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UNIT I
WASTE WATER TREATMENT AN OVERVIEW
Part A
1. Define Waste Water
Wastewater (or waste water) is any water that has been affected by human
use. Wastewater is used water from any combination of domestic, industrial, commercial or
agricultural activities, surface runoff or storm water, and any sewer inflow or sewer infiltration.
Wastewater comes in three main types namely Blackwater, Graywater and Yellow water. This
is wastewater that originates from toilet fixtures, dishwashers, and food preparation sinks. It is
made up of all the things that you can imagine going down the toilets, bath and sink drains.
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
8. Define Biosolids
Biosolids may be defined as organic wastewater solids that can be reused after
suitable sewage sludge treatment processes leading to sludge stabilization such as anaerobic
digestion and composting. Alternatively, the biosolids definition may be restricted by local
regulations to wastewater solids only after those solids have completed a specified treatment
sequence and/or have concentrations of pathogens and toxic chemicals below specified levels.
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
• Nitrites (NO2-)
• Nitrates (NO3-)
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St.Joseph’s College of Engineering Department of Chemical Engineering
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
2. Pretreatment is needed when dealing with toxic wastes, and the effects of nitrifying
organisms must be reduced.
3. Only the biodegradable organics are measured.
4. The test does not have stoichiometric validity after the soluble organic matter present in
solution has been used.
5. The relatively long period of time required to obtain test results
PART B
1. Discuss WWT process in detail.
2. Explain Activated Sludge Process (ASP).
3. Discuss in detail about trickling filter.
4. Discuss in detail about Rotating Biological filter.
5. Explain Wastewater regulations in detail.
6. What are the constituents/characteristics of WWT?
7. Explain BOD in detail.
8. Explain modeling of BOD reaction in detail.
9. Discuss microbial growth curve in detail.
10. Determine the concentration of total solids, total volatile solids, suspended solids, volatile
suspended solids, total dissolved solids and total volatile dissolved solids. Sample volume is 50
mL.
UNIT II
PROCESS ANALYSIS AND SELECTION
1. Write notes on packed bed reactors.
Packed-Bed reactors are filled with some type of packing material such as rock, slag,
ceramic etc. Can be operated in either downflow or upflow mode. Packing can be continuous or
in stages. Used in non-submerged and submerged trickling filter biological treatment units, depth
filtration, air stripping and natural treatment systems.
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
3. Infiltration/inflow (I/I): Infiltration is extraneous water that enters the collection system
through leaking joints, cracks, breaks, or pores. Inflow is storm water that enters the
collection system from storm drain connections (catch basin), roof ladders, or though
access port (manhole) covers.
4. Storm water: Runoff resulting from rainfall and snowmelt.
• Draw a system or control volume boundary to define the limits over which the mass balance
is to be applied.
• List all the pertinent data and assumptions that will be used in the schematic diagram.
• List all the rate expressions for the biological or chemical reactions that occur within the
control volume.
• Select a convenient basis on which the numerical calculations will be based.
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
Batch reactors
Nature of wastewater
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
2. The liquid within the control volume is not subject to evaporation (constant
volume)
3. The liquid within the control volume is mixed completely.
4. A chemical reaction involving a reactant A is occurring within the reactor.
5. The rate of change in the concentration of the reactant A that is occurring within
the control volume is governed by a first-order reaction.
Process applicability
Climatic constraints
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CH8004 Waste Water Treatment 2019-2020
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
PART B
1. Discuss in detail about variations in wastewater flowrates.
2. What are the various reactors used in wastewater treatment.
3. Discuss in detail about modeling ideal flow in reactors.
4. Discuss in detail about modeling in plug flow reactors.
5. Explain modeling non ideal flow in reactors.
6. Explain about plug flow in axial dispersion.
7. Discuss about complete mix reactors in series.
8. Explain about process selection in detail.
9. What are the factors that should be considered in planning pilot-plant studies for wastewater
treatment.
10. What are the reliability considerations in process selection.
UNIT III
CHEMICAL UNIT PROCESSES
PART A
1. Define Chemical Precipitation
Chemical precipitation, formation of a separable solid substance from a solution, either
by converting the substance into an insoluble form or by changing the composition of the solvent
to diminish the solubility of the substance in it. Chemical precipitation helps in removal of
phosphorus and suspended solids in primary sedimentation facilities used for physical-chemical
treatment. Also heavy metals removal.
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
Particle-particle interactions
Particle-solvent interactions
Alum,
Aluminium chloride,
Ferric chloride,
Ferric sulfate,
Ferrous sulfate,
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
17. What happens when alum is added to waste water? Give the reaction.
When alum is added to wastewater containing calcium and magnesium bicarbonates
alkalinity, the reaction that occurs may be illustrated as follows:
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
PART B
1. What is the role of unit process in wastewater treatment?
2. Explain Chemical Coagulation in detail.
3. What is the role of chemical precipitation?
4. Discuss chemical oxidation in detail.
5. Discuss about Chemical Neutralization.
6. Explain about half reaction potential in detail.
7. What are the strategies for phosphorous removal?
8. Explain particle particle interaction in detail.
9. Discuss in detail about surface properties including electrical characteristics
10. Discuss about Scaling control and Stabilization.
UNIT IV
BIOLOGICAL TREATMENT
1. Define Aerobic processes
Aerobic treatment is a biological process that uses oxygen to break down organic matter
and remove other pollutants like nitrogen and phosphorus. It converts the organic matter into
carbon dioxide and new biomass.
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
6. Define Nitrification.
Nitrification is the biological oxidation of ammonia or ammonium to nitrite followed by
the oxidation of the nitrite to nitrate. The transformation of ammonia to nitrite is usually the rate
limiting step of nitrification. Nitrification is an important step in the nitrogen cycle in soil.
Nitrification is an aerobic process performed by small groups of autotrophic bacteria and archaea.
7. Define Denitrification
Denitrification is the last step in the nitrogen cycle where the reduction of soil nitrate to
nitrogen-containing gases, such as nitric oxide, nitrous oxide, and nitrogen gas, takes place.
Specifically, soil microbes utilize nitrate as the terminal electron acceptor to form nitrite in
a process called reduction.
8. Define Stabilization
The biological process by which the organic matter in the sludge produced from the
primary settling and biological treatment of wastewater is stabilized, usually by conversion to
gases and cell tissue.
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CH8004 Waste Water Treatment 2019-2020
The microorganisms responsible for the conversion of organic material or nutrients are
attached to an inert packing material. The organic material and nutrients are removed from the
wastewater flowing past the attached growth also known as a biofilm.
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
17. What is the importance of exponential growth phase in bacterial growth curve?
During the exponential growth phase, bacterial cells are multiplying at their maximum rate,
as there are no limitations due to substrate or nutrients. The biomass growth curve increases
exponentially during this period. With unlimited substrate and nutrients, the only factor the rate of
exponential growth is temperature.
g biomass produced
Biomass Yield
g substrate utilized
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
PART B
1. Explain Activated Sludge process in detail.
2. Explain attached growth process in detail with a neat diagram.
3. Explain in detail about bacterial growth curve
4. Explain in detail about RBC (Rotating Biological Contractors)
5. Explain about treatment process and treatment functions in detail.
6. Discuss the role of microorganism in waste water treatment.
7. Briefly discuss about wastewater treatment plant.
8. Discuss about microbial metabolism
9. Discuss about nutrient requirements.
10. Discuss the current scenario of global waste water generation and suggest some measures for
treatment.
UNIT V
ADVANCED WASTE WATER TREATMENT
PART A
1. What is the need for AWWT?
Additional treatment required to remove suspended, colloidal and dissolved constituents
remaining after primary and secondary treatments.
To remove organic matter and total suspended solids beyond what can be accomplished
by secondary treatment process.
The need to remove residual total suspended solids to condition the treated waste water
for more effective disinfection
To meet more stringent discharge and reuse requirement
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
5. What are the various steps involved in the study of membrane filtration?
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
When the headloss becomes very high, the filter medium begins to clog and filter
medium must be washed. This process is termed as backwash.
This is accomplished by reversing the flow through the filter.
A sufficient flow of back water is supplied until the granular medium is fluidized
causing the particles to abrade each other.
18. What are the steps that takes place during filtration?
The following steps take place during filtration
STEP 1: The transport of the particles to the surface where they will be removed.
STEP 2: The removal of particles by one or more of the following mechanisms.
a) Straining
b) Impaction
c) Interception
d) Adhesion
e) Sedimentation
f) Chemical or physical adsorption.
g) Biological growth
Grain size is the principle filter medium characteristic that affects filtration.
If the filter medium is too small much of the driving force will be wasted in
overcoming the frictional resistance.
If it’s too large many of the large particles in the influent will pass directly through
the bed.
The optimum size is found using the size distribution curve, this is obtained using
the sieve analysis.
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St.Joseph’s College of Engineering Department of Chemical Engineering
CH8004 Waste Water Treatment 2019-2020
The filter medium is supported on a gravel layer, which in turn rests on an under drain
system.
The water to be filtered enters through an inlet channel, and filtered water is collected
in a under drain system.
The filtered water is disinfection, before sending into the atmosphere.
The filtered water can also be reused.
PART B
1. Discuss in detail about depth filtration.
2. Explain Surface Filtration.
3. Briefly explain ion exchange.
4. Discuss in detail the application of ion exchange.
5. Discuss Advanced Oxidation Process.
6. Discuss about the Classification of technologies Removal of Colloids and suspended particles.
7. Discuss about particle removal mechanism in depth filtration
8. Discuss about membrane filtration
9. What is the chemistry behind ion exchange?
10. Explain filtration process in detail with a neat sketch.
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St.Joseph’s College of Engineering Department of Chemical Engineering