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On 10 July, 2006, three concrete ceiling panels, each weighing 3.5 tons, Two rows of 12 ft. x 8 ft. ceiling panels each weighing 4700 lbs. and one
collapsed from the roof of the tunnel (Fort Point Channel Tunnel that row of 6 ft. x 8 ft. ceiling panel weighing 2500 lbs. fell on a car that was
connects to Ted Williams Tunnel in the city of Boston, USA). travelling in the tunnel at that time.
This accident killed one woman, who was sitting on the passenger seat of a Three rows of concrete ceiling panels fell from the roof of the tunnel.
car, and injured her husband who was on the driver’s seat.
This tunnel was part of a mega project known as the Big-Dig which started
construction in 1991 and finished in December 2007.
Initial project cost was $2.8 billion but the final cost was $14.8 billion.
Actual pictures
Epoxy
2 Originally, wedge anchor was proposed that can wedge inside the hole in
the concrete.
Bechtel changed it to adhesive anchors. Consultants had warned against
adhesive anchors which used epoxy as the adhesive as it was prone to
creeping during fire.
Wedge anchor There were signs of bolts pulling out of the concrete hole in less than 2
3
months of installation. There was delay in decision making on this and
the contractors completed the works on all the ceilings in the meantime.
The contractor had found that the diamond core drill had left the hole very
smooth with some residue material which was left at the end of the hole. No
further action was taken on this.
4 Pull test was to be done at a high load of 6350 lbs (instead of recommended
3250 lbs.) for all the lanes but the contractor insisted that it could be done
only on HOV lane as all the works had completed.
In this test of 187 bolts, 19 had pulled out. Out of the 19 bolts, 17 were
in the mock-up area and hence it was decided that the 17 had pulled out
because of the inexperience of the workers in the initial period. Hence,
there was no problem. No panel in other lanes was tested.
5 In the original design, Power-fast (Standard Set) epoxy was specified. But the 6 Post-collapse information: Investigation done after the collapse found that
project manager used Fast Set epoxy which had already shown inferior results 200 bolts in the Eastbound and Westbound tunnels (but none in HOV lane)
in tests performed in 1995-96. The standard epoxy had given satisfactory were loose.
result.
The manufacturer of the adhesive knew that Fast Set epoxy was being used
Anchor displacement
Reference:
in the tunnel and not the Standard Set epoxy
http://www.foundationperfor
mance.org/pastpresentations
/FowlerPresSlides-
10Nov10.pdf (3 April 2020)
7 Tests conducted way back in 1999 had found the problem with the method
of adhesive application. It was found that most of the bolt was bare, not
enough epoxy was applied. The holes were not filled with epoxy completely
before inserting the bolt. This had reduced the bonding strength between
the bolt and the concrete by about 38%.
Much of epoxy near the tip of the bolt was brittle and it crumbled easily.
There was dust adhered to the bolt surface which affected bonding.
The holes in the concrete were made by diamond coring drills which left
very smooth surface and the holes were not cleaned immediately giving
residue inside the hole that did not get removed even after cleaning.
Diamond coring drill left very smooth hole internal surface and hence
affected the bonding between the adhesive and the concrete.
Hole cleaning was not done immediately which left unremoved residue inside the hole.
Dust was found on the bolt surfaces
Adhesive on the failed bolts also showed voids which weakened the interface
strength
Consequence of a wrong decision should be considered before any engineering Ambient environment must be controlled:
project is started. In addition to temperature control, gaseous and humidity should also be controlled. For
example, humidity has strong influence on Nylon
For large strain, load should be changed for the same applied stress: Clamping stress should be considered in tensile tests:
The change in cross-sectional area due to large strain can mean that the stress is changing too.
Therefore, load should be gradually reduced as the cross-sectional area reduces in the same Length should be at least 10 times the diameter of the sample.
proportion for the same stress.
Extensometer or laser method should be used and strain should be measured
The loading rate immediately before measurement is to be controlled: away from the two ends.
In stress relaxation measurement, load cell should be stiff in comparison to the specimen
Creep test must be conducted over an extended period covering specific application:
𝜀 = 𝜀 sin 𝜔𝑡
𝜎 = 𝜎 sin(𝜔𝑡 + 𝛿)
A
where κ is the torsional stiffness constant and θ is the angular displacement. Λ = ln n (3.95)
Using strength of materials formulations, κ can be related to the shear modulus as, An +1
πr 4G where, An is the amplitude of the nth oscillation. For small damping,
κ= (3.92)
2l ΔA ΔA 1 ΔA2 1 2 1 3 1 4
where l is the length and r the radius of the rod, G is the shear modulus of the material. Λ = ln1 + = − ln(1 + x ) = x − x + x − x ...
An An 2 An2
2 3 4
Now, from the equation of motion for torsion pendulum (for small values of θ), the angular
speed, ω, is given as, κ Hence,
ω = 1 A2 − A2
Λ = n 2 n +1
(3.93)
I (3.96)
I is the moment of Inertia of the disk and κ is the torsional stiffness of the rod. 2 An An2 − An2+1 En − En +1 ΔE
= =
Combining Equation (3.92) and (3.93) and assuming G=G1 for small damping, we can But, A2 is proportional to stored energy, thus, An2 En E
write, πr 4G1 1 ΔE
2
ω = (3.94) Λ= = π tan δ (3.97)
2lI 2 E also, G2 = G1 tan δ
2π
Also, time period will be given as, T =
ω
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(c)
Flexure test fixtures : (a) three-point bending, (b) four-
point bending, and (c) compressive and tensile strains in
a three-point bending specimen.
(Based on Fig 4.5, p81, K P Menard, Dynamic Mechanical Analysis A Practical Guide, CRC Press, 1999) (Fig 4.7, p86, K P Menard, Dynamic Mechanical Analysis A Practical Guide, CRC Press, 1999)
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(a) (b)
Extension and sliding shear fixtures: (a) an extension
fixture for thin films or fibers. (b) A sliding plate shear
fixture using two round samples.
(Fig 4.10, p91, K P Menard, Dynamic Mechanical Analysis A Practical Guide, CRC Press, 1999)
tan δ (x10-1)
tan δ (x10-1)
Tg = Glass transition, main chain transition
gradual motion β
transition
Tm = Melting temperature or
more precisely softening
temperature
o Temperature oC
DMA of a nylon. Temperature C
(a) We can see in the storage modulus, E1, both a Tg at ~50 and a strong Tβ at – oC
Idealized DMA scan.
An idealized scan showing the effect of various molecular relaxations on the 80 oC. These are also seen as peaks in the tanδ. (b) The curves for the material
storage modulus, E1, curve. In some materials like PET, the beta transition that fails impact testing are overlaid. Note the lower modulus values and the
occurs as a broad slope, while in other it exhibits a relativity sharp drop. relatively weaker Tβ in the bad sample. Comparisons of the relative peak areas for
Tβ suggest that the second material is less able to damp vibrations below the Tg.
(Based on Fig 1.5, p19, K P Menard, Dynamic Mechanical Analysis A Practical Guide, CRC Press, 1999) (Based on Fig 1.4, p18, K P Menard, Dynamic Mechanical Analysis A Practical Guide, CRC Press, 1999)
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1
107 100
25 50 75 100 125 150
Curing in the DMA
The curing of very different materials can be studied using DMA. Both (Cake batter
and Epoxy) show the same type of curing behavior, an initial decrease in complex
viscosity (Pa.s) to a minimum followed by a sharp rise to a plateau. Note that
gelation is often taken as the E1–E2 crossover or where tan δ= 1.
(Fig 1.6, p20, K P Menard, Dynamic Mechanical Analysis A Practical Guide, CRC Press, 1999) (Fig 1.8, p22, K P Menard, Dynamic Mechanical Analysis A Practical Guide, CRC Press, 1999)
decrement, Λ
curing process starts.
Logarithmic
Temperature oC
Time–temperature studies in the DMA: We can fix the temperature and Storage shear modulus and logarithmic decrement as a function of
study property change as a function of time, environment, etc. In this case, temperature at the frequency of 3 Hz for polychlorotrifluoroethylene
an epoxy cures at 45°C and the curing reaction progresses with time. (PCTFE) and polyvinyl fluoride (PVF). (Based on Fig 6.5, p99, I M Ward and J Sweeney, “The Mechanical Properties of Solid Polymers” 2 nd
(Fig 5.1, p103, K P Menard, Dynamic Mechanical Analysis A Practical Guide, CRC Press, 1999) Edition, Wiley 2004) (originally taken from Schmieder and Wolf, Kolloidzeitschrift, 134, 149 (1953).
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(a)
(Based on Fig 6.6, p100, I M Ward and J Sweeney, “The Mechanical Properties of Solid Polymers” 2nd
Edition, Wiley 2004) (originally taken from Thompson and Woods, Trans. Faraday Soc., 52, 1383 (1956)).
Structural materials mass distribution on the Boeing 747 (year 1970), 777 (year
1995) and 787 (year 2011) airplanes
787
Composites
Aluminium
Titanium
Steel
Others
Sports
Aluminum
Steel
GFRP/CFRP
5.96 m 5.97 m
CFRP
GFRP
Bamboo, 1896
2008 2012
Stress (GPa)
Carbon Carbon fibre (Type 2) 1.75 250 2700
Honeycomb E-glass
Cellulose fibre 1.61 60 1200
Continuous fibre Discontinuous fibre 2.0
Glass (E-glass) 2.56 76 1400-2500
Unidirectional
Aligned Aramid (Kevlar) 1.45 125 2760
short fibre
1.0
Epoxy matrix 1.2-1.4 2.1-5.5 40-85
Random short
(Nanocomposites or Bidirectional
fibre Polyester matrix 1.1-1.4 1.3-4.5 45-85
microcomposites) etc.
Data from Table 25.1, p. 264, Ashby & Jones 2
0 1.0 2.0 3.0 4.0
Strain (%)
Multidirectional or
quasi-isotropic
Open cell structure Based on Fig. 3.2, p170 RJ Crawford
Important Matrices for composites Thermoplastics: Polypropylene, nylon, styrene based plastics, polyesters, acetal,
Thermoset and thermoplastic polymers and all metals. Even ceramics can also be used a matrix polycarbonate, polysulphone etc.
Unsaturated polyester resins and epoxy resins – they do not liberate volatiles during curing
Choice of the matrix depends on the application, service conditions and cost.
Thermosets:
and they can be moulded using low pressure and at room temperature Typical properties of fibre reinforced Nylon 66
Tensile properties of epoxy-based composites Material Weight Density Tensile Flexural
Material Volume Density (x1000 Tensile strength Tensile Data from Table 3.1, p171
fraction (kg/m3) Strength modulus
fraction (Vf) kg/m3) (GN/m2 or GPa) modulus RJ Crawford (Wf) (GN/m2 or (GN/m2 or
(GN/m2) GPa) GPa)
Nylon 66 - 1140 0.07 2.8
Epoxy (matrix) - 1200 0.07 6
Nylon 66/glass 0.40 1460 0.2 11.2
Epoxy/E-glass 0.57 1970 0.57 22
Nylon 66/carbon 0.40 1340 0.28 24.0
Epoxy/Kevlar 0.60 1400 0.65 40
Nylon 66/glass/carbon 0.20C/0.20 1400 0.24 20.0
Epoxy/Carbon 0.58 1540 0.38 80 G
Epoxy/Boron 0.60 2000 0.38 106 Nylon 66/glass beads 0.40 1440 0.09 5.6
Comparison of FRP with high strength steel and aluminium alloys for aircraft applications Effect of fibre content on the properties of glass fibre reinforced Nylon 66
Material Density Young’s Strength σf Fracture E/ρ σy/ρ (x Weight fractions Wf
(x1000 modulus E (MPa) toughness, KIC (x10−3 GPa 10-3 MPa
kg/m3) (GPa) (MPa m1/2) kg-1m3) kg-1 m3) Property 0 0.10 0.20 0.30 0.40 0.50 0.6
Density (kg/m3) 1140 1210 1280 1370 1460 1570 1700
Composites
Tensile strength 0.07 0.09 0.13 0.18 0.21 0.23 0.24
CFRP, 58% uniaxial C in 1.5 189 1050 32-45 126 700 (GN/m2 or GPa)
epoxy
% elongation at 60 3.5 3.5 3.0 2.5 2.5 1.5
GFRP, 50% uniaxial 2.0 48 1240 42-60 24 620 break
glass in polyester
Flexural modulus 2.8 4.2 6.3 9.1 11.2 15.4 19.6
Kevlar-epoxy (KFRP), 1.4 76 1240 54 886
(GN/m2 GPa)
60% uniaxial
Thermal 90 37 32 30 29 25 22
Metals expansion
High-strength steel 7.8 207 1000 100 27 128 (μm/m/oC)
Aluminium alloy 2.8 71 500 28 25 179 Water absorption 1.6 1.1 0.9 0.9 0.6 0.5 0.4
(24 hr)
4. For chopped fibre, length to diameter ratio is known as the aspect ratio.
σ c Ac = σ f A f + σ m Am (4.2b) L
5. For short fibre composites, greater the aspect ratio, greater will be the strength and
stiffness Geometry of deformation: Total strain in the composite
will be the same as in the fibres or the matrix
6. Volume fraction of the fibre Vf is the ratio of the volume of the fibre, vf, to the volume
of the composite vc. εc = ε f = εm (4.3) δL
Fc
Weight fraction of the fibre can be calculated from the volume fraction as follows: The stress-strain relationships will be given as, Fc
wf ρ f vf ρ f
Wf = = = Vf σ m = E mε m
wc ρ c vc ρ c (4.1) σ c = Ec ε c σ f = Efε f (4.4a, b, c)
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Combining Equation (4.2b) and (4.4) and applying F=σ A, where A is the cross-sectional area of the Strength of a composite in the longitudinal direction
specimen.
Ecε c Ac = E f ε f A f + Emε m Am (4.5) We can write Equation (4.2b) in the form of Force (= stress x area) as,
σ c Ac = σ f A f + σ m Am (4.8)
Now, using Equation (4.3), we can write, εc = ε f = εm (4.3)
Dividing both sides by Ac, we obtain,
Af A
Ec = E f + Em m Af A
σ c = σ f + σ m m
(4.6)
Ac Ac (4.9)
Ac Ac
If the fibres extend to the full length of the composite, then the area ratio Af Af L v f
= = = Vf Again, the surface ratios can be replaced with volume ratios for longitudinal fibre composites and
Ac Ac L vc
σ c = σ f (V f ) + σ m (Vm )
will be same as the volume ratio (= volume fraction). We can write, we can write,
(4.10)
Ec = E f V f + EmVm (4.7)
Now, for calculating the ultimate tensile strength of the composite, we replace the stresses to the
Equation (4.7) is also known as the rule of mixture. Similarly relations can also be written to determine maximum possible stress which is the ultimate tensile strength of the composite, the fibre and the
σ cu = σ fu (V f ) + σ mu (Vm )
strength, Poisson’s ratio, thermal conductivity etc. in the fibre direction. matrix. Thus,
(4.11)
Stress
0o 90o Unidirectional fibre volume fraction of fibre is above a critical
0o 90o σmu σfu value.
0o, 45o, 90o Matrix
σ’m This critical value is defined by the
Bi-directional fibre
following formula (at the critical point the
Strain
two lines cross each other):
Stress
45o
σ mu (1 − Vcrit ) = σ fuVcrit + σ m′ (1 − Vcrit )
Random fibre
45o σcu
90o (4.13)
Matrix Schematic Stress-Strain
behaviour of the fibre, the matrix σ cu = σ fu (V f ) + σ m′ (1 − V f ) From Figure (3.5), it is seen that the
effect of strengthening is effective only
and composites in different fibre V1
above V1. The value of V1 is obtained as
orientation arrangements. σmu σ cu = σ mu (1 − V f ) follows:
Strain
Since at the point of fracture of brittle fibres, the composite will fail which means σ’m Vcritical
σ mu = σ fuV1 + σ m′ (1 − V1 ) (4.14)
that the matrix will be stressed only up to the fracture strain of the fibre. Hence
σmu should be replaced by σ’m which is the stress in the matrix at the strain equal 0 Vf 1 σ mu − σ m′
to the fracture strain of the fibres.
Equation (4.11) can be re-written as,
σ cu = σ fu (V f ) + σ m (Vm )
′ (4.12)
Based on Figure 3.4, p175, RJ Crawford
Ref:
Fig3.5, p176, Crawford,
P267, Ashby & Jones 2
Vmax. ~0.8, Actual strength ~ 65% of the theoretical
V1 =
σ fu − σ m′
(4.15)
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σc = σ f = σm (4.17) E f Em
Also,
EcT = (4.20)
V f Em + Vm E f
200 EcL where ζ is a measure of the reinforcement geometry (aspect ratio) and it can be taken 2 for the
transverse tensile modulus (ζ =1 for shear modulus) and,
Modulus, GPa
150
Ef
−1
E
100 β is given as, β= m (4.22)
Ef
+ 2
Em
50 ET (Halpin-Tsai)
Em (Matrix)
EcT EcT (Transverse) E f Em
Brintrup gave equation for EcT as, EcT = (4.20)
0 (Equation (4.20) V f Em + Vm E f
0 0.2 0.4 0.6 0.8 1 Em′ E f
Fibre volume fraction (Vf)
EcT = (4.23)
E f (1 − V f ) + V f Em′
Inaccuracies arise due to the random distribution of the fibres rather than layered and
mismatch of the Poisson’s ratios of the fibres and the matrix. where, (
Em′ = Em / 1 −ν m2 )
Based on Fig.3.7, p179, RJ Crawford
21/05/2020
28 Using simplistic mechanics of materials approach, the shear modulus G12 for the composite can also
Normalized transverse modulus, ET/Em
Fibre volume fraction, Vf be given by the relation,
24 1 V f Vm (4.24)
0.78 = +
G12 G f Gm
20
0.75
16
Gf is actually G12f and Gm is the shear modulus of the matrix.
G f Gm
12
Or, G12 = (4.25)
0.70 V f Gm + VmG f
0.75, H-T
8 model
0.55 A further modification of Equation (4.25) was given empirically by Halpin-Tsai as,
4 0.40
0.04 (G f + Gm ) + V f (G f − Gm )
0 G12 = Gm (4.26)
(G f + Gm ) − V f (G f − Gm )
1 2 4 6 8 10 20 40 60 100 200 400 1000
Modulus ratio, Ef / Em
Comparison of Halpin-Tsai calculation (solid circles) with Adams and
Doner’s calculations for transverse modulus using finite difference
method and numerical calculation (J Composite Mater 1 (January 1967) pp 4-17)
Based on Fig 1 in J C Halpin and J L Kardos, The Halpin-Tsai Equations: A review, Polymer Engineering and Science, 16(5) (1976) 344-352.
Composite strength with fibre orientation Tensile strength in longitudinal and transverse directions and shear strength of
σcL σcT unidirectional continuous fibre composites with the following fibres (matrix is epoxy)
Fibre, f Fc
Fibre σcL (MPa) σcT (MPa) σcS (MPa) 1400
Boron
Matrix, m
Cross sectional area = A Fc (Vf=0.5) 1200 E-Glass
σcθ (MPa)
E-Glass 1082 27.6 41.4 Modmor
800
Carbon 634 6.89 27.6
L
θ
σcθ h (Thornel 25) 600
(Modmor)
200
σcT Fc Data taken from Table 4, page 480, LE Nielsen and RF Landel
0
0 10 20 30 40 50 60 70 80 90
(Mechanical Properties of Polymers and Composites, 2nd edition) θ (deg)
Fc
Longitudinal Transverse
1 cos 4 θ 1 1 sin 4 θ (4.27)
= + 2 − 2 cos 2 θ . sin 2 θ + 2 1 cos θ 4
1 1 sin θ 4
σ c2θ σ cL2 σ cS σ cL σ cT = + 2 − 2 cos 2 θ . sin 2 θ + 2 (4.27)
σ c2θ σ cL2 σ
cS σ cL σ cT
Above equation is taken from S. W. Tsai, Mechanics of Composite Materials, 1966, Air Force Mater. Lab Report, AFML-TR-66-149
Moduli of cross-ply laminated composite of boron fibre (0.7 volume fraction) in a polymer
Property control in any direction through laminates
Fibre orientation and Direction of the Tensile modulus Compressive Shear modulus
Laminates of fibre fabrics are laid one over another to achieve same properties in any stress (GPa) modulus (GPa) (GPa)
direction on the plane of the fabric. One ply and stress in the longitudinal 276 262 6.9
direction
Typically, the fibre direction is alternated by 90o which is known as cross-ply. Two plies at 90o to each other and stress 138 138 12.4
along the longitudinal direction of one
of the layers
Two plies at 90o to each other and stress 27.6 27.6 82.7
at 45o to the longitudinal direction of
One ply Two plies in cross-ply Two ply-45o each of the layers
Data taken from Table 7, page 482, LE Nielsen and RF Landel
(Mechanical Properties of Polymers and Composites, 2nd edition)
For the same fibre volume fraction, there is drastic decrease in the modulus and strength
Cross-ply Laminate composite
from single ply to two plies as the interface become the weakest zone where fracture
Stress
initiates.
90o layer cracks
For multi layered laminates, the layers should be stacked symmetrically on both sides of
the central plane.
Strain