Problem(17(

Problem(17(
Problem(17(
Problem(17(
Problem(18(
Problem(18(
Problem(18(
Problem(18(
Problem(19(

•  Same(as(Prob15(instead(of(vdW(EOS(use(corresponding(state(principle.(
•  Write(down(balance(equaAons(as(in(Prob(15(
•  Use(the(concepts(explained(in(Prob(17(i.e.(Ni(=(Pi(Vi/(R(Zi(Ti)(;(Nf(=(Pf(Vf(/(R(
Zf(Tf);(U(=(H(–(PV;(U(=(HIG(+(Tc(*((H(–(HIG)/Tc(–(NZRT(
•  Got(to(solve(the(equaAons(iteraAvely((show(3(iteraAons)(
(
Problem(19(
Problem(19(
From(Molar(Balance,((
(((((Ni(=(Nf(=>(Pi(Vi(/(Zi(R(Ti(=(Pf(2*Vi(/Zf(R(Tf((
You(know(iniAal(condiAons,(get(an(equaAon(for(Pf/Zf(Tf(=(xxxxx(___(Eqn(1(
From(Energy(Balance,(
((((Ui(=(Uf((
Express(the(above(equaAon(in(terms(of(H,(HIG,(Z,(and(T(at(iniAal(and(final(
condiAons(___(Eqn(2(
IniAal(Guess:((
((((Pf(=(pressure(calculated(if(the(gas(be(an(ideal(gas(
Step(1:(Calculate(Zf(Tf(using(Eqn(1(
Step(2:(Use(Zf(Tf(obtained(in(step(1(in(Eqn(2,(find(Tf(and(Pf(that(would(saAsfy(Eqn(2(
Step(3:(If(required,(modify(Pf(and(carry(out(Steps(1(to(3(
Problem(20(
Problem(20(
Problem(20(

xLSL(+(xvSv(=(Sin(
Problem(21(
Problem(21(
Problem(22(
Problem(22(
Problem(22(

Re-arrange this expression to

show part (a) and integrate the
part(a) wrt T to obtain part (b)