Professional Documents
Culture Documents
Uses of Nanotechnology in
Environmental Technology in Hessen
Innovation potentials for companies
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Hier ist die Zukunft
Uses of Nanotechnol-
ogy in Environmental
Technology in Hessen
Innovation potentials for
companies
prepared by:
Daniel Heubach
Severin Beucker
Claus Lang-Koetz
Fraunhofer-Institut für Arbeitswirtschaft
und Organisation IAO
Nobelstraße 12
D-70569 Stuttgart
Editors:
Dr. Rainer Waldschmidt, Maria Rieping (HMWVL)
Dr. Carsten Ott, Alfred Stein, Sabine Wesche
(HA, hessen-umwelttech)
Alexander Bracht, Markus Lämmer
(HA, hessen-nanotech)
Editorial offices Frantz, Göttingen
Publisher:
HA Hessen Agentur GmbH
Abraham-Lincoln-Straße 38-42
D-65189 Wiesbaden
Telephone 0049 (0) 611 774-8614
Fax 0049 (0) 611 774-8620
Internet www.hessen-agentur.de
www.hessen-umwelttech.de www.hessen-nanotech.de
Environmental technology
meets nanotechnology –
because success
thrives on innovation!
German companies have always held a leading Despite this, a business survey carried out by my
position in environmental technology. Hessian Ministry among more than 6,000 Hessian enter-
companies are right at the forefront and are sup- prises has shown that the potential of nanotech-
ported by the Hessian Environmental Technology nology is not yet sufficiently well understood.
initiative of my Ministry. Nevertheless, Hessen
Thus, true to the motto “Support strengths”, we
cannot rest on its laurels. In these times of con-
aim to integrate our existing strengths in nano-
stantly growing and changing markets, a key to
technology in Hessen with the prominent market
success is in research and the use of innovative
position of environmental technology businesses.
technologies.
The small and medium-sized environmental tech-
One of the most important new technologies of nology companies in Hessen serve as the lynch-
this new century is nanotechnology. The selective pin and are a key element in the value chain. Their
use and influencing of physical and chemical power of innovation and their detailed under-
properties can lead to nanotechnological innova- standing of the market are the levers we can and
tions which can affect all spheres of our lives in should use. It is only by working closely with small
the form of new products. All nanotechnology and medium-sized enterprises that Hessen can
sectors are being intensively researched in Hessen. continue to assume a strong position against
The Hessen NanoNetwork of Hessian Universities international competition.
founded in 2004, together with our Hessian
The present brochure is intended as a help towards
Nanotechnology initiative and our Technology
achieving this aim. I hope that we can arouse your
Transfer Network (TTN-Hessen), are supporting
interest in nanotechnology and thus encourage
Hessen universities by encouraging collaboration
the development of new environmental technol-
with Hessen enterprises. Leading companies
ogy products based on nanotechnology.
are already working as providers or users of nano-
technology.
1
Contents
Preface 1
Summary 4
1 Introduction to nanotechnology 8
1.1 Definition of nanotechnology ............................................................................ 8
2
2 Application potential and areas of application for
nanotechnology in environmental technology 19
2.1 Tasks and application areas of environmental technology ........................... 19
Appendix 39
Literature ............................................................................................................ 39
3
Summary
4
Surveys in the context of this brochure have shown
that nanotechnology is still largely unknown in the
environmental technology sector. At present, nano- For a fast overview:
technology research is strongly driven by technical
What’s new in nanotechnology?
possibilities while environmental technology is
problem-oriented. Both approaches need to be uChapter 1.2, page 9
merged in order to develop innovative products uFigure 5, page 9
and services – the potential is there.
What can nanotechnology do?
Hessen is well-positioned in both nanotechnology
and environmental technology. All nanotechnol-
uChapter 1.3, page 12
ogy sectors are being researched to a high interna- What applications already exist
tional level in Hessen and well-known companies and what are still to come?
are active in the nanotechnological field. In envi-
ronmental technology, Hessen is particularly well
uChapter 1.4, page 14
placed in the following fields: water / wastewater,
uFigure 8, page 16
waste, energy / clean air / climate protection, anal- What are possible applications for
ysis / measurement and control technology, and environmental technology?
integrated product policy. Thus all the necessary
facilities are available to advance research in the
uTable 1, page 20 / 21
overlapping areas of nanotechnology and environ-
uTable 2, page 26
mental technology and to put them to practical What concrete applications are there already
use. This makes a valuable contribution to environ- in environmental technology?
mental protection and at the same time strength-
ens the Hessian economy.
uChapter 2.4, page 29
How should environmental technology
The present brochure demonstrates the innovative
companies proceed?
potential of nanotechnology for environmental
technology companies in Hessen. It starts out with uChapter 3, page 34
a introduction to nanotechnology and its various
What contacts are available in Hessen?
functionalities on the basis of which the applica-
tion potential in environmental technology can be uInformation & addresses, page 49
assessed. The application potential is then set
against the facilities already available in Hessen’s
nanotechnology sector. Examples of possible uses
for nanotechnology are provided by selected envi-
ronmental technology applications in filtration,
pollutant decomposition, catalysis and sensors.
The brochure ends with an account of the innova-
tive potential of nanotechnology from the point of
view of technology management and demonstrates
approaches for effective technology transfer of
nanotechnology to environmental technology.
5
Introduction – why this brochure?
Nanotechnology will be among the key technolo- Nanotechnology is not a product or a process – it
gies of the twenty-first century (Bierhals 2000, describes new discoveries about material proper-
BMBF 2002, VDI 2004/2). It is important to under- ties and structure in the 10-9m dimension. The
stand the new functionalities and properties of combination of these findings with existing con-
materials and elements at the molecular level ventional products or technologies opens up com-
which are strongly dependent on the nanoscale pletely new perspectives. These extend not only to
effects of their components. Examples of such the product and its application areas, but also to
nanoscale effects are chemical surface properties the engineering of products. However, before
which result in new catalytic or adsorption function- analysing possible uses of nanotechnology in envi-
alities of materials. For example, a nanostructured ronmental technology, it is important first of all to
surface provides a layer which is not wetted either understand the effects and potentials of both tech-
by water or by oil (ultraphobic) and to which liquids nologies. Only in this way it is possible to make
and dirt do not adhere (see the Lotus effect in Fig- deliberate use of the properties of nanomaterials,
ure 1 as an example). integrate them at the macroscopic level and fit
them together to form new, complex product sys-
tems (Figure 2, page 7).
6
Integration of nanotechnology Product(system) in envi-
Nanomaterial
at macroscopic level ronmental technology
This includes, for example, energy efficient lighting For the preparation of this brochure, a select
systems, sturdier and lighter materials, significantly group of nanotechnology and environmental tech-
improved chemical and biological sensors or spe- nology experts were asked to give an account of
cific surface properties. their experience. Their statements, which have
been incorporated anonymously into the texts and
As in many other sectors, the practical use of nano-
conclusions of the brochure, give an idea of the
technology in environmental technology is just at
current state of nanotechnology and its possible
the beginning of its possibilities. On the one hand,
uses in environmental technology in Hessen.
this is because there is still research and develop-
ment work to be done in many areas of nanotech-
nology. On the other hand, basic nanotechnology
effects are still not known to many users and man-
ufacturers of environmental technology. Structure of this brochure
uAppendix:
Research programme and assessment
of market technology impact
7
1 Introduction to nanotechnology
1.1 Definition of nanotechnology The influencing of structures less than 100nm in
size is considered to be one of the working areas of
Definition: “Nanotechnology deals with systems, nanotechnology (see size comparison in Figure 3).
the functionalities and properties of which are The following effects are essential and functional
exclusively dependent on the nanoscale effects aspects of nanotechnology and are of particular
of their components” importance from the point of view of environmen-
tal technology:
Nanotechnology1 is based on the perceptions and uSize effects: The progressive miniaturisation
possibilities of specifically and consciously influ- into the nanoscale range enables new appli-
encing the properties and structures of materials cation areas and the implementation of func-
at the supramolecular level. Thus it is possible to tionalities in the smallest space2.
functionalise, miniaturise or specify materials and
surfaces in order to improve, for example, their
uStructure effects: With the understanding
and conscious construction of structures, it
chemical selectivity.
should be possible to influence the properties
Therefore, nanotechnology is neither a single sci- of materials at their very base and to use and
entific discipline nor a defined application area. integrate them into complex combined sys-
Its order of magnitude may be used as a definition. tems3.
Thus, nanotechnology deals with systems, the
functionalities and properties of which are exclu-
uSurface effect / boundary surface effect:
The design of structures at the molecular level
sively dependent on the nanoscale effects of their
and the increasing surface / volume ratio has
components (Bachmann 1998).
effects on the boundary surface of materials
and particles. The surface of a material and its
Figure 3: Nanofibres (horizontal) properties can become an important product
compared to a human hair (vertical) function (see Figure 4, page 9) by enlargement
under an electron microscope and functionalisation of the boundary surface.
(Source: Philipps-Universität Marburg)
1 The description “nano” is derived from the order of mag- complete knowledge of humanity on the head of a pin
nitude of the range under consideration, the nanometer (Hullmann 2001 and Bachmann 1998).
(nm = 10-9m). The word “nano” comes from the Greek
3 The basic concept of building up a large system from
and means “dwarf”.
small parts (considered as single atoms or molecules in
2 The American, Richard Feymann (1918 –1988), professor nanotechnology) is described as the “bottom-up
in theoretical physics, who received the Nobel Prize in approach”. In contrast, the “top-down approach”
1965 for his work in the field of quantum electrodynamics, describes the creation of small structures from larger
pointed out the unlimited possibilities for miniaturisation: units, as lithography methods in microelectronics.
“There is plenty of room at the bottom”. In the atomic
dimension, there would be enough room to store the
8
Surface effect, volume effect
200
• Number of atoms on
the surface increases
Surface
in km2
considerably with
decreasing diameter
1.2 Innovation potential of
• Properties (e.g. melting
nanotechnology point, chemical reactivity
100 change dramatically
1 cm
MACRO
To
Mechanics
p-
microbes 1 mm
ris
do
Mechanical
ati
wn
Electronics g
di
m
vi
1 μm Material design Sy
hard material layer thickness
al
sa
i
tio Quantisation
Viruses, 64MB/256MB chip 0,1 μm n Use of
gold leaf thickness, Gbit chip
biological principles,
Photolithography limit 10 nm physical laws and
NANO
1940 1950 1960 1970 1980 1990 2000 2010 2020 2030 2040 2050
9
The properties of macroscopic structures can be uThe enlarged surface of nanomaterials is mak-
specifically adjusted through controlled construc- ing new chemical processes possible by modi-
tion using atomic and molecular components (bot- fication of melting and boiling points, chemical
tom-up). The understanding of the molecular reactivity and catalytic yield. For example,
basics of new materials is opening up new per- nano-iron particles are being used for reduc-
spectives, among which is the manufacture of tion of pollutants and in water purification.
“switchable” materials which can, for example, Nanoscale zeolites can be used in environment
acquire polar and non-polar properties. The so- analysis or for oxidisation in cation exchangers;
called Carbon Nano Tubes (CNT, Figure 6) are a titanium dioxide particles can be used as
nanomaterial offering considerable potential. They nanoparticles in the photocatalysis of organic
can be used both as conductors and as semicon- contamination or metal organic frames as
ductors. nanocubes for hydrogen storage.
10
The objective is higher specifications, selectivity The experts see positive effects and possible uses
and functionalisation through nanotechnology for nanotechnology in the areas of environment
and health, for example the development of new
A great deal is expected from the new material methods for diagnosis and therapy or new drugs
properties identified in nanotechnology with and agrochemical products. Environment-friendly
regard to specification, selectivity and functionali- effects are expected from savings in resources or
sation as well as for the design of particles, materi- increases in energy use efficiency. Possible energy
als and components. savings through the increased use of LEDs with
nanotechnology, such as white LEDs for general
The ideas of Eric Drexler4 can be viewed as a less
lighting in Germany, are equivalent to the output
realistic future scenario. He represents the vision of
of two nuclear power stations (Bachmann 2004).
machine construction at the nanometer level, also
called molecular nanotechnology, and describes The further development of tools and technolo-
nanorobots which replicate themselves and can gies for measuring and manipulation will be a key
also manufacture material themselves5. Many task for mastering structuring and manufacturing
other researchers take a more realistic view. They methods in the nanoscale range, because the res-
consider that nanotechnology will not only design olution of the smallest nanoscale structures will
products and processes more efficiently in the require further research and development at these
short term, but will also lead to new applications orders of magnitude.
and functions (e. g. cancer therapy or data storage
media).
4 Researcher and the President of the Foresight Institute, 5 Engines of creation The Coming Era of Nanotechnology,
USA (www.foresight.org/FI/Drexler.html). Eric Drexler, 1986, and Unbounding the Future: The Nano-
technology Revolution by Eric Drexler and Chris Peterson,
William Morrow and Company, Inc., New York 1991.
11
1.3 Functionalities of nanotechnology Mechanical functionalities
With its wide range of effects and functionalities, The clearly improved mechanical functionalities of
nanotechnology is theoretically suitable for use in nanostructured solid bodies offer increased hard-
almost all sectors and technologies – including ness, break resistance and toughness at low tem-
environmental technology. Unlike other technolo- peratures or super plasticity at high temperatures.
gies, such as biotechnology, it cannot be defined The basis for these effects is a reduction in granu-
satisfactorily in terms of its areas of application. lar size, the grains being reduced to a size below
which no further plastic deformation can take
In addition, research in nanotechnology is still
place. For customers, this offers advantages such
largely driven by the possibilities of new materials
as extended service lives for production tools and
and methods (“technology push”) rather than by
components, or resource-efficient lubrication sys-
concrete, customer-oriented applications (“market
tems.
pull”). Until now, practical applications have in
many cases been identified more by chance than
Special geometric characteristics
by design.
The special geometric characteristics of nanostruc-
tures lie in their space requirement at the order of
The functionalities are the key to the
magnitude of atoms and molecules (see Figure 4).
application-oriented approach in
This results in atomic precision and extremely
nanotechnology
large surface/volume ratios of nanoporous and
nanoparticle materials. Customer benefits include
The functionalities identified for nanotechnology
adjustable pore sizes of nanoporous membranes,
materials, products and processes provide a good
molecule specific separation and selective cataly-
application-oriented access to nanotechnology for
sis or load separations and adsorption in environ-
business. These phenomena are closely associated
mental technology processes.
with product utilisation and function and thus with
customer-oriented demand, and forge the link
Electrical functionalities
between nanotechnology and environmental tech-
nology. The functionalities are introduced below The reduction of the particle size and the layer
(according to TAB 2004). thicknesses in the low nm-range results in the
development of additional electronic conditions.
An electron can only accept discrete, separate
energy levels separated by gaps. Such particles do
not behave like solid bodies, but instead are simi-
lar to atoms. They can be customised with regard
to their electronic and optical properties by delib-
erate influencing the structure. One practical use
of this effect is in elements with switchable electri-
cal statuses, optical switches, thermoelectric mate-
rials such as heat exchangers or antistatic surfaces.
12
Magnetic functionalities Chemical functionalities
The magnetic functionality in the nm-range is based The chemical functionality of nanoobjects is based
on paramagnetic and ferromagnetic properties of mainly on their surface structure: Nanostructured
solid bodies. The macroscopic magnetic properties materials exhibit a considerably large proportion of
can be influenced and paramagnetism occurs, surface atoms (see Figure 4, page 9). Such atoms
described here as superparamagnetism. In prac- are particularly reactive due to their unsaturated
tice, the magnetic resistance effect (MR effect) is bondings. Lattice hardening or a distorted bonding
used and is applied in magnetic field sensors, mag- angle result in a significantly enlarged surface
netic storage elements (Magnetic RAM, MRAM), or energy. This is useful for surfaces with customised
adhesives which are modified with nanoparticles in wetting behaviour, for spatial arrangement of func-
such a way that the adhesive properties become tional groups, for enhanced chemical selectivity
switchable. and reactivity, as well as chemical stability in vari-
ous chemical processes.
Optical functionalities
Biological functionalities
The optical functionalities are based on the fact
that the nanoparticles are clearly smaller in size The biological functionality of nanoscale materials
than the wavelength of visible light: they give off is understood to mean the interaction with com-
no reflection. By customising their size, it becomes plex biological systems such as cells, organisms or
possible to obtain a sharply limited, specified biomolecules. An essential element here is the
wavelength range (one colour) in which the mate- roughness and structuring in the micro- and
rial absorbs or emits light. Nanoparticles reveal nanometre range. Practical uses arise from the
new optical properties with regard to colour, fluo- “Nano2Bio” transfer direction, i. e. the use of nano-
rescence or transparency. This is used in transpar- tech processes and materials for studying biologi-
ent dispersions of nanoparticles or in optically cal issues, e. g. in nanoanalysis. At the same time,
functional surfaces such as, for example, the antire- the “Bio2Nano” transfer direction offers the oppor-
flection coating of solar cells, or in the area of opti- tunity to use biotechnology materials and con-
cal analysis and information transfer. struction plans for manufacturing technical
nanosystems – biological modules are used in the
nanoscale as components for technical systems.
The basis for these is provided by biological mod-
ules, functional or organisational principles.
13
1.4 State of research and practical Examples of nanotechnology applications
application
The first applications of nanotechnology are
Practical application of nanotechnology varies
already on the market
widely from one area of technology to another
(Hullmann 2001, Bachmann in VentureCapital
The first applications of nanotechnology are already
2002). However, in all application areas there are
available on the market. For example, these include
new materials or products which build on nano-
(see TAB 2004):
technology (see Figure 8). These range from
nanooptimised layers on electronic components uNanosize titanium particles as UV protection in
such as the GMR sensors (Giant Magneto Resis- sun creams,
tance) and nanomembranes to new processing
and analysis methods. The latter also represent the
uScratchproof varnishes for automobiles
(e. g. Daimler-Chrysler) and coatings with
basis for further work in nanotechnology.
Lotus effect (e. g. Lotusan® from sto AG,
The commercial use of nanotechnology materials see Figure 1, page 6),
and base materials to date has already been car-
ried out on a considerable scale for a range of
uNanoparticles made of platinum, rhodium and
palladium in vehicle exhaust catalytic convert-
well-researched materials, e. g. titanium dioxide
ers and fuel cells,
(TiO2) in paints or sun protection equipment, and
Carbon Black for car tyres. A world market value of uIron oxide pellets with a nanostructured sur-
8,000 million US$ is estimated for Carbon Black face for adsorption of arsenic in drinking water
in 2006 and a value of 1,200 million Euros is purification (Product Bayoxide® E33),
expected for Carbon Nano Tubes (CNT) (VDI
2004/2). The first concrete application areas are
uNanostructured Carbon Black particles
as filler material in car tyres,
also emerging for CNTs in composite materials.
Electrically conductive paint with CNTs in electro- uCopper nanoparticles as an additive
static spray painting is expected to save paint and in lubricants to reduce wear,
solvents. The research into basic mechanisms and
principles in the nm range is the starting point for
uImpregnation and cleaning agents with nano-
technology for better dirt repulsion and with
systematically developing the potential of new
an anti-tarnish function,
materials.
14
These examples clearly show that nanotechnology Dye sensitised solar cells with an efficiency of
until now has been mainly implemented to opti- approx. eight per cent are currently in the proto-
mise existing products in areas of conventional type stage. Numerous economic application areas
technology such as car manufacturing or the elec- are conceivable for them, for example in the form
tronics industry and has not yet resulted in revolu- of electronic price labels with an integrated dye
tionary new products or applications. However, it is sensitised solar cell module (Hinsch 2004).
expected that by 2015, nanotechnology will have
Hydrogen storage based on Carbon Nano Tubes
penetrated and influenced almost every branch of
or metal oxides and alloys and organic bondings
industry (VDI 2004/2).
such as nanocubes (Altmann 2004) can open up
new opportunities in the future for integrating fuel
State of development cell technology with a corresponding hydrogen
storage medium in small devices such as mobile
Figure 8 gives an overview of the state of develop-
telephones, digital cameras, PDAs, or laptops.
ment of selected application areas of nanotechnol-
Nanostructured hydrogen storage and quantum
ogy in different branches of industry.
point solar cells are still at the prototyping or
research stages.
Nanotechnology is expected to be used in
Experts see the following challenges and oppor-
environmental technology initially in mem-
tunities for the future research and commercia-
branes, solar cells, and hydrogen storage
lisation of nanotechnology:
15
Ultra-precision machining Sub 100nm NEMS
Precision structuring
engineering / SXM nanoanalytics X-ray optics
optics / analytics Diode laser
CNT
composite materials
Functional layers Magnetic fluids
Chemistry /
materials Nanoparticles/colloids Carbon nano tubes (CNT)
MRAM/FRAM Spintronics
Market readiness … already achieved … in 0–5 years … in 5–10 years … in 10–15 years
16
Stakeholders in Hessen 1.5 Research programmes
and market
Hessen is represented in all sectors of
To date, promotional measures by the public
nanotechnological research
authorities have been the most important impetus
for nanotechnology research. Many states have
An inventory of the material based technologies in
introduced their own promotional programmes
Hessen shows that Hessen is represented in all sec-
which promote separate nanotechnology research
tors of nanotechnology research by universities. In
areas; at the same time, research activities are often
addition, approximately 250 companies in Hessen
also coordinated by the state. In the USA, more
have been identified as being active in the areas of
than 800 million Euros were provided for nanore-
material and surface technology, microsystem
search in 2004; in Germany it was just under 300
technology and optical technologies, of which
million Euros with which the Federal Ministry of
more than 70 companies develop and provide or
Education and Research (BMBF) and the Federal
use nanotechnologies (FEH 2004, HA 2005).
Ministry of Economics and Labour (BMWA) pro-
Contact persons and organisations for nanotech- moted projects and institutions (VDI 2004/1). As in
nology and environmental technology in Hessen the USA, which promotes environmental research
and the nanotechnology competence networks in projects in nanotechnology through the Environ-
Hessen are listed in the Appendix (see pages mental Protection Agency (EPA), there are applica-
49/50). The universities of the recently founded tions of nanotechnology in the environmental tech-
NanoNetzwerk Hessen (NNH) and their contact nology field (Trück 2004 in the “Nanotechnology,
persons are listed separately on page 50. Page 51 Materials, Production (NMP)” programme) of the
shows the university nanotechnological research in 6th Framework Research Programme of the Euro-
Hessen by subject. Page 52 gives an overview of pean Union.
the Hessian stakeholders in the nano competence
The European Commission is pursuing the goal of
centres of the Federal Ministry of Education and
strengthening scientific excellence in Europe with
Research (BMBF).
the 7th Framework Research Programme (FRP). The
annual budget is to be significantly increased to
10,000 million Euros. More than 4,500 million
Euros annually is intended for thematic priorities
including the “technology initiatives”. Nanotech-
nologies, materials and sustainable development
are one of the thematic priorities in the 7th FRP.
According to the current timetable, the first calls
can be expected at the end of 20067.
6 Hullmann (2001) investigated international technology 7 Additional current information about the 7th European
transfer using nanotechnology in a study. Various indi- Commission Framework Research Programme is available
cators such as the number of publications, patents etc. at www.cordis.lu/era/fp7.htm
were included for this.
17
Research and development in Germany on the 1.6 Technology impact assessment
industrial side is currently concentrated in the raw
material and chemical sectors (Harper 2002).
Possible risks and impacts of nanotechnology
Industrial stakeholders in nanotechnology are
are being analysed and assessed
mainly represented by large companies such as
BASF, Degussa, Henkel or Siemens (see Reitberger
in Venture-Capital 2002, Hullmann 2001, own The analysis and assessment of possible risks and
research) and small startup companies. These have negative impacts of nanotechnology on humans
often been hived off from the university and non- and the environment are occupying a major place
university research area; there is often an intensive in public discussion and scientific research. The
exchange of knowledge and staff between startup escorting Innovation and Technology Analyses
companies and universities. Medium-sized enter- (ITA) on nanotechnology conducted by the Fed-
prises have been less involved in nanoresearch to eral Ministry for Education and Research (BMBF),
date. Networks of stakeholders such as the BMBF backed up by toxicological investigations, have
competence centres, the Fraunhofer Nanotechno- indicated possible risks arising out of the use of
logy Association or other research associations nanotechnology – at the same time, they drew
aim to make it possible particularly for small and attention to the opportunities which it opens up.
medium-sized enterprises to enter nanotechnol- However, a general assessment of nanotechnol-
ogy. Business networks such as Materials Valley e.V ogy is not yet possible. Instead, the specific possi-
for material-based technologies, MST-Netzwerk ble applications of nanotechnology must and will
Rhein-Main for microsystem technology and be examined in relation to their specific uses and
Optence e.V for optical technologies are providing the consequent limiting factors. The great oppor-
Hessian companies with an excellent platform for tunity, as opposed other new technologies such as
networking and for know-how transfer. The genetic engineering, lies in the fact that estimates
research programmes and market for nanotech- of the technological impacts can already be suc-
nology are shown in detail on pages 42 to 47. cessfully included in the analyses at very early
stages of development. This subject is described
in more detail on page 48.
18
2 Application potential and appli-
cation areas for nanotechnology
in environmental technology
2.1 Tasks and application areas of them in the first place. An example of this is the
environmental technology debate about production and product integrated
environmental protection.
The field of environment protection and renew-
able energies is considered to be one of the most
important sectors of the future. With approxi- Environmental technology is a cross-sector
mately 3.8 per cent of the German labour force, technology which uses disciplines such as process
there are more people employed in this area than technology, biology or chemistry
in mechanical engineering, vehicle manufacturing
or the food trade. With more than 70,000 employ- Environmental technology is also a cross-sector
ees in more than 2,000 companies concerned with technology which uses the most diverse basic tech-
environmental and energy technology, Hessen is nologies and disciplines such as process technol-
among the leaders in Germany. ogy, biology or chemistry. Technical solutions are
integrated in systems which support an ecological
and economically efficient solution to environmen-
The objectives of environmental technology are
tal problems or prevent these occurring. These are
air, water and soil protection, resource saving,
based on innovations in basic technologies such as
and the avoidance of environmental problems
materials technology, process technology, biotech-
nology, microtechnology and information technol-
The objectives of environmental technology in prac-
ogy, and at the same time on key technologies such
tice are air, water and soil protection, resource sav-
as nanotechnology (Angerer et al. 1998). Together
ing, and the avoidance of environmental problems.
with the basis technologies as drivers, the environ-
In the past, actions have usually been driven by exist-
mental protection objectives have also repeatedly
ing environmental problems; the matter was identi-
sparked off innovations in environmental technol-
fied starting from an environment problem, e. g. the
ogy. New regulations have resulted in further devel-
eutrophication of watercourses. Possible options and
opments, or new developments, in materials or
solutions based on this were determined. This under-
processes. Company philosophies oriented towards
standing of environmental technology can be
the primary objectives of sustainability have resulted
described as conventional environmental technol-
in new, ecologically compatible products.
ogy.
An example of innovations in nanotechnology
The media-related, cure-oriented view of environ- achieved by the setting of environment targets is
mental technology has given way to a preventive provided by the research projects at the USA Envi-
and holistic approach ronment Protection Agency for the reduction of
arsenic in drinking water. The aim of these projects
Thus it is important not only to recognise and elim- is to meet the legally prescribed limit value of ten
inate environmental pollution, or to avoid or min- microgrammes of arsenic per litre of drinking
imise harmful environmental impacts, for example water using nanotechnology-based filter systems
by filter systems – but also to avoid and prevent (see e. g. Trogler 2002).
19
Water / Wastewater
uApplication examples
Water treatment and wastewater treatment
systems, sewage technology and clarifier
technology
Waste / Recycling
uApplication examples
Recycling, waste treatment and waste disposal,
flue gas cleaning, landfill technology
Figure 9: Fixed bed reactor system made of iron hydroxide uPossible application areas of nanotechnology
pellets - Bayoxide® E33 – with very finely structured surfaces Sensitive pollutant detection, filtration, heat
in the nanorange for arsenic adsorption resistant wall panelling
(Source: Bayer AG, Severn Trents Services)
Energy / Clean Air / Climate Protection
uApplication examples
The basic environmental technology fields in Hes- Solar energy, wind energy, biomass,
sen are shown in Table 1. They are classified both by fuel cell technology
environmental compartments and by specific prod-
uct applications. (Possible application areas of
uPossible application areas of nanotechnology
Dye sensitised solar cells, organic solar cells,
nanotechnology are also shown to give a better
fuel cell (mobile hydrogen storage, separation
overview; these are described in detail in the fol-
of hydrogen, oxygen and water, catalytic fuel
lowing chapters).
conversion and implementation), miniaturised
battery systems, compact zeolite reactors
Table 1: Fields covered by environmental technology
in Hessen, specific product applications, and possible uses of
nanotechnology
20
Integrated Product Policy IPP
The most urgent challenges for global environ-
u Application examples ment protection are resource protection and
Production technology, material selection, the water and energy supply
increased efficiency
From a global point of view, the most urgent chal-
uPossible application areas of nanotechnology lenges for future environment protection are the
Specific material design, new types of alloys /
protection of resources, and the question of water
materials, lighter carrier and structure compo-
and energy supplies (European Commission
nents, precise machining process, quality con-
2004/2). Thus, worldwide initiatives were launched
trol at the atomic scale, switchable material
at the United Nations world summit meeting for
properties, environment friendly properties
sustainable development in Johannesburg in 1992
such as “non-contaminating”, new types of
which are also being energetically pursued by the
adhesive technologies, self-organisation
European Union in the context of the action plan
processes
for environmental technology.
Analytics / Measuring, Control and As part of the campaign against poverty, the
Regulation Technology Water Initiative has set out to provide clean drink-
ing water and develop clarifier systems with the
uApplication examples support of technologies and processes developed
Water and wastewater management, analytics,
in the EU. According to a market analysis by Frost
process monitoring and control
& Sullivan, seawater desalination alone for the
u Possible application areas of nanotechnology global market is forecast to have an average
Lab-on-chip sensor systems, annual growth rate of about ten per cent by 2010,
combined sensors / actuators by which time the worldwide market is expected to
be worth approximately 2,400 million US$. The
largest market shares are anticipated in the Gulf
countries, Saudi Arabia and Southern Europe
(Frost & Sullivan 2004/4).
To date there has been little information allowing
estimations of the future development of individ- The market volume in the EU for water pollution
ual environmental technologies and application monitoring systems in 2005 is estimated at more
areas. An essential impetus for the development of than 420 million US$ (Frost & Sullivan 1999). Tech-
the environmental technology market, particularly nology trends in this market are precise and long-
in water and wastewater treatment and water pol- term reliable operating systems.
lution monitoring systems, is provided by environ-
mental legislation8. Competitive features in this
largely saturated market in Germany are product
diversification and the cost factor.
8 An overview of future expected or changing EU, Germany This hessen-umwelttech action line project shows the
and Hessen legal environmental requirements is provided future market opportunities for environmental technology
by “Innovation radar environmental law” providers, resulting from the new regulations.
(see www.hessen-umwelttech.de).
21
It is anticipated that the market for water treatment In addition to direct use in energy systems, nano-
systems in Germany will continue to grow annually technology is also of interest in areas where its use
by two per cent until 2010. Accordingly, the market can reduce energy consumption. An example of
value in Germany for the year 2010 is estimated at this is the white LEDs based on nanotechnology.
more than 115 million US$. Membrane technol- Due to their high efficiency not only can energy
ogy, with more than half the turnover, will domi- costs be reduced, but CO2 emissions can be
nate the market (Frost & Sullivan 2004/2). halved as well. The possible energy saving by the
use of White LEDs in Germany corresponds theo-
Through the Energy Initiative it is proposed to
retically to the energy output of two nuclear power
achieve higher energy efficiency in developing
stations. They are approximately ten times more
countries by more intelligent use of fossil fuels and
efficient than conventional light bulbs. Their mar-
traditional biomass, and by increased use of
ket value in Germany alone is estimated at 500 mil-
renewable energy sources. It will be task of a
lion Euros. Annual sales growth of ten to fifteen per
Renewable Energies coalition to specify objec-
cent is forecast for innovative products in this area
tives and timeframes for increasing the proportion
(Bachmann 2004).
of renewable energy sources in the overall energy
mix, thus creating a significant need for environ- A survey among environmental technology suppli-
mental technology. Basic current environmental ers in Hessen showed that there are discernible
problems such as the greenhouse effect and air short and medium term trends in fuel cell develop-
pollution are associated with the energy supply ment and that hydrogen technology will play an
issue. important role in the long term. It was also estab-
lished that the market for renewable energies is
The rapid growth of portable wireless devices such
growing. It is assumed that there will be an
as laptops, mobile telephones, etc. is a basic impe-
increase in demand for biodegradable products,
tus for energy supply and storage systems. For
which means that impulses for innovation can be
example, lithium technology forms an important
expected from biochemistry (M-Result 2002).
application area of nanotechnology. Here, carbon
nano tubes are incorporated in the electrode (Frost
& Sullivan 2004/1). Another area is the develop-
ment of micro fuel cells. Central components for
these, such as the membrane, are also based on
nanotechnology. The direct methanol fuel cell will
have a major opportunity in this area. The first pro-
totypes of laptops, mobile telephones, cameras or
PDAs fitted with a fuel cell already exist (see Ras-
togi 2004). Average market growth rates of more
than 200 per cent over the next five years are fore-
cast for the global market of micro fuel cells for
portable devices (Frost & Sullivan 2004/3) – how-
ever, the market is starting at a very low level.
22
2.2 Application potentials of tal technology fields for concrete and economi-
nanotechnology in environ- cally interesting nanotechnology applications, for
mental technology example in emissions reduction or decontamina-
tion. The first membranes based on nanotechnol-
ogy exist in the filtration field (for example
Nanotechnology can enable new technologies
Nanoweb® from Hollingsworth & Vose). The nano-
or help to save inputs or energy
technology focus on some application areas of
environmental technology mentioned above are
Nanotechnology has considerable potential for
also confirmed by an analysis of the project pro-
solving problems related to the future challenges
motion of the American EPA National Center for
of scarce raw materials and the provision of clean
Environmental Research (Figure 10)9.
drinking water or efficient products and processes.
This is shown by analyses of the literature and by
Figure 10: Project promotion of the US EPA for nanotechnol-
discussions with experts. Nanotechnology can act
ogy and environmental technology according to the environ-
as an “enabler” of new technologies in the field of
mental technology classification (own research)
environmental technology or indirectly support
environmental protection, e. g. by savings in inputs
or energy. Furthermore, environmental technology
can be used to evaluate and master the effects of
nanotechnology. This may concern issues of 12%
Pollutant 4%
labour safety or analysis. degradation Effect on the environment
23
Technology area: Water / Wastewater Technology area: Energy, Clean Air,
Climate Protection
Catalytic and separation processes, i. e. chemical
process technology, are used in the water / waste- Solar energy, wind energy or fuel cell energy
water technology area and in purification pro- belong to the area of energy, clean air and climate
cesses. The use of nanotechnology in membrane protection. Technologies for mobile hydrogen
technology, catalytic surfaces, ion exchangers or storage, for separation of hydrogen, oxygen and
electrode separation processes in the purification water in the fuel cell, for catalytic fuel conversion
and treatment of water, air and earth contamina- and combustion in the fuel cell and technologies
tion has been demonstrated in scientific work. The in solar cell and battery development are already
possible uses in the area of filtration, catalysis or being worked on. All of these contain nanotech-
pollutant decomposition are shown in detail in nology materials. A new type of solar cell using
Chapter 2.4. nanotechnology is being researched with dye sen-
sitised solar cells and organic solar cells allowing
Technology area: Waste / Recycling new possible designs and applications (Hinsch
2004). The Gratzel cell, a cost-effective solar cell, is
Purification and separation processes for water /
also based on nanotechnology (TiO2 nanoparti-
wastewater also play an important role in the waste
cles, with dye molecules adhering to their surface,
/ recycling area, e. g. for purification of process
are used as base material). There is a glass elec-
water in production or landfill wastewater.
trode on the top of the cell through which sunlight
At present, there are no known examples or sce- reaches the inside of the cell. The intermediate
narios for specific applications in the waste tech- space is filled with an electrolyte.
nology area. However, there are a number of inter-
esting possibilities, such as adhesive bonding
which can be disbonded when required, or new
approaches for production processes using nan-
otechnology to manufacture multifunctional mate-
rials more cost-effectively and with lower resource Figure 11: Nanosilver may be incorporated in various
consumption and waste. And finally, a large contri- materials and protects against bacteria
bution to management with less waste and energy (Source: Fraunhofer IFAM)
consumption is expected from the visions of self-
assembly (bottom-up, see Figure 5, page 9), where
the atoms arrange themselves to form structures –
in much the same way as ice or salt crystals (Royal
Society 2004).
24
Technology area: Technology area: Analysis, Measuring /
Integrated Product Policy (IPP) Controlling / Regulation Technology (MCR)
Integrated Product Policy is concerned with actions Miniaturised sensors based on nanotechnology as
and technologies which improve the environmen- well as simple onsite analytics with remote tele-
tal friendliness of products. It covers, for example, metric query systems and onsite disposition (e. g.
the energy supply, the selection of materials, the in a borehole) are conceivable for the area of envi-
production process, resource consumption in the ronmental analytics. The work for this is in the
manufacturing and usage phases, and environ- research and prototyping stages. The possible
mentally friendly dismantling. Studies by Steinfeldt uses in the analytics field are shown in detail in
et al. (2004) on the sustainability effects of nano- Chapter 2.4.
technology products show that very large ecologi-
cal efficiency potential can be realised by using Evaluation of the functionalities and
coatings based on nanotechnology. The use of the technology areas
nanotube catalytic converters in styrene synthesis
In Table 2 on the following page, the application
achieves an energy saving potential of just under
potentials of nanofunctionalities (see Explanations
50 per cent at the styrene synthesis process stage,
on page 14) are compared qualitatively to environ-
thus demonstrating the importance of nanotech-
mental technology fields and assessed. The
nology for efficient resource management (Stein-
assessment is subjective and is concerned with
feldt et al. 2004).
identifying potential areas in which future applica-
Surfaces with environmentally safe properties are tions appear expedient or possible as far as we can
interesting: possibilities here include surfaces with know at present. The authors have presented a
non-contaminating and self-cleaning effects (see “snapshot” based on analyses of the literature and
Figure 1, page 6), or with insulation properties and replies received from experts.
protection mechanisms, e. g. against IR / UV radia-
tion or corrosion. The first products for surface
treatments (glass, wood), such as cleaning agents,
varnish and paint for the domestic user, are already
on the market. In the materials area, new switch-
able materials – research is being carried out, for
example, on switchable wetting behaviour – and
adhesive bondings are conceivable which are also
useful for the environment.
25
Environmental tech
Large application area obvious
Water /
Waste MCR Energy, clean a
Application area conceivable wastewater
Purification /
Monitoring /
Air cleaning,
Avoidance
treatment
Handling
cleaning
Analysis
Improved properties
with regard to
Catalytic converter
Special geo- Atomic precision, Ion exchanger Reactive Filter / Cataly-
metric features large surface / capacity ratio Filter systems surface tic converter
Fillers
Dye se
Electrical Lab-on-Chip
Nanotechnologie
Table 2 shows potential application areas of nano- Table 2: Application map for nanotechnology
technology in environmental technology as a type functionalities in environmental technology
of application map. Environmental technology
companies can see which nanotechnology func-
tionalities support and optimise processes and
products in their field. Nanoresearchers can iden-
tify which of their functionalities can be used in
environmental technology.
26
2.3 Comparison of the application
areas with the sector structure
hnology areas
of environmental technology
companies in Hessen
ir, climate protection IPP
Hessen is represented today in all important envi-
ronmental technology fields. Companies in this sec-
Resource efficiency
Material selection
tor in Hessen make an annual turnover of 12,400
Energy efficient
Energy systems
Energy storage
Specific material
systems and processes. The illustration shows that
Chemical
H2 storage design Efficient many environmental companies in Hessen are par-
Battery materials
Zeolites ticularly active in the area of water / wastewater. This
field is also a major application area for nanotech-
nsitised solar
organic solar nology.
Fuel cells /
y Switchable
materials The chemical, biological and geometric as well as –
to a lesser degree – mechanical and electrical func-
Adhesive
technology tionalities (see Table 2) have a large innovation
potential for environmental technology. In compar-
ison, there is a particularly large selection of com-
Glass substitution
ective Switchable
ctral coating panies in Hessen in the technology areas of water /
coating
wastewater, waste / recycling, and energy / clean
Chemical
H2 storage air / climate protection (see also Table 1 and Figure
12). This shows that Hessen has a particularly large
ensitised solar
organic solar Biocide surfaces innovation potential in the field of water and waste-
fuel cells Easy-to-Clean surfaces water with regard to the use of nanotechnology in
environmental technology. Individual applications
from these fields such as filtration, pollutant
decomposition or catalysis are shown in detail in
Chapter 2.4.
27
is a focus of the Justus-Liebig University in Gießen
Water / wastewater 37 % and the Philipps-Universität in Marburg. Nanosen-
sors are being researched at the Darmstadt,
Energy / heat 32 % Gießen, Kassel and Marburg universities, and at
the Gießen-Friedberg and Wiesbaden technical
Noise / clean air 31 % colleges. The research competence is considered
to be ‘good’ to ‘very good’. The new initiative for
Waste / recycling 30 % networking the nanoresearch universities in the
NanoNetzwerkHessen10 was introduced in March
Earth / landfill 22 % 2004 (see page 50). The competence networks in
decontamination
Hessen are also listed on page 50.
Other 14 %
In addition, the DECHEMA – society for chemical
technology and biotechnology – has been estab-
MCR technology 11 %
lished as an intermediary between research and
industry. Its role is to participate in the develop-
Figure 12: Proportion of companies per technology area ment of chemical technologies and processes and
excluding sector of “Environmental management / law / to work on new findings from research and devel-
Eco-Audit” and “Nature protection / ecology” (Total > 100 % opment for practical use.
as multiple classification is possible, M-Result 2002)
The transfer of knowledge and technical know-
how between scientific institutions and particularly
Hessen is represented in the nano competence the small and medium-sized enterprises (SME)
centres by a number of companies engaged in the from industry and commerce is promoted by the
sectors of nanotechnology relevant to envi- TechnologieTransferNetzwerk-Hessen (TTN-Hes-
ronmental technology. Hessen is well represented sen). The primary objective is to make the available
in the competence centres for nanoanalytics, func- technology in Hessen transparent and to link the
tionality through chemistry, and nanomaterials. stakeholders. It is intended that the access to inno-
Hessen is particularly strongly represented in the vative technologies and scientific findings should
chemical industry area, which serves to drive the be made easier particularly for small and medium-
nanoresearch application area: With the compa- sized enterprises, e. g. by supporting the search
nies Aventis Research & Technologies (now partly for suitable partners for the respective research
Sanofi Aventis Group), Degussa AG, Creavis GmbH and development tasks. In addition, the university
and Merck Patent GmbH, four Hessen companies and research experts will be offered the opportu-
from the chemistry sector are among the top 20 nity to present their technological know-how in the
nanopatent applicants (FEH 2004). virtual technology and competence market.
10 See www.nanonetzwerkhessen.de
28
2.4 Possible applications of nano- Application examples are:
technology in environmental
technology ufilter membranes made of deformable ceram-
ics with nanoparticles,
The possible applications of nanotechnology in
environmental technology are shown below under
ucarbon nanofibre membranes or CNTs for
filtration,
selected application headings. This presentation
makes no claims to completeness. The application umicroporous thin film based on inorganic,
areas can be assigned to one or more environmen- crystalline materials such as zeolite or porous
tal technology fields in Hessen (see Table 1, pages silicon
20 / 21 and Table 2, pages 26 / 27).
usupported polymer membranes, the pores of
which are filled with a functional polymer or
Application area: Filtration
oligomer liquid,
(filters, membranes)
29
Practical example of a membrane: Application area: pollutant retention
nanofibre coating for filter materials
Technology areas: water / wastewater, waste,
The development of filter materials with a new clean air, integrated product policy
type of architecture has been worked on in
Nanoparticles and nanostructured surfaces can be
cooperative research between the Philipps-
used in exhaust air cleaning and water purification
University Marburg (Prof. Dr. Andreas Greiner,
to retain pollutants by absorption, adsorption and
Prof. Dr. Joachim H.Wendorff) and the filter
immobilisation in exhaust air cleaning and water
manufacturer Hollingsworth & Vose – with finan-
purification. The technological base is formed by
cial support from the Federal Ministry of Educa-
fixed-bed nano-matrices from carbon, zeolites or a
tion and Research (BMBF). The technological
membrane with high selectivity, surface and sorp-
base is a nanofabric made of fibres revealing an
tion capacity.
average diameter of 200 nanometers or smaller.
The “Nanoweb®” filter, the development of Application examples are:
which emerged from the collaboration, is based
on a thin layer of fibres on a carrier material. The
udendritic nanoscale chelating agents for reten-
tion of metal ions such as Cu(II) ions from
nanofibre lattice determines the filter fineness.
industrial wastewaters (e. g. ultra-filtration) or
The advantage of this filter medium is a small
for reduction of chlorinated alkenes such as
overall pressure loss with simultaneous high
perchlorethylene (PCE), or
intake capacity of the separated particles. Filter
replacement intervals are increased and the umolecular sieve material made of porous, activa-
energy required to flow through the filter is sig- ted nanocarbon (Carbon Nano Tubes) as a sorp-
nificantly reduced. The plastic nanofibres are tion agent for dioxins or for gas separation.
manufactured using the electrospin process. The
Amongst other things, a significant benefit is the
filter can be used for different filtering purposes;
high sorption energy, particularly of Carbon Nano
the market value is estimated at several hundred
Tubes (it is almost three times higher than that of
million Euros.
activated charcoal). Other possible uses are seen
in the immobilisation of heavy metals or radionu-
The first products have already found an applica-
clides. However, large-scale applications in the
tion. Ion bombardment and etching, self-organisa-
near future are restricted by low availability and
tion of the electron spinning or molecular imprint-
high costs.
ing are used as manufacturing methods for nan-
otechnological membranes. The first products are already available on the mar-
ket (nanoscale fixed bed matrix for arsenic reduc-
Literature: EPA (2002), Masciangioli, Zhang (2003),
tion); a number of materials are currently being
Siegel et al. (1999), TAB (2004)
researched.
30
Application area: Catalytic Pollutant Practical example of pollutant decomposition:
Decomposition Sunlight replaces chlorine in the swimming pool
Technology areas: water / wastewater, clean air, An innovative swimming pool coating for clean-
integrated product policy ing the pool water (JUSTadd-WATER® technol-
ogy) is about to be launched on the market. It
Catalytic processes can decompose pollutants
was developed as a result of collaboration
using oxidation and reduction. Nanoparticles and
between the Technische Universität Darmstadt
nanostructured surfaces can be used here for
(Dr. Thomas Mayer, material and geoscience
example in exhaust air and wastewater catalysis
faculty, specialist area – surface research) and
technology, soil and polluted site decontamina-
Böhme Schwimmbadtechnik (Mario Böhme).
tion, odour breakdown, and in fuel cells or in com-
This resource-saving technology is based on the
bustion processes (petrol engine). The catalytic
cleaning effects of nature and protects the envi-
converters are partly activated by light (photo-
ronment by dispensing with the chemicals
catalysis). The technical bases and application
needed, e. g. chlorine, for water sterilisation in
examples are:
the established oxidation methods. The techno-
u catalytic converters with gold nanoparticles as logical base is a microscopically thin functional
an odour filter, layer which is distributed evenly over the surface
of the swimming pool. The layer consists of a
ucatalytically effective nanoparticles in (ceramic) special chemical compound based on nanotech-
films of fuel cells or for increased efficiency in
nology which uses two natural cleaning pro-
fuel combustion,
cesses: Firstly, all kinds of bacteria and algae are
u formation of catalytically effective nano metal killed directly on the swimming pool wall with
oxide particles by using the protein structure of electrons stimulated by light. Adhering dirt is
ferritin for the reduction of chromium-VI to broken down into its chemical structure by the
insoluble chromium-III in the groundwater, photocatalytic reaction, rinsed out by the water
and washed away by the water movement in the
unanoparticles of various oxidation and reduc- swimming pool. Secondly, the layer uses light to
tion agents (titanium dioxide, zinc oxide, iron
form active oxygen and hydroxyl radicals which
hydroxide pellet or bimetals such as iron / pal-
evenly distribute themselves in the water volume
ladium, iron / silver or zinc/palladium, etc.) can
of the swimming pool and thus also serve to ster-
stimulate pollutant breakdown and microbial
ilise the pool water.
growth. Zinc oxide nanoparticles can be used
as photocatalysts for the treatment of chlori-
nated phenols and simultaneously as sensors,
31
The benefits and uses of the implementation of Application area: nanosensors
nanotechnology can be seen in the production of (Lab-On-Chip systems)
highly selective catalysts for pollutant decomposi-
Technology areas: analytics, measurement,
tion and the process industry:
control and regulation technology
uimprovement in efficiency of available tech- Environmental analytics are concerned with
nologies such as in-situ pollutant decomposi-
analysing substances or substance mixtures and
tion, ultra-filtration,
their composition or determining their physical
upollutant decomposition in chemical reactions properties such as solubility, steam pressure, melt-
or in biological pollutant decomposition with- ing point, boiling point, and flash point.
out undesired side-products through high
Nanobased sensors can be used for detection,
reactivity of nanoparticles resulting from their
analysis and in-situ monitoring; they can also be
crystal form and lattice arrangement,
partly used simultaneously as catalysts (see app-
u nanoscale particles can be removed more lication area: catalytic pollutant decomposition).
effectively from the desired contamination Technological bases are formed by reaction, ad-
location, and sorption or bonding processes in sensors for use in
optical, biological, chemical or physical analysis.
usignificant resource savings by using cus-
tomised catalysts in the process industry which Chemical sensors consist of a receptor (made, for
increase the reaction yield and reduce the example, of metals, semi-conductors or polymers)
reaction energy. which interacts with the substances to be analysed.
These are converted into electrical impulses by a
It is true that the use of nanotechnology for manu-
transducer and forwarded. The following applica-
facturing catalysts is not new, but more targeted
tion examples of chemical sensors based on nano-
and rapid development started only a few years
technology are known:
ago with increasing technical progress in basic
research. The applications are still partially in the uconductometric, nanocrystalline metal oxide
pilot stage. Therefore, the essential challenges for sensors or semi-conductive single-wall CNT
the future will doubtless be in an acceleration of as conductometric gas sensors for detection
basic research and an increased implementation of nitrogen dioxide or ammonia,
and use of this basic cross-sector technology.
upalladium nanowire as conductometric
Literature: Bachmann (1998), Masciangioli und Zhang (2003), hydrogen sensor,
TAB (2004)
usensors – adsorbent, chemically functionalised,
or coated with nanoporous zeolite film – with
nano strain gauge, or
32
H2O2 The challenges are to master the critical dimen-
O2 sions and to reach long-term thermal and chemical
UV-light stability of the material. There are still partial prob-
_ lems in the coupling to electrical or optically read-
OH able structures. The development and manufac-
TiO2 → e– + h+
H2O ture require a high degree of interdisciplinarity
between the chip industry, biochemistry and engi-
neering.
Substrate
A number of sensors are already in use. Most of the
concepts, e. g. the development of more practical
Figure 14: New functionality through nanotechnology: chemical sensors based on molecularly imprinted
Photocatalysis with TiO2-nanoparticles (Source: NANO-X) polymers, are still at the research stage.
33
3 Innovation potential and
technology transfer approaches
As a cross-sector technology, nanotechnology has uif miniaturisation is to be further developed or
a large innovation potential for many technical compact systems (e. g. sensors and energy
applications in the field of environmental protec- supply) are necessary, or
tion. The use of nanotechnology can result in more
efficient, more selective or miniaturised solutions.
uif nanotechnology is relevant as an additional
competitive factor.
It can contribute directly to resource efficiency and
indirectly to the improvement and further develop-
First questions, how nanotechnology can be used
ment of environmental technology applications.
in one’s own products or to create new business
Thus, a coupling of both technologies can con-
areas
tribute to further strengthening of Hessen’s scien-
tific and economical position in the fields of envi-
ronmental technology and nanotechnology. To decide whether or how nanotechnology can
find use in a company’s own products and process
or for creating new business areas, the following
Nanotechnology is particularly interesting for
points should be checked (Classification according
Hessen’s environmental technology
to Bullinger 1994):
enterprises if …
Can nanotechnology replace a
34
Is nanotechnology complementary to Possible examples
35
Differentiation, technology leadership Knowledge transfer and exchange among the
and system integration are starting points for various disciplines drive the application forward
business strategy
Knowledge transfer and exchange among the vari-
ous disciplines are also an impetus for the use of
uPrice differentiation nanotechnology in environmental technology. To
The use of nanotechnology in environmental
date, the contact points between opportunity-
technology clearly results in more cost-effec-
driven and research-driven nanotechnology and
tive and more efficient products and processes
the problem-oriented approach of environmental
(e. g. low-cost solar cells with improved effi-
technology are still missing. Environmental tech-
ciency). Usage costs must be compared with
nology companies are often unaware of the spec-
manufacturing costs. Easy-to-clean surfaces
trum provided by nanotechnology or where its
save cleaning costs or result in more efficient
application areas are. Conversely it is also the case
system operation, e. g. the coating of solar cells.
that nanotechnology businesses and research insti-
uTechnology leadership differentiation tutions are unaware of the environmental technol-
The use of nanotechnology in environmental ogy problem areas and challenges.
technology (e. g. self-sufficient measurement
sensors for pollutants with high precision or The gaps between technology-push and
highly selective membranes) enhances a tech- market-pull must be closed
nology qualitatively, or fills a market niche.
Small and medium-sized enterprises (SME) will The objective and starting point for Hessian envi-
become “technology enablers” for nanotech- ronmental technology companies – particularly in
nology and thus assume a pioneering role. the fields: “water / wastewater”, “energy”, “clean
air”, “measuring and control technology” and for
uSystem integration by system providers integrated policy issues – is therefore to close the
As nanoresearch requires high expenditure
gap between technology-push and market-pull.
and qualified staff, horizontal or vertical coop-
erations in the value chain are useful and nec-
essary. In turn, such cooperations may emerge
on the market as system providers and thus
also follow the general trend in environmental
technology. In this way, the integration ability
among environmental technology companies
is particularly remarkable, as they often inte-
grate other technologies in their products and
services and provide them as systems with con-
crete customer benefits. Cooperation or opera-
tor models can form new business bases, offer-
ing Hessen’s SMEs the chance to participate in
nanotechnology as part of the value chain.
36
Basic starting points for technology transfer The HA Hessen Agentur GmbH14 manages these
action lines and is the contact partner for nano-
The promotion of technology and information
technological companies and environment tech-
transfer between environmental technology and
nology businesses which are interested in nano-
nanotechnology should already be effected in both
technology for improving their products or
disciplines in the early phases of research. Basic
processes. It advises on promotional and location
research should take the possibilities for subse-
issues and guides interested parties to the respon-
quent marketing more into account than it has
sible technology transfer points between university
done up to now. Vertical and horizontal coopera-
and business – in collaboration with the technology
tion in the value chain must therefore be pursued in
transfer network (TTN-Hessen)15 – and to European
order to combine product development and prac-
partners. The Hessen Agentur GmbH publishes
tice, and in particular to integrate SMEs in the
competence atlases for individual technologies in
development process.
order to provide an overview of the separate busi-
Various possibilities are available here for compa- ness and research activities in Hessen.
nies in Hessen. This can take place in virtual form
Against the background of the study of environ-
by setting up “Communities” or establishing busi-
mental technology providers in Hessen (M-Result
nesses in a value chain, or by research and devel-
2002), the following strategies of Hessen environ-
opment cooperation in a specific technology park
mental technology companies are also important
or industrial estate.
for nanotechnology transfer.
Materials Valley e.V.11, a competence network for
material research and material technology in the
uResearch: Key drivers of the environmental
technology market in the past were legislation
Rhein Main region, is a good example of how
and promotional programmes. The extensive
important impulse effects can be achieved by a
German and European research programmes
thematic cluster of competences and contribute to
provide opportunities for promoting technol-
the image of a technology and the region. A link-
ogy research and project consortia.
up between nanoscientists has been initiated in
Hessen with the recently established “NanoNetz- uCollaboration: The importance of joint research
werkHessen12” network. and development projects has been low up to
now. This contrasts with the particular research
The “hessen-nanotech” and “hessen-umweltech”13
intensity and interdisciplinarity of nanotechnol-
action lines of the Hessian Ministry of Economics
ogy, which means that businesses must
support the research and development of environ-
develop cooperation and networks to incorpo-
mental technology and nanotechnology products
rate know-how in their own research and devel-
and services – e. g. by competence atlases, infor-
opment.
mation brochures, events and projects – and make
Hessen’s competencies better known both inside
and outside the region.
11 http://materials-valley-rheinmain.de 14 www.hessen-agentur.de
12 www.nanonetzwerkhessen.de 15 www.ttn-hessen.de
13 www.hessen-nanotech.de and
www.hessen-umwelttech.de
37
u Differentiation: The strategy of smaller compa- To ensure the subsequent transfer of results, indus-
nies is market differentiation with an innovative try should increasingly make its requirement pro-
product. Nanotechnology can be an approach files available to researchers and institutions. Net-
here for using the available nanotechnology working with research and industry must be further
research competences in Hessen for joint envi- expanded if expert knowledge is to be more effec-
ronmental technology innovations. tively used and integrated in the future. The “hes-
sen-nanotech” and “hessen-umwelttech” action
A further opportunity to manage cooperation in
lines support companies and research institutions
research and development is offered by research
here by making contacts with research and devel-
programmes aimed at technical implementation of
opment.
available research results and the promotion of
mature products. In this way, entry to nanotechnol- However, it is also clear that nanotechnology –
ogy for companies is made possible via research like all branches of science – is an international
and development cooperation with universities research field. The networks are linked world wide.
and nanotechnology startup businesses. Accordingly, the exchange of information and par-
ticipation in research projects takes place interna-
tionally. However, at the regional level, the bound-
ary conditions for the establishment of technology
businesses can be decisively influenced in order to
achieve or maintain international technical market
leadership.
38
Appendix
Literature
In the author’s opinion, the literature printed in bold type is BMBF (2002)
recommended for an in-depth analysis or wide comprehen- Nanotechnologie in Deutschland – Standortbestimmung,
sive overview of nanotechnology. Studie des Bundesministerium für Bildung und Forschung
(Hrsg.), Referat Öffentlichkeitsarbeit, Bonn 2002
Altmann, Stephan (2004)
Chemical Nanotechnology for Sustainability, lecture by Bullinger, Hans-Jörg (1994)
Dr. Stephan M. Altmann, BASF Polymer Research / Poly- Einführung in das Technologiemanagement: Modelle,
mer Physics, BASF Ludwigshafen, at the “Nano meets Methoden, Praxisbeispiele, Teubner Verlag, Stuttgart 1994
environmental technology” symposium on July 02,
2004 at the Fraunhofer IAO in Stuttgart Colvin, Vicki (2003)
39
Farkas, Robert et al (2004) Harper, Tim (2002)
Nanotechnologie pro Gesundheit: Chancen und Risiken (Inno- The emerging cutting-edge Technology – Nanotechnol-
vations- und Technikanalyse), Bericht im Auftrag des Bundes- ogy international, in: VentureCapital Magazin Sonderaus-
ministeriums für Bildung und Forschung durch Aachener gabe: Nanotechnologie – Märkte und Visionen, 3. Jahr-
Gesellschaft für Innovation und Technologietransfer AGIT mbH gang, November 2002, Verlag GoingPublic Media AG,
(Aachen), Aachener Kompetenzzentrum Medizintechnik Wolfratshausen 2002
(Aachen), Fraunhofer Institut für Lasertechnik e.V. (ILT) (Aachen),
Hinsch, Andreas (2004)
Fraunhofer Institut für Molekularbiologie und Angewandte
Neue Potentiale in der Solarenergieforschung durch
Oekologie e.V. (IME) (Aachen) und IGES Institut für Gesund-
Nanotechnologie, lecture by Dr. Andreas Hinsch, Fraun-
heits- und Sozialforschung GmbH (Berlin), Aachen 2004
hofer ISE, Freiburg, at the “Nano meets environmental
Download at
technology” symposium on July 02, 2004 at the Fraun-
www.bmbf.de/pub/nano_pro_gesundheit_bericht.pdf
hofer IAO in Stuttgart
Feder, Barnaby (2003) Download at www.bum.iao.fraunhofer.de/nano
As uses grow, tiny materials’ safety is hard to pin down,
Hullmann, Angela (2001)
New York Times of 03/11/2003, New York 2003
Internationaler Wissenstransfer und technischer Wandel –
FEH (2004) Bedeutung, Einflussfaktoren und Ausblick auf technolo-
Materialbasierte Technologien in Hessen: eine Bestand- gische Implikationen am Beispiel der Nanotechnologie in
saufnahme, Studie der Forschungs- und Entwicklungs- Deutschland, Physika-Verlag, Heidelberg 2001
gesellschaft Hessen mbH (FEH), Wiesbaden, FEH-Report
Masciangioli, Tina; Zhang, Wei-Xian (2003)
Nr. 665, Wiesbaden 2004
Environmental Technologies at the Nanoscale,
Frost & Sullivan (1999) Environmental Science & Technology, March 1, 2003
European Water Pollution Monitoring Markets, Report Download at www.nano.gov/html/res/GC_ENV_
Nr. 3785-15, Frost & Sullivan Ltd, London 1999 PaperZhang_03-0304.pdf
40
Appendix
Royal Society and Royal Academy of Engineering (2004) VDI (2004/2)
Nanoscience and nanotechnologies: opportunities and Nanotechnologie als wirtschaftlicher Wachstumsmarkt –
uncertainties, Study of the Royal Society and the Royal Innovations- und Technikanalyse, Zukünftige Technolo-
Academy of Engineering, London, 2004 gien Nr. 53, Bearbeitung durch Wolfgang Luther, Nor-
(www.raeng.org.uk) bert Malanowski, Gerd Bachmann, Andreas Hoffknecht,
Dirk Holtmannspötter, Axel Zweck, Zukünftige Technolo-
Siegel, Richard; Hu, Evelyn; Roco, Mihail (1999)
gien Consulting der VDI Technologiezentrum GmbH,
Nanostructure Science and Technology – AWorldwide
Düsseldorf 2004
Study, by National Science and Technology Council
(NSTC), The Interagency Working Group on Nano-Science, VentureCapital Magazin (2002)
Engineering and Technology (IWGN), December 1999, VentureCapital Magazin Sonderausgabe: Nanotechnolo-
Maryland 1999 gie – Märkte und Visionen, 3. Jahrgang, November 2002,
Download at http://itri.loyola.edu/nano/final/ Verlag GoingPublic Media AG,Wolfratshausen 2002
VDI (2004/1)
Präsentationsmaterial „Reise in den Nanokosmos“ des
VDI Technologiezentrum GmbH, Zukünftige Technologien
Consulting, Download at
www.nanotruck.net/pdf/nanoTruck_Broschuere.pdf
41
Research programmes and the market
Nanoresearch, particularly basic materials research, USA
is largely financed out of public research funds.
National Nanotechnology Initiative (NNI),
Many countries have set up their own research pro-
www.nano.gov
grammes. The USA spent a total of 1,857 million
US $ for nanotechnology research and develop- Budget: 2002: 600 million US $
ment over the period from 1997 to 2003, and 2003: 770 million US $
approximately 770 million US $ in 2003. In the same 2004: 849 million US $
period, 1,281 million US $ was invested in research 2005: 982 million US $
and development in Western Europe, an increase of
21st Century Nanotechnology Development Act
500 per cent compared to 1997 (Greenpeace
2003). Figure 15 shows an international comparison Budget: 2005 to 2008:
of the expenditure on nanotechnology promotion just under 3,700 million US $
in 2004.
Elements of research project related to
environmental technology:
u Nanotechnology in environmental protection
u Possible effects of nanotechnology on the
environment and society
800
EU
Nanotechnology promotion
in millions of Euros
right:
Table 3: International and national research programmes
with respect to nanotechnology and relevance to the environ-
mental protection (own research)
42
Appendix
D Nanoresearch in the USA
43
Nanoresearch projects at the National Center For Environmental Research of the
U.S. Environmental Protection Agency (EPA)
44
Appendix
Nanoresearch in the EU ubetter coordination of national EU
research policies,
In the 6th Framework Programme of the European
Union, approximately 1,300 million Euros, 7.5 per ufavourable working conditions for technology
cent of the research funding applied for, is reserved transfer and innovation: transfer of research
for the primary subject areas of nanotechnology excellence in products and processes,
research and nanosciences, knowledge-based mul-
tifunctional materials, new production processes
upromotion of public acceptance for nano-
technology, and
and equipment. Altogether, 3,420 millionEuros will
be provided for projects in the “Industrial Technolo- uinclusion of the environmental, health and
gies” and “Materials” areas. Environmentally safety aspects in nanotechnology research.
friendly technologies, which also include applica-
tions of nanotechnology, play a central part here Nanoresearch in Germany
(European Commission 2003).
The Federal Ministry of Education and Research
Apart from long-term interdisciplinary research to (BMBF) has been promoting nanotechnology since
expand the present state of knowledge, the 6th the early 1990s in the framework of the “Material
Framework Programme focuses principally on Research” and “Physical Technologies” program-
engineering for the development of materials and mes and “Laser Research” and “Optoelectronics”. In
components, the development of measurement the last six years, the BMBF has promoted joint
and control equipment and instruments, and nanotechnology projects with a total of 340 million
applications in areas such as medicine, chemistry, Euros. Thus the expenditure has continually increa-
optics, energy technology and environmental sed.
technology (VDI 2004/1).
At the initiative of the BMBF, eight nano compe-
With respect to the next framework programme, tence centres have been established since 1998
the European Commission specified a harmonised with the aim of improving research networking and
innovation policy at the European level and criti- promoting collaborations18. The tasks of the com-
cised the unfavourable working conditions for petence centres include public relations, educa-
innovations in a communication of May 12, 2004 tion and further training, the creation of an eco-
and others. Against this background, the European nomically attractive milieu and advising interested
Commission proposed the following strategy:17 parties, mainly from industry, on the respective
nanotechnology field. The BMBF favours an initial
uplanned doubling of the budget for nanotech- coordination of R&D activities and projects,
nologies / new materials for the 7th Framework
together with advice for applicants on the centres.
Research Programme (to run from 2007 to
Table 4 shows the thematic focus points and total
2013) (budget to date in the 6th Framework
nanotechnology promotion funding by the BMBF
Programme: 1,300 million Euros),
for the period 2002 to 2005 (Bachmann and Rieke
utransnational collaboration of 2004).
research institutions,
45
Subject area: Nanomaterials Subject area: Communication technologies
Table 4: Thematic focus points and nano promotion grant from the BMBF from 2002 to 2005, in millions of Euros
(Bachmann und Rieke 2004)
Finally, mainstream innovations have been identi- u Nano for Life: nanomaterials and nanobio-
fied by the BMBF and a future research pro- technology for life sciences and health.
gramme with 250 million Euros has been put in
place for the reinforcement of nano competence
u NanoChem will be the focus point in the
framework programme “Material innovations
in Germany. The following focus points are pro-
for industry and society – WING”: Chemical
moted:
nanotechnologies are promoted for new
u NanoFab: ultra-precise high throughput materials and products.
manufacture for nanoelectronics,
A search for research projects in Germany with
u NanoLux: efficient radiation sources for clear reference to nanotechnology and applica-
innovative light applications, tions in environmental technology produced no
results. However, there are research projects, e. g.
u NanoMobil: nanomaterials and verification methods or filter systems based on
nanotechnologies in the car, and
nanotechnology which could also be used in envi-
ronmental technology.
46
Appendix
Nanoresearch by industry Market
The industry research and development activities Information about estimating markets, market
concentrate mainly on base materials and chem- sizes, the patent situation and time periods for
istry – German companies have traditionally been commercialisation is extremely limited. Applica-
strongly represented in this area (Harper 2002). tion and market perspectives of nanotechnology
This is confirmed by an assessment of patents for products and product groups have been
(see Reitberger in VentureCapital 2002, Hullmann analysed and evaluated in a current study by the
2001, own research): A large part of the business is VDI: “Future Technologies Consulting for the
represented by large established concerns such as BMBF”. There was a particular focus on the market
BASF, Degussa, Henkel or Siemens which have potential in selected lead markets: chemicals,
their own research departments and use spin-offs automotive construction, optics, medicine / life sci-
to enter the market with new competences and ences, and electronics. Indicators of the market
technologies. There are also spin-offs as start-ups potential have also been derived from patent data.
at the universities and cooperations between large In addition, information on the implementation of
enterprises and the universities with a view to ben- nanotechnology in German companies was
efiting jointly from their from knowledge and infra- acquired and evaluated in a survey (VDI 2004/2).
structure (cf. die Degussa Projekthäuser19) On the This showed that the chemicals area, including
other hand, small and medium-sized enterprises materials, clearly occupies the top position among
(SME) are still not a driving force in the research nanotechnology companies in Germany. The cen-
and development of nanotechnology systems. The tral functional characteristics are definitely conven-
reasons for this are the high investment costs for tional and application-specific, such as improved
personnel and infrastructure and insufficient coop- material properties and surface functionalisation
eration among companies. However, due to the (Werner 2004). According to a study by Business
special requirements which nanotechnology Communications Company Inc. (BCC), a tenfold
places on interdisciplinarity, it will not be long increase compared with the present day is antici-
before SMEs complete cooperation agreements pated in the period 2005-2010 for the area of
with divided competencies. nanofiltration and membranes (in Royal Society
2004). BCC gives a market volume of 70,000 mil-
An important contribution is made in Germany by
lion US$ over the next 20 years for seawater desali-
numerous small and medium-sized nano enter-
nation using nanofiltration techniques (in TAB
prises which were founded as start-ups and focus
2004).
on specialised development. Their business areas
are more oriented to manufacturing, analysis and However, it is anticipated that nanotechnology will
equipment technologies while the large enter- affect almost all sectors (Werner 2004). Among the
prises are more interested in system solutions with European states, Germany has certainly the best
large turnovers (Bachmann 2003/1). qualifications for successful activity in the nano-
technology field in the medium and long term
(Werner 2004).
19 See: www.creavis.com/site_creavis/de/default.cfm?
content=projecthouses/mission
47
Technology impact assessment
The technology impacts which can be associated Attention is currently being focused on the effects
with nanotechnology have been, and are continu- of nanoparticles on human health. Investigations
ing to be, analysed and evaluated. In addition to are being carried out into their dispersion and
the companies which carry out testing of any of their effects on human organs, e.g., for example
their products which contain nanotechnology, the overcoming the blood-brain barrier or possible
BMBF has commissioned a study of “Nanotechnol- effects on cell functions. At the moment it cannot
ogy and sustainability” (BMBF 2002, Steinfeldt be stated generally whether nanoparticles are
2003, Steinfeldt et al. 2004) and of “Nanotechnol- either dangerous or harmless (Colvin 2003). No
ogy for health – opportunities and risks” as an analyses of possible impacts arising out of the use
escorting measure for the promotion of nano- and disposal of nanotechnology products have
technology. The latter publication analyses medical been made, and no account has been taken of
applications and health effects of nanotechnolo- integrated product policy (IPP) aspects. The USA
gies in diagnosis, therapy and prevention, taking Environmental Protection is known to have con-
account of possible side effects (Farkas et al. 2004). ducted a research project on the application of life
The American EPA has initiated a four million US$ cycle analyses in nanotechnology (Royal Society
programme to examine the environmental effects 2004). There is also to some extent a lack of infor-
of nanotechnology. However, this contrasts with mation on positive and negative long-term effects
approx. 849 million US$ made available for nano- and product behaviour in connection with a num-
technology research and development in 2004 ber of potential applications of nanotechnology.
(Feder 2003). As shown in Table 4 (page 46), an The absence of standards also makes an evalua-
average of just under 0.3 per cent of the nanotech- tion difficult.
nology project promotion budget was spent on
A differential consideration of the various applica-
technology analysis in Germany in the 2002–2005
tion fields is necessary for the further development
grant period.
and consideration of possible opportunities and
The office for evaluating technology impact in the risks. Generalised assessments can hardly be made
German Bundestag (lower house of the German in view of the diversity of nanotechnology; instead,
Parliament) reveals in its final report, “Nanotech- potential opportunities and risks should be evalu-
nology status and perspectives”, that the state of ated in individual tests early and objectively against
research for potential environmental and health the concrete application background. For example
effects during the manufacture and application of the DECHEMA / VCI working group, “Responsible
nanotechnology processes and products is still Production and Use of Nanomaterials” 20, sets out
unsatisfactory. Insufficient knowledge could serve to identify opportunities and possible risks of
to hinder the introduction of nanotechnology on chemical nanotechnology and to advance success-
the market, because society could take this “insuf- ful economic and technical implementation by ini-
ficient knowledge” as a reason for general non- tiating appropriate actions with reference to ethi-
acceptance of nanotechnology (TAB 2004). cal, ecological, social and economic aspects.
20 See: www.dechema.de/NANOSAFETY.html
48
Appendix
Information & Addresses
Contact persons for nanotechnology and/or environmental technology advice in Hessen
49
Nanotechnology competence networks in Hessen
50
Appendix
Selection of university research in Hessen in the nanotechnology field
Universität Kassel
Process development and analytics
Nanostructuring Johann Wolfgang Goethe-Universität Frankfurt am Main
Johann Wolfgang Goethe-Universität Frankfurt am Main
Nanoanalytics
Universität Kassel
Justus-Liebig-Universität Gießen
Ultra-thin functional layers Fachhochschule Wiesbaden
Fachhochschule Wiesbaden
Nanobiotechnology
Molecular architectures Justus-Liebig-Universität Gießen
Universität Kassel Philipps-Universität Marburg
51
Participants from Hessen in the BMBF nano competence centres
CC-NanoBioTech NanoMat
Nanobiotechnology competence centre Industrial Stakeholders / SME:
Industrial Stakeholders / SME: None u Degussa AG, Hanau
Contact: u DECHEMA e.V., Frankfurt am Main
www.cc-nanobiotech.de u Merck KGaA, Darmstadt
CC-NanoBioTech u SusTech, Darmstadt
Universität Kaiserslautern u Technische Universität Darmstadt
Fachbereich Physik Contact:
Prof. Dr. Christiane Ziegler www.nanomat.de
Erwin-Schrödinger-Straße 56 Nanomat - Forschungszentrum Karlsruhe GmbH
D-67663 Kaiserslautern Dr. Regine Hedderich
Postfach 3640
CC-NanoChem Nanochemistry competence centre D-76021 Karlsruhe
Industrial Stakeholders / SME:
NanOp – Nanotechnology for optoelectronics
u Adam Opel AG, Rüsselsheim
u Degussa AG, Hanau Industrial Stakeholders / SME:
u Lurgi AG, Frankfurt am Main u Akzo Nobel HPMO, Marburg
u Merck KGaA, Darmstadt Contact:
u Siemens AG, Frankfurt am Main (formerly Siemens Axiva) www.nanop.de
u W.C. Heraeus GmbH, Hanau Institut für Festkörperphysik
u DECHEMA e.V., Frankfurt am Main Technische Universität Berlin
u Technische Universität Darmstadt Sekr. PN 5-6
Contact: Matthias Kuntz
www.cc-nanochem.de Hardenbergstraße 36
CC-NanoChem D-10623 Berlin (Germany)
c/o Leibniz-Institut für Neue Materialien
Prof. H. Schmidt Ultradünne funktionale Schichten Sachsen
Im Stadtwald – Geb. 43 (Ultra-thin functional layers)
D-66123 Saarbrücken Industrial Stakeholders / SME:
u Merck KGaA, Darmstadt
Nanoanalytics competence centre
u Leica Microsystems GmbH, Wetzlar
Industrial Stakeholders / SME: u Leybold Systems GmbH, Hanau
u Nanosensors, Wetzlar u Verband Deutscher Maschinen- und
u Omicron NanoTechnology GmbH, Taunusstein-Neuhof Anlagenbau e.V., Frankfurt am Main
u Oxford Instruments GmbH, Wiesbaden Contact:
u Telekom Technologiezentrum, Darmstadt www.nanotechnology.de
u Focus GmbH, Hünstetten Geschäftsstelle des Nano-CC-UFS im Fraunhofer IWS
u Universität Kassel Dresden
Contact: Dr. Ralf Jäckel
www.centech.de c/o Fraunhofer IWS Dresden
CeNTech GmbH – Münster Winterbergstraße 28
Dr. Frank Schröder-Oeynhausen D-01277 Dresden
Gievenbecker Weg 11
D-48149 Münster
(As of 2004, partially updated)
Ultra-precise surface machining competence centre
Industrial Stakeholders / SME:
u NTG Neue Technologien GmbH & Co. KG, Gelnhausen
Contact:
www.upob.de
CCN Ultrapräzise Oberflächenbearbeitung e.V.
– Braunschweig
Dr. Uwe Brand
Bundesallee 100
D-38116 Braunschweig
52
Appendix
World Wide Web links to nanotechnology
www.hessen-nanotech.de www.kompetenznetze.de/navi/de/Innovationsfelder/
nanotechnologie.html
Platform for nanotechnology in Hessen
Information server (Cordis) of the EU for
www.nanotech-hessen.de nanotechnology in the 6th framework programme
53
Occasional Paper Series
of the Aktionslinie hessen-umwelttech of the
Ministry of Economy, Transport, Urban and
Regional Development in Hessen
Volume 2 Nanomedicine
Innovation potentials in Hessen
for medical technology and the
pharmaceutical industry
(jointly with the Aktionslinie hessen-
biotech, only in German language)
Volume 3 NanoAutomotive
Innovation potentials in Hessen for the
automotive industry and its subcon-
tractors (only in German language)
Volume 4 NanoCommunication
Guide to communication of chances
and risks for small and medium-sized
nanotech companies in Hessen
(only in German language)
Volume 5 NanoOptics
Nanotechnologies for the optical
industry. A basis for future innovations
in Hessen (only in German language)
Volume 6 NanoProduction
Nanotechnology in the production
process as a potential innovation
source for companies in Hessen
(only in German language)