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By all measures, graphene should not exist. The fact it does comes down to some neat
loophole in physics which sees with an impossible 2D sheet of atoms behave like a good 3D
material.
The group of physicists led by researchers in the University of Arkansas didn’t set out to discover
For years scientists have believed if it had been possible to isolate the individual sheets of
graphite, leaving a 2-dimensional airplane of carbon ‘chicken wire’ to stand on its own.
In 2004 a set of physicists in the University of Manchester achieved the impossible, isolating
sheets by a lump of graphite that were an atom thick.
To exist, the 2D material had to be cheating in some way, behaving as a 3D material in order to
offer some level of robustness.
It turns out the ‘loophole’ has been the random jiggling of atoms popping back and forth, giving
the 2D sheet of graphene a handy third dimension.
TO PUT IT DIFFERENTLY, GRAPHENE WAS POSSIBLE BECAUSE IT WASN’T
PERFECTLY FLAT AT ALL, BUT VIBRATED ON A NUCLEAR LEVEL IN SUCH A
WAY THAT ITS OWN BONDS DIDN’T SPONTANEOUSLY UNRAVEL.
“The students felt we weren’t likely to learn anything useful,” states Thibado, “but I thought if we
were asking too easy a question”
Thibado pushed the experimentation into another direction, searching for a pattern by
altering the way that they looked at the information.