GOVT.MODEL SCHOOL,VILLUPURAM Dt.

NEET’22
XII-Chemical Kinetics

1.In a first order reaction 87.5% reactant is converted in to product in 15 minutes.The rate constant
for the reaction is given by

0.693 0.693 5
1) min-1 2) min-1 3) min-1 4) 0.693 x 5 min-1
5 15 0.693
2.Half life period of a first order reaction is 20 minutes.What is the time taken to reduce the
1
concentration of the reactant to th?
10
1) 6.6 min 2) 66.56 min 3) 150 min 4) 79.68 min
3.The rate law of a reaction is r1= k[A]a[B]b.If the concentration of A is doubled and that of B
r2
is halved,the new rate is r2,then what is the ratio of ?
r1
1
1) a- b 2) (a+ b) 3) a+b 4)2(a−b)
2
4.If the time required for the completion of 75% of a first order reaction is 30 minutes.The
time required for the completion of 93.75% of the reaaction in minutes is
1) 45 2)30 3)60 4)75
5. t1/4 can be taken as the time taken for the concentration of a reactant to drop to 3/4 th
of its initial value. If the rate constant for a first order reaction is k, the t 1/4 can be written
as
1) 0.75/k 2) 0.69/k 3) 0.29/k 4) 0.10/k

6. In a zero order reaction for every 10° rise in temperature,the rate is doubled.If the
temperature is increases from 10° C to 100° C .The rate of the reaction will become
1) 256 times 2) 512 times 3) 64 times 4) 128 times
7.For the reaction ,2A →B + 3C,
−d [ A ] d [B] d [C ]
If = K1[A]2 ; = K2[A]2 ; = K3[A]2
dt dt dt
Then,
1) K1 = K2 =K3 2) 2K1 = K2 =K3
K1 K3
2) 4K1 = K2 = 3K3 4) = K2 =
2 3
8.For the reaction of NO with Br2 to form NOBr

NO(g) + Br2 (g) NOBr2 (g)

NOBr2(g) + NO → 2NOBr(g)
 The order with respect to NO(g) is

1) 1 2) 0 3) 3 4) 2

9.Rate constant for a chemical reaction takes place at 500 K is expressed as K = A.e -1000.The activation
energy of the reaction is

(1) 100 cal/mol (2) 1000 Kcal /mol

(3) 104 kcal/mol (4) 106 kcal/mol

10.In the reaction 2SO2 + O2 →2SO3,The rate of appearance of SO3 is 4 x 10-4 M/s,the rate of
disappearance of O2 is

(1) 1.0 x 10-4 M/s (2) 2.0 x 10-4 M/s

(3) 6.0 x 10-4 M/s (4) 4.0 x 10-4 M/s

11.The rate constant,activation energy and Arrhenius parameter of a chemical reaction at 25°C are
X,10 X KJ /mol and 2X S-1.The value of rate constant as T→ꚙ is

(1) X S-1 (2) 2 X S-1 (3) ꚙ (4) 10 X S-1

12.For the reaction X→Y ,the activation energy for forward and backward reaction are 15 and 9
KJ /mol respectively and energy of X is 10 KJ/mol.Which of the following statement is incorrect?

(1) Threshold energy of the reaction is 25 KJ/mol

(2) Heat of reaction is 6 KJ/mol

(3) Energy of Y is 10 KJ/mol

(4) The reaction is endothermic

13.Which of the following elementary steps is bimolecular?

(1) 2A + B → A2B (2) A2 → 2A

(3) 2A → A2 (4) A +2B → C

14.

(1) Rate = K [A]2[B] (2) Rate = K[B]2

(3) Rate = K [A][B]2 (4) Rate = K [A][B]

15. A catalyst lowers the activation energy of a reaction from 20 KJ/mol to 10 KJ/mol.The
temperature at which uncatalyzed reaction will have same rate as that of catalysed at 27°C is

(1) 327°C (2) 283°C (3) 445°C (4)600°C