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Answer:

(a)

The differential equation for G (Gibbs free energy) is:

dG   SdT  VdP …… (1)

Take partial derivative of equation (1) with respect to P at constant T.

0
 G   T  P
   S   V
 P T  P  T P

 G 
  V
 P T

(b)

The differential equation for A (Helmholtz energy) is:

dA   SdT  PdV …… (2)

Take partial derivative of equation (2) with respect to P, at constant V.

 T    V  
0
 A  0
   S   P    V  V 

 P V  P V   P  V 
 P  1  P 
    
 A V S  T V

(c)

Use the Maxwell relation,

 T   V 
   
 P  S  S  P

Rewrite above equation as:

 T   V 
   
 P  S  S  P
 T   V   T 
      ...... (3)
 P  S  T  P  S  P

 T 
 
 S  P is defined in terms of CP as:

 S 
CP  T  
 T P
 T  T
   ...... (4)
 S  P CP

Substitute equation (4) in equation (3) and simplify as:

 T   V   T 
     
 P  S  T  P  CP 
 T  T  V 
    
 P  S CP  T  P

(d)

The fundamental property relation for H (enthalpy) is:

H  U  PV …… (5)

Take partial derivative of equation (5) with respect to T, at constant U.

0
 H   U    V   P  
    P  V   
 T U  T  U   T U  T U 
 H   V   P 
   P  V  
 T U  T U  T U