Professional Documents
Culture Documents
Introduction
1.1 General
In Iraq surface water are facing an increasing problem through the
disposal of pollutants due to the rapid growth of industrial and municipal
activities because of the increasing of population growth as well as the
increase of land drainage due to agricultural activities. Thus, there has been
an increasing concern about the water quality.
Using weighted arithmetic mean (WAM) to assess the water quality for
drinking water of Al-Abbassia branch.
Attention the decision makers about problems of water to control it.
1.4 Methodology
1-Collecting the data from department of standardization and
control(D.S.C,2016).
2-Choise four stations along AL-Abbasia branch.
3-Calculate water quality index by using weighted arithmetic mean
(WAM).
4-Compare the results with standard value.
5-Given the recommendation to the decision maker.
CHAPTER Two
Literature Review
ئ
Layla , 2012 this study was conducted at nine water treatment plants
distributed in four regions (Hilla, Hashemiya, Musayyib and Mahaweel) in
Babylon province in order to study water stability and water quality. Some of
the chemical and physical properties were analyzed, including pH, Turb., Ec,
Temp., Ca+2, Mg+2, Cl-, TH, Alk., SO4-2, Na+, TDS, TSS, K+, Fe+2 and Mn+2.
The samples were collected and analyzed for raw water and drinking water at
all treatment plants for a period of nine months. Water quality index (WQI)
was used to assess water quality. The results showed that the water quality
index (WQI) values ranged between (37.54-55.38) of raw water and (36.95-
55.04) of drinking water, and the worst water quality of raw water and
drinking water was in December.
Saad,2013 used water quality index (WQI) to assess the water quality
of Hemren Lake, Diyala province, using ten water quality parameters ( pH,
electrical conductivity(EC), hardness(TH), total dissolve
solids(TDS),sodium(Na+),calcium(Ca+2),magnesium(Mg+2),potassium(K+),
chloride(Cl-), phosphate) from 2008 to 2010 to evaluate the suitability of
Hemren Lake ecosystem for drinking and irrigation uses. The weighted
arithmetic index method (WAM) was used to calculate the water quality
index (WQI). The results indicated that drinking water quality of Hemren
Lake was good and marginal for the study period according to (WAM),
while the irrigation water quality was good according to (WAM). It was
suggested that monitoring of the lake and application of the WQI were
necessary to evaluate water quality of lakes in Iraq.
Awatif, et. al., 2013 studied the application of water quality index
(WQI) with ten physicochemical water quality parameters to evaluate the
quality of Euphrates River water for drinking usage. This was done by
subjecting the
water samples collected from seven stations within Al-Anbar province
during the period 2004-2010 to comprehensive physicochemical analysis.
The ten physicochemical parameters included: pH, alkalinity (Alk),
orthophosphate (PO4-3), nitrate (NO3-), sulphate (SO4-2), chloride (Cl-), total
hardness (TH), calcium (Ca), magnesium (Mg), and total dissolved solids
(TDS). The average annual overall WQI was found to be 107.59 through the
study period. The high WQI obtained is a result of the high concentrations of
orthophosphate and magnesium which can be attributed to the various human
activities taking place along the River banks. From this analysis the quality
of the Euphrates River is classified as "very poor quality" ranging poor water
at the River upstream near station (E1) and unsuitable for drinking at the
River downstream near station (E7) with an annual minimum WQI of 89.34
in 2008 and maximum 112.44 in 2009.
Atef, 2015 used water quality index method (WQI) to evaluate the
water quality of King Abdullah Canal (KAC). For this purpose, nine
different sampling sites were used in the calculation of WQI during the
period of January to December 2012. The samples were analyzed for various
physico- chemical parameters such as pH, electrical conductivity, total
suspended solids, ions of Sodium, Potassium, Calcium, Magnesium, Fluorite,
Chloride, Sulfate, Bicarbonate, and Nitrate in different seasons (winter,
spring, summer and autumn). The analyzed results (by WQI method) have
been used to suggest models for predicting water quality. The computed
WQI for the nine samples has a range from 46.66 to 542.08. The analysis
reveals that the water quality status of the study area is varying from
excellent to good in the upper part of the canal and from poor to very poor in
the lower part of the canal. Comparing with the World Health Organization
(WHO), the results indicate that the lower part of the canal is polluted.
Therefore, the water is not safe for domestic use and needs further treatment,
especially in the lower part of the canal.
CHAPTER THREE
THEORY
ئ
3.1 Water quality parameters: -
3.1.4 Total Dissolved Solid (TDS, mg/l): - total dissolved solid resulting
from soluble material (inorganic salts) include calcium, magnesium, sodium
and potassium salts of bicarbonate, chloride, sulphate, nitrate and phosphate,
these compound originate from weathering of rock and some of these
compound are added to the water in treatment plants (MWH, 2005). If TDS
levels are high, especially due to dissolved salts, many forms of aquatic life
are affected. Electrical conductivity indicates on the quantity of dissolved
salt in solution.
3.1.5 Chloride (Cl-, mg/l): - chlorides are salts of hydrochloric acid or metal
combined directly with chlorine, it is responsible for brackish taste in water
and it is a key indicator of water quality (Tebbutt, 1998).
3.1.9 Potassium (K+ , mg/l):- Potassium reacts rapidly and intensively with
water, forming a colorless basic solution of potassium hydroxide and
hydrogen gas. Potassium reacts with water more rapidly than sodium
(Wilkes, 2007 (.
3.1.10 Sodium (Na+ ,mg/l):- sodium reacts strongly with water. A colourless
solution formed, consisting of strongly basic sodium hydroxide and
hydrogen gas. A number of sodium ingredients do not react as mightily with
water, but are mightily water soluble (Wilkes, 2007.(
3.1.11 Sulfate (SO4 -2, mg/l): - Sulfate in surface waters results from the
weathering of gypsum and anhydrite or from the oxidation of sulfuric
compounds. It may result also from the industrial effluents, drainage water,
and ground water (Jamil, et at.,1984).
3.1.12 Total suspended solids (TSS, mg/l): - the most visible indicators of
water quality. These suspended particles can come from soil erosion, runoff,
discharges, stirred bottom sediments or algal blooms.
The particles that are larger than 2 microns found in the water column is
considered a total suspended solid. Most suspended solids are made up of
inorganic materials, also bacteria and algae can also contribute to the total
solids concentration.
Total suspended solids as a measurement of mass are reported in milligrams
of solids per liter water (mg/l). The most accurate method of determining
TSS is by filtering and weighing a water sample (Wetzel, R.G,2001).
3.2 Standards: -
Water quality standard for drinking water was taken from world health
organization (WHO) where gives a range of values for each parameter.
The water quality index was calculated using the assigned weighted
arithmetic index method. The important physicochemical parameters were
used with respect to their suitability for human consumption and availability
of data from each station. These parameters were compared with the
permissible values for drinking water quality that recommended by the
Standards based on the formula to calculate WQI proposed by (Tiwari and
Mishra ,1985):
𝑤 =𝐾
∑𝐾 …………. (3-1)
𝑖
Where: -
wi = Unit weight factor;
K = proportional constant
The quality rating scale (qi) is a number reflecting the relative value of
this parameter in the polluted water with respect to its standard permissible
value and is determined as follows:
𝑞𝑖 = (𝑉𝑖−𝑉10)
∗ 100 ……………. (3-2)
𝑆𝑖−𝑉10
Where:
qi= quality rating scale for the ith water quality parameter.
Vi= estimate permissible value of the ith parameter.
V10= Ideal value of the ith parameter pure water.
Si = standard permissible value of ith parameter.
The ideal values for all parameters (V10) = 0 except for pH (V10) = 7
𝑖=𝑛
Overall WQI = ∑ 𝑤𝑖 ∗ 𝑞𝑖 ………….. (3-3)
𝑖=1
Study area
ئ
Length of the Al-Abbasai river about 28km from point of branching and
extension along the area of the Al-Abbasia to the borders of the province of
Qadisiyah, where irrigate 55000 acres and discharge of operation 210m3/s..
a- Water supply system: the river represents the supply source for many
water treatment plants such as Al-Abbasia water treatment plants.
b- Irrigation: the river is the main source of the irrigation for large
agricultural areas locating on both sides of the branch Fig. (4-1).
Fig(4-1) Al-Abbasia branch.
Coordinates Distance
Accumulated
Abbreviation between
Stations distance
stations
X Y Km
km
A1
Al-Haidary 3540244 451496 0
----------
Abu-gharab A2 3552026 445861 5.5 5.5
Almuwash A3 3548065 449188 13 18.5
A4 23.5
AL-Tawela 3547069 453935 5
Fig (4-2) Stations location for water quality monitoring along the River.
Fig (4-3) Pollution of the AL-Abbasia branch.
Fig (4-4) Pollution of the AL-Abbasia branch.
CHAPTER FIVE
ئ
The highest value recorded was (37.3) (NTU) at station (A3) in March
2016, while the lowest value was (2.1) (NTU) at station (A1) in April 2016.
The maximum concentrations of turbidity exceeded WHO standards for
drinking water. Fig. (5-1) shows the maximum and minimum of the turbidity
during the period of the study for surface water and for all stations.
Turb.NTU
37.3
40
35
30
25
20
15
10 13.6 13.2
5 11.7
0
4.4
2.1 2.6 2.5
Fig. (5-1) The maximum and minimum values of the turbidity during
the period of the study at all stations.
5.1.2 Hydrogen power (pH):
The highest value recorded was (9.3) at station (A4) in April 2016,
while the lowest value was (7.2) at stations (A4) in March 2016. In general,
the maximum and minimum concentrations of pH were within WHO for
drinking water. Fig. (5-3) shows the max. and min. of the pH during the
period of the study.
pH
9.3
10
8.3 8.4 8.3
8
7.5 7.3 7.2
8
0
st.A1 st.A2 st.A3 st.A4
minmax
Fig. (5-2) The maximum and minimum values of the (pH) during
the period of the study at all stations.
The highest value recorded was (1626) (µs/cm) at station (A4) in April
2016, while the lowest value was (1011) (µs/cm) at station (A1) in march
2016. The maximum concentrations of conductivity exceeded WHO for
drinking water. Fig. (5-3) shows the max. and min. of the conductivity (EC)
during the period of the study.
EC. µS/cm
1800 1626
1600
1400 1300 1306 1270
1200 1126 1084
1000 1011 1012
800
600
400
200
0
Fig. (5-3) The maximum and minimum values of the conductivity during
the period of the study at all stations.
The highest value obtained was (602) mg/l as CaCO3 at station (A4) in
April 2016, while the lowest value obtained was (336) mg/l as CaCO 3 at
station (A2) in (May) and 2016. The maximum of total hardness
concentrations exceeded WHO standards for drinking water. Fig. (5-4) shows
the max. and min. of the total hardness during the period of the study.
TH mg/l
700 602
600
500 461 465 452
376 366
400 350 336
300
200
100
0
Fig. (5-4) The maximum and minimum values of total hardness during
the period of the study at all stations.
5.1.5 Calcium (Ca++):
The highest value obtained was (150) (mg/l) at station (A4) in March
2016. The lowest value was (84) (mg/l) at station (A2) during June 2016.
The maximum of calcium concentrations exceeded WHO standards for
drinking water. Fig. (5-5) shows the max. and min. of the calcium during the
period of the study for surface water and for all stations.
Ca mg/l
150
160
140
116 116 113
120
100 94 91
88 84
80
60
40
20
0
The highest value obtained was (55.3) (mg/l) at station (A4) in April
2016. The lowest value was (30.7) (mg/l) at station (A2) in June 2016. All
values of magnesium concentrations were within WHO for drinking water.
Fig. (5-6) shows the max. and min. of the magnesium during the period of
the study.
Mg mg/l
60 55.3
20
10
The highest value obtained was (170) (mg/l) at station (A4) in April
2016. The lowest value was (112) (mg/l) at station (A1) in June 2016. All
values of chloride concentrations were within WHO standards for drinking
water. Fig. (5-7) shows the max. and min. of chloride during the period of the
study.
Cl mg/l
170
180
160 140 140 138
140
120 120 118
112 112
100
80
60
40
20
0
The highest value obtained was 1178 (mg/l) at station (A1) in Jan
2016, while the lowest value obtained was (580) (mg/l) at station (A2) in
March 2016. The maximum concentrations of the total dissolved solids
exceeded WHO standards for drinking water. Fig. (5-8) shows the max. and
min. of total dissolved solids during the period of the study.
TDS mg/l
1178
1200 1050
1000 900
842
800682 692
610 580
600
400
200
Fig. (5-8) The maximum and minimum values of total dissolved solids
during the period of the study at all stations.
The highest value recorded was (122.5) (mg/l) at station (A4) in April
2016 and the lowest value was (60.9) (mg/l) at station (A1) in May 2016.
The maximum concentrations of sodium exceeded WHO standards for
drinking water. Fig. (5-9) shows the max. and min. of sodium during the
period of the study.
Na mg/l
140 122.5
120 103
94 96.6
100
80
65.2 68.1 66.9
60.9
60
40
20
0
The highest value recorded was (9.5) (mg/l) at stations (A4) in April
2016 and the lowest value was (3.6) (mg/l) at stations (A2) in May 2016. The
maximum concentrations of potassium exceeded (WHO)standards for
drinking water. Fig. (5-10) shows the max. and min. of potassium during the
period of the study.
K+ mg/l
9.5
10
8
6
6 5 5.1
4.5 4.2
3.9 3.6
4
0
st.A1 st.A2 st.A3 st.A4
min
max
Fig. (5-10) The maximum and minimum values of potassium during the
period of the study at all stations.
5.1.11
Sulphate SO4-2
The highest value recorded was (510) (mg/l) at stations (A4) in April
2016 and the lowest value was (224) (mg/l) at stations (A2) in May 2016.
The maximum concentrations of potassium exceeded WHO standards for
drinking water. Fig. (5-11) shows the max. and min. of potassium during the
period of the study.
SO4 mg/l
600
510
500
354 351 339
400
300 248 257 247
224
200
100
Fig. (5-11) The maximum and minimum values of sulphate during the
period of the study at all stations.
The highest value recorded was (82) (mg/l) at stations (A3, A4) in Jan
2016 and the lowest value was (12) (mg/l) at stations (A3) in Feb 2016. The
maximum concentrations of potassium exceeded WHO standards for
drinking water. Fig. (5-12) shows the max. and min. of potassium during the
period of the study.
Tss mg/l
90 82 82
76
80 70
70
60
50
40
30
20
22
10 16
0 12
6
Fig. (5-12) The maximum and minimum values of (TSS) during the
period of the study at all stations.
gg
The water quality index (WQI) along Al-abassia Branch within Al-Najaf
province has been calculated using the (WAM) method by some parameters
of raw water that were studied in respect to their suitability for human
consumption. The descriptive statistical analysis for the collected water
quality parameters are shown in table (5-1).
Table (5-1) Descriptive statistical of mean water quality values along Al-
abbasia Branch within Al-Najaf province during 2016.
Stations
&
Mean A4 A3 A2 A1
paramet
ers
7.945 7.91 7.82 7.98 8.08 pH
9.78 6.62 17.5 8.08 6.92 Turb.
Based on the WQI value (using eq. 3-5), water was categorized into five
groups ranging from Excellent water to Unfit and unsuitable for drinking.
Where K: is the proportionality constant assigned to the parameter which is
also weighed according to its relative importance in the quality of water for
drinking purposes. These weights have a range from 1 to 5 and it is given in
table (5-2). The unit weight (wi) for all the eleven chosen parameters with
standard values are given in table (5-2) . The computed overall WQI value of
all the samples and stations along Al-abbasia Branch was (86.66) which
implied that the water was generally "Very poor" as shown in table (5-3) and
fig. (5-13). The computed monthly overall WQI along Al-abassia Branch for
all samples and stations was (87.5), which implied that the water was
generally "Very poor" as shown in table (5-4). The monthly WQI variation
ranged higher value (98.793) at April 2016, and lower value (76.58) in Jun
2016 along Al- abassia Branch, and classified (Very poor water quality) as
shown in fig. (5- 14). The annual branch water quality index variation along
Al-abassia Branch ranged (84.064) "very Poor quality" at the upstream near
station (A1) and (85.612) "Very poor" at the downstream near station (A4)
which reflected the effects of pollution as shown in table (5-5) and fig. (5-
15). The high value of WQI was obtained as a result of the various human
activities taking place at the branch bank.
Table (5-2) Water quality parameter standards, assigned and unit
weight (Atef ,2015).
Standar
Water quality Proportional Unit weight
d value
Parameters weight (K) factor (wi)
(Si )
pH 6.5-8.5 4 0.118
Turb. 10 3 0.088
EC 1000 4 0.118
SO4-2 250 4 0.118
TDS 1000 4 0.118
TH 300 3 0.088
Ca+2 200 2 0.059
Mg+2 50 2 0.059
Na+ 200 2 0.059
K+- 12 1 0.029
Cl 250 3 0.088
TSS 25-40 2 0.059
34 1.00
Table (5-3) Computed overall WQI values of drinking water along Al-
abassia Branch.
Unit Proporti
Quality Ideal Standar Measure
WQI weight onal Paramet
rating value d value d value
factor weight ers
(qi)
(wi*qi) (wi) (K) (V10) (Si ) (Vi )
7.434 63 0.118 4 7 6.5-8.5 7.947 pH
8.6064 97.8 0.088 3 0 10 9.78 Turb.
13.7671 116.67 0.118 4 0 1000 1166.75 Ec
14.1057 119.54 0.118 4 0 250 298.863 So4
9.0414 76.622 0.118 4 0 1000 766.22 TDS
11.9363 135.64 0.088 3 0 300 406.94 T.H
2.99897 50.83 0.059 2 0 200 101.66 Ca+2
4.38252 74.28 0.059 2 0 50 37.14 Mg+2
2.31133 39.175 0.059 2 0 200 78.35 Na+
1.12616 38.833 0.029 1 0 12 4.66 K+
4.38944 49.88 0.088 3 0 250 124.72 Cl-
6.56375 111.25 0.059 2 0 25-40 44.5 Tss
86.6631 sum
100
80
75-100
WQI(86.66)
50-75
60 26-50
40
20 0-25
0
months
98.793 94.54
85.66 90.92 90.54
10083.18382.544 84.696
76.58
80
60
40
20
0
W…
Jan.FebMarAprMayJunJulAugSep
WQI
STATIONS
93.511
95
90
85.612
84.064 83.561
85
80
W…
75
st.A1 st.A2 st.A3 st.A4
WQI
6.1 Conclusions:
1. The maximum concentrations of (Cl-, Ca+2, Mg+2, EC, TH, Na+, K+ and
TDS) for surface water in April 2016.
2. The deterioration increased of water quality of Al-abassai Branch
during 2016-2017 because there are many agricultural drainages
surrounding the branch.
3. The results showed that the maximum values of (pH, TH, EC, TDS,
SO4-2, Mg+2and Turb.) were exceeded world health organization
(WHO) standards for drinking water. This means that the water is
certainly unfit for drinking purposes ( without treatment).
(
6.2Recommendations: -
6- Semenov, V., Einax, J.W., Stanimirova, I., and Kraft, J., (2002).
Environmetric modelling and interpretation of river water monitoring data.
Anal. Bional. Chem.
10- MWH, (2005), "Water Treatment Principals and Design", 2nd edition John
Wiley and Sons, Inc. Hoboken N.J.
12- Osmonics, (1997), "Pure Water Handbook", 2nd edition, Osmonics, Inc.
14- Tiwari, T.N. and Mishra, M., (1985), "A Preliminary Assignment of Water
Quality Index to Major River", Ind. J. Environ Protect 5, pp.276.
15- Layla Abd Al-kareem, (2012), "Assess the stability of the treated water
from water treatment plants in Babylon province". Thesis, M. Sc.,Department
of Environmental College of Engineering, Babylon University.
16- Awatif S., Basim H., and Ali A., (2013), "Application of Water Quality
Index and Water Suitability for Drinking of the Euphrates River within Al-
Anbar Province, Iraq", Journal of Engineering, No.(12), Vol.(19) December
2013.
إقرار المشرف
:أقر بأن المشروع
ASSESSMENT OF DRINKING WATER
FOR AL-ABBASIA BRANCH USING
WATER QUALITY INDEX
ت العلمية للقسمmاجري تحت اشرافي ووفقا للمتطلبا
المشرف
إقرار اللجنة
نؤيد بأننا اطلعنا على المشروع الموسوم:
ASSESMENT OF DRINKING WATER
FOR AL-ABBASIA BRANCH USING
WATER QUALITY INDEX
وكلجنة مناقشة قد تمت مناقشة الطالب (وسام صباح
ومحمد كريم وموفق عبد األيمة) في محتويات هذا
المشروع ونرى بانه قد اجتاز متطلبات نيل شهادة
البكالوريوس في الهندسة المدنية.
رئيس اللجنة:
التوقيع:
التاريخ:
عضو اللجنة:
التوقيع:
عضو اللجنة:
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