Professional Documents
Culture Documents
Page 1 of 46
Page 2 of 46
W. R.MEADOWS,,
SAFETYDATA SHEET
ified as non-hazardous p
HA as an "article," a manufa
ng manufacture that does n
SARA
%by Weight 313
dry chemical.
n monoxide, carbon dioxide, and incompl bustion products.
UIPMENT: Avoid smoke inhalation. Use a te res irator rotection.
. .L·.:.-~-.
P1!]1:0111lf8~1J~,Q'E~lf-t~
le. Product is a solid.
- . ,JPtlil~TI1N~·pt~~~.1t~ll~1iiI,~,
equirements.
PEL/STEL
conditions .
. N/A
APPEARANCE: R
:rAtrlL.
Page 3 of 46
SAFETYDATA SHEET
TENTIAL:N/E
Dave Carey
The information contained herein is based on the data available to us and is believed to be correct. However,
we make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained
from the use thereof We assume no responsibility for injuryfrom the use of this product described herein.
Page 4 of 46
g/assAdvantage
Safety Data Sheet Innovation and Recycling At Its Best
Crushed glass (glass sand) is not classified as a hazardous material by the criteria of the OSHA Hazard
Communication Standard, Title 29, Code of Federal Regulations, Section 1910.1200, Hazard Communication.
Contains no free (or crystalline) silica; all components are amorphous/non-crystalline.
Nuisance dust concern only.
Chemical Name: 100% Soda-Lime Silicon Dioxide Glass CAS Number: 65997-17-3
Known As: Crushed Glass Media
Inhalation: If product is inhaled, move to fresh air and contact a physician. Dust in excess of recommended
exposure limits may result in respiratory tract irritation.
Ingestion: Product is not hazardous if ingested, however consult a physician if a large amount is ingested.
Eyes: Flush thoroughly with water and contact physician if irritation persists.
Skin Contact: No known hazards, however, washing a~er contact is advised.
Spills: Sweep up and discard; avoid excessive dusting. This material is not a SARA Title III reportable substance.
Respiratory: If dust concentrations exceed recommended Permissible Exposure Limits, use NIOSH-approved
respirators.
Ventilation: Local exhaust.
Nuisance Dust (total): ACGIH 10 mg/m 3 TLV (units) depends upon particle size
Nuisance Dust (respirable): OSHA PEL 5 mg/m 3 depends upon particle size
Carcinogenity:
NTP: Not listed IARC Monographs: Not Listed OSHA Regulation: Not Listed
Routes of Entry:
Lungs (breathing): Yes Ingestion: No Skin: No
Health Hazard (acute & chronic): Dust in excess of recommended exposure limits may result in irritation to the
respiratory tract.
Respiratory Protection: If dust concentrations exceed recommended Permissible Exposure Limits, use NIOSH-
approved respirators.
Eye Protection: NIOSH-approved safety glasses or goggles (tight fitting recommended)
Ventilation: Local Exhaust Protective Gloves: Not required
Other Protective Clothing or Equipment: None required
Toxicity: N/A
Page 5 of 46
Waste Disposal Method: Dispose in approved landfill in accordance with federal, state and local regulations.
This material is not a SARA Title III reportable substance.
l
DOT Identification: Not regulated by DOT
N/A
Abbreviation References:
N/A = Not Applicable
mg/m3 = Milligrams per cubic meter
TLV = Threshold limit value
NIOSH = National Institute of Safety & Health
OSHA = Occupational Safety & Health Administration
CAS = Chemical Abstracts Service
ACGIH: American Conference of Government Industrial Hygienists
SARA Title III = Emergency Planning and Community Right-to-Know Act
DOT = Department of Transporatation
August 6, 2015
This information isfurnished without warranty, representation, inducement, or license of any kind, except that it is accurate to the best of
Glass Advantage Inc's knowledge or obtained from sources believed by Glass Advantage Inc to be accurate, and Glass Advantage Inc does
not assume any legal responsibility for use or reliance upon same. Customers are encouraged to conduct their own tests, read the product
label, and obtain data for sources, which they know to be reliable before using any product.
Page 6 of 46
W. R.MEADOWS.,
SAFETYDATA SHEET
HAZARD STATEMENTS
HMIS WARNING!
!Health! I1 I Flammable Liquid and vapor.
IFlammability I I2 I Causesskin, eye, respiratory irritation.
I Reactivity I Io I Suspected of causing genetic defects.
I Personal Protection I I I Causes damage to liver, kidneys, lungs, and blood.
Harmful if inhaled.
May be fatal if ingested and enters airway.
PRECAUTIONARY STATEMENTS
Use only in well-ventilated areas.
Avoid breathing vapors and direct contact.
Store in well-ventilated location.
Wear appropriate personal protective equipment.
Keep away from ignition sources.
Control vapors in confined spaces utilizing mechanical ventilation.
SAFE STORAGE: Keep containers closed when not in use. Store away from ignition sources.
Page 7 of 46
SAFETYDATA SHEET
HA AC
Chemical Name: PEL PELLCEILING PEL[STEL SKIN TWA TLV[CEILING TLV[STEL SKIN
1. Xylene 100 ppm N/E N/E N/E 100 ppm N/E 150 ppm N/E
2. Light Aromatic Naphtha N/E N/E N/E N/E N/E N/E N/E N/E
3. Petroleum Asphalt 5 mg/m
3*
N/E N/E N/E 5 mg/m 3 • N/E N/E N/E
4. Petroleum Oil 5 mg/m 3+ N/E N/E N/E 5 mg/m 3• N/E 10 mg/m 3• N/E
5. 1,2,4-Trimethylbenzene 25 ppm N/E N/E No 25 ppm N/E N/E No
•: Asphalt Fumes +: Petroleum Oil mist in air N/E: Not Established
ENGINEERINGCONTROLS:Use with adequate ventilation. Use explosion-proof equipment.
PERSONALPROTECTIVEEQUIPMENT: Safet lasses, chemical-resistant loves.
CONDI
HAZAR
combus
- ,):f!~~- - -
EYECONTACT: Direct contact may result in moderate irritation. Product vapors/mists may also cause irritation.
SKIN CONTACT: Direct contact may cause mild skin irritation. Prolonged/repeated contact may result in skin irritation/dermatitis.
INHALATION: Exposure to excessive vapor concentrations may result in transient central nervous system depression (headache, fatigue,
drowsiness, loss of coordination). Intentional misuse by deliberately concentrating/inhaling vapors may be harmful or fatal.
Repeated/prolonged occupational exposures to solvents may cause permanent brain and nervous system damage.
INGESTION: Not anticipated to be an exposure route. Ingestion will cause irritation of the digestive tract.
SIGNSAND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness and
swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort. Symptoms of respiratory irritation include
runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function. Symptoms of transient central nervous
system depression include: headache, fatigue, drowsiness, dizziness, and loss of coordination.
AGGRAVATEDMEDICALCONDITIONS: Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to this product.
OTHERHEALTHEFFECTS:Xylene and Aromatic Naphtha have been shown to cause the following effects in laboratory animals: liver/kidney
effects, blood abnormalities, effects on the spleen, testes, nervous system, adrenals, cardiovascular system, and harm to the fetus. The relevance
to humans is uncertain.
Dave Carey
The information contained herein is based on the data available to us and is believed to be correct. However, we make no
warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof We
assume no responsij)ilityfor injury from the use of this product described herein.
Page 8 of 46
SAFETY DATA SHEET
CRAFCD:,
AN ERGONEi COMPANY
1. Identificat-ion
Product identifier Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder,
Loop Detector, Pavement Joint Adhesive, Polyfiber, Fiber Asphalt, Marker Adhesive,
Quikstix, Asphalt Adhesive, PCF 100, High Slope, QWIKSEAL, QWIKDOT
Other means of identification Not available.
Recommended use Pavement Crack and Joint Sealing and Preservation
Recommended restrictions None known.
Manufacturer /Importer /Supplier /Distributor information
Manufacturer
Manufacturer: Crafco, Inc.
Address: 6165 West Detroit St
Chandler, AZ 85226 USA
Contact Name: Jim Chehovits
Telephone: 602-276-0406
E-mail: jim.chehovits@crafco.com
CHEMTREC: 80D-424-9300 (North America)
+ 1-703-527-3887 (International)
2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.
*Hazards not stated here are "Not classified", "Not applicable" or "Classification not possible".
Label elements
Hazard symbol None.
Signal word Not applicable.
Hazard statement Not applicable.
Prevention Not applicable.
Response Not applicable.
Storage Not applicable.
Disposal Not applicable.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.
3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
ASPHALT 8052-42-4 20 -100
DISTILLATES (PETROLEUM), 64742-52-5 0 -40
HYDROTREATED
HEAW
NAPHTHENIC
other components below reportable levels 0 - 75
Composition comments * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.
4~ First-aid measures
Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention, if needed. Call a physician if symptoms develop or persist.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Thoroughly wash (or discard) clothing and shoes
before reuse.
Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SDSUS
49B8 Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 1/6
Page 9 of 46
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO
NOT delay irrigation or attempt to remove the lens. Get medical attention if irritation develops and
persists.
Ingestion Rinse mouth. Do not induce vomiting. Do not use mouth-to-mouth method if victim ingested the
substance. call a POISON CENTERor doctor/physician if you feel unwell.
Most important Not available.
symptoms/ effects, acute and
delayed
Indication of immediate In case of ingestion, the decision of whether or not to induce vomiting should be made by the
medical attention and special attending physician. Certain pre-existing conditions may make workers particularly susceptible to
treatment needed the effects of this chemical: asthma, allergies, impaired pulmonary function.
General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves. Show
this safety data sheet to the doctor in attendance. Discard any shoes or dothing items that cannot
be decontaminated.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. carbon dioxide (CO2). Addition of water or foam to the fire
may cause frothing.
Unsuitable extinguishing Do not use a solid water stream as it may scatter and spread fire.
media
Specific hazards arising from Fire may produce irritating, corrosive and/or toxic gases. Development of hazardous combustion
the chemical gases or vapours possible in the event of a fire. The following may develop: Acrolein.
Special protective equipment Firefighters must use standard protective equipment inducting flame retardant coat, helmet with
and precautions for face shield, gloves, rubber boots, and in endosed spaces, SCBA. Firefighters should wear full
firefighters protective dothing including self contained breathing apparatus. Structural firefighters protective
clothing will only provide limited protection.
Fire-fighting In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective
equipment/instructions equipment induding flame retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA. ALWAYS stay away from tanks engulfed in flame. Fight fire from maximum
distance or use unmanned hose holders or monitor nozzles. In the event of fire, cool tanks with
water spray. By fire, toxic gases may be formed (COx, NOx). Keep run-off water out of sewers and
water sources. Dike for water control.
Specific methods In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with
water spray. Use water spray to cool unopened containers.
Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavernen SDS US
Page 10 of 46
US. ACGIH Threshold Limit Values
Components Type Value Form
ASPHALT(CAS 8052-42-4) TWA 0.5 mg/m3 Inhalable fraction.
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form
ASPHALT(CAS 8052-42-4) Ceiling 5 mg/m3 Fume.
DISTILLATES STEL 10 mg/m3 Mist.
(PETROLEUM),
HYDROTREATED HEAVY
NAPHll-lENIC (CAS
64742-52-5)
TWA 5 mg/m3 Mist.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should
controls be matched to conditions. If applicable, use process enclosures,local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommendedexposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptablelevel. Ensure adequate
ventilation, especiallyin confined areas.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses; chemical goggles (if splashing is possible). Wear chemical goggles; face shield
(if handling molten material).
Hand protection Chemical resistant gloves are recommended.If contact with forearms is likely wear gauntlet style
gloves.
Other Wear suitable protective clothing and eye/face protection. Use of an impervious apron is
recommended.
Skin protection
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
Thermal hazards During product use, there is a risk of thermal burns.
General hygiene When using do not smoke. Avoid contact with eyes. Avoid contact with skin. Keep away from food
considerations and drink. Handle in accordancewith good industrial hygiene and safety practice.
Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen sos us
4988 Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 3/6
Page 11 of 46
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature > 700 Of(> 371.11 oq
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density Not Available
Percent volatile 0%
Specific gravity 1 - 1.9
Material name: 0-afco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SDSUS
Page 12 of 46
Bioaccumulative potential Not available.
Mobility in soil Not available.
Other adverse effects Not available.
Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SPSUS
4988 Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 5/6
Page 13 of 46
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
Not Listed.
International Inventories
Counby(s) or region Inventory name Oninventory{yes/no)*
Australia· Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Substances Yes
(EINECS) .
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
References ACGIH
EPA: AQLJIREdatabase
US. IARC Monographs on Occupational Exposures to Chemical Agents
HSDB® - Hazardous Substances Data Bank
IARC Monographs. Overall Evaluation of Carcinogenicity
National Toxicology Program (NTP) Report on Carcinogens
ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices
Disclaimer The information in the sheet was written based on the best knowledge and experience current!),
available. The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
Revision Information Physical & Chemical Properties: Multiple Properties
Toxicological information: Acute toxicity
Toxicological information: Specific target organ toxicity- single exposure
Toxicological information: Specific target organ toxicity - repeated exposure
Toxicological information: Aspiration hazard
Toxicological information: Respiratory sensitization
Transport information: Further information
Regulatory Information: Risk Phrases - Class.
Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SDSUS
Page 14 of 46
W. R. MEADOWS,,
SAFETYDATA SHEET
Page 1 of 2
HMIS
I Health I I 11 Product is classified as non-hazardous per OSHA 1910.1200. Fiber Expansion Joint is
IFlammability I Ill defined by OSHA as an "article." A manufactured item that is formed to a specific shape or
I Reactivity I IOI design during manufacture that does not release or result in exposure to a hazardous
IPersonal Protection I I I chemical under normal use conditions.
ffl-1tlil~
SARA Vapor Pressure LEL
Chemical Name: CAS Number % by Weight 313 (mm Hg@20'Cl ~
1. Petroleum Asphalt 8052-42-4 35-40 No N/A N/A
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA) and
40 CFR Part 372, chemicals listed on the 313 List (40 CFR Part 373.65) are identified under the heading "SARA 313." NIA= Not Applicoble
OSHA ACGIH
Chemical Name: PEL PEL/CEILING PEL/STEL TLV/CEILING TLV/STEL SKIN
1. Petroleum Asphalt 5 mg/m 3 *N/E N/E No N/E N/E N/E
ENGINEERING CONTROLS: None required under normal use conditions.
PERSONAL PROTECTIVE E UIPMENT: Safet lasses chemical-resistant loves. N/E = Not Established *: Asphalt Fumes
I ~-Q@6Rllil .• •
% VOLATILE BY VOLUME: N/A
% VOLATILE BY WEIGHT: N/A
N/A
Page 15 of 46
SAFETYDATA SHEET
Dave Carey
The information contained herein is based on the data available to us and is believed to be correct. However, we
make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the
use thereof We assume no responsibility for injury from the use of this product described herein.
Page 16 of 46
W R. MEADOWS&
SAFETYDATA SHEET
s per OSHA 1
manufactured it
s not release or
ns.
CAS Number
quirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of
ed on the 313 List {40 CFRPart 373.65 are identified under the heading "SARA 313."
~eMm .....
_-_
yes with water to remove particles.
with water to remove particles. Wash affected areas with soap and water if available.
cted to be an exposure route.
, dry chem1
e recognize
UIPMENT:
ble. Product .
-~1SQ!PR
OSHA
PEL/CEILING PEL/STEL SKIN
Page 17 of 46
SAFETYDATA SHEET
Dave Carey
The information contained herein is based on the data available to us and is believed to be correct. However, we make no
warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof We
assume no responsibility for injuryfrom the use of this product described herein.
Page 18 of 46
W. R. MEADOWS~
HI., SAFETYDATA SHEET
Page 1 of 2
duct is a solid. If molten material is spilled, avoid direct contact. Allow material to cool and
H
Chemical Name: PEL PEL[CEILING PEL[STEL SKIN TLV TLV[CEILING TLV[STEL SKIN
3
1. Petroleum Asphalt 5 mg/m * N/E N/E No 3
0.5 mg/m * N/E N/E N/E
2. Petroleum Oil Base Stock 3
N/E N/E N/E No 5 mg/m + N/E N/E N/E
3. Limestone N/A N/A N/A No N/A N/A N/A N/A
*: Asphalt Fumes +: Mineral Oil Mist in Air N/E: Not Established
ENGINEERING CONTROLS: None required under normal use conditions.
PERSONAL PROTECTIVE EQUIPMENT: Safety glasses, chemical res'tstant gloves.
Page 19 of 46
SAFETYDATA SHEET
4210000
EYECONTACT:Direct contact may cause mild irritation. Contact with heated material may cause severe burns.
SKINCONTACT:Direct contact may cause slight skin irritation. Contact with heated material may cause severe burns.
INHALATION:Not anticipated to be an exposure route. Heated material may emit fumes. Exposure to fumes may result in respiratory irritation.
INGESTION:Not anticipated to be an exposure route.
SIGNSAND SYMPTOMS:Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness and
swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort. Symptoms of respiratory irritation include
runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function.
AGGRAVATED MEDICAL CONDITIONS:Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to this product.
OTHERHEALTHEFFECTS:ACGIH classifies asphalt as Not Classifiableas a Human Cardno en; A4.
POTENTIAL:N/E
BIOACCUMULATIVE
CONSIDERATIONS:None recognized.
OTHERREGULATORY
PREPARATIONDATE: 9/9/2014
PREPAREDBY: Dave Care
The information contained herein is based on the data available to us and is believed to be correct. However, we
make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the
use thereof We assume no responsibility for injury from the use of this product described herein.
Page 20 of 46
SAFETY DATA SHEET
SECTION 1. IDENTIFICATION
Telephone 800-258-2436
Precautionary Statements
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Page 21 of 46
SAFETY DATA SHEET
Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
Hazardous ingredients
Cmemical nai::tle .:( ;,ii: jt ,"i, ,fi'(!.\'.· Oolilcentr;afion (% w/w:) ;;ii,;;
c~7ii~~i:~/'.:
CAS-No.'!!•.••·~~;~:ii=
Limestone 1317-65-3 >= 46 - <= 57
Methvlvinyl bis(N-ethylacetamido )silane 87855-59-2 >= 0.8 - <= 3
Dimethyl, methylhydrogen siloxane, dehy- 68952-53-4 >= 0.9 - <= 2.2
drogenated, reaction with hydroxydiethyla-
mine
Magnesium carbonate 546-93-0 >= 0.9 - <= 1.2
Quartz 14808-60-7 >= 0.33 - <= 0.41
Titanium dioxide 13463-67-7 >= 0.26 - <= 0.35
N-ethylacetam ide 625-50-3 >= 0.1 - <= 0.4
Octamethylcyclotetrasiloxane 556-67-2 >= 0.19 - <= 0.26
Impurities in methylvinylbis(N- Not Assigned >= 0.05 - <= 0.2
ethylacetam ido)silane
General advice In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.
In case of skin contact In case of contact, immediately flush skin with plenty of water.
Page 22 of 46
SAFETY DAT A SHEET
In case of eye contact In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention.
Specific hazards during fire Exposure to combustion products may be a hazard to health.
ighting
Specific extinguishing meth- Use extinguishing measures that are appropriate to local cir-
ods cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.
Special protective equipment In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.
Page 23 of 46
SAFETY DATA SHEET
Page 24 of 46
SAFETY DATA SHEET
,, ,_
' ,,,·, '
(Form of ters I Permfosible
I
• } I '
'•,
··• ',, ', exposure) concentration ' i,
Titanium dioxide
Page 25 of 46
SAFETY DATA SHEET
Hand protection
Skin and body protection Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).
Hygiene measures Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
These precautions are for room temperature handling. Use at
elevated temperature or aerosol/spray applications may
require added precautions.
Appearance paste
Page 26 of 46
SAFETY DATA SHEET
Color gray
Odor Fishy
pH Not applicable
Solubility(ies)
Water solubility No data available
Viscosity
Viscosity, dynamic Not applicable
Page 27 of 46
SAFETY DATA SHEET
Possibility of hazardous reac- Use at elevated temperatures may form highly hazardous
tions compounds.
Can react with strong oxidizing agents.
Hazardous decomposition products will be formed at elevated
temperatures.
Ingredients:
Limestone:
cute oral toxicity LD50 (Rat):> 2,000 mg/kg
Methylvinyl bis(N-ethylacetamido)silane:
cute oral toxicity Acute toxicity estimate: 500 mg/kg
Method: Expert judgment
Magnesium carbonate:
IIAcute oral toxicity LD50 (Rat): > 2,000 mg/kg
Page 28 of 46
SAFETY DATA SHEET
Quartz:
Ircute oral toxicity LD50 (Rat): > 5,000 mg/kg
Titanium dioxide:
cute oral toxicity LD50 (Rat): > 5,000 mg/kg
N-ethylacetamide:
cute oral toxicity LD50 (Rat): 3,950 mg/kg
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
cute oral toxicity LD50 (Rat): > 4,800 mg/kg
Assessment: The substance or mixture has no acute oral tox-
icity
Remarks: On basis of test data.
Impurities in methylvinylbis{N-ethylacetamido)silane:
cute oral toxicity Acute toxicity estimate: 500 mg/kg
Method: Expert judgment
Page 29 of 46
SAFETY DATA SHEET
II
Skin corrosion/irritation
Not classified based on available information.
Ingredients:
Methylvinyl bis{N-ethylacetamido)silane:
Species: Rabbit
Result: No skin irritation
Remarks: On basis of test data.
Magnesium carbonate:
Method: EPISKIN Human Skin Model Test
II
Result: No skin irritation
Titanium dioxide:
Species: Rabbit
N-ethylacetamide:
Species: Rabbit
Result: No skin irritation
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
' Species: Rabbit
Result: No skin irritation
Remarks: On basis of test data.
Impurities in methylvinylbis{N-ethylacetamido)silane:
' Species: Rabbit
Result: No skin irritation
Remarks: Based on data from similar materials
Page 30 of 46
SAFETY DATA SHEET
II
Remarks: Based on data from similar materials
Magnesium carbonate:
Species: Rabbit
Result: No eye irritation
Method: OECD Test Guideline 405
Titanium dioxide:
Species: Rabbit
II
Result: No eye irritation
N-ethylacetamide:
Species: Rabbit
Result: No eye irritation
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
Species: Rabbit
Result: No eye irritation
Remarks: On basis of test data.
Impurities in methylvinylbis(N-ethylacetamido)silane:
Species: Rabbit
Result: Irreversible effects on the eye
Remarks: Based on data from similar materials
Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Ingredients:
Methylvinyl bis(N-ethylacetamido)silane:
Assessment: Does not cause skin sensitization.
Titanium dioxide:
l~
est Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse
Page 31 of 46
SAFETY DATA SHEET
I
result: negative
N-ethylacetamide:
est Type: lntracutaneous test
Routes of exposure: Skin contact
Species: Guinea pig
Result: negative
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
ssessment: Does not cause skin sensitization.
Impurities in methylvinylbis(N-ethylacetamido)silane:
ssessment: Does not cause skin sensitization.
Methylvinyl bis(N-ethylacetamido)silane:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Result: negative
Remarks: On basis of test data.
Magnesium carbonate:
Genotoxicity in vitro Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative
Remarks: Based on data from similar materials
Titanium dioxide:
Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
II
N-ethylacetamide:
Result: negative
Genotoxicity in vivo Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: lntraperitoneal injection
Method: OECD Test Guideline 474
Result: negative
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Remarks: On basis of test data.
Genotoxicity in vivo Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Rat
Application Route: inhalation (vapor)
Result: negative
Remarks: On basis of test data.
Test Type: Rodent dominant lethal test (germ cell) (in vivo)
Species: Rat
Application Route: Ingestion
Result: negative
Remarks: On basis of test data.
Germ cell mutagenicity - Animal testing did not show any mutagenic effects.
ssessment
Page 33 of 46
SAFETY DATA SHEET
Impurities in methylvinylbis(N-ethylacetamido)silane:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Result: negative
Remarks: Based on data from similar materials
Carcinogenicity
Not classified based on available information.
Ingredients:
Magnesium carbonate:
Species: Mouse
pplication Route: Ingestion
Exposure time: 18 Months
Result: negative
Remarks: Based on data from similar materials
Quartz:
Species: Humans
pplication Route: inhalation (dust/mist/fume)
Result: positive
Remarks: IARC: (International Agency for Research on Cancer)
hese substance(s) are inextricably bound in the product and therefore do not contribute to a
dust inhalation hazard.
Titanium dioxide:
Species: Rat
pplication Route: inhalation (dust/mist/fume)
Exposure time: 24 Months
Method: OECD Test Guideline 453
Result: positive
Remarks: The mechanism or mode of action may not be relevant in humans.
hese substance(s) are inextricably bound in the product and therefore do not contribute to a
dust inhalation hazard.
N-ethylacetamide:
Species: Mouse
pplication Route: inhalation (vapor)
Exposure time: 18 Months
Result: negative
Remarks: Based on data from similar materials
Page 34 of 46
SAFETY DAT A SHEET
Quartz 14808-60-7
Quartz 14808-60-7
Reproductive toxicity
Suspected of damaging fertility. Suspected of damaging the unborn child.
Ingredients:
Reproductive toxicity - As- Some evidence of adverse effects on sexual function and
sessment fertility, based on animal experiments.
Magnesium carbonate:
Effects on fertility Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials
Effects on fetal development Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials
N-ethylacetamide:
Effects on fetal development Test Type: Embryo-fetal development
Species: Mouse
Application Route: Ingestion
Result: positive
Remarks: Based on data from similar materials
Page 35 of 46
SAFETY DATA SHEET
I!
Reproductive toxicity - As- Some evidence of adverse effects on development, based on
sessment animal experiments.
Octamethylcyclotetrasiloxane:
Effects on fertility Test Type: Two-generation reproduction toxicity study
Species: Rat, male and female
Application Route: inhalation (vapor)
Symptoms: Effects on fertility.
Remarks: On basis of test data.
Effects on fetal development Test Type: Prenatal development toxicity study (teratogenicity)
Species: Rabbit
Application Route: inhalation (vapor)
Symptoms: No effects on fetal development.
Remarks: On basis of test data.
Reproductive toxicity - As- Some evidence of adverse effects on sexual function and
sessment fertility, based on animal experiments.
Impurities in methylvinylbis(N-ethylacetamido)silane:
Effects on fertility Species: Rat, male
Application Route: Ingestion
Symptoms: Effects on fertility.
Remarks: Based on data from similar materials
Reproductive toxicity - As- Some evidence of adverse effects on sexual function and
sessment fertility, based on animal experiments.
STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Ingredients:
Quartz:
outes of exposure: inhalation (dust/mist/fume)
arget Organs: Lungs
Octamethylcyclotetrasiloxane:
Routes of exposure: Ingestion
ssessment: No significant health effects observed in animals at concentrations of 100 mg/kg
bw or less.
llbw
or less.
Ingredients:
Magnesium carbonate:
pecies: Rat
OAEL: 124 - 127 mg/kg
pplication Route: Ingestion
xposure time: 90 Days
~
Quartz:
Species: Humans
LOAEL: 0.053 mg/m3
pplication Route: Inhalation
Remarks: These substance(s) are inextricably bound in the product and therefore do not
contribute to a dust inhalation hazard.
Titanium dioxide:
Species: Rat
NOAEL: 24,000 mg/kg
pplication Route: Ingestion
Exposure time: 28 Days
Species: Rat
NOAEL: 1O mg/m 3
pplication Route: inhalation (dust/mist/fume)
Exposure time: 2 y
Remarks: These substance(s) are inextricably bound in the product and therefore do not
contribute to a dust inhalation hazard.
N-ethylacetamide:
Species: Rabbit
NOAEL: 0.09 mg/I
LOAEL: 0.36 mg/I
pplication Route: inhalation (vapor)
Exposure time: 24 Months
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
Species: Rat
pplication Route: Ingestion
Remarks: On basis of test data.
Species: Rat
pplication Route: inhalation (vapor)
Remarks: On basis of test data.
Species: Rabbit
pplication Route: Skin contact
Remarks: On basis of test data.
Page 37 of 46
.17125
SAFETY DATA SHEET
II
Aspiration toxicity
Not classified based on available information.
Further information
Ingredients:
Octamethylcyclotetrasiloxane:
Remarks: Results from a 2 year repeated vapor inhalation exposure study to rats of octamethyl-
cyclotetrasiloxane (D4) indicate effects (benign uterine adenomas) in the uterus of female an i-
mals. This finding occurred at the highest exposure dose (700 ppm) only. Studies to date have
not demonstrated if these effects occur through pathways that are relevant to humans. Repeated
exposure in rats to D4 resulted in protoporphyrin accumulation in the liver. Without knowledge of
the specific mechanism leading to the protoporphyrin accumulation the relevance of this finding
to humans is unknown.
Ecotoxicity
Ingredients:
Limestone:
oxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): > 10,000 mg/I
Exposure time: 96 h
oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 1,000 mg/I
aquatic invertebrates Exposure time: 48 h
oxicity to algae EC50 (Desmodesmus subspicatus (green algae)): > 200 mg/I
Exposure time: 72 h
Methylvinyl bis(N-ethylacetamido)silane:
oxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/I
Exposure time: 96 h
Method: OECD Test Guideline 203
oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 69 mg/I
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202
Page 38 of 46
SAFETY DATA SHEET
Ecotoxicology Assessment
Ircute aquatic toxicity No toxicity at the limit of solubility.
Magnesium carbonate:
oxicity to fish LC50 (Pimephales promelas (fathead minnow)): 2,120 mg/I
Exposure time: 96 h
Remarks: Based on data from similar materials
oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 490 - 1,127 mg/I
aquatic invertebrates Exposure time: 48 h
Remarks: Based on data from similar materials
oxicity to algae ErC50 (Desmodesmus subspicatus (green algae)): > 100 mg/I
Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: Based on data from similar materials
Quartz:
Ecotoxicology Assessment
rcute aquatic toxicity No toxicity at the limit of solubility.
Titanium dioxide:
oxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)):> 100 mg/I
Exposure time: 96 h
Method: OECD Test Guideline 203
oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 100 mg/I
aquatic invertebrates Exposure time: 48 h
N-ethylacetamide:
IIToxicity to fish LC50 (Leuciscus idus (Golden orfe)): 3,390 mg/I
Page 39 of 46
19{25 C
SAFETY DATA SHEET
Exposure time: 96 h
Method: DIN 38412
Remarks: Based on data from similar materials
oxicity to daphnia and other EC50 (Daphnia magna (Water flea)):> 580 mg/I
aquatic invertebrates Exposure time: 48 h
Method: DIN 38412
Remarks: Based on data from similar materials
oxicity to algae EC50 (Desmodesmus subspicatus (green algae)): > 500 mg/I
Exposure time: 96 h
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
oxicity to fish LC50 (Cyprinodon variegatus (sheepshead minnow)):>
0.0063 mg/I
Exposure time: 336 h
Remarks: No toxicity at the limit of solubility.
oxicity to daphnia and other EC50 (Mysidopsis bahia (opossum shrimp)):> 0.0091 mg/I
aquatic invertebrates Exposure time: 96 h
Remarks: No toxicity at the limit of solubility.
oxicity to fish (Chronic toxic- NOEC (Oncorhynchus mykiss (rainbow trout)):>= 0.0044 mg/I
ity) Remarks: On basis of test data.
No toxicity at the limit of solubility.
oxicity to daphnia and other NOEC (Daphnia magna (Water flea)): >==0.0079 mg/I
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Remarks: On basis of test data.
No toxicity at the limit of solubility.
Ecotoxicology Assessment
1rhronic aquatic toxicity May cause long lasting harmful effects to aquatic life.
Ingredients:
II Biodegradation: 62.66 %
Method: OECD Test Guideline 301 B
Page 40 of 46
SAFETY DATA SHEET
II
Dimethyl, methylhydrogen siloxane, dehydrogenated, reaction with hydroxydiethylamine:
Biodegradability Result: Not readily biodegradable.
II
N-ethylacetamide:
Remarks: Based on data from similar materials
Octamethylcyclotetrasiloxane:
Biodegradability Result: Not readily biodegradable.
Biodegradation: 3.7 %
Exposure time: 28 d
Method: OECD Test Guideline 310
Stability in water Degradation half life: 69.3 - 144 h (24.6 °C) pH: 7
Method: OECD Test Guideline 111
Bioaccumulative potential
Ingredients:
Octamethylcyclotetrasiloxane:
Bioaccum ulation Species: Pimephales promelas (fathead minnow)
Bioconcentration factor (BCF): 12,400
Mobility in soil
No data available
Other adverse effects
Ingredients:
Octamethylcyclotetrasiloxane:
Results of PBT and vPvB Remarks: Octamethylcyclotetrasiloxane (D4) meets the cur-
assessment rent REACh Annex XIII criteria for PBT and vPvB. In Canada,
D4 has been assessed and deemed to meet the PiT criteria.
However, D4 does not behave similarly to known PBT/vPvB
substances. The weight of scientific evidence from field stud-
ies shows that D4 is not biomagnifying in aquatic and terres-
trial food webs. D4 in air will degrade by reaction with naturally
occurring hydroxyl radicals in the atmosphere. Any D4 in air
that does not degrade by reaction with hydroxyl radicals is not
expected to deposit from the air to water, to land, or to living
organisms .
Page 41 of 46
.21 /25
SAFETY DATA SHEET
Disposal methods
Resource Conservation and This product has been evaluated for RCRA characteristics
Recovery Act (RCRA) and does not meet the criteria of hazardous waste if discarded
in its purchased form.
International Regulations
UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation
49CFR
Not regulated as a dangerous good
109-89-7 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
II Reproductive toxicity
Page 42 of 46
SAFETY DATA SHEET
SARA313 This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minim is)
reporting levels established by SARA Title 111,
Section 313.
US State Regulations
TSCA All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory
exemption.
DSL All chemical substances in this product comply with the CEPA
1999 and NSNR and are on or exempt from listing on the
Canadian Domestic Substances List (DSL).
Page 43 of 46
SAFETY DATA SHEET
Further information
NFPA: HMIS®IV:
Flammability
::,
:5 en
cii iii
I
Q)
g
~
AICS -Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Ha-
zardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Sche-
dule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated
with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System;
IARC - International Agency for Research on Cancer; IATA - International Air Transport Associa-
tion; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous
Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Avia-
tion Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - Interna-
tional Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial
Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Ko-
Page 44 of 46
SAFETY DATA SHEET
rea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50
- Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Conven-
tion for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration;
n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Ob-
served (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR -
No Observable Effect Loading Rate; NTP - National Toxicology Program; NZloC - New Zealand
Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development;
OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative
and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances;
(Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Re-
covery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ -
Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SOS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-
stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB -
Very Persistent and Very Bioaccumulative
Sources of key data used to Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/
Items where changes have been made to the previous version are highlighted in the body of this
document by two vertical lines.
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided
relates only to the specific material identified at the top of this SOS and may not be valid when the
SOS material is used in combination with any other materials or in any process, unless specified
in the text. Material users should review the information and recommendations in the specific
context of their intended manner of handling, use, processing and storage, including an
assessment of the appropriateness of the SOS material in the user's end product, if applicable.
US/ Z8
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. 25/25
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