PRACTICA CALORIMETRIA

Tabla de datos experimentales

T amb 23.1 22.9 23.3 23.4 23.5 23.6
Tiempo (min)
0 10 20 30 40 50
CDistancia (cm)
0 27.9 50.9 56.8 59.3 60.1 60.8
A 5 25.2 41.0 46.1 48.1 48.8 49.4
L 10 24.6 34.4 38.7 40.4 41.0 41.5
15 24.6 30.5 34.1 35.7 36.1 36.5
E 24.6 28.0 31.0 32.4 32.7 33.2
20
N 25 24.3 26.4 28.9 30.2 30.5 30.9
T 30 24.2 25.5 27.7 28.9 29.3 29.6
A 35 23.9 25.0 27.1 28.2 28.5 28.8
M
V= 10.6 v
IE
I= 0.4 A
N n= 8
T
O

alumnos:
Jose Roberto Ramirez Segundo
Derick Daniel Lopez Lovera
2PM32
 23.9 23.5 23.1 23.4
empo (min) Tm
60 65 70
60.4 60.9 61.1 55.35556
48.7 49.5 49.7 45.16667
41.1 41.6 41.8 38.34444
36.4 36.6 36.8 34.14444
33.1 33.2 33.4 31.28889
30.9 31.0 31.1 29.35556
29.7 29.7 29.7 28.25556
28.9 28.9 28.9 27.57778
∑= 289.48889

10

20

30

40

50
 GRAFICA 1 (T vs t vs x)

70.0
60.0
50.0
40.0
30.0
20.0
10.0

10 0.0

20 0

5
30
10
40
15
50
20
60
25
65
30
70
35
 GRAFICA 2 (T vs t)

70.0

60.0

70.0
60.0 50.0

50.0
40.0 40.0
30.0
T (°C)

0.0 30.0
.0

20.0

10.0

0.0
0 10 20 30 40 50

t (min)
2 (T vs t)

10

15

20

25

30

35

40 50 60 65 70

t (min)
 𝑄_𝑖𝑛𝑖𝑐𝑖𝑎𝑙−𝑄_𝑋−𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜=0 K BTU
°F=32 56
°F=212 60
𝑄_𝑖𝑛𝑖𝑐𝑖𝑎𝑙−𝑄_𝑋=𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜 °F=752 67

𝑄_𝑖𝑛𝑖𝑐𝑖𝑎𝑙=𝑃=𝑉𝐼
𝐹𝑙𝑢𝑥=𝑄𝑥/𝐴 X (Temp)
0

100
𝑄_𝑋=𝑘𝐴 𝑑𝑇/𝑑𝑋 400
∑ 500

68
Datos
V= 10.6 v 66
I= 0.4 A
64
Qi= 4.24 W
Tambprom= 23.4 °C 62

60

58

56

54

52

50
0 50 100 150 200 250

𝑄_𝑖𝑛𝑖𝑐𝑖𝑎𝑙−𝑄_𝑋=𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜
𝑄_𝑖𝑛𝑖𝑐𝑖𝑎𝑙−𝑄_𝑋=𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜

𝑇="a+b" 𝑥" "

𝑥^2
𝑇="-0.000042 " 𝑥^2 "+
"+56.0
Estado Estacionario
X T
0 61.1
5 49.7
10 41.8
15 36.8
20 33.4
25 31.1
30 29.7
35 28.9

𝑄_𝑋=−𝑘𝐴 𝑑𝑇/𝑑𝑋

X T
0 61.1
5 49.7
10 41.8
15 36.8
20 33.4
25 31.1
30 29.7
35 28.9
 °C=0
°C=100 alumnos:
°C=400 Jose Roberto Ramirez Segu
Derick Daniel Lopez Love
2PM32
K X^2 X^3 X^4 XK X^2K
56 0 0 0 0 0

60 10000 1000000 100000000 6000 600000

67 160000 64000000 2.56E+10 26800 10720000
183 170000 65000000 2.57E+10 32800 11320000

Σ𝑌=𝑎𝑁+𝑏Σ𝑥+cΣ𝑥^2
Σ𝑋𝑌=𝑎Σ𝑥+𝑏Σ𝑥^2+cΣ𝑥^3
Σ𝑋^2 𝑌=𝑎Σ𝑥^2+𝑏Σ𝑥^3+cΣ𝑥^4

183=3𝑎+500𝑏+170000c
32800=500𝑎+170000𝑏+65000000c
11320000=170000𝑎+65000000𝑏+257000

100 150 200 250 300 350 400 450

𝑋=𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜
𝑋=𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜

𝑇="a+b" 𝑥" "+"c "

𝑥^2
000042 " 𝑥^2 "+0.044167 " 𝑥"
 K (BTU) K (Kcal)
5.854E+01 8.711E+01
5.809E+01 8.644E+01
57.773365 8.597E+01
57.5689067 8.566E+01
57.428685 8.545E+01
57.3332829 8.531E+01
57.2749963 8.523E+01
57.2416163 8.518E+01

𝐴 𝑑𝑇/𝑑𝑋 𝐹𝑙𝑢𝑥=𝑄𝑥/𝐴

Qx Qperdido Flux
21838.9588 -21834.7188 198.615435
15017.4605 -15017.4605 136.576999
9504.72182 -9504.72182 86.4411384
6404.99445 -6404.99445 58.2505225
𝑄_𝑖𝑛𝑖𝑐𝑖𝑎𝑙−𝑄_𝑋−𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜=0
4322.23691 -4322.23691 39.3087863
2626.55625 -2626.55625 23.887339
1499.36344 -1499.36344 13.6360311
𝑄_𝑖𝑛𝑖𝑐𝑖𝑎𝑙−𝑄_𝑋=𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜
61214.2921 -61210.0521 556.716251
𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜= -61210.0521 kcal/
 a b
3 500
Jose Roberto Ramirez Segundo ∆s= 500 170000
Derick Daniel Lopez Lovera 170000 65000000
3 500
500 170000

T.I b
183 500
∆a= 32800 170000
11320000 65000000
183 500
𝑥^3 32800 170000

3+cΣ𝑥^4 a T.I
3 183
∆b= 500 32800
00c 170000 11320000
3 183
𝑏+65000000c 500 32800

5000000𝑏+25700000000c
a b
3 500
∆c= 500 170000
170000 65000000
3 500
500 170000
 𝑄_𝑖𝑛𝑖𝑐𝑖𝑎𝑙=𝑃=𝑉𝐼
Q(inicial)= 4.24
V (volts)= 10.6
I (Amperes) = 0.4
Radio (cm) = 0.5
Area (cm^2)= 109.956

_𝑋−𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜=0
𝑋=𝑄_𝑝𝑒𝑟𝑑𝑖𝑑𝑜

𝑑𝑜= -61210.0521 kcal/s

 c
170000
65000000 ∆s= 1.44E+14
2.57E+10
170000
65000000

c
170000
65000000 ∆a= 8.064E+15 a= 56.000
2.57E+10
170000
65000000

c
170000
65000000 ∆b= 6.36E+12 b= 0.04416666667
2.57E+10
170000
65000000

T.I
183
32800 ∆c= -6E+09 c= -4.1666667E-05
11320000
183
32800
 X T X^2 X^3 X^4 XT X^2T
0 61.1 0 0 0 0 0
5 49.7 25 125 625 248.5 1242.5
10 41.8 100 1000 10000 418 4180
15 36.8 225 3375 50625 552 8280
20 33.4 400 8000 160000 668 13360
25 31.1 625 15625 390625 777.5 19437.5
30 29.7 900 27000 810000 891 26730
35 28.9 1225 42875 1500625 1011.5 35402.5
∑ 140 312.5 3500 98000 2922500 4566.5 108632.5

N= 8

8 140 3500
140 3500 98000
∆s= 3500 98000 2922500 ∆s= 882000000
8 140 3500
140 3500 98000

312.5 140 3500

4566.5 3500 98000
∆a= 108632.5 98000 2922500 ∆a= 5.285E+10 a=
312.5 140 3500
4566.5 3500 98000

8 312.5 3500
140 4566.5 98000
∆b= 3500 108632.5 2922500 ∆b=-1784685000 b=
8 312.5 3500
140 4566.5 98000

8 140 312.5
140 3500 4566.5
∆c= 3500 98000 108632.5 ∆c= 29337000 c=
8 140 312.5
140 3500 4566.5
Σ𝑌=𝑎𝑁+𝑏Σ𝑥+cΣ𝑥^2
Σ𝑋𝑌=𝑎Σ𝑥+𝑏Σ𝑥^2+cΣ𝑥^3

Σ𝑋^2 𝑌=𝑎Σ𝑥^2+𝑏Σ𝑥^3+cΣ𝑥^4

Estado Estacionario
70.0

60.0

50.0

40.0

30.0
59.92083
20.0

10.0

0.0
0 5 10 15 20 25 30 35 40

-2.023452
𝑇="0.0333 " 𝑥^2 "-2.0235"
𝑥+"59.921 "
0.033262
 alumnos:
Jose Roberto Ramirez Segundo
Derick Daniel Lopez Lovera
2PM32

35 40

"
o Ramirez Segundo
niel Lopez Lovera
 TERMOPAR 5
0 10 20 30 40 50 60
5 25.2 41.0 46.1 48.1 48.8 49.4 48.7

X 0 10 20 30 40 50
T 25.2 41.0 46.1 48.1 48.8 49.4
X^2 0 100 400 900 1600 2500
X^3 0 1000 8000 27000 64000 125000
X^4 0 10000 160000 810000 2560000 6250000
XT 0 410 922 1443 1952 2470
X^2T 0 4100 18440 43290 78080 123500

9 345
345 18225
18225 1058625
Σ𝑌=𝑎𝑁+𝑏Σ𝑥+cΣ𝑥^2
0.70764706 -0.03731373
-0.03731373 0.0031042
Σ𝑋𝑌=𝑎Σ𝑥+𝑏Σ𝑥^2+cΣ𝑥^3 0.00041176 -4.0336E-05

Σ𝑋^2 𝑌=𝑎Σ𝑥^2+𝑏Σ𝑥^3+cΣ𝑥^4

TERMOPAR 15
0 10 20 30 40 50 60
15 24.6 30.5 34.1 35.7 36.1 36.5 36.4
 X 0 10 20 30 40 50
T 24.6 30.5 34.1 35.7 36.1 36.5
X^2 0 100 400 900 1600 2500
X^3 0 1000 8000 27000 64000 125000
X^4 0 10000 160000 810000 2560000 6250000
XT 0 305 682 1071 1444 1825
X^2T 0 3050 13640 32130 57760 91250

9 345
345 18225
18225 1058625
Σ𝑌=𝑎𝑁+𝑏Σ𝑥+cΣ𝑥^2
0.70764706 -0.03731373
-0.03731373 0.0031042
Σ𝑋𝑌=𝑎Σ𝑥+𝑏Σ𝑥^2+cΣ𝑥^3 0.00041176 -4.0336E-05

Σ𝑋^2 𝑌=𝑎Σ𝑥^2+𝑏Σ𝑥^3+cΣ𝑥^4
 60.0
65 70 Termopar 5
49.5 49.7
∑ total 50.0 f(x) = − 0.009266666666667 x² + 0.9138 x + 28.9026666666667
60 65 70 345 R² = 0.899492041014345
48.7 49.5 49.7 406.5
3600 4225 4900 18225 40.0
216000 274625 343000 1058625
12960000 17850625 24010000 64610625
2922 3217.5 3479 16815.5
30.0
175320 209137.5 243530 895397.5

18225 406.5 20.0

1058625 16815.5
64610625 895397.5
10.0
0.00041176 28.9026667
-4.0336E-05 0.9138
5.60224E-07 -0.00926667 0.0
0 10 20 30 40 5

65 70 60.0
36.6 36.8 Termopar 15
∑ total
50.0 f(x) = − 0.009266666666667 x² + 0.9138 x + 28.9026666666667
R² = 0.899492041014345
 60.0
Termopar 15

60 65 70 345 50.0 f(x) = − 0.009266666666667 x² + 0.9138 x + 28.9026666666667

36.4 36.6 36.8 307.3 R² = 0.899492041014345
3600 4225 4900 18225
216000 274625 343000 1058625
40.0
12960000 17850625 24010000 64610625
2184 2379 2576 12466
131040 154635 180320 663825
30.0

18225 307.3
1058625 12466 20.0
64610625 663825

0.00041176 25.6467451
10.0
-4.0336E-05 0.45433585
5.60224E-07 -0.0044042

0.0
0 10 20 30 40 5
 Termopar 5

67 x² + 0.9138 x + 28.9026666666667

0 30 40 50 60 70 80

Termopar 15

7 x² + 0.9138 x + 28.9026666666667
 Termopar 15

7 x² + 0.9138 x + 28.9026666666667

30 40 50 60 70 80
alumnos:
Jose Roberto Ramirez Segundo
Derick Daniel Lopez Lovera
2PM32
 T amb 23.1 23.0 23.1 23.4 23.3
Tiempo (min)
0 2 5 7 10
Distancia (cm) 0 86.3 73.9 57.4 51.0 44.4
5 66.7 62.9 51.5 46.3 40.9
E 10 53.1 52.2 46.0 42.1 37.8
N 15 44.4 44.3 41.4 38.8 35.6
F 20 38.6 38.6 37.4 35.7 33.6
RI 25 34.8 34.8 34.4 33.4 31.9
A 30 32.5 32.6 32.5 31.9 31.0
35 31.4 31.5 31.5 31.1 30.3
M
IE
N V= 14.2
T I= 0.5
O n= 8

Tamb prom = 22.2

tiempo TEMPERATURt^2 t^3

0 66.7 0 0
2 62.9 4 8
5 51.5 25 125
7 46.3 49 343
10 40.9 100 1000
5
SUMA 24 268.3 178 1476

matriz A
5 24 178
24 178 1476
178 1476 13042

0.82363112 -0.28979827 0.0215562

-0.28979827 0.19323343 -0.01791354
0.0215562 -0.01791354 0.0018098
Usando el metodo de ecuaciones diferenciales se sabe que:

𝑑𝑇/𝑑𝑡=𝑘(𝑇−𝑇𝑎)
Aplicando c. integral: ln⁡|𝑇−𝑇𝑎|=𝑘𝑡+𝑐

𝑒^ln⁡|𝑇−𝑇𝑎| =𝑒^(𝑘𝑡
𝑇−𝑇𝑎=𝑒^𝑘𝑡 𝑒^𝑐
𝑇−𝑇𝑎=𝐶∗𝑒^𝑘𝑡

Ta= 22.2

distancia t T Ta
5 0 66.7 22.2
15 1 44.3 22.2

𝑄𝑥=𝑘(𝑇−𝑇
Radio(cm)= 0.5
Area(cm^2)= 109.956 t T Qx
0 66.7 -3424.69676
 2 62.9 -3132.25074
5 51.5 -2254.9127
7 46.3 -1854.72341
10 40.9 -1439.14223
 115.9
Termopares enfriamiento
Tm tvT
60
62.6 0 1 2 5
53.7 50 5 49.7 48.5 46.3 41.8
46.2 15 36.8 36.7 36.5 35.3
40.9
40
36.8
33.9
30
32.1
31.2
∑= 337.3 20

10

0
0 2 4 6 8 10 12

Termopar 5 Termopar 15

14
t^4 tT t^2T
0 0 0
16 125.8 251.6
625 257.5 1287.5 12

2401 324.1 2268.7

10000 409 4090
10
13042 1116.4 7897.8

8
matriz b
268.3
1116.4
6
7897.8

67.6959654
-3.50466859 4
0.07827089

0
30 35 40 45 50
 2

0
30 35 40 45 50

ln⁡|𝑇−𝑇𝑎|=𝑘𝑡+𝑐

𝑒^ln⁡|𝑇−𝑇𝑎| =𝑒^(𝑘𝑡+𝑐)
𝑇−𝑇𝑎=𝑒^𝑘𝑡 𝑒^𝑐
𝑇−𝑇𝑎=𝐶∗𝑒^𝑘𝑡

𝑇−𝑇𝑎=𝐶∗𝑒^𝑘𝑡

Cuando:
𝑇−𝑇𝑎=𝐶∗𝑒^(𝑘(0))
Ta= 22.2
t= 0 𝑇−𝑇𝑎=𝐶
T= 66.7
c= 44.5

𝑄𝑥=𝑘(𝑇−𝑇𝑎)𝐴
miento

7 12
37.3 32.8
33.1 30.4

8 10 12 14

ermopar 15

45 50 55
45 50 55

Cuando:
Ta= 22.2
36.7−23.23=26.4667∗𝑒^(𝑘(1))
t= 1
T= 44.3 ln⁡|(𝑇−𝑇𝑎)/𝑐|=𝑘
C= 44.5
0.49662921
K= -0.69991158
 Por lo tanto: 𝑇−𝑇𝑎=𝐶∗𝑒^3
7∗𝑒^(𝑘(1)) Ta= 22.2
t=
C=
3
44.5
𝑇=𝐶∗𝑒^3+Ta
k= -0.69991158
T= 27.6507567 𝑇="26.7197704 "
∗𝑒^3+Ta
197704 "