Shop Supplies SDS 2018

INVENTORY OF HAZARDOUS
CHEMICALSFORSDSBOOKS
Page COMMON NAME, HAZARDOUS CHEMICAL
3 Shop Supplies - Brake Cleaner

13 Shop Supplies - Carb & Throttle Body Cleaner
35 Shop Supplies - DEF, diesel exhaust fluid
47 Shop Supplies - Diesel Additive 9-1-1
57 Shop Supplies - FormulaShell SAE 30
73 Shop Supplies - Pennzoil Dex-Mere ATF
89 Shop Supplies - Power Steering Fluid
97 Shop Supplies - Quaker State SW-30 Synthetic Blend
Shop Supplies - Rotella Ultra ELC Antifreeze/Coolant Pre-
113 Diluted 50/50
129 Shop Supplies - Shell Rotella Tl 30
145 Shop Supplies - Shell Rotella TS l0W-30
159 Shop Supplies - Shell Spirax S4 TXM
175 Shop Supplies - Shell Spirax S6 ATF A295
191 Shop Supplies - Shell Spirax S6 AXME 80W-140
205 Shop Supplies - Shell Spirax S6 AXRME 75W-90
221 Shop Supplies - Shell T2 HD lSW-40
237 Shop Supplies - Shell Tellus S2 MX 46
253 Shop Supplies - Starting Fluid
275 Shop Supplies - Stihl, 2 cycle Oil
283 Shop Supplies - Stihl, Bar & Chain Oil
291 Shop Supplies - Synthetic DOT 3 Brake Fluid
299 Shop Supplies - WD-40
305 Shop Supplies - Windshield Washer Fluid
315 Shop Supplies - Zep 45
Page 1 of 326
Page 2 of 326
1
JOHNSEN S BRAKE CLEANER 16 OZ.
Safety Data Sheet
accordingto Federal Register/ Vol. 77, No. 58 / Monday,March26, 2012 / Rules and Regulations
Revisi'ondate: 08/19/2014 Version:
and.oftfiecompaii 1undettakin .· .·'·-.'" \;--:·:\_·;·'.~'\,,,- ·,\f

SECTION 1: Identificationof the sllbstahct:!frJiixture J:
t.'i.,: :' ·.Pr,pciuct 1r:ientif1er

Product form Mixture
Trade name JOHNSEN'S BRAKE CLEANER 16 OZ.
Product code 2420
Use of the substance/mixture : Brake Parts Cleaner
i q~f~11i;:i>flf\e~\ippli~{cii
'1;qi';,'J'; Uie'ii~tetydata·.sti.eet
,•\ 1;
Technical Chemical Company
P.O. BOX 139
Cleburne, Texas 76033
T 817-645-6088
1.4: >''· E;merganc:ytei~bone

ilulllbe(·:
Emergency number CHEMTREC 24 Hour 1-800-424-9300, 1-703-527-3887 (International)
~-Llii\'.¢ia~itication)1f(he,subsh)ncie
qtml)liure.
Classification (GHS-US)
Compressed gas H280
Acute Tax. 4 (lnhalatlgn) H332
Acute Tox. 4 (lnhalation:gas) H332
Eye lrrit. 2B H320
Care. 1B H350
Full 1ext of H-phrases: see section 16
2.2. ..·.··.
La~eleierniei,tS···
GHS-US labeling
Hazard pictograms (GHS-US)
GHS04 GHS07 GHSOB
Signal word (GHS-US) Danger

Hazard statements (GHS-US) H280 - Contains gas under pressure; may explode if heated
H320 - Causes eye irritation
H332 • Harmful ii inhaled
H350 - May cause cancer
Precautionary statements (GHS-US) P201 - Obtain special Instructions
P202 • Do not handle until all safety precautions have been read and understood
P261 • Avoid breathing dust,lume,gas,mist,vapor spray
P264 • Wash affected areas thoroughly after handling
P271 - Use only outdoors or In a well-ventilated area
P280 • Wear protective gloves,protective clothing.eye protection,lace protection
P304tP340 • If inhaled: Remove person to fresh air and keep comfortable for breathing
P305+P351 +P338 - II in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing .
P308+P313 • If exposed or concerned: Get medical advice/attention
P312 ·Calla POISON CONTROL CENTER, doctor, ii you feel unwell.
P337+P313 • II eye Irritation persists: Get medical advice/attention
P405 - Store locked up
P410+P403 • Protect from sunlight. Store in a well-ventilated place
P501 • Dispose of contents/container to appropriate waste disposal facility, In accordance with
local, regional, national, international regulations.
2.a:. '/
ptl'lediazards
Other hazards not contributing to the Contains gas under pressure; may explode ii heated.
classification
_2;4. ',_lfoktioiJVn
aciifetoxlclty,(GHS;ll~):
No data available
13/02/2015 EN (English US) 1/9
Page 3 of 326
JOHNSEN'S BRAKE CLEANER 16 OZ.
Safety Data Sheet
accordingto FederalRegister/ Vol. 77, No.58 / Monday,March26, 2012 I Rulesand Regulations
Not applicable
Care. 1B, H350

Aquatic Chronic2, H411
CarbonDioxide, Liquefied,Under Pressure (GASNo) 124-38-9 1 -5 Compressedgas, H280
The exact percentage is a trade secret.
First-aid measures general Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice
(show the label where possible).
First-aid measures after inhalation Allow victim to breathe fresh air. Allow the victim to rest. Remove victim to fresh air and keep at
rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you
feel unwell.
First-aid measures after skin contact Remove affected clothing and wash all exposed skin area with mild soap and water, followed by
warm water rinse.
First-aid measures after eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, tt present
and easy to do. Continue rinsing.
First-aid measures after Ingestion Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
Symptoms/injuries May cause cancer.

Symptoms/injuries after inhalation Danger of serious damage to health by prolonged exposure through inhalation. Hannful if
inhaled.
Symptoms/injuries after skin contact May cause slight irritation . Itching. Skin rash/inflammation. Red skin.
Symptoms/injuries after eye contact Irritation of the eye tissue. Inflammation/damage of the eye tissue. Redness of the eye tissue.
Causes eye irritation.
Symptoms/injuries after Ingestion May be harmful if swallowed and enters airways. May be fatal If swallowed and enters airways.
rA@l\t::1r:lli!'.1i4~tJQitsit~'iiJ.mm!lf11~~Pf/~l~rire~ir
1~:m®1~,,~ijo~bi@~"-'---•-
iij1Jq(i.~1frt
, ,·.·.•
· -
No additional infonnatlon available
;~:1t\'.}:'iEi:tin@l~11ipg•m~i~•~i;•
Suitable extinguishing media Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media Do not use a heavy water stream.
[$:ti;•.::'.
1:ipee,laUi~i:d~)r1~l@Ir~mttie~b~t1m£einlifur~
oi:_
Fire hazard : Not flammable.
'5;:3;]:
,; .,,Acivlce
fo(fii~f!ghter~-··
Firefighting instructions Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting Do not enter fire area without proper protective equipment, including respiratory protection.
Other information NFPA Aerosol Level 1.
General measures : Remove ignition sources.
6.1.1. For non-emergency personnel

Protective equipment Gloves. Safety glasses.
Emergency procedures E:vacuate unnecessary personnel.
6.1.2. For emergency responders

Protective equipment Equip cleanup crew with proper protection.
Emergency procedures Ventilate area.
;,t~ic;(;_r.1;@ftji)ajii,i;i_taJpfrt'!o~~qfl9nll•
Prevent entry to sewers and public waters. Notify authorities If liquid enters sewers or public waters.
13/02/2015 EN (EnglishUS) 2/9
Page 4 of 326
Satety Data Sheet
accordingto Federal Register/ Vol. 77, No. 58 / Monday, March 26, 2012 / Rulesand Regulations
For containment Dam up the liquid spill. Contain released substance, pump into suitable containers. Plug the leak,
cut off the supply.
Methods for cleaning up Store away from other materials.
BA:•; i :Reference •
toottier·sectipns:;
See Heading 8. Exposure controls and personal protection.
':·':'--Pr~ca~uons.1~E.-~at~·t1~n~U
:7/i/_,:~::. 1··:;,: hti, 1
':.'
Precautions for sale handling Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation of
vapor. Use only outdoors or in a well-ventilated area. Avoid breathing dust,fume,gas,mist,vapor
spray. Obtain special Instructions . Do not handle until all safety precautions have been read and
understood.
Hygiene measures Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Do not eat, drink or smoke when using this product. Wash
affected areas thoroughly after handling. Wash contaminated clothing before reuse.
;r;_f lnciucilniiiiny
sJ9_rj~fe
st9iilie;
'.:;<".T'¢:onct«~on ....
incomp~ti6iiities
Technical measures Proper grounding procedures to avoid static electricity should be followed. Comply with
applicable regulations.
Storage conditions Keep only in the original container in a cool, well ventilated place away from : Keep container
closed when not in use.
Incompatible products Strong bases. Strong acids.
Incompatible materials Sources of ignition. Direct sunlight.
Storage area Store in a well-ventilated place.
7.3/i:" ii $pedjf1q~n~.U$1:{$):
Follow Label Directions.
::L:','•\\,',:\'·,,'•,::
Jet_rli\chlofi:,ethylerfo:(t27~1(!4)•C·• ' :.
'\ ·:· ,:<•,::,,, ·.:.:t ' ' ;
'.//.·.::/'/:,,· .::·:•· ,·,.
', ': : .··,
USAACGIH ACGIH TWA (mg/m 3 ) 170 mg/m 3
USA ACGIH ACGIH TWA (ppm) 25 ppm
USA ACGIH ACGIH STEL (mg/m') 685 mg/m 3
USA ACGIH ACGIH STEL (ppm) 100 ppm
USA OSHA OSHA PEL (TWA) (ppm) 1_00ppm
USA OSHA OSHA PEL (Ceiling) (ppm) 200 ppm
..
..Carbl)A·
Oio~ide, UnderJ"ressllr~.
Liquefied,. ,,,
(1.24-~8°9)
,·
' '' . i-:
-::-,
,.•
USAACGIH ACGIH TWA (mgim') 9000 mg/m'
USAACGIH ACGIH TWA (ppm) 5000 ppm
USA ACGIH ACGIH STEL (mgim') 54000
USAACGIH ACGIH STEL (ppm) 30000 ppm
USA OSHA OSHA PEL (TWA) (mg/m 3) 9000 mg/m'
USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm
: ·..:·91_s
;_8;2,;· '.'cE~P9_llUre'.contr
Appropriate engineering controls Local exhaust venllation, vent hoods . Ensure good ventilation of the work station.
Personal protective equipment Gloves. Safety glasses. Avoid all unnecessary exposure.
Hand protection Wear protective gloves.

Eye protection Chemical goggles or safety glasses.
Skin and body protection Wear suitable protective clothing.
Respiratory protection Wear appropriate mask.
Other information Do not eat, drink or smoke during use.
13/02/2015 EN (English US) 3/9
Page 5 of 326
Safety Data Sheet
according to Federal Register/ Vol. 77, No. 58 I Monday, March 26, 2012 / Rules and Regulations
Physical state Gas

Appearance Liquid.
Molecular mass 165.83 g/mol
Color Colourless.
Odor Sweet odour. Ether-like odour.
Odor threshold 2.0· 71 ppm
pH 6.8 • 8.4
Relative evaporation rate (butyl acetate=1) 2
Relative evaporation rate (ether=1) 8
Melting point -22°C
Freezing point No data available
Boiling point 121 °C
Flash point None
Critical temperature 347°C
Auto-ignition temperature No data available
Decomposition temperature > 150 °C
Flammability (solid, gas) No data available
Vapor pressure 19 hPa
Vapor pressure at 50 °C 82 hPa
Relative vapor density at 20 °C 5.8
Relative density 1.62
Relative density of saturated gas/air mixture 1.1
Specific gravity/ density 1623 kg/m3
Solubility Insoluble in water. Substance sinks in water. Soluble in ethanol. Soluble In ether. Soluble in
acetone. Soluble in chloroform. Soluble in tetrachloromethane. Soluble in hexane. Soluble in
oils/fats.
Water: 0.015 g/100ml
Ethanol: soluble
Ether: soluble
Acetone:> 10 g/100ml
Log Pow 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 °C)
Log Kow No data available
Viscosity, kinematic 0.555 mm 2/s (20 °C)
Viscosity, dynamic No data available
Explosive properties No data available
Oxidizing properties No data available
Explosive limits No data available
Saturation concentration 127 g/m 3

VOCcontent 0%
No additional information available
Not established.
Not established.
tto;ftr:':i•¢p:iii:l1I@h~•,~fiWi1ctJ::
,, .
Direct sunlight. Extremely high or low temperatures.
l:tQ~,);tfri6'tj1'tiif.i~p_i~
.i:nit.~ti~l~\LT)·•.
Strong acids. Strong bases.
;· .:•J1~#irdQijftieii~mpo~1
[i'o;~; ;t1ari
~(gili.icits'_.
··
Toxic fume .. Carbon monoxide. Carbon dioxide.
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4/9
Page 6 of 326
1
Safety Data Sheet

according to Federal Register I Vol. 77, No. 68 / Monday, March 26, 2012 / Rules and Regulations
Acute toxicity Harmful if inhaled. Harmfulif Inhaled.
LD50 oral rat

LD50 dermal rabbit > 3000 mg/kg (Rabbit; Literaturestudy;> 10000 mg/kg bodyweight;Rabbit; Experimental
value)
LC50 inhalation rat (mg/I) 27.58 mg/I/4h (Rat; Literaturestudy)
LC50 inhalation rat (ppm)
LD50 oral rat > 2000 mg/kg (Rat; Equivalentor similar to OECD 401; Literaturestudy; 3835 mg/kg
bodyweight;Rat; Equivalentor similar to OECD 401; Experimentalvalue; 3005 mg/kg
bodyweight;Rat; Experimentalvalue)
LD50 dermal rabbit > 3000 mg/kg (Rabbit; Literaturestudy; >10000 mg/kg bodyweight;Rabbit; Experimental
value)
LC50 inhalation rat (mg/I) 27.58 mg/l/4h (Rat; Literaturestudy)
LC50 Inhalation rat (ppm) 3786 ppm/4h (Rat; Experimentalvalue)
Skin corrosion/Irritation Not classified
pH: 6.8 • 8.4
Serious eye damage/irritation Causes eye irritation.
pH: 6.8 • 8.4
Respiratory or skin sensitization Not classified
Germ cell mutagenlclty Not classified
Carcinogenicity May cause cancer.
IARC group
Reproductive toxicity Not classified
Specific target organ toxicity (single exposure) Not classified
Specific target organ toxicity (repeated Not classified

exposure)
Aspiration hazard Not classified
Potential Adverse human health effects and Based on available data, the classificationcriteria are not met. Harmfulif inhaled.
symptoms
Symptoms/injuries after inhalation Danger of serious damageto health by prolonged exposurethroughinhalation. Harmfulif
inhaled..
Symptoms/injuries after skin contact May cause slight irritation . Itching.Skin rash/inflammation.Red skin.
Symptoms/injuries after eye contact Irritation of the eye tissue. Inflammation/damageof the eye tissue. Redness of the eye tissue.
Causes eye irritation.
Symptoms/injuries after ingestion May be.harmful if swallowedand enters airways. May be fatal if swallowedand enters airways.
Ecology - general Dangerousfor the environment.

Ecology - air Not classifiedas dangerousfor the ozone layer (Regulation(EC) No 1005/2009). Not includedin
the list of fluorinatedgreenhousegases (Regulation(EC) No B42/2006).TA-Luft Klasse5.2.5/1.
CLEANER16 OZ,
JOHNSEN'S BR;&;KE
LC50 fish 1
EC50 Daphnia 1 8.5 mg/I (48 h; Daphnia magna;Locomotoreffect)
LC50 fish 2 13 mg/I (96 h; Lepomls macrochirus)
(,'.;'';:' ··•<, '
;,.,·· .•... i,::•·..::·.:.''.· ·./::.L.,··., .·.'' '.,.,,.'
.., .
Tetrachloroethylede(127°18-4);,\: : ;·
LC50 fish 1 4.99 mg/I (96 h; Salmo gairdnerl(Oncorhynchusmykiss); Locomotoreffect)

EC50 Daphnia 1 8.5 mg/I (48 h; Daphnla magna; Locomotoreffect)
LC50 fish 2 13 mg/I (96 h; Lepomls macrochirus)
Threshold limit algae 1 816 mg/I (96 h; Selenastrumcaprlcornutum;Cell numbers)
Threshold limit algae 2 3.64 mg/I (72 h; Chlamydomonasangulosa; Growth rate)
13/02/2015 EN (English US) 5/9
Page 7 of 326
JOHNSEN 1S BRAKE CLEANER 16 OZ.
Safety Data Sheet
accordingto Federal Register/ Vol. 77, No. 58 / Monday,March 26! 2012 / Rules and Regulations
Biochemical oxygen demand (BOD) 0.06 g 0 2 lg substance

ThOD 0.39 g 0 2 lg substance
BOD(% of ThOD)
Persistence and degradability Biodegradability: not applicable. Not applicable (gas).

Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable
BCF fish 2 25.8 • 77.1 (8 weeks; Cyprinus carpio)

BCF other aquatic organisms 1 63 (Modiolus modiolus; Mantle, dry weight)
BCF other aquatic organisms 2 39 (Buccinum undatum; Muscles, dry weight)
Log Pow 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 "C)
Bioaccumulative potential
BCF fish 1
BCF fish 2 25.8 • 77.1 (8 weeks; Cyprinus carpio)
BCF other aquatic organisms 1 63 (Modiolus modiolus; Mantle, dry weight)
BCF other aquatic organisms 2 39 (Buccinum undatum; Muscles, dry weight)
Log Pow 3.40 (Experimental value; 2.53; Experimental value; Equivalent or similar to OECD 107; 23 'C)
Other information Avoid release to the environment.
Waste disposal recommendations Dispose·in a safe manner in accordance with local/national regulations. Dispose of
contents/container to appropriate waste disposal facility, in accordance with local, regional,
· national, international regulations.
Ecology .'waste materials Avoid release to the environment.
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Page 8 of 326
Safety Data Sheet
according to Federal Register/ Vol, 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
In accordance with ADR /RID/ IMDG / IATA / ADN

US DOT (ground): UN1950, Aerosols, 2.2, Limited Quantity
ICAO/IATA (air): UN1950, Aerosols, 2.2, Limited Quantity
IMO/IMDG (water): UN1950, Aerosols, 2.2, Limited Quantity
·
;1u:/ JJ~krorief~Nririfngtja1i\~i
Proper Shipping Name (DOT) Aerosols
poison, (each not exceeding 1 L capacity)
Department of Transportation (DOT) Hazard 2.2 - Class 2.2 - Non-flammable compressed gas 49 CFR 173.115
Classes
Hazard labels (DOT) 2.2 • Non-flammable gas
6.1 · Poison Inhalation hazard
DOT Packaging Exceptions (49 CFR 173.xxx) 306

DOT Packaging Non Bulk (49 CFR 173.xxx) None
DOT Packaging Bulk (49 CFR 173.xxx) None
Marine pollutant Yes
..·· l\dd,l,tfoniii
sl1;3 .•' '
Ih1q@_a<i:h'.i9
Other infomnation No supplementary information available.
Overland transport
No additional infomnation available
Transport by sea
· DOT Vessel Stowage Location A - The material may be stowed "on deck" or "under deck" on a cargo vessel and on a
passenger vessel.
DOT Vessel Stowage Other 48 • Stow "away from" sources of heat,87 - Stow "separated from" Class 1 (explosives) except
Division 14,126 • Segregation same as for Class 9, miscellaneous hazardous materials
Air transport
DOT Quantity Limitations Passenger aircraft/rail Forbidden
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 Forbidden
CFR 175.75)
Listed on the United States SARA Section 302

Listed on United States SARA Section 313
RQ (Reportable quantity, section 304 of EPA's 100 lb Tetrach\oroethy\ene
List of Lists)
SARA Section 311/312 Hazard Classes Immediate (acute) health hazard
Delayed (chronic) health hazard
:~µ1.atloris:
·1s.1,.;lritefn~t1cina1
CANADA
.16
CL,EANEFI
JOHNSEN'S BRAK!;:. oz:
WHMIS Classrrication
EN (English US) 7/9

13/02/2015
Page 9 of 326
1
Safety Data Sheet

accordingto Federal RegisterI Vol. 77, No. 58 I Monday, March26, 2012 / Rules and Regulafions
Class D Division 1 Subdivision B • Toxic material causing immediate and serious toxic effects
Class D Division 2 Subdivision A.- Very toxic material causing other toxic effects
EU-Regulations
No additional information available
Classlfication according to Regulation (EC) No. 1272/2008 [CLP]
Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPDJ

Carc.Cat.3; R4D
Full text of A-phrases: see section 16
15.2.2. National regulations
U.S. • California • Proposition 65 • Maximum Allowable Dose Levels (MADL)

Not for sale in California or New Jersey
U.S.• Pennsylvania• RTK (Right to Know) List
U.S.· New Jersey· Right to Know Hazardous Substance List
U.S.· Massachusetts• Right To Know List
U.S.• Rhode Island• Hazardous Substance List
Training advic.e Normal use of this product shall imply use in accordance with the instructions on the packaging.
Other information None.
Full text of H·phrases: see section 16:
Acute Tox. 4 (Inhalation) Acute toxicity (inhalation) Category 4
Acute Tox. 4 (lnhalation:gas) Acute toxicity (inhalation:gas) Category 4
Aquatic Chronic 2 Hazardous to the aquatic environment - Chronic Hazard Category 2
Carc.18 Carcinogenicity Category 1B
Compressed gas Gases under pressure Compressed gas
Eye lrrit. 28 Serious eye darnage/eye irritation Category 28
H28D Contains gas under pressure; rnay explode if heated
H320 Causes eye irritation
H332 Harmful if inhaled
H350 May cause cancer
H411 Toxic lo aquatic life with long lasting effects
NFPA health hazard 2 - Intense or continued exposure could cause temporary

incapacitation or possible residual Injury unless prompt
medical attention is given.
NFPA lire hazard 0 · Materials that will not burn.
NFPA reactivity D • Normally stable, even under fire exposure conditions,
and are not reactive with water.
HMIS Ill Rating

Health 2 Moderate Hazard • Temporary or minor injury may occur
Flammability o Minimal Hazard
Physical 1 Slight Hazard
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Page 10 of 326
Safety Data Sheet
according to Federal Register/ Vol. 77, No. 58 / Monday, March 26, 20121 Rules and Regulations
Personal Protection : B
SDS US (GHS HazCom 2012) • TCC
The Supplier/dent/fledIn Section 1 of this MSDShas evaluated this product and certifiesIt to be labeledand packagedIn compliancewHhthe appllcableprovisions of the FederalHazardous
SubstanceAct as stated fn 16 CFR 1500and enforcedby the ConsumerProduct Safety Commfssfon,and whereapplicabfethe products that require Ch!JdResistant Closuresare packagedin
accordancewith the PolsonPrevention PackagingAct as stated In 16 CFR 1700and enforcedby the ConsumerProductSafety Commission.All closureshave been tested In accordancewith the
latest protocols. No other testing Is requiredto certifycompliancewlfh the above. The date of manufactureIs stamped on the product
D!sc/afmer: The Informationand recommendationscontained hereinare based upon tests believedto be re/fable. However,the manufacturer/distributorof this product doesnot guaranteetheir
accuracy or completenessNOR SHALL ANY OF THISINFORMAT/ON CONSTITUTEA WARRANTY,WHETHEREXPRESSEDOR IMPLIED,AS TO THE SAFETY OF THE GOODS, THE
MERCHANTABILITYOF THE GOODS, OR THEFITNESSOF THE GOODS FOR A PARTICULARPURPOSE.Adjustmentlo conform lo actual conditionsof usage may be required. The
assumes no responsibilityfor results obtainedor for Jncfdentalor consequentialdamages,Jnclud/nglost profits, arising from the use of these data. No warrantyagainst
manutacturer/d/strfbutor
Infringementof any patent,copyright or trademarkIs made or implied.
13/02/2015 EN (English US) 9/9
Page 11 of 326
Page 12 of 326
Page: 1
Revision Date: 05/23/2015

SAFETY DATA SHEET
Print Date: 6/1/2015
SOS Number: R0328421
Pyroil™ CARS & THROTTLE BODY CLEANER Version: 1.0
PYC16
29 CFR 1910.1200 (OSHA HazCom 2012)

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product identifier
Trade name Pyroil™ CARS & THROTTLE BODY
CLEANER
Recommended use of the chemical and restrictions on use
Details of the supplier of the safety data Emergency telephone number

sheet 1-800-ASH LAND ( 1-800-27 4-5263)
Ashland
P.O. Box 2219 Regulatory Information Number
Columbus, OH 43216 1-800-325-3751
United States of America
Product Information
614- 790-3333
EHS Customer Requests@ashland.com
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Flammable aerosols Category 1
Acute toxicity (Oral) Category 4
Acute toxicity (Inhalation) Category 4
Acute toxicity (Dermal) Category 4
Skin irritation Category 2
Eye irritation Category 2A
Specific target organ Category 1 (Central nervous system, Eyes)

systemic toxicity - single
exposure
Specific target organ Category 3 (Respiratory system, Central nervous system)

exposure
Specific target organ Category 2 (Auditory system)

systemic toxicity - repeated
exposure
Aspiration hazard Category 1
Page 13
1·122of 326
Page:2
SAFETY DATA SHEET Revision Date: 05/23/2015

Pyroil™ CARB & THROTTLE BODY CLEANER Version: 1.0
PYC16
GHS Label element

Hazard pictograms
Signal Word Danger
Hazard Statements Extremely flammable aerosol.

Harmful if swallowed, in contact with skin or if inhaled.
May be fatal if swallowed and enters airways.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Causes damage to organs (Central nervous system, Eyes).
May cause damage to organs (Auditory system) through
prolonged or repeated exposure.
Precautionary Statements Prevention:

Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Do not breathe dust/ fume/ gas/ misU vapors/ spray.
Wash skin thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Wear eye protection/ face protection.
Wear protective gloves/ protective clothing.
Response:
IF SWALLOWED: Immediately call a POISON CENTER or
doctor/ physician.
IF ON SKIN: Wash with plenty of soap and water. Call a
POISON CENTER or doctor/ physician if you feel unwell.
IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or doctor/ physician if
you feel unwell.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue
rinsing.
IF exposed: Call a POISON CENTER or doctor/ physician.
Do NOT induce vomiting.
If skin irritation occurs: Get medical advice/ attention.
If eye irritation persists: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Protect from sunlight. Do not expose to temperatures exceeding
50 °C/ 122 °F.
Disposal:
Page 14 of 326
Page:3

PYC16
Dispose of contents/ container to an approved waste disposal

plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture Mixture
Chemical nature Static Accumulator
Chemical nature Defatter
Hazardous components
,, i ,,
t~emioalNamE? . ' ,,,,• : .••··· OAS-~o. _{ '~.. : ·• Classtfication (Conbehtratipn (%)
ACETONE 67-64-1 Flam. Liq. 2; H225 51.80
Eye lrrit. 2A; H319
STOT SE 3; H336
METHANOL 67-56-1 Flam. Liq. 2; H225 22.07
Acute Tax. 3; H301
Acute Tax. 3; H331
Acute Tax. 3; H311
STOT SE 1; H370
XYLENE 1330-20-7 Flam. Liq. 3; H226 20.12
Acute Tax. 4; H312
Skin lrrit. 2; H315
Eye lrrit. 2A; H319
STOT SE 3; H335,
H336
Asp. Tax. 1; H304
3 / 22
Page 15 of 326
Page:4

PYC16
ETHYL BENZENE 100-41-4 Flam. Liq. 2; H225 6.03
Acute Tax. 4; H332
Skin lrrit. 2; H315
Eye lrrit. 2A; H319
STOT RE 2; H373
Asp. Tax. 1; H304
CARBON DIOXIDE 124-38-9 Press. Gas Liquefied 6.00

gas; H280
SECTION 4. FIRST AID MEASURES
General advice Move out of dangerous area.

Call a POISON CENTRE or doctor/physician if exposed or
you feel unwell.
Show this safety data sheet to the doctor in attendance.
Symptoms of poisoning may appear several hours later.
Do not leave the victim unattended.
If inhaled Move to fresh air.

Keep patient warm and at rest.
If unconscious place in recovery position and seek medical
advice.
Consult a physician after significant exposure.
In case of skin contact Remove contaminated clothing. If irritation develops, get

medical attention.
If on skin, rinse well with water.
Wash contaminated clothing before re-use.
In case of eye contact Immediately flush eye(s) with plenty of water.

Remove contact lenses.
Protect unharmed eye.
If swallowed Obtain medical attention.

Rinse mouth with water.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Page 16 of 326
Page:5

SAFETY DATA SHEET
Pyroil™ GARB & THROTTLE BODY CLEANER Version: 1.0
PYC16
Most important symptoms This material (or a component) has produced hyperglycemia
and effects, both acute and and ketosis following substantial ingestion.
delayed This product contains methanol which can cause intoxication
and central nervous system depression. Methanol is
metabolized to formic acid and formaldehyde. These
metabolites can cause metabolic acidosis, visual disturbances
and blindness. Since metabolism is required for these toxic
symptoms, their onset may be delayed from 6 to 30 hours
following ingestion. Ethanol competes for the same metabolic
pathway and has been used to prevent methanol metabolism.
Ethanol administration is indicated in symptomatic patients or
at blood methanol concentrations above 20 ug/dl. Methanol is
effectively removed by hemodialysis.
Inhalation of high concentrations of this material, as could
occur in enclosed spaces or during deliberate abuse, may be
associated with cardiac arrhythmias. Sympathomimetic drugs
may initiate cardiac arrhythmias in persons exposed to this
material.
Signs and symptoms of exposure to this material through
breathing, swallowing, and/or passage of the material through
the skin may include:
redness of the skin
stomach or intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways)
discomfort in the chest
effects on memory
muscle cramps
pain in the abdomen and lower back
Blurred vision
Shortness of breath
confusion
irregular heartbeat
cyanosis (causes blue coloring of the skin and nails from lack
of oxygen)
visual impairment (including blindness)
Harmful if swallowed, in contact with skin or if inhaled
Causes damage to organs.
May cause damage to organs through prolonged or repeated
exposure.
Notes to physician No hazards which require special first aid measures.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Page 17
5/22of 326
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Pyroil™ CARB & THROTTLE BODY CLEANER
Version: 1.0
PYC16
Foam
Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Unsuitable extinguishing High volume water jet

media
Specific hazards during Never use welding or cutting torch on or near drum (even
firefighting empty) because product (even just residue) can ignite
explosively.
Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion carbon dioxide and carbon monoxide

products Hydrocarbons
Aid eh yd es
Specific extinguishing
methods
Product is compatible with standard fire-fighting agents.
Further information Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Use a water spray to cool fully closed containers.
Special protective equipment In the event of fire, wear self-contained breathing apparatus.
for firefighters
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, Evacuate personnel to safe areas.

protective equipment and Remove all sources of ignition.
emergency procedures Use personal protective equipment.
Ensure adequate ventilation.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.
Environmental precautions Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Other information Comply with all applicable federal, state, and local regulations.
Suppress (knock down) gases/vapours/mists with a water
spray jet.
I ..··
:e-.:..,,.::
Page 18 of 326
Page:?

SAFETY DATA SHEET
PYC16
SECTION 7. HANDLING AND STORAGE
Advice on safe handling Open drum carefully as content may be under pressure.
Provide sufficient air exchange and/or exhaust in work rooms.
Do not breathe vapours/dust.
Do not smoke.
Container hazardous when empty.
Take precautionary measures against static discharges.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
Smoking, eating and drinking should be prohibited in the
application area.
For personal protection see section 8.
Dispose of rinse water in accordance with local and national
regulations.
Container may be opened only under exhaust ventilation
hood.
Conditions for safe storage BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
No smoking.
Electrical installations / working materials must comply with
the technological safety standards.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters

dompone~t~ \ •
,:, j .CAsNo, ',
0 valuet~pe,,,, , Control ··•· Basis'
I 1' -II
•(Forfhbf, parameters r
I
I exposure} '
.,Permissible . ,,
,,,',, .
,. I " : ' '
', ,,concentration•,..
ACETONE 67-64-1 TWA 500 ppm ACGIH
STEL 750 ppm ACGIH
REL 250 ppm NIOSH/GUID
590 mg/m3 E
PEL 1,000 ppm OSHA_TRA
2,400 mq/m3 NS
TWA 250 ppm ACGIHLIS p
STEL 500 ppm ACGIHLIS p
TWA 750 ppm Z1A
1,800 mq/m3
STEL 1,000 ppm Z1A
Page 19 of 326
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Version: 1.0
PYC16
2,400 mg/m3
METHANOL 67-56-1 TWA 200 ppm ACGIH
STEL 250 ppm ACGIH
260 mq/m3 E
STEL 250 ppm NIOSH/GUID
325 mq/m3 E
PEL 200 ppm OSHA_TRA
260 mg/m3 NS
TWA 200 ppm TN OEL
260 mg/m3
STEL 250 ppm TN OEL
325 mq/m3
XYLENE 1330-20-7 TWA 100 ppm ACGIH
STEL 150 oom ACGIH
435 mg/m3 NS
435 mq/m3 E
655 mq/m3 E
ETHYL BENZENE 100-41-4 TWA 20 ppm ACGIH
435 mg/m3 E
545 mq/m3 E
435 mq/m3 NS
CARBON DIOXIDE 124-38-9 TWA 5,000 oom ACGIH
STEL 30,000 ppm ACGIH
REL 5,000 ppm NIOSH/GUID
9,000 mg/m3 E
STEL 30,000 ppm NIOSH/GUID
54,000 mq/m3 E
9,000 mq/m3 NS
Biological occupational exposure limits
ACETONE 67-64-1 acetone Urine Samplin 50 mg/I

g time:
End of
shift.
Remarks: Nons ecific
METHANOL 67-56-1 methanol Urine Samplin 15 mg/I
g time:
End of
shift.
Remarks:
XYLENE
Page 20 of 326
Page:9

SAFETY DATA SHEET
SDS Number: R0328421
PYC16
ric acids in urine g time:

End of
shift.
ETHYL BENZENE 100-41-4 Sum of Creatinine Samplin 0.15 g/g ACGIH
mandelic in urine g time: BEi
acid and End of
phenylglyox shift.
ylic acid
Remarks: Nonspecific
Engineering measures Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below exposure guidelines (if
applicable) or below levels that cause known, suspected or
apparent adverse effects.
Personal protective equipment

Respiratory protection In the case of vapour formation use a respirator with an
approved filter.
In the case of dust or aerosol formation use respirator with an
approved filter.
A NIOSH-approved air-purifying respirator with an appropriate

cartridge and/or filter may be permissible under certain
circumstances where airborne concentrations are expected to
exceed exposure limits (if applicable) or if overexposure has
otherwise been determined. Protection provided by air-
purifying respirators is limited. Use a positive pressure, air-
supplied respirator if there is any potential for uncontrolled
release, exposure levels are not known or any other
circumstances where an air-purifying respirator may not
provide adequate protection.
Hand protection
Remarks The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection Wear chemical splash goggles when there is the potential for
exposure of the eyes to liquid, vapor or mist.
Skin and body protection Wear as appropriate:

impervious clothing
Safety shoes
Flame-resistant clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Discard gloves that show tears, pinholes, or signs of wear.
Wear resistant gloves (consult your safety equipment
supplier).
Hygiene measures Wash hands before breaks and at the end of workday.
When using do not eat or drink.
When using do not smoke.
Page 21
9 / 22of 326
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Version: 1.0
PYC16
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state aerosol
Odour No data available
Odour Threshold No data available
pH No data available
No data available
Boiling point/boiling range 133 °F / 56 °C

(1,013.232 hPa)
Calculated Phase Transition Liquid/Gas
Flash point -4 °F / -20 °C
Evaporation rate No data available
Flammability (solid, gas)
No data available
No data available
Flammability (liquids) Static Accumulating liquid
Flammability (liquids)
Flammability (liquids)
Upper explosion limit 36 o/o(V)
Calculated Explosive Limit
Lower explosion limit 1 o/o(V)
Vapour pressure 307.9692 hPa (25 °C)
Calculated Vapor Pressure
Relative vapour density No data available
Relative density No data available
Density 0.8132 g/cm3 (15.56 °C)
Solubility(ies)
Water solubility No data available
Solubility in other solvents No data available
Partition coefficient: n- No data available

octanol/water
Thermal decomposition No data available
Page 22 of 326
Page: 11

SAFETY DATA SHEET
PYC16
Viscosity
Viscosity, kinematic No data available
Heat of combustion Estimated 30.0 kJ/g
SECTION 10. STABILITY AND REACTIVITY
Reactivity No decomposition if stored and applied as directed.
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous Vapours may form explosive mixture with air.

reactions
Conditions to avoid Heat, flames and sparks.
excessive heat
Incompatible materials Acids

alkalis
aluminum
Amines
Ammonia
halogens
Lead
peroxides
Reducing agents
sodium
strong bases
Strong oxidizing agents
Zinc
Peroxides
Hazardous decomposition
products carbon dioxide and carbon monoxide
formaldehyde-like
Hydrocarbons
SECTION 11. TOXICOLOGICAL INFORMATION
Information on likely routes of Inhalation

exposure Skin contact
Eye Contact
Ingestion
Page 23 of 326
11/ 22
Page: 12

Pyroil™ CARS & THROTTLE BODY CLEANER
Version: 1.0
PYC16
Acute toxicity
Harmful if swallowed, in contact with skin or if inhaled
Components:
ACETONE:
Acute oral toxicity LO 50 (Rat, female): 5,800 mg/kg
Acute inhalation toxicity LC 50 (Rat, female): 76 mg/I

Exposure time: 4 h
Acute dermal toxicity LO 50 (Rabbit): > 7,426 mg/kg
METHANOL:
Acute oral toxicity LO LO (Human): 300 mg/kg
Assessment: The component/mixture is classified as acute
oral toxicity, category 3.
Acute inhalation toxicity LC 50 (Rat): 64000 ppm

Exposure time: 4 h

inhalation toxicity, category 3.
Remarks: Slightly toxic by inhalation
Acute dermal toxicity LO 50 (Rabbit): 12,800 mg/kg

dermal toxicity, category 3.
XYLENE:
Acute oral toxicity LO 50 (Rat): 3,523 - 8,600 mg/kg

Exposure time: 4 h
Test atmosphere: vapour
ETHYL BENZENE:
Acute oral toxicity LO 50 (Rat): ca. 3,500 mg/kg
Acute inhalation toxicity LC50 (Rat): 4000 ppm

Exposure time: 4 h
Skin corrosion/irritation
Product:
Remarks: May cause skin irritation and/or dermatitis.
Result: Repeated exposure may cause skin dryness or cracking.
Components:
I I,
Page 24 of 326
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SAFETY DATA SHEET
PYC16
ACETONE:
Result: Mildly irritating to skin
METHANOL:
Species: Rabbit
Result: Not irritating to skin
XYLENE:
Result: Irritating to skin
ETHYL BENZENE:
CARBON DIOXIDE:
Serious eye damage/eye irritation

Product:
Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin., Causes
serious eye irritation.
Components:
ACETONE:
Result: Irritating to eyes
METHANOL:
Species: Rabbit
Result: Mildly irritating to eyes
XYLENE:
ETHYL BENZENE:
Remarks: Exposure to a concentration of 5000 ppm causes intolerable irritation of the eyes
CARBON DIOXIDE:
Result: Not irritating to eyes
Respiratory or skin sensitisation

Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Components:
METHANOL:
Test Type: Maximisation Test (GPMT)
Species: Guinea pig
Assessment: Does not cause skin sensitisation.
Method: OECD Test Guideline 406
Germ cell mutagenicity

Not classified based on available information.
13/ 22
Page 25 of 326
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Version: 1.0
PYC16
Carcinogenicity
Reproductive toxicity
STOT • single exposure
Causes damage to organs (Central nervous system, Eyes).
Components:
ACETONE:
Exposure routes: Inhalation
Target Organs: Nervous system
Assessment: May cause drowsiness or dizziness.
METHANOL:
Target Organs: Central nervous system, Eyes
Assessment: The substance or mixture is classified as specific target organ toxicant, single
exposure, category 1.
XYLENE:
Assessment: May cause respiratory irritation., May cause drowsiness or dizziness.
STOT - repeated exposure

May cause damage to organs (Auditory system) through prolonged or repeated exposure.
Components:
ETHYL BENZENE:
Target Organs: Auditory system
Assessment: May cause damage to organs through prolonged or repeated exposure.
Aspiration toxicity
Product:
Components:
ACETONE:
May be harmful if swallowed and enters airways.
XYLENE:
ETHYL BENZENE:
Further information
Product:
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting., Concentrations substantially above the TLV value may cause narcotic effects.,
Solvents may degrease the skin.
Components:
METHANOL:
Remarks: Central nervous system
Page 26 of 326
Page: 15

SAFETY DATA SHEET
PYC16
ETHYL BENZENE:
Carcinogenicity:
IARC Group 2B: Possibly carcinogenic to humans
ETHYL BENZENE 100-41-4
OSHA No component of this product present at levels greater than or

equal to O.1% is identified as a carcinogen or potential
carcinogen by OSHA
NTP No component of this product present at levels greater than or

equal to 0.1 % is identified as a known or anticipated carcinogen
by NTP.
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
Components:
ACETONE:
Toxicity to fish LC 50 (Rainbow trout,donaldson trout (Oncorhynchus
mykiss)): 4,740 - 6,330 mg/I
Exposure time: 96 h
Test Type: static test
LC 50 (Fathead minnow (Pimephales promelas)): 8,733 -

9,482 mg/I
Exposure time: 96 h
Test Type: flow-through test
Toxicity to algae NOEC (Microcystis aeruginosa): 530 mg/I

Exposure time: 8 d
Toxicity to daphnia and other NOEC (Daphnia magna (Water flea)): 2,112 mg/I
aquatic invertebrates Exposure time: 28 d
(Chronic toxicity) Test Type: flow-through test
METHANOL:
mykiss)): 18,000 - 20,000 mg/I
Exposure time: 96 h
Toxicity to daphnia and other EC 50 (Water flea (Daphnia magna)): > 10,000 mg/I
aquatic invertebrates Exposure time: 48 h
15 /~2
Page 27 of 326
Page: 16

Pyroil™ CARS & THROTTLE BODY CLEANER Version: 1.0
PYC16
XYLENE:
Toxicity to fish LC 50 (Fathead minnow (Pimephales promelas)): 23.53 -
29.97 mg/I
Exposure time: 96 h
Toxicity to daphnia and other LC 50 (Water flea (Daphnia magna)): > 100- < 1,000 mg/I
ETHYL BENZENE:
Toxicity to fish LC 50 (Fathead minnow (Pimephales promelas)): 9.1 - 15.6
mg/I
Exposure time: 96 h
LC 50 (Rainbow trout,donaldson trout (Oncorhynchus

mykiss)): 4.2 mg/I
Exposure time: 96 h
Test Type: Renewal
Toxicity to daphnia and other EC 50 (Water flea (Daphnia magna)): 1.37 - 4.4 mg/I
Toxicity to algae (Pseudokirchneriella subcapitata (green algae)): 3.6 mg/I

End point: EC 50
Exposure time: 96 h
Test Type: Growth inhibition
Persistence and degradability

Components:
ACETONE:
Biodegradability Result: Readily biodegradable
Biodegradation: 90.9 %
Exposure time: 28 d
Method: OECD Test Guideline 301 B
METHANOL:
Biodegradability Biodegradation: 99 %
Exposure time: 28 d
Method: OECD Test Guideline 301 D
XYLENE:
Physico-chemical Remarks: The product evaporates readily.
re movability
ETHYL BENZENE:
Biodegradation: 70 - 80 %
Exposure time: 28 d
Page 28 of 326
Page: 17

SAFETY DATA SHEET
PYC16
Components:
ACETONE:
Partition coefficient: n- log Pow: -0.24
octanol/water
METHANOL:
Bioaccumulation Species: Green algae (Chiarella fusca vacuolata)
Bioconcentration factor (BCF): 28,400
Exposure time: 24 h
Concentration: 0.05 mg/I
Method: Static

octanol/water
XYLENE:
Partition coefficient: n- log Pow: 3.16
octanol/water
ETHYL BENZENE:
octanol/water
Mobility in soil
Components:
No data available
Other adverse effects
No data available
Product:
Additional ecological An environmental hazard cannot be excluded in the event of
information unprofessional handling or disposal., Harmful to aquatic life.
Components:
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
General advice The product should not be allowed to enter drains, water
courses or the soil.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Send to a licensed waste management company.
Dispose of in accordance with all applicable local, state and

federal regulations.
Contaminated packaging Empty remaining contents.

Empty containers should be taken to an approved waste
Page 29 of 326
17 / 22
Page: 18

Version: 1.0
PYC16
handling site for recycling or disposal.

Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
International transport regulations

REGULATION
ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE
CLASS HAZARDS GROUP POLLUTANT/
LTD. QTY.
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARD
OUS MATERIALS AND
WASTES
UN 1950 ORM-D, CONSUMER 2
: COMMODITY
I
INTERNATIONAL AIR TRANSPORT ASSOCIATION - PASSENGER
I UN 1950 ORM-D, CONSUMER
COMMODITY
2.1
INTERNATIONAL AIR TRANSPORT ASSOCIATION - CARGO

UNI 1950 . ORM-D, CONSUMER 2.1
COMMODITY
INTERNATIONAL MARITIME DANGEROUS GOODS

I UN 1950 AEROSOLS 2.1
TRANSPORT CANADA - INLAND WATERWAYS

TRANSPORT CANADA - RAIL

TRANSPORT CANADA - ROAD

IUN 1950 AEROSOLS 2.1 LIMITED
QUANTITY
U.S. DOT - INLAND WATERWAYS

Aerosols, flammable ORM
U.S. DOT· RAIL

I Aerosols, flammable ORM
Page 30 of 326
Page: 19

PYC16
U.S. DOT - ROAD

I AERO SOLES ORM
*ORM =ORM-D, CBL =COMBUSTIBLE LIQUID
IMarine pollutant
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment.
SECTION 15. REGULATORY INFORMATION
EPCRA- Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
XYLENE 1330-20-7 100 496.985781
SARA 311/312 Hazards Acute Health Hazard

Fire Hazard
Chronic Health Hazard
SARA 313 Component(s)

METHANOL 67-56-1 22.0_7%
XYLENE 1330-20-7 20.12 %
ETHYL BENZENE 100-41-4 6.03 %
Pennsylvania Right To Know

ACETONE 67-64-1 50.00 - 70.00 %
METHANOL 67-56-1 20.00 - 30.00 %
XYLENE 1330-20-7 20.00 - 30.00 %
ETHYL BENZENE 100-41-4 5.00 - 10.00 %
CARBON DIOXIDE 124-38-9 5.00 - 10.00 %
New Jersey Right To Know

ACETONE 67-64-1 50.00 - 70.00 %
METHANOL 67-56-1 20.00 - 30.00 %
19 / 22
Page 31 of 326
Page:20

PYC16
XYLENE 1330-20-7 20.00 - 30.00 %
ETHYL BENZENE 100-41-4 5.00 - 10.00 %
CARBON DIOXIDE 124-38-9 5.00 - 10.00 %
California Prop 65 WARNING! This product contains a chemical known to the

State of California to cause cancer.
ETHYL BENZENE 100-41-4
BENZENE 71-43-2
WARNING: This product contains a chemical known to the

State of California to cause birth defects or other reproductive
harm.
METHANOL 67-56-1
TOLUENE 108-88-3
BENZENE 71-43-2
The components of this product are reported in the following inventories:

TSCA On TSCA Inventory
DSL All components of this product are on the Canadian DSL.
AUSTR On the inventory, or in compliance with the inventory
NZIOC On the inventory, or in compliance with the inventory
ENCS On the inventory, or in compliance with the inventory
KECL On the inventory, or in compliance with the inventory
PICCS On the inventory, or in compliance with the inventory
IECSC On the inventory, or in compliance with the inventory
Inventories
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL
(Japan), KECI (Korea), NZloC (New Zealand), PICCS (Philippines), TSCA (USA)
Page 32 of 326
Page:21

SAFETY DATA SHEET
PYC16
SECTION 16. OTHER INFORMATION
Further information
NFPA: HMIS Ill:

Flammability
2*
.c
"iii
a.,
4
I
0 = not significant, 1 =Slight,

Special hazard. 2 = Moderate, 3 = High
4 = Extreme, • = Chronic
NFPA Flammable and Combustible Liquids Classification

Not applicable
Full text of H-Statements referred to under sections 2 and 3.

H225 Highly flammable liquid and vapor.
H226 Flammable liquid and vapor.
H280 Contains gas under pressure; may explode if heated.
H301 Toxic if swallowed.
H304 May be fatal if swallowed and enters airways.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H331 Toxic if inhaled.
H332 Harmful if inhaled.
H335 May cause respiratory irritation.
H336 May cause drowsiness or dizziness.
H370 Causes damage to organs.
H373 May cause damage to organs through prolonged or repeated exposure.
Sources of key data used to compile the Safety Data Sheet

Ashland internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for labelling
(GHS) and transport.
The information accumulated herein is believed to be accurate but is not warranted to be whether
the
originating with the company or not. Recipients are advised to confirm in advance of need that
Page 33
21 / of
22 326
Page:22

Pyroil™ CARS & THROTTLE BODY CLEANER
Version: 1.0
PYC16
information is current, applicable, and suitable to their circum

stances. This SOS has been prepared by
Ashland's Environmental Health and Safety Department
(1-800-325-3751 ).
List of abbreviations and acronyms that could be, but not

necessarily are, used in this safety data
sheet:
ACGIH : American Conference of Industrial Hygienists
BEi : Biological Exposure Index
CAS : Chemical Abstracts Service (Division of the Americ
an Chemical Society).
CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
FG : Food grade
GHS : Globally Harmonized System of Classification and
Labeling of Chemicals.
H-statement : Hazard Statement
IATA: International Air Transport Association.
IATA-DGR : Dangerous Goods Regulation by the "International
Air Transport Association" (IATA).
ICAO : International Civil Aviation Organization
ICAO-TI (ICAO) : Technical Instructions by the "International
Civil Aviation Organization"
IMDG : International Maritime Code for Dangerous Goods
ISO : International Organization for Standardization
logPow : octanol-water partition coefficient
LCxx: Lethal Concentration, for xx percent of test popula
tion
LDxx : Lethal Dose, for xx percent of test population.
ICxx : Inhibitory Concentration for xx of a substance
Ecxx : Effective Concentration of xx
N.O.S.: Not Otherwise Specified
OECD : Organization for Economic Co-operation and Develo
pment
OEL : Occupational Exposure Limit
P-Statement : Precautionary Statement
PBT : Persistent , Bioaccumulative and Toxic
PPE : Personal Protective Equipment
STEL : Short-term exposure limit
STOT : Specific Target Organ Toxicity
TL V : Threshold Limit Value
TWA: Time-weighted average
vPvB : Very Persistent and Very Bioaccumulative
WEL : Workplace Exposure Level
CERCLA: Comprehensive Environmental Response, Compe

nsation, and Liability Act
DOT : Department of Transportation
FIFRA: Federal Insecticide, Fungicide, and Rodenticide
Act
HMIRC: Hazardous Materials Information Review Comm
ission
HMIS : Hazardous Materials Identification System
NFPA: National Fire Protection Association
NIOSH : National Institute for Occupational Safety and Health
OSHA : Occupational Safety and Health Administration
PMRA : Health Canada Pest Management Regulatory Agenc
y
RTK : Right to Know
WHMIS: Workplace Hazardous Materials Information System
Page 34 of 326
Based on: GHS (rev 5)(2013)
Hazardous Products Regulations (HPR)
- Canada
Date of issue/ Date of revision 05/22/2017
Date of previous issue 11/05/2014
Version 2.0
SAFETY DATA SHEET
DEF Ultrapure Urea Sol 32.5%
I Section 1. Identification
Product identifier DEF Ultrapure Urea Sol 32.5%
Product type Liquid
Product code PA516U
Uses
Area of application Industrial applications, Professional applications
Supplier
Supplier's details Yara North America, Inc.
Address
Street 100 North Tampa Street, Suite 3200
Postal code 33602
City TAMPA
Country United States
Telephone number +1 813 222 5700

Fax no. +18138755735
e-mail address of person yna-hesq@yara.com
responsible for this SDS
Emergency telephone number US: Chemtrec 24-hours Emergency Response: 1-800-424-
(with hours of operation) 9300
Canada: 24 Hour Emergency Service, (Canutec 613-996-
6666)
National advisory body/Poison Center

Name Poisons and Drug Information Service
Telephone number +1 403 944 1414, (800) 332 1414 (Alberta only)
I Section 2. Hazards identification

Classification and labelling have been performed following the guidelines and recommendation
of GHS and the intended use.
Classification of the Not classified.

substance or mixture
GHS label elements

Signal word No signal word.
Hazard statements Not applicable.
Precautionary statements
Page 35 of 326
DEF Ultrapure Urea Sol 32.5% I
I Section 3. Composition/information on ingredients

Substance/mixture Mixture
There are no ingredients present which, within the current knowledge of the
supplier and in the
concentrations applicable, are classified as hazardous to health or the environm
ent, are PBTs,
vPvBs or Substances of equivalent concern, or have been assigned a workplac
e exposure limit
and hence require reporting in this section.
Occupational exposure limits, if available, are listed in Section 8.
Remark Aqueous urea solution with a content of 32,5% w/w urea

(CAS# 57-13-6).
ISection 4. First aid measures

Description of necessary first aid measures
Eye contact Rinse with plenty of running water. Check for and remove any
contact lenses. Get medical attention if irritation occurs.
Inhalation Avoid inhalation of vapor, spray or mist. If inhaled, remove to
fresh air. Get medical attention if you feel unwell.
Skin contact Wash with soap and water. Get medical attention if irritation
develops.
Ingestion Wash out mouth with water. If material has been swallowed
and the exposed person is conscious, give small quantities of
water to drink. Get medical attention if adverse health effects
persist or are severe.
Most important symptoms/effects, acute and delayed
Potential acute health effects
Eye contact No known significant effects or critical hazards.
Inhalation Exposure to decomposition products may cause a health
hazard. Serious effects may be delayed following exposure.
Skin contact No known significant effects or critical hazards.
Ingestion No known significant effects or critical hazards.
Over-exposure signs/symptoms
Eye contact No specific data.
Inhalation No specific data.
Skin contact No specific data.
Ingestion No specific data.
Indication of immediate medical attention and special treatment needed, if

necessary
Notes to physician Treat symptomatically. Contact poison treatment specialist
immediately if large quantities have been ingested or inhaled.
In case of inhalation of decomposition products in a fire,
symptoms may be delayed. The exposed person may need to
be kept under medical surveillance for 48 hours.
Specific treatments No specific treatment.
Protection of first-aiders No action shall be taken involving any personal risk or without
I Date of issue: 05/22/2017 Page:2/121
Page 36 of 326
suitable training.
See toxicological information (section 11)
I Section 5. Firefighting measures

Extinguishing media
Suitable extinguishing media Use an extinguishing agent suitable for the surrounding fire.
Unsuitable extinguishing None identified.
media
Specific hazards arising from In a fire or if heated, a pressure increase will occur and the
the chemical container may burst.
Hazardous thermal Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
ammonia
Avoid breathing dusts, vapors or fumes from burning
materials.
In case of inhalation of decomposition products in a fire,
symptoms may be delayed.
Special protective actions for Promptly isolate the scene by removing all persons from the
fire-fighters vicinity of the incident if there is a fire. No action shall be taken
involving any personal risk or without suitable training.
Special protective equipment Fire-fighters should wear appropriate protective equipment
for fire-fighters and self-contained breathing apparatus (SCBA) with a full
face-piece operated in positive pressure mode.
Remark None.
ISection 6. Accidental release measures

Personal precautions, protective equipment and emergency procedures
For non-emergency personnel No action shall be taken involving any personal risk or without
suitable training.Evacuate surrounding areas.Keep
unnecessary and unprotected personnel from entering.Do not
touch or walk through spilled material. Put on appropriate
personal protective equipment.
For emergency responders If specialized clothing is required to deal with the spillage, take
note of any information in Section 8 on suitable and unsuitable
materials. See also the information in "For non-emergency
personnel".
- Environmental precautions Avoid dispersal of spilled material and runoff and contact with
soil, waterways, drains and sewers. Inform the relevant
authorities if the product has caused environmental pollution
(sewers, waterways, soil or air).
Methods and material for containment and cleaning up

Small spill Stop leak if without risk. Move containers from spill area. Dilute
with water and mop up if water-soluble. Alternatively, or if
water-insoluble, absorb with an inert dry material and place in
an appropriate waste disposal container. Dispose of via a
Page 37 of 326
licensed waste disposal contractor.

Large spill Stop leak if without risk. Move containers from spill area.
Prevent entry into sewers, water courses, basements or
confined areas. Wash spillages into an effluent treatment plant
or proceed as follows. Contain and collect spillage with non-
combustible, absorbent material e.g. sand, earth, vermiculite or
diatomaceous earth and place in container for disposal
according to local regulations (see section 13). Dispose of via
a licensed waste disposal contractor. Note: see section 1 for
emergency contact information and section 13 for waste
disposal.
I Section 7. Handling and storage

Precautions for safe handling
Protective measures Put on appropriate personal protective equipment (see
Section 8).
Advice on general Eating, drinking and smoking should be prohibited in areas

occupational hygiene where this material is handled, stored and processed.
Workers should wash hands and face before eating, drinking
and smoking. Remove contaminated clothing and protective
equipment before entering eating areas. See also Section 8
for additional information on hygiene measures.
Conditions for safe storage, Store in accordance with local regulations. Store in original
including any incompatibilities container protected from direct sunlight in a dry, cool and well-
ventilated area, away from incompatible materials (see
section 10) and food and drink.Keep container tightly closed
and sealed until ready for use.Containers that have been
opened must be carefully resealed and kept upright to prevent
leakage. Do not store in unlabeled containers.
Use appropriate containment to avoid environmental
contamination.Sund storage facilities to prevent soil and water
pollution in the event of spillage.
Section 8. Exposure controls/personal protection

Control parameters
Occupational exposure limits None.
Appropriate engineering Good general ventilation should be sufficient to control worker

controls exposure to airborne contaminants.
Environmental exposure Emissions from ventilation or work process equipment should
controls be checked to ensure they comply with the requirements of
environmental protection legislation. In some cases, fume
scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to
acceptable levels.
Individual protection measures

Hygiene measures Wash hands, forearms and face thoroughly after handling
chemical products, before eating, smoking and using the
[ Date of issue : 05/22/2017 Page:4/12I
Page 38 of 326
lavatory and at the end of the working period. Wash

contaminated clothing before reusing. A washing facility or
water for eye and skin cleaning purposes should be present.
Eye/face protection Safety eyewear complying with an approved standard should
be used when a risk assessment indicates this is necessary to
avoid exposure to liquid splashes, mists, gases or dusts.
Skin protection
Hand protection Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this is
necessary. For general applications, we recommend gloves
with a thickness typically greater than 0.35 mm. It should be
emphasised that glove thickness is not necessarily a good
predictor of glove resistance to a specific chemical, as the
permeation efficiency of the glove will be dependent on the
exact composition of the glove material.
Body protection Personal protective equipment for the body should be selected
based on the task being performed and the risks involved.
Other skin protection Appropriate footwear and any additional skin protection
measures should be selected based on the task being
performed and the risks involved and should be approved by a
-I
specialist before handling this product.
Respiratory protection In case of inadequate ventilation wear respiratory protection.
(Pictograms)
~
\ Section 9. Physical and chemical properties
Appearance
Physical state Liquid
Color Colorless.
Odor slight, ammoniacal
Odor threshold Not determined.
pH 9 - 10
Melting/freezing point -11.5°C
Boiling/condensation point 100 °C

(100°C)
Sublimation temperature Not determined.

Flash point Not applicable
Evaporation rate Not determined.

Flammability (solid, gas) Non-flammable.
Lower and upper explosive Lower: Not determined.

(flammable) limits Upper: Not determined.
Vapor pressure Not determined.
Density 1.09 g/cm3
I Date of issue : 05/22/2017 Page:5/121
Page 39 of 326
DEFUltrapure Urea Sol 32.5% j
Relative density Not determined.

Solubility Not determined.
Solubility in water > 100 g/1
Partition coefficient: n- Not determined.
octanol/water
Auto-ignition temperature Not determined.
Decomposition temperature Not determined.
Viscosity Dynamic: 1.4 mPa.s @ 20 °C (20 °C)
Kinematic: Not determined.

Explosive properties None.
Oxidizing properties None.
I Section 10. Stability and reactivity

Reactivity No specific test data related to reactivity available for this
product or its ingredients.
Chemical stability The product is stable.
Possibility of hazardous Under normal conditions of storage and use, hazardous
reactions reactions will not occur.
Conditions to avoid Avoid contamination by any source including metals, dust and
organic materials.
Incompatible materials Urea reacts with calcium hypochlorite or sodium hypochlorite
to form the explosive nitrogen trichloride.
Remark Reactive or incompatible with the following materials:
Oxidizing agents
acids
alkalis
Nitrites and nitrates
Hazardous decomposition Under normal conditions of storage and use, hazardous
products decomposition products should not be produced.
I Section 11. Toxicological information

Information on toxicological effects
Acute toxicity
Conclusion/Summary No known significant effects or critical hazards.

Irritation/Corrosion
Conclusion/Summary
Skin No known significant effects or critical hazards.
Eyes No known significant effects or critical hazards.
I Date of issue : 05/22/2017 Page:6/12 j
Page 40 of 326
Respiratory No known significant effects or critical hazards.
Sensitization
Conclusion/Summary
Skin No known significant effects or critical hazards.
Respiratory No known significant effects or critical hazards.
Mutagenicity
Carcinogenicity
Teratogenicity
Specific target organ toxicity (single exposure)

No known significant effects or critical hazards.
Specific target organ toxicity (repeated exposure)

Aspiration hazard
Information on likely routes of Not available.

exposure

Eye contact No known significant effects or critical hazards.
Inhalation Exposure to decomposition products may cause a health
hazard. Serious effects may be delayed following exposure.
Skin contact No known significant effects or critical hazards.
Ingestion No known significant effects or critical hazards.
Symptoms related to the physical, chemical and toxicological characteristics

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Date of issue : 05/22/2017 Page:7/121
Page 41 of 326
Short term exposure

Potential immediate effects Not available.
Potential delayed effects Not available.
Long term exposure

Potential immediate effects Not available.
Potential delayed effects Not available.
Potential chronic health effects
General No known significant effects or critical hazards.

Carcinogenicity No known significant effects or critical hazards.
Mutagenicity No known significant effects or critical hazards.
Teratogenicity No known significant effects or critical hazards.
Developmental effects No known significant effects or critical hazards.
Fertility effects No known significant effects or critical hazards.
Over-exposure signs/symptoms
Numerical measures of toxicity

Acute toxicity estimates
Not available.
I Section 12. Ecological information

Toxicity
Mobility in soil
Soil/water partition Not available.
coefficient (KOC)
Mobility This product may move with surface or groundwater flows
because its water solubility is: high
Other adverse effects No known significant effects or critical hazards.
Page 42 of 326
DEF Ultrapure Urea Sol 32.5% /
I Section 13. Disposal considerations

Product
Methods of disposal The generation of waste should be avoided or minimized
wherever possible. Disposal of this product, solutions and
any by-products should at all times comply with the
requirements of environmental protection and waste
disposal legislation and any regional local authority
requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste
should not be disposed of untreated to the sewer unless
fully compliant with the requirements of all authorities with
jurisdiction. Waste packaging should be recycled.
Incineration or landfill should only be considered when
recycling is not feasible. This material and its container
must be disposed of in a safe way. Empty containers or
liners may retain some product residues. Avoid dispersal
of spilled material and runoff and contact with soil,
waterways, drains and sewers.
I Section 14. Transport information
Regulation: UN Class
14.1 UN number Not regulated.
14.2 UN proper shipping name Not applicable.
14.3 Transport hazard class(es) Not applicable.
14.4 Packing group Not applicable.

14.5 Environmental hazards No.
Additional information
Environmental hazards : No.
Regulation: IMDG

Marine (!Ollutant : Not available.
Regulation: IATA
/ Date of issue: 05/22/2017 Page:9/12 /
Page 43 of 326

Marine [!Ollutant : No.
Regulation: DOT Classification


Marine [!Ollutant : Not available.
Regulation: TDG Class


Not applicable.
Environmental hazards : No.
14.6 S[!ecial [!recautions for Transport within user's premises: Ensure that persons
Y..§fil transporting the product know what to do in the event of
an accident or spillage.
IMSBC Not applicable.
Trans[!ort in bulk according to Annex II of MARPOL and the IBC Code

Proper shipping name Urea solution
Ship type 3
Pollution category z
I Section 15. Regulatory information

Canadian lists
Canadian NPRI None of the components are listed.

CEPA Toxic substances None of the components are listed.
Inventory list
New Zealand Inventory of Chemicals (NZloC): All components are listed or exempted.
Korea inventory: All components are listed or exempted.
Page 44 of 326
DEF Ultrapure Urea Sol 32.5% j
China inventory (IECSC): All components are listed or exempted.

Australia inventory (AICS): All components are listed or exempted.
Canada inventory (DSL and NDSL): All components are listed or exempted.
Taiwan Chemical Substances Inventory (TCSI): All components are listed or exempted.
Taiwan Chemical Substances Inventory (TCSI): All components are listed or exempted.
United States inventory (TSCA 8b): All components are listed or exempted.
EC INVENTORY (EINECS/ELINCS): All components are listed or exempted.
Canada: All components are listed or exempted.
Section 16. Other information
Key to abbreviations ADN/ADNR = European Provisions concerning the International Carriage of

Dangerous Goods by Inland Waterway
ADR = The European Agreement concerning the International Carriage of
Dangerous Goods by Road
ATE= Acute Toxicity Estimate
BCF = Bioconcentration Factor
bw = Body weight
GHS = Globally Harmonized System of Classification and Labelling of
Chemicals
IATA = International Air Transport Association
IBC = Intermediate Bulk Container
IMDG = International Maritime Dangerous Goods
LogPow = logarithm of the octanol/water partition coefficient
MARPOL = International Convention for the Prevention of Pollution From
Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution)
NOHSC - National Occupational Health and Safety Commission
RID= The Regulations concerning the International Carriage of Dangerous
Goods by Rail
SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons
UN= United Nations
Procedure used to derive the classification

Classification Justification
Not classified. Calculation method
References EU REACH IUCLID5 CSR.

National Institute for Occupational Safety and Health, U.S.
Dept. of Health, Education, and Welfare, Reports and
Memoranda Registry of Toxic Effects of Chemical
Substances.
Sphera Solutions Inc., 4777 Levy Street, St Laurent, Quebec
HAR 2P9, Canada.
History
Date of printing 05/23/2017
Date of issue/Date of revision 05/22/2017
Date of previous issue 11/05/2014
Version 2.0
Prepared by Yara Chemical Compliance YCC .
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither
the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the
accuracy or completeness of the information contained herein. Final determination of
Date of issue : 05/22/2017 Page:11/121
Page 45 of 326
suitability of any material is the sole responsibility of the user.

All materials may present
unknown hazards and should be used with caution. Althoug
h certain hazards are described
herein, we cannot guarantee that these are the only hazards
that exist.
j Date of issue: 05/22/2017

Page:12/121
Page 46 of 326
POWER SERVICEPRODUCTS,INC. POWERftl'
SAFETYDATA SHEET /ERVICEIU®
I SECTION 1 - IDENTIFICATION
PRODUCT NAME: DIESEL 9•1 •1
Unless otherwise noted, all sections of this MSDS apply to each of the following products and
part numbers.
PART NUMBERS:
8016-09, 8025-09, 8025-12, 8080-06, 8050-02, 8055-01, 8260-01 18016-09, 18025-12, 18080-
06
COMPANY IDENTIFICATION:
Power Service Products, Inc.

P.O. Box.1089
Weatherford, TX 76086
Email: psp@powerservice.com
Phone: 800/643-9089 or 817-599-9486
Fax: 817-599-4893
Emergency Phone Number: Within USA 1-800-424-9300. Outside USA 001-703-527-3887

(Call Collect).
RECOMMENDED USES: Diesel fuel additive
I SECTION 2 - HAZARD(S) IDENTIFICATION
CLASSIFICATION UNDER 29 CFR 1910.1200(d)
(NC=product does not meet classification criteria)
Health Hazard Criteria Category

Acute Toxicity, Oral: NC
Acute Toxicity, Dermal: NC
Acute Toxicity, Inhalation, Vapors: NC
Skin Corrosion/Irritation: 2
Serious Eye Damage/Eye Irritation: 2
Respiratory Sensitization: NC
Skin Sensitization: NC
Gerrn Cell Mutagenicity: NC
Revised:January12,2017
Supersedes:September28, 2015
POWERSERVICEDIESEL 9• 1• 1 Page1of10
Page 47 of 326
Health Hazard Criteria Category
Carcinogenicity: NC
Reproductive Toxicity: NC
Specific Target Organ Toxicity, Single 3
Exposure:
Specific Target Organ Toxicity, Repeated NC
or ProlonQed Exposure:
Aspiration Hazard: 1
Physical Properties Criteria Category

Explosives: NC
Flammable Gases: NC
Flammable Aerosols: NC
Oxidizing Gases: NC
Gases Under Pressure: NC
Flammable Liquids: 3
Flammable Solids: NC
Self-Reactive Chemicals: NC
Pyrophoric Liquids: NC
Pyrophoric Solids: NC
Self-HeatinQ Chemicals: NC
Chemicals Which, in Contact with Water, NC
Emit Flammable Gases:
Oxidizing Liquids: NC
Oxidizing Solids: NC
Organic Peroxides: NC
Corrosive to Metals: NC
LABEL SIGNAL WORD, HAZARD STATEMENTS, SYMBOLS AND PRECAU

TIONARY
STATEMENTS UNDER 29 CFR 1910.1200(f):
Please see the Note regarding product labeling in Section 16.
Signal Word(s): Danger
Hazard Statement(s): Flammable liquid and vapor. May be fatal if swallowed

and enters
airways. Causes skin and serious eye irritation. May cause respiratory irritation.
Symbo~
Precautionary Statement(s): Keep away from sparks and open flames. No smoking.
Keep
container tightly closed. Use only non-sparking tools. Ground/Bond container and
receiving
equipment Use explosion-proof pumps when pumping. Take precautionary measure
s against
static discharge. Avoid breathing vapors. Use only outdoors or in a well-ventilated
area. Wash
Supersedes:September28,2015
POWERSERVICEDIESEL9•1 •1
Page2 of 10
Page 48 of 326
hands thoroughly after handling. Do not eat, drink or smoke when using this product. Wear
protective gloves and eye protection. Store locked up and in cool, well ventilated place. KEEP
OUT OF REACH OF CHILDREN.
Hazards Not Otherwise Classified: None
I SECTION 3 - COMPOSITION /INFORMATION ON INGREDIENTS
The specific chemical identity and exact concentration percentage has been withheld as a
Trade Secret. Specific chemical information will be made available to health professionals in
accordance with 29 CFR 1910.1200.
INGREDIENTS yLASSIFIED AS HEAL TH HAZARDS
Common Name/Synonyms
Chemical Name CAS Number Concentration
(%)
Aliphatic hydroxy hydrocarbons Trade secret Trade secret 40 - 90
Petroleum Distillates Trade secret Trade secret 10 - 30
\ SECTION 4 - FIRST AID MEASURES
As a precaution, exposure to liquids, vapors, mists and fumes should be minimized.
EYE CONT ACT: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists, get medical advice.
SKIN CONTACT: Wash with plenty of water. Take off contaminated clothing and wash it before
reuse. If skin irritation occurs get medical advice/attention.
INHALATION: Remove person to fresh air and keep comfortable for breathing. Call a doctor.
INGESTION: If swallowed, IMMEDIATELY call a doctor. Do NOT induce vomiting.
\ SECTION 5 - FIRE AND EXPLOSION HAZARD DATA
EXTINGUISHING MEDIA: Use water fog, alcohol-resistant foam, dry chemical or carbon
dioxide (CO 2) to extinguish flames.
SPECIFIC HAZARDS: Vapors are heavier than air and may travel along the ground to a distant
ignition source and flash back. See Section 10 for Stability and Reactivity. NOTE: EMPTY
CONTAINERS CONTAIN COMBUSTIBLE VAPORS THAT CAN CAUSE FLASH FIRES OR
EXPLOSIONS. CONTAINERS ARE SINGLE-TRIP CONTAINERS AND SHOULD NOT BE
USED FOR ANY REASON AFTER BEING EMPTIED. DO NOT USE CUTTING TORCH
POWERSERVICE DIESEL 9•1•1 Page3 of 10
Page 49 of 326
EQUIPMENT OR ANY OTHER FLAME OR OTHER SOURCES OF IGNITION ON ANY EMPTY
CONTAINER.
PROTECTIVE EQUIPMENT AND PRECAUTIONS: Use standard protective equipment

including self-contained breathing apparatus (SCBA).
\ SECTION 6 -ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY

PROCEDURES: Avoid contact with spilled material. Warn or evacuate occupants in
surrounding and downwind areas. Eliminate all sources of ignition in the vicinity of the spill or
released vapor. See Section 2 for Hazards Identification. See Section 4 for First Aid Measures.
See Section 5 for Fire Fighting Information. See Section 8 for Personal Protective Equipment.
SPILL CONTAINMENT AND CLEAN-UP: Eliminate potential sources of ignition. Stop leak if it
can be done without risk. Dike and contain spill. Do not touch or walk through spilled material.
Prevent entry into waterways, sewer, basements or confined areas. Remove with vacuum
trucks or pump to storage/salvage vessels. Soak up residue with an absorbent such as clay,
sand or other suitable material and dispose of properly. A vapor suppressing foam may be used
to reduce vapors. Local, state and federal laws and/or regulations may apply to releases and
disposal of this material, as well as those materials and items employed in the clean-up
releases. The user/responder will need to determine which local, state and federal laws and/or
regulations are applicable. The National Response Center can be reached at 1-800-424-8802.
I SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS FOR SAFE HANDLING: Avoid contact with eyes and skin. Use only with
adequate ventilation. Use proper bonding and/or grounding procedures. Prevent small spills and
leakage to avoid slip hazard. Material can accumulate static charges which may cause an
electrical spark (ignition source). Keep away from ignition sources such as heat, sparks, and
flames. No smoking.
CONDITIONS FOR SAFE STORAGE: DO NOT USE OR STORE near heat, sparks, or flame.
USE AND STORE ONLY IN A WELL-VENTILATED AREA Handle containers with care. Keep
container closed when not in use. Store locked up.
STORAGE TEMPERATURE: -40°F to 100°F (-40°C to 38°C)
EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN FLAMMABLE

VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION
HAZARD DATA
POWER SERVICE DIESEL 9•1•1 Page4 of 10
Page 50 of 326
I SECTION 8 • EXPOSURE CONTROLS/ PERSONAL PROTECTION
EXPOSURE GUIDELINES:
OSHA ACGIH NIOSH

CAS# PEL TLV STEL REL STEL IDLH Note
Ethylbenzene 100-41-4 100ppm 20ppm notest. 100ppm 125ppm 800ppm(LEL) n/a
Cumene 98-82-8 50 ppm 50ppm notes! 50ppm notest. 900ppm(LEL) Skin
PetroleumDistillates n/a 500ppm notest. notest notest notest notest n/a
2-Butanol 78-92-2 150ppm 100ppm notest 100ppm 150ppm 2,000ppm n/a
N-Butanol 71-36-3 100ppm 20ppm notest notest. notest. 1,400ppm(LEL) Skin
ENGINEERING CONTROLS: The level of protection and types of controls necessary will vary
depending upon potential exposure conditions. Local exhaust ventilation is recommended to
control exposure.
PERSONAL PROTECTIVE EQUIPMENT (PPE):
Eyes and Face: Eye protection such as safety glasses or chemical goggles is
recommended if contact is likely.
Skin: If prolonged or repeated skin contact is likely, chemical/oil resistant clothing and
gloves are recommended. Wear additional protective clothing as appropriate.
Respiratory: Wear a NIOSH/MSHA approved respirator as necessary.
Specific Hygiene Measures: Always observe good personal hygiene measures, such
as washing after handling the material and before eating, drinking, and/or smoking.
Routinely wash work clothing and protective equipment to remove contaminants.
Practice good housekeeping.
NOTE: These precautions are for room temperature handling.
\ SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance Liquid, straw yellow

Odor Strong solvent
Odor Threshold Not available
pH Not applicable
Melting point/Freezing point Not available
Initial Boiling Point and BoilinQ Range 187.?°F (86.5°C)
Flash Point 74°F (TCC) 23°C
Evaporation Rate Not available
Flammability Not available
Upper/ lower Flammability or Explosive Limits Not available
POWERSERVICEDIESEL9• 1• 1 Page5 of 10
Page 51 of 326
Vapor Pressure Not available
Vapor Density Not available
Relative Density/Specific Gravity (at 60°F) 0.8400
Solubility Not available
Partition Coefficient; n-octanol / water Not available
Auto-ignition Temperature Not available
Decomposition temperature Not available
Viscosity Not available
Pour Point <-159°F (-106°C)
I SECTION 10 -STABILITY AND REACTIVITY
REACTIVITY: see Incompatible Materials below
CHEMICAL STABILITY: This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature and pressure.
CONDITIONS TO AVOID: Flames, high energy ignition sources, and elevated temperatures.
INCOMPATIBLE MATERIALS: May react with oxygen, oxidizing agents, such as; chlorates,
nitrates, peroxides, etc., amines, caustics, alkanolamines halogens, chlorine.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides, products of incomplete

combustion.
HAZARDOUS POLYMERIZATION:
Hazardous polymerization will not occur.
I SECTION 11 -TOXICOLOGICAL INFORMATION
LIKELY ROUTES OF EXPOSURE
INGESTION INHALATION SKIN CONTACT EYE CONTACT SKIN ABSORPTION

X X X X
SYMPTOMS RELATED TO PHYSICAL, CHEMICAL AND TOXICOLOGICAL

CHARACTERISTICS: Breathing of high vapor concentrations may cause dizziness, light-
headedness, headache, nausea a.nd loss of coordination. Continued inhalation may result in
unconsciousness. The vapor or fumes from this material may cause respiratory irritation.
Breathing this material at elevated concentrations causes central nervous system effects.
Central nervous system effects may include headache, dizziness, nausea, vomiting, weakness,
loss of coordination, blurred vision, drowsiness, confusion or disorientation. At extreme
exposures, central nervous system effects may include respiratory depression, tremors, or
convulsions, loss of consciousness, coma or death.
POWERSERVICE DIESEL9• 1• 1 Page6 of 10
Page 52 of 326
DELAYED AND IMMEDIATE EFFECTS AND CHRONIC EFFECTS FROM SHORT- AND
LONG-TERM EXPOSURE: Repeated skin exposure to a component of this product may cause
irritation, even a burn; may cause a more severe response on covered skin, such as under
clothing or gloves. Inhalation exposure to a component of this product has caused fetotoxicity in
the presence of maternal toxicity in animals.
NUMERICAL MEASURES OF TOXICITY

Note: the information provided below are estimates; testing of the product is not available.
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation

(ATEmixestimate) (ATEmixestimate) (ATE mixestimate)
Does not meet criteria Does not meet criteria Does not meet criteria
SENSITIZATION: No information available.
MUTAGENICITY: No information available.
CARCINOGENICITY LISTINGS - the following chemicals are listed as indicated:
Chemical List
Cumene IARC, NTP
Ethylbenzene IARC
REPODUCTIVE TOXICITY: No information available.
TERATOGENICITY/EMBRYOTOXICITY: This product contains a component of a complex

mixture (Xylenes (1330-20-7)) that has been shown to cause teratogenicity and/or
em bryotoxicity.
SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE): Respiratory tract irritation.
SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE): No information available
ASPIRATION HAZARD: Aspiration hazard identified.
I SECTION 12 - ECOLOGICAL INFORMATION
ECOTOXICITY:
This material is expected to be toxic to aquatic organisms.
PERSISTENCE AND DEGRADABILITY: No information available.
BIOACCUMULATIVE POTENTIAL: No information available.
MOBILITY IN SOIL: No information available.
OTHER ADVERSE EFFECTS: No information available.
Revised:January12, 2017
POWERSERVICE DIESEL9•1•1 Page7 of 1O
Page 53 of 326
I SECTION 13 - DISPOSAL CONSIDERATIONS
RCRA Information: Disposal of unused product may be subject to RCRA hazardous waste
regulations (40 CFR Part 261 ). Disposal of the used product may also be regulated as
hazardous waste due to resulting mixture characteristics, mixture components or product use.
Such changes to the product may result in different and/or additional hazardous waste codes.
Potential RCRA waste code based on the product as shipped: D001 IGNITABILITY.
State or local laws may impose additional regulatory requirements regarding disposal. Waste
characterizations and compliance with applicable laws are the responsibility solely of the waste
generator.
EMPTY CONTAINER WARNING: EMPTY CONTAINERS MAY CONTAIN FLAMMABLE

VAPORS AND CAN BE DANGEROUS. SEE SECTION 5 FOR FIRE AND EXPLOSION
HAZARD DATA.
I SECTION 14-TRANSPORTATION INFORMATION
The following part numbers are classified as Limited Quantities:
8016-09, 8025-09, 8025-12, 8080-06, 18016-09, 18025-12, 18080-06
The following part numbers are regulated by DOT:
8050-02, 8055-01, 8260-01
PROPER SHIPPING NAME: Flammable Liquid, N.O.S., (Aliphatic Hydroxy

Hydrocarbons)
HAZARD CLASS: 3
I.D. NUMBER: UN 1993
PACKING GROUP: Ill
PLACARDING: Flammable Liquid
Air shipment is not recommended.
I SECTION 15 - REGULATORY INFORMATION
§14(a) Consumer Product Safety Act General Certificate of Conformity
Power Service Products, Inc. certifies that this product meets the statutory and regulatory
requirements of the US Consumer Products Safety Act, the Federal Hazardous Substances Act,
and the Poison Prevention Packaging Act of 1970, as applicable. The Power Service products
are manufactured in the United States in Weatherford, Texas, unless otherwise indicated on the
product label. The product manufacture lot code is stamped on the product container. This
Certification is based upon a reasonable testing program conducted by Power Service Products,
Inc. which includes a quality control program incorporating, as necessary, confirmation of
Supersedes:September28, 2015
POWERSERVICE DIESEL9• 1• 1 Page8 of 10
Page 54 of 326
to certify compliance.
compliance by component suppliers. Third-party testing is not required
Service Product s, Inc. EHS Manager
Further details may be obtained by contacting the Power
at 1-8 00-64 3-9089.
d 29 CFR
Contents of this SOS comply with the OSHA Hazard Communication Standar
1910.1200
TSCA STATUS:
ces Control Act
All chemical substances found in this product comply with the Toxic Substan
inventory reporting requirements.
EPA SARA TITLE Ill CHEMICAL LISTINGS:
Section 302 Extremely Hazardous Substances: None
Sections 311/ 312 Hazard Class:

Acute Health Effects: Yes Sudden Release of Pressure Hazard: No
Chronic Health Effects: Yes Reactivity Hazard: No
Fire Hazard: Yes
NFPA (NATIONAL FIRE PROTECTION ASSOCIATION) RATING:

HEALTH: 2
FIRE: 3
REACTIVITY: 0
Section 313:
The following
Specific chemical information is being withheld as a Trade Secret.
Section 313 of Title Ill of the
chemicals subject to the reporting requirements of EPCRA
(40 CFR Part 372) may be
Superfund Amendments and Reauthorization Act of 1986
not exceed the specifie d upper
present in this product at a concentration that does
weight percentage.
GAS Number .Chemical Name Max%

100-41-4 Ethylbenzene 10.0
78-92-2 sec Butyl alcohol 25.0
71-36-3 n-Butyl alcohol 25.0
for components of this

State or local laws may impose additional regulatory requirements
Employ er to maintain complia nce with State and
material. It is the responsibility solely of the
Local reporting.
CA Proposition 65
WARNING: Cancer and Reproductive Harm -www.P65Warnings.ca.gov.
Ji
\ SECTION 16 - OTHER INFORMATION
DATE OF PREPARATION/ REVISION: January 12, 2017
:
RevisedJanuary12,2017
September
Supersedes: 28,2015
DIESEL
E 9•1• 1 Page 9 of 10
POWER SERVIC
Page 55 of 326
NOTE regarding product labeling: The OSHA Hazard
Communication Standard applies to
hazardous chemicals known to be present in the workp
lace. However, the labeling and
Safety Data Sheet requirements do not apply to consu
mer products when they are used
in the workplace for the purposes intended by the manuf
acturer and the use results in a
duration and frequency of exposure which is not greate
r than the range of exposures
that could reasonably be experienced by consumers
when used for the intended
purpose. Power Service Products intends for product
packaged in 1 gallon or smaller
containers to be used by consumers and has labeled
those containers as required under
the Consumer Product Safety Commission regulations.
Power Service Products intends
for product packaged in containers larger than 1 gallon
to be used in the workplace and
has labeled those products as required by the OSHA
Hazard Communication Standard.
The Consumer Product Safety Commission and OSHA
Hazard Communication Standard
labeling requirements are different and variations betwe
en the consumer and industrial
labels may occur. It is the employer's responsibility to
purchase the appropriate product
for use in the workplace.
The information contained herein is offered in good faith

and is believed to be accurate based
on the data available to us as of the date of SOS prepar
ation. The information in this document
applies to this specific product as supplied. It may not
be appropriate for this product if the
product is used in combination with other materials. The
information in this document is not
intended to constitute product peliormance information. Some
of the information presented and
conclusions drawn herein are from sources other than
direct test data on the product. No
statement shall be construed as an endorsement of any
product or process. The recommended
industrial hygiene and safe handling procedures are believ
ed to be valid in the context of the
intended use as described in product labeling. Howev
er, each user should review these
recommendations in the specific context of the intended
use and determine whether they are
appropriate. You are urged to obtain material safety data
sheets for all products you buy,
process, use or distribute, and are encouraged to advise
those who may come in contact with
such products of the information contained therein. Regul
atory requirements are subject to
change and may differ between locations. It is the buyer's/user
's responsibility to ensure that his
activities comply with all federal, state, provincial or local
laws. No warranty or guarantee is
expressed or implied with respect to this product, the accura
cy and sufficiency of the data or
recommendations herein, or the results to be obtained
from the use of this product. IN NO
EVENT SHALL POWER SERVICE PRODUCTS, INC.
BE LIABLE FOR ANY LOSS, CLAIM,
DAMAGE OR LIABILITY OF ANY KIND, WHICH MAY
ARISE FROM OR IN CONNECTION
WITH THE INFORMATION CONTAINED IN THIS
DOCUMENT OR FROM THE USE,
HANDLING OR STORAGE OF THE PRODUCT BY THE
BUYER/USER, WHETHER DIRECT,
INDIRECT, OR CONSEQUENTIAL, OR FOR ANY CLAIM
BY ANY THIRD PARTY, BEYOND
THE PURCHASE PRICE OR REPLACEMENT OF THE
PRODUCT IN CONNECTION WITH
WHICH SUCH LOSS, CLAIM, DAMAGE OR LIABILITY AROS
E.
THE FOREGOING LIMITATIONS APPLY REGARDLESS
OF THE CAUSES OR
CIRCUMSTANCES GIVING RISE TO SUCH LOSS, CLAIM
, DAMAGE OR LIABILITY, EVEN IF
SUCH LOSS, CLAIM, DAMAGE, OR LIABILITY IS BASE
D ON NEGLIGENCE OR OTHER
TORTS OR BREACH OF CONTRACT.
POWERSERVICEDIESEL9•1 •1
Page10of 10
Page 56 of 326
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29 CFR
1910.1200
Version 1.3 Revision Date: 08/24/2016 Print Date: 08/25/2016
SECTION 1. IDENTIFICATION
Product name FormulaShell SAE 30 Motor Oil
Product code 001D7230

Manufacturer or supplier's details
Manufacturer/Supplier Shell Oil Products US
PO Box 4427
Houston TX 77210-4427
USA
SOS Request (+1) 877-276-7285
Customer Service
Emergency telephone number

Spill Information 877-504-9351
Health Information 877-242-7400

Recommended use : Engine oil.
GHS Classification
Not a hazardous substance or mixture.
GHS label elements
Hazard pictograms : No Hazard Symbol required
Signal word No signal word
Hazard statements PHYSICAL HAZARDS:

Not classified as a physical hazard under GHS criteria.
HEALTH HAZARDS:
Not classified as a health hazard under GHS criteria.
ENVIRONMENTAL HAZARDS:
Not classified as an environmental hazard under GHS criteria.
Precautionary statements Prevention:

No precautionary phrases.
Response:
Storage:
Disposal:
Other hazards which do not result in classification

Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin result-
ing in disorders such as oil acne/folliculitis.
Page 57 of 326
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29
CFR
1910.1200

Used oil may contain harmful impurities.
Not classified as flammable but will burn.
The classification of this material is based on OSHA HCS

2012 criteria.
Under normal conditions of use or in a foreseeable emerg
ency, this product does not meet the
definition of a hazardous chemical when evaluated accord
ing to the OSHA Hazard Communica-
tion Standard, 29 CFR 1910.1200.
SECTION 3. COMPOSITION/INFORMATION ON INGRE

DIENTS
Chemical nature Highly refined mineral oils and additives.
The highly refined mineral oil contains <3% (w/w) DMSO
-
extract, according to IP346.
* contains one or more of the following GAS-numbers: 64 742-

53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301
-69-
9.
Polyolefin Amide Al- Not Assigned

keneamine Pol ol <3
Alka I amine Not Assi ned <3
Interchangeable low vis- Not Assigned
cosity base oil (<20,5 est 0 - 90
40°c *
SECTION 4. FIRST-AID MEASURES
General advice Not expected to be a health hazard when used under norma
l
conditions.
If inhaled No treatment necessary under normal conditions of use.

If symptoms persist, obtain medical advice.
In case of skin contact Remove contaminated clothing. Flush exposed area with
wa-
ter and follow by washing with soap if available.
If persistent irritation occurs, obtain medical attention.
In case of eye contact Flush eye with copious quantities of water.

If swallowed In general no treatment is necessary unless large quantit

ies
are swallowed, however, get medical advice.
Most important symptoms Oil acne/folliculitis signs and symptoms may include format
and effects, both acute and ion
of black pustules and spots on the skin of exposed areas.
delayed Ingestion may result in nausea, vomiting and/or diarrhoea.
Protection of first-aiders When administering first aid, ensure that you are wearing
the
Page 58 of 326
SAFETY DATA SHEET
1910.1200
appropriate personal protective equipment according to the

incident, injury and surroundings.
Immediate medical attention, Treat symptomatically.

special treatment
SECTION 5. FIRE-FIGHTING MEASURES
Suitable extinguishing media Foam, water spray or fog. Dry chemical powder, carbon diox-
ide, sand or earth may be used for small fires only.
Unsuitable extinguishing Do not use water in a jet.

media
Specific hazards during fire- Hazardous combustion products may include:

fighting A complex mixture of airborne solid and liquid particulates and
gases (smoke).
Carbon monoxide may be evolved if incomplete combustion
occurs.
Unidentified organic and inorganic compounds.
Specific extinguishing meth- Use extinguishing measures that are appropriate to local cir-
ods cumstances and the surrounding environment.
Special protective equipment Proper protective equipment including chemical resistant

for firefighters gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self-Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).
Personal precautions, protec- : Avoid contact with skin and eyes.

tive equipment and emer-
gency procedures
Environmental precautions Use appropriate containment to avoid environmental contami-

nation. Prevent from spreading or entering drains, ditches or
rivers by using sand, earth, or other appropriate barriers.
Local authorities should be advised if significant spillages

cannot be contained.
Methods and materials for Slippery when spilt. Avoid accidents, clean up immediately.
containment and cleaning up Prevent from spreading by making a barrier with sand, earth
or other containment material.
Reclaim liquid directly or in an absorbent.
Soak up residue with an absorbent such as clay, sand or other
suitable material and dispose of properly.
Page 59 of 326
SAFETY DATA SHEET
1910.1200
Additional advice For guidance on selection of personal protective equipment

see Chapter 8 of this Safety Data Sheet.
For guidance on disposal of spilled material see Chapter 13 of
this Safety Data Sheet.
Technical measures Use local exhaust ventilation if there is risk of inhalation of

vapours, mists or aerosols.
Use the information in this data sheet as input to a risk as-
sessment of local circumstances to help determine appropri-
ate controls for safe handling, storage and disposal of this
material.
Precautions for safe handling Avoid prolonged or repeated contact with skin.
Avoid inhaling vapour and/or mists.
When handling product in drums, safety footwear should be
worn and proper handling equipment should be used.
Properly dispose of any contaminated rags or cleaning mate-
rials in order to prevent fires.
Avoidance of contact Strong oxidising agents.
Product Transfer This material has the potential to be a static accumulator.

Proper grounding and bonding procedures should be used
during all bulk transfer operations.
Storage
Other data Keep container tightly closed and in a cool, well-ventilated
place.
Use properly labeled and closable containers.
Store at ambient temperature.
Packaging material Suitable material: For containers or container linings, use mild
steel or high density polyethylene.
Unsuitable material: PVC.
Container Advice Polyethylene containers should not be exposed to high tem-

peratures because of possible risk of distortion.
SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

:r.=:-=,:---:-=-""""""'7"'!$""-9~0-:,;,f""'@-=e~BS::-1;'""'1s
lc:;i,,.p--,;;;;;Ti=.·····
~~=ra""'rri=e""";""'')'111'1',
ters/Permissible.,:ii 1, '.
0
·,,:i
1
fGanlntr~t1br {J·
'Ji·.i' ·
Oil mist, mineral Not Assigned T 'A ( inha - 5 mg/m3 US. ACGIH
able frac- Threshold
tion Limit Values
(Mist) 5 mg/m3 OSHA_ TRA
NS
Page 60 of 326
SAFETY DATA SHEET
0.1
TWA (Mist) 5 mg/m3 OSHA Z-1

TWA (lnhal- 5 mg/m3 ACGIH
able fraction)
No biological limit allocated.
Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or in the general
workplace may be required to confirm compliance with an OEL and adequacy of exposure con-
trols. For some substances biological monitoring may also be appropriate.
Validated exposure measurement methods should be applied by a competent person and sam-
ples analysed by an accredited laboratory.
Examples of sources of recommended exposure measurement methods are given below or con-
tact the supplier. Further national methods may be available.
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods
http://www.cdc.gov/niosh/
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods
http://www.osha.gov/
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances
http://www.hse.gov. uk/
lnstitut fur Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
L'lnstitut National de Recherche et de Securite, (INRS), France http://www.inrs.fr/accueil
Engineering measures The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Adequate ventilation to control airborne concentrations.
Where material is heated, sprayed or mist formed, there is

greater potential for airborne concentrations to be generated.
General Information:
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.
Ensure appropriate selection, testing and maintenance of
equipment used to control exposure, e.g. personal protective
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or mainte-
nance.
Retain drain downs in sealed storage pending disposal or
subsequent recycle.
Always observe good personal hygiene measures, such as
washing hands after handling the material and before eating,
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard con-
taminated clothing and footwear that cannot be cleaned.
Page 61 of 326
SAFETY DATA SHEET
1910.1200

Respiratory protection No respiratory protection is ordinarily required under normal
conditions of use.
In accordance with good industrial hygiene practices, precau-
tions should be taken to avoid breathing of material.
If engineering controls do not maintain airborne concentra-
tions to a level which is adequate to protect worker health,
select respiratory protection equipment suitable for the spe-
cific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air-filtering respirators are suitable, select an appro-
priate combination of mask and filter.
Select a filter suitable for the combination of organic gases
and vapours [Type A/Type P boiling point >65°C (149°F)].
Hand protection
Remarks Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. PVC, neoprene or nitrile rubber
gloves Suitability and durability of a glove is dependent on
usage, e.g. frequency and duration of contact, chemical re-
sistance of glove material, dexterity. Always seek advice from
glove suppliers. Contaminated gloves should be replaced.
Personal hygiene is a key element of effective hand care.
Gloves must only be worn on clean hands. After using
gloves, hands should be washed and dried thoroughly. Appli-
cation of a non-perfumed moisturizer is recommended.
For continuous contact we recommend gloves with break-
through time of more than 240 minutes with preference for>
480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same, but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model.
Eye protection If material is handled such that it could be splashed into eyes,
protective eyewear is recommended.
Skin and body protection Skin protection is not ordinarily required beyond standard
work clothes.
It is good practice to wear chemical resistant gloves.
Protective measures Personal protective equipment (PPE) should meet recom-

mended national standards. Check with PPE suppliers.
Environmental exposure controls

General advice Take appropriate measures to fulfill the requirements of rele-
vant environmental protection legislation. Avoid contamination
of the environment by following advice given in Chapter 6. If
Page 62 of 326
SAFETY DAT A SHEET
1910.1200
necessary, prevent undissolved material from being dis-

charged to waste water. Waste water should be treated in a
municipal or industrial waste water treatment plant before
discharge to surface water.
Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
Appearance Liquid at room temperature.
Colour amber
Odour Slight hydrocarbon
Odour Threshold Data not available
pH Not applicable
pour point -23 °C / -9 °FMethod: Unspecified
Initial boiling point and boiling > 280 °C / 536 °Festimated value(s)
range
Flash point 232 °C / 450 °F

Method: Unspecified
Evaporation rate Data not available
Flammability (solid, gas) Data not available
Upper explosion limit Typical 10 %(V)
Lower explosion limit Typical 1 %(V)
Vapour pressure < 0.5 Pa (20 °C / 68 °F)

estimated value(s)
Relative vapour density > 1estimated value(s)
Relative density 0.873 (15.0 °CI 59.0 °F)
Density 873 kg/m3 (15.0 °C / 59.0 °F)

Method: ASTM 04052
Solubility(ies)
Water solubility negligible
Solubility in other solvents Data not available
Partition coefficient: n- Pow: > 6(based on information on similar products)

octanol/water
Page 63 of 326
SAFETY DATA SHEET
According to OSHA Hazard Communication Standard, 29
CFR
1910.1200

Auto-ignition temperature >
320 °CI 608 °F
Viscosity
Viscosity, dynamic Data not available
Viscosity, kinematic 96 mm2/s (40.0 °CI 104.0 °F)

Method: Unspecified
11.38 mm2/s (100 °C / 212 °F)

Method: Unspecified
Explosive properties Not classified
Oxidizing properties Data not available
Conductivity This material is not expected to be a static accumulator.
Decomposition temperature Data not available
Reactivity The product does not pose any further reactivity hazards
in
addition to those listed in the following sub-paragraph.
Chemical stability Stable.
Possibility of hazardous reac- Reacts with strong oxidising agents.

tions
Conditions to avoid Extremes of temperature and direct sunlight.
Incompatible materials Strong oxidising agents.
Hazardous decomposition Hazardous decomposition products are not expected to form

products during normal storage.
Basis for assessment Information given is based on data on the components and
the toxicology of similar products.Unless indicated otherw
ise,
the data presented is representative of the product as a
whole, rather than for individual component(s).
Information on likely routes of exposure

Skin and eye contact are the primary routes of exposure
although exposure may occur following
accidental ingestion.
Acute toxicity
Page 64 of 326
SAFETY DATA SHEET
1910.1200
Acute oral toxicity LOSO(rat): > 5,000 mg/kg

Remarks: Expected to be of low toxicity:
Acute inhalation toxicity Remarks: Not considered to be an inhalation hazard under

normal conditions of use.
Acute dermal toxicity LOSO(Rabbit): > 5,000 mg/kg

Product:
Remarks: Expected to be slightly irritating., Prolonged or repeated skin contact without proper
cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis.
Product:
Remarks; Expected to be slightly irritating.
Product:
Remarks: Not expected to be a skin sensitiser.
Product:
Remarks: Not considered a mutagenic hazard.
Carcinogenicity
Product:
Remarks: Not expected to be carcinogenic.
Remarks: Product contains mineral oils of types shown to be non-carcinogenic in animal skin-
painting studies., Highly refined mineral oils are not classified as carcinogenic by the Internation-
al Agency for Research on Cancer (IARC).
IARC No component of this product present at levels greater than or

equal to 0.1 % is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH No component of this product present at levels greater than or

equal to 0.1 % is identified as a carcinogen or potential carcino-
gen by ACGIH.

equal to O.1% is identified as a carcinogen or potential carcino-
gen by OSHA.
Page 65 of 326
SAFETY DATA SHEET
1910.1200

by NTP.
Product:
Remarks: Not expected to impair fertility., Not expected to be

a developmental toxicant.
STOT - single exposure
Product:
Remarks: Not expected to be a hazard.
Product:
Aspiration toxicity
Product:
Not considered an aspiration hazard.
Further information
Product:
Remarks: Used oils may contain harmful impurities that have accumul
ated during use. The con-
centration of such impurities will depend on use and they may present
risks to health and the
environment on disposal., ALL used oil should be handled with caution
and skin contact avoided
as far as possible.
Remarks: Continuous contact with used engine oils has caused skin
cancer in animal tests.
Remarks: Slightly irritating to respiratory system.
Basis for assessment Ecotoxicological data have not been determined specifically
for this product.
Information given is based on a knowledge of the components
and the ecotoxicology of similar products.
Unless indicated otherwise, the data presented is representa-
tive of the product as a whole, rather than for individual com-
ponent(s).(LL/EL/IL50 expressed as the nominal amount of
product required to prepare aqueous test extract).
Ecotoxicity
Product:
Page 66 of 326
SAFETY DATA SHEET
1910.1200
ty) Remarks: Expected to be practically non toxic:

LL/EL/IL50 > 100 mg/I
Toxicity to daphnia and other

aquatic invertebrates (Acute Remarks: Expected to be practically non toxic:
toxicity) LL/EL/IL50 > 100 mg/I
Toxicity to algae (Acute tox-

icity) Remarks: Expected to be practically non toxic:
Toxicity to fish (Chronic tox- Remarks: Data not available

icity)
Toxicity to daphnia and other Remarks: Data not available

aquatic invertebrates (Chron-
ic toxicity)
Toxicity to bacteria (Acute Remarks: Data not available

toxicity)
Product:
Biodegradability Remarks: Expected to be not readily biodegradable.
Major constituents are expected to be inherently biodegrada-
ble, but contains components that may persist in the environ-
ment.
Product:
Bioaccumulation Remarks: Contains components with the potential to bioac-
cumulate.
Mobility in soil
Product:
Mobility Remarks: Liquid under most environmental conditions.
If it enters soil, it will adsorb to soil particles and will not be
mobile.
Remarks: Floats on water.

no data available
Product:
Additional ecological infor- Product is a mixture of non-volatile components, which are not
mation expected to be released to air in any significant quantities.
Not expected to have ozone depletion potential, photochemi-
cal ozone creation potential or global warming potential.
Poorly soluble mixture.
Page 67 of 326
SAFETY DATA SHEET
191 1200
May cause physical fouling of aquatic organisms.
Mineral oil is not expected to cause any chronic effects to

aquatic organisms at concentrations less than 1 mg/I.
Disposal methods
Waste from residues Waste product should not be allowed to contaminate soil or
ground water, or be disposed of into the environment.
Waste, spills or used product is dangerous waste.
Disposal should be in accordance with applicable regional,

national, and local laws and regulations.
Local regulations may be more stringent than regional or na-
tional requirements and must be complied with.
Contaminated packaging Dispose in accordance with prevailing regulations, preferably

to a recognized collector or contractor. The competence of
the collector or contractor should be established beforehand.
National Regulations
US Department of Transportation Classification (49 CFR Parts 171-180)

Not regulated as a dangerous good
International Regulations
IATA-DGR
IMDG-Code
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
Pollution category Not applicable
Ship type Not applicable
Product name Not applicable
Special precautions Not applicable
Special precautions for user
Remarks Special Precautions: Refer to Chapter 7, Handling & Storage,
for special precautions which a user needs to be aware of or
needs to comply with in connection with transport.
Additional Information MARPOL Annex 1 rules apply for bulk shipments by sea.
Page 68 of 326
SAFETY DATA SHEET
1910.1200
OSHA Hazards : No OSHA Hazards

EPCRA - Emergency Planning and Community Right-to-Know Act

This material does not contain any components with a CERCLA RQ., Shell classifies this material
as an "oil" under the CERCLA Petroleum Exclusion, therefore releases to the environment are not
reportable under CERCLA.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SARA 311/312 Hazards No SARA Hazards
SARA 302 No chemicals in this material are subject to the reporting

requirements of SARA Title 111, Section 302.
SARA 313 This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title Ill, Section 313.
Clean Water Act

This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act,
Section 311, Table 117.3.
California Prop 65 This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other re-
productive harm.
EINECS All components listed or polymer exempt.
TSCA All components listed.
DSL All components listed.
Further information
NFPA Rating (Health, Fire, Reac- 0, 1, 0
tivity)
A vertical bar (I) in the left margin indicates an amendment from the previous version.
Abbreviations and Acronyms The standard abbreviations and acronyms used in this docu-
ment can be looked up in reference literature (e.g. scientific
dictionaries) and/or websites.
ACGIH = American Conference of Governmental Industrial

Hygienists
ADR = European Agreement concerning the International
Page 69 of 326
SAFETY DATA SHEET
1910.1200
Carriage of Dangerous Goods by Road

AICS = Australian Inventory of Chemical Substances
ASTM = American Society for Testing and Materials
BEL = Biological exposure limits
BTEX = Benzene, Toluene, Ethylbenzene, Xylenes
CAS = Chemical Abstracts Service
CEFIC = European Chemical Industry Council
CLP = Classification Packaging and Labelling
COC = Cleveland Open-Cup
DIN = Deutsches lnstitut fur Normung
DMEL = Derived Minimal Effect Level
DNEL = Derived No Effect Level
DSL = Canada Domestic Substance List
EC = European Commission
ECS0 = Effective Concentration fifty
ECETOC = European Center on Ecotoxicology and Toxicolo-
gy Of Chemicals
ECHA = European Chemicals Agency
EINECS = The European Inventory of Existing Commercial
Chemical Substances
ELS0 = Effective Loading fifty
ENCS = Japanese Existing and New Chemical Substances
Inventory
EWC = European Waste Code
GHS = Globally Harmonised System of Classification and
Labelling of Chemicals
IARC = International Agency for Research on Cancer
ICS0 = Inhibitory Concentration fifty
ILS0 = Inhibitory Level fifty
INV= Chinese Chemicals Inventory
IP346 = Institute of Petroleum test method N° 346 for the
determination of polycyclic aromatics DMSO-extractables
KECI = Korea Existing Chemicals Inventory
LCS0 = Lethal Concentration fifty
LOSO= Lethal Dose fifty per cent.
LL/EL/IL = Lethal Loading/Effective Loading/Inhibitory loading
LLS0 = Lethal Loading fifty
MARPOL = International Convention for the Prevention of
Pollution From Ships
NOEC/NOEL = No Observed Effect Concentration / No Ob-
served Effect Level
OE_HPV = Occupational Exposure - High Production Volume
PBT = Persistent, Bioaccumulative and Toxic
PICCS = Philippine Inventory of Chemicals and Chemical
Substances
PNEC = Predicted No Effect Concentration
REACH = Registration Evaluation And Authorisation Of
Chemicals
RID = Regulations Relating to International Carriage of Dan-
gerous Goods by Rail
SKIN_DES = Skin Designation
STEL = Short term exposure limit
TRA = Targeted Risk Assessment
TSCA = US Toxic Substances Control Act
Page 70 of 326
SAFETY DATA SHEET
1910.1
c,o,cc·",'CCC J' _,,,,·z,FT X~Z"C!T,JTT~JJC',TJJ,'c''' ·,··•;··,,•o;'c·.
J:T'JF.'
TWA= Time-Weighted Average

vPvB = very Persistent and very Bioaccumulative
Revision Date 08/24/2016
This information is based on our current knowledge and is intended to describe the product for
the purposes of health, safety and environmental requirements only. It should not therefore be
construed as guaranteeing any specific property of the product.
Page 71 of 326
Page 72 of 326
SAFETY DATA SHEET
1910.1200
Product name Pennzoil Dex/Mere ATF
Product code : 001F1405

PO Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service


Recommended use : Transmission oil.
GHS Classification
Based on available data this substance/ mixture does not meet the classification criteria.
GHS label elements

HEALTH HAZARDS:

Response:
Storage:
Disposal:

Page 73 of 326
SAFETY DATA SHEET
1910.1200

The classification of this material is based on OSHA HCS 2012 criteria.
Under normal conditions of use or in a foreseeable emergency, this product

does not meet the
definition of a hazardous chemical when evaluated according to the OSHA
Hazard Communica-

The highly refined mineral oil contains <3% (w/w) DMSO-
* contains one or more of the following CAS-numbers: 64742-

53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9.
1'1
General advice Not expected to be a health hazard when used under normal
conditions.

In case of skin contact Remove contaminated clothing. Flush exposed area with wa-

rinsing.
If swallowed In general no treatment is necessary unless large quantities

Most important symptoms Oil acne/folliculitis signs and symptoms may include formation
and effects, both acute and of black pustules and spots on the skin of exposed areas.
Page 74 of 326
SAFETY DATA SHEET
1910.1200
Protection of first-aiders When administering first aid, ensure that you are wearing the

special treatment

media

gases (smoke).
occurs.


gency procedures


Page 75 of 326
SAFETY DATA SHEET
1910.1200


material.

Storage
place.

==~~"""",,,.,,.--:--;:,:j""l~"""•~'"': !"";,.,,.~-,.."""17'~
-:cca,;;--;,-,,...--,,,""'""'~
,;:ac:i:c-J...,..,' .1'.i:/-,i''!""i""':
inhal- 5
le frac-
on
Page 76 of 326
SAFETY DATA SHEET
1200
\c~'i;~:;;;-;cc;\':;-
Ci"i.i''.C'i'%\ .,,, ..,,, ..,., ...,,-x~;-,·-,- .,...., .... ;; ,-, , , ..,,..,·=~cc--,,-,,,: ---,:,n;--;-,-,,w;ff\'C"":'FiCP'":'::c,·,:c~cc:;-·s·1:
-,-;'W%'.'".C'\iii?V"1CCC'i:C''C'c::;-;\:·:,•w:
(Mist) 5 mg/m3 OSHA_TRA

NS
TWA (Mist) 5 ma/m3 OSHA Z-1
able fraction)
Monitoring Methods
http://www.hse.gov.uk/
http:/ /www.dguv.de/inhalt/index.jsp

controls.
product.
nance.
subsequent recycle.
Page 77 of 326
SAFETY DATA SHEET
1910.1200

conditions of use.
Hand protection
through time of more than 240 minutes with preference for >
work clothes.
Thermal hazards Not applicable

Page 78 of 326
SAFETY DAT A SHEET
1910.1200

vapour.
Colour red
pH Not applicable
pour point -48 °C / -54 °FMethod: ISO 3016
range

Method: ISO 2592
Upper explosion limit Typical 10 ¾M


estimated value(s)
Relative density 0.857 (15 °C / 59 °F)
Density 857 kg/m3 (15.0 °C / 59.0 °F)

Method: ISO 12185
Solubility(ies)
Page 79 of 326
SAFETY DATA SHEET
1910.1200

octanol/water

320 °C / 608 °F
Viscosity
Viscosity, kinematic 33.8 mm2/s (40.0 °C / 104.0 °F)

Method: ISO 3104
7.3 mm2/s (100 °C / 212 °F)

Method: ISO 3104
Reactivity The product does not pose any further reactivity hazards in

tions

the toxicology of similar products.Unless indicated otherwise,
Page 80 of 326
SAFETY DATA SHEET
1910.1200
Skin and eye contact are the primary routes of exposure although exposure may occur following
Acute toxicity
Product:
Acute oral toxicity LOSO(rat): > 5,000 mg/kg

Acute dermal toxicity LOSO(Rabbit): > 5,000 mg/kg

Product:
Product:
Remarks: Expected to be slightly irritating.
Product:
Product:
Carcinogenicity
Product:


gen by ACGIH.
Page 81 of 326
SAFETY DATA SHEET
1910.1200

gen by OSHA.

by NTP.
Product:

Product:
Product:
Aspiration toxicity
Product:
Further information
Product:
Remarks: Used oils may contain harmful impurities that have accumul
ated during use. The con-
as far as possible.
for this product.
Page 82 of 326
SAFETY DAT A SHEET
1

Ecotoxicity
Product:
Toxicity to fish (Acute toxici-



icity)

ic toxicity)

toxicity)
Product:
ment.
Product:
cumulate.
Mobility in soil
Product:
mobile.

no data available
Product:
Page 83 of 326
SAFETY DATA SHEET
1910.1200


Disposal methods
Waste from residues Recover or recycle if possible.
It is the responsibility of the waste generator to determine the
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal meth-
ods in compliance with applicable regulations.
Do not dispose into the environment, in drains or in water
courses
Waste product should not be allowed to contaminate soil or


Local legislation
Remarks Disposal should be in accordance with applicable regional,
US Department of Transportation Classification (49 CFR Parts 171-180

)
IATA-DGR
IMDG-Code
Page 84 of 326
SAFETY DAT A SHEET
0.1


SARA 302 No chemicals in this material are subject to the reporting re-
quirements of SARA Title 111, Section 302.
reporting levels established by SARA Title 111,
Section 313.
Clean Water Act

productive harm.
DSL Not all components listed.
Page 85 of 326
SAFETY DATA SHEET
1910.1200
Further information
tivity)

Hygienists
ECS0 = Effective Concentration fifty
gy Of Chemicals
Chemical Substances
ELS0 = Effective Loading fifty
Inventory
ICS0 = Inhibitory Concentration fifty
ILS0 = Inhibitory Level fifty
LCS0 = Lethal Concentration fifty
LL/EL/IL= Lethal Loading/Effective Loading/Inhibitory loading
LLS0 = Lethal Loading fifty
Page 86 of 326
SAFETY DATA SHEET

NOEC/NOEL = No Observed Effect Concentration/ No Ob-
served Effect Level
Substances
Chemicals
Sources of key data used to The quoted data are from, but not limited to, one or more
compile the Safety Data sources of information (e.g. toxicological data from Shell
Sheet Health Services, material suppliers' data, CONCAWE, EU
IUCLID date base, EC 1272 regulation, etc).
Page 87 of 326
Page 88 of 326
O'REILLYPOWER STEERINGFLUID
ill Safety Data Sheet

Conforms to HCS 2012 (29-CFR 1910.1200)
I
Product identifier
Product Name: O'REILLY POWER STEERING FLUID
Other names: F-79
Part/Product Number(s): 72810, 72813, 72805-3
Material Use: Automotive power steering fluid.

Uses advised against: Not for internal engine use.
Manufacturer: Omni Specialty Packaging, LLC
10399 Hwy 1 South
Shreveport, LA 71115
1-318-524-1100
Issuing date: May 8, 2015

Revision date: May 8, 2015
Revision number: O
Company contact: OMNI EHS Department; E-Mail: sds@osp.cc; Contact phone: 318-524-1100
(Monday-Friday, 8:00 AM - 4:00 PM, CST)
In case of emergency: CHEMTREC: Within USA and Canada: 1 (800) 524-9300 (24/7)
CHEMTREC Outside USA and Canada: +1 703-527-3887 (24/7
I
OSHA/HCS Status: This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29
CFR 1910.1200).
Classification of the
substance or Mixture: Not classified
GHS Label Elements

Hazard pictograms: None
Signal word: None
Appearance: Bright & Clear Physical State: Liquid Odor: Petroleum distillates
Hazard statement: None

General: Read label before use. Keep out of reach of children. If medical advice is needed, have product
container or label at hand.
Prevention: Not applicable

Response: Not applicable
Storage: Not applicable
Disposal: Not applicable
Hazards not otherwise classified (HNOC): Defatting to the skin.
Page 1 of 8
Page 89 of 326
O'REILLYPOWER STEERINGFLUID May 8, 2015
Petroleum mineral oil lubricant base stock with proprietary performance additives mixture.
I
Substance/mixture: Mixture
Comi;1onentsName CAS number Weight%*
Lubricant Base Oil (Petroleum) Highly refined Various 90-99.9
· mineral oils (C15-C50)
Power Steering Fluid Additive Mixture Proprietary 0.1-10
This product does not contain known hazardous materials at the .: 1% level or known carcinogens at the .: 0.1 % level as defined
by 29 CFR 1910.1200.
• The exact percentage of composition has been withheld as a trade secret.
Descrii;1tionof necessary first aid measures

General Advice: No specific first aid measures are required. Get medical attention if irritation develops and
persists.
Eye contact: In case of contact, immediately flush eyes with plenty of water for at least i 5 minutes. Eyelids
should be held away from the eyeball to ensure thorough rinsing. Check for and remove any
contact lenses. Get medical attention if irritation develops and persists.
Skin contact: Wash off immediately with soap and plenty of water while removing all contaminated clothes and
shoes. Get medical attention if irritation or allergic reaction develops and persists.
Inhalation: In case of inhalation of decomposition products in a fire, symptoms may be delayed. If

inhaled, remove to fresh air. The exposed person may need to be kept under medical
surveillance for 48 hours. Get medical attention if symptoms occur.
Ingestion: Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician.
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. Remove all
sources of ignition. Ensure that medical personnel are aware of the material(s) involved, take
precautions to protect themselves and prevent spread of contamination. Wear personal protective
clothing (see section 8).
Most imi;1ortantsymptoms and effects, both acute and delayed
See Section 11 for more detailed information on health effects and symptoms.
Most Important
Symptoms and Effects: Personnel with pre-existing skin disorders should avoid contact with this product. Under normal use
conditions, no adverse effects to health are known.
Eye contact: Not expected to cause prolonged or significant eye irritation.

Skin contact: Contact with skin is not expected to cause prolonged or significant irritation. Contact with skin is not
expected to cause an allergic skin response. Not expected to be harmful to internal organs if
absorbed through the skin.
Inhalation: Not expected to be harmful if inhaled. Contains petroleum-based mineral oil. May cause
respiratory irritation or other pulmonary effects following prolonged or repeated inhalation of oil
mist at airborne levels above the recommended oil mist exposure limit. Symptoms of respiratory
irritation may include coughing and difficult breathing.
Ingestion: Not expected to be harmful if swallowed.
Note to physician: Treat symptomatically ..
Page2 of 8
Page 90 of 326
May 8, 2015
O'REILLYPOWERSTEERINGFLUID
Uniform Fire Code: Class 111B
Flash Point: >137.8°C (>280°F)
Extinguishing Media
circumstances and
Suitable Media: In case of fire, use extinguishing measures that are appropriate to local
ent. Use water fog, alcohol resistant foam, dry chemical, carbon
the surrounding environm
dioxide (CO2) extinguisher or spray.
Unsuitable Media: CAUTION: Use of water spray when fighting fire may be inefficient.
Specific Hazards Arising from as product will

the Chemical: Keep product and empty container away from heat and sources of ignition
strong oxidizers may cause fire. In the event of fire, cool tanks with
burn. Contact with
be contained,
water spray. Fire residues and contaminated fire extinguishing water must
disposed of in
prevented from being discharged to any waterway, sewer or drain and
accordance with local regulations.
the following: Carbon dioxide (CO2) Carbon

Hazardous Combustion Products: Combustion products may include
monoxide (CO), and Nitrogen oxides.
of the incident if
Protection of Fire Fighters: Promptly isolate the scene by removing all persons from the vicinity
shall be taken involving any personal risk or without suitable
there is a fire. No action
demand,
training. As in any fire, wear self-contained breathing apparatus pressure-
MSHA/NIOSH (approved or equivalen t) and full protective gear.
es
Personal precautions, protective equipment and emergency procedur
training.
For non-emergency personnel: No action shall be taken involving any personal risk or without suitable
unnecess ary and unprotect ed personne l from
Evacuate surrounding areas. Keep
flames in
entering. ELIMINATE all ignition sources (no smoking, flares, sparks or
on appropriate
immediate area). Do not touch or walk through spilled material. Put
avoid falling.
personal protective equipment. Floors may be slippery; use care to
of any information
For emergency responders: If specialized clothing is required to deal with the spillage, take note
and unsuitable materials . Ensure adequate ventilation . Keep
in Section 8 on suitable
Take precautionary
people away from and upwind of spill/leak. Pay attention to flashback.
the product must
measures against static discharges. All equipment used when handling
n in "For non-emer gency personne l".
be grounded. See also the informatio
s, drains
Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterway
environmental
and sewers. Inform the relevant authorities if the product has caused
l information.
pollution (sewers, waterways, soil or air). See Section 12 for ecologica
Methods and materials for containment and cleaning up

an inert material and place in
Small Spills: Stop leak if without risk. Move containers from spill area. Absorb with
a licensed waste disposal contractor.
an appropriate waste disposal container. Dispose of via
entry into sewers, water courses,
Large Spills: Stop leak if without risk. Move containers from spill area. Prevent
or confined areas. Contain and collect spillage with non- combustible, absorbent material
basements
earth and place in container for disposal according to
e.g. sand, earth, vermiculite or diatomaceous
r.
local regulations. Dispose of via a licensed waste disposal contracto
of water, report immediately to the USEPA's National

NOTE: If RO (Reportable Quantity) is exceeded or if spills enter a body
local and state regulators regarding their reporting requirements.
Response Center at (800) 424-8802. Check with your

conditions that
Protective measures: Eye protection and face shield should be used if material is used under
equipment
increase the chances of splattering. Put on appropriate personal protective
Page 3 of 8
Page 91 of 326
O'REILLYPOWERSTEERINGFLUID
May 8,2015
(see Section 8). Keep out of reach of children.

Advice on general
occupational hygiene: Do not get in eyes, on skin or on clothing. Eating, drinking and
smoking should be
prohibited in areas where this material is handled, stored and
processed. Wash
thoroughly after handling. Remove contaminated clothing and
protective equipment
before entering eating areas.
See also Section 8 for additional information on hygiene measure
Conditions for safe storage, s.
Including any incompatibilities: Store in accordance with local regulations. Store in original containe
r protected from
direct sunlight in a dry, cool and well-ventilated area, away from
incompatible materials,
strong oxidizing agents (see Section i 0) and food and drink. Keep
away from heat,
sparks, flame and other sources of ignition (i.e., pilot lights, electric
motors and static
electricity). Keep container tightly closed and sealed until ready
for use. Containers that
have been opened must be carefully resealed and kept upright
to prevent leakage. Use
appropriate containment to avoid environmental contamination.
Avoid contaminating
soil or releases into sewage or drainage systems and bodies
of water.
Bulk material handling: Static Hazard: Electrostatic charge may accumulate and create
a hazardous condition
when handling this material. To minimize this hazard, bonding
and grounding may be
necessary but may not, by themselves, be sufficient.
Control parameters
Occupational Exposure Limits
TLV STEL PEL STEL TWA

Lubricant Base Oil (Petroleum) Ceiling
5 mg/m3 i O mg/m3 5 mg/m3
Hiahlv refined mineral oils (Ci5-C50) (mist) /mist) /mist)
Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposur
e to airborne
contaminants. Emergency shower and eyewash station.
Environmental exposure controls: Emissions from ventilation or work process equipment should
be checked to ensure
they comply with the requirements of environmental protection
legislation. In some
cases, fume scrubbers, filters or engineering modifications to
the process
equipment will be necessary to reduce emissions to acceptable
Individual protection measures levels.
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemica
l products,
before eating, smoking and using the lavatory and at the end
of the working
period. Appropriate techniques should be used to remove potentia
lly
contaminated clothing. Wash contaminated clothing before reusing.
Eye/Face Protection: Wear safety glasses with side shields. A face shield may be necessa
ry under
some conditions.
Skin and Body Protection
Hand protection: Wear protective gloves if prolonged or repeated contact is likely.

Wear
chemical resistant gloves. Recommended: Nitrile gloves. Consult
your supervisor
or Standard Operating Procedure (SOP) for special handling instructio
ns.
Body protection: No protective equipment is needed under normal use conditions.
For non-routine
tasks, personal protection equipment for the body should be selected
based on the
task being performed and the risks involved.
Other skin protection: Appropriate footwear and any additional skin protection measure
s should be
selected based on the task being performed and the risks involved
.
Respiratory protection: No respiratory protection is normally required. If user operation
generates an oil
mist, determine if airborne concentrations are below the occupat
ional exposure limit
for mineral oil mist. If not, wear an approved respirator that provides
adequate
protection from measured concentrations of this material. The correct
choice of
Page 4 of 8
Page 92 of 326
O'REILLY POWER STEERING FLUID May 8, 2015
respiratory protection depends upon the chemicals being handled, the conditions of
work and use, and the condition of the respiratory equipment. For air-purifying
respirators use a particulate cartridge. Use a positive pressure air-supplying
respirator in circumstances where air-purifying respirators may not provide
adequate protection.
Appearance (Typical or Target)

Physical State: Liquid
Color: Bright & Clear
Odor: Petroleum like
Odor threshold: Not available
pH: Not applicable
Boiling Point: Not available
Flash Point (Closed cup): > 137.8°C (>280°F) (Typical or Target)
Evaporation rate (Butyl acetate= 1): Not available
Flammability (solid, gas): Not applicable. Based on - Physical state
Flammable) Limit in Air Not available
Vapor pressure: Not available
Vapor density (Air= 1): >1
Relative density: 0.86 - 0.91 g/I at 15°C (Typical or Target)
Solubility: In soluble in water
Partition coefficient (n-Octanol/water): Not available
Auto-ignition temperature: Not available
Decomposition temperature: Not available
Viscosity- Kinematic (est (mm2/s)@ 40°C): 26- 74
Viscosity- Dynamic (cSt (mm2/s) @ 100°C): 4.5 - 8.8
VOC¾: 0%
I Section10. Stability ahd]=teactivity

·•.' :.1
Reactivity: Not reactive under normal storage conditions
Chemical stability: Stable under normal storage conditions
Possibility of hazardous reactions: None under normal processing.
Hazardous polymerization: Hazardous polymerization does not occur.
Conditions to avoid: Heat, flames and sparks.
Incompatible materials: Oxidizing agents and open flames.
Hazardous decomposition products: May include: Fumes, Oil vapors, Smoke, Carbon Oxides (including carbon monoxide
and carbon dioxide), Aldehydes, Nitrogen oxides, and incomplete combustion
products.
Substance/Mixture
,. .
AcuteToxicitv • .. ..,Oral LDS0 Dermal LDS0 Inhalation LCS0
Lubricant Base Oil (Petroleum) >2000 mg/Kg (rat) >2000 mg/Kg (rabbit) >2.18 mg/L (rat) 4h (mist)
Highly refined mineral oils (C15-
C50) Mixture - Tvoical
Aspiration hazard: Not expected to be an aspiration hazard.

Skin C orrosion/lrritation: No known significant effects or critical hazards.
Serious Eye Damage/Irritation: No known significant effects or critical hazards.
Skin Sensitization: No known significant effects or critical hazards.
Respiratory Sensitization: No known significant effects or critical hazards.
Specific Target Organ Toxicity
(Single Exposure)· STOT-SE: No known significant effects or critical hazards.
(Repeated Exposure) - STOT-RE: No known significant effects or critical hazards.
Page 5 of 8
Page 93 of 326
O'REILLY POWER STEERING FLUID May 8, 2015
Carcinogenicity: No known significant effects or critical hazards.

Germ Cell Mutagenicity: No known significant effects or critical hazards.
Reproductive Toxicity No known significant effects or critical hazards.
Information on Toxicity Effects of Compounds

Lubricant Base Mineral Oil (Petroleum)
Mineral oils are known to cause cancer because of carcinogenic components (e.g. Benzene). The lubricant base mineral oils
in this product have been highly refined by a variety of processes including severe solvent extraction, severe hydro cracking
or severe hydro treating to reduce aromatics and improve performance characteristics. The oils in the is product meets the
IP-346 criteria of less than 3 percent PHA's and are not considered to be a carcinogen by the International Agency for
Research on Cancer.
None of the oils in this product requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR
1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been
classified by the International Agency for Research on Cancer (IRAC) as: carcinogenic to humans (Group 1), probably
carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have not been classified by
the American Conference of Governmental Industrial Hygienists (ACGIH) as: confirmed human carcinogen (A 1), suspected
human carcinogen (A2), or confirmed animal carcinogen with unknown relevance to humans (A3).
The information is based on data available for the material, the components of the material, and similar materials.
Ecotoxicity: No testing has been performed by the manufacturer. Ecotoxicity hazard is based on an evaluation of data for the
components or a similar material. Not expected to be harmful to aquatic organisms.
Mobility: Base oil component - Low solubility and floats and is expected to migrate from water
to land. Expected to partition to sediment and wastewater solids.
Soil/water partition
coefficient (Koc): Not available.
Persistence and degradation

Biodegradation: The material is not expected to be readily biodegradable. The biodegradability of this
material is based on an evaluation of data for the components or a similar material.
Bioaccumulation: This product is not expected to bioaccumulate through food chain in the
environment.
Other adverse effects: No known significant effects or critical hazards.
Other ecological information: Spills may form a film on water surfaces causing physical damage to organisms.
Oxygen transfer could also be impaired.
Disposal recommendations based on material supplied.

Waste treatment methods: This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR
261 ). Consult the appropriate state, regional, or local regulations for additional requirements.
The generation of waste should be avoided or minimized wherever possible.
Product waste: Significant quantities of waste product residues should not be disposed of via the sanitary
sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-
recyclable products via a licensed waste disposal contractor. Disposal of this product,
solutions and any by-products should at all times comply with the requirements of
environmental protection and waste disposal legislation and any regional local authority
requirements. Incineration or landfill should only be considered when recycling is not
feasible. Oil collection services are available for used oil recycling.
Contaminated packaging: Empty containers or liners may retain some product residues and could pose a potential fire and
explosion hazard. Do not cut, puncture, or weld containers.
Page 6 of 8
Page 94 of 326
O'REILLYPOWER STEERINGFLUID May 8, 2015
Other information: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
General information: Petroleum Lubricating oil - Not regulated.
DOT Classification IMDG IATA

Power Steerin Fluid Not Re ulated Not Re ulated Not Re ulated
Special precautions for user: Transport within user's premises: Always transport in closed containers that are upright and
secure. Ensure that persons transporting the product know what to do in the event of an
accident or spillage.
United States Regulations
United States Inventory (TSCA Bb): All components are listed or exempted.
SARA 302/304: No products were found.
SARA 311/312: Immediate (Acute) Health Effects: No

Delayed (Chronic) Health Effects: No
Fire Hazard: No
Sudden Release of Pressure Hazard: No
Reactivity Hazard: No
SARA 313:
The following components of this material are found on the EPCRA 313 list:
None
Supplier notification: This product does not contain any hazardous ingredients at or above regulated
thresholds.
CWA {Clean Water Act): This product does not contain any substances regulated as pollutants pursuant to the Clean
Water Act (40 CFR 122.21 and 40 CFR 122.42)
CERCLA: This material, as supplied, does not contain any substances regulated as a hazardous
substance under the Comprehensive Environmental Response Compensation and Liability Act
(CERCLA) (40 CFR 302).
State Regulations
Massachusetts: None of the components are at or above regulated thresholds.
New Jersey: Petroleum Oil (Motor Oil)
Pennsylvania: None of the components are at or above regulated thresholds.
California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer.
None
Canada
WHMIS Hazard Class: Not classified. This Product Is Not Controlled Under WHMIS (Canada)
International Chemical Inventories:

All components comply with the following chemical inventory requirements: DSL (Canada)
NFPA Ratin Health Hazard - 1 Flammabilit - 1 lnstability/Reactivit - O

HMIS Ratin : Health Hazard - 1 Flammabilit - 1 Ph sical Hazards - 0
(NFPA & HMIS Hazard Rating Key: 0 - Minimum Hazard; 1 - Slight Hazard; 2 - Moderate Hazard; 3- High Hazard; 4 - Extreme Hazard;
• - Chronic Hazard Indicator, & PPE - Personal Protective Equipment Index A to L. These values are obtained using the guidelines or
Page 7 of 8
Page 95 of 326
O'REILLYPOWERSTEERINGFLUID May 8, 2015
published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating Association (for
HMIS or Hazardous Material Identification System).
Key to abbreviations:
OSHA = Occupational Safety and Health Administration LogPow = logarithm of the octanoVwater partition coefficient
ACGIH= American Conference of Industrial Hygienists OEL = Occupational Exposure Limit
ATE= Acute Toxicity Estimate SOS = Safety Data Sheet
BCF = Bioconcentration Factor STEL = Short term exposure Limit
CAS = Chemical Abstracts Service Registry Number UN = United Nations
est= Centistroke (mm2/s) UN Number= United Nations Number, a four digit number
GHS = Global Harmonized System of Classification and Labeling assigned by the United Nations Committee of Experts on
Of Chemicals. the Transportation of Dangerous Goods
IBC = Intermediate Bulk Container
Prepared By: OMNI Specialty Packaging EH&S Department

Revision Date: May 8, 2015
Status: Final
Revision Note: All Sections. First version in OSHA GHS SOS format.
Consumer Product Improvement Act of 200B. General Conformity Certification
For Consumer Product Packages: This product has been evaluated and is certified to be labeled and packaged In compliance with
the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product
Safety Commission. Where applicable the products that require Child Resistant Closures are packaged In accordance with the Poison
Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have
been tested in accordance with the latest protocols. No testing is required to certify compliance with the provisions. The date of the
manufacturing Is stamped on the product container.
Disclaimer
All reasonably practicable steps have been taken to ensure the information provided in this Safety Data Sheet is correct to the
best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance
for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text. This information is furnished upon condition
that the person receiving it shall make their own determination of the suitability of the material for their particular purpose.
End of Safety Data Sheet
Page 8 of 8
Page 96 of 326
SAFETY DATA SHEET
910.1200
Product name Quaker State 5W-30 Synthetic Blend Motor Oil
Product code 001E2942

PO Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service


GHS Classification
Based on available data this substance/ mixture does not meet the classification criteria.
GHS label elements
Hazard pictograms No Hazard Symbol required

HEALTH HAZARDS:

Response:
Storage:
Disposal:

Page 97 of 326
SAFETY DATA SHEET
1910.1200

Under normal conditions of use or in a foreseeable emergency, this

product does not meet the
definition of a hazardous chemical when evaluated according to the
OSHA Hazard Communica-
Chemical nature Synthetic base oil and additives.

Highly refined mineral oil.
The highly refined mineral oil is only present as additive dilu-
ent.

53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-4 7-5, 848301-69-
9.
Polyolefin polyamine sue- Not Assigned 1 - 3

cinimide ol ol **
Alkaryl amine bis(nonylphenyl)ami 36878-20-3 1 - 3
ne
Interchangeable low vis- Not Assigned 0 - 90
cosity base oil (<20,5 est
40°c *
** polymer exempt.
conditions.


rinsing.
Page 98 of 326
SAFETY DATA SHEET
1910.1200

special treatment

media

gases (smoke).
occurs.


gency procedures


Page 99 of 326
SAFETY DATA SHEET
1910.1200



material.

Storage
other data Keep container tightly closed and in a cool, well-ventilated
place.

Page 100 of 326

SAFETY DATA SHEET
1910.1200
Version 1.5 Revision Date: 11/10/2017 Print Date: 1~/11/2017
. Corpponents .·. ·.··••·· CAS 0 No . ValueJype ···· O.ontrol parame- .·. Bas.is
- 1'1 I '' ,:
(Forhlof .·. ters I Permissible. .·.
.... l ..
· exoos.wret concentration ·· i •··· \ !
Oil mist, mineral Not Assigned TWA ((inhal- 5 mg/m3 US. ACGIH
tion)) Limit Values
NS
able fraction)

Monitoring Methods
tact the suppliBr. Further national methods may be available.

controls.
product.
nance.
Page 101 of 326

SAFETY DATA SHEET
1910.1200
subsequent recycle.

conditions of use.
Hand protection
work clothes.
Page 102 of 326

SAFETY DAT A SHEET
1910.1200


vapour.
Colour amber
pH Not applicable
pour point -42 °C / -44 °FMethod: ASTM 097
range

Method: ASTM 093 (PMCC)

estimated value(s)
Page 103 of 326

SAFETY DATA SHEET
1910.1200
Density 837 kg/m3 (15.0 °C / 59.0 °F)

Method: ASTM 04052
Solubility(ies)

octanol/water

320 °CI 608 °F
Viscosity
Viscosity, kinematic 62.6 mm2/s (40.0 °CI 104.0 °F)

Method: ASTM 0445
10.9 mm2/s (100 °C / 212 °F)

Method: ASTM 0445

tions

Page 104 of 326

SAFETY DATA SHEET
1910.1200

Acute toxicity
Product:
Acute oral toxlcity LD50 (rat): > 5,000 mg/kg

Acute dermal toxicity LD50 (Rabbit): > 5,000 mg/kg

Product:
Serious eye d~mage/eye irritation
Product:
Product:
Product:
Carcinogenicity
Product:

Page 105 of 326

SAFETY DATA SHEET
1910.1200

gen by ACGIH.

equal to 0.1 % is on OSHA's list of regulated carcinogens.

by NTP.
Product:

Product:
Product:
Aspiration toxicity
Product:
Further information
Product:
Remarks: Used oils may contain harmful impurities that have accumulated during use. The con-
centration of such impurities will depend on use and they may present risks to health and the
environment on disposal., ALL used oil should be handled with caution and skin contact avoided
as far as possible.
Remarks: Continuous contact with used engine oils has caused skin cancer in animal tests.
for this product.
Page 106 of 326

SAFETY DAT A SHEET
1910.1

Ecotoxicity
Product:



icity)

ic toxicity)

toxicity)
Product:
ment.
Product:
cumulate.
Mobility in soil
Product:
mobile.

no data available
Product:
Page 107 of 326

SAFETY DATA SHEET
1910.1200

Disposal methods
courses


Local legislation

IATA-DGR
IMDG-Code
Not applicable for product as supplied. MARPOL Annex 1 rules apply for bulk shipment
s by sea.
Page 108 of 326

SAFETY DATA SHEET
1910.1200


EPCRA- Emergency Planning and Community Right-to-Know Act

quirements of SARA Title Ill, Section 302.
Clean Water Act

productive harm.
Further information
tivity)
Page 109 of 326

SAFETY DATA SHEET
1910.1200

Hygienists
EC50 = Effective Concentration fifty
gy Of Chemicals
Chemical Substances
EL50 = Effective Loading fifty
Inventory
IC50 = Inhibitory Concentration fifty
IL50 = Inhibitory Level fifty
LC50 = Lethal Concentration fifty
LOSO = Lethal Dose fifty per cent.
LL50 = Lethal Loading fifty
served Effect Level
Substances
Page 110 of 326

SAFETY DATA SHEET
1 0.1200
Chemicals
RID= Regulations Relating to International Carriage of Dan-
product for
This information is based on our current knowledge and is intended to describe the
It should not therefore be
the purposes of health, safety and environmental requirements only.
Page 111 of 326

Page 112 of 326
SAFETY DATA SHEET
1910.1200
Product name Rotella Ultra ELC Antifreeze/Coolant Pre-Diluted 50/50
Product code : 001C6892

PO Box 4427
USA
SDS Request (+1) 877-276-7285
Customer Service


Recommended use : Antifreeze and coolant.
GHS Classification
Acute toxicity (Oral) Category 4
Specific target organ toxicity Category 2 (Kidney)

- repeated exposure
GHS label elements

Hazard pictograms
Signal word Warning

HEALTH HAZARDS:
H302 Harmful if swallowed.
H373 May cause damage to organs through prolonged or re-
peated exposure if swallowed.

P264 Wash hands thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
Response:
P301 + P312 IF SWALLOWED: Call a POISON CENTER/doctor
Page 113 of 326

SAFETY DATA SHEET
1910.1200
if you feel unwell.

P330 Rinse mouth.
Storage:
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Hazardous components which must be listed on the label:

Contains ethanediol.
Contains bittering agent.

Intentional abuse, misuse or other massive exposure may cause multiple organ damage and or
death.
Chemical nature : Mixture of ethylene glycol, water and additives.
<Joncentrntioni
Ethanediol ethane-1,2-diol 107-21-1 40 - 60
Aerosol
Dieth lene I col 2,2'-ox diethanol 111-46-6 1 - 3
General advice DO NOT DELAY.

Keep victim calm. Obtain medical treatment immediately.
If inhaled Remove to fresh air. If rapid recovery does not occur,

transport to nearest medical facility for additional treatment.

rinsing.
If swallowed DO NOT DELAY.

If swallowed, do not induce vomiting: transport to nearest
medical facility for additional treatment. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
Rinse mouth.
Most important symptoms Kidney toxicity may be recognized by blood in the urine or
Page 114 of 326

SAFETY DATA SHEET
1910.1200
and effects, both acute and increased or decreased urine flow. Other signs and symptoms
delayed can include nausea, vomiting, abdominal cramps, diarrhoea,
lumbar pain shortly after ingestion, and possibly narcosis and
death.
High concentrations may cause central nervous system de-
pression resulting in headaches, dizziness and nausea; con-
tinued inhalation may result in unconsciousness and/or death.
Immediate medical attention, IMMEDIATE TREATMENT IS EXTREMELY IMPORTANT!

special treatment The preferred treatment is immediate transportation to a med-
ical facility and use of appropriate treatment including possible
administration of activated charcoal, gastric lavage and or
gastric aspiration. If none of the above are immediately avail-
able and a delay of more than one hour is anticipated before
such medical attention can be obtained, induction of vomiting
may be appropriate using IPECAC syrup (Contraindicated if
there are any signs of CNS depression). This should be con-
sidered on a case by case basis following specialist advice.
Specific other treatments may include ethanol therapy, fomep-
izole, treatment of acidosis and haemodialysis. Seek specialist
advice without delay.

media

gases (smoke).
occurs.

Page 115 of 326

SAFETY DATA SHEET
1910.1200
Personal precautions, protec- Avoid contact with skin and eyes.

gency procedures


Methods and materials for For large liquid spills (> 1 drum), transfer by mechanical
containment and cleaning up means such as vacuum truck to a salvage tank for recovery or
safe disposal. Do not flush away residues with water. Retain
as contaminated waste. Allow residues to evaporate or soak
up with an appropriate absorbent material and dispose of
safely. Remove contaminated soil and dispose of safely
For small liquid spills(< 1 drum), transfer by mechanical

means to a labeled, sealable container for product recovery or
safe disposal. Allow residues to evaporate or soak up with an
appropriate absorbent material and dispose of safely Remove
contaminated soil and dispose of safely.


U.S. regulations may require reporting releases of this materi-

al to the environment which exceed the reportable quantity
(refer to Chapter 15) to the National Response Center at
(800) 424-8802.

material.
Page 116 of 326

SAFETY DATA SHEET
1910.1200
Storage
place.
Unsuitable material: Zinc., Avoid contact with galvanized ma-
terials.


C6mponents.: c~s-No. ,ValueJYpe ~ontrol parame~,,,,
6f
(i=c;irrn tefs/ Permi§sible
concehtration 1
• •
Ethanediol 107-21-1 C (Aerosol 100 mg/m3 ACGIH

onl
Monitoring Methods
lnstitut tor Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dg uv .de/inhalt/index .jsp
Page 117 of 326

SAFETY DATA SHEET
1910.1200

controls.
product.
nance.
subsequent recycle.

conditions of use.
Hand protection
Page 118 of 326

SAFETY DATA SHEET
1910.1200

work clothes.


vapour.
Appearance liquid
Colour yellow
Odour characteristic
pH Not applicable
Melting point/freezing point -37 °C / -35 °F (100.0 hPa)

Method: ASTM D 1177
range
Flash point >= 287 °CI>= 549 °F

Method: Unspecified
Page 119 of 326

SAFETY DATA SHEET
According to OSHAHazard Communication Standard, 29 CFR
1910.1200
Upper explosion limit Typical 15 o/o(V)
Lower explosion limit Typical 3 o/o(V)
Vapour pressure Data not available
Relative vapour density Data not available
Relative density 1.070 - 1.080 (15.6 °C / 60.1 °F)
Density 1,070 - 1,080 kg/m3 (15.6 °C / 60.1 °F)

Method: ASTM 01122
Solubility(ies)
Water solubility completely soluble
Partition coefficient: n- Data not available

octanol/water

200 °CI 392 °F
Viscosity
Viscosity, kinematic Data not available

tions

Page 120 of 326

SAFETY DATA SHEET
1910.1200

Acute toxicity
Product:
Acute oral toxicity LOSO (rat): > 500 - 2,000 mg/kg
Remarks: Harmful if swallowed.
Remarks: There is a marked difference in acute oral toxicity

between rodents and man, man being more susceptible than
rodents. The estimated fatal dose for man is 100 milliliters
(1/2 cup). This material has also been shown to be toxic and
potentially lethal by ingestion to cats and dogs.
Ingestion may cause drowsiness and dizziness.
Acute inhalation toxicity LC 50 (Rat): > 5 mg/I

Exposure time: 4 h
Remarks: Low toxicity:
Acute dermal toxicity LOSO (Rabbit): > 5,000 mg/kg

Remarks: Low toxicity:
Product:
Product:
Product:
Product:
Carcinogenicity
Page 121 of 326

SAFETY DATA SHEET
1910.1200
Product:


gen by ACGIH.


by NTP.
Product:
Product:
Remarks: Kidney: can cause kidney damage.
Aspiration toxicity
Product:
Further information
Product:
for this product.
ponent(s).
Page 122 of 326

SAFETY DATA SHEET
1910.1200
Ecotoxicity
Product:
LC/EC/IC50 > 100 mg/I

toxicity) LC/EC/IC50 > 100 mg/I

LC/EC/IC50 > 100 mg/I

icity)

ic toxicity)

toxicity)
Product:
Biodegradability Remarks: Readily biodegradable.
Product:
Bioaccumulation Remarks: Not expected to bioaccumulate significantly.
Mobility in soil
Product:
If product enters soil, it will be highly mobile and may contam-
inate groundwater.
Dissolves in water.

no data available
Product:
Additional ecological infor- Not expected to have ozone depletion potential, photochemi-
mation cal ozone creation potential or global warming potential.
Page 123 of 326

SAFETY DATA SHEET
1910.1200
Disposal methods
courses


Local legislation
UN/ID/NA number UN 3082
Proper shipping name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S.
(Ethylene glycol)
Class 9
Packing group Ill
Labels 9
Reportable quantity Ethylene glycol
(5,000 lb)
Marine pollutant no
Remarks This material is not regulated under 49 CFR if in a container of
119 gallon capacity or less.
IATA-DGR
IMDG-Code
Page 124 of 326

SAFETY DATA SHEET
1910.1200
OSHA Hazards : Toxic by ingestion


; C~loulated
producf
lbs RO.·.
... .. ·•·.
Eth lene GI col 107-21-1 5000 *
*: Calculated RQ exceeds reasonably attainable upper limit.

Calculated RQ exceeds reasonably attainable upper limit.
Shell classifies this material as an "oil" under the CERCLA Petroleum Exclusion, therefore releas-
es to the environment are not reportable under CERCLA.
The components with RQs are given for information.
SARA 311/312 Hazards Acute Health Hazard
quirements of SARA Title 111,Section 302.
SARA313 The following components are subject to reporting levels es-

tablished by SARA Title 111,Section 313:
Ethanediol 107-21-1 47.2954 %
Clean Water Act

Page 125 of 326

SAFETY DATA SHEET
1910.1200
Ethanediol 107-21-1
Diethylene glycol 111-46-6
Ethanediol 107-21-1
California Prop 65 WARNING: This product contains a chemical known to the

harm.
Further information
tivity)

Hygienists
BEL= Biological exposure limits
DIN= Deutsches lnstitut fur Normung
gy Of Chemicals
Chemical Substances
Page 126 of 326

SAFETY DAT A SHEET
1910.1200
Inventory
LD50 = Lethal Dose fifty per cent.
served Effect Level
Substances
Chemicals
Page 127 of 326

Page 128 of 326
SAFETY DATA SHEET
1910.1200
Product name Shell Rotella T1 30
Product code 001 D5428

P.O. Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service


GHS Classification
GHS Label element
Hazard pictograms No Hazard Symbol required

HEAL TH HAZARDS:

Response:
Storage:
Disposal:

Page 129 of 326

SAFETY DATA SHEET
1910.1200

Under normal conditions of use or in a foreseeable emergency, this product does not meet tha
definition of a hazardous chemical when evaluated according to the OSHA Hazard Communica-

* contains one or more of the following GAS-numbers: 64742-

53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9.
Sulphurised calcium phe- Not Assigned 1 - 3

nate
Zinc dialkyl dithiophos- Phosphorodithioic 68649-42-3 1 - 2.4
phate acid, O,O-di-C1-14-
alkyl esters, zinc
salts
40°c *
conditions.



Page 130 of 326

SAFETY DATA SHEET
1910.1200

special treatment
Suitable extinguishing media Foam, water spray or fog. Dry chemical powder, carbon dio-
xide, sand or earth may be used for small fires only.

media

gases (smoke).
occurs.
Specific extinguishing me- Use extinguishing measures that are appropriate to local cir-
thods cumstances and the surrounding environment.


gency procedures


Page 131 of 326

SAFETY DATA SHEET
1910.1200


material.

Storage
place.


~====c=lc'ffl,::-:,-a~,,,--=-~~,~,~· •.~~Qn~.f~fu~J=p~ijtna~m~'.~~)-
,~
r~(.~ermls§lble
qr;ie'entration ii,,1f1
Page 132 of 326

SAFETY DAT A SHEET
191
tion)) Limit Values

NS
Monitoring Methods
lnstitut fi.ir Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dg uv .de/inhalt/index.jsp

controls.
Educate and train workers in the hazards and control meas-
ures relevant to normal activities associated with this product.
Drain down system prior to equipment break-in or mainten-
ance.
subsequent recycle.

Page 133 of 326

SAFETY DATA SHEET
1910.1200
conditions of use.
and vapours [Type NType P boiling point >65°C (149°F)].
Hand protection
work clothes.


Page 134 of 326

SAFETY DATA SHEET
1910.1200

vapour.
Colour amber
pH Not applicable
pour point -24 °C / -11 °FMethod: ASTM D97
Initial boiling point and boiling > 280 °CI 536 °Festimated value(s)
range

Method: ASTM D92

estimated value( s)
Density 887 kg/m3 (15.0 °C / 59.0 °F)

Method: ASTM D4052
Solubility(ies)
Partition coefficient: n- Pow:> 6(based on information on similar products)

octanol/water

320 °CI 608 °F
Page 135 of 326

SAFETY DATA SHEET
1910.1200
Viscosity
Viscosity, kinematic 107 mm2/s (40.0 °C / 104.0 °F)

Method: ASTM D445
11.9 mm2/s (100 °C / 212 °F)

Method: ASTM D445

tions


Acute toxicity
Product:
Acute oral toxicity LD50 (rat): > 5,000 mg/kg

Page 136 of 326

SAFETY DATA SHEET
1910.1200
Product:
Product:
Product:
Product:
Carcinogenicity
Product:


gen by ACGIH.

gen by OSHA.

by NTP.
Product:
Page 137 of 326

SAFETY DATA SHEET
1910.1200

Product:
Product:
Aspiration toxicity
Product:
Further information
Product:
as far as possible.
for this product.
Ecotoxicity
Product:
Toxicity to fish (Acute toxic-
ity) Remarks: Expected to be practically non toxic:

Page 138 of 326

SAFETY DATA SHEET
1910.1200
Toxicity to algae (Acute toxic-

ity) Remarks: Expected to be practically non toxic:
Toxicity to fish (Chronic toxic- Remarks: Data not available

ity)

ic toxicity)

toxicity)
Product:
ment.
Product:
cumulate.
Mobility in soil
Product:
mobile.

no data available
Product:
Additional ecological informa- Product is a mixture of non-volatile components, which are not
tion expected to be released to air in any significant quantities.


Page 139 of 326

SAFETY DATA SHEET
1910.1200
Disposal methods



International Regulation
IATA-DGR
IMDG-Code
Page 140 of 326

SAFETY DATA SHEET
1910.1200


SARA 313 The following components are subject to reporting levels es-
tablished by SARA Title 111,
Section 313:
Zinc dialkyl dithiophos- 68649-42-3 1.3333 %

phate
Clean Water Act

Distillates (petroleum), hydrotreated heavy 647 42-54-7
paraffinic
Zinc dialkyl dithiophosphate 68649-42-3
productive harm.
Further information
tivity)
Due to the conversion of this product to GHS classification and labelling, there has been a
significant change to the nature of the information presented in chapter 2.
~!~:~lt~
Page 141 of 326
SAFETY DATA SHEET
1910.1200


Hygienists
gy Of Chemicals
Chemical Substances
Inventory
served Effect Level
Substances
Chemicals
Page 142 of 326

SAFETY DAT A SHEET

product for
This information is based on our current knowledge and is intended to describe the
nts only. It should not therefore be
the purposes of health, safety and environmental requireme
Page 143 of 326

ii
Page 144 of 326
SAFETY DATA SHEET
1910.1200
Product name Shell Rotella TS 10W-30
Product code : 001F8878

PO Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service


GHS Classification
GHS label elements

HEALTH HAZARDS:

Response:
Storage:
Disposal:

Page 145 of 326

SAFETY DATA SHEET
1910.1200

Under normal conditions of use or in a foreseeable emergency, this product does not meet the


53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9.
Alkarvl amine 36878-20-3 1 - 3

Calcium sulphonate 70024-69-0 0.1 - 0.99
@40°C) *
conditions.



Page 146 of 326

SAFETY DATA SHEET
191 1

special treatment

media

gases (smoke).
occurs.


gency procedures


Page 147 of 326

SAFETY DATA SHEET
1910.1200


material.

Storage
place.

tion Limit Values
NS
OSHAZ-1
Page 148 of 326

SAFETY DATA SHEET
ITWA (lnhal- 15mg/m3

able fraction) .
I ACGIH

Monitoring Methods

controls.
product.
nance.
subsequent recycle.

Page 149 of 326

SAFETY DATA SHEET
1910.1200
conditions of use.
Hand protection
work clothes.


Page 150 of 326

SAFETY DATA SHEET
1910.1
c,iw,z,;c'°C''i''"C'l<Cl7"

vapour.
Appearance liquid
Colour Clear amber
pH Not applicable
pour point -51 °C / -60 °FMethod: ASTM 097
range

Method: ASTM 092
Upper explosion limit Typical 1o %M

estimated value(s)
Density 864 kg/m3 (15.0 °C / 59.0 °F)

Method: ASTM 04052
Solubility(ies)

octa nol/wate r

320 °CI 608 °F
Page 151 of 326

SAFETY DATA SHEET
0.1200
Viscosity
Viscosity, kinematic 12.2 mm2/s (100 °C / 212 °F)

Method: ASTM D445

tions


Acute toxicity
Product:

Page 152 of 326

SAFETY DATA SHEET
191
Product:
Product:
Product:
Components:
Calcium sulphonate:
Remarks: May cause an allergic skin reaction in sensitive individuals.
Remarks: Classified Skin Sensitiser Category 1B.
Product:
Carcinogenicity
Product:
Product:

Product:
Page 153 of 326

SAFETY DATA SHEET
1910.1200

Product:
Aspiration toxicity
Product:
Further information
Product:
Remarks: Used oils may contain harmful impurities that have accumulated
during use. The con-
as far as possible.
Remarks: Continuous contact with used engine oils has caused skin cancer
in animal tests.
for this product.
Ecotoxicity
Product:



icity)

ic toxicity)
Page 154 of 326

SAFETY DATA SHEET
191 1200

toxicity)
Product:
ment.
Product:
cumulate.
Mobility in soil
Product:
mobile.

no data available
Product:


Disposal methods

Page 155 of 326

SAFETY DATA SHEET
1910.1200


IATA-DGR
IMDG-Code
productive harm.
Page 156 of 326

SAFETY DATA SHEET
1910.1200
Further information
tivity)

Hygienists
GAS = Chemical Abstracts Service
COG = Cleveland Open-Cup
gy Of Chemicals
Chemical Substances
Inventory
INV = Chinese Chemicals Inventory
LL50 = Lethal Loading fifty ·
Page 157 of 326

SAFETY DATA SHEET
1910.1200

NOEC/NOEL = No Observed Effect Concentration I No Ob-
served Effect Level
Substances
Chemicals
This information is based on our current knowledge and is intende

d to describe the product for
the purposes of health, safety and environmental requirements
only. It should not therefore be
Page 158 of 326

SAFETY DATA SHEET
1910.1200
Product name Shell Spirax S4 TXM
Product code : 00108246

PO Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service


GHS Classification
GHS label elements

HEALTH HAZARDS:

Response:
Storage:
Disposal:

Page 159 of 326

SAFETY DATA SHEET
1910.1200



53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9.
Chem10~[11(:lrriiF
Zinc dialk ldithio 4259-15-8 1 - 2.4
Borated ester 2-hydroxy-4- 84819-41-0 0.1 - 0.9
tetradecyl-1,3,2-
dioxaborolane
40°c *
conditions.



Page 160 of 326

SAFETY DATA SHEET
1910.1200

special treatment

media

gases (smoke).
occurs.


gency procedures


Page 161 of 326

SAFETY DATA SHEET
1910.1200


material.

Storage
place.

Rm~~i:K?;, 9ITIJ~~:~~
~:rn:;,;~~q
}m.~~~:~; -~~~IT~
;;;'.}:::f::j:r!
:c!i' ~,,,,,,~,,
((inhal-
e-
Page 162 of 326

SAFETY DATA SHEET
191
NS
able fraction)
Monitoring Methods
Validated exposure measurement methods should be applied by a competent.person and sam-

controls.
product.
nance.
subsequent recycle.
Page 163 of 326

SAFETY DATA SHEET
1910.1200

conditions of use.
Hand protection
work clothes.


Page 164 of 326

SAFETY DATA SHEET
1910.1200

vapour.
Colour amber
pH Not applicable
pour point -42 °CI -44 °FMethod: ISO 3016
range
Flash point 220 °CI 428 °F

Method: ISO 2592

estimated value(s)
Density 882 kg/m3 (15.0 °C / 59.0 °F)

Method: ISO 12185
Solubility(ies)

octanol/water
Page 165 of 326

SAFETY DATA SHEET
1910.1200

320 °C / 608 °F
Viscosity

Method: ISO 3104
9.4 mm2/s (100 °C / 212 °F)

Method: ISO 3104

tions


Acute toxicity
Page 166 of 326

SAFETY DATA SHEET
1910.1200



Product:
Product:
Components:
Zinc dialkyldithiophosphate:
Remarks: Based on available data, the classification criteria are not met.
Product:
Components:
Borated ester:
Remarks: May cause an allergic skin reaction in sensitive individuals.
Product:
Carcinogenicity
Product:

Page 167 of 326

SAFETY DATA SHEET
1910.1200
ACGIH No component of this product present at levels greater than

or
gen by ACGIH.
OSHA No component of this product present at levels greater than

or
gen by OSHA.
NTP No component of this product present at levels greater than

or
equal to 0.1 % is identified as a known or anticipated carcinog
en
by NTP.
Product:

Product:
Product:
Aspiration toxicity
Product:
Further information
Product:
Remarks: Used oils may contain harmful impurities that have
accumulated during use. The con-
centration of such impurities will depend on use and they may
present risks to health and the
environment on disposal., ALL used oil should be handled with
caution and skin contact avoided
as far as possible.
for this product.
Page 168 of 326

SAFETY DATA SHEET
1910.1200

Ecotoxicity
Product:



icity)

ic toxicity)

toxicity)
Product:
ment.
Product:
cumulate.
Mobility in soil
Product:
mobile.
Page 169 of 326

SAFETY DATA SHEET
1910.1200

no data available
Product:


Disposal methods



IATA-DGR
IMDG-Code
Ship type : Not applicable
Page 170 of 326

SAFETY DATA SHEET
1910.1200




requirements of SARA Title Ill, Section 302.
Clean Water Act

productive harm.
Further information
Page 171 of 326

SAFETY DATA SHEET
1910.1200

tivity)

Hygienists
gy Of Chemicals
Chemical Substances
Inventory
served Effect Level
Page 172 of 326

SAFETY DATA SHEET
1910.1200

Substances
Chemicals
TWA = Time-Weighted Average
Page 173 of 326

Page 174 of 326
SAFETY DAT A SHEET
1910.1200
Product name Shell Spirax S6 ATF A295

PO Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service

Health Information 877-242-7 400

GHS Classification
Skin sensitisation Category 1
Chronic aquatic toxicity Category 3
GHS label elements

Hazard pictograms
Signal word Warning

HEAL TH HAZARDS:
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.

P273 Avoid release to the environment.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P302 + P352 IF ON SKIN: Wash with plenty of water and soap.
P333 + P313 If skin irritation or rash occurs: Get medical advice/
attention.
Page 175 of 326

SAFETY DATA SHEET
1910.1200
Storage:
Disposal:
posal plant.
Hazardous components which must be listed on the label:

Contains triazole derivatives.

Prolonged or repeated skin contact without proper cleaning can clog the
pores of the skin result-

The highly refined mineral oil is only present as additive dilu-
ent.

53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9.


rinsing.

Most important symptoms Skin sensitisation (allergic skin reaction) signs and symptoms
and effects, both acute and may include itching and/or a rash.
Page 176 of 326

SAFETY DATA SHEET
1910.1200
delayed Oil acne/folliculitis signs and symptoms may include formation

of black pustules and spots on the skin of exposed areas.
Ingestion may result in nausea, vomiting and/or diarrhoea.

special treatment

media

gases (smoke).
occurs.


gency procedures


Page 177 of 326

SAFETY DATA SHEET
1910.1200



material.

Storage
Other data Keep container tightly closed and in a cool, well 0 ventilated
place.

Page 178 of 326

SAFETY DATA SHEET
1910.1200
Comp()~ent~ · CAS-Nb, ·Value type Control paratne- . Basis ,..

.. (Fann.of, .. ters / ,Perrnlssible ...
. :··.·
.
.,
. -
.. exposure) concentration.· .
tion)) Limit Values
NS
TWA (Mist) 5 mi:i/m3 OSHA Z-1
able fraction)

Monitoring Methods
lnstitut fur Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA), Germany
http://www. dg uv .de/inhalt/index.jsp

controls.
product.
nance.
Page 179 of 326

SAFETY DATA SHEET
1910.1200
subsequent recycle.

conditions of use.
Hand protection
Eye protection Wear full face shield if splashes are likely to occur.
Skin and body protection Wear chemical resistant gloves/gauntlets and boots. Where
risk of splashing, also wear an apron.
Page 180 of 326

SAFETY DATA SHEET
1910.1200
Protective measures : Personal protective equipment (PPE) should meet recom-


vapour.
Colour red
pH Not applicable
range
Flash point 213°C/415°F

Method: ASTM D92 (COC)

estimated value(s)
Density 840 kg/m3 (15.0 °C / 59.0 °F)

Method: ASTM D287
Page 181 of 326

SAFETY DATA SHEET
1910.1200
Solubility(ies)

octanol/water

320 °CI 608 °F
Viscosity

Method: ASTM 0445
7.3 mm2/s (100 °C / 212 °F)

Method: ASTM 0445

tions

Basis for assessment : Information given is based on data on the components and
Page 182 of 326

SAFETY DATA SHEET
1910.1200


Acute toxicity
Product:
Acute oral toxicity LOSO (rat): > S,000 mg/kg

Acute dermal toxicity LOSO (Rabbit): > S,000 mg/kg

Product:
Product:
Product:
Remarks: Expected to be a skin sensitizer.
Product:
Carcinogenicity
Product:


Page 183 of 326

SAFETY DATA SHEET
1910.1200
gen by ACGIH.
OSHA No component of this product present at levels greater than

or
NTP No component of this product present at levels greater than

or
equal to 0.1 % is identified as a known or anticipated carcinog
en
by NTP.
Product:

Product:
Product:
Aspiration toxicity
Product:
Further information
Product:
Remarks: Used oils may contain harmful impurities that have
accumulated during use. The con-
centration of such impurities will depend on use and they may
present risks to health and the
environment on disposal., ALL used oil should be handled with
caution and skin contact avoided
as far as possible.
for this product.
ponent(s).(LL/EL/ILS0 expressed as the nominal amount of
Page 184 of 326

SAFETY DATA SHEET
1910.1200
Ecotoxicity
Product:
ty) Remarks: Expected to be harmful:
LL/EL/IL50 10-100 mg/I

aquatic invertebrates (Acute Remarks: Expected to be harmful:
toxicity) LL/EL/IL50 10-100 mg/I

icity) Remarks: Expected to be harmful:

icity)

ic toxicity)

toxicity)
Product:
ment.
Product:
cumulate.
Mobility in soil
Product:
mobile.

no data available
Product:
Page 185 of 326

SAFETY DATA SHEET
1910.1200


Disposal methods
courses


Local legislation

IATA-DGR
IMDG-Code
Page 186 of 326

SAFETY DATA SHEET
1910.1200

OSHA Hazards : Sensitiser

:opni~bn~ht ~Q !:calculated productRCi

\. lbs ..? i i .·..... ..·lbs .••.. ........
.
X lene, Mixed Isomers 1330-20-7 100 *

Calculated RQ exceeds reasonably attainable upper limit., Shell classifies this material as an "oil"
under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reporta-
ble under CERCLA., The components with RQs are given for information.
SARA 311/312 Hazards Immediate (Acute) Health Hazard
SARA302 No chemicals in this material are subject to the reporting re-

quirements of SARA Title 111,Section 302.
Clean Water Act

The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table
117.3:
Xylene, mixed isomers 1330-20-7 0.0068 %
diphenylamine 122-39-4
California Prop 65 WARNING: This product contains a chemical known to the

harm.
Page 187 of 326

SAFETY DATA SHEET
1910.1200
Further information
tivity)

Hygienists
gy Of Chemicals
Chemical Substances
Inventory
Page 188 of 326

SAFETY DAT A SHEET
1910.1200

served Effect Level
Substances
Chemicals
Page 189 of 326

Page 190 of 326
SAFETY DAT A SHEET
1
Product name Shell Spirax S6 AXME 80W-140

P.O. Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service


GHS Classification
Chronic aquatic toxicity Category 3
GHS Label element

Hazard pictograms : No symbol

HEALTH HAZARDS:
H412 Harmful to aquatic life with long lasting effects.

P273 Avoid release to the environment.
Response:
Storage:
Disposal:
posal plant.
Page 191 of 326

SAFETY DATA SHEET
1910.1
Chemical nature : Synthetic base oil and additives.
N-phenyl-1-naphthylamine N-phenyl-1- 90-30-2 0.25 - 0.9

na hth !amine
conditions.




special treatment
Suitable extinguishing media Foam, water spray or fog. Dry chemical powder, carbon dio-
xide, sand or earth may be used for small fires only.
Page 192 of 326

SAFETY DATA SHEET
1
media

gases (smoke).
occurs.
Specific extinguishing me- Use extinguishing measures that are appropriate to local cir-
thods cumstances and the surrounding environment.


gency procedures




Page 193 of 326

SAFETY DATA SHEET
1910.1200
material.

Storage
place.


Monitoring Methods
Monitoring of the concentration of substances in the breathing zone of workers or
in the general
workplace may be required to confirm compliance with an OEL and adequacy of
exposure con-
Validated exposure measurement methods should be applied by a competent person
and sam-
Examples of sources of recommended exposure measurement methods are given
below or con-
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical
Methods
Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical
Methods
Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardou
s Substances
L'lnstitut National de Recherche et de Securite, (INRS), France http://www.inrs.fr/ac
cueil
Page 194 of 326

SAFETY DATA SHEET
1910.1200

controls.
Educate and train workers in the hazards and control meas-
ures relevant to normal activities associated with this product.
Drain down system prior to equipment break-in or mainten-
ance.
subsequent recycle.

conditions of use.
Hand protection
Page 195 of 326

SAFETY DATA SHEET
910.1200

work clothes.


vapour.
Colour amber
pH Not applicable
pour point <= -40 °c / <= -40 °FMethod: ASTM D97
range
Page 196 of 326

SAFETY DAT A SHEET
1910.
Method: ASTM 092

estimated value(s)
Relative density 0.894 (15.6 °C / 60.1 °F)
Density 894 kg/m3 (15.6 °C / 60.1 °F)
Solubility(ies)

octanol/water

320 °C / 608 °F
Viscosity

Method: ASTM 0445
30.5 mm2/s (100 °C / 212 °F)

Method: ASTM 0445

tions
Page 197 of 326

SAFETY DATA SHEET
1910.1200



Skin and eye contact are the primary routes of exposure althoug
h exposure may occur following
Acute toxicity
Product:


Product:
Remarks: Expected to be slightly irritating., Prolonged or repeate
d skin contact without proper
cleaning can clog the pores of the skin resulting in disorders such
as oil acne/folliculitis.
Product:
Product:
Components:
N-phenyl-1-naphthylamine:
Remarks: May cause an allergic skin reaction in sensitive individu
als.
Page 198 of 326

SAFETY DAT A SHEET
Product:
Carcinogenicity
Product:


gen by ACGIH.

gen by OSHA.

by NTP.
Product:

Product:
Product:
Aspiration toxicity
Product:
Further information
Page 199 of 326

SAFETY DATA SHEET
1910.1200
as far as possible.
for this product.
Ecotoxicity
Product:
Toxicity to fish (Acute toxic-
ity) Remarks: Expected to be harmful:

Toxicity to algae (Acute toxic-

ity) Remarks: Expected to be harmful:
Toxicity to fish (Chronic toxic- Remarks: Data not available

ity)

ic toxicity)

toxicity)
Components:
N-phenyl-1-naphthylamine:
M-Factor (Acute aquatic tox-
icity)
Product:
Page 200 of 326

SAFETY DATA SHEET
1910.1200
ment.
Product:
cumulate.
Mobility in soil
Product:
mobile.

no data available
Product:
Additional ecological informa- Product is a mixture of non-volatile components, which are not
tion expected to be released to air in any significant quantities.

Disposal methods

Local legislation
Page 201 of 326

SAFETY DATA SHEET
1910.1200

IATA-DGR
IMDG-Code



Section 313.
Clean Water Act

productive harm.
Page 202 of 326

SAFETY DATA SHEET
1

Further information
tivity)
Due to the conversion of this product to GHS classification and labelling, there has been a
significant change to the nature of the information presented in chapter 2.

Hygienists
gy Of Chemicals
Chemical Substances
Inventory
Page 203 of 326

SAFETY DAT A SHEET
1910.1200
IMDG ==International Maritime Dangerous Goods

INV== Chinese Chemicals Inventory
IP346 == Institute of Petroleum test method N° 346 for the
KECI ==Korea Existing Chemicals Inventory
LC50 ==Lethal Concentration fifty
LD50 ==Lethal Dose fifty per cent.
LL/EL/IL== Lethal Loading/Effective Loading/Inhibitory loading
LL50 ==Lethal Loading fifty
MARPOL ==International Convention for the Prevention of
NOEC/NOEL ==No Observed Effect Concentration/ No Ob-
served Effect Level
OE_HPV ==Occupational Exposure - High Production Volume
PBT ==Persistent, Bioaccumulative and Toxic
PICCS ==Philippine Inventory of Chemicals and Chemical
Substances
PNEC ==Predicted No Effect Concentration
REACH ==Registration Evaluation And Authorisation Of
Chemicals
RID ==Regulations Relating to International Carriage of Dan-
SKIN_DES ==Skin Designation
STEL ==Short term exposure limit
TRA ==Targeted Risk Assessment
TSCA ==US Toxic Substances Control Act
TWA== Time-Weighted Average
vPvB ==very Persistent and very Bioaccumulative
This information is based on our current knowledge and is intended to describe

the product for
the purposes of health, safety and environmental requirements only. It should not
therefore be
Page 204 of 326

SAFETY DATA SHEET
1910.1200
Product name Shell Spirax S6 AXRME 75W-90

PO Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service


GHS Classification
GHS label elements
Page 205 of 326

SAFETY DATA SHEET
1910.1200


53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9.
conditions.


rinsing.

Page 206 of 326

SAFETY DATA SHEET
1910.1200

special treatment

media

gases (smoke).
occurs.


gency procedures


Page 207 of 326

SAFETY DAT A SHEET
1910.1200


material.

Storage
place.

''1~1yeJx p:~ ciT

:~fo:'
«::0,~tr
1 p~r~me,
1
1 i
' "(ftc:ir!J
1
of'l , .· t~rs'i BermIsslble ,
,!:lX.i:iiilli§;:,,;iJi:,!
'toon~l';ltitratio,.,"
h,',,
TWA ((inhal- 5 mg/m3
able frac-
Limit Values
Page 208 of 326

SAFETY DATA SHEET
1910.1200

NS
TWA (Mist) 5 mq/m3 OSHA Z-1
able fraction)
Monitoring Methods
National Institute of Occupational Safety and Health {NIOSH), USA: Manual of Analytical Methods

controls.
product.
nance.
subsequent recycle.
Page 209 of 326

SAFETY DAT A SHEET
1910.1200

conditions of use.
Hand protection
work clothes.

Page 210 of 326

SAFETY DATA SHEET
1910.1200

vapour.
Colour amber
pH Not applicable
pour point Method: ASTM 097

Not applicable
range
Flash point 215°C/419°F

Method: ASTM 092 (COG)

estimated value(s)
Density 889 kg/m3 (16 °C / 60 °F)

Method: ASTM 01298
Solubility(ies)
Page 211 of 326

SAFETY DATA SHEET
1910.1200

octanol/water

320 °CI 608 °F
Viscosity

Method: ASTM 0445
15 mm2/s (100 °CI 212 °F)

Method: ASTM 0445

tions

Page 212 of 326

SAFETY DATA SHEET
1910.1200
Acute toxicity
Product:


Product:
Product:
Product:
Components:
II -
Remarks: Experimental data has shown that the concentration of potentially sensitising compo-
nents present in this product does not induce skin sensitisation. May cause an allergic skin reac-
tion in sensitive individuals.
II Remarks: -
May cause an allergic skin reaction in sensitive individuals.
Product:
Carcinogenicity
Product:
Page 213 of 326

SAFETY DATA SHEET
1910.1200


gen by ACGIH.


by NTP.
Product:

Product:
Product:
Aspiration toxicity
Product:
Further information
Product:
as far as possible.
for this product.
Page 214 of 326

SAFETY DATA SHEET
1910.1200

Ecotoxicity
Product:
ty) Remarks: Expected to be harmful:


icity) Remarks: Expected to be harmful:

icity)

ic toxicity)

toxicity)
Components:
M-Factor (Acute aquatic tox-

icity)
Product:
ment.
Product:
cumulate.
Mobility in soil
Product:
Page 215 of 326

SAFETY DATA SHEET
1910.1200

mobile.

no data available
Product:

Disposal methods
courses


Local legislation

Page 216 of 326

SAFETY DATA SHEET
1910.1200
IATA-DGR
IMDG-Code


This material does not contain any components with a CERCLA RO., Shell classifies this material
This material does not contain any components with a section 304 EHS RO.
quirements of SARA Title 111, Section 302.
SARA313 This material does not contain any chemical components with
Clean Water Act

productive harm.
EINECS : All components listed or polymer exempt.
Page 217 of 326

SAFETY DATA SHEET
1910.1200
DSL Notified with Restrictions.
Further information
tivity)

Hygienists
BEL= Biological exposure limits
DIN= Deutsches lnstitut fur Normung
EC= European Commission
gy Of Chemicals
Chemical Substances
Inventory
IATA= International Air Transport Association
Page 218 of 326

SAFETY DATA SHEET
1910.1200

served Effect Level
Substances
Chemicals
Page 219 of 326

Page 220 of 326
SAFETY DATA SHEET
1910.1200
Product name Shell T2 HD 15W-40
Product code 001F8882

PO Box 4427
USA
SOS Request (+1) 877-276-7285
Customer Service


GHS Classification
GHS label elements

HEAL TH HAZARDS:

Response:
Storage:
Disposal:

Page 221 of 326

SAFETY DATA SHEET
1910.1200



53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9.
Chemical name111![t. ·•,,,,.:,,:;:c0~:,,
'$vri~nvms h?'
i:''ii>11'"''i ~"/~iS~-NO
,'':':iii c;~•ir;:!: ii1'!' ••.
. '\\l1:bond~ntratlbnWIJ1Y
Alkvlated phenol ester 12 5643-61-0 1 - 3
Alkarvl amine 36878-20-3 1 - 3
Zinc dialkyldithiophosphate Phosphorodithioic 113706-15-3 1 - 2.4
acid, mixed 0,0-
bis(sec-Bu and iso-
octyl) esters, zinc
salts
@40°C) *
conditions.



Page 222 of 326

SAFETY DATA SHEET
1910.1200

special treatment

media

gases (smoke).
occurs.


gency procedures


Page 223 of 326

SAFETY DATA SHEET
1910.1200


material.

Storage
place.


~=~~
-ontr~Fpar~rt\e:.t
rs;/P~rrn!s~!plJ
Page 224 of 326

SAFETY DATA SHEET
1910.1200 ,r: ,,:··=,·:·.·.·,y,·~:·y.T•oc,·'cc'•'C:••c'·:c,··
••: ' ..,·,··· .....'::"':·,·..,,, ,.. , ...,,,.,,...,,•.
·•·.·,r,·T•,·•··::··· ,.:'-W'Y:T' ··•:·sc;·r

tion)) Limit Values
NS
TWA (Mist) 5 ma/m3 OSHA Z-1
able fraction)

Monitoring Methods

controls.
product.
nance.
subsequent recycle.
Page 225 of 326

SAFETY DATA SHEET
1910.1200


conditions of use.
Hand protection
work clothes.
Page 226 of 326

SAFETY DATA SHEET
1910.1200

vapour.
Appearance liquid
Colour amber
pH Not applicable
pour point -36 °C I -33 °FMethod: ASTM D5950
range
Flash point 237 °C I 459 °F

Method: ASTM D92 (COG)

estimated value(s)
Density 875 kg/m3 (15.0 °C / 59.0 °F)

Method: ASTM D4052
Solubility(ies)
Page 227 of 326

SAFETY DATA SHEET
1910.1200

octanol/water

320 °C / 608 °F
Viscosity
Viscosity, kinematic 15.3 mm2/s (100 °C / 212 °F)

Method: ASTM D445
115.6 mm2/s (40.0 °C / 104.0 °F)

Method: ASTM D445

tions

Page 228 of 326

SAFETY DATA SHEET
1 200
..,.,..,,.".''"'
'"''"""~·,·,,,,,.c,c·,crrc···,···,,,

Acute toxicity
Product:


Product:
Product:
Components:
Zinc dialkyldithiophosphate:
Remarks: Based on available data, the classification criteria are not met.
Product:
Product:
Carcinogenicity
Product:
Page 229 of 326

SAFETY DATA SHEET
1910.1200


gen by ACGIH.

gen by OSHA.

by NTP.
Product:

Product:
Product:
Aspiration toxicity
Product:
Further information
Product:
as far as possible.
Page 230 of 326

SAFETY DATA SHEET
1910.1200 ,C""'"'i'V'''.''''.''CC)CTc~",'.Vi"'C'•'.='0.'"''.'"''C'c'''C':C"'..'"''.W!,\r'.''.''.7r?C"''i
for this product.
Ecotoxicity
Product:



icity)

ic toxicity)

toxicity)
Product:
ment.
Product:
cumulate.
Mobility in soil
Product:
mobile.
Page 231 of 326

SAFETY DATA SHEET
1910.1200

no data available
Product:


Disposal methods
courses


Local legislation

Page 232 of 326

SAFETY DATA SHEET
191 1
IATA-DGR
IMDG-Code
Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea.


6bmporiants \j . QAS-N9:1 CohipMent RQ ..¢alculatecf ptodutfRQ ..
' ,,
;:,,,•i,
.
.,,::
·
...
i . ' ',,'1
'i\ ·. (lbs): •·· \.. ,/(lbs) : \:,!i ••·•
Benzene 71-43-2 10 *
Toluene 108-88-3 1000 *
Toluene 108-88-3 100 *
Toluene 108-88-3 1000 *
Toluene 108-88-3 100 *
Ethylenediamine 107-15-3 5000 *
Fumaric acid 110-17-8 5000 *
Ethylene Glycol 107-21-1 5000 *

Calculated RQ exceeds reasonably attainable upper limit.

Calculated RQ exceeds reasonably attainable upper limit., Shell classifies this material as an "oil"
under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reporta-
ble under CERCLA., The components with RQs are given for information.
Compon~nts •· CAS-Ndl Gohlpqhent RQ Calculated product RQ
. . ... ..... lbs . lbs . .
*
Page 233 of 326

SAFETY DATA SHEET
1910.1200
quirements of SARA Title Ill, Section 302.
SARA 313 The following components are subject to reporting levels es-
tablished by SARA Title Ill, Section 313:
Zinc dialkyldithiophosphate 113706-15-3 1.4486 %
Clean Water Act

The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table
117.3:
Ethylenediamine 107-15-3 0.0144 %
fumaric acid 110-17-8 0.0144 %
toluene 108-88-3 0.0144 %
benzene 71-43-2 0.0144 %
Distillates (petroleum), solvent-dewaxed 64742-65-0
heavy paraffinic
Ethylenediamine 107-15-3
fumaric acid 110-17-8
toluene 108-88-3
benzene 71-43-2
diphenylamine 122-39-4
Ethanediol 107-21-1
Zinc dialkyldithiophosphate 113706-15-3
California Prop 65 WARNING! This product contains a chemical known to the

State of California to cause cancer.
WARNING: This product contains a chemical known to the
harm.
Further information
tivity)
Page 234 of 326

SAFETY DATA SHEET
1910.1200

Hygienists
gy Of Chemicals
Chemical Substances
Inventory
served Effect Level
Substances
Page 235 of 326

SAFETY DATA SHEET
1910.1200

Chemicals
TWA = Time-Weighted Average
Page 236 of 326

SAFETY DATA SHEET
191 200
Product name Shell Tellus S2 MX 46
Product code 001F8439

PO Box4427
USA
SOS Request (+1) 877-276-7285
Customer Service


Recommended use : Hydraulic oil
GHS Classification
GHS label elements

HEALTH HAZARDS:

Response:
Storage:
Disposal:
other hazards which do not result in classification

Page 237 of 326

SAFETY DATA SHEET
1910.1200

High-pressure injection under the skin may cause serious damage including local necrosis.


53-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0,
68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69-
9.
Interchangeable low vis- Not Assigned O - 90

40°c *
conditions.

When using high pressure equipment, injection of product

under the skin can occur. If high pressure injuries occur, the
casualty should be sent immediately to a hospital. Do not wait
for symptoms to develop.
Obtain medical attention even in the absence of apparent
wounds.


Page 238 of 326

SAFETY DATA SHEET
1
Local necrosis is evidenced by delayed onset of pain and
tissue damage a few hours following injection.

special treatment
High pressure injection injuries require prompt surgical inter-

vention an d possibly steroid therapy, to minimise tissue dam-
age and loss of function.
Because entry wounds are small and do not reflect the seri-
ousness of the underlying damage, surgical exploration to
determine the extent of involvement may be necessary. Local
anaesthetics or hot soaks should be avoided because they
can contribute to swelling, vasospasm and ischaemia. Prompt
surgical decompression, debridement and evacuation of for-
eign material should be performed under general anaesthet-
ics, and wide exploration is essential.

media

gases (smoke).
occurs.


genc procedures
============._,,,,.,.=========="""Z'z:-=:l"."l":===
Page 239 of 326
SAFETY DATA SHEET
1910.1200




material.

Storage
place.
Page 240 of 326

SAFETY DATA SHEET
1910.1200


Pohtrol pararne- i
ters/ Permissible ·.·
cot)tenfratioH
tion Limit Values
NS
Monitoring Methods

controls.
Page 241 of 326

SAFETY DATA SHEET
91 200
product.
nance.
subsequent recycle.

conditions of use.
Hand protection
Page 242 of 326

SAFETY DATA SHEET
1910.1200
work clothes.


vapour.
Appearance liquid
Colour clear
pH Not applicable
range

Method: ISO 2592
Upper explosion limit Typical 1O %M

estimated value(s)
Page 243 of 326

SAFETY DATA SHEET
1910.1200
Density 856 kg/m3 (15.0 °C / 59.0 °F)

Method: ISO 12185
Solubility(ies)

octanol/water

320 °C I 608 °F
Viscosity

Method: ASTM 0445
6.9 mm2/s (100 °C / 212 °F)

Method: ASTM 0445
580 mm2/s (O °CI 32 °F)

Method: ASTM 0445

tions
Page 244 of 326

SAFETY DATA SHEET
191 1 ss,.,,,.,·~,·,·,,"FC·•c•7r••··••
,...,,


Acute toxicity
Product:
Acute oral toxicity LOSO (rat): > S,000 mg/kg

Acute dermal toxicity LOSO (Rabbit): > S,000 mg/kg

Product:
Product:
Product:
Product:
Carcinogenicity
Page 245 of 326

SAFETY DATA SHEET
1 0.1200
Product:


gen by ACGIH.

gen by OSHA.

by NTP.
Product:

Product:
Product:
Aspiration toxicity
Product:
Further information
Product:
as far as possible.
Page 246 of 326

SAFETY DATA SHEET
1910.1200
Remarks: High pressure injection of product into the skin may lead to local necrosis if the prod-
uct is not surgically removed.
for this product.
Ecotoxicity
Product:



icity)

ic toxicity)

toxicity)
Product:
ment.
Product:
Page 247 of 326

SAFETY DATA SHEET
1910.1200
cumulate.
Mobility in soil
Product:
mobile.

no data available
Product:


Disposal methods


Page 248 of 326

SAFETY DATA SHEET
1910.1200

IATA-DGR
IMDG-Code



Section 313.
Clean Water Act

productive harm.
EINECS : All components listed or polymer exempt.
Page 249 of 326

SAFETY DATA SHEET
1910.1200
Further information
tivity)

Hygienists
gy Of Chemicals
Chemical Substances
Inventory
Page 250 of 326

SAFETY DATA SHEET
191 200

LOSO = Lethal Dose fifty per cent.
served Effect Level
Substances
Chemicals
Page 251 of 326

Page 252 of 326
Page: 1

Pyroil™ STARTING FLUID Version: 1.0
PYSFR11
29 CFR 1910.1200 (OSHA HazCom 2012)

Product identifier
Trade name Pyroil™
STARTING FLUID
Details of the supplier of the safety data Emergency telephone number

sheet 1-800-ASHLAND (1-800-274-5263)
Ashland
P.O. Box 2219 Regulatory Information Number
Columbus, OH 43216 1-800-325-3751
United States of America
Product Information
614- 790-3333
EHS Customer Requests@ashland.com
GHS Classification
Carcinogenicity Category 2
Reproductive toxicity Category 2
Specific target organ Category 3 (Central nervous system)

exposure
Aspiration hazard Category 1
GHS Label element

Hazard pictograms
Signal Word Danger
Hazard Statements Extremely flammable aerosol.

Suspected of causing cancer.
1122
Page 253 of 326

A'SHLAND:~> Page:2

SAFETY DATA SHEET
Print Date: 7/i 5/2015
Pyroil™ STARTING FLUID Version: 1 .0
PYSFR11
Suspected of damaging fertility or the unborn child.
Precautionary Statements Prevention:

Obtain special instructions before use.
Do not handle until all safety precautions have been read and
understood.
Keep away from heat/sparks/open flames/hot surfaces. - No
smoking.
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
Use only outdoors or in a well-ventilated area.
Wear protective gloves/ protective clothing/ eye protection/ face
protection.
Response:
IF SWALLOWED: Immediately call a POISON CENTER or
doctor/ physician.
IF INHALED: Remove person to fresh air and keep comfortable
for breathing. Call a POISON CENTER or doctor/ physician if
you feel unwell.
IF exposed or concerned: Get medical advice/ attention.
Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Protect from sunlight. Do not expose to temperatures exceeding
50 °C/ 122 °F.
Disposal:
Dispose of contents/ container to an approved waste disposal
plant.
Other hazards
None known.
Substance / Mixture Mixture
Chemical nature Defatter
Chemical Name . CAS~No. Classification Concentration (%)
SOLVENT NAPHTHA 64742-89-8 Flam. Liq. 2; H225 77.53
(PETROLEUM), LIGHT
ALIPHATIC STOT SE 3; H336
Asp.Tex. 1; H304
Aquatic Acute 2; H401
Aquatic Chronic 2;
Page 254 of 326

HLAND~ Page:

SAFETY DATA SHEET
PYSFR11
H411
ETHYL ETHER 60-29-7 Flam. Liq. 1; H224 19.55
Acute Tox. 4; H302
STOT SE 3; H336
n-HEPTANE 142-82-5 Flam. Liq. 2; H225 3.10
Skin lrrit. 2; H315
STOT SE 3; H336
Asp. Tox. 1; H304
CARBON DIOXIDE 124-38-9 Press. Gas Liquefied 2.01

gas; H280
ETHANOL 64-17-5 Flam. Liq. 2; H225 1.17
Eye lrrit. 2A; H319
STOT SE 3; H336
ETHYL CHLORIDE 75-00-3 Flam. Gas 1; H220 0.29
Care. 2; H351
TOLUENE 108-88-3 Flam. Liq. 2; H225 0.13
Skin lrrit. 2; H315
Eye lrrit. 2A; H319
Repr. 2; H361
STOT SE 3; H336
STOT RE 2; H373
3/ 22 ..
Page 255 of 326
Page:4

Pyroil TM STARTING FLUID Version: 1.0
PYSFR11
!Asp.Tox.1; H304
General advice Move out of dangerous area.

Call a POISON CENTRE or doctor/physician if exposed or
you feel unwell.
Symptoms of poisoning may appear several hours later.
Do not leave the victim unattended.
If inhaled Move to fresh air.

If unconscious place in recovery position and seek medical
advice.
Consult a physician after significant exposure.
In case of skin contact Remove contaminated clothing. If irritation develops, get

medical attention.
If on skin, rinse well with water.
Wash contaminated clothing before re-use.
In case of eye contact Flush eyes with water as a precaution.

Remove contact lenses.
If eye irritation persists, consult a specialist.
If swallowed Obtain medical attention.

Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
Most important symptoms Inhalation of high concentrations of this material, as could

and effects, both acute and occur in enclosed spaces or during deliberate abuse, may be
delayed associated with cardiac arrhythmias. Sympathomimetic drugs
may initiate cardiac arrhythmias in persons exposed to this
material.
Signs and symptoms of exposure to this material through

breathing, swallowing, and/or passage of the material through
the skin may include:
stomach or intestinal upset (nausea, vomiting, diarrhea)
irritation (nose, throat, airways)
Cough
loss of appetite
confusion
irregular heartbeat
respiratory failure
Page 256 of 326

A-SHLAND~, Page:5

SAFETY DATA SHEET
PYSFR11

Notes to physician No hazards which require special first aid measures.
Suitable extinguishing media Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Water spray
Foam
Alcohol-resistant foam
Dry chemical
Unsuitable extinguishing High volume water jet

media
Specific hazards during Never use welding or cutting torch on or near drum (even
firefighting empty) because product (even just residue) can ignite
explosively.
Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion Aldehydes

products carbon dioxide and carbon monoxide
organic compounds
Hydrocarbons
formaldehyde-like
Specific extinguishing
methods
Product is compatible with standard fire-fighting agents.
Further information Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment In the event of fire, wear self-contained breathing apparatus.
for firefighters
Personal precautions, Evacuate personnel to safe areas.

protective equipment and Remove all sources of ignition.
5 / 22
Page 257 of 326

.AN
SAFETY DATA SHEET
Page:6

PYSFR11
emergency procedures Use personal protective equipment.

Ensure adequate ventilation.
Persons not wearing protective equipment should be excluded
from area of spill until clean-up has been completed.
Environmental precautions Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for Suppress (knock down) gases/vapours/mists with a water
containment and cleaning up spray jet.
Contain spillage, soak up with non-combustible absorbent
material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and transfer to a container for disposal according to local /
national regulations (see section 13).
Other information Comply with all applicable federal, state, and local regulations.
Suppress (knock down) gases/vapours/mists with a water
spray jet.
Advice on safe handling Open drum carefully as content may be under pressure.
Do not breathe vapours/dust.
Do not smoke.
Container hazardous when empty.
Avoid exposure - obtain special instructions before use.
Avoid contact with skin and eyes.
application area.
regulations.
Container may be opened only under exhaust ventilation
hood.
exposure and temperatures over 50 °C. Do not open by force
red-hot objects.
Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
No smoking.
Electrical installations/ working materials must comply with
Page 258 of 326

.ASHLAND~,
Page:7

SAFETY DATA SHEET
PYSFR11

Components GAS-No, Value type Control Basis
(Form of parameters/
exposure) Permissible
concentration
TOLUENE 108-88-3 TWA 20 oom ACGIH
375 mQ/m3 E
560 mQ/m3 E
TWA 200 ppm OSHA/Z2
Ceiling 300 ppm OSHA/Z2
MAX. CONG 500 ppm OSHA/Z2
SOLVENT NAPHTHA 64742-89-8 TWA 500 ppm OSHA_TRA
(PETROLEUM), LIGHT NS
ALIPHATIC
TWA 300 oom ACGIH
TWA 2,000 mg/m3 OSHA_TRA
NS
TWA 1,370 mg/m3 ACGIH
ETHYL ETHER 60-29-7 TWA 400 oom ACGIH
STEL 500 oom ACGIH
1,200 mQ/m3 NS
TWA 400 ppm TN OEL
1,200 mq/m3
STEL 500 ppm TNOEL
1,500 mQ/m3
n-HEPTANE 142-82-5 REL 85 ppm NIOSH/GUID
350 mQ/m3 E
Ceil_Time 440 ppm NIOSH/GUID
1,800 mQ/m3 E
2,000 mQ/m3 NS
TWA 400 ppm ACGIH
STEL 500 oom ACGIH
CARBON DIOXIDE 124-38-9 TWA 5,000 ppm ACGIH
REL 5,000 ppm NIOSH/GUID
9,000 mg/m3 E
STEL 30,000 ppm NIOSH/GUID
54 000 mq/m3 E
9,000 mg/m3 NS
ETHANOL 64-17-5 REL 1,000 oom NIOSH/GUID
Page 259 of 326

..ASHiL,AND~~ Page:8

Pyroil™ STARTING FLUID
Version: 1.0
PYSFR11
1,900 mQ/m3 E
1,900 mQ/m3 NS
TWA 1,000 ppm Z1A
1,900 mg/m3
ETHYL CHLORIDE 75-00-3 TWA 100 oom ACGIH
2,600 mQ/m3 NS
TWA 1,000 ppm Z1A
2,600 mg/m3
Components CAS-No. Control Biological Samplin Permissible Basis
parameters . specimen g time concentratio
n
TOLUENE 108-88-3 o-Cresol, Creatinine Samplin 0.3 mg/g
with in urine g time:
hydrolysis End of
shift.
Remarks: Background
toluene Urine Samplin 0.03 mg/I
g time:
End of
shift.
toluene Blood Samplin 0.02 mg/I
g time:
Prior to
last shift
of work
week.
Engineering measures Provide sufficient mechanical (general and/or local exhaust)
ventilation to maintain exposure below exposure guidelines (if
applicable) or below levels that cause known, suspected or
apparent adverse effects.

Respiratory protection In the case of vapour formation use a respirator with an
approved filter.
In the case of dust or aerosol formation use respirator with an
approved filter.
A NIOSH-approved air-purifying respirator with an appropriate

cartridge and/or filter may be permissible under certain
circumstances where airborne concentrations are expected to
exceed exposure limits (if applicable) or if overexposure has
otherwise been determined. Protection provided by air-
purifying respirators is limited. Use a positive pressure, air-
supplied respirator if there is any potential for uncontrolled
release, exposure levels are not known or any other
circumstances where an air-purifying respirator may not
provide adequate protection.
Page 260 of 326

Page: 9

PYSFR11
Hand protection
Eye protection Not required under normal conditions of use. Wear splash-
proof safety goggles if material could be misted or splashed
into eyes.
Skin and body protection Wear as appropriate:

impervious clothing
Safety shoes
Flame-resistant clothing
Wear resistant gloves (consult your safety equipment
supplier).
Hygiene measures Wash hands before breaks and at the end of workday.
When using do not eat or drink.
Physical state aerosol
Odour No data available
pH No data available
No data available
Boiling point/boiling range 94.3 °F / 34.6 °C

(1,013.232 hPa)
Calculated Phase Transition Liquid/Gas
Flash point -49 °F / -45 °C
Calculated Flash Point
Flammability (solid, gas) No data available
Upper explosion limit 36.5 %(V)

Lower explosion limit 1.05 %(V)
Vapour pressure 717 .2616 hPa (25 °C)
Calculated Vapor Pressure
Relative density No data available
9 / 22
Page 261 of 326

~HLAND®
SAFETY DATA SHEET
Page: 10

PYSFR1 i
Density 0.7114 g/cm3 (15.56 °C)
Solubility(ies)
Water solubility No data available
Solubility in other solvents No data available

octanol/water
Viscosity
SECTION 10. ST ABILITY AND REACTIVITY
Reactivity No decomposition if stored and applied as directed.
Chemical stability Stable under recommended storage conditions.
Possibility of hazardous Vapours may form explosive mixture with air.

reactions
Conditions to avoid Heat, flames and sparks.
excessive heat
Incompatible materials Acids

Alkali metals
Ammonia
Bases
halogens
inorganic materials
Oxidizing agents
sodium
Sulphur compounds
Hazardous decomposition
products Aldehydes
carbon dioxide and carbon monoxide
formaldehyde-like
Hydrocarbons
organic compounds
Page 262 of 326

Page: 11

PYSFR11
Information on likely routes of Inhalation

exposure Skin contact
Eye Contact
Ingestion
Acute toxicity
Components:
SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC:
Acute oral toxicity LD 50 (Rat): > 8,000 mg/kg

Exposure time: 4 h
Acute dermal toxicity LO 50 (Rat): > 4,000 mg/kg
ETHYL ETHER:
Acute oral toxicity L050 (Rat): 1,200 - 1,700 mg/kg
Acute inhalation toxicity LC 50 (Rat): 32,000 mg/I

Exposure time: 4 h
n-HEPTANE:
Acute oral toxicity LO 50 (Rat): Expected > 5,000 mg/kg
Remarks: Information given is based on data obtained from
similar substances.
Acute inhalation toxicity LC 50 (Rat, male and female): > 29.29 mg/I
Exposure time: 4 h
Assessment: No adverse effect has been observed in acute
inhalation toxicity tests.
Acute dermal toxicity LO 50 (Rabbit): Expected> 2,000 mg/kg

Assessment: Not classified as acutel3/ toxic by dermal
absorption under GHS.
similar substances.
ETHANOL:
Acute oral toxicity LD 50 (Rat): 7,060 mg/kg
Acute inhalation toxicity LC 50 (Rat): 117 - 125 mg/I

Exposure time: 4 h
LC 50 (Mouse): 39 mg/I
Exposure time: 4 h
Acute dermal toxicity LO Lo (Rabbit): 20 g/kg
Page 263 of 326

A4SHLAN
SAFETY
D:® Page: 12
DATA SHEET Revision Date: 05/23/2015

PYSFR11
ETHYL CHLORIDE:
Acute inhalation toxicity LC 50 (Rat): > 19000 ppm
Exposure time: 4 h
TOLUENE:
Acute oral toxicity LD 50 (Rat): > 5,000 mg/kg

Exposure time: 4 h
Acute dermal toxicity LD 50 (Rabbit): 12,124 mg/kg
Product:
Components:
ETHYL ETHER:
n-HEPTANE:
CARBON DIOXIDE:
ETHANOL:
Result: Slightly irritating to skin
ETHYL CHLORIDE:
TOLUENE:

Product:
Remarks: Vapours may cause irritation to the eyes, respiratory system and the skin.
Components:
ETHYL ETHER:
Result: Severely irritating to eyes
Page 264 of 326

HLAND,~ Page: 13

SAFETY DATA SHEET
PYSFR11
n-HEPTANE:
CARBON DIOXIDE:
Result: Not irritating to eyes
ETHANOL:
ETHYL CHLORIDE:
TOLUENE:

Skin sensitisation: Not classified based on available information.
Respiratory sensitisation: Not classified based on available information.
Components:
n-HEPTANE:
Test Type: Maximisation Test (GPMT)
Species: Guinea pig
Result: Did not cause sensitisation on laboratory animals.

Components:
n-HEPTANE:
Genotoxicity in vitro Test Type: Chromosome aberration test in vitro
Test species: rat hepatocytes
Result: negative
Test Type: Ames test

Result: negative
Carcinogenicity
Components:
ETHYL CHLORIDE:
Carcinogenicity - Umited evidence of carcinogenicity in animal studies
Assessment
Components:
TOLUENE:
Reproductive toxicity - Some evidence of adverse effects on sexual function and
Assessment fertility, and/or on development, based on animal experiments.

Page 265 of 326

:HLAND® Page: 14

Print Date: 7/i 5/2015
Version: 1.0
PYSFR11
Components:
ETHYL ETHER:
n-HEPTANE:
ETHANOL:
TOLUENE:
Target Organs: Central nervous system

Components:
TOLUENE:
Target Organs: Neurologic: other (neuropsychological effects, auditory dysfunction and effects
on colour vision)
Assessment: May cause damage to organs through prolonged or repeated exposure.
Aspiration toxicity
Product:
Components:
n-HEPTANE:
TOLUENE:
Further information
Product:
Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting., Concentrations substantially above the TLV value may cause narcotic effects.,
Solvents may degrease the skin.
Components:
ETHYL CHLORIDE:
Remarks: Uver
Carcinogenicity:
Page 266 of 326

Page: 15

PYSFR11
human carcinogen by !ARC.

equal to 0.1 % is identified as a carcinogen or potential
carcinogen by OSHA.

by NTP.
Ecotoxicity
n-HEPTANE:
Toxicity to daphnia and other EC 50 (Water flea (Daphnia magna)): 1.5 mg/I
LC 50 (Mysidopsis bahia (opossum shrimp)): 0,1 mg/I

Exposure time: 96 h
Test Type: semi-static test
Toxicity to daphnia and other NOELR (Water flea (Daphnia magna)): 1 mg/I
(Chronic toxicity) Test Type: static test
Test substance: WAF
similar substances.
Ecotoxicology Assessment
Acute aquatic toxicity Very toxic to aquatic life,
Chronic aquatic toxicity Very toxic to aquatic life with long lasting effects.
ETHANOL:
mykiss)): 12,000 • 16,000 mg/I
Exposure time: 96 h
Toxicity to daphnia and other EC 50 (Water flea (Daphnia magna)): > 10,000 mg/I
ETHYL CHLORIDE:
Toxicity to daphnia and other EC50 (Water flea (Daphnia magna)): 58 mg/I
Method: Directive 67/548/EEC, Annex V, C.2.
15/22
Page 267 of 326

Page: i6
SAFETY DATA SHEET Revision Date: 05/23/20i 5

Print Date: 7/i 5/20i 5
PyroilTM STARTING FLUID Version: i .0
PYSFR11
Toxicity to algae EC50 (Desmodesmus subspicatus (green algae)): 118 mg/I

End point: Growth inhibition
Exposure time: 72 h
Method: Directive 67/548/EEC, Annex V, C.3.
TOLUENE:
Toxicity to fish LC50 (Oncorhynchus kisutch (coho salmon)): 5.5 mg/I
Exposure time: 96 h
TestType: flow-through test
Toxicity to daphnia and other EC50 (Water flea (Ceriodaphnia dubia)): 3.78 mg/I
Remarks: Mortality
Toxicity to algae EC50 (Pseudokirchneriella subcapitata (microalgae)): > 433

mg/I
Exposure time: 96 h
NOEC (Scenedesmus quadricauda (Green algae)): > 400

mg/I
Exposure time: 7 d
Toxicity to fish (Chronic NOEC (Oncorhynchus mykiss (rainbow trout)): i .39 mg/I
toxicity) Exposure time: 40 d
Test Type: flow-through test
Toxicity to daphnia and other NOEC (Water flea (Ceriodaphnia dubia)): 0.74 mg/I
(Chronic toxicity)

n-HEPTANE:
ETHYL CHLORIDE:
Biodegradability lnoculum: activated sludge
Result: Not readily biodegradable.
Biodegradation: O %
Exposure time: 28 d
Method: Directive 67/548/EEC Annex V, C.4.E.
TOLUENE:
ETHYL ETHER:
octanol/water
Page 268 of 326

.ASHLA
SAFETY
ND~ Page: 17
DATA SHEET Revision Date: 05/23/2015

PYSFR11
n-HEPTANE:
octanol/water
ETHANOL:
octanol/wa.ter
ETHYL CHLORIDE:
octanol/water
TOLUENE:
Bioaccumulation Species: Ide, silver or golden orie (Leuciscus ictus)
Bioconcentration factor (BCF): 94
Exposure time: 3 d
Concentration: 0.05 mg/I
Method: Not reported
Partition coefficient n- log Pow: 2.73

octanol/water
Mobility in soil
No data available
No data available
Product:
Additional ecological An environmental hazard cannot be excluded in·the event of
information unprofessional handling or disposal., Toxic.to aquatic lite with
long lasting effects.
SECTION 13. DISPOSALCONSIDERATIONS
Disposal methods
General advice The product should not be allowed to enter drains, water
courses or the soil.
Send to a licensed waste management company.
Dispose of in accordance with all applicable local, state and

federal regulations.

Empty containers should be taken to an approved waste
Do not burn, or use a cutting torch on, the empty drum.
Page 269 of 326

HLAND~o
SAFETY DATA SHEET
Pi:!ge: i 8
Revision Date: 05/23/20i 5

Pyroil™ STARTING FLUID Version: i .0
PYSFRi i
International transport regulations

REGULATION
ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE
CLASS HAZARDS GROUP POLLUTANT/
LTD. QTY.
MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND

WASTES
I UN 1950 Aerosols 2 LIMITED
QUANTITY
INTERNATIONAL AIR TRANSPORT ASSOCIATION· PASSENGER

I UN 1950 Aerosols 2.1 LIMITED
QUANTITY
INTERNATIONAL AIR TRANSPORT ASSOCIATION· CARGO

I UN 1950 Aerosols 2.1 LIMITED
QUANTITY
INTERNATIONAL MARITIME DANGEROUS GOODS

I UN 1950 AEROSOLS 2.1 LIMITED
QUANTITY
TRANSPORT CANADA· INLAND WATERWA VS

QUANTITY
TRANSPORT CANADA· RAIL

QUANTITY
TRANSPORT CANADA· ROAD

UN 1950 AEROSOLS 2.1 MARINE
POLLUTANT:(
ALIPHATIC
PETROLEUM
NAPHTHA)LIM
ITED
QUANTITY
U.S. DOT - INLAND WATERWAYS
Page 270 of 326

Page: 19

PYSFR11
UN 1950 Aerosols, flammable (engine 2.1

starting fluid)
U.S. DOT - RAIL

UN 1950 Aerosols, flammable (engine 2.1
starting fluid)
U.S. DOT - ROAD

IUN 1950 AEROSOLES 2.1
*ORM =ORM-D, CBL =COMBUSTIBLE LIQUID
IMarine pollutant
Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific
exceptions that can be applied. Consult shipping documents for descriptions that are specific to the
shipment. ·

Components• GAS-No. Component RO Calculated product RO
(lbs) (lbs)
ETHYL ETHER 60-29-7 100 511 ;380779
SARA 311/312 Hazards Chronic Health Hazard

Fire Hazard
Acute Health Hazard
Component(s)SARA 313 known GAS numbers that exceed the threshold (De Minimis)

SOLVENT NAPHTHA (PETROLEUM), 64742-89-8 70.00 - 90.00 %
LIGHT ALIPHATIC
ETHYL ETHER 60-29-7 10.00 - 20.00 %
n-HEPTANE 142-82-5 1.00- 5.00 %
CARBON DIOXIDE 124-38-9 1.00 - 5.00 %
ETHANOL 64-17-5 1.00 • 5.00 %
19/22
Page 271 of 326

Page:20

PYSFR11

SOLVENT NAPHTHA (PETROLEUM), 64742-89-8 70.00 • 90.00 %
LIGHT ALIPHATIC
ETHYL ETHER 60-29-7 10.00 - 20.00 %
n-HEPTANE 142-82-5 1.00 • 5.00 %
CARBON DIOXIDE 124-38-9 1.00 • 5.00 %
ETHANOL 64-17-5 1.00- 5.00 %
DISTILLATES (PETROLEUM), 64742-53-6 0.10 -1.00 %

HYDROTREATED LIGHT NAPHTHENIC
TOLUENE 108-88-3 0.10 - 1.00 %
California Prop 65 Proposition 65 warnings are not required for this product
based on the results of a risk assessment.
DSL All components of this product are on the Canadian DSL.
AUSTR On the inventory, or in compliance with the inventory
ENCS Not in compliance with the inventory
KECL On the inventory, or in compliance with the inventory
PIGGS On the inventory, or in compliance with the inventory
IECSC On the Inventory, or in compliance with the inventory
Inventories
AICS (Australia}, DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan}, ISHL
(Japan), KECI (Korea), NZloC (New Zealand), PIGGS (Philippines), TSCA (USA)
Page 272 of 326

·o··------,
~HL
SAFETY DATA SHEET
t';l
Page:2i
Revision Date: 05/23/20i 5

Pyroil™ STARTING FLUID Version: i .0
PYSFRi i
Further information
NFPA: HMIS Ill:

Flammability
2
-s 4
gj
:r
0
D= not significant, 1 =Slight,

Specialhazard. 2 = Moderate, 3 = High
4 = Extreme,*=Chronic
NFPA Flammable and Combustible Liquids Classification

Not applicable
Full text of H-Statements referred to under sections 2 and 3.

H220 Extremely flammable gas.
H224 Extremely flammable liquid and vapor.
H225 Highly flammable liquid and vapor.
H2BO Contains gas under pressure; may explode If heated.
H302 Harmful if swallowed.
H304 May be fatal if swallowed and enters airways.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H336 May cause drowsiness or dizziness.
H35i Suspected of causing cancer.
H361 Suspected of damaging fertility or the unborn child.
H373 May cause damage to organs through prolonged or repeated exposure
if inhaled.
H401 Toxic to aquatic lite.
H411 Toxic to aquatic life with long lasting effects.
Sources of key data used to compil~ the Safety Data Sheet

Ashland internal data including own and sponsored test reports
The UNECE administers regional agreements implementing harmonised classification for labelling
(GHS) and transport.
The information accumulated herein is believed to be accurate but is not warranted to be whether
originating with the company or not. Recipients are advised to confirm in advance of need that the
21/22
Page 273 of 326
Page:22
SAFETY DATA SHEET Revision Date: 05/23/20i 5

Version: i .0
PYSFR11
information is current, applicable, and suitable to their circumstances. This SOS

has been prepared by
Ashland's Environmental Health and Safety Department (i-800-325-3751 ).
List of abbreviations and acronyms that could be, but not necessarily are, used In
this safety data
sheet:
ACGIH : American Conference of Industrial Hygienists
BEi : Biological Exposure Index
CAS : Chemical Abstracts Service (Division of the American Chemical Society).
CMR : Carcinogenic, Mutagenic or Toxic for Reproduction
FG : Food grade
GHS : Globally Harmonized System of Classification and Labeling of Chemicals.
H-statement: Hazard Statement
IATA: International Air Transport Association.
IATA-DGR: Dangerous Goods Regulation by the "International Air Transport Associatio
n" (IATA).
ICAO : International Civil Aviation Organization
!CAO-Tl (ICAO) : Technical Instructions by the "International Civil Aviation Organizati
on"
IMDG : International Maritime Code for Dangerous Goods
ISO : International Organization for Standardization
logPow : octanol-water partition coefficient
LCxx : Lethal Concentration, for xx percent of test population
LDxx : Lethal Dose, for xx percent of test population.
ICxx : Inhibitory Concentration for xx of a substance
Ecxx : Effective Concentration of xx
N.O.S.: Not Otherwise Specified
OECD : Organization for Economic Co-operation and Development
OEL : Occupational Exposure Limit
P-Statement : Precautionary Statement
PBT: Persistent, Bioaccumulative and Toxic
PPE : Personal Protective Equipment
STEL : Short-term exposure limit
STOT : Specific Target Organ Toxicity
TL V : Threshold Limit Value
TWA: Time-weighted average
vPvB : Very Persistent and Very Bioaccumulative
WEL: Workplace Exposure Level
CERCLA : Comprehensive Environmental Response, Compensation, and Liability

Act
DOT : Department of Transportation
FIFRA : Federal Insecticide, Fungicide, and Rodentlcide Act
HMIRC : Hazardous Materials Information Review Commission
HMIS : Hazardous Materials Identification System
NFPA : National Fire Protection Association
NIOSH : National Institute for Occupational Safety and Health
OSHA : Occupational Safety and Health Administration
PMRA : Health Canada Pest Management Regulatory Agency
RTK : Right to Know
WHMIS : Workplace Hazardous Materials Information System
Page 274 of 326

STIHL HP (HIGH PERFORMANCE)2-CYCLEENGINEOIL
Packaged for Stihl Incorporated, 536 Viking Drive, Virginia Beach, VA 23452
W1v11"'1
Safety Data Sheet
Conforms to HCS 2012 (29 CFR 1910,1200)
ISection 1. Identification
Product identifier
Product Name: STIHL HP (High Per1ormance) 2-Cycle Engine Oil
Other names: F3E
Part/Product Number(s): 0781-319-8008, 0781-319-8009, 0781-319-8010, 0781-319-8014, 0781-319-8015, 0781-319-8016,
0781-319-8044, 0781-319-8045, 0781-319-8049, 0781-319-8051, 7010-871-0208, 7010~871-0177
Material Use: 2-cycle engine fuel additive

Uses advised against: Not for use in non-2-cycle engines
10399 Hwy 1 South
Shreveport. LA 71115
1-318-524-1100

Revision date: June 2, 2015
Revision number: 001
Company contact: OMNI EHS Department; E-Maf!: sds@osp.cc; Contact phone: 318-524-1100
CHEMTREC Outside USA and Canada: +1 703-527-3887 (24/7)
!Section 2. Hazards Identification

OSHAJHCS Status: This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29
CFR 1910.1200).
Classification of the substance or Mixture: Not classified
GHS Label Elements
Hazard pictograms:
Signal word: None
Appearance: Blue Physical State: liquid Odor: Petroleum distillates


Page 1 of8
Page 275 of 326

STIHLHP(HIGHPERFORMANCE)
2-CYCLE
ENGINEOil June 2, 2015
Other information: Product diluted with gasoline must be handled with the same precautions used for gasoline. Before
mixing, the Safety Data Sheet for gasoline should be consulted for any precautionary measures
necessary.
ISection 3. Composition/Information on Ingredients

Petroleum mineral oil lubricant base stock with proprietary performance additives mixture.
Comgooents Name CAS number Weight 0{q"
Lubricant Base Oil (Petroleum) Highly refined Various 85-95
mineral oils /C15-C501
2-Cyde Engine Oil Additives Mixture Proprietary 5-15
This product does not contain known hazardous materials at the.:: 1% level or known carcinogens at the::: 0.1% level
as defined
by29 CFR 1910.1200.
' The exact percentage of composition has been withheld as a trade secret.
ISection 4. First Aid Measures

General Advice: No specific first atd measures are required. Get medical attention if irritation develops and
persists.
Eye contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Eyelids
Skin con ta.ct: Wash off immediately with soap and plenty of water while removing all contaminated clothes and
shoes. Get medical attention if irritation or allergic reaction develops and pers\sts.
Inhalation: ln case of inhalation of decomposition products in a fire, symptoms may be delayed. If

surveillance for 48 hours. Get medical attention If symptoms occur.
Ingestion: Do NOT induce vomiting. Drink plenty of waler. If symptoms persist, call a physician.
Protection of first-aiders: No action shall be taken involving any personal risk or without suitable training. Remove all
sources of ignition. Enslire that medical personnel are aware of the material(s) involved, take
Most important symptoms and effects, both acute and delayed

Most Important
Symptoms and Effects: Personnel ,vlt.hpre-existing skin disorders should avoid contact with this product. Under
normal use

Skin contact: Contact with skln is not expected to cause prolonged or significant Irritation. Contact with skin is not
expected to cause an allergic skin response. Not expected lo be harmful to internal organs if
Inhalation: Not expected to be harmful if inhaled. Contains petroleum-based mineral oil. May cause
Ingestion: Not expected to be harmful if swallowed.
Note to physician: Treat symptomatically.
Page 2 of8
Page 276 of 326

STIHLHP (HIGHPERFORMANCE)
2-CYCLEENGINEOIL June 2, 2015
ISection 5. Fire-Fighting Measures

Uniform Fire Code: Class IHB
Flash Point: 222°C (432'F)
Extinguishing Media
Suitable Media: In case of fire, use extinguishing measures that are appropriate to local circumstances and
the surrounding environment. Use water fog, alcohol resistant foam, dry chemical, carbon
Specific Hazards Arising from
the Chemical: Keep product and empty container av,,,ayfrom heat and sources of ignition as product v,,111
burn. Contact with strong oxidizers may cause fire. In lhe event of fire, cool tanks with
water spray. Fire residues and contaminated fire extinguishing water must be contained,
prevented from being discharged to any v,,,ater.vay,sewer or drain and disposed of in
Hazardous Combustion Products: Combustion products may include the following: Carbon dioxide (CO2) Carbon
Protection of Fire Fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident lf
there is a fire. No action shall be taken involving any personal risk or without suitable
training. As in any fire, wear self-contained breathing apparatus pressure-demand,
MSHAJNIOSH (approved or equivalent) and full protective gear.
ISection 6. Accidental Release Measures

For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. ELIMINATE all ignition sources (no smoking, fiares, sparks or flames in
immediate area). Do not touch or walk through spilled material. Put on appropriate
personal protective equipment. Floors may be slippery; use care to avoid falling.
For emergency responders: If specialized clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. Ensure adequate ventilation. Keep
people away from and upwind of spfll/leak. Pay attention to flashback. Take precautionary
measures against static discharges. All equipment used when handling the product must
be grounded. See also the information in "For non-emergency personnel".
Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). See Section 12 for ecological information.
Small Spills: Stop leak if without risk. Move containers from spill area. Absorb with an inert material and place in
an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor.
Large Spills: Stop leak if without risk. Move containers from spill area. Prevent entry into sewers, water courses,
basements or confined areas. Contain and collect spillage with non- combustible, absorbent material
e.g. sand, earth. vermiculfle or diatomaceous earth and place in container for disposal according to
local regulations. Dispose of via a licensed waste disposal contractor.
NOTE: If RO (Reportable Quantity) is exceeded or if spills enter a body of water, report immediately to the USEPA's National
Response Center at (800) 424-8802. Check with your local and state regulators regarding their reporting requirements.
Page 3 of 8
Page 277 of 326

STIHLHP (HIGHPERFORMANCE)2-CYCLEENGINEOil June 2, 2015
ISection 7. Handling and Storage

Precautjons
for safe handling
Protective measures: Eye protection and face shield should be used if material is used under conditions that
increase the chances of splattering. Put on appropriate personal protective equipment
(see Section 8). Keep out of reach of children.
NOTE: Product dlluted with gasoline must be handled with the same precautions used for gasoline. Before mixing, the
Safety Data Sheet for gasoline should be consulted for any precautionary measures necessary.
Advice on general
occupational hygiene: Do not get In eyes, on skin or on clothing. Eating, drinking and smoking should be
prohibited in areas where this material is handled, stored and processed. Wash
thoroughly after handling. Remove contaminated clothing and protective equipment
See also Section 8 for additional information on hygiene measures.
Conditions for safe storage,

Including any incompatibilities: Store in accordance with local regulations. Store in original container protected from
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials,
strong oxidizing agents (see Section 10) and food and drink. Keep away from heat,
sparks, flame. and other sources of ignition (i.e., pilot lights, electric motors and static
electricity). Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Use
appropriate containment to avoid environmental contamination. Avoid contaminating
soil or releases into sewage or drainage systems and bodies of water.
ISection 8. Exposure Controls/Personal

Control parameters
Protection
f
0 ccupa1ona ·ts
IE xposure L'1m1
Chemical name
ACGJH OSHA NIOSH
TLV STEL PEL STEL TWA Ceiling
Lubricant Base Oil (Petroleum) 5 mg/m3 10 mg/m3 5 mg/m3
Hiahlv refined mineral oils /C15-C50l lmlstl {mist) /mist) - - -
Appropriate engineering controls: Good general ventilation should be sufficient to control worker exposure to airborne
Environmental exposure controls: Emissions from ventilation or work process equ!pment should be checked to ensure
they comply with the requirements of environmental protection legistation. ln some
cases, fume scrubbers, fitters or engineering modifications to the process
equipment wiUbe necessary to reduce emissions to acceptable levels.
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products,
before eating, smoking and using the lavatory and at the end of the working
period. Appropriate techniques should be used to remove potentially
contaminated clothing. Wash contaminated clothing before reusing. Ensure that
eyewash stations and safety showers are close to the workstation location.
Eye/Face Protection: Wear safety glasses with side shields. A face shield may be necessary under
some conditions.
Skinand Body Protection
Hand protection: Wear protective gloves if prolonged or repeated contact Is likely. Wear
chemical resistant gloves. Recommended: Nitrile gloves. Consult your supervisor
or Standard Operating Procedure (SOP) for special handling instructions.
Body protection: No protective equipment is needed under normal use conditions. For non-routine
tasks, personal protection equipment for the body should be selected based on the
Page 4 of8
Page 278 of 326

STIHl HP (HIGHPERFORMANCE)2-CYCU:ENGINEOil June 2, 2015
tasl1being performed and the risks involved.
Other skin protection: Appropriate footwear and any additional skin protection measures should be
selected based on the task being performed and the risks involved.
Respiratory protection: No respiratoryprotection is normally required. If user operation generates an oil

mist, determine if airborne concentrations are below the occupational exposure limit
for mineral oil mist. If not, wear an approved respirator that provides adequate
protectionfrom measured concentrations of this material. The correct choice of
respirator in circumstances where air-purifying respiratorsmay not provide
ISection 9. Physical and Chemical Properties

Color: Blue
Odor: Petroleum distillates
pH: Not applicable
Flash Point (Closed cup): 222•c (432°F) {Typical or Target)
Pour Point: -25°C (-13''F) (Typical or Target)
Flammability (solfd, gas): Not applicable. Based on - Physical state
Vapor density (Air= 1): >1
Relative density: 0.8820 - 0.8990 g/1at 15°C (Typical or Target)
Partition coefficient (n-Octanollwater): Nol available
Viscosity- Kinematic (cSt (mm2/s)@40°C): 85 to 100
Viscosity- Kinematic (cSt (mm2/s)@ 100°C):10.3to 12
voe %: <0.026%
ISection 10. Stability and Reactivity Not reactive under normal storage conditions
Reactivity:
Possibility of ha.zardous reactions: None under normal processing.
Hazardous pofymerizati.on: Hazardouspolymerization does not occur.
Incompatible materials: Oxidizing agents, Halogens, Halogenated compounds
Hazardous decomposition products: May include: Fumes, Oil vapors, Smoke, Carbon Oxides (including carbon monoxide
products.
ISection 11. Toxicological Information

Basis for Assessment: Informationgiven is based on product data, a knowledge of the components and the
toxicity of similar products.
Likely Routs of Exposure: Exposure may occur via skin absorption, skin or eye contact, inhalation, ingestion.
Substance/Mixture
Page 5 of8
Page 279 of 326

STIHl HP (HIGH PERFORMANCE)
1-CVCLEENGINEOIL June 2, 2015
Acute Toxlcitv Oral LOSO Dermal LOSO Inhalation LC50
Lubricant Base Oil (Petroleum) >2000 mg/Kg {rat) >2000 mg/Kg (rabbit) >2.18 mg/L (rat) 4h (mist}
C50) Mixture - Typical

Skin Corrosion/Irritation: No known significant effects or critical hazards.
Serious Eye Damage/Irritation: No known significant effects or critical hazards.
Skin Sensi.tization: No known significant effects or critical hazards.
Respiratory Sensitization: No known significant effects or critical hazards.

(Single Exposure) • STOT-SE.: No known significant effects or critical hazards.
Specific Ta.rget Organ Toxicity
(Repeated Exposure)- STOT-RE.: No known significant effects or critical hazards.
Reproductive Toxicity No known significant effects or critical hazards.
Mineral oils are known to cause cancer because of carcinogenic components (e.g. Benzene). The
lubricant base mineral oils
In this product have been highly refined by a variety of processes including severe solvent extraction,
severe hydro cracking
or severe hydro treating to reduce aromatics and improve performance characteristics. The oils in
the is product meets the
IP-346 criteria of less than 3 percent PHA's and are not considered to be a carcinogen by the Internationa
l Agency for
Research on Cancer.
None of the alls in this product requires a cancer warning under the OSHA Hazard Communication
Standard (29 CFR
1910..1200). These oils have not been listed in the National Toxicology Program (NTP} Annual Report
nor have they been
classified by the International Agency for Research on Cancer (tRAC) as: carcinogenic to humans
(Group 1), probably
carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 2B). These oils have
not been classified by
the American Conference of Governmental Industrial Hyglenlsts (ACGIH) as: confirmed human carcinogen
(A 1), suspected
human carcinogen (A2), or confirmed animal carcinogen with unknown relevance to humans (A3).
2-Cycle engine oils mix with gasoline:

2-cycle engine oils diluted with gasoline must be handled with the same precautions used for gasollne.
Before mixing, the
Safety Data Sheet for gasoline should be consulted for any precautionary measures necessary.
ISection 1.2.Ecological Information

The information ls based on data available for the material, the components of the material, and similar
materials.
Ecotoxicity: No testing has been performed by the manufacturer. Ecotoxicity hazard Is based on an evaluation
of data for the
Mobility: Base oil component - Low solubility and floats and is expected to migrate from water
to land. Expected to partition to sediment and wastewater solids.
coefficient (Koc): Not available.

Biodegradation: The material is not expected to be readily biodegradable. The biodegradability of
this material is based on an evaluation of data for the components or a similar
material.
Bioa.ccumulation: This product is not expected to bioaccumulate through food chain in the
environment.
Page 6of8
Page 280 of 326

STIHl HP (HIGH PERFORMANCE)2-CYCLEENGINEOil June 2, 2015
other ecological information: Spills may form a film on waler surfaces causing physical damage to organisms.
ISection 13. Disposal Considerations

Disposal recommendations based on material supplied,
sewer but processed in a suitable effluent treatment plant. Dispose of surplus and non-
environmental protection and waste disposal legislation and any regional locat authority
other information: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
ISection 14. Transport Information

General information: Petroleum Lubricating oil - Nol regulated.
DOT Classification JMDG IATA

Stihl HP 2-C cle Not Re ulated Not Re ulated Not Re ulated
Special precautions for user: Transport \\4thin user's premises: Always transport ln closed containers that are upright and
ISection 15. Regulatory Information

SARA.3111312: Immediate (Acute) Health Effects: No
Fire Hazard: No
SARA 313:
The following components of thls material are found on the EPCRA 313 list:
None
thresholds.
CWA (Clean Water Act): This product does not contain any substances regulated as poflutants pursuant to the
Clean Water Act (40 CFR. 122.21 and 40 CFR 122.42)
substance under the Comprehensive Environmental Response Compensation and Liability
Act (CERCLA) (40 CFR 302).
Page 7 of8
Page 281 of 326

STIHLHP (HIGH PERFORMANCE)2.-CYCLE
ENGINEOil June 2, 2015
State Regulations
Massachusetts: None of the componentsare at or above regulated thresholds.
New Jersey: None of the components are at or above regulated thresholds.
Pennsylvania: None of the componentsare at or above regulated thresholds.
California Proposition 65.: WARNING: This product contains a chemical known to the State of California to cause cancer.
Ethylbenzene- <0.1
Canada
WHMIS Hazard Class: Nol classtfied.

Ail components comply with the following chemical inventory requirements:DSL (Canada}
I Section 16. Other Information

Health Hazard -1
Health Hazard -1
(NFPA& HMISHazardRatingKey:0 - MinimumHazard;1 - SlightHazard;2 - ModerateHazard;3 - High Hazard;4 - Extreme

Hazard;* - ChronicHazardIndicator,& PPE - PersonalProtectiveEquipmentIndexA to L. Thesevaluesare obtainedusingthe
guldelinesor publishedevaluationspreparedby the NationalFireProtectionAssociation(NFPA)or the NationalPaintand Coaling
Association(for HMISor HazardousMaterialIdentificationSystem).
OSHA = Occupational Safety and Health Administration LogPow = logarithm of the octanollwater partition coefficient
ACGIH= American Conference of Industrial Hygienists OEL = Occupational Exposure Limtt
ATE= Acute Toxicity Estimate SOS = Safety Data Sheet
BCF = Bi.oconcentration Factor STEL = Short term exposure Limit
CAS = Chemical Abstracts Service Registry Number UN= United Nations
est= Centistroke (mm2Js) UN Number= United Nations Number, a four digit number
GHS = Global HaTTTionized System of Classification and Labeling assigned by the United Nations Committee of Experts on
Of Chemicals. the Transportation of Dangerous Goods
IBC = lntem1ediate Bulk Container

Revision Date: June 2, 2015
Status: Final
Revision Note: Revision 001 of OSHA GHS SOS format.
Consumer Product Improvement Act of 2008, General Conformity Certification
For Consumer Product Packages: This product has been evaluated and is certifie.d lo be labeled and packaged in compliance with
the appllcable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product
Safety Commission. Where applicable the products that require Child Resistant Closures are packaged in accordance with the Poison
Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. AU closures have
manufacturing is stamped on the product container.
Disclaimer
All reasonably practicablesteps have been taken to ensure the information provided in this Safety Data Sheet is correct lo the
best of our kno-,,1edge,information and belief at the date of its publication.The information given is designed only as guidance
for safe handling, use.,processing, storage, transportation,disposal and release and is no! to be considered a warranty or quality
specificatlon. The informationrelates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text. This Information is furnished upon condition
that the person receiving it shall make their own determinationof the suitability of the material for their particular purpose.

Page 8of8
Page 282 of 326

STIHLPLATINUM BAR & CHAIN Oil
Packaged for Stihl Incorporated, 536 Viking Drive, Virginia Beach, VA 23452
Safety Data Sheet

Conforms to Hes 2012 (29 CFR 1910.1200)
ISection 1. Identification
Product identifier
Product Name: STIHL PLATINUM BAR & CHAIN OIL
Other names: F-4
Part/Product Number(s): 0781-516-5001, 0781-516-5003, 0781-516-5005, 0781-516-5006, 0781-516-5007, 7010-871-181,
7010-871-0211
Material Use: Bar and chain oil, lubricant

Uses advised against: Not for internal engine use.
10399 Hwy 1 South
1-318-524-11 DO

Revision date: June 2, 2015
Company contact: OMNI EHS Department; E-Mail: sds@osp.cc: Contact phone: 318-524-1100
In case of emergency: CHEMTREC: Within USA and Canada: 1 (800) 524-9300 {24n)
CHEMTREC Outside USA and Canada: +1 703-527-3887 (2417
!Section 2. Hazards Identification

OSHA/HCS Status: This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29
CFR 1910.1200).
GHS Classification of the
Substance or Mixture: Not classified
GHS Label Elements

Hazard pictograms: None
Signal word: None

Page 1 of8
Page 283 of 326

STIHLPLATINUMBAR& CHAINOIL June 21 2015
ISection 3. Composition/Information on Ingredients

Petroleum mineral oil lubricant base stock wlth proprietary performance additives mixture.
Com12onents Name CAS number Weight "{rt
Lubricant Base Oil (Petroleum) Highly refined Various 95-99
mineral oils (C15-C50)
Bar & Chain Oil Additive Mixture Proprietary 1-5
Thls product does not contain knovm hazardous mate.rialsat the?:: 1% level or known carcinogens
at the?::0.1% level as defined
by 29 CFR 1910.1200.
' The exact percentage of composition has been \\4thheld as a trade secret.
ISection 4. First Aid Measures .j

General Advice: No specific first aid measures are required. Get medical attention if irritation develops and
persists.
Skin contact: Wash offimmediately with soap and plenty of water white removing all contaminated clothes and
Inhalation: In case of inhalation of decomposition products In a fire, symptoms may be delayed. lf

surveillance for 48 hours. Get medical attention if symptoms occur.
Ingestion: Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician.
Protection offirst-aiders: No action shall be taken involving any personal risk or without suitable training. Remove all
sources of ignition. Ensure that medical personnel are aware of the material(s) involved, take
Most Important
Symptoms and Effects: Personnel with pre-existing skin disorders should avoid contact \/\1ththis
product. Under normal use

Skin contact: Contact with skin is not expected to cause prolonged or significant Irritation. Contact with skin is not
lnha.lation: Not expected to be harmful if inhaled. Contains petroleum-based mineral oil. May cause
Ingest.ion: Not expected to be harmful if swallowed.
Page 2 of8
Page 284 of 326

STIHLPLATINUMBAR&.CHAINOil June 2, 2015
ISection 5. Fire-Fighting Measures

Uniform Fire Code: Class 111B
Flash Point: >93.3°C (>200"F)
Extinguishing Media
Suitable Media: ln case of fire, use extingulshing measures that are appropriate lo local circumstances and
the surrounding environment. Use water fog, alcohol resistant foam, dry chemlcal, carbon
the Chemical: Keep product and empty container away from heat and sources of ignition as product will
burn. Contact with strong oxidizers may cause fire. In the event of fire, cool tanks with
water spray. Fire residues and contaminated fire extinguishing water must be contained,
prevented from being discharged to any waterway, sewer or drain and disposed of in
Protection of Fire Fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident ff
MSHNNIOSH (approved or equivalent) and full protective gear.
ISection 6. Accidental Release Measures

Personal precautions. protective equipment and emergency procedures
entering. ELIMINATE an ignition sources (no smoking, flares, sparks or flames in
immediate area). Do not touch or walk through spilled material. Put on appropriate
personal protective equipment (see Section 8). Floors may be slippery; use care to
avoid falling.
For emergency responders: If specialized clothing ls required to deal with the spillage, take note of any Information
in Section 8 on suitable and unsuitable materials. Ensure adequate ventilation. Take
precautionary measures against static discharges. All equipment used when handling the
product must be grounded. See also the information in "For non-emergency
personnel".
Environmental precautions: Avoid dispersal of spilled material onto soHor into water.vays, drains and sewers.
Inform the relevant authorities if the product has caused environmental pollution
(sewers, waterways, soil or air). See Section 12 for ecological information.
basements or confined areas. Contain and collect spillage with non-combustible, absorbent material
( e.g. sand, earth, vermiculite or diatomaceous earth) and place in container for disposal according to
NOTE: If RQ (Reportable Quantity) is exceeded or if spills enter a body of water, report immediately to the USEPA's National
Page 3 of8
Page 285 of 326

STIHLPLATINUM BAR & CHAIN OIL June 2, 2015
ISection 7. Handling and Storage

Protective measures: Safety glasses ,'.1thside shields. Eye protection and face shield shoutd be used if material
is used under conditions that increase the chances of splattering. Put on appropriate
personal protective equipment (see Section 8). Keep out of reach of children.
Advice on general
occupational hygiene: Do not get in eyes, on skin or on clothing. Eating, drinking and smoking should be
Conditfons for safe storage,
direct sunllght in a dry, cool and welt-ventilated area., away from incompatible materials,
strong oxidizing agents (see Section 10) and food and drink. Keep away from heat,
sparks, flame and other sources of ignition (i.e., ptlot lights, electric motors and static
electricity). Keep container tightly closed and sealed until ready for use. Containers that
have been opened must be carefully resealed and kept upright to prevent leakage. Use
appropriate containment to avoid environmental contamination. Avoid contaminating
soil or releases into sewage or drainage systems and bodies of water.
Bulk material handling: Static Hazard: Electrostatic charge may accumulate and create a hazardous condition
when handling this material. To minimize this hazard, bonding and grounding may be
necessary but may not, by themselves, be sufficient.
ISection 8. Exposure Controls/Personal Protection

Control parameters
Chemical name ACGIH OSHA NIOSH
TLV STEL PEL STEL TWA Ceilinct
Lubricant Base Oil (Petroleum) 5 mg/m3 10 mg/m3 5 mg/m3
HiQhlv refined mineral oils (C15-C50) (mist} /mist) lmistl - - -
Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. ln some
cases, fume scrubbers, fillers or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
lndivjdual protection measures
period. Appropriate techniques should be used lo remove potentially
contaminated clothing. Wash contaminated clothing before reusing.
Eye/Face Protection: Wear safety glasses with side shields. A face shield may be necessary under
some conditions.
Hand protection:' Wear protective gloves if prolonged or repeated contact is likely. Wear
chemical resistant gloves. Recommended: Nitrite gloves. Consult your supervisor
or Standard Operating Procedure (SOP) for special handling instructions.
Body protection: No protective equipment is needed under normal use conditions. For non-routine
tasks, personal protection equipment for the body should be selected based on the
task being performed and the risks involved.
Page 4of8
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STIHl PLATINUM BAR & CHAIN Oil June 2, 2015
Respiratory protection: No respiratory protection is normally required. If user operation generates an oil
mist, determine if airborne concentrations are below the occupationalexposure limit
for mineral oil mist. If not, wear an approved respirator that provides adequate
proteclfon from measured concentrationsof this material. The correct choice of
respirator in circumstances where air-purifying respirators may not provide
ISection 9. Physical and Chemical Properties

Color: Straw colored
Odor: Petroleum like
pH: Not applicable
Flash Point (Closed cup): >93.3',C (>200°F) (Typical or Target)
Vapor density (Air= 1.): >1
Relative density: 0.90 - 0.92 g/1 at 15°C (Typical or Target)
Partition coefficient (n-Octanolfwater): Not available
Viscosity- Kinematic (cSt (mm2/s)@40°C): 120-173
Viscosity- Kinematic (cSt (mm2/s) @100°C):1 o - 12.4
voe%: o%
ISection
Reactivity:
10. Stability and Reactivity
Not reactive under normal storage conditions
Incompatible materials: Oxidizing agents and open flames.
Hazardous decomposition products: May include: Fumes, Oil vapors, Smoke, Carbon Oxides (includlng carbon monoxide
products.
I Section 11. Toxicological Information

Basis for Assessment: rnformationgiven is based on product data, a knowledge of the components and the
toxicity of similar products.
Likely Routs of Exposure: Exposure may occur via skin absorption. skin or eye contact, inhalation, ingestion.
Substance/Mixture
Acute Toxicitv Oral LOSO Dermal LOSO Inhalation LC50
Lubricant Base Oil (Petroleum) >2000 mg/Kg (rat) >2000 mg/Kg (rabbit) >2.18 mg/L (rat) 4h (mist)
C50'! Mixture - Tvoical
Page 5 of8
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STIHL PLATINUM BAR & CHAIN Oil June 2, 2015
Skin. Corrosion/lrritati.on: No known significant effects or critical hazards.

Serious Eye Oamage/lrritati.on: No known significant effects or critical ha.zards.
Skin Sensitization: No known significant effects or critical hazards.
Resp.iratory Sensitization: No known significant effects or critical hazards.
(Single Exposure)• STOT-SE: No known significant effects or critical hazards.
(Repeated Exposure) - STOT-RE: No known significant effects or critical hazards.
Reproductive T'oxiclty No known significant effects or critical hazards.

Mineral oils are known to cause cancer because of carcinogenic components (e.g. Benzene). The lubricant base mineral oils
in this product have been highly refined by a variety of processes including severe solvent extraction, severe hydro cracking
or severe hydro treating to reduce aromatics and Improve performance characteristics. The oils in the is product meets the
IP-346 criteria of less than 3 percent PHA's and are not considered to be a carcinogen by the International Agency for
Research on Cancer.
None of the alls in this product requires a cancer warning under the OSHA Hazard Communication Standard (29 CFR
1910.1200). These oils have not been listed in the National Toxicology Program (NTP) Annual Report nor have they been
classified by the International Agency for Research on Cancer (IRAC) as: carcinogenic to humans (Group 1), probably
carcinogenic to humans (Group 2A), or possibly carcinogenic to humans (Group 28). These oils have not been classified by
the American Conference of Governmental Industrial Hygienists (ACGI H) as: confirmed human carcinogen (A 1), suspected
human carcinogen (A2), or confirmed animal carcinogen with unl<nown relevance to humans (A3).
ISection 12. Ecological Information

The information ts based on data available for the material, the components of the material, and similar materials.
Ecotoxicity: No testing has been performed by the manufacturer. Ecotoxicity hazard is based on an evaluation of data for the
Mobility: Base oil component - Low solubility and floats on water and is expected to mlgrate
from water to land. Expected to partition to sediment and wastewater so!ids.

Biodegradation: The material is not expected to be readily biodegradable. The biodegradability of
this material is based on an evaluation of data for the components or a similar
material.
Bloaccumulation: This product is not expected to bioaccumulate through food chain in the
environment.
other ecological information: Spills may form a film on water surfaces causing physical damage to organisms.
j Section 13. Disposal Considerations

sewer
butprocessed
inasuiJabte
effluent
treatment
plantQjspose
0t surplus
and020-
Page6 ofB
Page 288 of 326

STIHLPLATINUMBAR& CHAINOil June 2, 2015
environmental protection and waste disposal legislation and any regional local authority
Other informaUon: Avoid dispersal of spilled material and runoff and contact wllh soil, waterways, drains and
sewers.
I Section 14. Transport Information

General information: Petroleum Lubricating oil - Not regulated.

Bar & Chain Oil Nol Re ulated NolR ulated Not Re ulated
I Section 15. Regulatory Information

United States Inventory (TSCA Sb): All components are listed or exempted.
SARA 311/312: Immediate (Acute) Health Effects: No

Fire Hazard: No
SARA.313:
None
thresholds ..
CWA !Clean Water Act}: This product does not contain any substances regulated as pollutants pursuant to the Clean
State Regulations
Pennsylvania: None of the components are at or above regulated thresholds.
California Proposition 65: WARNING: This product contains a chemical knovvn to the State of Callfornia lo cause cancer.
None
Canada
WHMIS Hazard Class: Not classified. This Product Is Not Controlled Under WHMlS (Canada)

Page 7 of8
Page 289 of 326

STIHL PLATINUM BAR & CHAIN Ofl June2,2015
ISection 16. Other Information

NFPA Ratin : Health Hazard -1 Flammabiflt - 1 lnstabilit !Reactivit - O
HMIS Ratin : Health Hazard -1 Flammabilit - 1 Ph sical Hazards - 0
(NFPA & HMIS Hazard Rating Key: D - MinimumHazard;1 - Slight Hazard;2 - ModerateHazard;3 - High Hazard;4 - Extreme
Hazard;• - Chronic HazardIndicator,& PPE - PersonalProtectiveEquipmentIndexA to L These valuesare obtainedusing
the
guidelinesor publishedevaluationspreparedby the NationalFire ProtectionAssociation(NFPA)or the NationalPaint and Coating
Association(for HMISor HazardousMaterialIdentificationSystem).
OSHA= OccupationalSafetyand HealthAdministration LogPow = logarithm of the octanol/water partition coefficient
ACGIH=American Conferenceof IndustrialHygienists OEL = OccupationalExposureLimit
ATE = Acute Toxicity Estimate SOS = Safety Dala Sheet
BCF = BiocancentrationFactor STEL = Short term exposureLimit
CAS = ChemicalAbstractsService RegistryNumber UN= United Nations
est = Centlstroke(mm2Js) UN Number= UnitedNationsNumber,a four digit number
GHS = Global HarmonizedSystem of Classificationand Labeling assignedby the United NationsCommitteeof Expertson
Of Chemicals.. the Transportationof DangerousGoods
IATA = InternationalAir TransportAssociation
IBC = IntermediateBulk Container
IMDG= InternationalMaritimeDangerousGoods

Revision Date: June 2, 2015
Status: Final
Revision Note: Revision 001 of OSHA GHS SOS format.
For Consumer Product Packages: This product has been evaluated and is certified to be labeled and packaged
in compliance with
the appHcable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the
Consumer Product
Safety Commission. Where applfcable the products that require Child Resistant Closures are packaged in accordance
with the Poison
Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission.
All closures have
been tested in accordance with the ta.testprotocols. No testi'ng is required to certify compliance with the provisions.
The date of the
manufacturing is stamped on the product container.
Disclaimer
Afl reasonably practicable steps have been taken to ensure the Informationprovided in this Safety Data Sheet is correct lo
the
best of our kn0\\1edge,information and betief al the date of its publication.The information given is designed only as guidance
for safe handling, use, processing,storage, transportation, disposal and release and is not to be considered a v.iarrantyor
quafity
speclficatfon.The information relates only to the specific material designated and may not be valid for such material used
in
combination\\~th any other materials or in any process, unless specified in the text. This information is furnished upon condition
that the person receiving it shall make their own determinationof the suitability of the material for their particular purpose.
Page 8 of8
Page 290 of 326

0 1 REILLY SYNTHETICDOT 3 BRAKEFLUID
ill~ Safety Data Sheet

Conforms to HCS 2012 {29 CFR 1910.1200)
Product identifier
Product Name: O'REILLY SYNTHETIC DOT 3 BRAKE FLUID
Other names: Heavy Duty High Temp Formula Synthetic DOT3 Brake Fluid
Part/Product Number(s): 72105-3, 72120, 72126
Material Use: Automotive brake fluid
Uses advised against: No information available
10399 Hwy 1 South
1-318-524-1100
Issuing date: July 13, 2015

Revision date: July 13, 2015
Company contact: OMNI EHS Department; E-Mail: sds@osp.cc; Contact phone: 318-524-1100
CHEMTREC Outside USA and Canada: +1 703-527-3887 (24/7)
z~:Hazards
iSe~Ubn lde11tificat!6ni·•···
OSHA/HCS Status:
·.
This product is considered hazardous by the 2012 OSHA Hazard Communication Standard (29
·I
CFR 1910.1200).
Classification of the
Substance or Mixture: Serious Eye Damage/Eye Irritation - Category 1
GHS Label Elements

Hazard pictograms:
Signal word: DANGER

Appearance: Clear Physical State: Liquid Odor: Petroleum distillates
Physical Hazard statement: None
Health Hazard statement: Harmful if swallowed.
Causes serious eye damage.
General: Read label before use. Keep out of reach of children. II medical advice is needed, have
product container or label at hand.
Prevention: Wear eye/face protection.

Wear protective gloves/protective clothing/eye protection/face protection
Page 1 of 8
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O'REILLYSYNTHETICDOT 3 BIR.AKE
FLUID July 13, 2015
Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.
Storage: Store locked up.

Disposal: Dispose of contents/container to an approved waste disposal plant.
Hazards not otherwise classified (HNOC): No data available.
Other information: No information available.
Automotive brake fluid and additives mixture.
Substance/mixture· Mixture
Components Name CAS number Weight%*
Triethylene glycol, monobutyl ether 143-22-6 50-60
Diethylene glycol, monobutyl ether 112-34-5 20-30
Triethylene glycol 112-27-6 10-15
• The exact percentage of composition has been withheld as a trade secret.

General Advice: No specific first aid measures are required. Get medical attention if irritation develops and persists.
contact lenses. Get medical attention.
Skin contact: Wash off Immediately with soap and plenty of water while removing all contaminated clothes and
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention immediately If symptoms occur.
Ingestion: If swallowed, do NOT Induce vomiting. Never give anything by mouth to an unconscious person.
Drink plenty of water. Call a POISON GEATER or doctor/physician if symptoms occur.
Protection of first-aiders: No action shall be taken Involving any personal risk or without suitable training. Wear personal
protective clothing (see section 8).
Most Important
Symptoms and Effects: Personnel with pre-existing skin disorders should avoid contact with this product. Under normal use
Eye contact: Causes serious eye irritation. Symptoms may include burning, red eyes and tearing.
Skin contact: Contact with skin is not expected to cause prolonged or significant irritation. Contact with skin is not
Inhalation: May cause respiratory irritation or other pulmonary effects following prolonged or repeated
inhalation of oil mist at airborne levels above the recommended oil mist exposure limit.
Symptoms of respiratory irritation may include coughing and difficult breathing.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Page 2 of 8
Page 292 of 326

O'REILLYSYNTHETICDOT 3 BRAKEFLUID July 13, 2.015
Uniform Fire Code: Combustible liquid

Flash Point: 203°C (397.4°F)
Extinguishing Media
Suitable Media: In case of fire, use extinguishing measures that are appropriate to local circumstances and
the surrounding environment. Use water fog, alcohol resistant foam, dry chemical, carbon
Unsuitable Media: None.

the Chemical: During a fire, smoke may contain the original material in addition to combustion products of
varying composition which may be toxic and/or irritation.
monoxide (CO), and trace amounts of Nitrogen oxides.
Protection of Fire Fighters: Promptly isolate the scene by removing all persons tram the vicinity of the incident if
MSHA/NIOSH (approved or equivalent) and full protective gear.
I
entering. Do not touch or walk through spilled material. Put on appropriate personal
protective equipment. Floors may be slippery; use care to avoid falling.
For emergency responders: If specialized clothing is required to deal with the spillage, take note of any information
in Section 8 on suitable and unsuitable materials. Do not get in eyes. Ensure adequate
ventilation. Keep people away from and upwind of spill/leak. See also the information in
"For non-emergency personnel".
Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air). See Section 12 for ecological information.
basements or confined areas. Contain and collect spillage with non-combustible, absorbent material
e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to
NOTE: If RO (Reportable Quantity) is exceeded or if spills enter a body of water, report immediately to the USEPA's National
Protective measures: Do not get in eyes. Eye protection and face shield should be used. Put on appropriate
Page 3 of 8
Page 293 of 326

O'REILLYSYNTHETICDOT 3 BRAKEFLUID July13, 2015
personal protective equipment (see Section 8). Keep out of reach of children.
Advice on general
occupational hygiene: Do not get in eyes, on skin or on clothing. Eating, drinking and smoking should be
Conditions for safe storage,
direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials,
strong oxidizing agents (see Section 10) and food and drink. Keep container tightly
closed and sealed until ready for use.
1:.seotrt>:n·
a:;exposurecohtro1"$1P~ fson~
otectid l(f>f
rt\',·;<; :>i'.):':~,I
Control parameters
This product does not have any hazardous materials with occupational exposure limits established by region specific
regulatory
bodies.
Nl0$H.··.·,
..··
TWA Ceiling
Triethylene glycol, monobutyl ether
CAS 143-22-6 None listed None listed None listed None listed None listed None listed
Triethylene glycol
Diethylene glycol monobutyl ether
Environmental exposure controls: None specific.

period. Wash contaminated clothing before reusing. Ensure that eyewash
stations and safety showers are close to the workstation location.
Eye/Face Protection: Wear safety glasses with side shields. A face shield and goggles may be
necessary under some conditions,
Hand protection: Wear protective gloves if prolonged or repeated contact is likely. Wear
chemical resistant gloves. Recommended: Butyl rubber, Neoprene,
Nitrile/butadiene rubber (Nitrile or NBR), Polyvinyl chloride ("PVC" or "vinyl").
Consult your supervisor or Standard Operating Procedure (SOP) for special
handling instructions.
Body protection: No protective equipment is needed under normal use conditions, Wear clean body-
covering clothing; For non-routine tasks, personal protection equipment for the
body should be selected based on the task being performed and the risks involved.
Respiratory protection: No respiratory protection is normally required.

Page 4 of 8
Page 294 of 326

O'RIEILLYSYNTHETICDOT 3 BRAKEFLUID July 13, 2015
Color: Clear
Odor: Etheric
pH: 10.5 SUS
Boiling Point: 232.2°C (450°F) (Typical or Target)
Flash Point (Closed cup): 203°C (397.5°F) (Typical or Target)
Evaporation rate (Butyl acetate = 1): Not available
Flammable) Limit in Air: Not available
Vapor density (Air = 1): >1
Relative density: 1.015 kg/I at 15°C (Typical or Target)
Solubility: Completely soluble in water
Partition coefficient (n-Octanol/water): Not available
Viscosity- Kinematic (cSt (mm2/s)@ 40°C): Not available
Viscosity- Dynamic (cSt (mm2/s)@ 100°C): Not available
VOC%: 0% Not a VOC
Reactivity: Not reactive under normal storage conditions

Conditions to avoid: None known based on information supplied.
Incompatible materials: Strong oxidizing agents.
Hazardous decomposition products: May include: Fumes, Smoke, Carbon Oxides (including carbon monoxide and carbon
dioxide) and incomplete combustion products.

I
Product Information
Inhalation: May cause irritation of respiratory tract.
Skin Corrosion/Irritation: May cause skin irritation. Repeated exposure may cause skin dryness or cracking.
Serious Eye Damage/Irritation: Causes serious eye damage.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.
ent Information
-·)..C50Inhalation
= 3480 mg/kg (Rabbit
er = 338 = 2700 m /kg (Rabbit
= 15000 = 22460 m /k (Rabbit)

Skin Sensitization: No information available.
Respiratory Sensitization: No information available.

Single Exposure (STOT-SE): No information available.
Repeated Exposure (STOT-RE): No information available.
Carcinogenicity: Contains no ingredients listed as a carcinogen.
Germ Cell Mutagenicity: No information available.
Reproductive Toxicity No information available.
Page 5 of 8
Page 295 of 326

O'REILLV SYNTHETICDOT 3 BRAKEFLUID July 13, 2015
Symptoms: Eye contact with liquid may cause irritation including stinging, burning, tearing or redness
of the eyes.
The following values are calculated based on chapter 3.1 of the GHS document.
Acute Toxicity Estimate (ATEmix) - Oral: 5191 mg/kg (Category 5)
Acute Toxicity Estimate (ATEmix) • Dermal: 3658 mg/kg (Category 5)
The information is based on data available for the material, the components of the material, and similar materials.
Ecotoxicity: The environmental impact of this product has not been fully investigated
toJ.•'. ty
.·.··\·•.·•·•••·Toxr~j
Microor a'.nismi:;':
Triethylene glycol, monobutyl EC50 72h: >500 mg/L LCSO96h: 2200-4600 mg/L EC50 48h: >500 mg/L
ether (Desmodesmus Static (Leuciscus idus) (Daphnia magna)
subsplcatus) LC 50 96h: ; 2400 mg/L Not available
(Pimephales promelas)
LC50 96h ; 2400 mg/L
Static Plme hales romelas
Triethylene glycol Not available LC50 96h: ""56200-63700 EC50" 850 mg/L 5 min EC50 4Bh: ;42426 mg/L
mg/L flow-through (Daphnia magna)
(Pimephales promelas)
LC50 96h ; 10000 mg/L
Static (Leuclscus
macrochirus)
LC50 96h ; 61 000 mglL flow-
through (Lepomls
macrochirus)
Dlethylene glycol monobutyl EC50 72h: >100 mg/L LC50 96h: ; 1300 mg/L EC50 4Bh:; 2850 mg/L
ether (Desmodesmus Static (Leuclscus Not available (Daphnia magna)
subsplcatus) macrochlrus)
Mobility: No information available.

coefficient (Koc): No information available.

Biodegradation: No information available.
Bioaccumulation: No information available.
Other adverse effects: No information available.
Other ecological information: No information available.

Waste Disposal methods: This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR
Contaminated packaging: Do not re-use empty containers. Empty containers should be taken to an approved waste
Other Information: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers.
General information:
I
Page 6 of 8
Page 296 of 326

O'REILLYSYNTHETICDOT 3 BRAKE FLUID July 13, 2015

Brake Fluid DOT 3 Not Re ulated Not Re ulated Not Re ulated
secure

SARA 311/312: Immediate (Acute) Health Effects: Yes
Fire Hazard: No
SARA 313:
SARA 313 -Threshold

Components Name CAS number Weight%*
Values%
Triethylene alvcol, monobutyl ether 143-22-6 50-60 1.0
Diethylene glycol monobutyl ether 112-34-5 20-30 1.0
CWA (Clean Water Act): This product does not contain any substances regulated as pollutants pursuant to the Clean
State Regulations
Illinois: Triethylene glycol monobutyl ether, Diethylene glycol monobutyl ether,
Pennsylvania: Triethylene glycol monobutyl ether, Diethylene glycol monobutyl ether, Triethylene glycol
Rhode Island: Triethylene glycol
California Proposition 65: WARNING: This product contains a chemical known to the State of California to cause cancer.
None.
Canada
WHMIS Hazard Class: B3 - Combustible liquid

NFPA Ratin : Health Hazard - 2 Flammability - 1 lnstability/Reactivit - 0

HMIS Ratin : Health Hazard - 2 Flammabilit - 1 Ph sical Hazards - 0 PPE- B
(NFPA & HMIS Hazard Rating Key: O - Minimum Hazard; 1 - Slight Hazard; 2 - Moderate Hazard; 3 - High Hazard; 4 - Extreme
Hazard; • - Chronic Hazard Indicator, & PPE - Personal Protective Equipment Index A to L. These values are obtained using the
guidelines or published evaluations prepared by the National Fire Protection Association (NFPA) or the National Paint and Coating
Association (for HMIS or Hazardous Material Identification System).
OSHA= Occupational Safety and Health Administration LogPow = logarithm of the octanol/water partition coefficient
ACGIH= American Conference of Industrial Hygienists OEL = Occupational Exposure Limit
ATE= Acute Toxicity Estimate SDS = Safety Data Sheet
BCF = Bioconcentration Factor STEL = Short term exposure Lim it
GAS= Chemical Abstracts Service Registry Number UN = United Nations
cSt = Centistroke (mm2/s) UN Number= United Nations Number, a four digit number
Page 7 of 8
Page 297 of 326

O'REILLYSYNTHETICDOT 3 BRAKEFLUID July 13, 2015
GHS = Global HarmonizedSystem of Classificationand Labeling assignedby the United Nations Committeeof Experts on
Ot Chemicals. the Transportationof DangerousGoods
IATA = InternationalAir TransportAssociation
!BC= IntermediateBulk Container
IMDG = InternationalMaritime DangerousGoods

Revision Date: July 15, 2015
Status: Final
Revision Note: Revision #001 of the OSHA GHS SOS format.

For Consumer Product Packages: This product has been evaluated and is certified to be labeled and packaged In compliance with
the applicable provisions of the Federal Hazardous Substance Act as stated in 16 CFR 1500 and enforced by the Consumer Product
Safety Commission. Where applicable the products that requ·1reChild Resistant Closures are packaged in accordance with the Poison
Prevention Packaging Act as stated in 16 CFR 1700 and enforced by the Consumer Product Safety Commission. All closures have
manufacturing ls stamped on the product container.
Disclaimer
All reasonably practicable steps have been taken to ensure the information provided in this Safety Data Sheet is correct to the
best of our knowledge, information and belief at the date of its publication. The information given is designed only as guidance
for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality
specification. The information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text. This information is furnished upon condition
that the person receiving it shall make their own determination of the suitability of the material for their particular purpose.
Page 8 of 8
Page 298 of 326

Safety Data Sheet
1 - Identification
Manufacturer: WD-40 Company
Product Name: WD-40 Specialist® Water Resistant Address: 1061 Cudahy Place (92110)
Silicone Lubricant P.O. Box 80607
San Diego, California; USA
Product Use: Cleaner, Lubricant 92138-0607
Telephone:
Restrictions on Use: None identified Emergency only: 1-888-324-7596 (PROSAR)
Information: 1-888-324-7596
SOS Date Of Preparation: 07/18/2014 Chemical Spills: 1-800-424-9300 (Chemtrec)
1-703-527-3887 (International Calls)
2 - Hazards Identification
Hazcom 2012/GHS Classification:
Flammable Aerosol Category 1
Gas Under Pressure: Compressed Gas
Aspiration Toxicity Category 1
r Product
Note: This product is a consumer product and is labeled in accordance with the US Consume
take preceden ce over OSHA Hazard Commun ication labeling. The
Safety Commission regulations which
elements below. The labeling below applies to
0 4>
actual container label will not include the label
industrial/professional products.
La~IElements:~
DANGER!
Extremely Flammable Aerosol.
Contains gas under pressure; may explode if heated.
Prevention
Keep away from heat, sparks, open flames, hot surfaces - No smoking.
Response
vomiting.
IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce
Storage
Store locked up.
in a well-ventilated place.
Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Store
Disposal
s.
Dispose of contents and container in accordance with local and national regulation
3 - Composition /I nformat1on on ngred"

1ents
Ingredient CAS# Weight Percent US Hazcom 2012/ GHS
Classification
LVP Petroleum Solvent 64742-47-8 60-80 Aspiration Toxicity Cateaorv 1
Polv(dimethvlsiloxane) 63148-62-S 1-5 Not Hazardous
Page 1 of 5
Page 299 of 326

Propellant (propane, n-butane) 74-98-6/106-97-8 10-30 Flammable Gas Category 1
Gas Under Pressure,
Compressed Gas
Note: The exact percentages are a trade secret.
4 - First Aid Measures

Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison
control center
or the WD-40 Satety Hotline at 1-888-324-7596 immediately.
Eye Contact: Flush thoroughly with water. Remove contact lenses it present atter the tirst 5 minutes
and
continue tlushing tor several more minutes. Get medical attention it irritation persists.
Skin Contact: Wash with soap and water. It irritation develops and persists, get medical attention.
Inhalation (Breathing): It irritation is experienced, move to fresh air. Get medical attention it irritation
or other
symptoms develop and persist.
Signs and Symptoms of Exposure: Harmtul or fatal is swallowed. If swallowed, may be aspirated
and
cause lung damage. May cause eye and respiratory irritation. Inhalation may cause coughing,
headache and
dizziness. Skin contact may cause drying of the skin.
Indication of Immediate Medical Attention/Special Treatment Needed: Immediate medical
attention is
needed for ingestion.
5 - Fire Fighting Measures

Suitable (and unsuitable} Extinguishing Media: Use water fog, dry chemical, carbon dioxide
or foam. Do
not use water jet or flooding amounts of water. Burning product will float on the surface and spread
fire.
Specific Hazards Arising from the Chemical: Extremely Flammable aerosol. Contents under
pressure.
Keep away from ignition sources and open flames. Exposure of containers to extreme heat and
flames can
cause them to rupture often with violent force. A vapor and air mixture can create an explosion
hazard in
confined spaces. Combustion will produce oxides of carbon, nitrogen and sulfur and hydrocarbo
ns.
Special Protective Equipment and Precautions for Fire-Fighters: Firefighters should always
wear positive
pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers
with
water. Use shielding to protect against bursting containers.
6 - Accidental Release Measures

Personal Precautions, Protective Equipment and Emergency Procedures: Wear appropriate
protective
clothing (see Section 8). Eliminate all sources of ignition and ventilate area.
Methods and Materials for Containment/Cleanup: Leaking cans should be placed in a plastic
bag or open
pail until the pressure has dissipated. Contain and collect liquid with an inert absorbent
and place in a
container for disposal. Clean spill area thoroughly. Report spills to authorities as required.
7 - Handling and Storage

Precautions for Safe Handling: Avoid contact with eyes. Avoid prolonged contact with skin. Avoid
breathing
vapors or aerosols. Use only with adequate ventilation. Keep away from heat, sparks, pilot lights,
hot surfaces
and open flames. Unplug electrical tools, motors and appliances before spraying or bringing the
can near any
source of electricity. Electricity can burn a hole in the can and cause contents to burst into flames.
To avoid
serious burn injury, do not let the can touch battery terminals, electrical connections on motors
or appliances
or any other source of electricity. Wash thoroughly with soap and water after handling. Keep containers
closed when not ·In use. Keep out of the reach of children. Do not puncture, crush or incinerate
containers,
even when empty.
Conditions for Safe Storage: Store in a cool, well-ventilated area, away from incompatible materials
Do not
store above 120°F or in direct sunlight. U.F.C (NFPA 30B) Level 3 Aerosol. Store away from
oxidizers.
8 - Exposure Controls/Personal Protection

Chemical I
LVP Petroleum Solvent j 1200 mg/m3 TWA (manufacturer recommend
ed)
Poly(dimethylsiloxane) I None Established
Page 2 of5
Page 300 of 326

Propane I 1000 ppm TWA OSHA PEL
n-Butane / 1000 ppm STEL ACGIH TLV
The Following Controls are Recommended for Normal Consumer Use of this Product
Appropriate Engineering Controls: Use in a well-ventilated area.
Personal Protection:
Eye Protection: Avoid eye contact. Always spray away from your face.
Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations
where skin contact is likely.
Respiratory Protection: None needed for normal use with adequate ventilation.
For Bulk Processing or Workplace Use the Following Controls are Recommended
Appropriate Engineering Controls: Use adequate general and local exhaust ventilation to maintain
exposure levels below that occupational exposure limits.
Personal Protection:
Eye Protection: Safety goggles recommended where eye contact is possible.
Skin Protection: Wear chemical resistant gloves.
Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are
exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant
type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice.
Work/Hygiene Practices: Wash with soap and water after handling.
9 - Physical and Chemical Properties
Appearance: Colorless liquid Flammable Limits: LEL: 0.6% UEL: 5.0%

(Solvent Portion)
Odor: Mild petroleum odor Vapor Pressure: 0.07 mmHg @25°C
Odor Threshold: Not established Vapor Density: 5.3 (Petroleum Solvent)
pH: Not Appllcable Relative Density: Not Determined
Melting/Freezing Point Not established Solubilities: Insoluble in water
Boiling Point/Range: 221 °C (430°F) Partition Coefficient; n- Not established
octanol/water:
Flash Point: <·30°C (-22°F) (CC Autoignition Not established
ASTM D3828) Temperature:
Evaporation Rate: Not established Decomposition Not established
Temperature:
Flammabilitv (solid, oas) Flammable Aerosol Viscosity: Not established
voe: 20% Pour Point: Not established
10- Stabilitv and Reactivitv

Reactivity: Not reactive under normal conditions
Chemical Stability: Stable
Possibility of Hazardous Reactions: May react with strong oxidizers generating heat.
Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Do not puncture or incinerate
containers.
Incompatible Materials: Strong acids, alkalis, and oxidizers.
Hazardous Decomposition Products: Carbon monoxide and carbon dioxide, oxides of nitrogen and sulfur,
smoke, fumes, and/or unburned hydrocarbons.
11 - Toxicological Information
Symptoms of Overexposure:
Inhalation: Mist or vapor can irritate the throat and lungs. High concentrations may cause nasal and
respiratorytrtitation and central nervous system effects such as headache, dizziness and nausea. Intentional
abuse may be harmful or fatal.
Page 3 of5
Page 301 of 326

Skin Contact: May cause skin irritation with short-term exposure with redness, itching and burning of the
skin. Prolonged and/or repeated contact may produce defatting and dermatitis.
Eye Contact: Contact may be irritating to eyes. May cause redness, stinging, swelling and tearing.
Ingestion: This product has low oral toxicity. If swallowed, this material may cause irritation of the mouth,
throat and esophagus. Swallowing may cause gastrointestinal irritation, nausea, vomiting, diarrhea,
dizziness, drowsiness and other central nervous system effects. This product is an aspiration hazard. If
swallowed, can enter the lungs and may cause chemical pneumonitis, severe lung damage and death.
Chronic Effects: None expected.
Carcinogen Status: None of the components are listed as a carcinogen or suspect carcinogen by IARC,
NTP, ACGIH or OSHA.
Reproductive Toxicity: None of the components is considered a reproductive hazard.
Numerical Measures of Toxicity:

The oral toxicity of this product is estimated to be greater than 5,000 mg/kg and the dermal toxicity greater
than 2,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by
established criteria. It is an aspiration hazard.
12 - Ecological Information
Ecotoxicity: No specific aquatic toxicity data is currently available, however components of this product are
not expected to be harmful to aquatic organisms
Persistence and Degradability: No data available.
Bioaccumulative Potential: Bioaccumulation is not expected based on an assessment of the ingredients.
Mobility in Soil: No data available
Other Adverse Effects: None known
13 - Disposal Considerations
If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous
waste (D001). However, it is the responsibility of the generator to determine at the time of disposal the proper
classification and method of disposal. Do not puncture or incinerate containers, even empty. Dispose in
accordance with federal, state, and local regulations.
14 - Transportation Information
DOT Surface Shipping Description:
UN1950, Aerosols, 2.1 Ltd. Qty (Note: Shipping Papers are not required for Limited Quantities unless
transported by air or vessel - each package must be marked with the Limited Quantity Mark)
IMDG Shipping Description: Un1950, Aerosols, 2.1, LTD QTY
lCAO Shipping Description: UN1950, Aerosols, flammable, 2.1 NOTE: WD-40 does not test aerosol cans to
assure that they meet the pressure and other requirements for transport by air. We do not recommend that
our aerosol products be transported by air.
15 - Regulatory Information
U.S. Federal Regulations:

CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements,
however, oil spills are reportable to the National Response Center under the Clean Water Act and many
states have more stringent release reporting requirements. Report spills required under federal, state and
local regulations.
SARA TITLE Ill:
Hazard Category For Section 311/312: Acute Health, Fire Hazard, Sudden Release of Pressure
Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title Ill
Section 313 Reporting requirements: None
Section 302 Extremely Hazardous Substances (TPQ): None
EPA Toxic Substances Control Act (TSCA) Status: All of the components of this product are listed on the
TSCA inventory.
Page 4 of 5
Page 302 of 326

Page 303 of 326
voe Regulations: This product complies with the consumer product voe limits of CARB, the US EPA and
states adopting the OTC voe rules.
California Safe Drinking Water and Toxic Enforcement Act (Proposition 65): This product does not
contain chemicals regulated under California Proposition 65.
Canadian Environmental Protection Act: One of the components is listed on the NDSL. All of the other
ingredients are listed on the Canadian Domestic Substances List or exempt from n9tification.
Canadian WHMIS Classification: Class A (Compressed Gas), Class B-5 (Flammable Aerosol), Class O-2-B
(Toxic material causing other chronic effects)
This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the
MSDS contains all of the information required by the CPR.
16 - Other Information:
HMIS Hazard Rating:
Health - 1 (slight hazard), Fire Hazard - 4 (severe hazard), Physical Hazard - O (minimal hazard)
Revision Date: July 2014 Supersedes: June 2011
Revision Summary: Convert to Hazcom 2012. Changes in all sections.
Prepared by: Industrial Health & Safety Consultants, Inc. Shelton, CT, USA
APPROVED BY: I. Kowalski
1051200/No.0040902
Page 5 of5
Page 304 of 326

. SEE
SAFELY~·~
Safety Data Sheet
J Section 1: Identification
Product Identifier
Detergent
Product Name
Trade Name: SPLASHOriginal Blue Windshield Wash -20°F

PN (Part number): 234526
Relevant identified uses of the substance or mixture and uses advised against
-Material for industrial applications

-Industrial and professional use
-Consumer end use
Details of the supplier of the safety data sheet
Manufacturer
SPLASHProducts
51 E. Maryland Ave.
St. Paul, MN 55117
Phone: (651) 489-8211

i-80D-535-5053
J Section 2: Hazard(s} Identification
OSHA/Hes status
This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR1910.1200).
Classification of the substance or mixture
Flammable Liquid, Category 3

Acute toxicity, Oral Category 5
Acute toxicity, Inhalation Category 5
Acute toxicity, Dermal Category 5
Specific Target Organ Toxicity {STOT)following single exposure, Category 1
GHS label elements
Hazard pictograms
Signal word-DANGER
Page 1 of 9
Page 305 of 326

Methanol
Hazard statements
Flammable liquid and vapor

May be harmful if swallowed
May be harmful if inhaled
May cause skin irritation
Causes d<Jmageto organs- liver, kidneys, central nervous system and optic nerve
Prevention
Do not breathe mist.

Wear protective gloves/protective clothing/eye protection/face protection.
Take off contaminated clothing and wash before use
Store away from heat and ignition sources
Keep away from oxidizing materials and strong acids
Response
JFSWALLOWED: Do NOTinduce vomiting unless directed to do so by medical personnel. Never give

anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a
physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
IF ONSKIN(or hair): Wash with soap and water. Get medical attention if irritation develops. Cold water may
be used.
IFIN EYES:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty
of water for at least 30 minutes. Cold water may be used. Get medical attention immediately.
lF EXPOSED
or CONCERNED:
Immediately call a POISONCENTER
or a doctor/physician.
Storage
Store in a well-ventilated place.

Disposal
Dispose of contents and container in accordance with all local, regional, national and international
regulations.
Hazards not otherwise classified
Product is stable.
Section 3: Composition/Information on Ingredients
Substance/mixture:Mixture
Chemical name: Methanol
Other means of identification: No
CASnumber/other identifiers
Ingredient name % CASnumber
Methanol 30-32 67-56-1
Section 4: First Aid Measurements
Eye contact: Checkfor and remove any contact lenses. Jn case of contact, immediately flush eyes with plenty of water
for at least 3D minutes. Cold water may be used. Get medical attention immediately.
Inhalation: Bringaccident victims out into the fresh air. Calla physician immediately in severe cases or if recovery is
not rapid.
Page 2 of9
Page 306 of 326

plenty of water. Remove contaminated clothing and
Skin contact: After contact with skin, wash immediately with
wash before reuse.
by medical personnel. Never give anything by mouth to
Ingestion: Do NOTinduce vomiting unless directed to do so
material are swallowed, call a physician immediately. Loosen tight
an unconscious person. If large quantities of this
clothing such as a collar, tie, belt or waistband.
Most important symptoms/effects, acute and delayed

Eye contact
Can cause irritation to eyes and mucous membranes.
Inhalation
Sore throat, shortness of breath, coughing and congestion.
Skin contact
Irritation, itching, dermatitis.
Ingestion
Irritation to mucous membranes.
nt needed, if necessary
Indication of immediate medical attention and special treatme
Notes to physician
and bronchitis.
Exposure may aggravate acute or chronic asthma, emphysema
Specific treatments
N/A
Protection of first-aiders
N/A
See toxicological information (Section 11)
Section 5: Fire Fighting Measures
Extinguishing media
Suitable extinguishing media
foam.
SMALLFIRE:Use DRYchemical powder, CO2 or appropriate
use water jet.
LARGEFIRE:Use water spray, fog or foam. Do not
Unsuitable extinguishing media
None known
Specific hazards arising from the chemical
exposed to heat may explode.
Vapors may travel back to ignition source. Closed containers
ion
Hazardous thermal decomposition products/Products of combust
Products of combustion are carbon oxides (CO, CO2).
Special protective actions for fire fighters
or waterways.
Do not release runoff from fire control methods to sewers
Special protective equipment for fire-fighters
piece
approved self-contained breathing apparatus with full face
In the event of a fire, wear full protective clothing and NIOSH-
mode.
operated in the pressure demand or other positive pressure
Section 6: Accidental Release Measures

For non-erm!rgency personnel
e equipment as specified in Section 8. Isolate hazard area.
Ventilate area of leak or spill. Wear appropriate personal protectiv
l':~p unnecessary and unprotected personnel from entering.
Page 3 of 9
Page 307 of 326

Environmental precautions -
Methods and materials for containment and cleaning up:
Exposure to the spilled material may be s.everely irritating or toxic. Follow personal protective equipment recommendations
found in Section 8 of this SDS. Personal protective equipment needs must be evaluated based on information provided on this
sheet and the special circumstances created by the spill including: the material spilled, the quantity of the spill, the area in
which the spill occurred, and th.e expertise of employees in the area responding to the spill. Never exceed any occupational
exposure limits.
Prevent the spread of any spill to minimize harm to human health and the environment if safe to do so. Wear complete and
proper personal protective equipment following the recommendation of Section 8 at a minimum. Dike with suitable absorbent
material like granulated clay. Gather and store in a sealed container pending a waste disposal evaluation. Shut off ignition
·sources; including electrical equipment and flames. Do not allow smoking in the area.
Sectlon 7: Handling and Storage

Protective measures, advice on general occupational hygiene and conditions for safe storage, including any incompatibilities:
Keep away from heat, sparks, open flames, hot surfaces.
- No smoking.
Keep container tightly closed. Ground or bond container and receiving equipment. Use explosion-proof
electrical/ventilating/lighting, etc. equipment: Use only non-sparking tools. Take precautionary measures against static
discharge. No not breathe dust, fumes, gas, mist, vapors or spray. Wash thoroughly after handling. Do not eat, drink or smoke
when using this product. Wear protective gloves, clothing, and eye and face protection. Keep container tightly closed in a cool,
well-ventilated place. Keep away from oxidizing materials and strong acids.
Store in a well-ventilated area. Keep cool. Keep in an area suitable for flammable liquids.
Section 8: Exposure Controls/Personal Protection
Control parameters
Occupational exposure limits
Ingredient name Exposure limits
Methanol ACGIH OSHA

(TWA) (STEU (TWA) (STEL)
3
200 ppm 250 ppm 200 ppm; 260 mg/m N/A
Appropriate engineering controls and Environmental exposure controls
A system of local and/or general exhaust.is recommended to keep employee exposures below the Airborne Exposure Limits.
Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source,
preventing dispersion of it into the general work area. Please refer to the ACGIHdocument, Industrial Ventilation, A Manual of
Recommended Practices, most recent edition, for details.
Hygiene measures
None
Eye/face protection: Use chemical safety goggles.
Skin protection~
Hand protection and Body protection: Wear impervious protective clothing, including boots, gloves, lab
coat, apron or coveralls, as appropriate, to prevent skin contact.
Other skin protection
Wash hands and other exposed areas with mild soap and water before eating or drinking.
Respiratory protection: No respiratory protection required under normal circumstances.
Respirator Type(s) {NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a
half face piece particulate respirator (NIOSHtype N95 or better filters) may be worn for up to ten times the exposure
Page 4 of 9
Page 308 of 326

limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier,
whichever is lowest. A full face piece particulate respirator (NIOSHtype NlO0 filter) may be worn up to 50 times the
exposure limit, or the maximum.use concentration specified by the appropriate regulatory agency, or respirator
supplier, whichever is lowest. lfoil particles (e.g. lubricants, cutting fluids, Glycerin,etc.) are present, use a NIOSH
type R or P filter. For emergencies or instances where the exposure levels are not known, use a full face piece
positive-pressure, air-supplied respirator. WARNING:Air-purifyingrespirators do not protect workers in Oxygen-
deficient atmospheres.
Section 9: Physical and Chemical Properties
Appearance
Physical state: Blue liquid
Odor: Alcohol
Odor threshold: Not determined
pH: 8.0
Specific Gravity: 0.949
Melting point: -20°C
Boiling point: 87°C
Flash point: 33°C
Evaporation rate (BuAc=l): 2.1
Flammability (solid, gas): Yes
Lower and upper explosive {flammable) limits: LEL 6%, UEL 36%
Vapor pressure: 128 hPa at 20°C
Vapor density (Air-1): 1.11
Solubility: Soluble in water
Partition coefficient: n-octanolfwater: Not Established
Auto-ignition temperature: Not Applicable
Decomposition temperature: Not Established
Viscosity: Not determined
voe%:31
Section 10: Stability and Reactivity
Reactivity
Stable under recommended storage conditions.
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
Will not occur.
Conditions to avoid
Temperatures above the flash point and avoid excessive heat, open flame or other sources of ignition.
Incompatible materials
Strong acids
Strong oxidizing agents
Strong reducing agents
Magnesium
Water-reactive materi°als
Hazardou!i,decomposition products
Page 5 of 9
Page 309 of 326

Will not occur.
Section 11: Toxicological Information
Acute toxicity
Product/ingredient name Test Results

Methanol Acute toxicity, oral (male rat} LOSO=7,300 mg/kg
Acute toxicity, dermal LOSO=lS,800 mg/kg
Acute toxicity, inhalation (rat) LCSORat: 87.S mg/I 6.00 Hours
Summary Comments:
Sensitization
Product/ingredient name Test Results Basis

Methanol No evidence of sensitization effect
Summary Comments:
Carcinogenicity

Methanol No known carcinogenic effects
Summary Comments:
Specific target organ toxicity [single exposure)

Methanol STOT-one-time exposure-oral >5,000 mg/kg
STOT-one-time exposure-dermal >20,000 mg/kg
STOT-one-time exposure-inhalation >20,000 mg/kg
Summary Comments:
Specific target organ toxicity (repeated exposure)

Methanol RfD-oral 0.5 mg/kg Daily Exposure
Summary Comments:
Liver damage when RfDoral ingestion is exceeded daily.
Aspiration hazard

Methanol Human exposure studies Tolerance at 200 ppm/40 hours
Summary Comments:
Information on the likely routes of exposure
Inhalation may blur vision. Ingesting may irritate the gastrointestinal tract.
Eye contact: Irritating to the eyes.

Inhalation: Acute exposure of humans to methanol by inhalation or ingestion may result in visual disturbances, such
as blurred or dimness of vision, leading to blindness. Neurological damage, specifically permanent motor dysfunction,
may also result.
Skin contact: Contact of skin with methanol can produce mild dermatitis in humans.
Ingestion: Tests involving acute exposure of rats, mice, and rabbits have demonstrated methanol to have low acute
toxicity from oral exposure.
Page 6 of9
Page 310 of 326

Symptoms related to the physical, chemical and toxicological characteristics
Eye contact: Eye irritation.
Inhalation: Blurred vision.
Skin contact: Skin irritation.
Ingestion: May irritate the gastrointestinal tract, cause nausea, and vomiting.
Potential chronic health effects (Methanol)
Carcinogenicity: No known carcinogens.
Mutagenicity: No data avai\able.
Teratogenicity: No data available.
Developmental effects: No data available.
Fertility effects: No data available.
Acute toxicity estimates
Toxic by inhalation, in contact with skin and if swallowed. Amounts as small as 30-250 ml of pure methanol may be fatal.
Section 12: Ecological Information

Toxicity
Acute Fish toxicity: (Methanol)
LCS0- Oncorhynchus mykiss (rainbow trout) - 19,000 mg/I - 96 h
LCSD- Lepomis macrochirus (Bluegill)- 15,400 mg/I - 96 h
Acute toxicity for daphnia: (Methanol)
ECSD- Daphnia magna (Water flea) - 24,500 mg/I - 48 h
EClD0- Daphnia magna (Water flea) - 10,000 mg/I - 24 h
Acute toxicity for algae: (Methanol)
ECS0- Scenedesmus capricornutum (fresh water algae) - 22,000 mg/I - 96 h
Acute bacterial toxicity: (Methanol)
No data available.
Ecotoxicology Assessment: (Methanol)
Material is expected to be slightly toxic to aquatic life.
Biodegradability: (Methanol}
When released into the soil, this material is expected to readily biodegrade. When released into water, this material is
expected to readily biodegrade. When released into the air, this material is expected to be readily degraded by reaction with
photochemically produced hydroxyl radicals.
Stability in water: (Methanol)
When released into the soil, this material is expected to quicklyevaporate. When released into the soil, this material is
expected to leach into groundwater.
Photodegradation: (Methanol)
No data available
Volatility (Henry's Law constant): [Methanol)
Partition coefficient n-octanol/water (log K wl= -0.77
0
Bioaccumul'ative potential
Bioaccumulation: (Methanol)
Bioaccumulation Cyprinus carpio (Carp) - 72 d at 20°C
Page 7 of9
Page 311 of 326

Bioconcentration factor (BCF):1.0
Mobility in soil: (Methanol)
Distribution among environmental compartments:

When released into the soil, this material is expected to quicklyevaporate. When released into the soil, this material is
expected to leach into groundwater.
Other adverse effects:
When released into the water, this material is expected to have a half-life between 1 and 10 days. When released into the air,
this materialis expected to exist in the aerosol phase with a short half-life. When released into air, this material is expected to
have a half-life between 10 and 30 days. When released into the air, this material is expected to be readily removed from the
atmosphere by wet deposition.
Section 13: Disposal Considerations
Disposal methods
Dispose in accordance with applicable international, national and local laws, ordinances and statutes.
Section 14: Transport Information
UN Number: N/A
DDT Proper Shipping Name: Limited Quantity, Consumer Commodity, ORM-D
Exemptions: Per 49 CFR173.150 (pg Ill, inner package not over 5.0 L)
Transport hazard Class(es):N/A
Packing Group: N/ A
Land Transport ADR/RID and GGVS/GGVE (Cross Border/ Domestic)

Transport Hazard Class(es):N/A
Maritime Transport IMDG/GGVSea

Transport Hazard Ciass(es):N/A
Marine Pollutant: No
Air Transport ICAO-TI and IATA-DGR

Transport Hazard Ciass(es):N/A
Section 15: Regulatory Information
Chemical Inventory Status-Part 1
Ingredient (CAS#) TSCA .EC Japan Australia
Methanol Yes Yes Yes Yes
{67-56-1)
Chemical Inventory Status-Part 2

Ingredient (CAS#) Korea Canada Canada Philippines
DSL NDSL
Methanol Yes Yes No Yes
(67-56-1)
Federal, State & International Regulations-Part 1

SARA302 SARA313
Ingredient (CAS#) RQ TPQ ListChemical Category
Methanol No No Yes No
{67-56-1)
Federnl, State & International Regulations-Part 2
Page 8 of9
Page 312 of 326

RCRA TSCA
Ingredient {CAS#} CERCLA 261.33 8{d}
Methanol 5000 lb. U154 No
(67-56-1}
Chemical Weapons Convention: No

TSCA 12b: No
CDTA: No
SARA 311/312:
Acute: Yes, Chronic: Yes, Fire: Yes, Pressure: No, Reactivity: No
Mixture/Liquid
Australian Hazchem Code: 2PE
Poison Schedule: No information found
Section 16: Other Information
Date of issue: 12/18/14
Version: la
Revised Sections(s): New
Prepared by: Andrew Gioino, SPLASHPRODUCTS
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor
any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown
hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are
the only hazards that exist.
Page 9 of9
Page 313 of 326

Page 314 of 326
SAFETY DATA SHEET
Version 2.0 Revision Date 02/23/2018 Print Date 03/01/2018
Material name ZEP 45 DUAL FORCE AERO DZ
Material number 000000000000374301

Company Zep Inc.
Address 350 Joe Frank Harris Parkway, SE

Emerson, GA 30137
Telephone 404-352-1680
Emergency telephone numbers
For SDS Information Compliance Services 1-877-428-993 7

For a Medical Emernencv 877-541-2016 Toll Free - All Calls Recorded
For a Transportation CHEMTREC: 800-424-9300 - All Calls Recorded.
Emergency In the District of Columbia 202-483-7616

Recommended use Lubricant
Emergency Overview
Appearance Aerosol containing a compressed gas
Colour amber
GHS Classification
Gases under pressure Compressed gas
GHS label elements
Hazard pictograms
Signal word Danger
Hazard statements H222 Extremely flammable aerosol.

H280 Contains gas under pressure; may explode if heated.

P210 Keep away from heat/sparks/open flames/hot surfaces.
No smoking.
P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or bum, even after
use.
1 / 11
Page 315 of 326
SAFETYDATASHEET
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
P403 Store in a well-\€ntilated place.
Substance/ Mixture Mixture
64742-47-8 >= 50 - < 70

Distillates (petroleum), hydrotreated heaVy 64742-52-5 >=10-<20
naphthenic
Propanol, 1(or 2)-(2-methoxymethylethoxy)-, 88917-22-0 >= 1 - < 5
acetate
carbon dioxide 124-38-9 >= 1 - < 5
The exact percentages of disclosed substances are withheld as trade secrets.
General advice Mo\€ out of dangerous area.

Do not lea\€ the victim unattended.
If inhaled If unconscious, place in reco\€ry position and seek medical

advice.
In case of skin contact If skin irritation persists, call a physician.

Wash off immediately with plenty of water for at least 15
minutes.
If on clothes, remo\€ clothes.
In case of eye contact Remo\€ contact lenses.

Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If in eyes, rinse with water for 15 minutes.
If swallowed Keep respiratory tract clear.

Ne\€r gi\€ anything by mouth to an unconscious person.
DO NOT induce \Omiting unless directed to do so by a
physician or poison control center.
Most important symptoms Effects may be delayed, symptoms may include minor eye or
and effects, both acute and skin irritation.
delayed O\€rexposure may cause mild eye or skin irritation.
Notes to physician Treat symptomaticalty. Symptoms may be delayed.
2111
Page 316 of 326
SAFETY DATA SHEET
Suitable extinguishing media Alcohol-resistant foam

Dry chemical
Unsuitable extinguishing High \Ulume water jet

media
Specific hazards during Do not allow run-off from fire fighting to enter drains or water
firefighting courses.
Hazardous combustion Carbon dioxide (CO2)

products Carbon monoxide
Smoke
Specific extinguishing Use extinguishing measures that are appropriate to local
methods circumstances and the surrounding environment.
Further information For safety reasons in case of fire, cans should be stored
separately in closed containments.
Special protecti'A:l equipment Wear self-contained breathing apparatus for firefighting if

for firefighters necessary.
Personal precautions, Use personal protecti'A:l equipment.

protecti'A:l equipment and Ensure adequate 'A:lntilation.
emergency procedures Remo'A:l all sources of ignition.
Evacuate personnel to safe areas.
Beware of vapours accumulating to form explosi'A:l
Environmental precautions Pre'A:lnt product from entering drains.

Pre'A:lnt further leakage or spillage if safe to do so.
If the product contaminates ri'A:lrs and lakes or drains inform
respecti'A:l authorities.
Methods and materials for Soak up with inert absorbent material (e.g. sand, silica gel,
containment and cleaning up acid binder, uni'A:lrsal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
Advice on safe handling Do not breathe vapours or spray mist.

A\Uid exposure - obtain special instructions before use.
A\Uid contact with skin and eyes.
3/;11
Page 317 of 326
SAFETYDATASHEET
application area.
regulations.
Always replace cap after use.
exposure and temperatures o.er 50 °C. Do not open by force
red-hot objects.
No smoking.
Keep in a dry, cool and well-ventilated place.
Electrical installations / working materials must comply with
Materials to a'vOid Oxidizing agents
,1J>c)~ame
'Permi,
~cm16~ntit1m1.
Distillates (petroleum), 64742-47-8 TWA 500 ppm OSHA Z-1
h drotreated Ii ht 2,000 m /m3
TWA 400 ppm OSHA PO
1,600 m /m3
TWA Mist 5 m /m3 OSHA Z-1
TWA (Mist) 5 mg/m3 OSHA PO
TWA Mist NIOSH REL
ST Mist NIOSH REL
PEL 5 mg/m3 CAL PEL
articulate
Distillates (petroleum), 64742-52-5 TWA (Mist) 5 mg/m3 OSHA Z-1
hydrotreated heaVy naphthenic
TWA 5 mg/m3 ACGIH
(lnhalable
fraction)
carbon dioxide 124-38-9 TWA ACGIH
STEL ACGIH
TWA 5,000 ppm NIOSH REL
9,000 mg/m3
ST 30,000 ppm NIOSH REL
54,000 mg/m3
TWA 5,000 ppm OSHA Z-1
9,000 m /m3
TWA 10,000 ppm OSHA PO
18,000 m /m3
STEL 30,000 ppm OSHA PO
54,000 mg/m3
PEL 5,000 m CAL PEL
Page 318 of 326

SAFETYDATASHEET
9,000 mq/m3
STEL 30,000 ppm CAL PEL
54,000 mq/m3
Engineering measures effective ventilation in all processing areas

Respiratory protection Use respiratory protection unless adequate local exhaust
ventilation is provided or exposure assessment demonstrates
that exposures are within recommended exposure guidelines.
Hand protection
Material Protective gloves
Eye protection Safety glasses
Skin and body protection Impervious clothing

Hygiene measures When using do not eat or drink.

Wash hands before breaks and at the end of workday.
Appearance Aerosol containing a compressed gas
Colour amber
pH Not applicable
Melting point/freezing point Not applicable
Boiling point Not applicable
Flash point
Not applicable
Flammability (solid, gas) Extremely flammable aerosol.
Upper explosion limit No data available

Lower explosion limit No data available
Vapour pressure No data available
5 I 11
Page 319 of 326
SAFETYDATASHEET
Density 0.8715 g/cm3

Solubility(ies)
Water solubility insoluble
octanol/water
Auto-ignition temperature not determined
Viscosity
Heat of combustion > 20 kJ/g
Reactivity Stable
Chemical stability Stable under normal conditions.
Possibility of hazardous Vapours may form explosi.e mixture with air.

reactions No decomposition if stored and applied as directed.
Conditions to av0id Heat, flames and sparks.

Extremes of temperature and direct sunlight.
Incompatible materials Oxidizing agents
Hazardous decomposition Carbon oxides

products
Potential Health Effects
Aggravated Medical None known.

Condition
Symptoms of O.erexposure Effects may be delayed, symptoms may include minor eye or
skin irritation.
Carcinogenicity:
IARC No component of this product present at le.els greater than or
ACGIH No component of this product present at le.els greater than or
equal to 0.1 % is identified as a carcinogen or potential
carcinogen by ACGIH.
Page 320 of 326

SAFETYDATASHEET
OSHA No component of this product present at le\.\'lls greater than or

NTP No component of this product present at le\.\'lls greater than or
by NTP.
Acute toxicity
Product:
Acute dermal toxicity Acute toxicity estimate : 3,754 mg/kg

Method: Calculation method
Components:
Distillates (petroleum), hydrotreated light:
Acute oral toxicity LD50 Rat: > 5,000 mg/kg
Acute inhalation toxicity LC50 Rat: > 4.6 mg/I

Exposure time: 6 h
Acute dermal toxicity LD50 Rat: > 2,000 mg/kg
Distillates (petroleum), hydrotreated heavy naphthenic:

Acute oral toxicity LD50 Rat: > 5,000 mg/kg
Acute inhalation toxicity LC50 Rat: > 5 mg/I

Exposure time: 4 h
Acute dermal toxicity LD50 Rabbit: > 5,000 mg/kg
Product:
Remarks: May cause skin and eye irritation in susceptible persons.

Product:
Remarks: May irritate eyes.

No data available
No data available
Carcinogenicity
No data available
No data available
7 I 11
Page 321 of 326
SAFETY DATA SHEET

No data available

No data available
Aspiration toxicity
No data available
Further information
Product:
Remarks: No data available
Components:
Remarks: No data available
Ecotoxicity
No data available
No data available
Product:
Partition coefficient: n- Remarks: No data available

octanol/water
Mobility in soil
No data available
No data available
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone- CAA Section 602 Class I
Substances
Remarks This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological No data available

information
Page 322 of 326

SAFETYDATASHEET
Components:
Additional ecological : No data available

information
Disposal methods
Waste from residues Do not dispose of waste into sewer.
Dispose of in accordance with local regulations.

Dispose of as unused product.
Do not bum, or use a cutting torch on, the empty drum.
Transportation Regulation: 49 CFR (USA):

ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):

UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited uantit
Transportation Regulation: IATA (Cargo Air):

UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited uantit
Transportation Regulation: IATA (Passenger Air):

UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantit
Transportation Regulation: IDG (Canada):

UN1950, AEROSOLS, FLAMMABLE, 2.1, - Limited quantit
The product as delivered to the customer conforms to packaging requirements for shipment by road
under US Department of Transportation (DOT) regulations. Additional transportation classifications
noted above are for reference only, and not a certification or warranty of the suitability of the packaging
for shipment under these alternative transport regulations.
TSCA list No substances are subject to a Significant New Use Rule.
No substances are subject to TSCA 12(b) export notification

requirements.
Page 323
9/ 11
--·
of 326
---- - -- --
SAFETYDATASHEET
Components CAS-No. Component RO Calculated product RQ

(lbs) (lbs)
naphthalene 91-20-3 100 *
SARA 311/312 Hazards Flammable (gases, aerosols, liquids, or solids)

Gases under pressure

requirements of SARA Title 111,Section 302.
Section 313.
California Prop. 65
WARNING: This product can expose you to chemicals

including naphthalene, which is/are known to the State of
California to cause cancer. For more infonmation go to
www.P65Wamings.ca.gov.
DSL All components of this product are on the Canadian DSL

For infonmation on the country notification status for other regions please contact the
manufacturer's regulatory group.
Inventory Acronym and Validity Area Legend:
TSCA (USA), DSL (Canada), NDSL (Canada)
Page 324 of 326

SAFETYDATASHEET
Further information
NFPA: HMIS Ill:

Flarrrrability
HEALTH - 2
.c :J
[/)
1ij
Ql
6i
2:
FL.AMMABILITY · 4
I
~
2
0 = not significant, 1 =Slight,

Special hazard. 2 = fvbderate, 3 = High
4 = Extrerre, * = Olronic
OSHA - GHS Label Information:
Hazard pictogra1Tl3
Signal word Danger:

Hazard staterrents Extrerrely flammable aerosol. Contains gas under pressure; may explode if heated.
Frecautionary staterrents
Prevention: Keep aw ayfromheatlsparks/open flarres/hot surfaces. No srroking. D:>
not spray on an open flarre or other ignition source. Fressurized container: D:>not
pierce or burn, even after use.
Storage: Frotect from sunlight. D:>not expose to terrperatures exceeding 50 °C/ 122
°F. Store in a well-ventilated place.
Version: 2.0
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Zep Inc. markets products under well recognized and established brand names such as Zep®,
Zep Commercial®,Zep Professional®, Enforcer®, National Chemical™, Selig™, Misty®, Next
Dimension™, Petro®, i-Chem®, TimeMist®, TimeWick™, MicrobeMax®, Country Vet®,
Konk®, Original Bike Spirits®, Blue Coral®, Black Magic®, Rain-X®, Niagara National™, FC
Forward Chemicals®, Rexodan®, Mykal™, and a number of private labeled brands.
Page 325
11 / 11 of 326
Page 326 of 326

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INVENTORY OF HAZARDOUS

3 Shop Supplies - Brake Cleaner

and.oftfiecompaii 1undettakin .· .·'·-.'" \;--:·:\_·;·'.~'\,,,- ·,\f

t.'i.,: :' ·.Pr,pciuct 1r:ientif1er

Use of the substance/mixture : Brake Parts Cleaner

1.4: >''· E;merganc:ytei~bone

GHS04 GHS07 GHSOB

Signal word (GHS-US) Danger

13/02/2015 EN (English US) 1/9

Care. 1B, H350

Symptoms/injuries May cause cancer.

General measures : Remove ignition sources.

6.1.1. For non-emergency personnel

6.1.2. For emergency responders

13/02/2015 EN (EnglishUS) 2/9

USAACGIH ACGIH TWA (mg/m 3 ) 170 mg/m 3

USA ACGIH ACGIH TWA (ppm) 25 ppm

USA ACGIH ACGIH STEL (mg/m') 685 mg/m 3

USA ACGIH ACGIH STEL (ppm) 100 ppm

USA OSHA OSHA PEL (TWA) (ppm) 1_00ppm

USA OSHA OSHA PEL (Ceiling) (ppm) 200 ppm

USAACGIH ACGIH TWA (mgim') 9000 mg/m'

USAACGIH ACGIH TWA (ppm) 5000 ppm

USA ACGIH ACGIH STEL (mgim') 54000

USAACGIH ACGIH STEL (ppm) 30000 ppm

USA OSHA OSHA PEL (TWA) (mg/m 3) 9000 mg/m'

USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm

Hand protection Wear protective gloves.

13/02/2015 EN (English US) 3/9

Physical state Gas

Saturation concentration 127 g/m 3

No additional information available

13/02/2015 EN (English US)

Safety Data Sheet

Acute toxicity Harmful if inhaled. Harmfulif Inhaled.

LD50 oral rat

Specific target organ toxicity (repeated Not classified

Ecology - general Dangerousfor the environment.

LC50 fish 1 4.99 mg/I (96 h; Salmo gairdnerl(Oncorhynchusmykiss); Locomotoreffect)

13/02/2015 EN (English US) 5/9

Biochemical oxygen demand (BOD) 0.06 g 0 2 lg substance

Persistence and degradability Biodegradability: not applicable. Not applicable (gas).

BCF fish 2 25.8 • 77.1 (8 weeks; Cyprinus carpio)

Other information Avoid release to the environment.

13/02/2015 EN (English US)

In accordance with ADR /RID/ IMDG / IATA / ADN

ICAO/IATA (air): UN1950, Aerosols, 2.2, Limited Quantity

IMO/IMDG (water): UN1950, Aerosols, 2.2, Limited Quantity

DOT Packaging Exceptions (49 CFR 173.xxx) 306

Listed on the United States SARA Section 302

EN (English US) 7/9

Safety Data Sheet

Classlfication according to Regulation (EC) No. 1272/2008 [CLP]

Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPDJ

15.2.2. National regulations

U.S. • California • Proposition 65 • Maximum Allowable Dose Levels (MADL)

NFPA health hazard 2 - Intense or continued exposure could cause temporary

HMIS Ill Rating

13/02/2015 EN {English US)

SDS US (GHS HazCom 2012) • TCC

13/02/2015 EN (English US) 9/9

Revision Date: 05/23/2015

29 CFR 1910.1200 (OSHA HazCom 2012)

Recommended use of the chemical and restrictions on use