Professional Documents
Culture Documents
Troy Fraebel
Corrosion Specification Specialist
Incorporated in 1866
Henry Sherwin
Edward Williams
1
Over 3,325 Service Centers
2
Agenda
• Structural Joints Using High Strength Bolts and
Coatings Qualified for Class A or Class B Slip
• Surface Preparation of Steel (SSPC-SP 1 to SP 15)
• Steel Primers
– Zinc-rich
– Epoxy
– MCU
– Alkyd
– Acrylic
• High Performance
Steel Topcoats
– Fluoropolymers
– Polysiloxanes
– Polyurethanes
– Acrylic
Protective & Marine Coatings
Slip-Critical
Joint
3
Standards Organizations
Involved
“Familiarity with the referenced AISC, ASCE, ASME, ASTM and SSPC specification
requirements is necessary for the proper application of this Specification.”
4
Why Blast
Clean?
• Clean and Profile
Standards
SSPC-SP 1 Solvent Cleaning
SSPC-SP 2 Hand Tool Cleaning
SSPC-SP 3 Power Tool Cleaning
SSPC-SP 5 / NACE 1 White Metal Blast Cleaning
SSPC-SP 6 / NACE 3 Commercial Blast Cleaning
SSPC-SP 7 / NACE 4 Brush-Off Blast Cleaning
SSPC-SP 8 Pickling
SSPC-SP 10 / NACE 2 Near-White Blast Cleaning
SSPC-SP 11 Power Tool Cleaning to Bare Metal
SSPC-SP 12 / NACE 5 Surface Preparation and Cleaning of Steel
and other Hard Materials by High and Ultra
High Water Jetting
SSPC-SP 14 / NACE 8 Industrial Blast Cleaning
SSPC-SP 15 Commercial Power Tool Cleaning
SSPC-SP 16 Brush-Off Blast Cleaning of Coated and
Uncoated Galvanized Steel,
Stainless Steels, and Non-Ferrous Metals
5
SSPC-SP2 Hand Tool Cleaning
“Hand Tool Cleaning removes all loose mill scale, loose rust,
loose paint, and other loose detrimental foreign matter. It is
not intended that adherent mill scale, rust, and paint be
removed by this process. Mill scale, rust, and paint are
considered adherent if they cannot be removed by lifting with
a dull putty knife.
knife ”
6
SSPC-SP10 Near-White Blast
“A Near-White Blast cleaned surface, when viewed without
magnification, shall be free of all visible oil, grease, dust, dirt,
mill scale, rust, coating, oxides, corrosion products, and other
foreign matter, except for staining as noted below…
7
Centrifugal Blast Cleaning
• Savings of time, labor, energy,
and abrasive
• Superior, more uniform cleaning
Active/Anodic
Magnesium
Zinc
Aluminum
Cadmium
Tin Mill Scale
Lead
Steel
Iron
Copper
410 Passive
304 Passive
Silver
Graphite
Gold
Platinum
Passive/Cathodic
SSPC-VIS 1
8
The plies of slip-
critical joints with
coated faying
surfaces shall not
be assembled
before the coating
has cured for the
minimum time that
was used in the
qualifying tests.
Appendix A
Purpose and Scope
The purpose of this testing procedure is
to determine the mean slip coefficient of
a coating for use in the design of slip-
critical joints. Adherence to this testing
method provides that the creep
deformation of the coating due to both
the clamping force of the bolt and the
service-load joint shear are such that the
coating will provide satisfactory
performance under sustained loading.
9
Definition of Essential
Variables
• The time interval between application of the
coating and the time of testing
Testing
Configurations
10
Protective & Marine Coatings
NO Masking
Reduced Cost
11
Barrier
• Most coatings serve as a protective
barrier by isolating the metal from the
environment. Film reinforcement further
slows this action down.
Inhibitive
• Some pigments used in manufacturing primers
control corrosion by forming inhibitive
compounds.
• Th
These compoundsd are slightly
li htl soluble
l bl iin water,
t
and upon contact with water vapor, passivate
the substrate.
Active/Anodic
Sacrificial Magnesium
• When a zinc coating is applied to steel, Zinc
Aluminum
the zinc, being more “active” than the Cadmium
steel, sacrifices itself to protect the steel Tin
from corrosion. Lead
Steel
I
Iron
• This is based on the galvanic series. Copper
410 Passive
304 Passive
Silver
Graphite
Gold
Platinum
Passive/Cathodic
12
Class B Primers
• Two or three-component, solvent-based,
inorganic, ethyl silicate, zinc-rich coating
• Two or three-component, water-based,
inorganic, zinc silicate coating
• Two or three-component catalyzed polyamide
epoxy, organic zinc-rich coating
• Three-component water based organic amine
• adduct zinc-rich coating
• Moisture-cured urethane (MCU) zinc primer
• Non-zinc Epoxy Primer
Zinc-Rich Primers
Contain High Percentage of Zinc Dust in the
Dried Film So That There Is Direct Contact
Between Zinc Particles and Steel
13
Corrosion Rate of Zinc vs. pH
60
Relative Corrrosion Rate
50
40
30
20
10
0
0 2 4 6 8 10 12 14 16
pH
• Shop Application
• Performance Similar to
Galvanizing
• Heat Resistance to 750 F
• Low Temperature Application
Fabrication Shop
Paint Booth
Application of
Zinc Rich Primer
14
Organic Zinc Rich
• Tolerates Less Stringent Surface Preparation
Class A Primers
• Standard two-component fast cure
epoxy
15
Epoxy Primers
• Epoxy Resins or Emulsions of Epoxy
Resins Which Cross-Link with Polyamides,
Amines, or Other Hardeners.
• They Cure by Polymerization - The
chemical joining of polymer chains
Catalyzed Epoxies
16
Solvent Based Epoxy
Limitations
• Barrier Protection Only
• Two-Component, Limited Pot Life
• Chalks and Fades on Exterior
Exposure
• Recoat Window Restrictions
• Solvent Odor
• Special Application Equipment
Might be Required
Protective & Marine Coatings
Manufacturer
Certifications
Available
17
Non-Slip Critical Primers
Alkyds
• Synthetic Resins Derived From a Reaction
Between an Alcohol and an Acid. The Resins
are Blended With Drying Oils and
18
Drying Oil Amount
Aromatic Aliphatic
Solvent Res. Solvent Res.
P
Poor Penetrates
P t t
Penetration Rust
Fast Long Recoat
Recoatability Time
(2 Hrs)
Harder Film Softer /
Quickly Pliable Film
Embrittles
Quickly Good Exterior
Chalks Durability
Industrial Acrylics
• Cure by Solvent
Evaporation
AND Coalescence
• Co-Solvents (coalescing
solvents) act as plasticizers
for acrylics. These co-
solvents contribute VOC’s to
WB coatings. Co-solvents
must remain in the film until
evaporation.
19
“Ambient Cure” WB Acrylics
O2
Primers
and
Topcoats
“Regular” Acrylics “Ambient Cure” Acrylics
High Performance
Steel Topcoats
Fluoropolymer Urethane
• Ambient cured
• Superior color and gloss retention
• Available in a wide range of colors
• G ffiti resistant
Graffiti i t t
20
Polysiloxane Technology
• High solids epoxy siloxane combines the
properties of both a high performance epoxy
and a polyurethane in one coat
• Isocyanate-free
• Replaces a two coat epoxy/polyurethane
system
t alone
l or over zinc-rich
i i h primer
i
• High-gloss, self-priming coating
• High solids, low VOC
• Long term color and gloss performance
• Corrosion and chemical resistant
• Outstanding application properties
Polysiloxane Topcoat
Polyurethanes
• A polyurethane coating is that derived from
the reaction product of an isocyanate
component and a resin blend component.
• Polyol + Isocyanate = Polyurethane + CO2
• Good Chemical Resistance
• Hard, Yet Flexible Films
• Excellent Color and Gloss Retention
• Low-Temp, Formula Dependent
Application
• No Sweat-In Time Required
21
Types of Polyurethanes
Aliphatic
Excellent Color Retention
Excellent Gloss Retention
Primarily Used as Finish Coats
More Expensive than Aromatics
Aromatic
Yellows & Chalks in Sunlight
Yellows & Chalks in Bright Artificial Light
Used as Primers & Intermediate Coats
Less Expensive than Aliphatics
22
Mildew Resistant
Polyurethane
• Mildew Resistant
aliphatic acrylic
polyurethane
• Excellent color and
gloss retention
• Ambient Cure
• Cross-linking /
branching
• Superior Color &
Gloss Retention
http://www.paintsquare.com/sspcvideoproceedings/
?fuseaction=view&procID=6
Protective & Marine Coatings
23
Questions?
Troy Fraebel
Sherwin-Williams Company
1703 Auburn Circle
Lexington, KY 40505
859.552.7027
216.830.7977 efax
troy.e.fraebel@sherwin.com
www.sherwin-williams.com/protective
24