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Course Project
Due date: Tuesday, April 23, 2019 Time: 5.00 pm
The report (typed or scanned) must be submitted along with the Excel sheets
Important note: If the problem statement has any missing data, you may get it from the standard data
base or any Chemical Engineering books and mention the same in the report. You may refer to Solen and
Harb, Introduction to Chemical Engineering: Tools for Today and Tomorrow, 5 th Edition, 2011.
Methanol is an important solvent, which is majorly used in organic synthesis. This is originally
produced from oxidation of methane produced from fossil fuels. Due to depletion of fossil fuels, other
methods are developed. One such production process is the production of methanol from the gas phase
hydrogenation of carbon dioxide using a catalyst at high pressures and moderate temperatures. This
process reduces the carbon foot print.
mol
rA k pCO2 pH 2 pCO2 & pH 2
irreversible reaction. The rate of reaction is given by lit sec . Where, are
partial pressures of carbon dioxide and hydrogen. The rate constant is given by the Arrhenius
mol 6000
k 2
2 x10 2 exp ; T in K
lit.sec. kPa T
expression, .
The heat of the reaction as function of temperature is given by
kJ
ΔH Reaction
[ mol . K ]
=−49 .18−0 . 02T
.
The feed consists of separate streams of hydrogen and carbon dioxide at atmospheric pressure and 25 oC
in the given mole ratio (Please refer to the spread sheet attached). The feed streams need to pressurized
to the reactor pressure (assigned to you. See the attached spread sheet). The temperature of the
pressurized feed streams must be brought to the reactor temperature (assigned to you. See the spread
sheet attached). The reactor is continuously stirred tank reactor for the gas phase reaction. The
conversion in the reactor is 80% (irrespective of pressure and temperature). It is required to produce
1000 kgmoles/min methanol. The product from the reactor is cooled 30 oC to separate out methanol and
water as liquid from the unreacted products in separator #1. The liquid stream needs to be separated
further in to methanol and water using a flash separator (separator #2). What temperature you would
recommend for separator #2 (Give only a logical answer).
Technical Information:
1. The pressure drop in each cooler or heater (both are heat exchangers) is 25 psi. The pressure
drop in the reactor is 30 psi. The minimum LMTD required for all heaters and coolers is 7 oC.
2. The cooling water is available at 18 oC and the outlet cooling water temperature must not
exceed 36oC. The heat transfer coefficient for water cooled exchangers is 200W/(m 2 K).
3. For all heating purposes, saturated steam is available 350 oC and is allowed only to condense
(saturated liquid). The enthalpy of vaporization of water is 2100 kJ/(kg.K). If steam is used as a
heat exchanging fluid, the heat transfer coefficient is 1200 W/(m 2 K).
4. For all cooling purposes, cold water is available at a temperature of 20 oC from cooling tower.
The maximum coolant temperature to which it can be raised is 36 oC.
5. The cost of reactants and products are:
a. Carbon dioxide – Rs. 2800 per ton
b. Hydrogen – Rs. 1120 per kg
c. Methanol – Rs. 35,000 per ton
d. Water- Rs. 27.74 per ton
6. The cost of all the equipment can be found using Table 13.2 from Solen & Harb.
7. The M&S index for 2019 is 2190.
Important Information
1. The references are not limited. You can refer to any other relevant articles available on the
internet.
2. This document should not be uploaded at any of the public websites like Scribd, Facebook and
Twitter and so on.
3. Any updates of this document will be updated in AUMS / WhatsApp.
Course Instructor: Dr. Udaya Bhaskar Reddy Ragula