu2S + FeS + SO2 b) 2Cu2S + 3O2 2Cu2O + 2SO2
c) 2Cu2O + Cu2S 6Cu + SO2 d) 2FeS + 3O2 2FeO + 2SO2
17. Select the wrong statement
a) All cuprous salts are blue in colour
b) Transition metals are highly reactive
c) All cuprous salts are white in colour
d) Mercury is a liquid metal
18. Choose the wrong statment regarding K2Cr2O7
a) It is a powerful oxidizing agent
b) It is used in tanning industry
c) It is soluble in water
d) It reduces ferric sulphate to ferrous sulphate
19. For a transition metal ion, the effective magnetic moment in BM is given by the formula
a) n(n-1) b) n(n+1) c) n(n+2)

co m
d) n(n+1) (n+2)
I
20. The correct statement in respect of d-block elements is
ai .
a) They are all metals
s o l A
b) They sho variable valency
l v i L
k a A
c) They form coloured ions and complex salts
. M
ww
d) All above statement are correct
A
w
21. Which compound is formed when excess of KCN is added to an aqueous solution of copper sulphate
N
a) Cu2 (CN)2
.A N
b) K2 [Cu(CN)6 ] c) K [Cu(CN)2 ]
22. Which of the following has the maximum number of unpaired electrons?
d) Cu2 (CN)2 + (CN)2
a) Mn2+
R
b) Ti3+ c) V3+
23. Among the following statement, the incorrect one is
d) Fe2+
a) Calamine and siderite are carbonates

b) Argentite and cuprite are oxides
c) Zine blende and pyrites are sulphides
d) Malachite and azurite are ores of copper
24. The chemical composition of slag formed during the smelting process in the extraction of copper is
a) Cu2O+FeS b) FeSiO3 c) CuFeS2 d) Cu2S+FeO
25. The transition element with the lowest atomic number is

a) Scandium b) Titanium c) Zinc d) Lanthanum
26. Which transition element show highest oxidation state
a) Sc b) Ti c) Os d) Zn

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5. f - BLOCK ELEMENTS 2 x 1= 2
1. The electronic configuration of Lanthanides is
a) [Xe]4f0 5d0 6s0 b) [Xe]4f1-7 5d1 6s1
c) [Xe]4f1-14 5d1 6s2 d) [Xe]4f1-14 5d1-10 6s2
2. The electronic configuration of Actinides is
a) [Rn]5f0-14 6d0 7s0 b) [Rn]5f0-14 6d0-2 7s0
c) [Rn]5f0-14 6d0-2 7s1 d) [Rn]5f0-14 6d0-2 7s2
3. The lanthanide contraction is responsible for the fact that
a) Zn and Y have about the same radius b) Zr and Nb have similar oxidation state
c) Zr and Hf have about the same radius d) Zr and Zn have the same oxidation state
4. The most common oxidation state of lanthanides is
a) +2 b) +1 c) +3 d) +4
5. Lanthanides are extracted from
a) Limonite b) M onazite c) M agnetite d) Cassiterite
co
6. The elements in which the extra electron enters (n-2) f orbitals are calledm
a) s - block elements
I
b) p - block elements
ai .
c) d - block elements
o l A
d) f - block elements
s
v i
7. The Lanthanides contraction is due to
l L
. k a
a) Perfect shielding of 4f electron
M A b) Imperfect shielding of 4f electron
w
c) Perfect shielding of 3d electron d) Imperfect shielding of 3d electron
8. Ceria is used in
a) toys
ww
N
b) tracer bullets
A c) gas lamp materials d) none of the above
a) MnO2 b) CeO2
N
9. .................. is used in gas lamp material
.A c) N2O5 d) Fe2O3
R
10. Alloys of Lanthanides are called as
a) Mish - metals b) Metalloids c) Plate metals d) Actinides
11. Metallothermic processes involving Lanthanides are called as
a) Aluminothermic process b) Lanthanido - thermic process
c) Reduction process d) Oxidation process
12. ................... form oxocations
a) Lanthanides b) Actinides c) Noble gases d) Alkalimetals
13. Maximum oxidation state exhibited by Lanthanides is

a) +1 b) +2 c) +3 d) +4
14. Lanthanides are separated by
a) Fractional distillation b) Steam distillation
c) Fractional Crystallisation d) Sublimation

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6. COORDINATION COMPOUNDS AND

BIO-COORDINATION COMPOUNDS 1 x 1= 1
1. Which a double salt
a) K2SO4.Al2(SO4)3.24H2O b)NaCl c) K4[Fe(CN)6] d) KCl
2. An example of a complex compound having coordination number 4
a) K4[Fe(CN)6] b)[Co(en)3]Cl3 c) [Fe(H2O)6]Cl3 d) [Cu(NH3)4]Cl2
3. The geometry of [Cu(NH3)4]2+ complex ion
a) Linear b) Tetrahedral c) Square planar d) Angular
4. An example of a chelating ligand is
a) NO-2 b) Chloro c) Bromo d) en
5. The geometry of complex ion [Fe(CN6]4- is
a) tetrahedral b) square planar c) Octahedral d) triangular
6. The oxidation number of Nickel in the complex ion, [NiCl4]2- is
a) +1 b) -1 c) +2 d) -2
7. Which is not an anionic complex?
co m
a) [Cu(NH3)4]Cl2 b) K4[Fe(CN)6]
I ai .
c) K3[Fe(CN)6] d) [NiCl4]2-
8. The geometry of [Ni(CN)4]2- is
s o l A
a) Tetrahedral
v i
b) Square planar
l L c) Triangular d) Octahedral
k a
9. An example of an ambidentate ligand is
. M A
a) CN- b) Cl-
ww c) NO2-
A
d) I-
w
10. [FeF6]4- is paramagnetic because
a) F-is a weaker ligand N N b) F-is a strong ligand
.A
c) F - is a flexidentate ligand d) F - is a chelating ligand
11. In [Fe (CN)6] the central metal ion is
II 4-
a) Fe b) Fe+2
R c) Fe+3
12. The coordination number of Ni (II) in [Ni(CN)4]2- is
d) CN-
a) 2 b) 4 c) 5 d) 6
13. The name of [Pt IV(NH3)2Cl2]2+ is
a) Diamminedichloroplatinum (IV) ion b) Diamminedichloroplanitate (IV)
c) Diamminedichloroplatinum d) Dichlorodiammineplatinum (IV) ion
14. For a compound K4[Fe(CN)6] 4K + [Fe(CN6]4-, the complex ion is
+
a) K+ b) CN- c) FeII d) [Fe(CN)6]4-

15. A metal ion from the first transition series forms an octahedral complex with magnetic moment of 4.9
BM and another octahedral complex which is diamagnetic. The metal ion is
a) Fe2+ b) Co2+ c) Mn2+ d) Ni2+
16. Paramagnetic moment is expressed in
a) Debye unit b) K Joules c) BM d) ergs
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17. The type of isomerism found in the complexes [Co(NO2)(NH3)5]SO4 and [Co(SO4)(NH3)5]NO2
a) Hydrate isomerism b) Coordination isomerism
c) Linkage isomerism d) Ionisation
18. Valence bond theory does not explain the property of complex compound
a) geometry b) magnetic c) nature of ligand d) colour
7. NUCLEAR CHEMISTRY 1 x 1= 1
Choose the correct answer:-
1. The phenomenon of radioactivity was discovered by
a) Mada curie b) Pierre curie c) Henry Becquerrel d) Rutherford
2. The most penetrating radiations are
m
a) α rays b) β rays c) γ rays d) All are equally penetrating
3. In the nuclear reaction, 92U238

. co
Pb206, the of α and β particles emitted are
i
a) 7α, 5β b) 6α, 4β
o l AI
82
c) 4α, 3β
a
d) 8α, 6β
v is L
4. Which one of the following particles is used to bombard 13Al27 to give 15p30 and a neutron
a) α particle
al
b) deuteron
k A c) proton d) neutron
5. The reaction 5B8
w. M
Be8 takes place due to
A
4
a) α decay
ww
b) β decay c) electron capture d) positron decay
6. Radioactivity is due to
N
a) Stable electronic configuration N
b) Stable nucleus
c) Unstable nucleus
R .A
d) Unstable electronic configuration
7. In the following radioactive decay, 92X232 y220 , how many α and β Particles are ejected.
89
a) 3α, 3β b) 5α, 3β c) 3α, 5β d) 5α, 5β

8. 92U235 nucleus absorbs a neutron and disintegrates into 54Xe139, 38Sr94 and x. What will be the
product x?
a) 3 neutrons b) 2 neutrons c) α particle d) β particle
9. Loss of a β-particle is equivalent to
a) Increase of one proton b) Decrese of one neutron only
c) Both (a) and (b) d) None of these
10. Which of the following is used as neutron absorber in the nuclear reactor?
a) Water b) Deuterium c) Some compound of uranium d) Cadmium

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PHYSICAL CHEMISTRY
8. SOLID STATE - II 1 x 1= 1
Choose the correct answer.
1. The number of chloride ions that surrounds the central Na+ ion in NaCl crystal is ..............
a) 12 b) 8 c) 6 d) 4
2. The Bragg’s equation is
a) λ=2d sinθ b) nd=2λsinθ c) 2λ=nd sinθ d) nλ=2d sinθ
3. A regular three dimensional arrangement of indentical points in space is called
a) Unit cell b) Space lattice c) Primitive d) Crystallography
4. The smallest repeating unit in space lattice which when repeated over and again results in the crystal
of the given substance is called
a) Space lattice b) Crystal lattice c) Unit cell d) Isomorphism
5. The crystal structure of CsCl is
a) Simple cubic b) face-centred cubic c) Tetragonal
co m d) Body centred cubic

6. An example for Frenkel defect is
I ai .
A ol
a) NaCl b) AgCl c) CsCl d) FeS
is L
7. Semiconductors which exhibit conductivity due to the flow of excess negative electrons are called
v
a) Super conductors
al A
b) n-type semiconductors
k
c) p-type semiconductors d) Insulators
. M
8. In the Bragg’s equation for diffraction of X-rays, ‘n’ represents
w
a) The number of moles
ww
N A
b) Avogadro number c) A quantum number
9. The number of close neighbours in a body centred cubic lattice of identical sphares is
d) Order of reflection
a) 6 b) 4
.A N
c) 12 d) 8
10. The crystals which are good conductors of electricity and heat are
a) Ionic crystals
R b) Molecular crystals
11. In a simple cubic cell, each point on a corner is shared by
c) Metallic crystals d) Covalent crystals
a) One unit cell b) Two unit cell c) 8 unit cell d) 4 unit cell
12. The ability of certain ultra cold substances to conduct electricity without resistance is called
a) Semiconductor b) Conductor c) Superconductor d) Insulator
13. The total number of atoms per unit cell is bcc is
a) 1 b) 2 c) 3 d) 4
14. Rutile is
a) TiO2 b) Cu2O c) MoS2 d) Ru
15. Semiconductors are used as
a) rectifiers b) transistors c) solar cells d) all the above
16. An example of metal deficiency defect
a) NaCl b) AgCl c) CsCl d) FeS
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9. THERMONYNAMICS - II 2 x 1= 2
1. The amount of heat exchanged with the surrounding at constant temperature and pressure is called
a) Δ E b) Δ H c) Δ S d) Δ G
2. All the naturally occuring processes proceed spontaneously in a direction which leads to
a) decrease of entropy b) increase in enthalpy
c) increase in free energy d) decrease of free energy
3. In an adiabatic process which of the following is true?
a) q = w b) q = 0 c) ΔE = q d) PΔV = 0
4. When a liquid boils, there is
a) an increase in entropy
b) a decrease in entropy
c) an increase in heat of vapourisation
d) an increase in free energy
5. If ΔG for a reaction is negative, the change is
a) Spontaneous b) Non-spontaneous
co m
c) Reversible
I
d) Equilibrium
ai .
o l A
6. Which of the following does not results in an increase in the entropy?
s
v i L
a) crystallisation of sucrose from solution
l
b) rusting of iron
. k a
M A
ww
c) conversion of ice to water
d) vaporisation of camphor
A
w N
7. In which of the following process, the process is always non-feasible?
a) ΔH>0, ΔS>0
c) ΔH>0, ΔS<0
.A N
b) ΔH<0, ΔS>0
d) ΔH<0, ΔS<0
a) ΔG = ΔH + TΔS
R
8. Change in Gibb’s free energy is given by
b) ΔG = ΔH - TΔS
c) ΔG = ΔH x TΔS d) None of the above
9. For the reaction 2Cl(g) Cl2(g), the signs of Δ H and Δ S respectively are
a) +, – b) +, + c) –,– d) –, +
10. CHEMICAL EQUILIBRIUM - II 2 x 1= 2

1. State of chemical equilibrium is
a) dynamic b) stationery c) none d) both
2. If the equilibrium constants of the following reactions are 2A B is K1 and B 2A is K2, then
a) K1 = 2K2 b) K1 = 1/K2 c) K2 = (K1)2 d) K1 = 1/K22

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3. In the reversible reaction 2HI H2 + I2, is

a) greater than Kc b) less than Kc c) Equal to Kc d) Zero
4. In the equilibrium N2 + 3H2 2NH3 , the maximum yield of ammonia will be obtained with the
process having
a) low pressure and high temperature b) low pressure and low temperature
c) high temperature and high pressure d) high pressure and low temperature
5. For the homogeneous gas reaction at 600 K

4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g)
a) (mol dm-3)-2 b) (mol dm-3) c) (mol dm-3) 10 d) (mol dm-3)-9
6. Two moles of ammonia gas are introduced into a previously evacuated 1.0 dm3 vessel in which it
partially dissociates at high temperature. At equilibrium 1.0 mole of ammonia remains. The equilibrium
constant Kc for the dissociation is
a) 27/16 (mole dm-3)2 b) 27/8 (mole dm-3)2
c) 27/4 (mole dm-3)2 d) None
co m
.
7. An equilibrium reaction is endothermic if K1 and K2 are the equilibrium constants at T1 and T2
temperature respectively and if T2 is greater than T1 than
l I ai
a) K1 < K2 b) K1 > K2
v is o A
c) K1 = K2
L d) None
k al A
w.
11. CHEMICAL KINETICS
M - II 1 x 1= 1
w w
N A
1. Hydrolysis of an ester by dilute HCl is an example for
(a) Second order reaction
(c) pseudo first order reaction
.A N (b) zero order reaction
(d) first order reaction
R
2. The unit of zero order rate constant is
(a) litre mol–1sec–1 (b) mol litre–1 sec–1 (c) sec–1 (d) litre2 sec–1
3. The excess energy which a molecule must process to becom active is known as
ty
(a) kinetic energy (b) threshold energy

(c) potential energy (d) activation energy
4. Arrhenius equation is
(a) k = Ae–1/RT (b) k = Ae–RT/Ea (c) k = Ae–Ea/RT (d) k = AeEa/RT
5. The term A in arrhenius equation is called as
(a) Probability factor (b) Activation of energy
(c) Collision factor (d) Frequency factor
6. The sum of the powers of the concentration terms that occur in the rate equation is called
(a) molecularity (b) Order
(c) rate (d) rate constant

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7. Reactions in which the reacting molecules resact in more than one way yielding different set of products
are called
(a) consecutive reactions (b) parallel reactions
(c) opposing reactions (d) chain reactions
8. The half life period of a first order reaction is 10 minutes. Then its rate constant is
(a) 6.93 x 102 min–1 (b) 0.693 x 10–2 min–1
(c) 6.932 x 10–2 min–1 (d) 69.3 x 10–1 min–1
9. For a reaction : aA bB, the rate of reaction is doubled when the concentratin of A is increased
by your times. The rate of reaction is equal to
(a) k [A]a (b) k [A]½ (c) k [A]1/a (d) k [A]
d [N2O5]
10. 2N2O5 4NO2 + O2, = k1[N2O5],
dt
d [NO2] d [O2 ]
= k2 [N2O5] and = k3 [N2O5], the relation between k1, k2 and k3 is
dt dt
(a) 2k1 = 4k2 = k3 (b) k1 = k2 = k3 (c) 2k1 = k2 = 4k3 (d) 2k1 = k2 = k3
o m
11. For a reaction, Ea = 0 and k = 4.2 x 105 sec–1 at 300 K, the value of k at 310K will be
c
(a) 4.2 x 105 sec–1
I
(b) 8.4 x 105 sec–1
ai .
(c) 7.4 x 104 sec–1
o l A
(d) unpredictable
s
l v i L
. k a
12. SURFACE
A
CHEMISTRY
M
3 x 1= 3
w w A
1. The migration of colloidal particles under the influence of an electric field is known as
(a) electroosmosis w N
(b) cataphoresis
(c) electrodialysis N
(d) electrophoresis
.A
2. Which one is the correct factor that explains the increase of rate of reaction by a catalyst
(a) shap selectivity
R
(c) increase of free energy
(b) particle size
(d) lowering of activation energy
3. Fog is a colloidal solution of
(a) gas in liquid (b) liquid in gas (c) gas in solid (d) solid in gas
4. The phenomenon of Tyndall’s effect is not observed in
(a) emulsion (b) colloidal solution
(c) true solution (d) None
5. The Tyndall’s effect associated with colloidal particles is due to
(a) presence of change (b) scattering of light
(c) absorption of light (d) reflection of light
6. In case of physical adsorption, there is desorption when
(a) temperature increases (b) temperature decreases
(c) pressure increases (d) concentration increases
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7. Colloidal medicines are more effective because

(a) they are clean (b) they are easy to prepare
(c) the germs more towards, them (d) they are easily assimilated and adsorbed
8. Oil soluble dye is mixed with emulsion and emulsion remains colourless then, the emulsion is
(a) O/W (b) W/O (c) O/O (d) W/W
9. For selective hydrogenation of alkyness into alkene the catalyst used is
(a) Ni / 250°C (b) Pt / 25°C
(c) Pd, partially inactivated by quinoline (d) Raney nickel
10. For chemisorption, which is wrong
(a) irreversivle
(b) it requires activation energy
(c) it forms multimolecular layers on adsorbate
(d) surface compounds are formed
11. An emulsion is a colloidal solution of
(a) two solids (b) two liquids (c) two gases (d) one solid one liquid
12. Colloids are purified by
co m
(a) precipitation (b) coagulation
I i
(c) dialysis
a . (d) filtration
s o l A
l v i
13. ELECTRO CHEMISTRY
L
-I 1 x 1= 1
. k a
M A
1. The process in which chemical change occurs on passing electricity is termed as ................
(a) neutralisation
w w A
(b) hydrolysis (c) electrolysis (d) ionisation
w N
2. The laws of electrolysis were enunciated first by ...................
(a) Dalton (b) Faraday
.A N (c) Kekule (d) Avogadro

3. When one coulomb of electricity is passed through an electrolytic solution, the mass deposited on the
R
electrode is equal to ........................
(a) equivalent weight
(c) electrochemical equivalent
(b) molecular weight
(d) one gram
4. Faraday’s laws of electrolysis are related to ...............
(a) atomic number of the cation (b) atomic number of the anion
(c) equivalent weight of the electrolyte (d) speed of the cation
5. The specific conductance of a 0.01 M solution of KCl is 0.0014 ohm–1 cm–1 at 25oC. Its equivalent
conductance is ..................
(a) 14 ohm–1 cm2 eq–1 (b) 140 ohm–1 cm2 eq–1
(c) 1.4 ohm–1 cm2 eq–1 (d) 0.14 ohm–1 cm2 eq–1
o
6. The equivalent conductivity of CH3COOH at 25 C is 80 ohm–1 cm2 eq–1 and at infinite dilution 400
ohm–1 cm2 eq–1. The degree of dissociation of CH3COOH is ......................
(a) 1 (b) 0.2 (c) 0.1 (d) 0.3

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7. When sodium acetate is added to acetic acid, the degree of ionisation of acetic acid ................
(a) increases (b) decreases (c) does not change (d) becomes zero
8. NH4OH is a weak base because ...............
(a) it has low vapur pressure (b) it is only partially ionised
(c) it is completely ionised (d) it has low density
9. Which one of the following formulae represents Ostwald’s dilution law for a binary electrolyte whose
degree of dissociation is α and concentration C.
(1-α) C α 2C
(a) K = (b) K =
α 1-α
(1-α)C α 2C
(c) K = (d) K =
α2 (1- α)C
10. Ostwald’s dilution law is applicable in the case of the solution of ................
(a) CH3COOH (b) NaCl (c) NaOH (d) H2SO4
11. Which one of the following relationship is correct?
1
(a) pH =
[H+]
(b) pH = log10 [H+]
co m
I ai .
l
1
(c) log10 pH = [H+]
v is o LA
(d) pH = log10
[H+]
l
12. When 10–6 mole of a monobasic strong acid is dissolved in one litre of solvent, the pH of the solution
is ......................
. k a
M A
w
(a) 6 (b) 7 (c) less than 6 (d) more than 7
(a) 1 X 10–12 ww
N A
13. When pH of a solution is 2, the hydrogen ion concentration in moles litre - 1 is ..............
(b) 1 X 10–2 (c) 1 X 10–7 (d) 1 X 10–4
(a) 1 (b) 10–1 .A N

14. The pH of a solution containing 0.1 N NaOH solution is .................
(c) 13 (d) 10–13
R
15. A solution which is resistant to changes of pH on addition of small amounts of an acid or a base is
known as .................
(a) buffer solution (b) true solution
(c) isohydric solution (d) ideal solution
16. The hydrogen ion concentration of a buffer solution consisting of a weak acid and its salt is given by
.................
[Acid]
(a) [H+] = Ka (b) [H+] = Ka [Salt]
[Salt]
[Salt]
(c) [H+] = Ka [Acid] (d) [H+] = Ka
[Acid]
17. Indicators used in acid - base titrations are ..................
(a) strong organic acids (b) strong organic bases
(c) weak organic acids or weak organic bases (d) non-eletrolysis
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18. For the titration between oxalic acid and sodium hydroxide, the indicator used in ...............
(a) potassium permanganate (b) phenolphthalein
(c) litmus (d) methyl orange
16. HYDROXY DERIVATIVES 1 x 1= 1

1. Which has the highest boiling point?
(a) CH3CH3 (b) CH3OH (c) C2H5OH (d) C3H8
2. Which is soluble in H2O?

(a) Phenol (b) Alkanes (c) Alcohols (d) Alkenes
3. Order of reactivity of alcohol towards sodium metal is
(a) primary < secondary > tertiary
(b) primary > secondary > tertiary
(c) primary < secondary < tertiary
(d) primary > secondary < tertiary
co m
I
4. The boiling point of ethyl alcohol should be less than that of
ai .
(a) propane
s o l A
(b) formic acid
(c) dimethyl ether
l v i L
(d) None of the above
. k a A
5. Ethyl alcohol cannot be used as a solvent for CH3MgI because
M
ww
(a) CH3MgI reacts with alcohol giving methane
A
w N
(b) The reaction between them is explosive in nature
(c) CH3MgI is converted to C2H5MgI
.A N
(d) Alcohol is immicible with CH3MgI
intermediate formed is
(a) sulphonium ion
R
6. When alcohols are converted to alkyl chlorides by thionyl chloride in presence of pyridine the
(b) chlorosulphonic acid

(c) alkyl chlorosulphite (d) chlorosulphite
7. On oxidation of an alcohol gives an aldehyde having the same number of carbon atoms as that of
alcohol. The alcohol is
(a) 1o alcohol (b) 2o alcohol (c) 3o alcohol (d) None
8. A compound that gives a positive iodoform test is
(a) 1-pentanol (b) 2-pentanone
(c) 3-pentanone (d) pentanal
9. The compound that racts fastest with Lucas reagent is
(a) butan - 1 - ol (b) butan - 2 - ol
(c) 2 methyl propan - 1 - ol (d) 2 - methyl propan - 2 - ol

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10. The ionization constant of phenol is higher than that of ethanol because
(a) phenoxide ion is bulkier than ethoxide
(b) phenoxide ion is sronger base than ethoxide
(c) phenoxide ion is stablized through delocalisation
(d) phenoxide ion is less stable than ethoxide ion
11. Among the following compounds strongest acid is
(a) HC = CH (b) C6H6 (c) C2H6 (d) CH3OH
12. The most unlikely representation of resonance structures of p-nitrophenoxide ion is
o o- o
o-
(a) (b) (c) (d) -
N N N
N + + +
(-)
o o (-) o o o- o
o o(-)
13. p-nitrophenol is having lower pKa value than phenol because
(a) phenol is more acide than p-nitro phenol
co m
I i .
(b) anion of p-nitrophenol is more stabilised by resonance than that of phenol
a
o l A
(c) degree of ionisation of p-nitro phenol is less than that of phenol
s
v i L
(d) anion of p-nitrophenol is less stable than that of phenol
l
(a) (CH3)3COH a
14. The reaction of Lucas reagent is fast with
. k M
(b) (CH3)2CHOH
A (c) CH3(CH2)2OH (d) CH3CH2OH
ww A
15. When phenol is distilled with Zn dust it gives
(a) benzaldehyde
w N
(b) benzoic acid (c) toluene (d) benzene
(a) benzoic acid

N
16. A compound that undergoes bromination easily is
.A
(b) benzene (c) phenol (d) toluene
(a) position isomerism

R
17. Isomerism exhibited by ethylene glycol is
(b) chain isomerism
(c) functional isomerism (d) both (a) and (c)
18. Ethylene diamine is converted to ethylene glycol using
(a) Na2CO3 solution (b) nitrous acid (c) NaHCO3 (aqueous) (d) Baeyer’s reagent
19. Ethylene glycol forms terylene with

(a) adipic acid (b) phthalic anhydride (c) terephthalic acid (d) oxalic acid
20. 1 - propanol and 2 - propanolcan be best distinghished by
(a) oxidation with KMnO4 followed by reaction with Fehling solution
(b) oxidation with acid dichromate followed by reaction with Fehling solution
(c) oxidation by heating with copper followed by reaction with Fehling solution
(d) oxidation with concentrated H2SO4 followed by reaction with Fehling solution

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21. Glycerol is used

(a) as a sweeteing agent
(b) in the manufacture of good quality soap
(c) in the manufacture of nitro glycerin
(d) in all the above
22. The alcohol obtained by the hydrolysis of oils and fats is
(a) pentanol (b) propanol (c) glycerol (d) glycol
23. The number of secondary alcoholic group in glycerol is
(a) 1 (b) 2 (c) 3 (d) 0
24. The active component of dynamite is
(a) Keiselghur (b) Nitro glycerine
(c) Nitro benzene (d) Trinitro toluene
25. The reaction of ethylene glycol with PI3 gives
(a) ICH2CH2I (b) CH2 = CH2 (c) CH2 = CHI (d) ICH = CHI
17. ETHERS
co m 2 x 1= 2
I ai .
s o l A
1. The isomerism exhibited by C2H5OC2H5 and CH3 – O – CH – CH3 is
l v i L |
(a) Functional
. k a
M
(b) metamerism A CH3
(c) position (d) chain
ww A
2. Which one of the following is simple ether?
(a) CH3 – O – C2H5
w N (b) C2H5 – O – CH3
(c) C2H5 – O – C2H5
.A
3. Diethyl ether can be decomposed with
N (d) C3H7 – O – C2H5
(a) HI
4. Oxygen atom of ether is

R
(b) KMnO4 (c) NaOH (d) H2O
(a) very active (b) Replacable (c) oxidising (d) Comparatively inert
5. According to Lewis concept of acids and bases, ethers are
(a) Neutral (b) Acidic (c) Basic (d) Amphoteric
6. Intermolecular hydrogen bonds are not present in
(a) CH3COOH (b) C2H5OC2H5 (c) CH3CH2OH (d) C2H5NH2
7. When ethyl Iodide is treated with dry silver oxide it forms
(a) Ethyl alcohol (b) diethylether (c) silver ethoxide (d) ethylmethyl ether
8. Williamson’s synthesis is an example of
(a) nucleophilic addition (b) electrophilic addition
(c) electrophilic substitution (d) Nucleophilic substitution reaction
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9. When ether is exposed to air for sometime an explosive substance produced is

(a) peroxide (b) oxide (c) TNT (d) superoxide
10. Ether is formed when alkylhalide is treated with sodium alkoxide. This method is known as
(a) Hoffmann reaction (b) Williamson’s synthesis
(c) Wurtz synthesis (d) Kolbe’s reaction
18. CORBONYL COMPOUNDS 1 x 1= 1

1. The chain isomer of 2-methyl propanal is
(a) 2-butanone (b) butanal
(c) 2-methyl propanol (d) but 3 - ene - 2 - ol
2. Schiffs reagent gives pink colour with
(a) acetone (b) acetaldehyde (c) ethyl alcohol (d) methyl acetate
3. Isopropyl alcohol vapours with air over silver catalyst at 520 K give
(a) tert.butyl alcohol (b) acetaldehyde
co m
(c) acetone (d) 2-propanol
I ai .
o l
4. Methyl ketones are usually characterised by
s A
(a) the Fehling’s solution
l v i L
(b) the iodoform test
(c) the Schiff’s test
. k a A
(d) the Tollen’s reagent
M
w
5. Which of the following compounds is oxidised to give ethyl methyl ketone?
(a) 2-propanol
ww
6. Formaldehyde polymerises to give
N A
(b) 2-pentanone (c) 1-butanol (d) 2-butanol
(a) paraldehyde
7. Tollen’s reagent is
.A N
(b) paraformaldehyde (c) formalin (d) formic acid
R
(a) ammoniacal cuprous chloride
(c) ammoniacal silver nitrate
(b) ammoniacal cuprous oxide
(d) ammoniacal silver chloride
8. When acetaldehyde is heated with Fehling solution, it gives a precipitate of
(a) Cu2O (b) CuO (c) CuO + Cu2O (d) Cu
9. The compound that does not undergo Cannizzaro reaction is
(a) formaldehyde (b) acetaldehyde
(c) benzaldehyde (d) trimethyl acetaldehyde
10. The formation of cyanohydrin from a ketone is an example of

(a) electrophilic addition (b) nucleophilic addition
(c) nucleophilic substitution (d) electrophilic subtitution
11. Hydrogenation of benzoyl chloride in the presernce of Pd on BaSO4 gives
(a) phenol (b) benzoic acid (c) benzyl alcohol (d) benzaldehyde

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12. From which of the following, tertiary butyl alcohol is obtained by the action of methyl magnesium
iodide?
(a) HCHO (b) CH3CHO (c) CH3COCH3 (d) CO2
13. During reduction of aldehydes with hydrazine and C2H5ONa the product formed is
(a) R–CH = N–NH 2
(b) R–C = N
(c) R – C – NH2 (d) R – CH3
||
O
14. Aldol is
(a) 2-hydroxy butanol (b) 3-hydroxy butanol
(c) 3-hydroxy butanal (d) 2-hydroxy butanal
15. In the reduction of acetaldehyde using LiAlH4 the hydride ion acts as
(a) electrophile (b) nucleophile (c) both (a) and (b) (d) a free radical
16. Which of the following statement is wrong?

(a) 2-pentanone and 3-pentanone are position isomers
co m
I
(b) aqueous solution of formaldehyde is known as formalin
ai .
s o l A
(c) aldehydes and ketones undergo nucleophilic substitution
l v i
(d) aldehydes act as reducing agents
L
. k a A
17. A cyanohydrin of a compound X on hydrolysis gives lactic acid. THe X is
M
(a) HCHO
ww
(b) CH3CHO
A (c) (CH3)2 CO (d) C6H5CH2CHO
w N
18. The IUPAC name of CH3 – C = CH – C – CH3 is
|
CH3
(a) 4-methylpent-3-en-2-one
O
.A N
||
(b) 2-methylpent-3-en-2-one
(c) 3-methylpent-2-en-1one
R (d) None of these
19. Which of the following does not give iodoform test?

(a) aceto phenone (b) benzophenone
(c) CH3 – CHOH (d) CH3 – CH – CH2 CH2 – CH3
| |
CH3 OH
20. The compound which does not reduce Fehling solution is

(a) formaldehyde (b) acetaldehyde
(c) benzaldehyde (d) propionaldehyde
Conc. H2SO4
21. CH3COCH3 The product is
(a) mesitylene (b) mesityl oxide
(c) phorone (d) paraldehyde
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22. Which compound on strong oxidation gives propionic acid?

(a) CH3 – CH – CH3 (b) CH3 – CO – CH3
|
OH
(c) CH3 (d) CH3 CH2 CH2 OH

|
CH3 – C – OH
|
CH3
23. The compound used in the preparation of the tranquilizer, sulphonal is
(a) acetone (b) acetophenone
(c) isopropyl alcohol (d) glycol
distillation
24. Calcium acetate + calcium benzoate gives
(a) benzophenone (b) benzaldehyde
(c) acetophenone ` (d) phenyl benzoate
25. Bakelite is a product of reaction between
(a) formaldehyde and NaOH (b) phenol and methanal
co m
(c) aniline and NaOH
I ai .
(d) phenol and chloroform
s l
o ACIDSLA 1 x 1= 1
v
19. CARBOXYLIC
l i
. k a
M A
(a) C2H5OH
w w
1. Which of the following is least acidic
(b) CH3COOH
A (c) C6H5OH (d) ClCH2COOH
w N
2. Weakest acid among the following is
(a) Acetic acid
.A N
(b) Phenol
3. Ester formation involves the reaction of
(c) Water (d) Acetylene
R
(a) an aldehyde and a ketone
(b) an alcohol with RMgX
(c) Two molecules of an acid with dehydrating agent
(d) an acylhalide with an alcohol
4. Heating a mixture of sodium acetate and soda lime gives
(a) methane (b) ethane (c) acetic acid (d) oxalic acid
5. The acid which reduces Tollen’s reagent is
(a) acetic acid (b) benzoic acid (c) formic acid (d) oxalic acid
CH3
|
6. The IUPAC name of CH3 – CH2 – CH – COOH is
(a) α - methyl butric acid (b) 3-methyl butanoic acid
(c) 2-methyl butanoic acid (d) Iso pentanoic acid

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7. The Isomerism exhibited by CH3CH2COOH and CH3COOCH3 is

(a) metamerism (b) position (c) chain (d) functional
8. The acid that cannot be prepared by Grignard reagent
(a) acetic acid (b) formic acid (c) butyric acid (d) benzoic acid
9. Which order of arrangement is correct iterms of the strength of the acid
(a) CH3–CH2COOH > CH3COOH < HCOOH < ClCH2COOH
(b) ClCH2COOH < HCOOH < CH3COOH < CH3CH2COOH
(c) CH3–CH2COOH < CH3COOH < HCOOH < ClCH2COOH
(d) HCOOH > CH3CH2COOH < CH3COOH > ClCH2COOH
10. The compound which does not undergo intermolecular dehydration with P2O5 is
(a) acetic acid (b) formic acid (c) propionic acid (d) Butyric acid
H
160oC
11. C=O The product is
HO
(a) CO + H2O (b) HCOOH (c) H2 + CO2
co m
(d) HCHO + O2
I ai .
l
12. When chlorine is passed through acetic acid in presence of red P, it forms.
(a) acetyl chloride
v is o A
(b) Trichloro acetaldehyde
L
(c) Trichloro acetic acid
k al (d) Methyl chloride

A
w.
13. Which of the following compounds will react with NaHCO3 solution to give sodium salt and CO2 ?
M
(a) acetic acid
ww
N A
(b) n-hexanol (c) phenol (d) both (a) and (c)
14. When propanoic acid is treated with aqueous sodium - bicarbonatate, CO2 is liberated. The “C” of
CO2 comes from
(a) methyl group
(c) methylene group
.A N (b) carboxylic acid group
(d) bicarbonate
R
15. Carboxylic acids are more acidic than phenol and alcohol because of
(a) inter molecular hydrogen bonding (b) formation of dimers
(c) highly acidic hydrogen (d) greater resonance stabilisation of their conjugate base
16. Among the following the strongest acid is
(a) ClCH2COOH (b) Cl3CCOOH (c) CH3COOH (d) Cl2CHCOOH
17. Which of the following compound is optically active?
(a) CH3CH2COOH (b) HOOC–CH2–COOH
(c) CH3CH(OH)COOH (d) Cl2CHCOOH
18. CH3CH(OH)COOH ? The product is
H2O2/Fe2+
(a) CH3COCOOH (b) CH3CH2COOH
(c) CH3CHOHCHO (d) HOOCCH2COOH

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19. The compound found in some stony deposit in kidneys is

(a) potassium oxalate (b) oxalic acid
(c) potassium succinate (d) calcium oxalate
20. Ethylene cyanide on hydrolysis using acid gives
(a) oxalic acid (b) succinic acid
(c) adipic acid (d) propionic acid
20. ORGANIC NITROGEN COMPOUNDS 3 x 1= 3

1. Bromo ethane reacts with silver nitrite to give
(a) C2H5NO2 (b) C2H5–O–NO (c) C2H5Ag + NaBr (d) C2H5NC
O
2. The isomerism exhibited by CH3 – CH2 – N and CH3 CH2 – O – N = O is
O
(a) position (b) chain (c) functional (d) tautomerism
co m
.
3. In nitro alkanes –NO2 group is converted to – NH2 group by the reaction with
(a) Sn/HCl (b) Zn dust
l I
(c) Zn/NH4Cl
ai (d) Zn/NaOH
v is o A
4. When nitromethane is reduced with Zn dust + NH4Cl in neutral medium, we get
L
(a) CH3NH2
k al A
(b) C2H5NH2
(c) CH3NHOH
w. (d) C2H5COOH
M
5. The compound that is most reactive towards electrophilic nitration is
(a) Toluene
ww
(b) benzene
N A (c) benzoic acid (d) nitrobenzene
(a) nitro propane

(c) 2-nitro-1-propanol
N
6. Nitromethane condenses with acetaldehyde to give
.A (b) 1-nitro-2-propanol
(d) 3-nitro propanol
(a) aniline
R
7. Which of the following compounds has the smell of bitter almonds?
(b) nitro methane
(c) benzene sulphonic acid (d) nitrobenzene
8. Nitration of nitrobenzene results in
(a) o-dinitro benzene (b) 1,3,5-trinitro benzene
(c) p-dinitro benzene (d) m-dinitro benzene
9. Nitrobenzene on electrolytic reduction in con. sulphuric acid, the intermediate formed is
(a) C6H5NH – NHC6H5 (b) C6H5 – NHOH
(c) C6H5 – N = N – C6H5 (d) C6H5.HSO4
10. Electrophile used in the nitration of benzene is
(a) hydronium ion (b) sulphonic acid
(c) nitronium ion (d) bromide ion

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11. The reduction of CH3 – CH2 – C = N with sodium and alcohol results in the formation of
(a) CH3 – CH– CH3 (b) CH3 – CH2 – CH2 – OH + N2
NH2
(c) CH3 – CH2 – CH2 – NH2 (d) CH3 – CH2 – NH2
12. The basic character of amines is due to the
(a) tetrahedral structure
(b) presence of nitrogen atom
(c) lone pair of electrons on nitrogen atom
(d) high electronegativity of nitrogen
13. The organic compound that undergoes carbylamine reaction is
(a) (C2H5)2NH (b) C2H5NH2
(c) (C2H5)3N (d) (C2H5)4 N+ I–
14. Primary amine acts as
(a) Electrophile (b) lewis base
co m
.
(c) Lewis acid (d) Free radical
l I
15. Oxidation of aniline with acidified potassium dichromate gives
ai
(a) p-benzo quinone
v is o A
(b) benzoic acid
L
(c) benzaldehyde
k al A
(d) benzyl alcohol
.
16. Which one of the following is a secondary amine?
(a) aniline
ww M
(b) diphenyl amine
A
(c) sec.butylamine
w N (d) tert.butylamine
17. C6H5NH2
(a) C6H5Cl
NaNO 2/HCl
N
X. Identify X.
.A
(b) C6H5NHOH
(c) C6H5N2Cl R(d) C6H5OH
18. Which of the following will not undergo diazotisation?
(a) m-toluidine (b) aniline
(c) p-amino (d) benzyl amine
19. Anilin differs from ethylamine by the reaction with
(a) metallic sodium
(b) an alkyl halide
(c) chloroform and caustic potash
(d) nitrous acid
20. When aqueous solution of benzene diazonium chloride is boiled the product formed is
(a) benzyl alcohol (b) benzene + N2
(c) phenol (d) phenyl hydroxylamine

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21. BIOMOLECULES 2 x 1= 2
1. Which is a mono saccharide among the following
(a) Sucrose (b) Cellulose (c) Maltose (d) Glucose
2. Identify the reducing sugar.
(a) Sucrose (b) Cellulose (c) Starch (d) Glucose
3. Sucrose is not
(a) a di saccharide (b) a non - reducing sugar
(c) hydrolysed to only glucose (d) hydrolysed to glucose & fructose
4. Sucrose contains glucose and fructose linked by
(a) C1 – C1 (b) C1 – C2 (c) C1 – C4 (d) C1 – C6
5. Glucose is not oxidised to gluconic acid by
(a) Br2/H2O (b) Fehling solutions (c) Tollen’s reagent (d) Conc. HNO3
6. Inversion of sucrose refers to
(a) oxidation of sucrose
o m
(b) reduction of sucrose
c
I
(c) hydrolysis of sucrose to glucose and fructose
ai .
(d) polymerisation of sucrose
o l A
7. Glucose forms __________with acetic anhydride and sodium acetate.
s
(a) di acetate
v i
(b) tetra acetate
l L (c) penta acetate (d) hexa acetate
k a
8. The amino acid without chiral carbon is
. M A
(a) Glysine
ww
(b) Alanine
9. The building block of proteins are
A
(c) Proline (d) Thyrosine
(a) α-hydroxy acids w N

(b) α-amino acids (c) β-hydroxy acids (d) β-amino acids
10. Which is not true of amino acid?
.A
(a) amino acid forms Z witter ion
N (b) has isoelectric point
(c) dual behaviours
R
11. Two amino acids say A, B - react to give
(d) amino acid is insoluble in NaOH solution
(a) two dipeptides (b) three dipeptides (c) four dipeptides (d) only one
12. A di peptide does not have
(a) two peptide units (b) portions of two amino acids
(c) an amido group (d) salt like structure
13. Proteins are not sensitive to
(a) acids (b) bases (c) elevated temperature (d) water
14. Denaturation does not involve
(a) breaking up of H - bonding in proteins
(b) the loss of biological action of enzyme
(c) the loss of secondary stucture
(d) loss of primary structure of proteins
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15. Specificity of enzyme is due to

(a) the sequence of amino acids (b) secondary structure
(c) tertiary structure (d) all of the above
16. Ultimate products of hydrolysis of proteins is
(a) aniline (b) aliphatic acid (c) amino acid (d)aromatic acid
17. Proteins are
(a) polypeptides (b) polyacids (c) poly phenols (d) poly esters
18. Which of the following contains a lipid?
(a) starch (b) mineral oil (c) edible oil (d) peptide
19. Which among the following contains triglyceride?
(a) Wax (b) Cooking oil (c) Essential oil (d) Albumin
20. Which contains a long chain ester?
(a) wax (b) cooking oil (c) turpentine oil (d) cellulose
21. An example of a fatty acid obtained from a cooking oil is
(a) acetic acid (b) stearic acid (c) benzoic acid
co m (d) oxalic acid
.
22. Which is not a saturated fatty acid?
(a) Palmitic acid
l
(b) Stearic acid
I ai
(c) Olei acid (d) Glyceric acid
is o
23. Alkaline hydrolysis of cooking oil gives
v LA
(a) soap (b) glycerol
k al A
(c) fatty acid (d) both (a) and (b)
24. Hair and nail contains
(a) cellulose
w.
(b) fat M
(c) keratin (d) lipid
ww
N A
25. Important constituent of cell wall is
(a) lipid (b) cellulose
.A N (c) protein (d) vitamin
R
ALL THE BEST
“ All the Glitters are not Gold “”

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HIGHER SECONDARY SECOND YEAR

Chemistry
March - 2006
O
1. The isomerism exhibited by CH3- CH2- N and CH3- CH2- O - N=O is
O
a) position b) chian c) functional d) tautomerism
2. Which of the following nitro - compounds behave as an acid in the presence of strong alkali?
a) Primary b) secondary c) tertiary d) both (a) and (b)
3. Conversion of diazonium chloride to chlorobenzene is called
a) Sandmeyar’s reaction b) Stephan’s reaction
c) Gomberg reaction c) schotten - Baumann reaction
4. Proteins are
a) polypeptides b) polyacids c) polyphenols d) polyesters
5. Mixture of equal molecules of D (+) glucose D (-) fructose in called
a) fruit sugar b) invert sugar c) cane sugar
co m d) non-sugar
a) meso-oxalic acid
AI
6. Oxidation of glycerol with bismuth nitrate gives
b) glyceric acid
ol ai .
c) tartronic acid
al v is
A L d) both (b) and (c)
7. According to lewis concept of acid and bases, ethers are
a) neutral
. k
b) acidic
w M c) basic d) amphoteric
ww A
8. The compound mixed with ethanol to serve as substitute for petrol is
N
N
a) methoxy methane b) ethoxy ethane c) methanol d) ethanal
A
9. Aldol is
a) 2 - hydroxy butanol
c) 3-hydroxy butanal
R . H2O2/Fe 2+
b) 3-hydroxy butanol
d) 2-hydroxy butane
10. CH3CH(OH)COOH X. The X is

a) CH3COCOOH b) CH3CH2COOH c) CH3CHOHCHO d) CH2(COOH)2
11. For a reaction Ea = 0 and K=4.2 x 10 sec at 300 K, the value of K at 310 K will be.
5 -1
a) 4.2x105 sec-1 b) 8.4x105 sec-1 c) 8.4x10-5 sec-1 d) unpredictable

12. The iron catalyst used in the Haber’s process is poisoned by
a) Pt b) H2 c) H2S d) As2O3
13. Curd is a colloidal solution of
a) liquid in liquid b) liquid in solid c) solid in liquid d) solid and liquid
14. An emulsion is a colloidal solution of
a) two solids b) two gases c) two liquids d) solid and liquid
electrode is equal to
a) Equivalent weight b) molecular weight c) Electrochemical equivalent d) one gram
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a) One unit cell b) two unit cells c) eight unit cells d) four unit cells
17. The change of entropy for the process H2O(liq) H2O (vap) involving Δ H(vap) = 40850Jmol-1 at
373K is
a) 120 J mol-1 K-1 b) 9.1 x 10-3 J mol-1 K-1
c) 109.52 J mol-1 K-1 d) 9.1 x 10-4 J mol-1 K-1
18. Which of the following does not result in an increase in the entropy?
a) Rusting of iron b) crystallization of sucrose from solution
c) Vaporization of camphor d) conversion of ice to water
19. For the homogenous gas reaction at 600K, 4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g) the equilibrium
constant Kc has the unit
a) mol dm-3 b) (mol dm-3)-1 c) (mol dm-3)10 d) (mol dm-3)9
20. 2H2O(g) + 2Cl2(g) 4 HCl(g) + 5O2(g)
a) KP = KC b) KP > KC c) KP < KC d) KP = KC= 0
co m
I .
a) Scandium b) titanium c) zinc d) lanthanum
ai
l A
22. The elements in which extra electron enter (n-2)f orbital are
a) s-block elements
is o L
b) p-block elements
c) d-block elements
al v Ad) f-block elements
. k M
23. The isotope used as a power source in long mission space probes is
w
a) U-235 b) Pu-235
ww N A c) Pu-238 d) U-238
24. The type of isomerism found in the complexes (Pt (NH3)4 [CuCl4] and (Cu(NH3)4 [PtCl4]
a) ionization isomeirsm
c) linkage isomerism
.A N b) co-ordination isomerism
d) ligand isomerism
a) 24 hours
R
25. After 24 hours 0.125g of the initial quantity of 1g of a radioactive isotope is left out. The half - life
period is
b) 12 hours c) 8 hours d) 16 hours
a) Bohr b) Heisenberg c) De Broglie d) Pauli
27. The momentum of a particle which has De Broglie wavelength of 1Ao ( h = 6.626 x 10-34 Kgm2s-1) is
a) 6.66 x 10-23 Kg ms-1 b) 6.66 x 10-24 Kg ms-1
c) 6.66 x 10-34 Kg ms-1 d) 66.6 x 10-23 Kg ms-1
28. The order of ionization energy is
a) s < p < d < f b) s > p > d > f c) s > d > p > f d) s < d < p < f
29. The general electronic configuration of carbon family is
a) ns2 np2 b) ns2 np3 c) ns2 np1 d) ns2 np4
30. Which of the following compounds will not positive chromyl chloride test?
a) Cu Cl2 b) C6H5Cl c) Zn Cl2 d) HgCl2

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Chemistry
June - 2006
1. Ethylene diamine forms glycol with
a) nitrous acid b) Na2Co3 solution c) NaHCO3 solution d) Bayer’s reagent
2. When ethers are exposed to air for a long time, they form
a) peroxides b) halides c) oxides d) superoxides
3. The isomerism exhibited 1 propanal and methoxy ethane is
a) chain b) position c) functional d) metamerism
4. The compound that does not answer idofom test is
a) acetophenone b) isopropyl alcohol c) 2-pentanol d) benzophenone
5. The compound found as stony deposits in kidneys is
a) Potassium Oxalate b) Oxalic acid
c) Potassium Succinate d) calcium oxalate
co m
I
6. Semiconductors which exhibit conductivity due to the flow of excess negatively charged electron are
called
ai .
a) Super conductors
v is o l
LA
b) n-type semiconductors
A
c) p-type semicondictors d) insulators
al
7. The amount of heat exchanged with the surrounding at constant temperature and pressure is called
k
a) Δ E
w.
b) Δ H
A M c) Δ S d) Δ G
ww N
8. If Δ G of a reaction is negative, the change is
N
a) spontaneous b) non - spontaneous c) reversible d) none of these
.A
9. For the homogenous gaseous reaction at 600K 4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g), the
equilibrium constant Kc has the unit
a) (mol dm-3)-1
R b) mol dm-3 c) (mol dm-3)-4 d) (mol dm-3)-2
10. If the equilibrium constant for the formation of a product is 25, the equilibrium constant for the
decomposition of the same product is
1
a) 25 b) c) 5 d) 625
25
11. De Broglie equation is
a) λ = mv / h b) λ = hmv c) λ = hv / m d) λ = h / mv
12. The bond order of nitrogen molecule is
a) 1 b) 2 c) 3 d) 4
13. Effective nuclear charge Z* can be calculated using the formula
a) Z* = Z - S b) Z* = Z + S c) Z* = S - Z d) Z = Z* - S
14. The metalloid among the following is
a) Pb b) P c) Ge d) Sn
15. The chemical composition of slag formed during the smelting process in the extraction of copper is
a) Cu2O + FeS b) Fe SiO3 c) Cu Fe S2 d) Cu2S + FeO
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16. Organic compounds that does not undergo diazotization is

a) m - toluidine b) aniline c) p - aminophenol d) benzyl amine
17. The intermediate formed on electrolytic reduction of nitrobenzene in conc. H2SO4 is
a) C5H5NH - NHC6H5 b) C6H5 - NHOH
c) C6H5 - N = N - C6H5 d) all of these
18. The compound that does not show tautomerism is
a) Nitrobenzene b) nitro-methane c) nitro-ethane d) 2-nitropropane
19. The reducing sugar is
a) sucrose b) cellulose c) starch d) glucose
a) glycine b) alanine c) proline d) tyrosine
21. The half - life period of a first order reaction is 10 minutes. The rate constant is
a) 6.93 x 102min-1 b) 0.693 x 10-2min-1
c) 6.932 x 10-2min-1 d) 69.3 x 10-1min-1
22. Tyndall’s effect is not observed in
co m
a) emulsions
I
b) colloidal solutions
i .
c) true solutions
a
d) none of these
o l A
23. Decomposition of hydrogen peroxide is retarded in the presence of
s
a) alcohol
v i
b) glycerin
l L c) MnO2 d) MO
24. An example of gel is
. k a
M A
w
a) Paint b) Pumice - Stone c) Milk d) curd
a) methyl orange ww N A
25. The indicator suitable for the titration of oxalic acid against NaOH is
b) potassium permanganate
c) Phenophthalein
.A N d) litmus
26. The transition element showing maximum oxidation state is
a) Sc
R
b) Ti
27. Elements that form oxocations are
c) Os d) Zn
a) lanthanides b) actinides c) noble gases d) base metals

28. The radioactive lanthanide is
a) terbium b) lutetium c) promethium d) gadolinium
29. An example of ambidentate ligand is
a) Cl b) NO-2 c) H2O d) NH2
30. Which is one of the following particles is used to bombard 13Al27 to give 15P30 and a neutron?
a) α - particle b) β - particle c) neutron d) proton

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Chemistry
October - 2006
1. The metal used in galvansing iron sheets is
a) chromium b) zinc c) copper d) silver
2. Among the lanthanides elements, with the increase in atomic number the tendency to act as reducing
agent
a) increase b) decrease c) no change d) none of these
3. The long mission space probes use __________ as power source
a) Pu b) U c) Th d) Pm
4. Which if the following is cationic complex?
a) K4 [Fe(Cn)6 b) [Cu(NH3)6]Cl2 c) K3 [Cr(C2O4)3] d) K3[Fe(CN)6]
5. Loss of - particle is equivalent to
a) increase of one proton only b) decrease of one neutron
c) loss of proton d) both (a) and (b)
co m
a reaction is
o l AI ai .
6. The first order rate constant of a reaction is 0.0693 min-1. Then the required for 50% completion of
a) 10 min b) 1 min
l v is
A L c) 100 min
a
d) 50 min
a) Temperature increase
w. k M
b) Temperature decrease
c) Pressure increase
ww N
8. Smoke is a colloidal solution of A d) concentration increase
a) gas in solid
.A N
b) solid in gas
9. Colloidal medicine are more effective because
c) gas in liquid d) liquid in gas
a) they are clean

R
c) the germs move towards them
b) they are easy to prepare
d) the are easily assimilated and adsorbed
10. When sodium acetate is added to a solution of acetic acid, the degree of ionization of acetic acid
a) increases b) decrease c) does not change d) becomes unity
11. The nitro group can be reduced to primary amino group by
a) Sn/con.Hcl b) Zn dust c) Zn/NH4Cl d) Zn/NaOH
a) (C2H5)2NH b) C2H5NH2 c) (C2H5)3N d) (C2H5)4N+I-
13. The nitrogen compound used in the preparation of sulpha drugs is
a) methylamine b) nitromethane c) amino benzene d) nitrobenzene
14. Nucleic acid is made up of
a) an organic base b) sugar unit c) phosphoric acid d) all of these
15. Ultimate product of hydrolysis of protein is
a) aniline b) aliphatic acid c) amino acid d) aromatic acid

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16. The circumference of the circular orbit of electron is an integral multiple of its
a) frequency b) momentum c) mass d) wavelength
17. The nature of hybridization in IF7 molecule is
a) Sp2d2 b) Sp3d4 c) Sp3d3 d) sp2d4
18. On moving down a group, the radius of an ion
a) decreases b) increase
c) first increases and then decreases d) remains a constant
19. The toxin element of boron family is
a) boron b) indium c) thallium d) gallium
20. The general outer electronic configuration of d block element is
a) (n - 1) d1-10 b) (n - 1) d1-10 ns1-2 c) (n - 1) d10 ns1-2 d) (n - 1)d5 ns1
21. The crystal structure of CsCl is
a) simple cube b) face - centred cube
c) body - centred cube d) edge centred cube
22. Change in Gibbs free energy is given by
co m
a) Δ G = Δ H + T Δ S
o l AI b) Δ G = Δ H -T Δ S
ai .
L
c) Δ G = Δ H. T Δ S d) none of these
v is
A
23. For the reaction constant 2Cl(g) Cl2(g) the signs of Δ H and Δ S are respectively.
k al
M
a) +, - b) +, + c) -, - d) -, +
w.
A
24. If the equilibrium constants of the reactions 2A B is K1and B 2A is K2, then
ww N
a) K1=2K2 b) K1= 1/K2 c) K1 = ( K2) 2
d) K1= (1/K1) 2
N
25. When Δ ng in a homogeneous gaseous equilibrium is positive, then
.A
a) Kp = Kc b) Kp < Kc c) Kp > Kc d) Kp = Kc / 2
R
26. The characteristic odour of lower phenols is _________
a) carbolic acid b) fruity c) oil of bitter almonds d) rotten fish
a) Very active b) inert c) oxidizing d) replaceable
28. Diethyl ether behaves as a
a) Lewis acid b) lewis base c) neutral compound d) bronsted acid
29. The formation of a cyanohydrins with a ketone is example of
a) electrophilic substitution b) nucleophilic addition
c) nuclerophilic substitution d) electrophilic addition
30. The isomerism exhibited by CH3CH2COOH and CH3COOCH3 is
a) metamerism b) functional isomerism
c) chain isomerism d) position isomerism

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Chemistry
MARCH-2007
1. Aniline differs from ethylamine in its reaction with
a) CH3 I b) CHCl3 and caustic KOH
b) HNO2 d) CH3 COCl
2. The compound most reactive towards electrophilic nitration is
a) Methyl benzene b) Benzene c) Benzoic acid d) Nitrobenzene.
3. Nitro-acinitro tautomerism is exhibited by
a) nitromethane b) nitrobenzene c) chloropicrin d) o-toluidine
4. The reducing sugar among the following is
a) sucrose b) cellulose c) glucose d) starch
5. Which is not true of amino acid?
a) It forms Zwitterion b) Has isoelectric point
c) Dual behaviour d) Insoluble in NaOH solution
co m
a) 1-butanol
o l AI
6. The compound that reacts the fastest with Lucas reagent is
b) 2-butanol ai .
c) 1-propanol
al v is
A L
d) 2-methyl -2-propanol.
a) acidic
w. k
b) basic
M c) neutral d) amphoteric
ww N A
8. Zeisel’s method of detection and estimation of alkoxy group in alkaloids involves the reaction of ether
with
a) HI b) Cl2
.A N c) PCl5
9. Schiff’s reagent gives pink colour with
d) AlCl3
a) acetone
R
b) acetaldehyde c) ethanol
10. The acid that cannot be prepared from Grignard reagent is
a) Formic acid b) Acetic acid c) propionic acid
d) ether.
d) Benzoic acid
11. 50% of a fist order reaction is completed in 20 minutes. The time required for 75% completion is
a) 60 minutes b) 10 minutes c) 40 minutes d) 80 minutes
a) precipitation b) coagulation c) dialysis d) filtration
a) temperature decreases b) temperature increases
c) pressure increases d) concentration increases
a) liquid in gas b) gas in Liquid c) gas in solid d) solid in gas.
15. The indicator used in the titration of ammonium hydroxide with hydrochloric aicd is
a) KMnO b) Methyl oranre c) phenolphthalein d) Litmus.

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16. An ion leaves its regular site and occupies a position in the space between the lattice sites. This defect
is called as
a) Schottky defect b) Frenkal defect c) Impurity defect d) Vacancy defect
a) an increase in entropy b) a decrease in entropy
c) an increase in heat of vaporisation d) an increase in free energy
18. The amount of heat exchanged with the surroundings at constant pressure is called
a) Δ E b) Δ H c) Δ S d) Δ G
19. In the reversible reaction 2HI H2 + I2, Kp is
a) greater than kc b) less then kc c) equal to kc d) zero
20. Which of the following gaseous equlibria is favoured by increase temperature ?
a) N2O 4 2NO2; Δ H =+59 kJ mol-1
b) N2+ 3H2 2NH3; Δ H =-22 k cal mol-1
c) 2SO2+ O2 2SO3; Δ H =-47 k cal mol-1
d) Both (b) and (c)
co m
21. Bordeaux mixture contanins
a) AgNO3+HNO3
o l
b) ZnSO4+H2SO4
AI ai .
c) CuSO4+Ca(OH)2 d) KMnO4+HCl
a) MnO2
al
b) CeO2 is
22. The compound used in gas lamp meterial is
v A Lc) N2O5 d) Fe2O3
. k
w M
a) Gadolinium
ww N
24. An example of a chelating ligand isA
b) Lutetium c) promethium d) Cerium
a) chloro
25. Radioactivity is due to
.A
b) Bromo
N c) en d) NO2-
c) unstable nucleus R
a) Stable electronic confiuration b) stable nucleus
d) unstable elctronic configuration.
26. Which of the particles having same kinetic enargy, would have the maximum de Brogile de wavelength.
a) Proton b) neutron c) α particle d) β particle
27. Inter-molecular hydrogen bonding is present in
a) HF b) H2o c) ethanol d) all of these
28. The scale which is based on an empirical realition between the energy of a bond and the
electronegativities of bonded atoms is that of
a) Pauling b) Mulliken d) Sanderson d) Alfred Rochow.
29. An element is burnt in limited supply of air to given oxide A which on treatment with water gives an acld
B. Acid B on hearting gives and C which gives yellow prectipilite with silver nitatate Solution. Oxide A
is
a) P2O3 b) SO2 c) CO2 d) NO2
30. The ion with maximum number of unpaired electons is
a) Mg2+ b) Ti3+ c) V3+ d) Fe2+
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Chemistry
JUNE-2007
1. Nitromethane on condensation with acetaldehyde gives
a) 1-nitropropane b) 1-nitro-2-propanol
c) 2- nitro -1-propanol d) 3- nitropropanol
2. The basic character of amines is due to the
a) tetrahedral structure b) presence of nitrogen atom
c)electronegativity of nitrogen d) presence of lone pair of electrons.
3. Which of the following compounds has the smell of bitter almonds?
a) Aniline b) Nitromethane
c) Benzene sulphonic acid d) Nitrobenzene
4. Sucrose contains glucose and fructose linked by
a) C1-C1 carbon b) C1-C2 carbon c) C1-C4 carbon d) C1-C6 carbon
5.The building blocks of proteins are
co m
a) α -hydroxy acid b) α -amino acid
o l AI
6. The compound which reacts fastest with Lucas reagent is ai .
c) β -hydroxy acid d) β-amino acid
a) butan -1-ol
c) 2-methyl-1- propanol
al v is
A L
b) butan-2-ol
d) 2-methyl-2- propanol.
. k M
w
a) acidic
ww
b) basic
N A c) neutral d) amphotreic.
N
8. The ether used in perfumery is
.A
a) dithyl ether b) dimethyl ether c) methyl phenyl ether d) diphenyl ether
9. Tertiary butyl alcohol can be prepared by treating methyl magnesium iodide with
R
a) formaldehyde ( HCHO )
c) acctone ( CH3COCH3 )
b) acetaldehyde ( CH3CHO )
d) carbon dixdde ( CO2 )
10. The strongest acid among the following is
a) Cl CH2 COOH b) Cl3 C COOH c) CH3COOH d) Cl2 CH COOH
11. Hydrolysis of an ester by dilute HCI is an example for
a) zero order rection b) first order rection
c) pseudo - first order rection d) second order rection
12.Colloidal modicines are more effective because
a) they are clean b) they are aesy to prepare
c) the germs move towards them d) they are easily assimilated and absorbed
13. Which type of colloid is a sol?
a) Solid in liquid b) liquid in solid c) Solid in Solid d) Gas in Solid
14. The platinum catalyst used in the oxidation of SO2 by contact process is poisoned by
a) As2O3 b) V2O5 c) Fe2O3 d) CuCl2.
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15. If 0.2 ampere can deposit 0.1978 g of copper in 50 minutes, how much of copper will be deposited
by 600 coulombs?
a) 19.78 g b) 1.978 g c) 0.1978 g d) 197.8 g.
16. In a simple cubic cell, each point in a corner is shared by
a) one unit cell b) two unit cells c) four unit cells d) eight unit cells.
a) an increase in entropy b) a decrease in entropy
c) an increase in free energy d) an increase in heat of vaporisation.
18. The entropy change involved in the process of H2O (s) H2O (l) at 00c and 1atm pressure
involving Δ H fusion = 6008 J mol-1 is
a) 22.007J mol-1 K-1 b) 22.007J mol K-1
c) 220.07 J mol-1 K-1 d) 2.2007 J mol K-1
19. In an endothermic equilibrium reaction. if K1 and K2 are the equilibrium constants at T1 and T2
temperatures repectivly and if T2 is greater than T1 than
m
a) K1 < K2 b) K1 > K2 c) K1 = K2 d) none of these.
co
I
20. The maximum yield of ammonia by Haber’s process is
ai .
A
a) 78 % b) 97% c) 37% d) 89%
o l
s L
21. K2Cr2O7 reacts with KI and dilute sulphuric acid and liberates
v i
l A
a) O2 b) I2 c) H2 d) SO2
k a
M
22. The oxide used in gas lamp material is
w.
A
a) MnO2 b) N2O5 c) CeO2 d) Fe2O3
ww N
23. Radioactive element of lanthanide is
a) Cerium
.A N
b) Promethium
24. In [Fe(CN)6]-4 the central metal ion is
c) Gadolinium d) Lutetium.
R
a) Fe b) Fe +2
c) Fe+3 d) (CN)-
25. When 7N15 is bombarded with a proton it gives 6C12 and
a) α -paeticle b) β-particle c) neutron d) proton.
26. The hybridisation involved in XeF6 is
a) sp3 d3 b) sp3 d2 c) sp3 d d) sp3
27.Intramolecular hydrogen bonding is present in
a) m- nitrophenol b) o- nitrophenol c) p- nitrophenol d) none of these.
28. When XA>>XB, A-B boud is
a) polar covalent b) non- poar covallent c) ionic d)metallic.
29. Which of the following does not belong to group 14?
a) C b) Si c) Ga d) pb.
a) Zn b) Sc c) Ti d) La.

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Chemistry
SEPTEMER-2007
1. The colour of purple of cassius is
a) purple b) blue c) bluish green d) apple green
2. ___________ form oxocations.
a) Lanthanides b) Actinides c) Noble gases d) Alkali metals.
a) Misch metals b) metallotds c) plate metals d) Actinides.
4. In [FeII(CN)6]4- the central metal ion is
a) Fe b) Fe+2 c) Fe+3 d) (CN)-
5. Which one of the following particles is used to bombard 13 Al 27 to give 15 P 30 and a neutron?
a) α - particle b) Deuteron c) proton d) Neutron.
6. The sum of the powers of the concentration terms that occur in the rate equatic is called
a) molecularity b) order c) rate
co m
d) rate constant.
o l AI
ai .
s L
a) emulsion b) colloidal Solution c) true solution d) none of these.
v i
l A
8. Coconut charcoal has a great capacity of the ___________ of gases.
k a
M
a) adsorption b) absorption c) desorption d) all of these.
w.
A
9. Emulsifying agent is used for
ww N
a) precipitation of an emulsion b) coagulation of an emulsion
N
c) stabilization of an emulsion d) none of these.
.A
10.When one coulmb of electricity is passed through an electrolyte solution the mass deposited on the
a) equivalent weight
11. CCl3 NO2 is used as
R b) molecular weight c) electrochemical equivalent d) one gram
a) soil sterilizing b) organic synthesis c) good solvent d) antioxidant

a) (C2 H5)2 NH b) C2 H5NH2 c) (C2 H5)3 N d) (C2 H5)4 N+ I-
13. The reaction between benzene diazonium chloride and benzene in the presence of NaOH is
a) perkin’s reaction b) Gattermann’s reaction
c) Sandmeyer reaction d) Gomberg- Bachmann reaction.
14. Glucose forms __________ with acetic anhydride and sodium acetate.
a) di-acetate b) tetra- acetate c) penta- acetate d) hexa - acetate
15. The precipitation of protein is called
a) peptisation b) denaturation c) renaturation d) none of these.
a) Bohr b) Heisenberg c) de Broglie d) Pauli.
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17. Energy levels of molecular orbitals have been determined experimentally by

a) Spectroscopic studies b) x-ray diffraction
c) Crystallographic studies d) none of these.
18. When XA>>XB, A-B boud is
a) polar covalent b) non- poar covallent
c) ionic d) metallic.
19. The noble gases are unreactive because they
a) have same number of electrons b) have an atomicity of one
c) are gases with low density d) have stable electronic configuration
20. Ferrochrome is an alloy of
a) Cr, C, Fe, Ni b) Cr, Co, Ni, C c) Fe, Cr d) Cr, Ni, Fe
21. The total number of atoms per unit cell in bcc is
a) 1 b) 2 c) 3 d) 4
22. If Δ G for a reaction is negative, the change is
a) spontaneous b) non- spontaneous
o m
c) reversible
c
d) irreversible
23. For the reaction 2Cl(g)
I i .
Cl2(g) the signs of Δ H and Δ S respectively are
A ol a
L
a) +, - b) +, + c) - , - d) -, +
v is
A
24. In a reaction 2O3 3O2 the value of Kc is
[O3]3
k al
[O2]2 [O2]3 [O3]
a)
[O2]2
b)
w.[O3] 3
AM [O3]
c)
2
[O2]
d)
ww N
25. In the synthesis of NH3 between N2 and H2 reaction the unit of Kp is
N
a) lit2 mol-2 b) atm-2 c) lit atm-1 d) atm-1
A
26. A compound that reacts fastest with Lucas reagent is
a) butan -1-ol
R .
c) 2-methyl propan -1-ol
b) butan-2-ol
d) 2-methyl propan-2-ol
a) neutral b) acidic c) basic d) amphoteric.
28.Which among the follwing is a an unsymmetrical ether?
a) C6H5-O-C6H5 b) C2H5-O-C2H5 c) CH3-O-CH3 d) C6H5-O-CH3
29. schiff’s reagent gives pink colour with
a) acetone b) acetaldehyde c) ethyl alcohol d) methyl acetate.
30. Which order of arrangement is correct in terms of the strength of the acid?
a) CH3 CH2 COOH > CH3 COOH < HCOOH < ClCH2 COOH
b) ClCH2 COOH < HCOOH < CH3 COOH < CH3 CH2 COOH
c) CH3 CH2 COOH < CH3 COOH < HCOOH < ClCH2 COOH
d) HCOOH > CH3 CH2 COOH < CH3 COOH > ClCH2 COOH

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Chemistry
MARCH - 2008
1. Silver obtained from silver coin is purified by fusion with
a) AgNO3 b) HNO3 c) H2SO4 d) borax
2. Alloys of lanthanides are called as
a) plate metals b) actinides c) misch- metals d) metalloids
3. The common oxidation state of actinide is
a) +2 b) +3 c) +4 d) +6
4. [FeF6]4- is paramagnetic because
a) F-is a weaker ligand b) F- is a stronger ligand
c) F- is a chelating ligand d) F-is a flexidentate ligand.
5. In nuclear reaction __________ is / are balanced on both sides.
a) mass b) number of atoms
c) mass number d) atomic number and mass number.
co m
reaction is
o l AI ai .
6. Half-life period of a first order reaction is 20 min. The time taken for the completion of 99.9% of the
a) 20 min
v is
b) 2000 min
al A L c) 250 sec
7. The Tyndall effect is associated with colloidal particle due to
d) 200 min
a) scattering of light
w. k M b) presence of charge
ww
c) diffusion of light
N A d) reflection of light
N
.A
a) precipitation b) coagulation c) dialysis d) filtration.
9. Which one of the following factors is false regarding catalyst?
R
a) samll quantity is enough
c) Remains unchanged in mass and chemical composition
b) Initiate the reaction
d) Specific in its action.
10. When pH of a solution is 2. the hydrogen ion concentration in moles litre-1 will be
a) 1x10-12 b) 1x10-4 c) 1x10-7 d) 1x10-2
11. The -NO2 group in nitro-alkane is converted into-NH2 group by the reagent
a) Zn / NH4Cl b) Zn dust c) Sn / HCl d) Zn / NaOH.
a) (C2 H5)2 NH b) C2 H5NH2 c) (C2 H5)3 N d) (C2 H5)4 N+ I-
13. Use of chloropicrin is as
a) Explosive b) Dye c) Anaesthetic d) Sterilizing agent.
a) Glycine b) Alanine c) Proline d) Tyrosine.
15. Sorbitol and Mannitol are
a) isomers b) polymers c) epimers d) dimers
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16.Hybridisation in SF6 molecule is

a) sp3 b) sp3d2 c) sp3 d d) sp3d3
17. In a molecule eight electrons are present in bonding molecluar orbital and four electrons are present in
anti- bonding molecular orbital. Its bond order is
a) 3 b) 4 c) 2.5 d) 2
18. The metal of having maximun electron affinity is
a) sodium b) calcium c) gold d) silver
19. Which of the following has the property of etching on glass?
a) HI b) HF c) HBr d) HCl
20. paramagnetism is the property of
a) paired electrons b) completely filled electronic subshells
c) unpaired electrons d) completely vacant electronic subshells
21. An example for metaldeficiency defect is
a) NaCl b) AgCl c) FeS d) CsCl
co m
a) spontaneous
c) reversible
l AI
b) non- spontaneous
d) irreversible
o ai .
a) are path functions
al is
A L
23. Entropy (s) and the entropy change (Δ s) of a process
v b) are state functions
c) are constants
w. k M d) have no values
a) H2 (g) + I2 (g)
ww N A
24. Which one of the following has-negavtive value for Δ ng?
2 HI (g)
b) PCl5 (g)
c) 3 H2 (g) + N2 (g)
.A N
PCl3 (g) + Cl2 (g)
2 NH3 (g)
a) dynamic
R
d) 2 H2 O (g) + 2Cl2 (g)
25. State of a chemical equilibrium is
b) Stationary
4 HCl (g) + O2 (g)
c) both (a) & (b) d) none of these

26. A compound that undergoes bromination easily is
a) benzoic acid b) benzene c) phenol d) toluene
27. Ether is formed when alkyl halide is treated with sodium alkoxide. The method is known as
a) Hoffimann’s reaction b) Williamson’s synthesis
c) Wurtz reaction d) Kolbe’s reaction
28. When ether is exposed to air for some time, an explosive substance produced is
a) peroxide b) TNT c) superoxide d) gun cotton
29. Hydrogenation of benzoyl chloride in the presence of pd and BaSO4 gives
a)phenol b) benzoic acid c) benzyl alcohol d) benzaldehyde
30. Concentrated solution of sodium acetate on electrolysis gives
a) ethane b) propane c) methane d) butane
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Chemistry
JUNE - 2008
1. Which of the following is wrong statement regarding K2 Cr2 O7?
a) Oxidising agent b) Used in tanning dustry
c) Soluble in water d) Reduces ferric sulphate to ferrous sulphate
2. The common oxidation state of lanthanides is
a) +2 b) +1 c) +3 d) +4
a) misch metals b) metalloids c) Plate metals d) actindes
4. The co-ordination number of Cr(III) in [ Cr (H 2O) 4 Cl2 ] Cl. 2 H2O is
a) 3 b) 4 c) 6 d) 2
5. The reaction 5B8 4
Be8 akes place due to
a) α -decay b) β - decay c) electron capture d) positron decay
o m
6. In a first order reaction the concentration of the reactant is increased by 2 times. The rate of the reaction
c
is increased by
a) 2 times b) 4 times
o l AI c) 10 times
ai . d) 6 times
a) they are clean

al is
A L
v b) they are easy to prepare
. k M
c) they are easily assimilated and adsorbed
w
d) the germs move towards them
a) Shape selectivty
ww N A
8. Which one is correct factor that explains the increase of reaction by a catalyst?
b) particle size
c) Increase of free energy
.A N d) Lower of activation energy

9. The function of FeCl3 in the conversion of Fe (OH)3 precipitate into a colloid is
a) peptising agent
c) reducing agent R b) emulsifying agent
d) precipitating agent
10. Equivalent conductance of acetic acid at 250c is 80 ohm-1cm2(gram equivalent)-1 and at infinite
dilution is 400 ohm-1 cm2 (gram equivalent)-1 The degree of dissociation is
a) 1 b) 0.2 c) 0.1 d) 0.3
NaNO2 / HCl
11. C6H5NH2 X. X is
273 K
a) C6 H5 Cl b) C6 H5 NHOH c) C6 H5 N2 Cl d) C6 H5 OH
12.Oil of mirbane is
a) nitrobenzene b) benzaldehyde c) methyl salicylate d) aspirin
a) electrophile b) Lewis acid c) free radical d) Lewis base
14. Ultimate product of hydrolysis of proteins is
a) anline b) aliphatic acid c) amino acid d) aromatic acid.
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a) oxidation of sucrose b) reduction of sucrose
c) sucrose to glucose and fructose d) polymerisation of sucrose
313.6
16. En = , En= -34.84, n value is
n2
a) 4 b) 3 c)2 d) 1
17.water exists in liquid state. This is due to
a)high boiling point b)low boiling point
c)freezing point is zero d) hydrogen bond.
18. Effective nuclear charge is given by the equation
a) z * = z - s b) z * = z + s c) z * = s - z d) z = z * - s
19.the compound used to arrest the bleeding is
a) K2SO4 b) potash alum c) Al2(SO4)3 d) KI
20. The number of unpaired electrons in, Ti3+ is 1. Its magnetic moment in BM is
a)1.414 b) 2 c) 1.732 d) 3
co m
21. In Bragg’s equation n represents
o l AI ai .
L
a) number of moles b) Avogadro number
v is
A
c) quantum number d) order of reflection
k al
a) Δ G = Δ H+T Δ S
w.
A M b) Δ G= Δ H -T Δ S
ww N
c) Δ G = Δ H x T Δ S a) Δ G= T Δ S + Δ H
N
23. H2O(l) H2O(g). In this process the entropy
.A
a) remains constant b) decreases c) increases d) becomes zero
R
a) dynamic b) stationary c) none of these d) both (a) and (b)
25. H2(g)+I2(g) 2HI(g). The equilibrium constant Kc for this reaction is 16. Kp value is
1
a) b) 4 c) 64 d) 16
16
26. The reaction of ethylene glycol with PI3 gives
a) ICH2 CH2I b) CH2 = CH2 c) CH2 = CHI d) ICH = CHI
27. The number of ether isomers possible for C4 H10O is
a) 7 b) 5 c) 4 d) 3
a) more reactive b) replaceable c) oxidising d) comparatively inert
29. The compound that does not reduce Fehling solution is
a) formaldehyde b) acetaldehyde c) benzaldehyde d) propionaldehyde
30. Ethylene dicyanide on hydrolysis gives
a) oxalic acid b) succinic acid c) adipic acid d) propionic acid
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Chemistry
SEPTEMBER - 2008
1. The number of secondary alcoholic group in glycerol is
a) 1 b) 2 c) 3 d) 0
2. When ethyl iodide is treated with dry silver oxide. It forms
a) ethyl alcohol b) diethyl ether c) silver ethoxide d) ethyl methyl ether
3. propanone is usually characterised by
a) Fehling’s solution b) Iodoform test
c) Schiff’s test d) Tollen’s reagent
4. The compound used in the preparation of triphenyl methane dye is
a) methanol b) phenyl methanal c phenyl methanol d) ethanal
5. The acid that cannot be prepared by Grignard reagent is
a) acetic acid b) benzoic acid c) formic acid d) butyric acid
6. An example of metal deficiency defect is
co m
a) NaCl b) AgCl
o l AI
c) CsCl
7. If Δ G for a reaction is negative, the change is i
d) FeS
a .
a) spontaneous
v is
A L
b) non-spontaneous
al
c) reversible d) irreversible
8. The entropy change for the process, water (liq) to water (vap) involving Δ H(vap) =40850 J mol-1 at 373K
is
w. k M
ww
a) 22.007J mol -1 K -1
c) 109.52J mol -1 K -1
N A b) 7.307J mol -1 K -1
d) 0.2287J K -1
9. In the reversible reaction 2HI
a) greater than Kc
.A N H2 + I2, Kp is
b) less than Kc c) equal to Kc d) zero
c) 5000C to 5500C
R
10. The optimum range of temperature used in contact process for the manufacture of SO3 is
a) 4000C to 4500C b) 18000C to 27000C
d) 3500C to 4500C
a) Bohr b) Heisenberg c) de Broglie d) Pauli
12. Inter- molecular hydrogen bonding is present in
a)o-nitrophenol b)salicylic acid
c) o- hydroxy benzaldehyde d) hydrogen fluoride
13. Which among the following has higher electron affnity value?
a) Fluorine b) chlorine c)bromine d)iodine
14.The compound used in smoke screen is
a) PCl3 b) PCl5 c) PH3 d) H3 PO3
15.The Catalyst used in the manufacture of polythene is
a) V2O5 b) Fe c) Mo d) TiCl4.

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a) electrophile b) lewis base c) Lewis acid d) free radical
NaNO 2
17. C6 H5 NH2 X. Identify X.
HCl 0oC
a) C6 H5 Cl b) C6 H5 NHOH c) C6 H5 N2Cl d) C6 H5 OH
18. Which of the following will not undergo Hofmann’s bromamide reaction?
a) Ethanamide b) Propanamide
c) Methanamide d) Phenyl methanamide
19. Glucose is not oxidised to gluconic acid by
a) Br2 / H2O b) Fehling’s solution
c) Tollen’s reagent d) Conc. HNO3
20. The optically inactive amino acid is
a) glycine b) alanine c) proline d) phenyl alanine
m
21. Decomposition of nitrogen pentoxide CCl4 is an example for
co
I
a) second order reaction b) third order reaction
ai .
A
c) zero order reaction d) first order reaction
o l
s L
22. Fog is the colloidal solution of
v i
l A
a) gas in liquid b) liquid in gas c) gas in solid d) solid in gas
k a
. M
23. An example of lyophilic colloid is
a) Sulphur in water
w A
b) phosphorus in water
ww N
c) starch d) all of these
a) precipitation
.A N
b) coagulation c) dialysis d) filtration
R
25. When 10-6 mole of a monobasic strong acid is dissolved in one litre of solvent,the pH of the solution is
a) 6 b) 7 c) 4 d) less than 6
26.The correct electronic configuration of chromium is
a) [Ar] 3d6 4s0 b) [Ar] 3d5 4s1 c) [Ar] 3d4 4s2 d) [Ar] 3d3 4s2 4p1
27. The maximum oxidation state exhibited by lanthanides is
a) + 3 b) + 4 c) + 6 d) + 7
28. ThO2 is used in
a) toys b) tracer bullets c) gas lamp materials d) dyeing cotton
29. An example of bidentate chelating ligand is
a) NO-2 b) NO-3 c) en d) SO42-
30. Half -life period of a radioactive element is 1500 years. The value of disintegration constant in terms
of seconds is
a) 0.1465 x 10-10sec-1 b) 0.2465 x 10-10sec-1
c) 0.1465 x 10-8sec-1 d) 0.3645 x 10-10sec-1

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Chemistry
MARCH - 2009
1. When an aqueous solution of benzene diazonium chloride is boiled, the product formed is
a) benzyl alcohol b) benzene + N2 c) phenol d) phenyl hydroxylamine
2. Oxidation of aniline with acidfied K2Cr2O7 gives
a) p-benzoquinone b) benzoic acid c) benzaldehyde d) benzyl alcohol
3. When among the following is a tertiary amine?
a) (CH3)3 - C - NH2 b) CH3 - CH - NH - CH3
CH3
CH3
c) (CH3)2 - N - C2 H5 d) CH3 - CH2 - C - C2 H5
NH2
co m
I .
a) sucrose b) cellulose c) glucose d) starch
ai
l A
a) Alanine b) Glycine
is o L
c) proline d) Thyrosine
a) kieselghur
al v
6. The active component of dynamite is
b) nitroglycerine
A c) nitrbenzene d) trinitrotoluene
w. k
7. Anisole on bromination yields
M
a) m- bromoanisole
ww N A
b) o-bromoanisole
c) o-&p-bromoanisole d) benzoic acid
a) HI b) KMnO4
.A N c) NaOH
9. The compound that does not undergo cannizzaro reaction is
d) H2O
R
a) formaldehyde b) benzaldehyde c) acetaldehyde d) trimethyl acetal dehyde
10. Which one of the following is least acidic?
a) C2 H5 OH b) CH3 COOH c) C6 H5 OH d) ClCH2 COOH
11. The excess energy which a molecule possesses to become active is known as
a) Kinetic energy b) potential energy c) activation energy d) threshold energy
12. In the reaction between oxalic acid and potassium permanganate, in the presence of dil. H2SO4
__________acts as an autocatalyst.
a) K2SO4 b) MnSO4 c) MnO2 d) Mn2O3
13. In the case of physical adsorption, there is desorption when
a) temperature increases b) temperature decreases
14. The blue colour of the sky is due to
a) Tyndall effect b) Brownian movement c) electrophoresis d) electro-osmosis
15. Faraday’s laws of electrolysis are related to
a) atomic number of the cation b) atomic number of the anion
c) equivalent weight of the electrolyte d) speed of the cation
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16. The number of close neighbours in a body centred cubic lattice of identical sphere is
a) 6 b) 4 c) 12 d) 8
17. All the naturally occurring processes proceed spontaneously in a direction which leads to
a) decrease of entropy b) increase in enthalpy
18. The percentage efficiency of a heat engine that operates between 127oC and 27oC is
a) 20% b) 50% c) 100% d) 25%
19. For the homogeneous gas reaction at 600 K
4 NH3 (g) + 5 O2 (g) 4 NO (g) + 6 H2O (g)
the equilibrium constant Kc has the unit
a) (mol dm-3)-1 b) (mol dm-3) c) (mol dm -3)10 d) (mol dm -3)-9
20. If the equilibrium constant of the reaction 2A B is K1 and the equilibrium constant of the
reaction B 2A is K2, then
1 1
a) K1= b) K1= 2 K2 c) K1= d) K2= (K1)2
K2 K22
co m
a) Ni2+ b) Cu+
o l I
21. Which of the following ions will give colourless aqueous solution?
A c) Cu2+
ai . d) Fe2+
a) +1 b) +2
al is L
22. Maximum oxidation state exhibited by lanthanides is
v A c) +3 d) +4
. k M
23. Which of the following is a radioactive lanthanide ?
w
a) Pu
ww
b) Ac
N A c) Th
24. Which one of the following is a cationic complex?
d) Pr
a) K4 [ Fe (CN) 6 ]
c) K3 [ Cr (C2 O4 ) 3]
.A N b) [ Cu (NH3 ) 4 ]Cl2
d) K3[ Fe (CN) 6]
R
a) α -particle b) proton
c) Neutron d) Deutreon
a) o-nitrophenol b) m-nitrophenol c) p-nitrophenol d) p-aminophenol

27. The hybridisation in SO42- ion is
a) sp3 b) sp3 d2 c) sp3 d d) sp3 d3
28. The electron affinity of an atom is
a) directly proportional to its size b) inversely proportional to its size
c) independent of its size d) none of these
29. An element which was burnt in limited supply of air to give oxide A, which on treatment with water
gives an acid B. Acid B on heating gives acid C which gives yellow precipitate with AgNO3 solution.
Compound A is
a) SO3 b) NO2 c) P2O3 d) SO3
30. A metal which precipitates gold from its aurocyanide complex is
a) Cr b) Ag c) Pt d) Zn
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Chemistry
JUNE - 2009
1. Compound which undergoes iodoform test is
a) 1 - pentanol b) 2 - pentanone c) 3 - pentanone d) pentanal
2. The preparation of diethyl ether by williamson’s synthesis is a/an
a) nucleophilic addition reaction b) electrophilic substitution reaction
c) electrophilic substitution reaction d) nucleophilic substitution reaction
3. In the formation of oxonium salt when ethereal oxygen reacts with strong mineral acid is called
a) electronation b) protonation c) deprotonation d) dehydration
4. Which of the following compounds is oxidized to give ethyl methl ketone?
a) 2 - propanol b) 2 - pentanone c) 1 - butanol d) 2 - butanol
5. Ethylene dicyanide on hydrolysis using acid gives
a) oxalic acid b) succinic acid c) adipic acid d) propionic acid
6. The size of the anion in Frenkel defect crystal is
co m
a) larger than the cation
c) equal in size with cation
o l AI ai .
b) smaller than the cation
d) both are larger in size
a) an increase in entropy
al v is
A L b) a decrease in entropy
w. k M
c) an increase in heat of vaporization d) an increase in free energy
ww N A
N
a) Δ G = Δ H + T Δ S b) Δ G = Δ H -T Δ S
.A
c) Δ G = Δ H x T Δ S d) Δ G = Δ H / T Δ S
R
9. In the reversible reaction 2HI(g) H2(g) + I2(g) Kp is
a) greater than Kc b) less than Kc c) equal to Kc d) 0
10. In the Haber process the yield of ammonia is greater
a) at high pressure b) at low pressure
c) at high temperature d) in absence of catalyst
12. Number of spherical nodes in 2s orbital is
a) 1 b) 2 c) 3 d) 4
13. On moving down the group, the radius of an ion
a) decrease b) increase c) no change d) all of these
14. Which of the following shows negative oxidation state only?
a) Br b) F c) Cl d) I
15. The outer electronic configuration of chromium is
a) 3d64s0 b) 3d54s1 c) 3d44s2 d) 3d34s24p1
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16. Innirtoalkanes - NO2 group is converted to NH2 group by the reaction with
a) Sn/HCl b) Zn dust c) Zn/NH4Cl d) Zn/NaOH
17. The tertiary nitro compounds is
a) 2-nitro propane b) 1 - nitropropane
c) 1 - nitro-2, 2-dimathyl propane d) 2-nitro, 2 - methlpropane
18. The intermediate formed in the nitration of benzene is
a) Arrenium ion b) Carbon ion
c) Oxonium ion d) Nitrite ion
a) oxidation of sucrose b) reduction of sucrose
c) hydrolysis of sucrose to glucose and fructose d) polymerization of sucrose
20. A dipeptide does not have
a) two peptide units b) portions of two amino acids
c) an amido group d) salt like structure
o m
21. The sum of the powers of the concentration terms that occur in the rate equation is called
c
a) molecularity b) order
o l AI c) rate
ai . d) rate constant
L
22. The phenomenon of Tyndall effect is not observed in
v is
A
a) emulsion b) colloidal solution c) true solution d) suspension
al
23. Catalyst used in Deacon’s method of manufacture of chlorine is
k
a) NO
w.
b) CuCl2
A M c) Fe2O3 d) Ni
ww N
24. Argyrols is
N
a) colloidal silver b) colloidal animony
.A
c) colloidal gold d) milk magnesia
R
25. When sodium acetate is added to acetic acid the degree of ionisation of acid
a) decrease b) does not change c) increase d) becomes zero
26. The reagent which is added first in the separation of silver from silver coin
a) conc.sulphuric acid b) conc.hydrochloric acid
c) con.nitric acid d) aquaregia
27. ________ forms (s) oxocation
a) Lanthamide b) Actinides c) Noble gases d) Alkali metals
28. ________ is the oxidation state of U in UF6
a) +6 b) +4 c) +3 d) +0
29. The coordination number of Nickel in the complex ion [NiCl4]2 - is
a) +1 b) +4 c) +2 d) +6
30. Loss of a β - particle is equivalent to
a) increase of one proton b) decrese of one neutron only
c) both (a) and (b) d) increase of one neutron only

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Chemistry
SEPTEMBER -2009
1. When phenol is distilled with zinc dust, it gives
a) benzalddehyde b) benzoic acid c) toluene d) benzene
2. Which one of the following ethers is used in perfumery?
a) Dimethyl ether b) Diethyl ether c) Ethyl methyl ether d) Methyl phenyl ether
3. When ethyl iodide is treated with dry silver oxide it forms
a) Ethyl alcohol b) Diethyl ether c) silver methoxide d) Ethyl methyl ether
a) acetone b) acetaldehyde c) ethanol d) ether
a) acetic acid b) butyric acid c) formic acid d) benzoic acid
6. The total number of atoms per unit cell in bcc is
co m
I .
a) 1 b) 2 c) 3 d) 4
ai
l A
7. Which of the following processes is always non-feasible?
a) Δ H > 0, Δ S > 0
is o L
b) Δ H < 0, Δ S > 0
c) Δ H > 0, Δ S < 0
al v Ad) Δ H < 0, Δ S < 0
. k M
8. The net work obtained from a system is given by
w
a) W + P Δ V
ww
9. In the equilibrium N2 + 3 H2
N A
b) W - P Δ V c) - W + P Δ V a) - W - P Δ V
2 NH3 The maximum yield of ammonia will be obtained with the
N
process having
.A
R
c) high pressure and high temperature d) high pressure and low temperature
10. The rate constant of the forward reverse reactions are 8 x 10-5 and 2 x 10-4 respectively. The value of
Kc is
a) 0.04 b) 0.02 c) 0.2 d) 0.4
11. de Broglie equation is
mv hv h
a) λ= h b) λ = hmv c) λ= d) λ= mv
m
12. The hybridisation in CO32- ion is
a) sp2 b) sp3 c) sp d) sp3 d
13. Amongthe following which has higher electron affinity value?
a) Fluorine b) chlorine c) Bromine d) Iodine
14. An element which belongs to Group 14 is soft in nature, does not react with pure water, but dissolves,
but dissolves in water containing dissolved air. Then the element is
a) C b) Ge c) Pb d) Ti
15. The correct outer electronic configuration of copper atom is
a) 3d10 4s2 b) 3d10 4s1 c) 3d9 4s2 d) 3d5 4s2
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16. Which one of the following will not undergo diazotisation?

a) m-toluidine b) Aniline c) p-aminophenol d) Benzylamine
17. Which one of the following compounds has the smel of bitter almonds?
a) Aniline b) Nitromethane c) Benzene sulphonic acid d) Nitrobenzene
18. The basic strength of amine is in the order of
a) NH3 > CH3 NH2 > ( CH 3 ) 2 NH b) ( CH 3 ) 2 NH > CH3 NH2 > NH3
c) CH3 NH2 > ( CH 3 ) 2 NH > NH3 d) NH3 > ( CH 3 ) 2 NH > CH3 NH2
a) two peptide units b) portions of two amino acids
c) an amido group d) salt like structure
20. The important constituent of cell wall is
a) liqid b) cellulose c) protein d) vitamin
21. Reactions in which the reacting molecules react in more than one way yielding different set products
are called
a) consecutive reactions b) parallel reactions
co m
c) opposing reactions
o l AI
d) chain reactions
ai .
a) precipitation
al v is
b) coagulation
A L c) dialysis
23. Decomposition of hydrogen peroxide is retarded in the presence of
d) filtration
a) alcohol
. k
b) glycerine
w M c) manganess dioxide d) Molybdenum
a) long chain alcohol

ww A
24. The emulsifying agent used in O/W emulsion is
N b) lamp black c) protein d) glycerol
a) increase
.A N
25. When sodium acetate is added to acetic acid, the degree of ionisation of acetic acid
b) decreases c) does not change d) becomes zero
R
26. The substance used in making ruby red glass and high class pottery is
a) colloidal silver
27.Alloys of lanthanidesare called
b) purple of cassius c) ruby silver d) ruby copper
a) Metalloids b) plate metals c) Actinides d) Misch metals

28. According to Fajan’s rule decrease in size of Ln ion in Ln (OH)3.
3+
a) increases the covalent character

b) decreases the covaient character
c) increases the basic character
d) increases the ionic character
a) tetrahedral b) suqare planar c) triangular d) octahedral
a) α rays b) β rays c) γ - rays d) all are equally penetrating

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Chemistry
MARCH 2010
1. Spiting of silver can be prevented by covering the molten metal with a thin layer of
a) borax b) charcoal c) sand d) silver bromide
2. Lanthanide contraction is due to
a) perfect shielding of 3d electron b) imperfect shielding of 3d electron
c) perfect shielding of 4f electron d) imperfect shielding of 4f electron
3. Which is used as a power source in long mission space probes?
a) Uranium-235 b) Uranium -238 c) plutonium -238 d) Mish metal
4. [ FeF6 ] 4- is paramgnetic because
a) F- is a weaker ligand b) F- is a stronger ligand
c) F- is a fiexidentate ligand d) F- is a chelating ligand
5. Half- life period of a radioactive element is 100 seconds. Its average life period
a) 100 seconds b) 50 seconds c) 200 seconds
co m d) 144 seconds
a) zero order reaction

o l AI
6. Hydrolysis of an ester by dilute HCl is an example for
a
b) first order reactioni .
c) second order reaction
al v is
A L
d) pseudo first order reaction
7. The Tyndall effect associated with colloidal particle is due to
a) presence of charge
w. k M
b) scattering of light c) absorotion of light d) reflection of light
ww
N A
N
.A
9. The colloid used for stomach disorder is
a) colloidal silver b) colloidal antimony c) colloidal gold d) Milk of magnesia
R
10. Ostwald’s dilution law is applicable in the case of
a) CH3COOH
Cu2 Cl2 / HCl
b) NaCl c) NaOH d) H2SO4
11. C6H5N2Cl X. the compound X is

a) C6 H5 NH2 b) C6 H5 NHNH2 c) C6 H5 - C6 H5 d) C6 H5 Cl
12. The basic character of amines is due to
a) tertrahedral structure b) presence of nitrogen atom
c) lone pair of electrons on nitrogen atom d) high electronegativity of nitrogen
13. Aniline reacts with benzoyl chloride in the presence of sodium hydroxie and gives benzanilide. This
reaction is known as
a) Gattermann reaction b) Sandmeyer;s reaction
c) Schotten- Baumann reaction d) Gomber’g Bachmann reaction
15. When starch is heated to 200 C - 250 C. the propduct is
0 0
a) dextrin b) caramel c) barley sugar d) cellulose

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16. The hybridistion in SF6 molecule is

a) sp3 b) sp3 d c) sp3 d2 d) sp3 d3
17. Which one of the following experiments confirmed the wave nature of electrom?
a) G.P Thomson’s gold foil experiment b) Black boby rediation
c) photoelectric effect d) Millikan’s oil - drop experiment
18. When XA >> XB, A-B bond is
a) polar covalent b) non - polar covalent
c) ionic d) metallic
19. A mong the halogen acids, the weakest acid is
a) HI b) HBr c) HCl d) HF
20. Which transition element shows the highest oxidation state?
a) Os b) Ti c) Sc d) Zn
21. The co-ordination number of ZnS is
a) 3 b) 4 c) 6 d) 8
22. Which of the following does not result in an increase in entropy?
co m
a) Rusting of iron
o l AI ai .
b) conversion of ice to water
L
c) Crystallisation of sucrose from solution d) Vaporisation of camphor
v is
A
23. Thermodynamic condition for irreversible spontaneous process at constant T and P is
a) Δ G < 0
k al
b) Δ S < 0 c) Δ G > 0 d) Δ H > 0
w.
24. In the equilibrium N2 + 3 H2
A M 2 NH3 The maximum yield of ammonia will be obtained with
ww
the process having
N
a) low pressure and high temperature
N
b) low pressure and low temperature
.A
c) high temperature and high pressure d) high pressure and low temperature
25. The equilibrium constant for the reaction 2A B is 25 mol-1 dm3 at 900K. What is the
a) 25 R
equilibrium constant for the reaction B
b) 625 c) 0.04
26. The compound that reacts fastest with Lucas reagent is
2A in dm-3 mol at the same temperature?
d) 0.4
a) butan-1-ol b) butan-2-ol
c) 2- methyl propan-1-ol d) 2- methyl propan-2-ol
27. Which one of the following is a simple ether?
a) CH3 - O - C2 H5 b) C2 H5 - O - C H3
c) C2 H5 - O - C2 H5 d) C3 H7 - O - C2 H5.
28. The IUPAC name of phenatole is
a) ethyl phenyl ether b) methyl phenyl ether c) diethyl ether d) diphenyl ether
29. The compound uesd in the preparation of the tranquilizer sulphonal is
a) acetone b) acetophenone c) isopropyl alcohol d) glycol
30. The isomerism exhibited CH3 CH2 COOH and CH3 COOCH3 is
a) metamerism b) position c) chain d) functional

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Chemistry
JUNE - 2010
1. Ether is formed when alkyl halide is treated with sodium alkoxide. This method is known as ______
a) Hoffmann reaction b) Williamson’s synthesis
c) Wurtz reaction d) Kolbe’s reaction
2. Ethers should never be evaporated to dryness because _________
a) they form explosive peroxide b) they are insoluble in water
c) they are inert d) they are lighter than water
3. Schiff’s reagent gives pink colour with ___________
a) acetone b) acetaldehyde c) ethyl alcohol d) methyl acetate
4. The acid which reduces Tollen’s reagent is ___________
a) acetic acid b) benzoic acid c) formic acid d) oxalic acid
5. Chloropicrin is used as ___________
co m
I
a) explosive b) dye c) anaesthetic d) soil sterilizing
ai .
A
6. Total number of atoms per unit cell in bcc is __________
o l
s L
a) 1 b) 2 c) 3 d) 4
v i
l A
7. Standard free energies of formation of elements are taken as _________
k a
M
a) Positive b) negative c) zero d) all of these
w.
A
8. State of chemical equilibrium is __________
ww N
a) dynamic b) stationary c) none of these d) both (a) and (b)
a) Kc = Kp b) Kc < Kp N
9. In an equilibrium reaction if Δ n (g) is positive then __________
.A
c) Kc > Kp Kc = 0
R
10. The excess energy which a molecule must possess to become active is known as __________
a) Kinetic energy b) threshold energy
c) potential energy d) activation energy
12. The intra molecular hydrogen bonding is present in __________
a) o-nitrophenol b) m-nitrophenol
c) p-nitrophenol d) p-hydroxy benzaldehyde
13. The electron affinity of an atom is __________
a) directly prportional to its size b) Inversely proportional to its size
c) independent of its size d) none of these
14. The compound with garlic odour is __________
a) P2O3 b) P2O5 c) H3PO3 d) H3PO4
15. The outer most electronic configuration of chromium is _________
a) 3d64s0 b) 3d54s1 c) 3d44s2 d) 3d34s24p1
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16. Electrophile used in the nitration of benzene is ________

a) hydronium ion b) sulphonic acid c) nitronium ion d) bromide ion
17. Primary amine act as ___________
a) electrophile b) Lewis base c) Lewis acid d) Free radial
18. The amino acid without chiral carbon is ___________
a) Glycine b) Alanine c) Proline d) Tyrosine
19. Important constituent of cell wall is _________
a) lipid b) cellulose c) proteins d) vitamins
20. Which one of the following is a state function?
a) q b) Δ q c) w d) Δ s
21. An emulsion is a colloidal solution of _________
a) two solids b) two liquids
c) two gases d) one solid and one liquid
22. The autocatalyst in the oxidation of oxalic acid by acidified KMnO4 is _________
a) K2SO4 b) MnSO4 c) KMnO4
co m d) CO2
23. The sky looks blue due to __________
o l AI ai .
L
a) adsorption b) dispersion c) reflection d) scattering of light
v is
A
24. The pH of a solution containing 0.1 N NaOH solution is _________
a) 1 b) 10-1
k al c) 13 d) 10-13
w. M
25. The number of secondary alcoholic group(s) in glycerol is _________
A
ww N
a) 1 b) 2 c) 0 d) 3
N
26. Which of the following has the maximum number of unpaired electrons?
.A
a) Mn2+ b) Ti3+ c) V3+ d) Fe2+
R
27. Alloys of lanthanides are called ___________
a) Mish metals b) Metalloids c) Plate metals d) actinides
28. The isotope of which element is used in nuclear fission reaction?
a) Barium b) Lead c) uranium d) caesium
29. An example of a bidentate ligand is ___________
a) Cl- b) en c) NO2- d) I-
30. Radioactivity is due to __________
a) stable electronic configuration b) stable nucleus
c) unstable nucleus d) unstable electronic configuration

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Chemistry
September -2010
1. If the magnetic moment value is 5.92 BM, the number of unpaired electrons is
a) 5 b) 3 c) 4 d) 6
2. _________ is used in gas lamp material
a) MnO2 b) CeO2 c) N2O5 d) Fe2O3
3. _________ from oxocations
a) Lanthanides b) Actinides c) Noble gases d) Alkali metals
4. The geometry of complex ion [ Fe (CN) 6 ] is 4-
a) tetrahedral b) square planar c) octahedral d) triangular

a) α - particle b) Deuteron c) proton d) Neutron
6. For a reaction aA bB the rate of reaction is doubled when concentration of A is increased by
four times. The rate of reaction is equal to
co m
a) K [ A ]a b) K [ A ] 1/2
o l AI ai .
c) K [ A ] 1/a
d) K [ A ]
a) electro-osmosis
al
8. Which type of colloid is a sol? v is
A L
b) hot dialysis c) electrodialysis d) electrophoresis
a) Solid in liquid
w. k M
b) Liquid in solid c) Solid in Solid d) Gas in Solid
ww
a) temperature increases
N A
9. In case of a physical adsorption, there is desorption when
b) temperature decerases
c) pressure increases
.A N d) concentration increases
10. When pH of a solution is 2, the hydrogen ion concentration in moles/ litre is
a) 1 x 10 -12
R b) 1 x 10 -2
11. The isomerism exhibited by CH3- N

O
c) 1 x 10 -7
and CH2-N
O
d) 1 x 10 -4
is
O OH
a) position b) chain c) functional d) tautomerism
12. The product obtained when nitrobenzene is treated with Zn/ NaOH is
a) aniline b) azoxybenzene c) azobenzene d) hydrazobenzene
a) m- toluidine b) Aniline c) p-amino phenol d) Benzyl amine
a) two peptide units b) portion of two amino acids
c) an amino group d) Salt like structure
15. Glucose reacts with acetic anhydride in the presence of pyridine to give
a) monoacetate b) diacetate c) penta- acetate d) no reaction
16. The bond order of oxygen molccule is
a) 2.5 b) 1 c) 3 d) 2
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17. The hybridisation in IF7 molecule is

a) sp3 d b) sp3 d2 c) sp3 d) sp3 d3
18. The bond length of Cl2 molecule is
a) 0.74 A b) 1.44 A c) 1.98 A d) 2.28 A
19. The compound used as smoke screen is
a) PCl3 b) PCl5 c) PH3 d) H3PO3
20. Formation of coloured ions is possible when compounds contain
a) Paired electrons b) unpaired electrons
c) lone pair of electrons d) none of these
a) one unit cell b) two unit cell c) 8 unit cell d) 4 unit cell
22. All the naturally occurring processes proceed spontaneously in a direction which leads to
a) decrease of entropy b) increase of enthalpy
o m
23. The entropy change involved in the process water (liq) to water ( vapour, 373 K) involving Δ H vap =
c
40850 J mol-1 at 373K is
a) 10.952 J mol -1 K-1
o l AI b) 109.52 J mol -1 K-1
ai .
c) 100.952 J mol K -1 -1
al v is
A L a) 1095.2 J mol K-1
24. If the equilibrium constants of the following reactions 2A
-1
Bis K1 and B 2A is K2, then
w. k 1
M 1
A
a) K1 = 2K2 b) K1 = c) K2 = ( K1)2 d) K1 =
K2 K2 2
ww N
25. When Δ ng in a homogeneous gaseous equilibrium is positive, then
N
Kc
a) Kp = Kc b) Kp < Kc c) Kp > Kc d) Kp =
.A
2
R
a) primary < secondary > tertiary
b) primary > secondary > tertiary
c) primary < secondary < tertiary
d) primary > secondary < tertiary
27. According to lewis concept of acids and bases, ethers are
a) neutral b) acidic c) basic d) amphoteric
28. Higher ethers can be prepared from lower members by the action of
a) conc. H2SO4 b) AgOH c) sodium alkoxide d) Grignard reagent
distillation
29. Calcium acetate + Calcium benzoate ?
a) Benzophenone b) Benzaldehyde
c) Acetophenone d) phenyl benzoate.
a) acetic acid b) formic acid c) butyric acid d) benzoic acid

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Chemistry
MARCH 2011
1. Compound which is used as medicine for Asthma and whooping cough is
a) Benzyl acetate b) Ethyl acetate c) Benzyl benzoate d) Benzyl formate
2. Number of ether isomers possible for the molecular formula C4 H10 O is
a) one b) two c) three d) four
3. When ether is exposed to air for some time, an explosive substance produced is
a) peroxide b) Oxide c) TNT d) Superoxide
4. A cyanohydrin of a compound X on hydrolysis giyes lactic acid. X is
a) HCHO b) C3 CHO c) ( CH3 )2 CO d) C6H5 CH2 CHO
5. The compound found in some stony deposit in kidneys is
a) potassium oxalate b) oxalic acid c) potassium succinate d) calcium oxalate
m
6. The Bragg’s equation is
co
I
a) λ = 2d sin θ b) nd = 2λ sin θ c) 2λ = nd sin θ d) nλ = 2d sin θ
ai .
A
7. According to Trouton’s rule, the value of change in entropy of vaporisation is
o l
s L
a) 21 cal. deg-1 mole-1 b) 12 cal. deg-1 mole-1
v i
l A
c) 21 K. cal. deg. mole-1 d) 12 K cal. deg.mole-1
k a
. M
8. In Which of the following, the process is always non feasible
a) Δ H > 0, Δ S > 0
w A
b) Δ H < 0, Δ S > 0 c) Δ H > 0, Δ S < 0 d) Δ H < 0, Δ S < 0
ww N
9. In the manufacture of ammonia by Haber’s process the maximum yield of ammomia will be obtained
N
with the process having
.A
R
10. The relationship between Kp and Kc for the equilibrium
2 H2O (g) + 2 Cl2 (g) 4 HCl (g) +O2(g) is
a) Kp = Kc b) Kp = Kc (RT)2 c) Kp = Kc (RT)1 d) Kp = Kc (RT)-2
a) o-nitrophenol b) m-nitrophenol c) p-nitrophenol d) none of these
12. The momentum of a particle which has de- Broglie wavelength of 1Å (h = 6.626x10 -34 kgm2 s-1 ) is
a) 6.63 x 10-23 kg ms-1 b) 6.63 x 10-24 kg ms-1
c) 6.63 x 10-34 kg ms-1 d) 6.63 x 1034 kg ms-1
13. Effective nuclear charge can be calculated using the formula
a) Z * = Z - S b) Z * = Z + S c) Z * = S - Z d) Z = Z * - S
14. Inert gas used in beacon lights for safety of air navigation is
a) Helium b) Argon c) Neon d) Xenon
15. Which one of the following will have maximum magnetic moment?
a) 3d2 b) 3d6 c) 3d7 d) 3d9
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16. Nitromethane condenses with acetaldehyde to give

a) nitropropane b) 1-nitro-2- propanol
c) 2- nitro -1-propanol d) 3- nitropropanol
17. Which one of the following is a secondary amine?
a) Aniline b) Diphenyl amine
c) Secondary butyl amine d) tertiary butyl amine
18. When aqueous solution of benzene diazonium chloride is boiled, the product formed is
a) Benzyl alcohol b) Benzene +N2 c) Phenol d) phenyl hydroxyl amine
a) Glyine b) Alanine c) proline d) Tyrosine
20. Invert sugar is a mixture of equal amount of
a) D ( + ) glucose and sucrose b) D ( - ) fructose and sucrose
c) D ( + ) glucose and D ( - ) fructose d) sucrose and maltose
21. The t1/2 of first order reaction is 100 minutes. the rate constant of the reaction is
a) 6.93 x 103 min-1 b) 0.693 x 10-3 min-1
o m
c) 6.93 x 10 -3 min-1
c
d) 69.3 x 10-2 min-1
I
A ol ai .
L
a) they are clean b) they are easy to prepare
v is
A
c) the germs move towards them d) they are easily assimilated and adsorbed
k al
23. The decomposition of hydrogen peroxide in the presence of colloidal platinum is a/an
a) positive catalysis
w.
AM
b) negative catalysis c) auto- catalysis d) induced catalysis
ww N
24. For chemisorption which is wrong?
N
a) It is irreversible b) It requires activation energy
.A
c) It forms multilayers on adsorbate d) Surface compounds are formed
R
25. For the titration between oxalic acid and sodium hydroxide, the indicator used is
a) potassium permanganate b) phenolphthalein
c) litmus d) methyl orange
26. Which compound is formed when excess of KCN is added to an aqueous solution of copper
sulphate?
a) Cu (CN)2 b) K2 [Cu (CN)6] c) K [ Cu (CN)2] d) Cu2 (CN)2 + (CN)2-
a) Mish metals b) Metalloids c) plate metal d) actinides
28. Lanthanide contraction due to
a) perfect shielding of 4f electrons b) imperfect shielding of 4f electrons
c) perfect shielding of 3d electrons d) imperfect shielding of 3d electrons
29. An example of a chelating ligand is
a) nitro b) chloro c) bromo d) en
30. 92U235 nucleus absorbs a neutron and disintegrates into 54 Xe139, 38 Sr 94 and X. What is X?
a) 3 neutrons b) 2 neutrons c) α-particle d) β-particle
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Chemistry
1. Rutile is JUNE - 2011
a) TiO2 b) Cu2O c) MoS2 d) Ru
2. Free energy (G) and the free energy change (ΔG) correspond to the
a) System only b) Surrounding only
c) System and surrounding d) all of these
3. The entroy change ΔS(fusion) = involved in the process of H2O(S) H2O(l) at 0oC and 1 atm
pressure involving ΔH(fusion) = 6008 Jmol-1 is
a) 22.007 Jmol-1 K-1 b) 22.007 Jmol K-1
c) 220.07 Jmol-1 K-1 d) 2.2007 Jmol-1 K-1
4. When Δn(g) in a homogeneous gases equilibrium is positive, then
a) Kp = Kc b) Kp < Kc c) Kp > Kc d) Kp = Kc / 2
5. Forward reaction takes place, when?
a) Q < Kc b) Q > Kc c) Q = Kc
co m d) Kc = 1/Q
I
6. Which of the following compounds has the smell of better almonds?
o l A ai .
L
v is
A
c) Benzene sulphonic acid d) Nitrobenzene
k al
7. Nitro-acinitro tautomerism is exhibited by
a) nitronmethane
w.
A M
b) nitro benzene c) chloropicrin d) o-toluidine
ww N
8. Use of chloropicrin (CCl3NO2) is as
N
a) explosive b) dye c) anaesthetic d) sterilizing agent
.A
9. _________ is involved in the process of blood coagulation
R
a) Fats and oils b) Cephaalin c) Glycolipids d) Lecithins
10. Mixture of equal molecules of D (+) glucose D (-) fructose is called as
a) Fruit sugar b) Invert sugar c) Cane sugar d) Non-sugar
11. Bordeaux mixture contains
a) AgNO3 + HNO3 b) ZnSO4 + H2SO4 c) CuSO4 + Ca(OH)2 d) KMnO4 + HCl
12. The isotope used as a power source in long mission space probes is
a) U-235 b) Pu-235 c) Pu-238 d) U-238
13. Cera is used in
a) toys b) tracer bullets c) gas lamp meterial d) none of these
14. The coordination number of Ni (II) In [Ni (CN)4]2- is
a) 2 b) 4 c) 5 d) 6
15. Find out the missing in a reaction 5Be 8
4
Be8+?
a) α - particle b) β - particle c) electron capture d) positron
16. When phenol is distilled with zinc dust, It gives
a) benzaldehyde b) benzoic acid c) toluene d) benzene
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17. Williamson’s synthesis is an examble of

a) nucleophilic addition b) electrophilic addition
c) electrophilic substitution d) nucleophilic substitution
18. Diethyl ether behaves as a
a) Lewis acid b) Lewis base c) Neutral compound d) Bronsted acid
19. Aldol is
a) 2 - hydroxy butanol b) 3 - hydroxy butanol
c) 3 - hydroxy butanal d) 2 - hydroxy butanal
20. The isomerism exhibited by CH3CH2COOH and CH3COOCH3 is
a) Metamerism b) Position c) Chain d) Functional
21. In the energy of an electron in the second Bohr orbit of H-atom is - E, What is the energy of the
electron in the Bohr’s first orbit?
a) 2E b) -4E c) -2E d) 4E
22. The Hybridisation involved in XeF6 is
a) Sp3d3 b) Sp3d2 c) Sp3d
co m d) Sp3
o l AI
23. Among the following which has the maximun ionisation energy
ai .
L
a) Alkali metals b) Alkaline earth metals
v is
A
al
24. The lightest gas which is non-inflammable is
k
a) He
w
b) H2
.
A M c) N2 d) Ar
ww N
25. Silver salt used in photography is
N
.A
26. For a reaction Ea = O and k = 4.2 x 105 sec-1 at 300 k value of k at 310 K will be
R
a) 4.2 x 105 sec-1 b) 8.4 x 105 sec-1
c) 8.4 x 105 sec d) unpredictable
27. An emulsion is a colloidial solution of
a) two solids b) two liquids c) two gases d) one solid and one liquid
a) temperature increases b) temperature decreases
29. The oxidation of sodium sulphite by air is retarded by
a) MnO2 b) H2S c) Alcohol d) AS2O3
30. The pH of a solution containing 0.1 N NaOH solution is
a) 1 b) 10-1 c) 13 d) 10-13

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Chemistry
October - 2011
1. Which of the following pairs have almost equal radii?
a) Mo, W b) Y, La c) Zr, Hf d) Nb, Ta
2. The most common oxidation state of lanthanide is
a) +2 b) +1 c) +3 d) +4
3. The fuel used in nuclear power plant is
a) Copper b) Lead c) Uranium d) Radium
4. The co-ordination number of Ni II in (Ni (Cl)4]2- is
a) 2 b) 4 c) 5 d) 6
5. Loss of a β- partieie is equivalent to
a) Increase of one proton only b) decrease of one neutron only
c) both (a) & (b) d) none of these
6. If the activation energy is high, then the rate of the reaction is
co m
a) high b) moderate
o l AI c) low
ai .
d) cannot be predicted
L
v is
A
a) electro osmosis b) electrolysis
k al
M
c) electrodialysis d) electrophoresis
w.
A
8. For chemisorption, which is wrong?
ww N
a) It is irreversible b) It requires activation energy
N
c) It forms multimolecular layers on absorbate d) Surface compounds are formed
.A
9. The catalyst used for the decomposition of KClO3 is
R
a) MnO2 b) Cl2 c) V2O5 d) Pt
10. When one coulomb of electricity is passed through an electrolytic solution mass deposited on the
a) equivalent weight b) molecular weight
c) electrochemical equivalent d) one gram
11. The isomerism exhibited by CH3 - CH2 NO2 and CH3 - O - N = O is
a) position b) chain c) functional d) tautomerism
12. When nitromethane is reduced with Zn dust + NH4Cl we get
a) CH3NH2 b) C2H5NH2 c) CH3NHOH d) C2H5COOH
a) hydronium ion b) sulphonic acid c) nitronium ion d) bromide ion
14. The reducing sugar of the following is
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16. The bond order of oxygen molecule is

a) 2.5 b) 1 c) 3 d) 2
17. Molecular orbital with the least energy is
a) 1s b) * 1s c) py
2
d) * py
18. Among the following which has the maximum Ionisatlon energy?
a) Alkali metals b) Alkaline earth metals
19. The shape of PCl5 is
a) Pyramidal b) Trigonal bipyramidal
c) Linear d) Tetrahedral
20. The general outer electronic configuration of d-block elements is?
a) (n-1)d1-10ns0-2 b) (n-1)d1-5ns2 c) (n-1)d0ns1 d) (n-1)d1-10ns1-2
21. The total number of atoms per unit cell in BCC is
a) 1 b) 2 c) 3 d) 4
22. The network obtained from a system is given by
co m
a) w - P Δ V b) w + PΔ V
o l AI c) - w + PΔ V
ai . d) -w-PΔ V
L
23. Entropy is a ________ function
v is
A
a) state b) path c) exact d) inexact
k al
24. The fraction of total moles of reactant dissociated is called
w.
a) dissociation equilibrium
A M b) degree of association
ww N
c) degree of dissociation d) dissociation constant
N
25. Two moles of ammonia gas arc Introduced into a previously evacuated 1.0 dm3vessel in which it
.A
partialy dissociates at high temperature. At equilibrium 1.0 mole of ammonia remains. The equilibrium
constant Kc for the dissociation is
a) 27/16 (mole dm-3)2
c) 27/4 (mole dm-3)2 R b) 27/8 (mol dm-3)2
d) none of these
a) primary < secondary > tertiary b) primary > secondary > tertiary
c) primary < secondary < tertiary d) primary > secondary < tertiary
a) HI b) KMnO4 c) NaOH d) H2O
28. Which of the following produces ether, when heated with cone. H2SO4 at 413K?
a) Organic acid b) Aldehyde c) Alcohol d) Ketone
29. Methyl ketones are characterised by
a) fehling’s solution b) Iodoform test
c) Schiffs test d) Tollen’s reagent
30. The acid which reduces Tollen’s reagent is
a) acetic acid b) benzoic add c) formic arid d) oxalic acid

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Chemistry
March - 2012
1. The compound that undergoes bromination easily is
a) benzoic acid b) benzene c) phenol d) toluene
a) HI b) KMnO4 c) NaOH d) H2O
3. How many alcohol isomers are possible for the formula C4H10O?
a) 4 b) 2 c) 3 d) 7
a) acetone b) acetaldehyde c) ethyl alcohol d) methyl acetate
5. Which of the following compounds is optically active?
a) CH3CH2COOH b) HOOC - CH2 - COOH
c) CH3CH(OH)COOH d) Cl2CHCOOH
co m
6. The number of close neighbours in a body centred cubic lattice of identical spheres is
a) 6 b) 4
o
c) 12
l AI d) 8
ai .
s L
7. Which of the following processes is always non - feasible?
v i
l A
a) Δ H > 0, Δ S > 0 b) Δ H < 0, Δ S > 0
k a
M
c) Δ H > 0, Δ S < 0 d) Δ H < 0, Δ S < 0
w.
A
8. In SI unit 1 eu is
ww N
a) 41.84 EU b) 4.184 EU c) 418.4 EU d) 4184 EU
K2 respectively then
.A
1
N
9. If the equilibrium constants of the following reactions 2A B is K1 and B
1
2A are K1 and
R
a) K1 = 2K2 b) K1 = c) K2 = ( K1)2 d) K1 =
K2 K2 2
10. The equilibrium constant Kc for A (g) B (g) is 2.5 x 10-2. The rate constant of forward reaction
is 0.05 sec . Therefore the rare constant of the reverse reaction is
-1
a) 2 seconds-1 b) 0.2 second c) 2 Minutes d) 0.2 minute

11. de Broglie equation is
a) λ = mv / h b) λ = hmv c) λ = hv / m d) λ = h / mv
12. The hybridisation in NH ion is
+
4
a) sp b) sp2 c) sp3 d) sp3d

13. Among the following which has higher electron affinity value?
a) Fluorine b) Chlorine c) Bromine d) Iodine
14. The compound with garlic odour is
a) P2O3 b) P2O5 c) H3PO3 d) H3PO4
a) paired electrons b) completely filled electronic subshells
c) unpaired electrons d) completely vacant electronic subshells
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H3PO2
16. C6H5N2Cl X + N2 + HCl. The compound X is
Cu+
a) C6H5Cl b) C6H5NHNH2 c) C6H6 d) C6H5NO2
a) m - toluidine b) aniline c) p - aminophenol d) benzyl amine
18. Which of following componds is called oil of mirbane?
c) Benzene diazonium chloride d) Nitrobenzene
21. The term A in arrhenius equation is called as
a) probability factor b) activation energy
c) collision factor d) frequency factor
co m
o l AI
22. The Tyndall’s effect associated with colloidal particles is due to
ai .
s L
a) presence of charge b) scattering of light
v i
l A
c) absorption of light d) reflection of light
k a
M
w.
A
ww N
24. Medicine used as an eye lotion is
N
a) silver sol b) colloidal gold c) colloidal antimony d) milk of magnesia
.A
25. Ostwald’s dilution law is applicable in the case of the solution of
R
a) CH3COOH b) NaCl c) NaOH d) H2SO4
26. Which of the following ions will give colourless aqeous solution?
a) Ni2+ b) Fe2+ c) Cu2+ d) Cu+
27. _________ form oxocations.
28. Fuel used in nuclear power plants is
a) U 235 b) Pu 235 c) Pu 238 d) U 238
29. The geometry of [Ni (CN)4]2- is
a) Tetrahedral b) Square planar c) Triangular d) Octahedral
30. Half - life period of 79Au 198
nucleus is 150 days. The average life is
a) 216 days b) 21.6 days c) 261 days d) 26.1 days

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Chemistry
JUNE - 2012
1. An example for Frenkel defect is
a) NaCl b) AgBr c) CsCl d) FeS
2. In which of the following, process in always non-feasible?
a) Δ H > 0, Δ S > 0 b) Δ H < O, ΔS < 0 c) Δ H > 0, Δ S < 0 d) Δ H < 0, Δ S < 0
3. A peocess accompanied by increase in free energy tends to be
a) reversible process b) irreversible process
c) non-spontaneous process d) spontaneous process
4. If the equilibrium constants of the reactions 2HI H2 + I2 and H2 + I2 2HI are K1 and K2
respectively, then
a) K1=2K2 b) K1= 1/K2 c) K2 = ( K2)2 d) K1= 1/K22
5. Two moles of ammonia gas are introduced into a previously evacuated 1.0 dm3 vessel in which it
constant Kc for this dissociation is

co m
partially dissociates at high temperature. At equilibrium 1.0 mole of ammonia remains. The equilibrium
a)
27
16
(mole dm-3)2
o l
b)
I
27
A8
(mole dm-3)2
ai .
c)
27
4
(mole dm-3)2
al v is
A L
d) None of these
k M
6. When nitromethane is reduced with Zine dust + NH4Cl, it forms is
w.
A
a) CH3NH2 b) C2H5NH2 c) CH3NHOH d) C2H5COOH
ww N
7. When aquequs solution of benzene diazonium chloride is boiled, the product formed is
N
a) Benzyl alcohol b) Phenol c) Benzene + N2 d) Phenyl hydroxylamine
.A
R
a) (C2H5)2NH b) C2H5NH2 c) (C2H5)3N d) (C2H5)4N+1-
pyridine
9. Glucose + accetic anhydride
a) di acetate b) tetra acetate c) penta acetane d) hexa acetate
10. Which of the following is not true for amino acid?
a) Amino acid forms zwitter ion b) Amino acid has isoelectric poit
c) Amino acid has dual behaviour d) Amino acid is insoluble in NaOH solution
11. Which of the following compounds is not coloured?
a) Na2CuCl4 b) Na2CdI4 c) K4[Fe(CN)6] d) K3[Fe(CN)6]
12. ________ form oxocations
a) Lanthanum b) Promethium c) Gadolinium d) Terbium
14. The unit of paramagnetic moment is
a) debye b) k Joules c) BM d) ergs

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15. After 24 hours only 0.125 g out of the initial quantity of 1 g of a radioisotope remains. Then its half - life
period is
a) 3 hours b) 6 hours c) 8 hours d) 12 hourse
16. Glycerol is used
a) as a sweetening agent b) in the manufacture of good quality soap
c) in the manufacture of nitroglycerine d) all of these
a) HI b) KMn04 c) NaOH d) H2O
18. The solvent used for the Grignard reagent is
a) ethyl alcohol b) diethyl ether c) acetone d) benzene
19. The compound which does not reduce Fehling’s solution is
a) formaldehyde b) acetaldehyde c) benzaldehyde d) propionaldehyde
20. Among the following the strongest acid is
a) ClCH2COOH b) Cl3C-COOH c) CH3COOH d) Cl2CH-COOH
co m
a) 1 b) 2
o
c) 2.5
l A
22. The type of hybridisation in PCl5 molecule isI d) 3
ai .
a) sp3d2 b) sp3d
al v is
A Lc) sp3
23. Among the following, which has the maximum ionisation energy?
d) sp2
a) Alkali metals
w. k M b) Noble gases
ww
c) Alkaline earth metals
N A d) Halogens
N
.A
a) Tetrahedral b) octahedral c) square planar d) pyramidal
25. Which transition element shows the highest oxidation state?
a) Sc b) Ti
R c) Os
26. Decomposition of nitrogen pentoxide in CCl4 is a
d) Zn
a) zero order reaction b) first order reaction

c) pseudo-first order reaction d) fractional order reaction
27. For chemisorption which of the following is wrong?
a) Irreversible b) It requires activation energy
c) It forms multimolecular layers on adsorbate d) Surface compounds are formed
a) emulsion b) colloidal solution
c) true solution d) none of these
29. The rate of decomposition of hydrogen peroxide decreases in presence of
a) Platinum b) Iron c) Mn02 d) Glycerine
30. The pH of 0.1 N NaOH solution is
a) 1 b) 10-1 c) 13 d) 10-13
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Chemistry
OCTOBER - 2012
1. The crystal lattice with coordination number four is
a) CsCl b) ZnO c) BN d) NaCl
2. All the naturally occurring processes proceed spontaneously in a direction which lead to
a) decrease in entopy b) increase in enthaly
c) increase in free energy d) decrease in free energy
3. The entropy change for the following process possessing Δ H (transition) as 2090 J.mol-1 1 mol Sn
(α, 13oC) 1 mole Sn (β, 13oC)
a) 22.007 J.mol-1K-1 b) 7.307 JK-1mol-1
c) 0.314 J.molK-1 d) 109.52 J.mol-1K-1
4. In an equilibrium reaction, when Q<K then
a) forward reaction is favoured
b) reverse reaction is favoured
co m
I .
c) both forward and reverse reaction are favoured
ai
l A
d) none of these
is o L
5. Which of the following gaseous reactions Kp<Kc?
a) PCl5(g)
l v
PCl3(g) + I2(g)
a A b) H2(g) + I2(g) 2HI(g)
c) N2(g) + 3H2(g)
w. k 2NH3(g)
M
d) CO(g) + H2O(g) CO2(g) + H2(g)
a) C6H5NH - NHC6H5
ww N A
6. Nitrobenzene on electrolytic reduction in cone. Sulphuric acid, the intermediate formed is
b) C6H5NHOH c) C6H5 - N = N - C6H5 d) C6H5HSO4
a) Ammonia N
7. Which one of the following is the most basic?
.A
b) Methylamine c) Dimethylamine d) Aniline
R
8. The compound which does not undergo diazotisation reaction is
a) m-toluidine b) benzylamine
9. The building block of proterins are
c) aniline d) p-aminophenol
a) α - hydroxy acids b) α - amino acids c) β - hydroxy acids d) β - amino acids

10. An example for reducing disaccharide is
a) Glucose b) Fructose c) Sucrose d) Lactose
11. The most malleable and ducitle of all metals is
a) silver b) gold c) copper d) zinc
12. The maximum oxidation state exhibited by lanthanide is
a) +1 b) +3 c) +2 d) +4
13. Which is used in Gas lamp materials?
a) Ceria b) Thoria c) Mish metal d) Both (a) and (b)
14. The Type of isomerism found in the complexes [Co(NO2) (NH3)5] SO4 and [Co(SO4) (NH3)5]NO2 is
a) Hydrate isomerism b) Coordination isomerism
c) Linkage isomerism d) lonisation isomerism
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15. After 24 Hours, only 0.125g out of the initial quantity of 1 g of a radioisotope remains behind. Then its
half-life perod is
a) 0.8 hours b) 8 hours c) 100 hours d) 80 hours
16. Order at reactivity of Alcohol towards sodium metal is
a) primary < secondary > tertiary b) primary > secondary < tertiary
c) primary > secondary > teriary d) primary < secondary < tertiary
17. When diethyl ether reacts with chlorine in presence of sunlight it gives
a) chlorodiethyl ether b) dichlorodiethyl ether
c) perchlorodiethyl ether d) both (a) and (b)
18. Intermolecular hydrogen bonds are not present in
a) CH3COOH b) C2H5OC2H5 c) CH3CH2OH d) C2H5NH2
Conc H2SO4
19. 3CH3COCH3 the product is
a) Mesitylene b) Mesityl oxide c) Phorone d) Paraldehyde
co m
I .
a) Acetic acid b) Formic acid c) Butyric acid d) Benzoic Acid
ai
l A
21. De Broglie equation is
a) λ = mv / h b)
is o L
λ = hmv c) λ = hv / m d) λ = h / mv
l v
22. The hybridisation in ICI-4 ion is
a A
a) sp3
w. k
b) sp3d
M c) sp3d2 d) sp3d3
a) high
ww b) low
N A
23. Noble gases have _________ electron affinity.
c) zero d) very low
a) Carbon N
24. Which of the following is the second most abundant element in earth’s crust?
.A
b) Silicon c) Germanium d) Tin
26. Arrhenius equation is

R
25. When excess of KCN is added to an equeous solution of copper sulphate, it gives
a) Cu(CN)2 b) K2[Cu(CN)6] c) K[Cu(CN)2] d) Cu2(CN)2 + (CN)2
a) K = A.e-I/RT b) K = A.e-RT/Ea c) K = A.e-Ea/RT d) K = A.eEa/RT

28. The Iron catalyst used in the synthesis of ammonia in Haber’s process is poisoned by
a) AS2O3 b) V2O5 c) H2S d) Glycerine
29. The migration of colloidal particles under the influence of an electric field known as
a) Electro - osmosis b) Brownian movement
c) Electro - dialysis d) Cataphoresis
30. When pH of a solution is 2, the hydrogen ion concentration in moles. Lit-1 is
a) 1 x 10-12 b) 1 x 10-2 c) 1 x 10-7 d) 1 x 10-4

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Chemistry
March - 2013
1. ....................... form oxocations.
2. The metals present in Nichrome alloy.
a) Cr, Ni, Fe b) Cr, Co, Ni c) Cr, Fe d) Cr, Fe, Cu
3. 2H2O(g) + 2Cl2(g) 4 HCl(g) + O2(g) The relationship between KP and KC for the equilibrium is.
a) KP = KC b) KP = KC(RT)2 c) KP = KC(RT)1 d) KP = KC(RT)-2
4. The aminoacid without Chiral carbon is.
5. Silica gel is utilised for the ....................... of the number of gases.
a) adsorption b) absorption c) desorption d) all of these
6. 92
U235 nucleus absorbs a neutron and disintegrates into 54Xe139, 38Sr94 and X. What is X?
a) 3 neutrons b) 2 neutrons c) α - particle
co m d) β - particle
a) Na2CO3 solution
o l I
7. Ethylene diamine is converted to ethylene glycol using.
A
b) Nitrous acid
ai .
c) NaHCO3 solution d) Baeyer’s reagent
a) Sn/HCl
al is
b) Zn dust L
8. In nitroalkanes - NO2 group is converted to - NH2 group by using the reagent.
v A c) Zn/NH4Cl d) Zn/NaOH
. k M
9. Strong mineral acids ......................... the ethereal oxygen forming oxonium salts.
w
a) electronate
ww N A
b) protonate c) deprotonate d) dehydrate
10. When pH of a solution is 2, the hydrogen ion concentration in moles litre-1 will be.
a) 1 x 10-12
.A
11. Paramagnetism is the property of.N
b) 1 x 10-4 c) 1 x 10-7 d) 1 x 10-2
a) paired electrons
c) unpaired electons R b) completely filled electronic sub-shells
d) completely vacant electronic sub-shells
12. In the manufacture of ammonia by Haber’s process, the maximum yield of ammonia will be obtained
with the process having.
13. The noble gases are unreactive because they.
a) have same number of electrons b) have an atomicity
c) are gases with low density d) have stable electronic configuration
14. Emulsifying agent is used for.
a) precipitation of an emulsion b) denaturation of an emulsion
c) stabilization of an emulsion d) oxidation of an emulsion
15. [FeF6]4 - is paramagnetic because.
a) F - is a weaker ligand b) F - is a stronger ligand
c) F - is a flexidinate ligand d) F - is a chelating ligand
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16. The total number of atoms per unit cell in fcc is.
a) 1 b) 2 c) 3 d) 4
17. Among the following the strongest acid is.
a) CH3COOH b) HCOOH
c) ClCH2COOH d) CH3CH2COOH
18. The hybridisation in PCl5 molecule is.
a) sp3 b) sp3d2 c) sp3d d) sp2
19. Conversion of benzene diazonium chloride to chlorobenzene is
a) Sandmeyer’s reaction b) Stephen’s reaction
c) Gomberg reaction d) Schotten - Baumann reaction
20. Which of the following does not result in an increase in entropy?
a) Rusting of iron b) Conversion of ice to water
c) Crystallisation of sucrose from solution d) Sublimation of camphor
21. The organic compound that undergoes carbylamine reaction is.
a) (C2H5)2NH b) C2H5NH2 c) (C2H5)3N
co m d) (C2H5)4N+I-
I i .
22. For a reaction Ea = 0 and K=4.2 x 105 sec-1 at 300 K, the value of K at 310 K will be.
A ol a
L
a) 4.2x105 sec-1 b) 8.4x105 sec-1 c) 8.4x10-5 sec-1 d) 4.2x10-5 sec-1
v is
A
23. Maximun oxidation state exhibited by lanthanides is.
a) +1 b) +2
k al c) +3 d) +4
w.
AM
24. On moving down a group, the radius of an ion.
ww N
a) decreases b) increases
N
c) first increases and then decreases d) remains constant
A
25. Thermodynamic condition for irreversible spontaneous process at constant T and P is.
a) Δ G < 0
R .b) Δ G = 0
26. Which one of the following is a simple ether?
c) Δ G > 0 d) a and c
a) CH3 - O - C2H5 b) C6H5 - O - CH3

c) C2H5 - O - C2H5 d) C3H7 - O - C2H5
27. Dual character of an electon was explained by.
a) Bohr b) Heisenberg c) De Broglie d) Pauli
28. The compound that does not undergo Cannizaro reaction is.
a) formaldehyde b) benzaldehyde
c) acetaldehyde d) trimethyl acetaldehyde
29. The phenomenon of Tyndall’s effect is not observed in.
a) emulsion b) colloidal solution c) true solution d) gel
30. The reducing sugar is.
a) Sucrose b) Cellulose c) Starch d) Glucose

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Chemistry
JUNE - 2013
1. Chloropicrin is
a) CCl3CHO b) CCl3NO2 c) CHCl3 d) CH3NO2
2. The rate constant for a first order reaction is 1.54 x 10-3 sec-1. Its half life period is.
a) 540 seconds b) 450 seconds c) 45 seconds d) 54 seconds
3. ................... is used in gas lamp material.
a) MnO2 b) CeO2 c) N2O5 d) Fe2O3
4. For an isothermal process, the entropy change of the universe during a reversible process is.
a) Zero b) More c) Less d) None of the above
NaNO2 / HCl
5. C6H5NH2 X. Identify X.
273 K - 278K
a) C6 H5 Cl b) C6 H5 NHOH c) C6 H5 N2 Cl d) C6 H5 OH
6. Ruby glass is a colloidal solution of.
co m
a) Solid - sol b) Gel
o l AI c) Emulsion
ai . d) sol
L
7. Paramagnetic moment is expressed in.
v is
A
a) Debye Unit b) Kilojoules c) BM D) ergs
al
8. β - particle is represented as.
k
a) +1e0
w.
b) -1e0
A M c) 1H1 d) 2He4
ww N
9. The compound used in the preparation of the tranquilizer, sulphonal is.
N
a) acetone b) acetophenone c) Isopropyl alcohol d) glycol
.A
10. The unit of electron affinity is.
R
a) MeV b) JK -1 c) eV d) KJ mol -1
11. The equivalent conductivity of CH3COOH at 25oC is 80 ohm -1 cm2 eq-1 and at infinite dilution 400
ohm-1 cm2 eq-1. The degree of dissociation of CH3COOH is .....................
a) 1 b) 0.2 c) 0.1 d) 0.3
12. The number of secondary alcoholic group in glycerol is.
a) 1 b) 2 c) 3 d) 0
13. IUPAC name of this compound CH2O - CH - CH3
CH3
a) 1 - Methoxy propane b) Methyl isopropyl ether
c) Isopropyl methyl ether d) 2 - Methoxy propane
14. State of Chemical equilibrium is.
a) dynamic b) stationary c) none d) both (a and b)
15. The phenomenon of Tyndall’s effect is not observed in.
a) Emulsion b) Colloidal solution c) True solution d) Gel
16. Glucose is not oxidised to gluconic acid by.
a) Br2/H2O b) Fehling’s solution c) Tollens Reagent d) Conc. HNO3
17. Which of the following compounds will not give positive chromyl chloride test?
a) CuCl2 b) HgCl2 c) ZnCl2 d) C6H5Cl
18. For the reaction 2Cl(g) Cl2(g) the signs of Δ H and Δ S respectively are.
a) +, - b) +, + c) -, - d) -, +
19. Aspirin is.
a) Salicylic acid b) Acetyl salicylic acid
c) Salicylaldehyde d) Methyl Salicylate
a) Irreversible b) It requires activation energy
c) It forms multimolecular layers on adsorbate d) Surface compounds are formed
21. In the formation of HI from H2 and I2 , Kp = Kc because.
a) Δ ng = 2 b) Δ ng = 1 c) Δ ng = 0 d) Δ ng = -1
m
a) Paired electrons b) Completely filled electronic subshells
co
I
c) unpaired electrons d) Completely vacent electronic sub shells
ai .
A
o l
s L
a) 1 b) 2 c) 3 d) 4
v i
l A
24. Radioactive element of lanthanide is.
k a
. M
a) Thorium b) Lanthanum c) Uranium d) Promethium
w A
25. Semiconductors which exhibit conductivity due to the flow of excess negative electrons are called.
ww N
a) Super conductors b) n - type semiconductors
c) p - type semiconductors
.A N d) Insulators
26. ................. occur in the white matter of the brain and of all nervous tissue.
R
a) Lacithin b) Cephalin c) Galactolipids d) Amino acid
27. The organic compound that undergoes carbylamine reaction is.
a) (C2H5)2NH b) C2H5NH2 c) (C2H5)3N d) (C2H5)4N+I-
28. The intramolecular hydrogen bonding is present in.
a) o - nitrophenol b) m - nitrophenol
c) p - nitrophenol d) None of the above
29. Intermolecular hydrogen bonds are not present in.
a) CH3COOH b) C2H 5OC 2H 5 c) CH3CH2OH d) C2H5NH2
30. The compound with garlic taste is.
a) H3PO4 b) H3PO3 c) P2O3 d) P2O5

Chemistry
October - 2013
1. When ether is exposed to air for sometime an explosive substance produced is
a) Peroxide b) Oxide c) TNT d) Superoxide
2. Among the halogen acids, the weakest acid is
a) HF b) HCl c) HBr d) HI
3. In a reversible reaction 2HI H2 + I2 Kp is
a) greater than Kc b) less than Kc c) equal to Kc d) zero
a) Δ G = Δ H + T Δ S b) Δ G = Δ H -T Δ S
c) Δ G = Δ H x T Δ S d) Δ G = Δ H / T Δ S
5. The compound that does not undergo Cannizaro reaction is
a) Formaldehyde b) Acetaldehyde
c) Benzaldehyde d) Trimethyl acetaldehyde
co m
6. An example of ambidentate Ligand is
I ai .
a) NH3 b) H2O
s o l A
c) NO 2
-
d) I
-
NaNO2 / HCl
l v i L
7. C6H5NH2
0oC
. k a X. X is
M A
a) C6 H5 Cl
w A
b) C6 H5 NHOH c) C6 H5 N2 Cl d) C6 H5OH
ww N
8. For a reaction Ea = 0 and K = 4.2 x 10 sec at 300 K, the value of K at 310 K will be
5 -1
a) 4.2 x 105 sec-1

c) 7.4 x 105 sec-1
.A N b) 8.4 x 105 sec-1
d) 4.2 x 10-5 sec-1
R
9. Which element in Lanthanide is radioactive?
a) Cerium b) Promethium c) Holmium
10. Among the following which has higher electronegativity value?
d) Lutetium
a) Fluorine b) Chlorine c) Bromine d) Iodine

11. In the oxidation of SO2 in contact process the catalytic poison is
a) As2O3 b) V2O5 c) Fe2O3 d) CuCl2
12. Which of the following compound doesn’t show tautomerism?
a) Nitro benzene b) Nitromethane c) Nitro ethane d) 2-nitropropane
electrode is equal to.
a) equivalent weight b) molecular weight
c) electrochemical equivalent d) one gram
14. The hybridisation in SF6 molecule
a) sp3 b) sp3d2 c) sp3d d) sp3d3

15. Electrophile used in nitration of benzene is
a) Hydronium ion b) Sulphonic ion
c) Nitronium ion d) Bromide ion
16. IUPAC name of phenetole is
a) Phenoxy benzene b) ethoxy benzene
c) Methoxy benzene d) Propoxy benzene
17. In the following radioactive decay 92X232 Y220 how many α and β particles are ejected.
89
a) 3α, 3β b) 5α, 3β c) 3α, 5β d) 5α, 5β

18. Electrophoresis is a ________ property of a colloid.
a) Optical b) Kinetic c) Electrical d) Magnetic
19. An emulsion is a Colloidal solution of
a) two solids b) two liquids c) two gases d) one solid and one liquid
20. Silver salt used in Photography is
21. Proteins are.
co m
a) Polypeptides b) Polyacids
I i
c) Polyphenols
a . d) Polyester
o l A
22. The molecular orbitals are filled according to
s
v
a) Pauli’s exclusion principle
l i L b) Hund’s rule
c) Aufbau principle
. k a
M A d) All the above
w
23. Which one of the following crystal has 8:8 structure?
a) MgF2
ww
b) CsCl
N A c) KCl d) NaCl
24. A ‘d’ block metal ion has a magnetic moment of 1.732 BM. The number of unpaired electrons are
a) 1 b) 2
.A N c) 3
25. The SI unit of entropy is...........(ANSWER :d)
d) 4
a) Cal K-1 mol-1

R b) erg K-1 mol-1
26. Cephalins have been implicated in the process of
c) J deg-1 mol-2 d) J K-1 mol-1
a) Metabolism b) Organisation of the body

c) Blood purification d) Blood coagulation
27. _________ forms oxocations.
28. The rate constant of the forward and reverse reactions are 8 x 10-5 and 2 x 10-4 respectively, Kc
is__________
a) 0.004 b) 0.02 c) 0.2 d) 0.4
29. The acid that cannot be prepared by grignard reagent is
a) Acetic acid b) Formic acid c) Butyric acid d) Benzoic acid
30. When phenol is distilled with Zn dust it gives.
a) benzaldehyde b) benzoic acid c) toluene d) benzene

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��
PTA - �� I-V
��
co m
a i. I
l
lv iso L A
.k a MA
ww A
w N N
R .A
R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed.

PGT(CHEMISTRY),
GOVT. GIRLS HR. SEC. SCHOOL GINGEE,
e mail: sss smalai@ g mail.c o m.
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Chemistry
PTA-Model Question paper -I
Choose and write the corret answer 30x1=30
1. En = -313.6/n2, If the value of Ei = -34.84 to which value ‘n’ corresponds to
(a) 4 (b) 3 (c) 2 (d) 1
(a) 2.5 (b) 3 (c) 2 (d) 4
3. Noble gases have ..................... electron affinity
(a) High (b) low (c) zero (d) very low
(a)Tetrahedral (b) Octahedral (c) square planar (d) Pyramidal
5. Copper is extracted from
co m
(a) Cuprite (b) copper glance
6. silver salt used in photography is
o l AI (c) Malachite
ai . (d) Copper pyrites
(a) AgCl (b) AgNO3
al v is
AL
7. The most common oxidation state of Lanthanides is
(c) AgF (d) AgBr
(a) +2
. k
(b) +1
w M (c) +3 (d) +4
(a) MnO2
ww
(b) CeO2 A
8. __________ is used in gas lamp material
N (c) N2O5 (d) Fe2O3

(a) Tetrahedral
.A N
(b) Square planar (c) Triangular (d) Octahedral
R
10. Which of the follower is used as neutron absorber in nuclear reactors?
(a)Water (b) Deuterium (c) Uranium
11. The number of Chloride ions present per unit of CSCl ?
(d) Cadmium
(a) 6 (b) 8 (c) 1 (d) 4

12. In an adiabtic process Which of the following is correct?
(a) q=w (b) q=0 (c) Δ E=q (d) p Δ v=0
(a) an increase in entropy (b) a decrease in entropy
(c) an increase in heat of vapourisation (d) an increase in free energy
(a) Dynamic (b) Stationary (c) Both (a) & (b) (d) None
15. For an endothermic equilibrium reaction, if K1and K2 are the equilibrium constants at T1 and T2
temperatures respectively and if T2>T1,then
(a) K1<K2 (b) K1>k2 (c) K1=K2 (d) None
16. The unit of zero order rate constant is
(a) sec-1 (b) mol lit-1 sec-1 (c) mol sec-1 (d) lit2 sec-1

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17. Oil soluble dye is mixed with emulsion and emulsion remains colorless then, the emulsion is
(a) O/W (b) W/O (c) O/O (d) W/W
(a) Precipitation (b) coagulation (c) Dialysis (d) Filtration
19. Fe(OH)3 colloidal particles adsorb __________ ions
(a) Fe3+ (b) Mg2+ (c) Ca2+ (d) Cu2+
20. Ostwald’s dilution law is applicabe to the solution of
(a) CH3COOH (b) NaCl (c) NaOH (d) H2SO4
21. The reaction of lucas reagent is fast with
(a) ethanol (b) methanol (c) 2-propanol (d) 2-methl 2-propanol
22. An Organic compound C4H10O When heated with excess HI gives Only one type of alkyl iodide. The
compound is
(a) diethylether (b) methyl n-propylether
co m
I .
(c) methyl iso propylether (d) n-butyl alcohol
ai
l A
23. When ether is exposed to air for sometime an explosive substance prpduced is
(a) peroxide (b) Oxide
is o L (c)TNT (d) superoxide
l v A
24. The compound that does not undergo cannizzaro reaction is
a
(a) Formaldehyde
w. k M
(b) Acetaldehyde
A
(c) Benzaldehyde (d) Trimethyl Acetaldehyde
ww N
25. Which oi the following is least acidic?
(a) C2H5OH (b) CH3COOH
.A N
26. Nitration of nitrobenzene at 373K results in
(c) C6H5OH (d) ClCH2COOH
R
(a) O-dinitro benzene (b) 1,3,5-trinitro benzene
(c) P-dinitro benzene (d) m-dinitro benzene
(a) Electrophile (b) Lewis base (c) Lewis base (d) Free radical
(a) m-toluidine (b) anline (c) p- amino phenol (d) benzylamine
29. Important constituent of cell wall is
(a) Lipid (b) Cellulose (c) Protein (d) Vitamin
30. The most abundant carbohydrate is
(a) glucose (b) fructose (c) Starch (d) cellulose

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Chemistry
PTA-Model Question paper -II
1.de-Broglie equation is
mv hv h
(a) λ= h (b)�λ=hmv (c) λ= (d) λ=
m mv
2. The hybridisation in SF6 molecule is
(a) sp3 (b) sp3d2 (c) sp3d (d) sp3d3
3. Across the period, electron affinity generally
(a) decreases (b) increases
(c) decreases and increases (d) increases and then decreases
4. Which has least melting point?
m
(a) B (b) Al (c) Ga (d) In
co
I
5. Formation of coloured ions is possible when metal ions contain
ai .
A
(a) paired electrons (b) unpaired electrons
o l
s L
(c) lone pairs of electrons (d) none of the above
v i
(a) 0
.
(b) 1.73 l
M A
6. The value of magnetic moment of Ti3+ ion is
k a (c) 2.83 (d) 3.87
w A
7. The lanthanide contraction is due to
ww N
(a) perfect shielding of 4f electrons (b) Imperfect shielding of 4f electrons
.A N
(c) perfect shielding of 3d electrons
8. The actinide that exhibits oxidation state +6 is
(d) Imperfect shielding of 3d electrons
R
(a) Ac (b) Th (c) Pa (d) U
9. The geometry of [Fe(CN)6]4- is
a) tetrahedral b) Square planar c) triangular d) Octahedral
10. In the nuclear reaction, 92U238 82
Pb206 the number of α and β particles emitted are
a) 7α, 5β b) 6α, 4β c) 4α, 3β d) 8α, 6β
11. Frenkel defect is found in
a) Nacl b) AgCl c) CsCl d) FeS
12. Which of the following does not result in an increase in the entropy ?
a) Crystallisation of sucrose from solution b) Rusting of iron
c) conversion of ice to water d) Vapourisation of Camphor
a) Spontaneous b) Non-Spontaneous c) Reversible d) All of these
14. If the equilibrium constants of the following reactions are 2A B is K1and B 2A is
K2, then
1 1 2
a) K1=2K2 b) K1= c) K2= ( K1 )2 d) K1=
K2 K2
15.At chemical equilibrium
1
a) Q > Kc b) Q < Kc c) Q = Kc d) Q = K
c
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16. The half life period of a first order reation is 10 minits. then its rate constant is
a) 6.93 x 102 min-1 b) 0.693 x 102min-1 c) 0.693 x 102min-1 d) 69.3 x 10-1 min-1
17. Somke is a colloidal solution of
18. 2SO2 + O2 2SO3 Homogeneous catalyst for this reaction is
a) Pt b) V2O5 c) NO d) As2O3
19. Which one of the following is used in the Purification of drinking water?
a) colloidion b) alum c) silver bromide d) chromium salt
20. The specific conductance of 0.01M solution of KCL is 0.0014 ohm-1cm-1 at 250C. It’s equivalent
conductance is
a) 14ohm-1-cm2 equi-1 b) 140ohm-1-cm2 equi-1
c) 1.4ohm-1-cm2 equi-1 d) 0.14ohm-1-cm2 equi-1
co m
21.An alcohol which dose not undergo dehydrogenation when passed Over heated Cu at 573K is
I .
a) n- butyl alcohol b) sec- butyl alcohol
ai
l A
c) iso- butyl alcohol d) tert- butyl alcohol
is o L
22.When ethyl iodide is treated with dry silver oxide it forms
a) ethyl alcohol
l v
b) diethyl ether
a A c) silver ethoxide d) ethyl methyl ether
. k M
23. A reaction of ether in which α hydrogen atom involves
w
a) halogenation
ww
c) oxonium salt formation
N A b) peroxide formation
d) all of these
a) acetone N
24. Decolourised Schiff’s reagent gives pink colour with
.A
b) acetaldehyde c) ethyl alcohol d) methyl acetate
R
25. Acetyl chloride cannot be prepared from acetic acid using
a) PCl5 b) PCl3 c) SOCl2
d) NaCl
a) hydronium ion b) sulphuric acid c) nitronium ion d) bromide ion

27. Nitro benzene on reduction using tin and hydrochloric acid gives
a) aniline b) phenyl hydroxyl amine c) hydrazo benzene d) azobenzene
28. An organic compund ‘A’ with molecular formula C3H9N neither give nitrogen nor yellow oily liqyid
with HNO2. Then ‘A’ is
a)CH3CH2CH2NH2 b) CH3- CH2- NH - CH3
c) CH3-N-CH3 d) All of these
CH3
29. A mono saccharide among the following is
a) Sucrose b) Cellulose c) Maltose d) Glucose
30. which is not true of an amino acid?
a) amino acid foms zwitter ion b) has isoelectric point
c) dual behaviour d) amino acid is insoluble in NaOH solution
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Chemistry
PTA-Model Question paper -III
1. The energy of electron in an atom is given by En=
- 2 2me4 - 4 2me4 - 2 2me2 - 4 2e2m
a) b) c) d)
n2 h 2 n2 h 2 n2 h 2 n2h2
2.Bond order in oxygen molecule is
a) 0 b) 1 c) 2 d) 3
3. The Element with the highest electron affinnity is
a) fluorine b) chlorine c) bromine d) iodine
4.The shape of PCl5 is
a) trigonal pyramidal b) trigonal bipyramidal c) linear d) terahedral
5. The correct outer electronic configuration of copper is
co m
I .
a) 3d9 4s2 b) 3d10 4s1 c) 3d4 4s2 d) 3d54S1
ai
l A
6.The maganetic moment of V3+ ion is
a) ) 3 BM b) 2 ) 2 BM
is o )
L c) 0 d) 35 BM
l v A
7.In f-block elements the following shells are incomplete
a
a) n b) (n-1)
w. k M c) (n-2) d) all the above
a) Lanthanides
ww
8.__________ from oxocations
N
b) ActinidesA c) Noble gases d) Alkalimetals
9. Which is not an anionic complex?
a) [Cu(NH3)4]Cl2
.A N
b) K3[Fe(CN)6] c) K4[Fe(CN)6] d) K2[Zn(CN)4]
c) both (a) and (b)

R
10. Loss of β- particles is equivalent to
a) increase of one proton only b) decrease of one neutron only
d) none of these
11. A regular three dimensional arrangement of identical points in space is called
a) unit cell b) space lattice c) isomorphism d) crystal lattice
12. For the reaction 2Cl(g) Cl2(g) the sings of Δ H and Δ S respectively are
a) +,- b) +,+ c) -,- d) -,+
13. All naturally occuring processes proceed spontaneously in a direction Which leads to
a) decrease in entropy b) increase in enthalpy
c) increase in free energy d) decrease in free energy
14. The active mass of 28g of nitrogen in 2 litres is
a) 1 M b) 0.5 M c) 2 M d) 4 M
15. The catalyst used in the Synthesis of SO3 by contact process is
a) Fe b) I2 c) Mo d) V2O5
16. For a reaction aA bB the rate of a reaction is incresed by twice when the concentration of the
reactant is increaesed by four times. The rate equation is Rate=
1 3
a) K[A] 2 b) K[A] 2 c) K[A]4 d) K[A]2

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a) gas in liquid b) liquid in gas c) gas in soild d) soild in gas
18. The migration of colloidal particles under the influence of electric fleld is known as
a) dialysis b) cataphoresis c) electro- osmosis d) electro dialysis
19. principle of cottrell smoke precipitator is coagulation by
a) addition of electrolyte b) addition of oppositely charged colloid
c) oppositely charged electrode d) all of these
20. A solution which is resistant to change of pH on addition of small amount of an acid or a base is known
as
a) buffer solution b) true solution c) neutral solution d) ideal solution
21. When phenol is heated with Zinc dust it gives
a) benzene b) 2,4,6 - trinitro benzene
c) 1,3,5 - trinitro benzene d) no reaction
co m
I .
ai
l A
a) very reactive b) replaceable c) oxidising d) comparatively inert
is o L
23. When an ether ‘A’ is treated with hot concentrated hydroiodic acid gives only ethyl iodide. then A is
a) diethyl ether
al v A d) methyln-propyl ether
c) methyl isopopyl ether
w. k M d) all of these
a) formaldehyde
N A
24. The compound which does not reduce Fehling’s solution is
ww b) acetaldehyde
c) benzaldehyde
N
d) propionaldehyde
.A
25.The isomerism exhibited by CH3CH2COOH and CH3COOCH3 is
a) metamerism
R b) position
26. The basic character of amines is due to
a) tetrahedral structure
c) chain d) functional
b) presence of nitrogen atom

c) lone pair of electrons on nitrogen atom d) high electronegativity of nitrogen
27. When aqueous solution of benzene diazonium chloride is boiled the product is
a) benzyl alcohol b) benzene and nitrogen
c) phenol d) phenyl hydroxyl amine
28. IUPAC name of methyl cyanide is
a) methane nitrile b) aceto nitrile c) ethane nitrile d) cyano methane
29. primary structure of proteins refers to
a) the amino acids present b) the shape of protein
c) the peptide bond d) the sequence of amino acid
30. Sucrose is a non reducing disaccharide, because
a) C1of glucose is bonded to C1of fructose b) C2 of glucose is bonded to C1of fructose
c) C1 of glucose is bonded to C2of fructose d) C2 of glucose is bonded to C2of fructose

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Chemistry
PTA-Model Question IV
1. If the energy of an electron in the second Bohr orbit of H-atom is -E What is the energy of the electron
in the first orbit?
a) 2E b) -2E c) -4E d) 4E
2. The type of hybridisation in CO32- ion is
a) sp b) sp2 c) sp3 d) sp3d
3. When XA>>XB, A-B bond is
a) polar covalent b) non - polar covalent c) lonic d) metallic
4. Which shows only -1 oxidation state?
a) fluorine b) bromine c) chlorine d) iodine
m
5. Paramagnetism is the Property of
co
I
a) Paired electrons b) Completely filled electronic sub-shells
ai .
l A
c) unpaired electrons d) completely vacant electronic subshells
s o
6. Which of the following is not coloured?
i L
a) [Cu(NH3)4]2+
al v A
b) [CdCl4]2- c) K4[Fe(CN)6] d) K2[Cu(CN)4]
. k M
7.Actinide contraction is due to imperfect shielding of
w A
a) 4f electrons b) 5f electrons c) 6d electrons d) 7s-electrons
ww N
8. The lanthanide contraction is responsible for the fact that
.A N
a) Zn and Y have about the same radius
c) Zr and Hf have about the same radius
b) Zr and Nb have similar oxidation state
d) Zr and Zn have the same oxidation state
R
9. The type of hybridisation of the central metal ion in the complex [Ni(CN)4]2- is
a) sp3 b) sp3 d c) d sp2 d) d sp3
a) α -rays b) β-rays c) r-rays d) all are equally penetrating
11. In a simple cubic cell each point on a corner is shared by
a) one unit cell b) eight unit cell c) four unit cell d) two unit cell
12. Which of the following, the process is always non feasible
a) ΔH >0,ΔS>0 b) ΔH <0,ΔS>0 c) ΔH >0,ΔS<0 d) ΔH <0,ΔS<0
13. The standard free energy value (Go) of formation of an element in its stable state is
a) Zero b) negative c) positive d) unpredictable
14. In the reversible 2HI H2 + I2 Kp is
a) greater than kc b) less then kc c) equal to Kc d) zero
15. Two moles of ammonia gas introduced into a previously evacuated 1.0 dm3 vessel in which it partially
dissociates at high temerature. At equilibrium 1.0 mole of ammonia remains The equilibrium constant
Kc for the dissociation is
a) 27/16 ( mol dm-3 )2 b) 27/8 ( mol dm-3 )2
c) 27/4 ( mol dm-3 )2 d) None of these
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d[N2O5]
16. 2N2 O5 4NO2 + O2 , - = K1[N2O5]
dt
d[NO2] d[O2]
= K2[N2O5] and = K3[N2O5] the relation between K1,K2 and K3 is
dt dt
a) 2K1=4K2=K3 b) K1=K2=K3
c) 2K1=K2=4K3 d) 2K1,=K2=K3
17. The Tyndall effect associated with colloidal particles is due to
a) presence of charge b) scattering of light
c) absorption of light d) reflection of light
18. In the case of physical absorption, there is desorption when
a) temperature increases b) tempereature decreases
co m
I
19. Rubber is obtained by
ai .
A
a) dissolving latex in a suitable solvent
o l
s L
b) coagulation of latex
v i
l A
c) evaporation of latex
k a
M
d) all of these
w.
A
20. The unit of cell constant is
ww N
a) ohm-1m-1 b) m-1 c) ohm-1m2eq-1 d) no unit
21. The IUPACname of (CH3)3C-OH is
a) 2,2-dimethyl- 1-propanol
.A N b) neopenthyl alcohol
R
c) 2-methyl -2-propanol d) Trimethylene carbinol
22. Willamson’s synthesis is an example of
a) nucleophilic addition b) electrophilic addition
c) electrophilic substitution d) nucleophilic substitution
23. 1-Methoxy propane and 2-Methoxy propane are
a) metamers b) position isomers
c) functional isomers d) chain isomers
24. Acetophenone and benzophenone can be distinguished by
a) lucas test b) ferric chloride solution
c) iodoform test d) carbylamine test
25. The acid that reduces Tollen’s reagent is
a) methanoic acid b) oxalic acid c) salicylic acid d) oleic acid
26.When nitro methance is condensed with acetone it gives
a) 1-nitro-2-propanol b) 1-nitro-2-methyl-2-propanol
c) 1-nitro-2-methoxy propane d) no reaction

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27. Nitrobenzene on electrolytic reduction in conc sulphuric acid the intermediate formed is
a) C6H5-NH-NH-C6H5 b) C6H5NH OH
c) C6H5-N=N-C6H5 d) C6H5HSO4
O
28. The isomerism exhibited by CH3- CH2- N and CH3- CH2- O - N=O is
O
a) position b) chian c) functional d) tautomerism
29.The amino acid without chiral carbon is
a) glycine b) alanine c) proilne d) thyrosine
30. In acid medium amino acids exist in the from of
a) cations b) anions
c) dipolar ions d) neutral molecules
co m
o l AI ai .
al v is
AL
w. k M
ww N A
.A N
R

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Chemistry
PTA-Model question-V
1. Which of the following particle having same kinetic energy, would have the maximum de-Brogile wave
length?
a) α - Particle b) Proton c) β - Particle d) neutron
2. Which one of the following molecule is paramagnetic?
a) H2 b) He2 c) N2 d) O2
3. Among the following Which has maximum ionisation energy
a) alkali b) alkaline earth metals c) halogens d) noble gases
4. An element which is in 15th group and third period was burnt in limited supply of air to give oxide A.A
is
a) NO2 b) P2O3 c) P2O5 d) SO3
5. The correct statement in respect of d-block elements is
co m
a) they are all metals
o l A
c) they form coloured ions and complex saltsI ai .
b) they show variable valency
d) all the above statement are correct.
v is
6. Zn displaces Au from K[Au(CN)2], because
al
a) Zn is more electro positive than Au
AL b) Au is more electro positive than Zn
w. k
c) Zn is more electro negative than Au
M d) Atomic mass of Zn is greater than Au
ww N A
7. The elements in which the extra electron enters (n-2) orbitals are called
N
a) s- block elements b) p-block elements
.A
c) d-block elements d) f-block elements
R
a) mish - metals b) metalloid c) plate metals d) actinides
9. IUPAC name of the complex K3[Cr(C2O4)3]3H2O is
a) potassium tri oxalato chromate (III) trihydrate
b) triaquo potassium tri oxalato chromate (III)
c) potassium tris (oxalato) chromate (III) trihudrates
d) potassium tris (oxalato) chromate (III) trihudrate
10. High speed projectiles may chip a heavy nucleus into several fragments in
a) nuclear fission reactions b) nuclear fusion reactions
c) spallation reaction d) all of these
11. Bragg’s equations is
a) nλ =2d sin θ b) nd =2λ sin θ c) λd =2n sin θ d) ndλ =2 sin θ
12. Aliquid which obeys Trouton’s rule is
a) H2 b) H2O c) CH3 COOH d) CCl4
13. Change in Gibb’s free energy is given by
a) Δ G = Δ H +T Δ S b) Δ G = Δ H - T Δ S
c) Δ G = Δ H x T Δ S d) none of the above
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14. The relation between Kp and Kc of a reversible reaction is

a) Kc=Kp(RT) Δng b) Kp=Kc(RT) Δng
c) Kp=Kc d) Kp=1/Kc
15. In the equilibrium N2+3H2 2NH3 The maximum yield of ammonia will be obtained with the
process having
a) low pressure and high temperature
b) low pressure and low temperature
c) high pressure and high temperature
d) high pressure and low temperature
16. In a first order reaction, the time taken to react 99.9% of the raection is _________ times its half life
period
a) two b) five c) ten d) hundred
co m
I
a) irreversible
ai .
A
b) it requires activation energy
o l
s L
c) it forms multimolecular layers on adsorbant
v i
l A
d) surface compounds are formed
k a
M
18. An emulsion is a collidal solution of
w.
A
a) two solids b) two liquids
ww N
c) two gases d) one solid and one liquid
19.Awrong statement about catalyst is
.A N
a) remains unchanged in mass and chemical composition at the end of the reaction.
R
b) only a small quantity is needed
c) they do not affect the position of equilibrium
d) they can initiate a reaction.
20. Equimolar solution of which one of the following has greater PH value
a) HCl b) CH3COOH c) NaOH d) NH4OH
21.Iso- butyl alcohol when subjected to victor meyer’s test gives
a) blue colour b) red colour
c)violet colour d) no colour
22. According to lewis concept of acids and bases, ethers are
a) neutral b) acidic c) basic d) amphoteric
23. PCl5does not give HCl with
a) ethyl alcohol b) diethylether
c) acetic acid d) phenol
24. From which of the following tertiary butyl alcohol is obtained by the action of methyl magnesium
iodide?
a) HCHO b) CH3CHO c) CH3COCH3 d) CO2

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25. Which one of the following compound gives violet colour with neutral ferric chloride and also
effervescence with sodium bicarbonate?
a) aspirin b) methyl salicylate
c) salicylic acid d) phenol
26. Which one of the following will not undergo diazotisation?
a) m-toluidine b) aniline
c) p- amino phenol d) benzyl amine
27. Biphenyl is the product of
a) Schotten Bauman’s reaction
b) Gomberg reaction
c) Friedel craft’s reaction
d) sand meyer reaction
28. During nitration of aniline m-nitro aniline is also formed due to
co m
I .
a) meta directing nature of -NH2 group
ai
l A
b) protonation of -NH2 group
c) +I effect of -NH2 group
is o L
d) resonance in benzene
al v A
. k
29. Inversion of sucrose referes to
w M
a) oxidation of sucrose
ww
b) reducation of sucrose
N A
d) polymerisation of sucrose
.A N
c) hydrolysis of sucrose, to glucose and fructose
a) - C - NH2
R
30. Which one of the following represents peptide bond
O O
b) - C - N -
H
O
c) - C - NH2 d) - C - NH3 -


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HIGHER SECONDARY - SECOND YEAR

w. kP.G. TEACHER IN CHEMISTRY

Higher Secondary - Second Year

2 Periodic Classification 1(5) - - - - - - 1(1) - - 1(3) - - - - - 09

3 p-Block elements - - 1(3) - - - 1(3) - 1(5) - - - - - - 1(1) 12

4 d-Block elements - 1(5) 1(3) - - - 1(3) 1(1) - - - 1(1) 1(5) - - - 18

5 f-Block elements - - - - - 1(5) - 1(1) - - - 1(1) - - - - 07

6 Co-ordination & Bio-coordination

7 Nuclear Chemistry - - - - 1(5) - - - - - - 1(1) - - 1(3) - 09

w. k M1(5) - - 1(1) - - 1(3) 1(1) - - - 1(1) - - - - 11

19 Carboxylic Acids - - 1(3) - 1(5) - - - - 1(5) - 1(1) - - - - 14

20 Organic Nitrogen Compounds 1(5) - - - - - - 2(1) - - - 1(1) - - 1(3) - 11

21 Bio molecules - - - 1(1) - - - 1(1) 1(5) - - - - - - - 07

22 Chemistry in Action - - - - - - 1(3) - - 1(5) - - - - - - 08

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, vii

HIGHER SECONDARY - SECOND YEAR

1. En= - 313.6 , If the value of Ei = -34.84 to which value ‘n’ corresponds

2. Dual character of an electron was explained by

7. The energy of electron in an atom is given by En=

4π2me4 2π2me2 2π2me4 2πme4

8. The bond order of Oxygen molecule is

9. The hybridisation in SF6 molecule is

10. The intramolecular hydrogen bonding is present in

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 1

M A b) inversely proportional to its size

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 3

a) d-d transistion b) Presence of water molecules

a) n(n-1) b) n(n+1) c) n(n+2)

a) Calamine and siderite are carbonates

25. The transition element with the lowest atomic number is

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 5

M A b) Imperfect shielding of 4f electron

13. Maximum oxidation state exhibited by Lanthanides is

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 6

6. COORDINATION COMPOUNDS AND

a) K+ b) CN- c) FeII d) [Fe(CN)6]4-

3. In the nuclear reaction, 92U238

a) 3α, 3β b) 5α, 3β c) 3α, 5β d) 5α, 5β

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 8

co m d) Body centred cubic

10. CHEMICAL EQUILIBRIUM - II 2 x 1= 2

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 10

3. In the reversible reaction 2HI H2 + I2, is

5. For the homogeneous gas reaction at 600 K

a) (mol dm-3)-2 b) (mol dm-3) c) (mol dm-3) 10 d) (mol dm-3)-9

(a) kinetic energy (b) threshold energy

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 11

7. Colloidal medicines are more effective because

.A N (c) Kekule (d) Avogadro

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 13

(a) 1 (b) 10–1 .A N

16. HYDROXY DERIVATIVES 1 x 1= 1

2. Which is soluble in H2O?

(b) chlorosulphonic acid

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 15

(a) benzoic acid

(a) position isomerism

19. Ethylene glycol forms terylene with

R.ANNAMALAI M.Sc (Che).,M.Sc (Psy).,M.Phil.,B.Ed. PGT(CHE), G(G)HSS, GINGEE, Page : 16

21. Glycerol is used

4. Oxygen atom of ether is

9. When ether is exposed to air for sometime an explosive substance produced is