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Tema 1
Tema 1
These methods succeed in removing many pollutants, but this is not enough either for
the pollutants that remain in the water or for the law that foresees (que prevé) a greater
putrification.
d,e,f These are the categories in which more can be done as a removal of more
diffuse methods (Current methods).
Screening:
Wastewater screening retains solids found in the wastewater. These solids must be
removed at the very beginning of the water treatment process, as these solids could
make the whole system less efficient, damage expensive and essential water treatment
equipment or contaminate water, causing small to large scale natural upsets for a
region’s entire ecosystem.
Chemical processes – chemical precipitation, coagulation, adsorption, chlorination etc.
Flow equalization: the process of controlling hydraulic velocity, or flow rate, through a
wastewater treatment system. The equalization of flow prevents short term, high
volumes of incoming flow, called surges, from forcing solids and organic material out
of the treatment process.
Flotation: Dissolved air flotation (DAF) is a water treatment process that clarifies
wastewaters (or other waters) by the removal of suspended matter such as oil or solids.
The removal is achieved by dissolving air in the water or wastewater under pressure and
then releasing the air at atmospheric pressure in a flotation tank basin. The released air
forms tiny bubbles which adhere to the suspended matter causing the suspended matter
to float to the surface of the water where it may then be removed by a skimming device.
They are getting diffused so they can be considered conventional. (Due to the more
restricted regulations of the past years).
General properties:
a) All of them are CHEMICAL OXIDATION PROCESSES of the
POLLUTANTS.
b) They operate at ROOM TEMPERATURE AND PRESSURE.
c) In order to OXIDIZE POLLUTANTS, you use RADICALS (Pretty strong
oxidizing species, highly reactivity, non-selective reactivity, short lifetime).
d) Radicals will not travel a long distance far from their source because they have a
SHORT LIFETIME: 10-9 s.
e) Non-selective, so they can attack both ORGANIC and NON-ORGANIC
POLLUTANTS.
Ideal Process starting from POLLUTANT MIXTURE. (Not always this result, usually
we have by-products).
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THEORY OF AOP:
The basic principle of AOPs entails the generation of hydroxyl free radical HO∙, non-
selective chemical oxidant, as a strong oxidant for destroying organic compounds which
cannot be oxidized by conventional oxidants such as ozone, oxygen and chlorine.
Hydroxyl radicals are effective in the destruction of organic chemicals due to the fact
they are reactive electrophiles which not only react rapidly, but also non-selectivity with
almost all organic compounds that electron-rich. Their oxidation potential is quantified
as 2.80 V, and this makes them to exhibit faster rates of oxidation reactions compared to
conventional oxidations.
Table 1. Oxidation potential of various oxidants
AOPS
Los que tienen asterisco (*) tienen INDUSTRIAL APPLICATIONS.
Using chemicals (1) Photolytic (2) Photocatalytic (3) Electrochemical (4)
O3* O3/UV* TiO2/UV Anodic hydrolysis
O3/H2O2* H2O2/UV* TiO2/H2O2/UV Electro-Fenton
Fenton* PAA/UV TiO2/UV/Bias
Photo-Fenton* TiO2/UV/H2O/Bias
Fenton Process:
The Fenton reagent is a mixture of iron (II) salt and hydrogen peroxide. Fenton
described the oxidation power of hydrogen peroxide on various organic molecules in
which OH∙ radicals are produced from H2O2 through addition of Fe (II) as the catalyst.
Fe2+ + H2O2 Fe3+ + OH- + OH·
Fe3+ + H2O2 Fe2+ + HOO· + H+
Applications of AOPs:
AOPs are usually applied to wastewaters with low COD due to the low cost of H 2O2
and/or ozone required for the generation of hydroxyl radicals.
Overview:
The reasoning behind using AOPs for disinfection is that free radicals that are generated
from ozone are more powerful oxidants that ozone alone and this makes them effective
for oxidation of microorganisms and refractory organic materials in wastewater.
However, the fact that the half-life of the hydroxyl free radical is short and as a result it
is impossible to achieve high concentrations. Extremely low concentrations imply that
the required detention times for disinfection if microorganisms are much higher and are
determined on the basis of CT concept.