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PLASMA TECHNOLOGY AND ITS APPLICATIONS IN THE

CURRENT ENVIRONMENTAL SCENARIO

Receipt No: 287

Team Members:

Abhay Amin

Parashar Thanki

College:

Nirma University

Phone Numbers:

Abhay (9974408270)

Parashar (9925664286)

Email IDs:

Abhay (abhay.amin@gmail.com)

Parashar (parashar.me@gmail.com)

I
INDEX

1. Introduction

2. The Problem: Global Waste Management and Sources of Energy

3. The Answer

4. Introduction To Plasma Technology

5. Plasma Technology In Waste Management

6. Plasma-Arc Waste Disposal And Its Working

7. The Residue

8. Applications

9. Comparison and Conclusion

10. Bibliography

II
LIST OF FIGURES

1. Block Diagram of Plasma Waste Converter

2. Plasma Torch

3. Plasma Furnace

4. Air Cooled Slag

5. Rock Wool

6. Tile Product

7. Roadbed Aggregate

8. Roofing Granules

9. Rock Wool

10. Landfill Remediation Technique

III
INTRODUCTION deep wells has apparently lead to explosions
and minor earthquakes.
This paper aims at highlighting the uses of
plasma technology in the current
environmental scenario, where we are facing
problems of waste disposal and alternate Another major problem that we face today is
fuels. Here is where, the question arises: the ever-increasing usage of conventional
why plasma technology? So, let us first take sources of energy. The earth has a limited
a look at the problems that we face in the supply of fossil fuels. Hence, it should not
world today, and then we will look at how be the case that when we run out of these
plasma technology provides us with an conventional sources, the progress of the
effective solution for the same. human race stops suddenly. Even the
development in the usage of non-
conventional sources of energy is not
THE PROBLEM sufficient to solve this problem.
In today’s world, we humans are developing
at an astounding rate. Be it in the industrial THE ANSWER
sector or in the financial sector, our growth
knows no bounds. In our quest for maximum However, we believe that we have the
benefit at minimum cost, we have focused solution to this problem - Plasma
only on the material aspects of things Technology. We can make use of plasma arc
without caring about the future implications. disposal methods that uses plasma
technology. So, let us take a look at how
plasma technology establishes a link
The disposal of garbage waste is a problem between waste management and a source of
that grows with industrialization and alternative fuel.
population. We have always needed a
method of disposing our wastes. According
to ResearchAndMarkets.com, the amount of INTRODUCTION TO PLASMA
municipal solid waste (MSW) generated
worldwide in 2006 was 2.02 billion tons. Plasma is essentially an ionized gas. It is
widely touted as the fourth state of matter.
Conventional methods of waste disposal do Plasma is a gas with free-roaming electrons
not address the serious issue of that carries a current and generates a
contamination, as the harmful residues left magnetic field.
behind cannot be treated further.
Incineration, for example, generates gaseous Plasma can be produced by applying a high
pollutants that are harmful for the potential across two electrodes in the
environment. Also, pumping of wastes into presence of a gas. This ionizes the gas
molecules. On Earth, we can see natural
displays of plasma fields in lightning.
IV
Plasma has an endless number of but it also produces byproducts that are
applications. It finds its applications in fields valuable commodities themselves.
ranging from etching grooves on computer
chips, to improving the strength of materials. Plasma technology utilizes the high
However, looking at the present temperatures of plasma. In a plasma arc
environmental scenario, where waste waste disposal system, a plasma torch is
management and sources of alternate fuel applied to the wastes. The temperatures
are the main concern, plasma comes to the generated by a plasma torch can be hotter
rescue.

PLASMA TECHNOLOGY IN WASTE than the surface of the sun (more than 6000
MANAGEMENT degree Celsius).

Looking at waste management techniques, At these temperatures, waste does not stand
conventional methods of waste disposal do a chance. The molecules break down in a
not address the serious issue of process called molecular dissociation. This
contamination, as the harmful residues left is because, on exposure to the intense energy
behind cannot be treated further. generated by the heat of a plasma torch, the
Incineration, for example, has serious issues molecular bonds become excited and break
such as the emission of gaseous pollutants. It apart. All that remains are the elemental
also produces dioxins, which may have components of the molecules. With carbon
serious environmental consequences in the disulphide, for example, we end up with
general vicinity of the incinerator. atoms of carbon and sulphur.
Incineration also leaves behind fly ash,
which can be hazardous and has to be
further treated.

Besides, none of the presently available PLASMA ARC WASTE DISPOSAL


waste disposal methods can generate AND ITS WORKING
commercially useful byproducts. Plasma arc
waste disposal is unique in that it not only Let us now take a look at the working of a
gets rid of garbage and generates electricity, plasma arc waste disposal plant, also known
as a plasma waste converter. Given below is
the basic block diagram of a plant.

V
Block Diagram Of Plasma Waste Converter

VI
The above figure explains the working of a
The plant has the following basic plasma torch in a simple manner.
components:
1. Pre-treatment processes. The waste now passes into the furnace,
2. Gas/Air supply where the actual pyrolysis takes place. The
3. Power supply. furnace has plasma torches present inside,
3. Plasma torch. which break down the matter. The torches
5. Furnace. are placed in the lower half of the furnace.
6. Slag drain. The furnace is airtight, that is it does not
7. Gas vent. allow any hot gases produced to leave the
furnace. The furnace is lined with a
In order to feed garbage into the waste refractory material in order to be able to
converter, a conveyer system is used. withstand the intense heat.
Although a plasma torch can break down
wastes without any pre-treatment, in order to The furnace also has a drainage system to
make the plant more efficient, we can pass remove the slag as it gets collected at the
the wastes through a grinding mechanism. bottom of the furnace. It also has a vent
system to remove the synthetic gases
(syngas) that is produced.

The converter has an electric power supply,


which is used to supply the potential
required for the plasma torch. There is also a
gas supply, which supplies the medium
required to be ionized for creating the
plasma. We can also use air instead of
another gas. A plasma torch can generate
temperatures from 4000 to 7000 degree
Celsius. It operates at power levels of
100kW to 200MW.

A Plasma Furnace

This is the basic working of the plasma


waste converter plant. Let us now take a
look at the process that the slag and syngas
undergo for further treatment.

The amount of gas and slag produced


Plasma Torch depend on the type of waste. If the waste has
a lot of carbon-based material, like bio- The solid byproduct obtained from this
wastes, plastics and MSW then more syngas process is the slag. The main benefit of
is generated. Waste with inorganic materials plasma arc waste disposal lies in the fact that
will not generate as much syngas. Instead, it weight of the slag is about 20% of the
will get vitrified and produces more slag. original waste and the volume of the slag is
about 5% of the original waste. The slag can
The slag runs out of the bottom of the take different forms based on how we cool
furnace into a pool of water. The slag is it.
converted into granular pieces that are
completely inert and can be used as an If slag is cooled using air, we get a black,
aggregate or shaped into paving bricks or glassy material that can be used in concrete
other construction materials. or asphalt. If we blow compressed air
through the molten slag, we get rock wool. It
The syngas leaves the furnace at a is also a very efficient insulating material,
temperature of nearly 1100 degree Celsius, about twice as effective as fiber glass. The
and goes to a heat recovery boiler. It reduces current cost of rock wool maybe reduced by
the temperature of syngas to about 200 one-tenth, as it is produced as a byproduct
degree Celsius. The steam thus generated is rather than obtaining it by a specific
sent to the power plant to generate manufacturing process as it is done
electricity by running a steam turbine. currently.
Syngas is a gas mixture that consists of
varying amounts of CO and H2. It is
produced by the following chemical
reactions:

C + H2O → CO + H2 - (1)

C + O2 → CO2 - (2)

CO2 + C → 2CO - (3)


Air-cooled slag, a black glassy material
The syngas produced can be used for many
purposes. Firstly, the syngas can be used
directly as a fuel gas for combustion
purposes. It can also be used in a gas turbine
to generate electricity. This electricity can
be used within the plant to meet its own
energy requirements and the excess can be
sold back to the power grid.

THE RESIDUE
unlimited supply of residue obtained as a
byproduct. This residue can be further used
in a wide number of applications. Hence, the
disposal of residue will definitely not cause
a major problem.

APPLICATIONS OF RESIDUE

The vitrified sediment obtained from the


slag can be re-used for a variety of
applications:
Rock Wool
1. Architectural Tile Manufacture.
Hence, we can clearly see that plasma arc
technology is ideally suited for waste 2. Rock Wool Insulation.
treatment purposes. This is because of the
following reasons: 3. Roadbed Aggregate (used for paving
roads and pavements).
1. It breaks down the wastes into their
elemental constituents instead of smaller 4. Roofing Granules.
compounds which may be hazardous.

2. Any kind of waste can be broken down by


this method.

3. Even medical or chemically contaminated


or hazardous waste can be treated in a
plasma waste converter.
Tile Product
4. It provides us with a possible solution to
the disposal of asbestos containing material.

5. Organic materials are gasified and melted.


Most suitable method for plastics, as its only
byproduct is fuel gas.

6. Inorganic materials are melted and


immobilized in a rock-like vitrified mass Roadbed Aggregate
which is virtually unleachable, as mentioned
above in the case of rock wool and the
black, glassy material.

As we have a solution for a wide range of


waste materials, we have a virtually
Roofing Granules Rock Wool

LANDFILL REMEDIATION CONCEPT

This is the in-situ application of the plasma-


arc disposal method. In this concept, the
furnace housing the plasma torch is built at
the landfill itself. The furnace is passed into
the heap of landfill by making a passage
through the landfill.
Landfill Remediation Technique

As we can see from the figure, the plasma be 100% stored in the gas tankers above the
furnace is lowered into the landfill. Another landfill.
similar hole is drilled parallel to the hole for
the furnace. Once the process of plasma arc The method is also environmentally safe as
disposal starts, the formation of syngas all microorganisms are killed. The slag that
begins. This syngas flows up through the is produced in this method is virtually
adjacent pipe and can be stored in gas unleachable and the elements in the slag will
tankers. never enter the earth’s surface or the
atmosphere. The slag can be transported to
This method is commercially very viable, as the desired plant for further processing.
it totally cuts the costs of building a full-
scale operational plant. The furnace can be COMPARISON AND CONCLUSION
installed at the site of the landfill. The We have seen that the use of plasma
syngas produced is also not wasted as it can technology for waste management has
proved to be a very effective solution for our
current needs of waste disposal and sources incineration in any form. In case of
of energy. It has unique treatment incineration, the wastes are subjected to
capabilities that are unequalled by any of the combustion, as a result of which gaseous
existing technologies. pollutants are emitted. However, the process
taking place in a plasma converter is
For example, 74% of the waste in the US is pyrolysis, i.e. breaking down of the wastes
dumped in landfills. As stated before, over 2 in the presence of heat. Incineration also
billion tons of waste was produced in the emit varying levels of heavy metals like
world in 2006. This number is estimated to arsenic, mercury, lead, etc. These metals can
be toxic even in minute quantities.
increase by 37% by the year 2011. If we However, plasma technology faces no such
continue to make use of landfills, then we problems, as it breaks down the elements
will have to make use of more and more into their elemental constituents, and the in-
land. This will put the amount of available organic materials are converted into slag,
land under serious threat, as we require more which is highly unleachable, and is
and more land these days for agriculture and guaranteed to be safe.
housing purposes, in order to meet the
demands of the ever-increasing population. Hence, in conclusion, we would like to
stress that plasma technology IS the solution
Another area where plasma technology may to our environmental problems. In
come to the forefront is that the plasma comparison to conventional methods, this
furnace can be used for in-situ vitrification method is not only highly efficient for waste
of contaminated soils. This method is also disposal but also provides us with an
highly beneficial as the contaminating alternate source of energy, solving most of
agents will be removed and slag and syngas our problems.
will be obtained as byproducts of the same
process, thereby making it environmentally
as well as commercially successful.

We can clearly see that none of the existing


technologies have any such applications,
where the byproducts are commodities of
such commercial value. At the same time,
none of the current methods have the
efficiency that has been demonstrated by
plasma technology, as such a high
temperature cannot be created in those
technologies.

The main point to be understood here is that


plasma-arc disposal method is NOT
3. Hazardous Waste Incineration and Human
BIBLIOGRAPHY Health - by C. C. Travis, S. Chrystal Cook
1. Database of Tetronics Inc. 4. Google - for small bits of information.
2. Environmental Engineering - by Gerard
Kiely

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