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INVENTORY OF HAZARDOUS

CHEMICALS FOR SDS BOOKS

Page COMMON NAME, HAZARDOUS CHEMICAL

3 Concrete - Backer Rod, CERA-ROD


5 Concrete - Blastglass
7 Concrete - Cold applied joint sealer - #158
9 Concrete - Crafco Joint sealer
15 Concrete - Fibre Expansion Joint
17 Concrete - Foam Expansion Joint
19 Concrete - Hi-Spec hot applied joint sealant
21 Concrete - Silicone Joint Sealant 888

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W. R.MEADOWS,,
SAFETYDATA SHEET

Product: CERA-ROD~ Part Number: 4680500


Manufacturer: W. R. MEADOWS, INC. Address: 300 Industrial Drive
Hampshire, Illinois 60140
Telephone: (847) 214-2100 In case of emergency, dial (800) 424-9300 (CHEMTREC)
Revision Date: 2/15/2018
Product Use: Backer Rod

ified as non-hazardous p
HA as an "article," a manufa
ng manufacture that does n

SARA
%by Weight 313

Ill of the Superfund Amendments and


identified under t

dry chemical.
n monoxide, carbon dioxide, and incompl bustion products.
UIPMENT: Avoid smoke inhalation. Use a te res irator rotection.
. .L·.:.-~-.
P1!]1:0111lf8~1J~,Q'E~lf-t~
le. Product is a solid.
- . ,JPtlil~TI1N~·pt~~~.1t~ll~1iiI,~,
equirements.

PEL/STEL

conditions .

. N/A
APPEARANCE: R
:rAtrlL.

EYE CONTACT: Direct contact may cause mechanical irritation.


SKIN CONTACT: Direct contact may cause slight mechanical skin irritation.
INHALATION: Not anticipated to be an exposure route.
INGESTION: Not anticipated to be an exposure route.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include
redness and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
AGGRAVATED MEDICAL CONDITIONS: None recognized.
OTHER HEALTH EFFECTS: None recognized

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SAFETYDATA SHEET

TENTIAL:N/E

HAZARDOUS/NON-HAZARDOUS MATERIAL:Not regulated by DOT.


UN NUMBER: None HAZARDCLASS:N/A PACKINGGROUP: N/ A
UN PROPERSHIPPINGNAME: N/ A
ENVIRONMENTAL HAZARDS:None recognized.
BULKTRANSPORTATION INFORMATION:None.
SPECIAL
PRECAUTIONS: None.

Dave Carey

The information contained herein is based on the data available to us and is believed to be correct. However,
we make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained
from the use thereof We assume no responsibility for injuryfrom the use of this product described herein.

Page 4 of 46
g/assAdvantage
Safety Data Sheet Innovation and Recycling At Its Best

Product Name: Blastglass®


Manufactured By: Glass Advantage, Inc. Address: 230 15 th Street NW, West Fargo, ND 58078
Phone: 701-277-9200 Fax: 701-364-1281

Crushed glass (glass sand) is not classified as a hazardous material by the criteria of the OSHA Hazard
Communication Standard, Title 29, Code of Federal Regulations, Section 1910.1200, Hazard Communication.
Contains no free (or crystalline) silica; all components are amorphous/non-crystalline.
Nuisance dust concern only.

Chemical Name: 100% Soda-Lime Silicon Dioxide Glass CAS Number: 65997-17-3
Known As: Crushed Glass Media

Inhalation: If product is inhaled, move to fresh air and contact a physician. Dust in excess of recommended
exposure limits may result in respiratory tract irritation.
Ingestion: Product is not hazardous if ingested, however consult a physician if a large amount is ingested.
Eyes: Flush thoroughly with water and contact physician if irritation persists.
Skin Contact: No known hazards, however, washing a~er contact is advised.

Non-flammable, non-combustible, non-hazardous, inorganic material.

Spills: Sweep up and discard; avoid excessive dusting. This material is not a SARA Title III reportable substance.
Respiratory: If dust concentrations exceed recommended Permissible Exposure Limits, use NIOSH-approved
respirators.
Ventilation: Local exhaust.

Precautions: Spillage may result in slippery conditions.


When transferring material, care should be taken to avoid dusting.

Nuisance Dust (total): ACGIH 10 mg/m 3 TLV (units) depends upon particle size
Nuisance Dust (respirable): OSHA PEL 5 mg/m 3 depends upon particle size
Carcinogenity:
NTP: Not listed IARC Monographs: Not Listed OSHA Regulation: Not Listed
Routes of Entry:
Lungs (breathing): Yes Ingestion: No Skin: No
Health Hazard (acute & chronic): Dust in excess of recommended exposure limits may result in irritation to the
respiratory tract.
Respiratory Protection: If dust concentrations exceed recommended Permissible Exposure Limits, use NIOSH-
approved respirators.
Eye Protection: NIOSH-approved safety glasses or goggles (tight fitting recommended)
Ventilation: Local Exhaust Protective Gloves: Not required
Other Protective Clothing or Equipment: None required

Appearance: Solid, transparent, colored particle Odor: Odorless Odor Threshold: N/ A


Melting Point: 726°C (1340°F) Boiling Point: N/A Freezing Point: N/ A
Vapor Pressure: N/A Vapor Density: N/A Evaporation Rate: N/A
Solubility in Water: Insoluble 0/o Volatile by Volume: N/A Specific Gravity: 2.5
pH: N/A Flash Point: N/A Flammability: N/A

Stability: Material is stable Incombatibilities: Hydrofluoric Acid


Hazardous Polymerization: Will not occur Hazardous Decomposition Products: None

Toxicity: N/A

Ecological Concerns: N/A

Page 5 of 46
Waste Disposal Method: Dispose in approved landfill in accordance with federal, state and local regulations.
This material is not a SARA Title III reportable substance.
l
DOT Identification: Not regulated by DOT

N/A

Abbreviation References:
N/A = Not Applicable
mg/m3 = Milligrams per cubic meter
TLV = Threshold limit value
NIOSH = National Institute of Safety & Health
OSHA = Occupational Safety & Health Administration
CAS = Chemical Abstracts Service
ACGIH: American Conference of Government Industrial Hygienists
SARA Title III = Emergency Planning and Community Right-to-Know Act
DOT = Department of Transporatation
August 6, 2015

This information isfurnished without warranty, representation, inducement, or license of any kind, except that it is accurate to the best of
Glass Advantage Inc's knowledge or obtained from sources believed by Glass Advantage Inc to be accurate, and Glass Advantage Inc does
not assume any legal responsibility for use or reliance upon same. Customers are encouraged to conduct their own tests, read the product
label, and obtain data for sources, which they know to be reliable before using any product.

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W. R.MEADOWS.,
SAFETYDATA SHEET

Product: #158 Part Number: 4230000


Manufacturer: W.R. MEADOWS,INC. Address: 300 Industrial Drive
Hampshire, Illinois 60140
(847) 214-2100 In case of emergency, dial (800) 424-9300 (CHEMTREC)
11/5/2015
Rubberized As halt Sealer

HAZARD STATEMENTS
HMIS WARNING!
!Health! I1 I Flammable Liquid and vapor.
IFlammability I I2 I Causesskin, eye, respiratory irritation.
I Reactivity I Io I Suspected of causing genetic defects.
I Personal Protection I I I Causes damage to liver, kidneys, lungs, and blood.
Harmful if inhaled.
May be fatal if ingested and enters airway.
PRECAUTIONARY STATEMENTS
Use only in well-ventilated areas.
Avoid breathing vapors and direct contact.
Store in well-ventilated location.
Wear appropriate personal protective equipment.
Keep away from ignition sources.
Control vapors in confined spaces utilizing mechanical ventilation.

SARA Vapor Pressure LEL


Chemical Name: CAS Number % bJIWeight 313 Imm Hg@20°Cl ~
1. Xylene 1330-20-7 1-5 Yes 6.6 1.1
2. Light Aromatic Naphtha 64742-95-6 25-30 No <10 @ 25•c o.9
3. Petroleum Asphalt 8052-42-4 30-35 No N/A N/A
4. Petroleum Oil 64742-65-0 5-10 No N/A N/A
5. 1,2,4-Trimethylbenzene 95-63-6 5-10 Yes N/A 0.9
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA)and 40 CFR
Part 372, chemicals listed on the 313 List (40 CFRPart 373.65) are identified under the heading "SARA 313." N/A: Not Applicable
--:-,~JRi;~~~fll~fflN.t~HJRSll;;~Jl)-01,;EtltJR'ESJ~li'"
i;@ . "
EYE CONTACT: Move victim from exposure source and into fresh air. Flush eyes with water for Fifteen (15) minutes. Product is thick and may be
difficult to remove. If symptoms persist, seek medical attention.
SKIN CONTACT: Wash affected areas with mild soap and water. Product may be difficult to remove. Do not use petroleum solvents.
INHALATION: If respiratory symptoms develop move victim from exposure source and into fresh air. If symptoms persist, seek medical attention.
INGESTION: Not anticipated to be an exposure route. If ingested, do not induce vomiting. Dilute by giving victim water or milk. Seek immediate
medical attention.

FLASHPOINT: 103 degrees F


EXTINGUISHING MEDIA: Water fog, foam, dry chemical, or carbon dioxide.
CHEMICAL/COMBUSTION HAZARDS: Oxides/compounds of nitrogen/sulfur. carbon dioxide, carbon monoxide, and incomplete combustion
products.
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid direct contact. Use of eye protection and chemical-resistant gloves is recommended.
· · · resent.
;ail~,'.
SPILL OR LEAK PROCEDURES: Evacuate the hazard area of unprotected personnel. Remove/extingui
Product is thick and will not flow quickly when spilled. Wear appropriate personal protective equip

SAFE STORAGE: Keep containers closed when not in use. Store away from ignition sources.

Page 7 of 46
SAFETYDATA SHEET

HA AC
Chemical Name: PEL PELLCEILING PEL[STEL SKIN TWA TLV[CEILING TLV[STEL SKIN
1. Xylene 100 ppm N/E N/E N/E 100 ppm N/E 150 ppm N/E
2. Light Aromatic Naphtha N/E N/E N/E N/E N/E N/E N/E N/E
3. Petroleum Asphalt 5 mg/m
3*
N/E N/E N/E 5 mg/m 3 • N/E N/E N/E
4. Petroleum Oil 5 mg/m 3+ N/E N/E N/E 5 mg/m 3• N/E 10 mg/m 3• N/E
5. 1,2,4-Trimethylbenzene 25 ppm N/E N/E No 25 ppm N/E N/E No
•: Asphalt Fumes +: Petroleum Oil mist in air N/E: Not Established
ENGINEERINGCONTROLS:Use with adequate ventilation. Use explosion-proof equipment.
PERSONALPROTECTIVEEQUIPMENT: Safet lasses, chemical-resistant loves.

CONDI
HAZAR
combus
- ,):f!~~- - -
EYECONTACT: Direct contact may result in moderate irritation. Product vapors/mists may also cause irritation.
SKIN CONTACT: Direct contact may cause mild skin irritation. Prolonged/repeated contact may result in skin irritation/dermatitis.
INHALATION: Exposure to excessive vapor concentrations may result in transient central nervous system depression (headache, fatigue,
drowsiness, loss of coordination). Intentional misuse by deliberately concentrating/inhaling vapors may be harmful or fatal.
Repeated/prolonged occupational exposures to solvents may cause permanent brain and nervous system damage.
INGESTION: Not anticipated to be an exposure route. Ingestion will cause irritation of the digestive tract.
SIGNSAND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness and
swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort. Symptoms of respiratory irritation include
runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function. Symptoms of transient central nervous
system depression include: headache, fatigue, drowsiness, dizziness, and loss of coordination.
AGGRAVATEDMEDICALCONDITIONS: Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to this product.
OTHERHEALTHEFFECTS:Xylene and Aromatic Naphtha have been shown to cause the following effects in laboratory animals: liver/kidney
effects, blood abnormalities, effects on the spleen, testes, nervous system, adrenals, cardiovascular system, and harm to the fetus. The relevance
to humans is uncertain.

HAZARDOUS/NON-HAZARDOUSMATERIAL: Not Regulated by domestic ground shipment.


UN NUMBER: None HAZARDCLASS:None PACKINGGROUP: None
UN PROPERSHIPPINGNAME: Tars, Liquid
ENVIRONMENTALHAZARDS:None recognized.
BULKTRANSPORTATIONINFORMATION: Not applicable. Product not supplied in bulk configuration.
SPECIALPRECAUTIONS:None.

Dave Carey

The information contained herein is based on the data available to us and is believed to be correct. However, we make no
warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof We
assume no responsij)ilityfor injury from the use of this product described herein.

Page 8 of 46
SAFETY DATA SHEET
CRAFCD:,
AN ERGONEi COMPANY

1. Identificat-ion
Product identifier Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder,
Loop Detector, Pavement Joint Adhesive, Polyfiber, Fiber Asphalt, Marker Adhesive,
Quikstix, Asphalt Adhesive, PCF 100, High Slope, QWIKSEAL, QWIKDOT
Other means of identification Not available.
Recommended use Pavement Crack and Joint Sealing and Preservation
Recommended restrictions None known.
Manufacturer /Importer /Supplier /Distributor information
Manufacturer
Manufacturer: Crafco, Inc.
Address: 6165 West Detroit St
Chandler, AZ 85226 USA
Contact Name: Jim Chehovits
Telephone: 602-276-0406
E-mail: jim.chehovits@crafco.com
CHEMTREC: 80D-424-9300 (North America)
+ 1-703-527-3887 (International)
2. Hazard(s) identification
Physical hazards Not classified.
Health hazards Not classified.
Environmental hazards Not classified.
OSHA defined hazards Not classified.
*Hazards not stated here are "Not classified", "Not applicable" or "Classification not possible".
Label elements
Hazard symbol None.
Signal word Not applicable.
Hazard statement Not applicable.
Prevention Not applicable.
Response Not applicable.
Storage Not applicable.
Disposal Not applicable.
Hazard(s) not otherwise None known.
classified (HNOC)
Supplemental information None.

3. Composition/information on ingredients
Mixtures
Chemical name Common name and synonyms CAS number %
ASPHALT 8052-42-4 20 -100
DISTILLATES (PETROLEUM), 64742-52-5 0 -40
HYDROTREATED
HEAW
NAPHTHENIC
other components below reportable levels 0 - 75
Composition comments * All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in
percent by volume.

4~ First-aid measures
Inhalation If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention, if needed. Call a physician if symptoms develop or persist.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Thoroughly wash (or discard) clothing and shoes
before reuse.

Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SDSUS
49B8 Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 1/6

Page 9 of 46
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. If a contact lens is present, DO
NOT delay irrigation or attempt to remove the lens. Get medical attention if irritation develops and
persists.
Ingestion Rinse mouth. Do not induce vomiting. Do not use mouth-to-mouth method if victim ingested the
substance. call a POISON CENTERor doctor/physician if you feel unwell.
Most important Not available.
symptoms/ effects, acute and
delayed
Indication of immediate In case of ingestion, the decision of whether or not to induce vomiting should be made by the
medical attention and special attending physician. Certain pre-existing conditions may make workers particularly susceptible to
treatment needed the effects of this chemical: asthma, allergies, impaired pulmonary function.
General information If you feel unwell, seek medical advice (show the label where possible). Ensure that medical
personnel are aware of the material(s) involved, and take precautions to protect themselves. Show
this safety data sheet to the doctor in attendance. Discard any shoes or dothing items that cannot
be decontaminated.

5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. carbon dioxide (CO2). Addition of water or foam to the fire
may cause frothing.
Unsuitable extinguishing Do not use a solid water stream as it may scatter and spread fire.
media
Specific hazards arising from Fire may produce irritating, corrosive and/or toxic gases. Development of hazardous combustion
the chemical gases or vapours possible in the event of a fire. The following may develop: Acrolein.
Special protective equipment Firefighters must use standard protective equipment inducting flame retardant coat, helmet with
and precautions for face shield, gloves, rubber boots, and in endosed spaces, SCBA. Firefighters should wear full
firefighters protective dothing including self contained breathing apparatus. Structural firefighters protective
clothing will only provide limited protection.
Fire-fighting In case of fire and/or explosion do not breathe fumes. Firefighters must use standard protective
equipment/instructions equipment induding flame retardant coat, helmet with face shield, gloves, rubber boots, and in
enclosed spaces, SCBA. ALWAYS stay away from tanks engulfed in flame. Fight fire from maximum
distance or use unmanned hose holders or monitor nozzles. In the event of fire, cool tanks with
water spray. By fire, toxic gases may be formed (COx, NOx). Keep run-off water out of sewers and
water sources. Dike for water control.
Specific methods In the event of fire and/or explosion do not breathe fumes. In the event of fire, cool tanks with
water spray. Use water spray to cool unopened containers.

6. Accidental release measures


Personal precautions, Keep unnecessary personnel away. Wear appropriate protective equipment and clothing during
protective equipment and clean-up. Ventilate closed spaces before entering them. Do not touch or walk through spilled
emergency procedures material.
Methods and materials for ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Dike far
containment and cleaning up ahead of spill for later disposal. Following product recovery, flush area with water.

Never return spills in original containers for re-use.


Environmental precautions Prevent further leakage or spillage if safe to do so. Runoff or release to sewer, waterway or ground
is forbidden.

7. Handling and storage


Precautions for safe handling The product is non-combustible. If heated, irritating vapors may be formed. Do not use in area~
without adequate ventilation. Wash hands thoroughly after handling. Wash hands after handling.
Observe good industrial hygiene practices.
Conditions for safe storage, Prevent electrostatic charge build-up by using common bonding and grounding techniques. Store in
including any a well-ventilated place. Keep the container tightly closed and dry. Store in a closed container away
incompatibilities from incompatible materials. Keep out of the reach of children.

8. Exposure controls/personal protection


Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components Type Value Form

DISTILLATES PEL 5 rng/m3 Mist.


(PETROLEUM),
HYDROTREATEDHEAVY
NAPHTHENIC (CAS
64742-52-5)

Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavernen SDS US

4988 Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 2/6

Page 10 of 46
US. ACGIH Threshold Limit Values
Components Type Value Form
ASPHALT(CAS 8052-42-4) TWA 0.5 mg/m3 Inhalable fraction.
US. NIOSH: Pocket Guide to Chemical Hazards
Components Type Value Form
ASPHALT(CAS 8052-42-4) Ceiling 5 mg/m3 Fume.
DISTILLATES STEL 10 mg/m3 Mist.
(PETROLEUM),
HYDROTREATED HEAVY
NAPHll-lENIC (CAS
64742-52-5)
TWA 5 mg/m3 Mist.
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should
controls be matched to conditions. If applicable, use process enclosures,local exhaust ventilation, or other
engineering controls to maintain airborne levels below recommendedexposure limits. If exposure
limits have not been established, maintain airborne levels to an acceptablelevel. Ensure adequate
ventilation, especiallyin confined areas.
Individual protection measures, such as personal protective equipment
Eye/face protection Wear safety glasses; chemical goggles (if splashing is possible). Wear chemical goggles; face shield
(if handling molten material).
Hand protection Chemical resistant gloves are recommended.If contact with forearms is likely wear gauntlet style
gloves.
Other Wear suitable protective clothing and eye/face protection. Use of an impervious apron is
recommended.
Skin protection
Respiratory protection When workers are facing concentrations above the exposure limit they must use appropriate
certified respirators.
Thermal hazards During product use, there is a risk of thermal burns.
General hygiene When using do not smoke. Avoid contact with eyes. Avoid contact with skin. Keep away from food
considerations and drink. Handle in accordancewith good industrial hygiene and safety practice.

9. Physical and chemical properties


Appearance Solid.
Physical state Solid.
Form Solid.
Color Black. Dark brown
Odor Product is a black, semi-solid with a burnt tar odor.
Odor threshold Not available.
pH Not available.
Melting point/freezing point 150 - 250 °F (65.56 - 121.11 °C) ASTMD36 Softening Point
Initial boiling point and > 800 Of (> 426.67 oq
boiling range
Flash point > 400.0 Of (> 204.4 oq
Evaporation rate Not available.
Flammability (solid, gas) Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower Not available.
(%)
Flammability limit - Not available.
upper(%)
Explosive limit - lower Not available.
(%)
Explosive limit - upper Not available.
(%)
Vapor pressure Not available.
Vapor density Not available.
Relative density Not available.

Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen sos us
4988 Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 3/6

Page 11 of 46
Solubility(ies)
Solubility (water) Not available.
Partition coefficient Not available.
(n-octanol/water)
Auto-ignition temperature > 700 Of(> 371.11 oq
Decomposition temperature Not available.
Viscosity Not available.
Other information
Density Not Available
Percent volatile 0%
Specific gravity 1 - 1.9

10. Stability and reactivity


Reactivity Not available.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous Hazardous polymerization does not occur.
reactions
Conditions to avoid Strong oxidizing agents.
Incompatible materials Incompatible witti oxidizing agents.
Hazardous decomposition Upon decomposition, product emits acrid dense smoke witti carbon dioxide, carbon monoxide, trace
products oxides of nitrogen and sulfur, and water.

11. Toxicological information


Information on likely routes of exposure
Ingestion May cause gastrointestinal discomfort if swallowed. Do not induce vomiting. Vomiting may
increase risk of product aspiration.
Inhalation May be harmful if inhaled. However, this product does not currently meet the criteria for
classification.
Skin contact Frequent or prolonged contact may defat and dry the skin, leading to discomfort and dermatitis,
Eye contact May be irritating to eyes.
Symptoms related to the Not available.
physical, chemical and
toxicological characteristics
Information on toxicological effects
Acute toxicity Not classified.
Skin corrosion/irritation Not classified. May cause defatting of the skin, but is neither an irritant nor a sensitizer.
Serious eye damage/ eye Not classified.
irritation
Respiratory or skin sensitization
Respiratory sensitization Not classified.
Skin sensitization Not classified.
Germ cell mutagenicity Non-mutagenic based on Modified Ames Assay.
carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity Contains no ingredient listed as toxic to reproduction
Specific target organ toxicity Not classified.
- single exposure
Specific target organ toxicity Not classified.
- repeated exposure
Aspiration hazard Not classified.
Chronic effects Prolonged or repeated contact may cause drying, cracking, or irritation of the skin.

12. Ecological information


Ecotoxicity This product.has no known eco-toxicological effects. Not expected to be harmful to aquatic
organisms.
Persistence and degradability Not available.

Material name: 0-afco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SDSUS

4988 Version#: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 4/6

Page 12 of 46
Bioaccumulative potential Not available.
Mobility in soil Not available.
Other adverse effects Not available.

13. Disposal considerations


Disposal instructions Dispose of contents/container in accordance with local/regional/national/international regulations.
When this product as supplied is to be discarded as waste, it does not meet the definition of a
RCRAwaste under 40 CFR 261.
Hazardous waste code Not applicable.
Waste from residues / Dispose of in accordance with local regulations.
unused products
Contaminated packaging Offer rinsed packaging material to local recycling facilities.

14. Transport information


DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
Transport in bulk according to Not available.
Annex II of MARPOL 73/78
and the IBC Code
Further information If the product is shipped at temperatures below 212°F (100°C), it is not regulated for transport by
ground, air or vessel. If shipped above 212 deg F: "UN3257, Elevated Temperature Liquid, n.o.s.
(Asphalt mixture), 9, PG III"

15. Regulatory information


US federal regulations All components are on the U.S. EPATSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List ( 40 CFR 302.4)
Not listed.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 No
Hazardous chemical
SARA 313 (TRI reporting)
Not regulated.

other federal regulations


Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Not regulated.
Safe Drinking Water Act Not regulated.
(SDWA)
US state regulations WARNING: This product contains a chemical known to the State of california to cause cancer.
US. Massachusetts RTK - Substance List
Not regulated.
US, New Jersey Worker and Community Right-to-Know Act
Not regulated.

Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SPSUS
4988 Version #: 08 Revision date: 08-18-2015 Issue date: 11-25-2013 5/6

Page 13 of 46
US. Pennsylvania RTK - Hazardous Substances
Not regulated.
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
Not Listed.
International Inventories
Counby(s) or region Inventory name Oninventory{yes/no)*
Australia· Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Substances Yes
(EINECS) .
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
(PICCS)
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).

16. Other information, including date of preparation or last revision


Issue date 11-25-2013
Revision date 08-18-2015
Version# 08
Further information HMIS® is a registered trade and service mark of the NPCA.

References ACGIH
EPA: AQLJIREdatabase
US. IARC Monographs on Occupational Exposures to Chemical Agents
HSDB® - Hazardous Substances Data Bank
IARC Monographs. Overall Evaluation of Carcinogenicity
National Toxicology Program (NTP) Report on Carcinogens
ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices
Disclaimer The information in the sheet was written based on the best knowledge and experience current!),
available. The information provided in this Safety Data Sheet is correct to the best of our
knowledge, information and belief at the date of its publication. The information given is designed
only as a guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered a warranty or quality specification. The information relates only to the
specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.
Revision Information Physical & Chemical Properties: Multiple Properties
Toxicological information: Acute toxicity
Toxicological information: Specific target organ toxicity- single exposure
Toxicological information: Specific target organ toxicity - repeated exposure
Toxicological information: Aspiration hazard
Toxicological information: Respiratory sensitization
Transport information: Further information
Regulatory Information: Risk Phrases - Class.

Material name: Crafco Roadsaver, Polyflex, Parking Lot, Asphalt Rubber, DF, Superflex, Matrix Binder, Loop Detector, Pavemen SDSUS

4988 Version #; 08 Revision date: 08-18-2015 Issue date: 11-25-2013 6/6

Page 14 of 46
W. R. MEADOWS,,
SAFETYDATA SHEET
Page 1 of 2

Product: FIBRE EXPANSION JOINT Part Number: 1103360


Manufacturer: W.R. MEADOWS, INC. Address: 300 Industrial Drive
Hampshire, Illinois 60140
Telephone: (847) 214-2100 In case of emergency, dial (800) 424-9300 (CHEMTREC)
Revision Date: 11/9/2017
Product Use: Expansion Joint in Concrete Construction

HMIS
I Health I I 11 Product is classified as non-hazardous per OSHA 1910.1200. Fiber Expansion Joint is
IFlammability I Ill defined by OSHA as an "article." A manufactured item that is formed to a specific shape or
I Reactivity I IOI design during manufacture that does not release or result in exposure to a hazardous
IPersonal Protection I I I chemical under normal use conditions.
ffl-1tlil~
SARA Vapor Pressure LEL
Chemical Name: CAS Number % by Weight 313 (mm Hg@20'Cl ~
1. Petroleum Asphalt 8052-42-4 35-40 No N/A N/A
Under the reporting requirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of 1966 (SARA) and
40 CFR Part 372, chemicals listed on the 313 List (40 CFR Part 373.65) are identified under the heading "SARA 313." NIA= Not Applicoble

EYE CONTACT: Flush eyes with water to remove fibers


SKIN CONTACT: Flush with water to remove fibers. Wash affected areas with soap and water if available
INHALATION: Not expected to be an exposure route. If a dust exposure occurs, remove victim from exposure source and treat
symptomatically.
INGESTION: Not ex ected to be an ex osure source.
~==-~.
~~.-~-
.~.~,=~-~::=c~.·~"\":':c~;~~-;=_~~:
=-;m!"::!"':.:s~t=-~=e,::::-Ji":'11,~:7.!;=,:i::,=.=
1 pt':::s::Cif&""·•~"'""t:1i~iwf""y1'1111llll::,;;,:J==~
1

: Water fog, foam, dry chemical.


ON HAZARDS: Stacked material will retain heat and has the potential to reignite.
AL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Use
·._,. :~.1':-!111i~\\'IJl!~l:Cilll~~~,J~~J)fflll!t~~E!]-

OSHA ACGIH
Chemical Name: PEL PEL/CEILING PEL/STEL TLV/CEILING TLV/STEL SKIN
1. Petroleum Asphalt 5 mg/m 3 *N/E N/E No N/E N/E N/E
ENGINEERING CONTROLS: None required under normal use conditions.
PERSONAL PROTECTIVE E UIPMENT: Safet lasses chemical-resistant loves. N/E = Not Established *: Asphalt Fumes
I ~-Q@6Rllil .• •
% VOLATILE BY VOLUME: N/A
% VOLATILE BY WEIGHT: N/A
N/A

STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur.


CONDITIONS AND MATERIALS TO AVOID: None recognized.
HAZARDOUS DECOMPOSITION PRODUCTS: None recognized.

Page 15 of 46
SAFETYDATA SHEET

EYECONTACT: Direct contact may cause mild irritation.


SKIN CONTACT:Direct contact may cause slight skin irritation.
INHALATION: Not anticipated to be an exposure route.
INGESTION:Not anticipated to be an exposure route.
SIGNSAND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness
and swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
AGGRAVATEDMEDICALCONDITIONS:None recognized.
OTHERHEALTHEFFECTS:Wood dust is listed by the IARCas a human carcinogen {Group 1)

HAZARDOUS/NON-HAZARDOUSMATERIAL: Not regulated by DOT.


UN NUMBER: None HAZARDCLASS:N/A PACKINGGROUP: N/A
UN PROPERSHIPPING NAME: N/A
ENVIRONMENTALHAZARDS: None recognized.
BULKTRANSPORTATIONINFORMATION: None.
SPECIALPRECAUTIONS: None.

Dave Carey

The information contained herein is based on the data available to us and is believed to be correct. However, we
make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the
use thereof We assume no responsibility for injury from the use of this product described herein.

Page 16 of 46
W R. MEADOWS&
SAFETYDATA SHEET

Product: Deck-O-Foam® Expansion Joint Part Number: 4610000


Manufacturer: W.R. Meadows®, Inc. Address: 300 Industrial Drive
Hampshire, Illinois 60140
{847) 214-2100 In case of emergency, dial {800) 424-9300 {CHEMTREC)
9/9/2014

s per OSHA 1
manufactured it
s not release or
ns.

CAS Number

quirements of Section 313 of Title Ill of the Superfund Amendments and Reauthorization Act of
ed on the 313 List {40 CFRPart 373.65 are identified under the heading "SARA 313."
~eMm .....
_-_
yes with water to remove particles.
with water to remove particles. Wash affected areas with soap and water if available.
cted to be an exposure route.

, dry chem1
e recognize
UIPMENT:

ble. Product .
-~1SQ!PR

OSHA
PEL/CEILING PEL/STEL SKIN

rmal use conditions.

STABILITY: Stable. HAZARDOUS POLYMERIZATION: Will not occur.


CONDITIONS AND MATERIALS TO AVOID: None recognized.
HAZARDOUS DECOMPOSITION PRODUCTS: None recognized.
~ ~ =-·
I ,,, --., , -

EYE CONTACT: No adverse effects with normal product use.


SKIN CONTACT: No adverse effects with normal product use.
INHALATION: Not anticipated to be an exposure route.
INGESTION: Not anticipated to be an exposure route.
SIGNS AND SYMPTOMS: Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness and
swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort.
AGGRAVATED MEDICAL CONDITIONS: None recognized.
OTHERHEALTH EFFECTS:None recognized.

Page 17 of 46
SAFETYDATA SHEET

HAZARDOUS/NON-HAZARDOUSMATERIAL: Not regulated by DOT.


UN NUMBER: None. HAZARDCLASS:N/A PACKINGGROUP: N/A
UN PROPERSHIPPINGNAME: N/A
ENVIRONMENTALHAZARDS: None recognized.
BULKTRANSPORTATIONINFORMATION: None.
SPECIALPRECAUTIONS: None.

Dave Carey

The information contained herein is based on the data available to us and is believed to be correct. However, we make no
warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the use thereof We
assume no responsibility for injuryfrom the use of this product described herein.

Page 18 of 46
W. R. MEADOWS~
HI., SAFETYDATA SHEET
Page 1 of 2

Product: HI-SPEC®JOINT SEALING COMPOUND Part Number: 4210000


Manufacturer: W.R. Meadows®, Inc. Address: 300 Industria I Drive
Hampshire, Illinois 60140
Telephone: (847} 214-2100 In case of emergency, dial (800) 424-9300 (CHEMTREC}
Revision Date: 9/9/2014
Product Use: Hot-A lied Joint Sealant

HMIS HAZARD STATEMENTS


!Health! Ill WARNING!
fFlammabilityl 111 Causes skin irritation.
IReactivity I 101 Heated material will cause burns.
IPersonal. Protection I I I PRECAUTIONARY STATEMENTS
Avoid direct contact with heated material.
Avoid inhalation of fumes.

% by SARA Vapor Pressure LEL


Chemical Name: CAS Number Weight 313 Imm Hg@Z0"Cl ~
1. Petroleum Asphalt 8052-42-4 50-55 No N/A N/A
2. Petroleum Oil Base Stock 64742-65-0 10-15 No N/A 0.9
3. Limestone 1317-65-3 25-30 No N/A N/A
Under the reporting requirements of Section 313 of TTtle Ill of the Superfund Amendments and Reauthorization Act of 1966 {SARA}and 40 CFR
Part 372, chemicals listed on the 313 List (40 CFR Part 373.65) are identified under the heading "SARA 313." N/A = Not Applicable
---•,:.,--, ·----- -.r. ------=·--, ..........,.,,..,-..--,·,---·-
- ·-· i;! ~
EYE CONTACT: Not expected to be an exposure route as supplied, If contact with molten material occurs, seek immediate medical attention.
SKIN CONTACT: Wash affected areas with soap and water if available. If contact with hot molten material occurs, cool affected area with water.
Do not attempt to remove congealed solid. Do not use petroleum solvents to remove solids adhered to skin. Seek immediate medical attention.
INHALATION: Not expected to be an exposure route as supplied. If irritation occurs due to exposure to fumes produced by hot molten product,
move victim from exposure source and treat symptomatically. If symptoms persist, seek medical attention.
INGESTION: Not expected to be an exposure source.
......,~
FLASHPOINT: Not applicable; product is a solid.
EXTINGUISHING MEDIA: Water fog, foam, dry chemical.
CHEMICAL/COMBUSTION HAZARDS: Oxides and compounds of nitrogen/sulfur, carbon monoxide/dioxide, and incomplete combustion products,
PRECAUTIONS/PERSONAL PROTECTIVE EQUIPMENT: Avoid smoke inhalation. Hot material may spatter if hit by a direct stream of water. Use
ap ropriate ersonal protective equipment.

duct is a solid. If molten material is spilled, avoid direct contact. Allow material to cool and

SAFE STORAGE: Prevent job-site damage.


.,......__,:._..:.,_
_:_,.....,:'.
__

H
Chemical Name: PEL PEL[CEILING PEL[STEL SKIN TLV TLV[CEILING TLV[STEL SKIN
3
1. Petroleum Asphalt 5 mg/m * N/E N/E No 3
0.5 mg/m * N/E N/E N/E
2. Petroleum Oil Base Stock 3
N/E N/E N/E No 5 mg/m + N/E N/E N/E
3. Limestone N/A N/A N/A No N/A N/A N/A N/A
*: Asphalt Fumes +: Mineral Oil Mist in Air N/E: Not Established
ENGINEERING CONTROLS: None required under normal use conditions.
PERSONAL PROTECTIVE EQUIPMENT: Safety glasses, chemical res'tstant gloves.

BOILING POINT: N/A VAPOR DENSITY:N/A % VOLATILE BY VOLUME: N/A


EVAPORATION RATE: N/A pH LEVEL: N/A % VOLATILE BY WEIGHT: N/A
WEIGHT PER GALLON: N/A PRODUCTAPPEARANCE: Black solid VOCCONTENT: N/A

Page 19 of 46
SAFETYDATA SHEET
4210000

TO AVOID: Nqne recognized.


CONDITIONSAND MATERIALS
HAZARDOUSDECOMPOSITION PRODUCTS:None recognized.

EYECONTACT:Direct contact may cause mild irritation. Contact with heated material may cause severe burns.
SKINCONTACT:Direct contact may cause slight skin irritation. Contact with heated material may cause severe burns.
INHALATION:Not anticipated to be an exposure route. Heated material may emit fumes. Exposure to fumes may result in respiratory irritation.
INGESTION:Not anticipated to be an exposure route.
SIGNSAND SYMPTOMS:Symptoms of eye irritation include tearing, reddening, and swelling. Symptoms of skin irritation include redness and
swelling. Gastrointestinal irritation symptoms include nausea, vomiting, and abdominal discomfort. Symptoms of respiratory irritation include
runny nose, sore throat, coughing, chest discomfort, shortness of breath, and reduced lung function.
AGGRAVATED MEDICAL CONDITIONS:Pre-existing skin, eye, and respiratory disorders may be aggravated by exposure to this product.
OTHERHEALTHEFFECTS:ACGIH classifies asphalt as Not Classifiableas a Human Cardno en; A4.

POTENTIAL:N/E
BIOACCUMULATIVE

HAZARDOUS/NON-HAZARDOUS MATERIAL:Not regulated by DOT.


UN NUMBER: None. HAZARDCLASS:N/A PACKINGGROUP: N/A
UN PROPERSHIPPINGNAME: N/A
ENVIRONMENTAL HAZARDS:None recognized.
BULKTRANSPORTATION INFORMATION: None.
SPECIALPRECAUTIONS: None.

CONSIDERATIONS:None recognized.
OTHERREGULATORY

PREPARATIONDATE: 9/9/2014
PREPAREDBY: Dave Care

The information contained herein is based on the data available to us and is believed to be correct. However, we
make no warranty, expressed or implied regarding the accuracy of this data or the results to be obtained from the
use thereof We assume no responsibility for injury from the use of this product described herein.

Page 20 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

SECTION 1. IDENTIFICATION

Product name DOWSIL ™ 888 Silicone Joint Sealant

Product code 04104518

Manufacturer or supplier's details


Company Identification THE DOW CHEMICAL COMPANY
2030 WILLARD H DOW CENTER
MIDLAND Ml 48674-0000
UNITED STATES

Telephone 800-258-2436

24-Hour Emergency Contact Chemtrec +1 800-424-9300

Local Emergency Number 800-424-9300

E-mail address : SDSQuestion@dow.com


Recommended use of the chemical and restrictions on use
Recommended use : Construction materials and additives

SECTION 2. HAZARDS IDENTIFICATION

GHS classification in accordance with 29 CFR 1910.1200


Eye irritation Category 2A

Reproductive toxicity Category 2

GHS label elements


Hazard pictograms

Signal Word Warning

Hazard Statements H319 Causes serious eye irritation.


H361fd Suspected of damaging fertility. Suspected of damaging
the unborn child.

Precautionary Statements
Prevention:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read
and understood.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.

Page 21 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

Response:
P305 + P351 + P338 IF IN EYES: Rinse cautiously with water
for several minutes. Remove contact lenses, if present and easy
to do. Continue rinsing.
P308 + P313 IF exposed or concerned: Get medical advice/
attention.
P337 + P313 If eye irritation persists: Get medical advice/ atten-
tion.
Storage:
P405 Store locked up.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.

Other hazards
None known.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substance / Mixture Mixture

Chemical nature Silicone


Sealant

Hazardous ingredients
Cmemical nai::tle .:( ;,ii: jt ,"i, ,fi'(!.\'.· Oolilcentr;afion (% w/w:) ;;ii,;;
c~7ii~~i:~/'.:
CAS-No.'!!•.••·~~;~:ii=
Limestone 1317-65-3 >= 46 - <= 57
Methvlvinyl bis(N-ethylacetamido )silane 87855-59-2 >= 0.8 - <= 3
Dimethyl, methylhydrogen siloxane, dehy- 68952-53-4 >= 0.9 - <= 2.2
drogenated, reaction with hydroxydiethyla-
mine
Magnesium carbonate 546-93-0 >= 0.9 - <= 1.2
Quartz 14808-60-7 >= 0.33 - <= 0.41
Titanium dioxide 13463-67-7 >= 0.26 - <= 0.35
N-ethylacetam ide 625-50-3 >= 0.1 - <= 0.4
Octamethylcyclotetrasiloxane 556-67-2 >= 0.19 - <= 0.26
Impurities in methylvinylbis(N- Not Assigned >= 0.05 - <= 0.2
ethylacetam ido)silane

SECTION 4. FIRST AID MEASURES

General advice In the case of accident or if you feel unwell, seek medical
advice immediately.
When symptoms persist or in all cases of doubt seek medical
advice.

If inhaled If inhaled, remove to fresh air.


Get medical attention.

In case of skin contact In case of contact, immediately flush skin with plenty of water.
Page 22 of 46
SAFETY DAT A SHEET

DOWSIL ™ 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

Remove contaminated clothing and shoes.


Get medical attention.
Wash clothing before reuse.
Thoroughly clean shoes before reuse.

In case of eye contact In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes.
If easy to do, remove contact lens, if worn.
Get medical attention.

If swallowed If swallowed, DO NOT induce vomiting.


Get medical attention.
Rinse mouth thoroughly with water.

Most important symptoms Causes serious eye irritation.


and effects, both acute and Suspected of damaging fertility. Suspected of damaging the
delayed unborn child.

Protection of first-aiders First Aid responders should pay attention to self-protection,


and use the recommended personal protective equipment
when the potential for exposure exists.

Notes to physician Treat symptomatically and supportively.

SECTION 5. FIRE-FIGHTING MEASURES

Suitable extinguishing media Water spray


Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical

Unsuitable extinguishing None known.


media

Specific hazards during fire Exposure to combustion products may be a hazard to health.
ighting

Hazardous combustion prod- Carbon oxides


ucts Metal oxides
Silicon oxides
Formaldehyde
Nitrogen oxides (NOx)

Specific extinguishing meth- Use extinguishing measures that are appropriate to local cir-
ods cumstances and the surrounding environment.
Use water spray to cool unopened containers.
Remove undamaged containers from fire area if it is safe to do
so.
Evacuate area.

Special protective equipment In the event of fire, wear self-contained breathing apparatus.
for fire-fighters Use personal protective equipment.

Page 23 of 46
SAFETY DATA SHEET

DOWSILTM 888 Silicone Joint Sealant

Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protec- Use personal protective equipment.


tive equipment and emer- Follow safe handling advice and personal protective
gency procedures equipment recommendations.

Environmental precautions Discharge into the environment must be avoided.


Prevent further leakage or spillage if safe to do so.
Retain and dispose of contaminated wash water.
Local authorities should be advised if significant spillages
cannot be contained.

Methods and materials for Soak up with inert absorbent material.


containment and cleaning up For large spills, provide diking or other appropriate
containment to keep material from spreading. If diked material
can be pumped, store recovered material in appropriate
container.
Clean up remaining materials from spill with suitable
absorbent.
Local or national regulations may apply to releases and
disposal of this material, as well as those materials and items
employed in the cleanup of releases. You will need to
determine which regulations are applicable.
Sections 13 and 15 of this SDS provide information regarding
certain local or national requirements.

SECTION 7. HANDLING AND STORAGE

Technical measures See Engineering measures under EXPOSURE


CONTROLS/PERSONAL PROTECTION section.

Local/Total ventilation Use only with adequate ventilation.

dvice on safe handling Do not get on skin or clothing.


Do not swallow.
Do not get in eyes.
Handle in accordance with good industrial hygiene and safety
practice, based on the results of the workplace exposure
assessment
Take care to prevent spills, waste and minimize release to the
environment.

Conditions for safe storage Keep in properly labeled containers.


Store in accordance with the particular national regulations.

Materials to avoid Do not store with the following product types:


Strong oxidizing agents

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Ingredients with workplace control parameters

Page 24 of 46
SAFETY DATA SHEET

DOWSIL ™ 888 Silicone Joint Sealant

Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

,, ,_
' ,,,·, '
(Form of ters I Permfosible
I
• } I '
'•,
··• ',, ', exposure) concentration ' i,

Limestone 1317-65-3 TWA (total 15 mg/m 3 OSHAZ-1


dust)
TWA (respir- 5 mg/m3 OSHAZ-1
able fraction)
TWA (Res- 5 mg/m3 NIOSH REL
pirable) (Calcium carbo-
nate)
TWA (total) 10 mg/m 3 NIOSH REL
(Calcium carbo-
nate)
Magnesium carbonate 546-93-0 TWA (Res- 5 mg/m3 NIOSH REL
pirable)
TWA (total) 10 mq/m 3 NIOSH REL
TWA (total 15 mg/m 3 OSHA Z-1
dust)
TWA (respir- 5 mg/m3 OSHAZ-1
able fraction)
Quartz 14808-60-7 TWA (respir- 10 mg/m3 OSHA Z-3
able) I %SiO2+2
TWA (respir- 250 mppcf OSHAZ-3
able) I %SiO2+5
TWA(Res- 0.025 mg/m 3 ACGIH
pirable frac- (Silica)
tion)
TWA (Res- 0.05 mg/m 3 NIOSH REL
pirable dust) (Silica)
TWA (Res- 0.05 mg/m 3 OSHAZ-1
pirable dust)
Titanium dioxide 13463-67-7 TWA (total 15 mg/m 3 OSHAZ-1
dust)
TWA 10 mg/m 3 ACGIH
(Titanium dioxide)
Octamethylcyclotetrasiloxane 556-67-2 TWA 10 ppm US WEEL
Hazardous components without workplace control parameters
lnqredients ••,•·,
. ,'
,'j
CAS-'No. ·..·,·•,·
Methylvinyl bis(N- 87855-59-2
ethylacetamido )silane
Dimethyl, methylhydrogen 68952-53-4
siloxane, dehydrogenated,
reaction with hydroxydiethyla-
mine
N-ethylacetam ide 625-50-3
Impurities in methylvinylbis(N- Not Assigned
ethylacetamido )silane
These substance(s) are inextricably bound in the product and therefore do not contribute
to a dust inhalation hazard.
Quartz

Titanium dioxide

Page 25 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

Engineering measures Processing may form hazardous compounds (see section


10).
Ensure adequate ventilation, especially in confined areas.
Minimize workplace exposure concentrations.

Personal protective equipment


Respiratory protection General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are
unknown, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any
hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled
release, exposure levels are unknown, or any other
circumstance where air purifying respirators may not provide
adequate protection.

Hand protection

Material Chemical-resistant gloves

Remarks Choose gloves to protect hands against chemicals depending


on the concentration specific to place of work. Breakthrough
time is not determined for the product. Change gloves often!
For special applications, we recommend clarifying the
resistance to chemicals of the aforementioned protective
gloves with the glove manufacturer. Wash hands before
breaks and at the end of workday.

Eye protection Wear the following personal protective equipment:


Safety goggles

Skin and body protection Select appropriate protective clothing based on chemical
resistance data and an assessment of the local exposure
potential.
Skin contact must be avoided by using impervious protective
clothing (gloves, aprons, boots, etc).

Hygiene measures Ensure that eye flushing systems and safety showers are
located close to the working place.
When using do not eat, drink or smoke.
Wash contaminated clothing before re-use.
These precautions are for room temperature handling. Use at
elevated temperature or aerosol/spray applications may
require added precautions.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance paste

Page 26 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

Color gray

Odor Fishy

Odor Threshold No data available

pH Not applicable

Melting point/freezing point No data available

Initial boiling point and boiling Not applicable


range

Flash point 100 °C


Method: closed cup

Evaporation rate Not applicable

Flammability (solid, gas) Not classified as a flammability hazard

Self-ignition The substance or mixture is not classified as pyrophoric. The


substance or mixture is not classified as self heating.

Upper explosion limit/ Upper No data available


flammability limit

Lower explosion limit/ Lower No data available


flammability limit

Vapor pressure Not applicable

Relative vapor density No data available

Relative density 1.48

Solubility(ies)
Water solubility No data available

Partition coefficient: n- No data available


octanol/water

Autoignition temperature No data available

Decomposition temperature No data available

Viscosity
Viscosity, dynamic Not applicable

Explosive properties Not explosive

Oxidizing properties The substance or mixture is not classified as oxidizing.

Molecular weight No data available

Page 27 of 46
SAFETY DATA SHEET

DOWSILTM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

SECTION 10. STABILITY AND REACTIVITY

Reactivity Not classified as a reactivity hazard.

Chemical stability Stable under normal conditions.

Possibility of hazardous reac- Use at elevated temperatures may form highly hazardous
tions compounds.
Can react with strong oxidizing agents.
Hazardous decomposition products will be formed at elevated
temperatures.

Conditions to avoid None known.

Incompatible materials Oxidizing agents

Hazardous decomposition products


Thermal decomposition Formaldehyde

SECTION 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure


Skin contact
Ingestion
Eye contact
Acute toxicity
Not classified based on available information.
Product:
Acute oral toxicity Acute toxicity estimate:> 5,000 mg/kg
Method: Calculation method

Ingredients:

Limestone:
cute oral toxicity LD50 (Rat):> 2,000 mg/kg

r Assessment: The substance or mixture has no acute oral tox-


icity

Methylvinyl bis(N-ethylacetamido)silane:
cute oral toxicity Acute toxicity estimate: 500 mg/kg
Method: Expert judgment

cute dermal toxicity LD50 (Rat): > 2,000 mg/kg


Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: On basis of test data.

Magnesium carbonate:
IIAcute oral toxicity LD50 (Rat): > 2,000 mg/kg
Page 28 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

Method: OECD Test Guideline 420


Assessment: The substance or mixture has no acute oral tox-
icity

Quartz:
Ircute oral toxicity LD50 (Rat): > 5,000 mg/kg

Titanium dioxide:
cute oral toxicity LD50 (Rat): > 5,000 mg/kg

cute inhalation toxicity LC50 (Rat): > 6.82 mg/I


Exposure time: 4 h
Test atmosphere: dust/mist
Assessment: The substance or mixture has no acute inhala-
tion toxicity

N-ethylacetamide:
cute oral toxicity LD50 (Rat): 3,950 mg/kg
Remarks: Based on data from similar materials

cute inhalation toxicity LCD (Rat): 2.19 mg/I


Exposure time: 8 h
Test atmosphere: vapor
Remarks: Based on data from similar materials

Octamethylcyclotetrasiloxane:
cute oral toxicity LD50 (Rat): > 4,800 mg/kg
Assessment: The substance or mixture has no acute oral tox-
icity
Remarks: On basis of test data.

cute inhalation toxicity LC50 (Rat): 2975 ppm


Exposure time: 4 h
Test atmosphere: vapor
Assessment: The substance or mixture has no acute inhala-
tion toxicity
Remarks: On basis of test data.

cute dermal toxicity LD50 (Rabbit): > 2.5 ml/kg


Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: On basis of test data.

Impurities in methylvinylbis{N-ethylacetamido)silane:
cute oral toxicity Acute toxicity estimate: 500 mg/kg
Method: Expert judgment

cute dermal toxicity LD50 (Rat): > 2,000 mg/kg


Assessment: The substance or mixture has no acute dermal
toxicity
Remarks: Based on data from similar materials

Page 29 of 46
SAFETY DATA SHEET

DOWSILTM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

II
Skin corrosion/irritation
Not classified based on available information.
Ingredients:

Methylvinyl bis{N-ethylacetamido)silane:
Species: Rabbit
Result: No skin irritation
Remarks: On basis of test data.

Dimethyl, methylhydrogen siloxane, dehydrogenated, reaction with hydroxydiethylamine:


' Result: Skin irritation

IIRemarks: Based on data from similar materials

Magnesium carbonate:
Method: EPISKIN Human Skin Model Test

II
Result: No skin irritation

Titanium dioxide:
Species: Rabbit

II Result: No skin irritation

N-ethylacetamide:
Species: Rabbit
Result: No skin irritation
Remarks: Based on data from similar materials

Octamethylcyclotetrasiloxane:
' Species: Rabbit
Result: No skin irritation
Remarks: On basis of test data.

Impurities in methylvinylbis{N-ethylacetamido)silane:
' Species: Rabbit
Result: No skin irritation
Remarks: Based on data from similar materials

Serious eye damage/eye irritation


Causes serious eye irritation.
Ingredients:

Methylvinyl bis{N-ethylacetamido )silane:


Species: Rabbit
Result: Irreversible effects on the eye
Remarks: On basis of test data.

Page 30 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

Dimethyl, methylhydrogen siloxane, dehydrogenated, reaction with hydroxydiethylamine:


Result: Irritation to eyes, reversing within 21 days

II
Remarks: Based on data from similar materials

Magnesium carbonate:
Species: Rabbit
Result: No eye irritation
Method: OECD Test Guideline 405

Titanium dioxide:
Species: Rabbit

II
Result: No eye irritation

N-ethylacetamide:
Species: Rabbit
Result: No eye irritation
Remarks: Based on data from similar materials

Octamethylcyclotetrasiloxane:
Species: Rabbit
Result: No eye irritation
Remarks: On basis of test data.

Impurities in methylvinylbis(N-ethylacetamido)silane:
Species: Rabbit
Result: Irreversible effects on the eye
Remarks: Based on data from similar materials

Respiratory or skin sensitization

Skin sensitization
Not classified based on available information.
Respiratory sensitization
Not classified based on available information.
Ingredients:

Methylvinyl bis(N-ethylacetamido)silane:
Assessment: Does not cause skin sensitization.

est Type: Buehler Test


Species: Guinea pig
Result: negative
Remarks: On basis of test data.

Titanium dioxide:

l~
est Type: Local lymph node assay (LLNA)
Routes of exposure: Skin contact
Species: Mouse

Page 31 of 46
SAFETY DATA SHEET

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6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

I
result: negative

N-ethylacetamide:
est Type: lntracutaneous test
Routes of exposure: Skin contact
Species: Guinea pig
Result: negative
Remarks: Based on data from similar materials

Octamethylcyclotetrasiloxane:
ssessment: Does not cause skin sensitization.

est Type: Maximization Test


Species: Guinea pig
Result: negative
Remarks: On basis of test data.

Impurities in methylvinylbis(N-ethylacetamido)silane:
ssessment: Does not cause skin sensitization.

est Type: Buehler Test


Species: Guinea pig
Result: negative
Remarks: Based on data from similar materials

Germ cell mutagenicity


Not classified based on available information.
Ingredients:

Methylvinyl bis(N-ethylacetamido)silane:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Result: negative
Remarks: On basis of test data.

Test Type: Bacterial reverse mutation assay (AMES)


Result: negative
Remarks: On basis of test data.

Magnesium carbonate:
Genotoxicity in vitro Test Type: In vitro mammalian cell gene mutation test
Method: OECD Test Guideline 476
Result: negative
Remarks: Based on data from similar materials

Titanium dioxide:
Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Result: negative

Genotoxicity in vivo Test Type: In vivo micronucleus test


Species: Mouse
Page 32 of 46
SAFETY DAT A SHEET

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Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

II
N-ethylacetamide:
Result: negative

Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)


Result: negative
Remarks: On basis of test data.

Genotoxicity in vivo Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Mouse
Application Route: lntraperitoneal injection
Method: OECD Test Guideline 474
Result: negative
Remarks: Based on data from similar materials

Octamethylcyclotetrasiloxane:
Genotoxicity in vitro Test Type: Bacterial reverse mutation assay (AMES)
Result: negative
Remarks: On basis of test data.

Test Type: Mutagenicity (in vitro mammalian cytogenetic test)


Result: negative
Remarks: On basis of test data.

Test Type: Chromosome aberration test in vitro


Result: negative
Remarks: On basis of test data.

Test Type: In vitro sister chromatid exchange assay in mam-


malian cells
Result: negative
Remarks: On basis of test data.

Test Type: DNA damage and repair, unscheduled DNA syn-


thesis in mammalian cells (in vitro)
Result: negative
Remarks: On basis of test data.

Genotoxicity in vivo Test Type: Mammalian erythrocyte micronucleus test (in vivo
cytogenetic assay)
Species: Rat
Application Route: inhalation (vapor)
Result: negative
Remarks: On basis of test data.

Test Type: Rodent dominant lethal test (germ cell) (in vivo)
Species: Rat
Application Route: Ingestion
Result: negative
Remarks: On basis of test data.

Germ cell mutagenicity - Animal testing did not show any mutagenic effects.
ssessment

Page 33 of 46
SAFETY DATA SHEET

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Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

Impurities in methylvinylbis(N-ethylacetamido)silane:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Result: negative
Remarks: Based on data from similar materials

Test Type: Bacterial reverse mutation assay (AMES)


Result: negative
Remarks: Based on data from similar materials

Carcinogenicity
Not classified based on available information.
Ingredients:

Magnesium carbonate:
Species: Mouse
pplication Route: Ingestion
Exposure time: 18 Months
Result: negative
Remarks: Based on data from similar materials

Quartz:
Species: Humans
pplication Route: inhalation (dust/mist/fume)
Result: positive
Remarks: IARC: (International Agency for Research on Cancer)
hese substance(s) are inextricably bound in the product and therefore do not contribute to a
dust inhalation hazard.

Carcinogenicity - Assess- Positive evidence from human epidemiological studies (inhala-


ment tion)

Titanium dioxide:
Species: Rat
pplication Route: inhalation (dust/mist/fume)
Exposure time: 24 Months
Method: OECD Test Guideline 453
Result: positive
Remarks: The mechanism or mode of action may not be relevant in humans.
hese substance(s) are inextricably bound in the product and therefore do not contribute to a
dust inhalation hazard.

Carcinogenicity - Assess- Limited evidence of carcinogenicity in inhalation studies with


ment animals.

N-ethylacetamide:
Species: Mouse
pplication Route: inhalation (vapor)
Exposure time: 18 Months
Result: negative
Remarks: Based on data from similar materials

Page 34 of 46
SAFETY DAT A SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

IARC Group 1: Carcinogenic to humans

Quartz 14808-60-7

Group 2B: Possibly carcinogenic to humans

Titanium dioxide 13463-67-7

OSHA No component of this product present at levels greater than or


equal to 0.1 % is on OSHA's list of regulated carcinogens.

NTP Known to be human carcinogen

Quartz 14808-60-7

Reproductive toxicity
Suspected of damaging fertility. Suspected of damaging the unborn child.
Ingredients:

Methylvinyl bis(N-ethylacetam ido)silane:


Effects on fertility Species: Rat, male
Application Route: Ingestion
Symptoms: Effects on fertility.
Remarks: On basis of test data.

Reproductive toxicity - As- Some evidence of adverse effects on sexual function and
sessment fertility, based on animal experiments.

Magnesium carbonate:
Effects on fertility Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials

Effects on fetal development Test Type: Combined repeated dose toxicity study with the
reproduction/developmental toxicity screening test
Species: Rat
Application Route: Ingestion
Method: OECD Test Guideline 422
Result: negative
Remarks: Based on data from similar materials

N-ethylacetamide:
Effects on fetal development Test Type: Embryo-fetal development
Species: Mouse
Application Route: Ingestion
Result: positive
Remarks: Based on data from similar materials

Page 35 of 46
SAFETY DATA SHEET

DOWSIL rM 888 Silicone Joint Sealant

Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

I!
Reproductive toxicity - As- Some evidence of adverse effects on development, based on
sessment animal experiments.

Octamethylcyclotetrasiloxane:
Effects on fertility Test Type: Two-generation reproduction toxicity study
Species: Rat, male and female
Application Route: inhalation (vapor)
Symptoms: Effects on fertility.
Remarks: On basis of test data.

Effects on fetal development Test Type: Prenatal development toxicity study (teratogenicity)
Species: Rabbit
Application Route: inhalation (vapor)
Symptoms: No effects on fetal development.
Remarks: On basis of test data.

Reproductive toxicity - As- Some evidence of adverse effects on sexual function and
sessment fertility, based on animal experiments.

Impurities in methylvinylbis(N-ethylacetamido)silane:
Effects on fertility Species: Rat, male
Application Route: Ingestion
Symptoms: Effects on fertility.
Remarks: Based on data from similar materials

Reproductive toxicity - As- Some evidence of adverse effects on sexual function and
sessment fertility, based on animal experiments.

STOT-single exposure
Not classified based on available information.
STOT-repeated exposure
Not classified based on available information.
Ingredients:

Quartz:
outes of exposure: inhalation (dust/mist/fume)
arget Organs: Lungs

fssessment: Shown to produce significant health effects in animals at concentrations of 0.02


mg/l/6h/d or less.

Octamethylcyclotetrasiloxane:
Routes of exposure: Ingestion
ssessment: No significant health effects observed in animals at concentrations of 100 mg/kg
bw or less.

Routes of exposure: inhalation (vapor)


ssessment: No significant health effects observed in animals at concentrations of 1 mg/l/6h/d or
less.

Routes of exposure: Skin contact


ssessment: No significant health effects observed in animals at concentrations of 200 mg/kg
Page 36 of 46
SAFETY DAT A SHEET

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Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

llbw
or less.

Repeated dose toxicity

Ingredients:

Magnesium carbonate:
pecies: Rat
OAEL: 124 - 127 mg/kg
pplication Route: Ingestion
xposure time: 90 Days
~
Quartz:
Species: Humans
LOAEL: 0.053 mg/m3
pplication Route: Inhalation
Remarks: These substance(s) are inextricably bound in the product and therefore do not
contribute to a dust inhalation hazard.

Titanium dioxide:
Species: Rat
NOAEL: 24,000 mg/kg
pplication Route: Ingestion
Exposure time: 28 Days

Species: Rat
NOAEL: 1O mg/m 3
pplication Route: inhalation (dust/mist/fume)
Exposure time: 2 y
Remarks: These substance(s) are inextricably bound in the product and therefore do not
contribute to a dust inhalation hazard.

N-ethylacetamide:
Species: Rabbit
NOAEL: 0.09 mg/I
LOAEL: 0.36 mg/I
pplication Route: inhalation (vapor)
Exposure time: 24 Months
Remarks: Based on data from similar materials

Octamethylcyclotetrasiloxane:
Species: Rat
pplication Route: Ingestion
Remarks: On basis of test data.

Species: Rat
pplication Route: inhalation (vapor)
Remarks: On basis of test data.

Species: Rabbit
pplication Route: Skin contact
Remarks: On basis of test data.
Page 37 of 46
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II
Aspiration toxicity
Not classified based on available information.
Further information

Ingredients:

Octamethylcyclotetrasiloxane:
Remarks: Results from a 2 year repeated vapor inhalation exposure study to rats of octamethyl-
cyclotetrasiloxane (D4) indicate effects (benign uterine adenomas) in the uterus of female an i-
mals. This finding occurred at the highest exposure dose (700 ppm) only. Studies to date have
not demonstrated if these effects occur through pathways that are relevant to humans. Repeated
exposure in rats to D4 resulted in protoporphyrin accumulation in the liver. Without knowledge of
the specific mechanism leading to the protoporphyrin accumulation the relevance of this finding
to humans is unknown.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity

Ingredients:

Limestone:
oxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): > 10,000 mg/I
Exposure time: 96 h

oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 1,000 mg/I
aquatic invertebrates Exposure time: 48 h

oxicity to algae EC50 (Desmodesmus subspicatus (green algae)): > 200 mg/I
Exposure time: 72 h

Methylvinyl bis(N-ethylacetamido)silane:
oxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/I
Exposure time: 96 h
Method: OECD Test Guideline 203

NOEC (Oncorhynchus mykiss (rainbow trout)): 50 mg/I


Exposure time: 96 h

LC50 (Dania rerio (zebra fish)): > 100 mg/I


Exposure time: 96 h

oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 69 mg/I
aquatic invertebrates Exposure time: 48 h
Method: OECD Test Guideline 202

oxicity to algae EC50 (Pseudokirchneriella subcapitata (green algae)):> 100


mg/I
Exposure time: 72 h
Method: OECD Test Guideline 201

Page 38 of 46
SAFETY DATA SHEET

DOWSILTM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

NOEC (Pseudokirchneriella subcapitata (green algae)): 100


mg/I
Exposure time: 72 h

Dimethyl, methylhydrogen siloxane, dehydrogenated, reaction with hydroxydiethylamine:

Ecotoxicology Assessment
Ircute aquatic toxicity No toxicity at the limit of solubility.

Magnesium carbonate:
oxicity to fish LC50 (Pimephales promelas (fathead minnow)): 2,120 mg/I
Exposure time: 96 h
Remarks: Based on data from similar materials

oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): 490 - 1,127 mg/I
aquatic invertebrates Exposure time: 48 h
Remarks: Based on data from similar materials

oxicity to algae ErC50 (Desmodesmus subspicatus (green algae)): > 100 mg/I
Exposure time: 72 h
Method: OECD Test Guideline 201
Remarks: Based on data from similar materials

oxicity to microorganisms EC50: > 900 mg/I


Exposure time: 3 h
Method: OECD Test Guideline 209
Remarks: Based on data from similar materials

Quartz:

Ecotoxicology Assessment
rcute aquatic toxicity No toxicity at the limit of solubility.

rhronic aquatic toxicity No toxicity at the limit of solubility.

Titanium dioxide:
oxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)):> 100 mg/I
Exposure time: 96 h
Method: OECD Test Guideline 203

oxicity to daphnia and other EC50 (Daphnia magna (Water flea)): > 100 mg/I
aquatic invertebrates Exposure time: 48 h

oxicity to algae EC50 (Skeletonema costatum (marine diatom)):> 10,000 mg/I


Exposure time: 72 h

oxicity to microorganisms EC50: > 1,000 mg/I


Exposure time: 3 h
Method: OECD Test Guideline 209

N-ethylacetamide:
IIToxicity to fish LC50 (Leuciscus idus (Golden orfe)): 3,390 mg/I
Page 39 of 46
19{25 C
SAFETY DATA SHEET

DOWSILTM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date of first issue: 11/18/2014

Exposure time: 96 h
Method: DIN 38412
Remarks: Based on data from similar materials

oxicity to daphnia and other EC50 (Daphnia magna (Water flea)):> 580 mg/I
aquatic invertebrates Exposure time: 48 h
Method: DIN 38412
Remarks: Based on data from similar materials

oxicity to algae EC50 (Desmodesmus subspicatus (green algae)): > 500 mg/I
Exposure time: 96 h
Remarks: Based on data from similar materials

oxicity to microorganisms EC10 (Pseudomonas putida): > 10,000 mg/I


Exposure time: 17 h
Method: DIN 38 412 Part 8
Remarks: Based on data from similar materials

Octamethylcyclotetrasiloxane:
oxicity to fish LC50 (Cyprinodon variegatus (sheepshead minnow)):>
0.0063 mg/I
Exposure time: 336 h
Remarks: No toxicity at the limit of solubility.

oxicity to daphnia and other EC50 (Mysidopsis bahia (opossum shrimp)):> 0.0091 mg/I
aquatic invertebrates Exposure time: 96 h
Remarks: No toxicity at the limit of solubility.

oxicity to algae ErC50 (Pseudokirchneriella subcapitata (green algae)): >


0.022 mg/I
Exposure time: 72 h
Remarks: No toxicity at the limit of solubility.

oxicity to fish (Chronic toxic- NOEC (Oncorhynchus mykiss (rainbow trout)):>= 0.0044 mg/I
ity) Remarks: On basis of test data.
No toxicity at the limit of solubility.

oxicity to daphnia and other NOEC (Daphnia magna (Water flea)): >==0.0079 mg/I
aquatic invertebrates Exposure time: 21 d
(Chronic toxicity) Remarks: On basis of test data.
No toxicity at the limit of solubility.

Ecotoxicology Assessment
1rhronic aquatic toxicity May cause long lasting harmful effects to aquatic life.

Persistence and degradability

Ingredients:

Methylvinyl bis(N-ethylacetamido )silane:


Biodegradability Result: Not readily biodegradable.

II Biodegradation: 62.66 %
Method: OECD Test Guideline 301 B

Page 40 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

II
Dimethyl, methylhydrogen siloxane, dehydrogenated, reaction with hydroxydiethylamine:
Biodegradability Result: Not readily biodegradable.

II
N-ethylacetamide:
Remarks: Based on data from similar materials

Biodegradability Result: Inherently biodegradable.


Biodegradation: 100 %
Exposure time: 6 d
Remarks: Based on data from similar materials

Octamethylcyclotetrasiloxane:
Biodegradability Result: Not readily biodegradable.
Biodegradation: 3.7 %
Exposure time: 28 d
Method: OECD Test Guideline 310

Stability in water Degradation half life: 69.3 - 144 h (24.6 °C) pH: 7
Method: OECD Test Guideline 111

Bioaccumulative potential

Ingredients:

Octamethylcyclotetrasiloxane:
Bioaccum ulation Species: Pimephales promelas (fathead minnow)
Bioconcentration factor (BCF): 12,400

Partition coefficient: n- log Pow: 6.48 (25.1 °C)


octanol/water

Mobility in soil
No data available
Other adverse effects

Ingredients:

Octamethylcyclotetrasiloxane:
Results of PBT and vPvB Remarks: Octamethylcyclotetrasiloxane (D4) meets the cur-
assessment rent REACh Annex XIII criteria for PBT and vPvB. In Canada,
D4 has been assessed and deemed to meet the PiT criteria.
However, D4 does not behave similarly to known PBT/vPvB
substances. The weight of scientific evidence from field stud-
ies shows that D4 is not biomagnifying in aquatic and terres-
trial food webs. D4 in air will degrade by reaction with naturally
occurring hydroxyl radicals in the atmosphere. Any D4 in air
that does not degrade by reaction with hydroxyl radicals is not
expected to deposit from the air to water, to land, or to living
organisms .

Page 41 of 46
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SECTION 13. DISPOSAL CONSIDERATIONS

Disposal methods
Resource Conservation and This product has been evaluated for RCRA characteristics
Recovery Act (RCRA) and does not meet the criteria of hazardous waste if discarded
in its purchased form.

Waste from residues Dispose of in accordance with local regulations.

Contaminated packaging Empty containers should be taken to an approved waste


handling site for recycling or disposal.
If not otherwise specified: Dispose of as unused.product.

SECTION 14. TRANSPORT INFORMATION

International Regulations

UNRTDG
Not regulated as a dangerous good
IATA-DGR
Not regulated as a dangerous good
IMDG-Code
Not regulated as a dangerous good
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Not applicable for product as supplied.
Domestic regulation

49CFR
Not regulated as a dangerous good

SECTION 15. REGULATORY INFORMATION

EPCRA - Emergency Planning and Community Right-to-Know

CERCLA Reportable Quantity

109-89-7 100 *
*: Calculated RQ exceeds reasonably attainable upper limit.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

SARA 302 Extremely Hazardous Substances Threshold Planning Quantity


This material does not contain any components with a section 302 EHS TPQ.
SARA 311/312 Hazards Serious eye damage or eye irritation

II Reproductive toxicity

Page 42 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

SARA313 This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minim is)
reporting levels established by SARA Title 111,
Section 313.

US State Regulations

Pennsylvania Right To Know


Limestone 1317-65-3
Dimethyl siloxane, hydroxy-terminated 70131-67-8
Aluminum oxide 1344-28-1
Cobalt titanite green spinel 68186-85-6
C.I. Pigment Yellow 119 68187-51-9
Aluminium 7429-90-5
California Prop. 65
WARNING: This product can expose you to chemicals including Cobalt titanite green spinel,
which is/are known to the State of California to cause cancer. For more information go to
11www.P65Warnings.ca.gov.
California Permissible Exposure Limits for Chemical Contaminants
Limestone 1317-65-3
California Regulated Carcinogens
II Quartz 14808-60-7
The ingredients of this product are reported in the following inventories:
NZloC All ingredients listed or exempt.

TSCA All chemical substances in this product are either listed on the
TSCA Inventory or are in compliance with a TSCA Inventory
exemption.

AICS All ingredients listed or exempt.

ENCS/ISHL Consult your local Dow Chemical office.

REACH For purchases from Dow Chemical EU legal entities, all


ingredients are currently pre/registered or exempt under
REACH. Please refer to section 1 for recommended uses. For
purchases from non-EU Dow Chemical legal entities with the
intention to export into EEA please contact your DC
representative/local office.

IECSC One or more components of this product may not be listed on


the IECSC inventory, but this component(s) is (are) registered
with volume limitation under Dow Chemical entity in China.
Consult your local Dow Chemical office.

PICCS Consult your local Dow Chemical office.

DSL All chemical substances in this product comply with the CEPA
1999 and NSNR and are on or exempt from listing on the
Canadian Domestic Substances List (DSL).

TCSI All ingredients listed or exempt.

Page 43 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SDS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

SECTION 16. OTHER INFORMATION

Further information

NFPA: HMIS®IV:
Flammability

::,
:5 en
cii iii
I
Q)
g
~

HMIS® ratings are based on a 0-4 rating


scale, with O representing minimal ha-
zards or risks, and 4 representing signifi-
Special hazard.
cant hazards or risks. The"*" represents
a chronic hazard, while the "/" represents
the absence of a chronic hazard.

Full text of other abbreviations


ACGIH USA. ACGIH Threshold Limit Values (TLV)
NIOSH REL USA. NIOSH Recommended Exposure Limits
OSHAZ-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim-
its for Air Contaminants
OSHAZ-3 USA. Occupational Exposure Limits (OSHA) - Table Z-3 Min-
eral Dusts
US WEEL USA. Workplace Environmental Exposure Levels (WEEL)
ACGIH /TWA 8-hour, time-weighted average
NIOSH REL/TWA Time-weighted average concentration for up to a 10-hour
workday during a 40-hour workweek
OSHA Z-1 / TWA 8-hour time weighted average
OSHA Z-3 / TWA 8-hour time weighted average
USWEEL/TWA Time weighted average

AICS -Australian Inventory of Chemical Substances; ASTM - American Society for the Testing of
Materials; bw - Body weight; CERCLA - Comprehensive Environmental Response, Compensation,
and Liability Act; CMR - Carcinogen, Mutagen or Reproductive Toxicant; DIN - Standard of the
German Institute for Standardisation; DOT - Department of Transportation; DSL - Domestic Sub-
stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Ha-
zardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Sche-
dule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated
with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized
System; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System;
IARC - International Agency for Research on Cancer; IATA - International Air Transport Associa-
tion; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous
Chemicals in Bulk; IC50 - Half maximal inhibitory concentration; ICAO - International Civil Avia-
tion Organization; IECSC - Inventory of Existing Chemical Substances in China; IMDG - Interna-
tional Maritime Dangerous Goods; IMO - International Maritime Organization; ISHL - Industrial
Safety and Health Law (Japan); ISO - International Organisation for Standardization; KECI - Ko-

Page 44 of 46
SAFETY DATA SHEET

DOWSIL TM 888 Silicone Joint Sealant

Version Revision Date: SOS Number: Date of last issue: 04/28/2017


6.0 10/20/2017 773940-00011 Date offirst issue: 11/18/2014

rea Existing Chemicals Inventory; LC50 - Lethal Concentration to 50 % of a test population; LD50
- Lethal Dose to 50% of a test population (Median Lethal Dose); MARPOL - International Conven-
tion for the Prevention of Pollution from Ships; MSHA - Mine Safety and Health Administration;
n.o.s. - Not Otherwise Specified; NFPA - National Fire Protection Association; NO(A)EC - No Ob-
served (Adverse) Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR -
No Observable Effect Loading Rate; NTP - National Toxicology Program; NZloC - New Zealand
Inventory of Chemicals; OECD - Organization for Economic Co-operation and Development;
OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative
and Toxic substance; PICCS - Philippines Inventory of Chemicals and Chemical Substances;
(Q)SAR - (Quantitative) Structure Activity Relationship; RCRA - Resource Conservation and Re-
covery Act; REACH - Regulation (EC) No 1907/2006 of the European Parliament and of the
Council concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals; RQ -
Reportable Quantity; SADT - Self-Accelerating Decomposition Temperature; SARA - Superfund
Amendments and Reauthorization Act; SOS - Safety Data Sheet; TCSI - Taiwan Chemical Sub-
stance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations;
UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB -
Very Persistent and Very Bioaccumulative

Sources of key data used to Internal technical data, data from raw material SDSs, OECD
compile the Material Safety eChem Portal search results and European Chemicals Agen-
Data Sheet cy, http://echa.europa.eu/

Revision Date 10/20/2017

Items where changes have been made to the previous version are highlighted in the body of this
document by two vertical lines.

The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and
shall not be considered a warranty or quality specification of any type. The information provided
relates only to the specific material identified at the top of this SOS and may not be valid when the
SOS material is used in combination with any other materials or in any process, unless specified
in the text. Material users should review the information and recommendations in the specific
context of their intended manner of handling, use, processing and storage, including an
assessment of the appropriateness of the SOS material in the user's end product, if applicable.

US/ Z8

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