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Nr. crt.

t, °C k*106, min-1 T, K 1/T, K-1 ln k x^2 x*y


1 20 1.65 293.15 0.003411 0.500775 1.163644E-05 0.0017082561
2 40 6.40 313.15 0.003193 1.856298 1.019753E-05 0.0059278237
3 60 19.00 333.15 0.003002 2.944439 9.009908E-06 0.0088381779
4 80 44.00 353.15 0.002832 3.78419 8.018287E-06 0.0107155306
5 90 74.00 363.15 0.002754 4.304065 7.58277E-06 0.0118520311
0.015192 13.38977 4.644494E-05 0.0390418195

Arrhenius
D=
5

4 f(x) = − 5692.92639961157 x + 19.9748543768142 Da=


R² = 0.9984001180987
ln k

3 Db=

2
a=Da/D=

1 b=Db/D=

R squared - no sense to use


0
0.0025 0.0027 0.0029 0.0031 0.0033 0.0035
But, in order to find the true A
1/T

k0=exp(a)
Ea=-b*R
5 0.0151915726
0.0151916 4.644494E-05

13.389767 0.0151915726
0.0390418 4.644494E-05

5 13.389766985
0.0151916 0.0390418195

19.974854 compare the value with that given by trendline…

-5692.9264 compare the value with that given by trendline…

R squared - no sense to use the formula since the value is given by trendline…

But, in order to find the true Arrhenius equation, you have some calculus left: k = k0 * exp (-Ea/RT)

4.73E+08 ln k = ln k0 - Ea/RT
47308.218
Nr. T, °C k×104, h-1 T, K 1/T, K-1 k, h-1 ln k ln kh
1 50 1.08 323.15 0.003095 0.000108 -9.133379 0.076961
2 70.1 7.34 343.25 0.002913 0.000734 -7.217002 1.993339
3 89.4 45.4 362.55 0.002758 0.00454 -5.394828 3.815512
4 101 138 374.15 0.002673 0.0138 -4.283087 4.927254

0
0.00265 0.0027 0.00275
k0 = 2.54778E+15 -1

-2

-3

ln k
-4
f(x) = − 11459.3
Chart Title -5
R² = 0.9983467
6 -6

-7
5
f(x) = − 11459.3512162543 x + 35.4736639174895 -8
R² = 0.998346798178034
4 -9

-10
3

0
0.00265 0.0027 0.00275 0.0028 0.00285 0.0029 0.00295 0.003 0.00305 0.0031 0.00315
0
0.00265 0.0027 0.00275 0.0028 0.00285 0.0029 0.00295 0.003 0.00305 0.0031 0.00315
-1

-2

-3
ln k

-4

-5 f(x) = − 11459.3512162543 x + 26.2633235455133


R² = 0.998346798178035
-6

-7

-8

-9
1/T, K-1
-10

k0 = 2.5461E+11

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