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Unit3td 170610080817 PDF
Unit3td 170610080817 PDF
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Assistant Professor : NAPHIS AHAMAD
MECHANICAL ENGINEERING
This relates to the 2nd law since the 2nd law predicts that
not all heat provided to a cycle can be transformed into an
equal amount of work, some heat rejection must take place.
dS 0
S 2 S1
i. Pure substances:
Any process: Δs = s2 – s1 (kJ/kgK)
Isentropic process: s2 = s1
T2 P2
s2 s1 C p , av ln R ln
T1 P1
for isentropic process
k
P2 v1
P1 s const . v2
NAPHIS AHAMAD(ME)JIT 6/10/2017
7
Isentropic Efficiency for Turbine
T1 600o C s1 8.0311 kgkJ. K
State 2 s
sat.mixture
P2 0.01 MPa
kJ
x2 s 0.984
s2 s s1 8.0311 kg . K
h 2545.6 kJ
2s kg
wa h1 h2 a State 2a
h2 a h1 wa
P2 0.01 MPa sup erheated
2660.9 kJ
kg h2 a 2660.9 kJ
kg T
2a 86.85o
C
NAPHIS AHAMAD(ME)JIT 6/10/2017
11
*
*
zero. Its value depends on the process, and thus it is not a property of
NAPHIS AHAMAD(ME)JIT 14 6/10/2017
the system. Also, in the absence of any entropy transfer, the entropy
Equation 2 has far-reaching implications in thermodynamics. For an
isolated system (or simply an adiabatic closed system), the heat transfer
∆Sisolated ≥ 0
increase entropy.
Entropy is an extensive property, and thus the total entropy of a system is equal to the sum
of the entropies of the parts of the system. An isolated sys-tem may consist of any number of
subsystems . A system and its surroundings, for example, constitute an isolated system since
both can be enclosed by a sufficiently large arbitrary boundary across which there is no heat,
work, or mass transfer . Therefore, a system and its surroundings can be viewed as the two
subsystems of an isolated system, and the entropy change of this isolated system during a
process is the sum of the entropy changes of the system and its surroundings, which is equal
to the entropy generation since an isolated system involves no entropy transfer. That is, Sgen
ones. Note that Ssurr refers to the change in the entropy of the surroundings as a
* Since no actual process is truly reversible, we can conclude that some entropy is
generated during a process, and therefore the entropy of the universe, which can be
irreversible a process, the larger the entropy generated during that process. No
The increase of entropy principle does not imply that the entropy of a
negative during a process (Fig. 3), but entropy generation cannot. The
Even when the cv(T ) and cp(T ) functions are available, performing long
two reasonable choices are left: either perform these integrations by simply
tabulate the results. But here we are going to present variable specific heats
(Exact Analysis)
conditions all these forms can not be converted completely into work. This
-Available part
-Unavailable part
could be converted into useful work by ideal processes which reduce the
system to a dead state(a state in equilibrium with the earth and its
atmosphere).
NAPHIS AHAMAD(ME)JIT 25 6/10/2017
-There can be only one value for maximum work which the system alone
• ‘Unavailable energy’ orAnergy’: is the portion of energy which could
that of the earth, transfer of energy ceases, and although the system
This section considers how the maximum amount of work available from a
that it is impossible to construct a heat engine that does not reject energy
to the surroundings
possible variations of the state of the system which do not alter its
This concept will now be generalized to consider all the possible work
equilibrium with its surroundings (i.e. not at the ambient, or dead state,
conditions)
The maximum work that can be obtained from a constant volume, closed
system
Hence, the maximum useful work which can be achieved from a closed system is W
This work is given the symbol dA
A = U + po V - TOS
It is a combination of properties
without defining both these datum levels The datum levels are what
NAPHIS AHAMAD(ME)JIT 30 6/10/2017
1 to 2 is given by
a = u + pov - Tos
= NAPHIS
( h2 AHAMAD(ME)JIT
+ v2(Po-P2) - (h1+ V1(Po – P1)) -To(S
312 - S1) 6/10/2017
Availability of a Steady Flow System
Consider a steady flow system and let it be assumed that the flowing
fluid has the following properties and characteristics; Internal energy u,
specific volume v, specific enthalpy h, pressure p, velocity c and
location z
System delivers a work output W units
=Q – To (S1 – S2)
Irreversibility