ORDINARIA, SHERWIN D. ANALYTICAL CHEMISTRY LAB.

BSMLS-1G

GROUP V ANIONS

LAB ACTIVITY NO. 8

Divide into 4-portions

UNKNOWN SAMPLE

FIRST PORTION SECOND PORTION THIRD PORTION FOURTH PORTION

+5 drops of concentrated HNO3 Place the Evaporating dish +5 drops of

concentrated H²SO⁴ Evaporating to almost + Equal volume of urea in HCI solution
dryness
+ 2 drops of 0.5 M A5NO³ allow
to start mixture in 2mins Let casserole cool 3drops +3drops of carminic
acid warm slightly

centrifuge
TEST ONE TEST TWO
PRECIPITATE CENTRIFUGATE

+NaCO3 1 drop portion in depression of spot plate 2

drops of concentrated H²SO⁴ 1 drop of a-
Discard naphthylamine stand for 3mins
VIGOROUS
EVOLUTION OF GAS

YES
NO
Place
FORMATION OF + NITRITE ION
- NITRITE ION small
WHITE
PRECIPITATE crystal
END ferrous
YES sulfate
+ NITRATE
PURPLE RING APPERANCE in a
AROUND THE DROP OR
ION
REAGENT depressi
YES CHANGE OF
RED COLOR TO
BLUISH VIOLET on of
+ CHLORATE ION spot
END plate + 1
NO
drop of
END YES - BORATE ION
NO unknow
+ BORATE ION
- NITRATE ION
n
NO
FORMATION OF sample +
BROWN RING NO

- CHLORATE ION AROUND THE 1 of

CRYSTAL
END - NITRATE ION
concentr
YES

+ NITRATE ION END ated

H²SO⁴