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Characteristics of Hydrocarbons
Drilling
PETROLEUM
In its most general sense, the term “Petroleum” refers to the whole spectrum of Hydrocarbons
–
gaseous, liquid and solid.
In ALIPHATIC compounds, the atoms are arranged in the chain to give an ‘OPEN’ structure. The open
chain can be either ‘Straight’ or ‘Branched’.
2. CYCLIC COMPOUNDS
The Alkanes are saturated hydrocarbon compounds in which each carbon atom is bonded to 4 other
atoms–(other carbons or hydrocarbons).
They have only ‘Single carbon – carbon bonds’ (and single hydrogen bonds), in their molecules.
Methane CH 4 H C H
H
H H
E thane C 2H 6 H C C H
H H
H H H
Propane C 3H 8 H C C C H
H H H
H H H H
B utane C 4H 1 0 H C C C C H
H H H H
H H H H H
Pentane C 5H 1 2 H C C C C C H
H H H H H
H H H H H H
Hexane C 6H 1 4 H C C C C C C H
H H H H H H
H H H H H H H
Heptane C 7H 1 6 H C C C C C C C H
H H H H H H H
SOME PHYSICAL PROPERTIES OF N-ALKANES
Name Number of Formula State at Boiling
Carbon N.T.P. Point (0C)
Atoms
Ethane 2 C 2H 6 Gas 89
Propane 3 C 3H 8 Gas 42
These branch chains are referred to as ‘ISOMERS’ (usually ‘Iso… for short). Isomers are saturated, single
Bond compounds. Following are some examples of Isomers.
H H H H H H H H
H H H H C
H C C C C C H H C C H
H C C C C H
H H H H H H H
H H H H
H C H
Normal Butane n-C4H10 Normal-Pentane n-C5H12
H
H Iso-Butane i-C4H10
H H H H
H C H
H H
H C C C C H
H C C C H
H H H
H C H H H
H C H
H H
Iso-Pentane i-C5H12 Iso-Pentane i-C5H12
ALIPHATIC HC’s - CYCLO ALKANES
These are formed by the ‘closing’ of the carbon chain. Each ‘C’ atom uses TWO electrons to form bonds
with two other ‘C’ atoms. The two remaining electrons of each ‘C’, can bond with ‘H’atoms to give a
Saturated molecule. The general formula is ( CnH2n).
C C
Cyclopropane (C3H6) C
Cyclopentane (C5H10)
Cyclohexane (C6H12)
ALIPHATIC HC’s – ALKENES
The alkenes are unsaturated hydrocarbon compounds containing a carbon-carbon ‘Double Bond’.
The general formula for Alkenes is (CnH2n) where ‘n’represents a number equal to the number of ‘C’atoms.
The simplest alkene is called ‘ETHENE’ or ‘ETHELENE’. Its chemical formula is (C2H4), and its structural
formula is:
H H
H C C H
ALIPHATIC HC’s – ALKENES
FORMUL A OF SOME A L K E NE S
Compound Name Molecular Formula Structural Formula
H H
E thene C 2H 4
H C C H
H H H
Propene C 3H 6 H C C C H
H
H H H H
B utene C 4H 8 H C C C C H
H H
H H H H H
Pentene C 5H 1 0 H C C C C C H
H H H
H H H H H H
Hexene C 6H 1 2 H C C C C C C H
H H H H
H H H H H H H
Heptene C 7H 1 4 H C C C C C C C H
H H H H H
ALIPHATIC HC’s – ALKENES
1. Alkenes Combus on C2H4 + 3O2 2CO2 + 2H2O + Heat
2. Alkenes Hydrogena on: Alkenes can react with hydrogen in the presence of nickel or pla num that
act as a catalyst. A catalyst is a substance that speeds up a chemical reac on. Hydrogena on
converts alkenes to alkanes.
Pt
3. Alkenes Polymeriza on: is the joining together of a large number of small molecules to form one
large molecule. The product of the reac on is called a polymer. Gaseous alkenes can polymerize
when exposed to high temperature and pressure to form long chains of carbon atoms. When ethene
is heated under a pressure of 100 atmospheres in the presence of oxygen, its molecules join together
to form polyethene.
ALIPHATIC HC’s – ALKYNES
The alkynes are unsaturated hydrocarbons with a carbon-carbon ‘Triple Bond’in their molecules.
The alkynes are given their name by dropping the ‘-ane’ ending of its corresponding alkane, and replacing
it with ‘-yne’.
The simplest alkyne is called ‘ETHYNE’ or ‘ACETYLENE’. Its molecular formula is (C2 H 2 ), and the structural
formula is:
H C C H
1. Combus on of Alkynes is: C2H2 + 5/2O2 2CO2 + H2O + Heat
2. The reac on takes place in two steps. In the first step ethene is produced, and in the second
step ethene is hydrogenated to ethane with the help of the catalyst. The net reac on is:
Pt
C2H2 + 2H2 CH3 CH3
ALIPHATIC HC’s – ALKYNES
Compound Name Molecular Formula Structural Formula
H C C H
E thyne C 2H 2
H
Propyne C 3H 4 H C C C H
H
H H
B utyne C 4H 6 H C C C C H
H H
H H H
Pentyne C 5H 8 H C C C C C H
H H H
H H H H
Hexyne C 6H 1 0 H C C C C C C H
H H H H
ALIPHATIC HC’s - ALKADIENES
The alkadienes are unsaturated hydrocarbons with TWO ‘Double Bonds’ in their molecules (have
two – ene groups – hence the ‘- diene’ ending).
The posi ons of the two double bonds are specified by numbers, and the general formula is (CnH2n-2).
The two most important alkadienes are:
Structural Formula
C
UNSATURATED CYCLIC COMPOUNDS
Cyclic compounds can also be unsaturated by containing a double bond in the ‘Ring Chain’. Their
general formula is (CnH2n-2).
The most important group of cyclic unsaturated hydrocarbons is the ‘AROMATIC’ series.
The simplest aroma c compound is BENZENE (C6H6). All other aroma cs are based on the Benzene
Ring molecule which has alterna ng single & double bonds within the carbon ring chain. Due to this,
each ‘C’ atom has used up to 3 bonds leaving only a single bond to a ach to another atom.
AROMATIC HYDROCARBONS
Aroma c hydrocarbons contain one or more aroma c rings
Aroma c rings are cons tuted of six carbon atoms bound with alterna ng single and double bonds.
This par cular structure is characterized by high chemical stability.
The most simple aroma c hydrocarbon is benzene
Benzene, Toluene, Ethylbenzene and Xylenes are commonly indicated as BTEX
Benzene
Tolue (C6H6)
ne
BENZENE (C6H6)
The double bonding in the molecule is not fixed. They are constantly changing posi on and maintain
the alterna ng arrangement. This phenomenon is called (Resonance).
Water (0.1-2%)
Crude oils vary in color, from clear to tar-black, and in viscosity, from water to almost solid.
• Dry gas wells ( as non-associated gas). Contains lower concentra ons of C5+ than the associated
gas.
From the usage point of view, natural gas is classified as SWEET or SOUR.
Relative density is the density of the system divided by that of reference substance at specified
conditions. Relative density is the new SI metric terms replacing specific gravity. The reference for liquid
is water; for gas it is air.
уL = (ρ liquid)/ (ρ water)
уL = 141.50/(131.5+°API)
MAIN HYDROCARBONS CHARACTERISTICS AND PROPERTIES
Viscosity
Viscosity is a measure of a fluid’s resistance to flow.
It describes the internal fric on of a moving fluid.
The coefficient of viscosity (normally shortened to dynamic viscosity) is a shear force per unit area.
The poise was the original unit; 1 poise= 1 (dyne -sec)/cm2. For petroleum systems the cen poises
(cp) is the most convenient unit. It may be expressed in force units or equivalent mass units. In SI
metric the Pa s is the preferred unit.
Hea ng Value: Amount of energy released when a fuel is burned completely in a steady-flow
process and the products are returned to the state of the reactants.
The hea ng value is dependent on the phase of water/steam in the combus on products. If H2O
is in liquid form, hea ng value is called HHV (Higher Hea ng Value). When H2O is in vapour
form, hea ng value is called LHV (Lower Hea ng Value).
MAIN HYDROCARBONS CHARACTERISTICS AND PROPERTIES
Boiling Point
the temperature at which the vapour pressure of a liquid is equal to the external pressure.
vapour pressure of a liquid is the pressure exerted by its vapour when the liquid and vapour are in
dynamic equilibrium.
Vapour pressure and boiling point have an intimate relationship. The boiling point is the temperature at
which the vapour pressure of the liquid equals the external pressure.
MAIN HYDROCARBONS CHARACTERISTICS AND PROPERTIES
H/C Dew Point
The condensa on temperature of heavy hydrocarbon components in gas
WELL AND WELL TYPES
A well is a hole drilled in the earth from which petroleum flows or is pumped
Oil
Oil and Natural Gas
Only Natural Gas
WELL AND WELL TYPES
Another way to classify oil wells is by their purpose in contribu ng to the development
of a resource. They can be characterized as:
Explora on wells
Appraisal wells
Wildcat wells
Produc on wells
WELL AND WELL TYPES
Oil Producers
Gas Producers
Water Injectors
Gas Injectors
Aquifer Producers
WELL AND WELL TYPES
Well Schema c
OIL & GAS WELL LIFE CYCLE
An oil well is a general term for any boring through the Earth's surface that is
designed to find and acquire Oil and Gas or hydrocarbons. Usually some natural gas
is produced along with the oil. A well that is designed to produce mainly or only gas
is termed a gas well. The crea on and life cycle of a well can be divided up into five
segments:
• Planning
• Drilling
• Comple on
• Produc on
• Abandonment.
OIL & GAS WELL LIFE CYCLE
Planning
- Geologists are the ones who are responsible for finding oil. Their task is to find the right condi ons for
an oil trap - the right source rock, reservoir rock and entrapment.
- Many years ago, geologists interpreted surface features, surface rock and soil types, and perhaps some
small core samples obtained by shallow drilling.
- Modern oil geologists examine surface rocks and terrain, with the addi onal help of satellite images.
- However, they also use a variety of other methods to find oil. They use sensi ve gravity meters to
measure ny changes in the Earth's gravita onal field that could indicate flowing oil, as well as sensi ve
magnetometers to measure ny changes in the Earth's magne c field caused by flowing oil.
- They even detect the smell of hydrocarbons using sensi ve electronic noses called sniffers.
- Finally and most commonly, they use seismology, crea ng shock waves that pass through hidden rock
layers and interpre ng those waves that are reflected back to the surface.
OIL & GAS WELL LIFE CYCLE
Planning
- Seismologists interpret the readings for signs of oil and gas traps. Once geologists find a
prospec ve oil strike, they mark the loca on using GPS coordinates on land or by marker
buoys on water.
- Once the site has been selected, scien sts survey the area to determine its boundaries,
and conduct environmental impact studies if necessary.
- A er all the legal issues are se led, the crew goes about preparing the land for drilling.
OIL & GAS WELL LIFE CYCLE
• Once the land has been prepared, several holes are dug to make way for the rig and the main hole.
• A rectangular pit called a cellar is dug around the loca on of the actual drilling hole.
• The cellar provides a work space around the hole for the workers and drilling accessories.
• The crew then begins drilling the main hole.
• The first part of the hole is larger and shallower than the main por on, and is lined with a large-
diameter conductor pipe.
• The well is created by drilling a hole 5 to 50 inches (127.0 mm to 914.4 mm) in diameter into the earth
with a drilling rig that rotates a drill string with a bit a ached.
• A er the hole is drilled, sec ons of steel pipe (casing), slightly smaller in diameter than the borehole,
are placed in the hole.
• Cement is placed between the outside of the casing and the borehole.
OIL & GAS WELL LIFE CYCLE
• The casing provides structural integrity to the newly drilled wellbore, in addi on to isola ng
poten ally dangerous high pressure zones from each other and from the surface.
• With these zones safely isolated and the forma on protected by the casing, the well can be drilled
deeper (into poten ally more-unstable and violent forma ons) with a smaller bit, and also cased
with a smaller size casing.
• Modern wells o en have two to five sets of subsequently smaller hole sizes drilled inside one
another, each cemented with the casing.
• This process is all facilitated by a drilling rig which contains all necessary equipment to circulate the
drilling fluid, hoist and turn the pipe, control downhole, remove cu ngs from the drilling fluid, and
generate on-site power for these opera ons.
OIL & GAS WELL LIFE CYCLE
OIL & GAS WELL LIFE CYCLE
When a well drilling is completed, its casing appearance will be as given below:
OIL & GAS WELL LIFE CYCLE
Comple on
• A er drilling and casing the well, it must be 'completed'. Comple on is the process in which
the well is enabled to produce oil or gas.
• In a cased-hole comple on, small holes called perfora ons are made in the por on of the
casing which passed through the produc on zone, to provide a path for the oil to flow from
the surrounding rock into the produc on tubing.
• In many wells, the natural pressure of the subsurface reservoir is high enough for the oil or
gas to flow to the surface. However, this is not always the case, especially in depleted fields
where the pressures have been lowered by other producing wells, or in low permeability oil
reservoirs.
• Installing smaller diameter tubing may be enough to help the produc on, but ar ficial li
methods may also be needed. Common solu ons include downhole pumps, gas li , or
surface pump jacks.
OIL & GAS WELL LIFE CYCLE
Produc on
• The produc on stage is the most important stage of a well's life, when the oil and gas are
produced.
• By this me, the oil rigs and workover rigs used to drill and complete the well have moved off
the wellbore, and the top is usually ou i ed with a collec on of valves called a Christmas tree.
• These valves regulate pressures, control flows and allow access to the wellbore in case further
comple on work is needed.
• From the outlet valve of the produc on tree, the flow can be connected to a distribu on
network
of pipelines and to degassing sta on to separate and supply the products to refineries, natural
gas compressor sta ons, or oil export terminals.
• As long as the pressure in the reservoir remains high enough, the Christmas tree is all that is
required to produce the well. If the pressure depletes and it is considered economically viable,
ar ficial li methods can be employed.
OIL & GAS WELL LIFE CYCLE
Produc on
Xmas Tree
OIL & GAS WELL LIFE CYCLE
Abandonment
• A well is said to reach an "economic limit" when its most efficient produc on rate does not
cover the opera ng expenses, including taxes.
• When the economic limit is reached, the well becomes a liability and is abandoned.
• In this process, tubing is removed from the well and sec ons of well bore are filled with
cement to isolate the flow path between gas and water zones from each other, as well as the
surface.
• Completely filling the well bore with cement is costly and unnecessary.
• The surface around the wellhead is then excavated, and the wellhead and casing are cut off, a
cap is welded in place and then buried.
NORMAL DRILLING OPERATION
STOVE PIPES
CONDUCTOR PIPES
SURFACE CASINGS
INTERMEDIATE CASINGS
PRODUCTION CASINGS
LINEAR CASINGS
DIRECTIONAL DRILLING
Wells meant to be drilled ver cally will wander few degrees from ver cal and move in different direc ons
Rou ne measurements are taken during drilling to determine if a well is devia ng from ver cal by more
than the allowed amount (normally less than 5 degrees).
Direc onal drilling is used when a well is inten onally deviated to reach a bo omhole loca on (BHL) that
is different from the surface loca on (SL)
(see next few slides showing several reasons for direc onal drilling)
DIRECTIONAL DRILLING
The two faster and o en more reliable methods of direc onal drilling are:
Original Well
Sidetrack
Correct Original Well
Well
ed Sidetrack
Path
Path
Original
Well
Reservoir
Reservoir
Reservoir
Horizontal Well
Vertical Well
Long Radius
Medium Radius
Short Radius
Run bit a bit with predetermined diameter and BHA. Drill out the float collar, cement, and casing
shoe of the casing just run.
Drill the new hole using the proper BHA for either a vertical or deviated hole to the casing point.
During parameters, hydraulics and directional surveys will be in accordance with the drilling
programme. Mud and bits will be as per the drilling programme.
On reaching the casing point, circulate just to have the shale shakers clean.
Run electrical logs as per the Geological Programme.
Run a bit to bottom to check the hole, circulate to condition the mud and pull out of the hole to run
the casing string.
DRILLING A SECTION OF HOLE
Drag Bits
Rolling Cu er Bits
Diamond Bits
Special Purpose Bits
BITS
Drag Bits
The oldest of the rotary bits, the drag bit u lizes flat cu er blades to scrape away the rock. These bits,
though rela vely simple and inexpensive, and s ll used for drilling so , shallow forma ons, have been
largely replaced by other types.
Rolling Cu er Bit
These bits operate similarly to drag bits, in that they have no moving parts such as cones or bearings,
but rely on industrial diamonds to crack and abrade the forma on. The diamonds are set in a high
strength steel matrix, with a pa ern and spacing op mally designed for the drilling condi ons
expected. The loca on of the drilling fluid outlets is cri cal in the design of a bit that will allow
cu ngs to be